CN106715356A - 挤出的水泥基材料 - Google Patents
挤出的水泥基材料 Download PDFInfo
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- CN106715356A CN106715356A CN201580033711.1A CN201580033711A CN106715356A CN 106715356 A CN106715356 A CN 106715356A CN 201580033711 A CN201580033711 A CN 201580033711A CN 106715356 A CN106715356 A CN 106715356A
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- cement
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- weight
- starch
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- 239000000463 material Substances 0.000 title claims abstract description 105
- 239000004568 cement Substances 0.000 title claims abstract description 88
- 239000000203 mixture Substances 0.000 claims abstract description 68
- 239000010440 gypsum Substances 0.000 claims abstract description 43
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000835 fiber Substances 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 31
- 229920002472 Starch Polymers 0.000 claims description 30
- 235000019698 starch Nutrition 0.000 claims description 30
- 239000008107 starch Substances 0.000 claims description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 25
- 239000006254 rheological additive Substances 0.000 claims description 25
- 239000012783 reinforcing fiber Substances 0.000 claims description 20
- 238000001125 extrusion Methods 0.000 claims description 13
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 10
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 10
- 239000001856 Ethyl cellulose Substances 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 229920001249 ethyl cellulose Polymers 0.000 claims description 8
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 8
- 239000003365 glass fiber Substances 0.000 claims description 8
- 150000004676 glycans Chemical class 0.000 claims description 8
- -1 polypropylene Polymers 0.000 claims description 8
- 229920001282 polysaccharide Polymers 0.000 claims description 8
- 239000005017 polysaccharide Substances 0.000 claims description 8
- 239000004576 sand Substances 0.000 claims description 8
- 229920003043 Cellulose fiber Polymers 0.000 claims description 7
- 239000000428 dust Substances 0.000 claims description 7
- 235000013312 flour Nutrition 0.000 claims description 7
