CN106904667B - 从含锰废弃物中回收提纯镍钴的方法 - Google Patents
从含锰废弃物中回收提纯镍钴的方法 Download PDFInfo
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- CN106904667B CN106904667B CN201710213748.3A CN201710213748A CN106904667B CN 106904667 B CN106904667 B CN 106904667B CN 201710213748 A CN201710213748 A CN 201710213748A CN 106904667 B CN106904667 B CN 106904667B
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- Prior art keywords
- nickel cobalt
- manganese
- acid
- cobalt manganese
- nickel
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- QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000011572 manganese Substances 0.000 title claims abstract description 36
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 238000000034 method Methods 0.000 title claims abstract description 35
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 34
- 239000002699 waste material Substances 0.000 title claims abstract description 26
- 238000004064 recycling Methods 0.000 title claims abstract description 13
- 238000000746 purification Methods 0.000 title claims abstract description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 57
- KFDQGLPGKXUTMZ-UHFFFAOYSA-N [Mn].[Co].[Ni] Chemical compound [Mn].[Co].[Ni] KFDQGLPGKXUTMZ-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000012535 impurity Substances 0.000 claims abstract description 30
- 239000007788 liquid Substances 0.000 claims abstract description 28
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000002253 acid Substances 0.000 claims abstract description 26
- 239000002893 slag Substances 0.000 claims abstract description 26
- 235000011121 sodium hydroxide Nutrition 0.000 claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 claims abstract description 14
- 239000002184 metal Substances 0.000 claims abstract description 14
- 239000000706 filtrate Substances 0.000 claims abstract description 12
- 238000007127 saponification reaction Methods 0.000 claims abstract description 12
- 239000007800 oxidant agent Substances 0.000 claims abstract description 11
- 230000001590 oxidative effect Effects 0.000 claims abstract description 9
- SOXUFMZTHZXOGC-UHFFFAOYSA-N [Li].[Mn].[Co].[Ni] Chemical compound [Li].[Mn].[Co].[Ni] SOXUFMZTHZXOGC-UHFFFAOYSA-N 0.000 claims abstract description 6
- SEVNKUSLDMZOTL-UHFFFAOYSA-H cobalt(2+);manganese(2+);nickel(2+);hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mn+2].[Co+2].[Ni+2] SEVNKUSLDMZOTL-UHFFFAOYSA-H 0.000 claims abstract description 5
- 239000012074 organic phase Substances 0.000 claims abstract description 5
- QZRMKGRPCTVXBS-UHFFFAOYSA-N 2,6,8-trimethylnonan-4-yl dihydrogen phosphate Chemical compound CC(C)CC(C)CC(CC(C)C)OP(O)(O)=O QZRMKGRPCTVXBS-UHFFFAOYSA-N 0.000 claims abstract description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 32
- 238000000605 extraction Methods 0.000 claims description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 229910052759 nickel Inorganic materials 0.000 claims description 15
- 229910017052 cobalt Inorganic materials 0.000 claims description 14
- 239000010941 cobalt Substances 0.000 claims description 14
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 229940099596 manganese sulfate Drugs 0.000 claims description 9
- 239000011702 manganese sulphate Substances 0.000 claims description 9
- 235000007079 manganese sulphate Nutrition 0.000 claims description 9
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 9
- 239000005864 Sulphur Substances 0.000 claims description 8
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 8
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 7
- 229910001385 heavy metal Inorganic materials 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- 238000002386 leaching Methods 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 3
- 239000000654 additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- UBXWAYGQRZFPGU-UHFFFAOYSA-N manganese(2+) oxygen(2-) titanium(4+) Chemical group [O--].[O--].[Ti+4].[Mn++] UBXWAYGQRZFPGU-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 18
- 239000002994 raw material Substances 0.000 description 8
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical group O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002910 solid waste Substances 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 238000011001 backwashing Methods 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000009388 chemical precipitation Methods 0.000 description 2