- 239000011435 rock Substances 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- 239000002893 slag Substances 0.000 claims description 7
- 238000007711 solidification Methods 0.000 claims description 7
- 230000008023 solidification Effects 0.000 claims description 7
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 6
- 238000005452 bending Methods 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 5
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 5
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 5
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 5
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 5
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 5
- 229920000609 methyl cellulose Polymers 0.000 claims description 5
- 239000001923 methylcellulose Substances 0.000 claims description 5
- 235000010981 methylcellulose Nutrition 0.000 claims description 5
- 239000011368 organic material Substances 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 230000006835 compression Effects 0.000 claims description 4
- 238000007906 compression Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 239000013308 plastic optical fiber Substances 0.000 claims description 4
- 102000004169 proteins and genes Human genes 0.000 claims description 4
- 108090000623 proteins and genes Proteins 0.000 claims description 4
- 229920000945 Amylopectin Polymers 0.000 claims description 3
- 229920000856 Amylose Polymers 0.000 claims description 3
- 229920001353 Dextrin Polymers 0.000 claims description 3
- 239000004375 Dextrin Substances 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 235000019425 dextrin Nutrition 0.000 claims description 3
- 229910021485 fumed silica Inorganic materials 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 229920002085 Dialdehyde starch Polymers 0.000 claims description 2
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims description 2
- MKRNVBXERAPZOP-UHFFFAOYSA-N Starch acetate Chemical compound O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)OC(C)=O)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 MKRNVBXERAPZOP-UHFFFAOYSA-N 0.000 claims description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 2
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 claims description 2
- 239000006071 cream Substances 0.000 claims description 2
- 238000005520 cutting process Methods 0.000 claims description 2
- 239000011507 gypsum plaster Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 239000004575 stone Substances 0.000 claims description 2
- 238000004078 waterproofing Methods 0.000 claims description 2
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 claims 4
- 239000001509 sodium citrate Substances 0.000 claims 4
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 2
- 239000004743 Polypropylene Substances 0.000 claims 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 2
- 229910002026 crystalline silica Inorganic materials 0.000 claims 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 2
- 229920001155 polypropylene Polymers 0.000 claims 2
- 235000012239 silicon dioxide Nutrition 0.000 claims 2
- 241000790917 Dioxys <bee> Species 0.000 claims 1
- 229910003978 SiClx Inorganic materials 0.000 claims 1
- 241000209140 Triticum Species 0.000 claims 1
- 235000021307 Triticum Nutrition 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 239000011810 insulating material Substances 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 230000002265 prevention Effects 0.000 claims 1
- 238000005096 rolling process Methods 0.000 claims 1
- 239000013049 sediment Substances 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 238000000518 rheometry Methods 0.000 abstract description 5
- 239000003562 lightweight material Substances 0.000 abstract 1
- 230000002787 reinforcement Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 9
- 239000002131 composite material Substances 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 239000004927 clay Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 229920003091 Methocel™ Polymers 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 230000001857 anti-mycotic effect Effects 0.000 description 1
- 239000002543 antimycotic Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 239000007799 cork Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910021487 silica fume Inorganic materials 0.000 description 1
- 238000009751 slip forming Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/14—Apparatus or processes for treating or working the shaped or preshaped articles for dividing shaped articles by cutting