- 229910001429 cobalt ion Inorganic materials 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 2
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000012265 solid product Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 206010006895 Cachexia Diseases 0.000 description 1
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002696 manganese Chemical class 0.000 description 1
- KNLQKHUBPCXPQD-UHFFFAOYSA-N manganese;sulfuric acid Chemical compound [Mn].OS(O)(=O)=O KNLQKHUBPCXPQD-UHFFFAOYSA-N 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 208000016318 wasting Diseases 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/006—Compounds containing, besides nickel, two or more other elements, with the exception of oxygen or hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/10—Sulfates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (6)
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CN106904667B true CN106904667B (zh) | 2018-11-02 |
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Families Citing this family (17)
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CN110911675B (zh) * | 2018-09-15 | 2020-11-10 | 深圳市金航深海矿产开发集团有限公司 | 一种海底多金属结核制取锂电正极材料前驱体的方法 |
CN110964930B (zh) * | 2018-09-30 | 2021-07-27 | 深圳市金航深海矿产开发集团有限公司 | 一种利用海底多金属结核制备掺钇三元正极材料及其前驱体的方法 |
CN111286605B (zh) * | 2018-12-06 | 2021-09-03 | 深圳市金航深海矿产开发集团有限公司 | 一种海底多金属结核有价金属回收以及联产ncm前驱体的方法 |
CN111455171B (zh) * | 2019-01-22 | 2021-10-08 | 深圳市金航深海矿产开发集团有限公司 | 一种海底多金属结核提取有价金属并联产锂电正极材料前驱体及掺钛正极材料的方法 |
CN109868373A (zh) * | 2019-02-02 | 2019-06-11 | 广东芳源环保股份有限公司 | 一种从镍、钴、锰混合物中分步浸出镍、钴的方法 |
CN109797294B (zh) * | 2019-02-02 | 2021-11-09 | 广东芳源环保股份有限公司 | 一种镁水中回收镍、钴的方法 |
CN111180819B (zh) * | 2019-12-30 | 2021-07-27 | 荆门市格林美新材料有限公司 | 一种电池级Ni-Co-Mn混合液和电池级Mn溶液的制备方法 |
CN112626348A (zh) * | 2020-11-30 | 2021-04-09 | 贵州中伟资源循环产业发展有限公司 | 回收金属镍钴的方法和镍钴锰三元溶液的制备方法 |
CN112575195A (zh) * | 2020-12-02 | 2021-03-30 | 贵州鹏程新材料有限公司 | 一种废旧废料渣的再提取钴镍的工艺 |
CN112725628A (zh) * | 2020-12-23 | 2021-04-30 | 贵州大龙汇成新材料有限公司 | 一种从硫化锰渣中回收有价元素的方法 |
CN112678880A (zh) * | 2020-12-23 | 2021-04-20 | 贵州大龙汇成新材料有限公司 | 一种锰渣的回收利用方法 |
CN113802003A (zh) * | 2021-08-23 | 2021-12-17 | 广东邦普循环科技有限公司 | 废旧锂电池的回收及制备三元前驱体的方法 |
CN113718116A (zh) * | 2021-08-30 | 2021-11-30 | 安徽南都华铂新材料科技有限公司 | 一种从酸性富锂溶液中萃取镍钴锰的方法 |
CN114212806B (zh) * | 2022-01-18 | 2023-08-18 | 贵州红星电子材料有限公司 | 硫化镍钴锰渣的回收方法 |
CN115584400B (zh) * | 2022-09-23 | 2024-01-09 | 广东邦普循环科技有限公司 | 一种镍钴锰金属液的投料方法 |
CN115818732A (zh) * | 2022-10-28 | 2023-03-21 | 中南大学 | 一种红土镍矿高压浸出液中镍钴锰共同萃取直接制备三元前驱体的方法 |
WO2024149937A1 (en) * | 2023-01-10 | 2024-07-18 | University Of Oulu | A method for separating manganese in leaching of cobalt and/or nickel from delithiated solid raw material and use of delithiated solid raw material comprising cathode material |
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CN105206889B (zh) * | 2015-07-29 | 2018-10-26 | 浙江三晟化工有限公司 | 一种废旧镍钴锰酸锂三元电池正极材料的处理方法 |
CN105256141B (zh) * | 2015-10-26 | 2017-12-19 | 广西银亿再生资源有限公司 | 一种电镀污泥资源化处理及综合回收利用的方法 |
CN105296744B (zh) * | 2015-10-26 | 2017-10-20 | 广西银亿再生资源有限公司 | 一种红土镍矿资源化处理及综合回收利用的方法 |
CN106319228B (zh) * | 2016-08-26 | 2018-06-19 | 荆门市格林美新材料有限公司 | 一种从含镍钴锰废渣中同步回收镍钴锰的方法 |
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Denomination of invention: Recovery and purification of nickel and cobalt from manganese containing waste Effective date of registration: 20201027 Granted publication date: 20181102 Pledgee: Tongren branch of China Construction Bank Corp. Pledgor: GUIZHOU DALONG HUICHENG NEW MATERIAL Co.,Ltd. Registration number: Y2020980007234 |
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Date of cancellation: 20221104 Granted publication date: 20181102 Pledgee: Tongren branch of China Construction Bank Corp. Pledgor: GUIZHOU DALONG HUICHENG NEW MATERIAL Co.,Ltd. Registration number: Y2020980007234 |
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Denomination of invention: A method for recovering and purifying nickel and cobalt from manganese containing waste Granted publication date: 20181102 Pledgee: Tongren branch of China Construction Bank Corp. Pledgor: GUIZHOU DALONG HUICHENG NEW MATERIAL Co.,Ltd. Registration number: Y2024980006908 |