- B28B11/16—Apparatus or processes for treating or working the shaped or preshaped articles for dividing shaped articles by cutting for extrusion or for materials supplied in long webs
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/24—Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
- B28B11/243—Setting, e.g. drying, dehydrating or firing ceramic articles
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/0048—Fibrous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
- C04B2103/0079—Rheology influencing agents
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/20—Retarders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/20—Retarders
- C04B2103/22—Set retarders
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00129—Extrudable mixtures
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/40—Porous or lightweight materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Civil Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Press-Shaping Or Shaping Using Conveyers (AREA)
- Combustion & Propulsion (AREA)
Abstract
一种由混合物形成的可挤出的水泥基材料,该混合物包含水泥、水、石膏、辅助材料、增强纤维和流变改性剂。可挤出的水泥基材料是轻质材料,其具有约1.4至2.4g/cm3范围内的密度、约5至100MPa范围内的抗压强度以及约5至35MPa范围内的抗弯强度。注意,水泥可以包含石膏,使得石膏不添加到混合物中。
Description
发明领域
本发明一般地涉及复合材料领域,更具体地涉及挤出的水泥基材料。
背景技术
一般使用大量的水以形成浆料产生水泥基材料,该浆料太湿不能挤出。
发明概述
本发明提供一种由混合物形成的可挤出的水泥基材料,所述混合物包含水泥、水、石膏、辅助材料、增强纤维和流变改性剂。注意,水泥可包含石膏,使得石膏不添加到混合物中。可挤出的水泥基材料是具有约1.4至2.4g/cm3范围内的密度、约5至100MPa范围内的抗压强度和约5至35MPa范围内的抗弯强度的轻质材料。
另外,本发明提供一种由混合物形成的可挤出的水泥基材料,该混合物包含以湿重百分比计约0.1-90%范围内的水泥、约10-60%范围内的水、以湿重百分比计约0.1-90%范围内的石膏、以湿重百分比计约0.1-50%范围内的辅助材料(例如砂、岩石、飞灰、矿渣、硅粉(silica fume)、碳酸钙等)、以湿重百分比计约1-20%范围内的增强纤维和以湿重百分比计约0.5-10%范围内的流变改性剂。注意,水泥可以包含石膏,使得石膏不添加到混合物中。
另外,本发明提供一种用于通过以下制备可挤出的水泥基材料的方法:将水泥、石膏、辅助材料、增强纤维和流变改性剂与水混合,使用挤出机通过模具挤出混合物,和使挤出的混合物凝固。注意,水泥可以包含石膏,使得石膏不添加至混合物。
另外,本发明提供了一种通过以下步骤制备可挤出的水泥基材料(复合材料)的方法:(1)将约0.1-90%湿重的水泥和0.1-90%湿重的石膏与约10-60%湿重的水混合;(2)将水泥-石膏-水混合物与约0.1-50%湿重的辅助材料(例如砂、岩石、飞灰、矿渣、硅粉、碳酸钙等)和约1-20%湿重的增强纤维共混;和(3)添加约0.5-10%湿重的流变改性剂至混合物。然后可挤出并固化(例如使静置、加热、蒸汽处理等)得到的可挤出的水泥基材料。注意,水泥可以包含石膏,使得石膏不添加至混合物。
附图简述
可通过结合附图参照以下描述更好地理解本发明的上述和其它优点,其中:
无。
发明描述
尽管下文详细讨论了本发明的各种实施方案的制备和使用,但是应当理解,本发明提供了可以在各种各样的具体上下文中体现的许多可应用的发明构思。本文所讨论的具体实施方案仅仅是说明制备和使用本发明的具体方式,而不限制本发明的范围。
以其湿的状态、具有在凝固之前加入的水的普通波特兰水泥(OPC)、铝酸钙水泥(CAC)、Sorel水泥(氧化镁和氯化镁水泥)、CSA水泥(硫铝酸钙水泥)、磷酸盐水泥或现有技术中已知的其它水泥类型,可以流变改性成粘土状材料,这允许使用称为挤出的常规粘土生产方法。
具有水的水泥可以在与多种材料诸如细石灰石、砂、石膏、硅粉、火成二氧化硅(fumed silica)、熟石膏、飞灰、矿渣、岩石、纤维素纤维、玻璃纤维、塑料纤维、PVA纤维、德兰尼特纤维等组合的复合材料组合物中作为粘结剂使用,当流变改性时可如上所述将其挤出。注意,水泥可以包含少量的石膏(例如0.3%等),因此当所需的石膏含量在该范围的下端时,可以不需要向混合物中添加石膏(见下文)。
通过添加流变改性剂来稳定水泥-石膏-水混合物,典型地以约0.5至10%湿重的量添加。
流变改性剂分为以下类别:(1)多糖及其衍生物,(2)蛋白质及其衍生物,和(3)合成有机材料。多糖流变改性剂可以进一步细分为(a)纤维素基材料及其衍生物,(b)淀粉基材料及其衍生物,和(c)其他多糖。
适合的纤维素基流变改性剂包括例如甲基羟乙基纤维素、羟甲基乙基纤维素、羧甲基纤维素、甲基纤维素、乙基纤维素、羟乙基纤维素、羟乙基丙基纤维素等。
适合的淀粉基材料包括例如小麦淀粉、预胶凝小麦淀粉、马铃薯淀粉、预胶凝马铃薯淀粉、支链淀粉、直链淀粉、海凝胶(seagel)、淀粉乙酸酯、淀粉羟乙基醚、离子淀粉、长链烷基淀粉、糊精、胺淀粉、磷酸盐淀粉和双醛淀粉。
目前优选的流变改性剂是羟丙基甲基纤维素,其实例是Methocel 240和Methocel240S。
对于挤出,使具有总湿材料的约10-60wt.%的水和适合的流变改性混合物的水泥基复合材料感觉和表现与塑性粘土相似。材料触摸起来感觉是塑性的/可变形的,并且可以类似于粘土使用粘土挤出机将其挤出,其中通过螺旋输送机将材料向前输送通过筒并且通过模具连续地形成具有形状稳定性的最终形状。
根据水含量和流变改性混合物的量,挤出的材料可具有或多或少的形状稳定性。
通过向材料中添加增强纤维,在水泥凝固之前将实现增加的稳定性。此外,已经发现纤维添加减少或消除在生产过程的干燥阶段期间的材料收缩和干燥收缩裂纹,并且进一步提供干材料的增加的抗弯强度和韧性。纤维的优选类型是纤维素(硬木或软木)纤维、塑料(基于聚乙烯醇或丙烯酸)纤维和玻璃纤维;纤维素纤维和塑料纤维主要用于目的是低于冻结或环境温度的绝缘,而玻璃纤维主要用于目的是高于环境的温度或需要耐火性的绝缘。此外,可以应用纤维类型的组合。优选的纤维长度对于纤维素纤维为约1至2mm,对于塑料纤维为约4至10mm,对于玻璃纤维为约6至20mm。优选的纤维直径为约10至40微米。
为了增加在凝固(硬化)之前可以挤出水泥基材料的时间,使用少量添加的适合的常规混凝土缓凝剂(例如,来自BASF公司的Delvo)可以将凝固时间延迟最长达数小时。可以通过使用螺旋输送机将混合物输送通过筒,并使用挤出机通过模具连续地将混合物成形为具有形状稳定性的最终形状来挤出水泥基材料。挤出后,材料将在几小时内形成最终产品的初始和最终凝固。
为了形成由OPC水泥制成的产品的最终28天强度,可以使该产品在潮湿的环境中静置约28天,或者可以借助其自身内部(放热)热产生或借助如现有技术中常规的蒸汽固化,通过加热在24-48小时内加速强度形成。
由CAC水泥、Sorel水泥、CSA水泥、磷酸盐水泥或其他水泥类型制成的产品将在24小时内达到其最终强度,并且不必需要额外的固化。
在实现最终强度形成后,将产品干燥以产生成品复合材料。硬化后,可以根据需要(例如,切割成一定尺寸、砂磨、修整、涂漆、密封、纹理化、图像化等)来精加工硬化的材料。
在一个实施方案中,可以通过用水或溶剂基硅烷喷涂产品使成品具有防水性。这种产品Protectosil BHN通常由BASF出售。还可以用抗真菌或抗微生物涂料来喷涂成品。此外,成品可以进行涂漆、染色或纹理化。
制成的轻质水泥基复合材料将具有约1.4至2.4g/cm3范围内的密度、约5至100MPa范围内的抗压强度和约5至35MPa范围内的抗弯强度。
组成范围如下所示:
水泥可以为以重量计0.1%、0.2%、0.3%、0.4%、0.5%、0.6%、0.7%、0.8%、0.9%、1.0%、2%、3%、4%、5%、6%、7%、8%、9%、10%、11%、12%、13%、14%、15%、16%、17%、18%、19%、20%、21%、22%、23%、24%、25%、26%、27%、28%、29%、30%、31%、32%、33%、34%、35%、36%、37%、38%、39%、40%、41%、42%、43%、44%、45%、46%、47%、48%、49%、50%、51%、52%、53%、54%、55%、56%、57%、58%、59%、60%、61%、62%、63%、64%、65%、66%、67%、68%、69%、70%、71%、72%、73%、74%、75%、76%、77%、78%、79%、80%、81%、82%、83%、84%、85%、86%、87%、88%、89%或90%或之间的其它增量百分比。
水可以为以重量计10%、11%、12%、13%、14%、15%、16%、17%、18%、19%、20%、21%、22%、23%、24%、25%、26%、27%、28%、29%、30%、31%、32%、33%、34%、35%、36%、37%、38%、39%、40%、41%、42%、43%、44%、45%、46%、47%、48%、49%、50%、51%、52%、53%、54%、55%、56%、57%、58%、59%或60%或之间的其它增量百分比。
石膏可以为以重量计0.1%、0.2%、0.3%、0.4%、0.5%、0.6%、0.7%、0.8%、0.9%、1.0%、2%、3%、4%、5%、6%、7%、8%、9%、10%、11%、12%、13%、14%、15%、16%、17%、18%、19%、20%、21%、22%、23%、24%、25%、26%、27%、28%、29%、30%、31%、32%、33%、34%、35%、36%、37%、38%、39%、40%、41%、42%、43%、44%、45%、46%、47%、48%、49%、50%、51%、52%、53%、54%、55%、56%、57%、58%、59%、60%、61%、62%、63%、64%、65%、66%、67%、68%、69%、70%、71%、72%、73%、74%、75%、76%、77%、78%、79%、80%、81%、82%、83%、84%、85%、86%、87%、88%、89%或90%或之间的其它增量百分比。
辅助材料可以为以重量计0.1%、0.2%、0.3%、0.4%、0.5%、0.6%、0.7%、0.8%、0.9%、1.0%、2%、3%、4%、5%、6%、7%、8%、9%、10%、11%、12%、13%、14%、15%、16%、17%、18%、19%、20%、21%、22%、23%、24%、25%、26%、27%、28%、29%、30%、31%、32%、33%、34%、35%、36%、37%、38%、39%、40%、41%、42%、43%、44%、45%、46%、47%、48%、49%或50%或之间的其它增量百分比。
增强纤维可以为以重量计0.5%、0.6%、0.7%、0.8%、0.9%、1.0%、2%、3%、4%、5%、6%、7%、8%、9%、10%、11%、12%、13%、14%、15%、16%、17%、18%、19%或20%或之间的其它增量百分比。
流变改性剂可以为以重量计0.5%、0.6%、0.7%、0.8%、0.9%、1.0%、1.1%、1.2%、1.3%、1.4%、1.5%、1.6%、1.7%、1.8%、1.9%、2.0%、2.1%、2.2%、2.3%、2.4%、2.5%、2.6%、2.7%、2.8%、2.9%、3.0%、3.1%、3.2%、3.3%、3.4%、3.5%、3.6%、3.7%、3.8%、3.9%、4.0%、4.1%、4.2%、4.3%、4.4%、4.5%、4.6%、4.7%、4.8%、4.9%、5.0%、5.1%、5.2%、5.3%、5.4%、5.5%、5.6%、5.7%、5.8%、5.9%、6.0%、6.1%、6.2%、6.3%、6.4%、6.5%、6.6%、6.7%、6.8%、6.9%、7.0%、7.1%、7.2%、7.3%、7.4%、7.5%、7.6%、7.7%、7.8%、7.9%、8.0%、8.1%、8.2%、8.3%、8.4%、8.5%、8.6%、8.7%、8.8%、8.9%、9.0%、9.1%、9.2%、9.3%、9.4%、9.5%、9.6%、9.7%、9.8%、9.9%或10%或之间的其它增量百分比。
缓凝剂可以为以重量计0.1%、0.2%、0.3%、0.4%、0.5%、0.6%、0.7%、0.8%、0.9%、1.0%、1.1%、1.2%、1.3%、1.4%、1.5%、1.6%、1.7%、1.8%、1.9%、2.0%、2.1%、2.2%、2.3%、2.4%、2.5%、2.6%、2.7%、2.8%、2.9%、3.0%、3.1%、3.2%、3.3%、3.4%、3.5%、3.6%、3.7%、3.8%、3.9%、4.0%、4.1%、4.2%、4.3%、4.4%、4.5%、4.6%、4.7%、4.8%、4.9%、5.0%、5.1%、5.2%、5.3%、5.4%、5.5%、5.6%、5.7%、5.8%、5.9%、6.0%、6.1%、6.2%、6.3%、6.4%、6.5%、6.6%、6.7%、6.8%、6.9%、7.0%、7.1%、7.2%、7.3%、7.4%、7.5%、7.6%、7.7%、7.8%、7.9%、或8.0%或之间的其它增量百分比。
因此,本发明提供了由包含水泥、水、石膏、辅助材料、增强纤维和流变改性剂的混合物形成的可挤出的水泥基材料。可挤出的水泥基材料是轻质材料,其具有约1.4至2.4g/cm3范围内的密度、约5至100MPa范围内的抗压强度以及约5至约35MPa范围内的抗弯强度。注意,水泥可以包含石膏,使得石膏不添加到混合物中。在一些实施方案中,可以向混合物中添加缓凝剂。
另外,本发明提供了一种可挤出的水泥基材料,其由混合物形成,该混合物包含以湿重量百分比计约0.1至90%范围内的水泥、约10至60%范围内的水、以湿重百分比计约0.1至90%范围内的石膏、以湿重百分比计约0.1至50%范围内的辅助材料(例如砂、岩石、飞灰、矿渣、硅粉、碳酸钙等)、以湿重量百分比计约0.5至20%范围内的增强纤维和以湿重百分比计约0.5至10%范围内的流变改性剂。注意,水泥可以包含石膏,使得石膏不添加到混合物中。在一些实施方案中,约0.1至8%湿重范围内的缓凝剂可以加入到混合物中。
此外,本发明提供一种通过以下制造可挤出的水泥基材料的方法:将水泥、辅助材料、增强纤维和流变改性剂与水混合,使用挤出机通过模具挤出混合物,并使挤出的混合物凝固。注意,水泥可以包含石膏,使得石膏不添加到混合物中,或者石膏与水混合,或两者。在一些实施方案中,可以向混合物中加入缓凝剂。
此外,本发明提供了通过以下步骤制备可挤出的水泥基材料(复合材料)的方法:(1)混合约0.1-90%湿重的水泥和0.1-90%湿重的石膏与约10至60%湿重的水,其中水泥包含石膏,或石膏与水泥和水混合,或两者;(2)将所述水泥-石膏-水混合物与约0.1至50%湿重的辅助材料(例如砂、岩石、飞灰、矿渣、硅粉、碳酸钙等)和约0.5至20%湿重的增强纤维共混;和(3)加入约0.5至10%湿重的流变改性剂至混合物。然后可将得到的可挤出的水泥基材料挤出并固化(例如,使静置、加热、蒸汽处理等)。在一些实施方案中,可以将约0.1至8%的湿重范围内的缓凝剂添加到混合物中。
在另一个实施方案中,可挤出的水泥基材料(复合材料)可以通过以下步骤制备:(1)将批料的所有成分同时计量加入混合器(例如,Eirich强力混合器等)中并混合这些成分;(2)将混合物倒入料斗中并通过模具挤出混合物以形成细长片材;(3)将细长片材通过一组或多组(例如两组等)压延机轧制到最终厚度;(4)将细长片材切割成具有特定长度的一组单独片材;(5)拾取单独片材中的一个或多个并将它们堆放在托盘上;(6)用塑料和绝缘覆盖物覆盖堆叠物,并将堆叠物放置在固化室中保持特定的一段时间(例如24至48小时或固化各片材所需的其它时间段);(7)精加工每个单独的片材(例如,弄方正边缘,砂磨以使表面平滑和使尺寸精确(exact);以及(8)将一种或多种涂料或油墨施加到每个单独的片材(例如借助涂布或印刷工艺施加UV涂料、防火涂料、颜料、图像、纹理化或其组合)。
尽管已经详细描述了本发明的优选实施方案,但是本领域技术人员将理解,在不脱离如所附权利要求中阐述的本发明的精神和范围的情况下,可以在其中进行各种修改。
Claims (40)
1.一种由混合物形成的可挤出的水泥基材料,所述混合物包含:
以湿重百分比计约0.1-90%范围内的水泥;
以湿重百分比计约0.1-90%范围内的石膏;
以湿重百分比计约0.1-50%范围内的辅助材料;
以湿重百分比计约0.5-20%范围内的增强纤维;
以湿重百分比计约0.5-10%范围内的流变改性剂;
总湿材料重量的10-60%范围内的水;和
所述混合物是可挤出的。
2.根据权利要求1所述的可挤出的水泥基材料,其中所述水泥包含石膏,并且石膏不添加至混合物。
3.根据权利要求1所述的可挤出的水泥基材料,所述混合物具有粘土状稠度。
4.根据权利要求1所述的可挤出的水泥基材料,所述辅助材料包括砂、硅粉、火成二氧化硅、飞灰、矿渣、岩石、纤维素纤维、玻璃纤维、塑料纤维、聚乙烯醇(PVA)纤维或其组合。
5.根据权利要求1所述的可挤出的水泥基材料,所述增强纤维包括纤维素纤维、玻璃纤维、聚丙烯纤维、聚乙烯醇(PVA)纤维、德兰尼特纤维或其组合。
6.根据权利要求1所述的可挤出的水泥基材料,所述流变改性剂包括多糖、多糖衍生物、蛋白质、蛋白质衍生物、合成有机材料、合成有机材料衍生物或其组合。
7.根据权利要求6所述的可挤出的水泥基材料,所述多糖包括纤维素基材料、纤维素基材料衍生物、淀粉基材料、淀粉基材料衍生物或其组合。
8.根据权利要求7所述的可挤出的水泥基材料,所述纤维素基材料选自主要由以下组成的组:甲基羟乙基纤维素(MHEC)、羟甲基乙基纤维素(HMEC)、羧甲基纤维素(CMC)、甲基纤维素(MC)、乙基纤维素(EC)、羟乙基纤维素(HEC)、羟乙基丙基纤维素(HEPC)和羟丙基甲基纤维素(HPMC)。
9.根据权利要求7所述的可挤出的水泥基材料,所述淀粉基材料选自主要由以下组成的组:小麦淀粉、预胶凝小麦淀粉、马铃薯淀粉、预胶凝马铃薯淀粉、支链淀粉、直链淀粉、海凝胶、淀粉乙酸酯、淀粉羟乙基醚、离子淀粉、长链烷基淀粉、糊精、胺淀粉、磷酸盐淀粉或双醛淀粉。
10.根据权利要求1所述的可挤出的水泥基材料,进一步包含以湿重百分比计约0.1-8%范围内的缓凝剂。
11.根据权利要求10所述的可挤出的水泥基材料,所述缓凝剂包括柠檬酸钠,或者熟石膏、柠檬酸钠和结晶二氧化硅的混合物。
12.根据权利要求1所述的可挤出的水泥基材料,所述可挤出的水泥基材料具有约1.4至2.4g/cm3范围内的密度、约5MPa至100MPa范围内的抗压强度和约5至35MPa范围内的抗弯强度。
13.一种由混合物形成的可挤出的水泥基材料,所述混合物主要由以下组成:
以湿重百分比计约0.1-90%范围内的水泥;
以湿重百分比计约0.1-90%范围内的石膏;
以湿重百分比计约0.1-50%范围内的辅助材料;
以湿重百分比计约0.5-20%范围内的增强纤维;
以湿重百分比计约0.5-10%范围内的流变改性剂;
总湿材料重量的10-60%范围内的水;和
所述混合物是可挤出的。
14.可挤出的水泥基材料,其中所述水泥包含石膏,并且石膏不添加至混合物。
15.一种用于制备可挤出的水泥基材料的方法,所述方法包括以下步骤:
将水泥、辅助材料、增强纤维和流变改性剂与水混合,其中水泥包含石膏,或者石膏与水混合,或两者;
使用挤出机通过模具挤出混合物;和
使挤出的混合物凝固。
16.根据权利要求15所述的方法,所述混合物包含:
以湿重百分比计约0.1-90%范围内的水泥;
以湿重百分比计约0.1-90%范围内的石膏;
以湿重百分比计约0.1-50%范围内的辅助材料;
以湿重百分比计约0.5-20%范围内的增强纤维;
以湿重百分比计约0.5-10%范围内的流变改性剂;和
总湿材料重量的10-60%范围内的水。
17.根据权利要求15所述的方法,所述混合物主要由以下组成:
以湿重百分比计约40-90%范围内的水泥;
以湿重百分比计约0.1-90%范围内的石膏;
以湿重百分比计约0.1-50%范围内的辅助材料;
以湿重百分比计约0.5-20%范围内的增强纤维;
以湿重百分比计约0.5-10%范围内的流变改性剂;和
总湿材料重量的10-60%范围内的水。
18.根据权利要求15所述的方法,其中将水泥、辅助材料、增强纤维和流变改性剂与水混合的步骤包括以下步骤:
将水泥与水混合,其中水泥包含石膏;
将水泥-石膏-水混合物与辅助材料和增强纤维共混;和
将流变改性剂添加至混合物。
19.根据权利要求15所述的方法,其中将水泥、辅助材料、增强纤维和流变改性剂与水混合的步骤包括以下步骤:
将水泥和石膏与水混合;
将水泥-石膏-水混合物与辅助材料和增强纤维共混;和
将流变改性剂添加至混合物。
20.根据权利要求15所述的方法,所述混合物具有粘土状稠度。
21.根据权利要求15所述的方法,使用挤出机通过模具挤出混合物的步骤包括以下步骤:
使用螺旋输送机输送所述混合物通过筒;和
使用挤出机通过模具连续地将所述混合物成形为具有形状稳定性的最终形状。
22.根据权利要求15所述的方法,所述辅助材料包括砂、硅粉、火成二氧化硅、飞灰、矿渣、岩石、纤维素纤维、玻璃纤维、塑料纤维、聚乙烯醇(PVA)纤维或其组合。
23.根据权利要求15所述的方法,所述增强纤维包括纤维素纤维、玻璃纤维、聚丙烯纤维、聚乙烯醇(PVA)纤维、德兰尼特纤维或其组合。
24.根据权利要求15所述的方法,所述流变改性剂包括多糖、多糖衍生物、蛋白质、蛋白质衍生物、合成有机材料、合成有机材料衍生物或其组合。
25.根据权利要求24所述的方法,所述多糖包括纤维素基材料、纤维素基材料衍生物、淀粉基材料、淀粉基材料衍生物或其组合。
26.根据权利要求25所述的方法,所述纤维素基材料选自主要由以下组成的组:甲基羟乙基纤维素(MHEC)、羟甲基乙基纤维素(HMEC)、羧甲基纤维素(CMC)、甲基纤维素(MC)、乙基纤维素(EC)、羟乙基纤维素(HEC)、羟乙基丙基纤维素(HEPC)和羟丙基甲基纤维素(HPMC)。
27.根据权利要求25所述的方法,所述淀粉基材料选自主要由以下组成的组:小麦淀粉、预胶凝小麦淀粉、马铃薯淀粉、预胶凝马铃薯淀粉、支链淀粉、直链淀粉、海凝胶、淀粉乙酸酯、淀粉羟乙基醚、离子淀粉、长链烷基淀粉、糊精、胺淀粉、磷酸盐淀粉或双醛淀粉。
28.根据权利要求15所述的方法,其中所述混合步骤进一步包括将以湿重百分比计约0.1-8%范围内的缓凝剂与水混合。
29.根据权利要求28所述的方法,所述缓凝剂包括柠檬酸钠,或者熟石膏、柠檬酸钠和结晶二氧化硅的混合物。
30.根据权利要求15所述的方法,所述可挤出的水泥基材料在凝固、固化或干燥之后具有约1.4至2.4g/cm3范围内的密度、约5MPa至100MPa范围内的抗压强度和约5至35MPa范围内的抗弯强度。
31.根据权利要求15所述的方法,其中挤出的混合物包括细长片材,并且进一步包括通过一组或多组压延机轧制细长片材的步骤。
32.根据权利要求31所述的方法,进一步包括以下步骤:
将所述细长片材切割成具有指定长度的一组单独片材;
将所述一组单独的片材堆叠到托盘上;
用塑料和绝缘材料覆盖堆叠物;
通过使被覆盖的堆叠物静置指定的时间段来固化所述堆叠物;和
弄方正和砂磨每个单独片材。
33.根据权利要求32所述的方法,其中所述指定的时间段为约24至48小时。
34.根据权利要求15所述的方法,其中使挤出的混合物凝固最长达2至3小时。
35.根据权利要求15所述的方法,进一步包括固化挤出的混合物的步骤。
36.根据权利要求15所述的方法,进一步包括干燥挤出的混合物的步骤。
37.根据权利要求15所述的方法,进一步包括将挤出的混合物模制、切割、修整、砂磨或者特形铣成指定形状的步骤。
38.根据权利要求15所述的方法,进一步包括用防水剂喷涂挤出的混合物的步骤。
39.根据权利要求15所述的方法,进一步包括将一种或多种涂料或油墨施加至挤出的混合物的步骤。
40.根据权利要求39所述的方法,其中所述一种或多种涂料或油墨包括UV涂料、防火涂料、颜料、图像、纹理或其组合。
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115636649A (zh) * | 2022-10-24 | 2023-01-24 | 上海镎素工业技术有限公司 | 可挤出加工水泥基材料及其制备方法 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111003958A (zh) * | 2013-04-24 | 2020-04-14 | 知识产权古里亚有限责任公司 | 挤出的轻质热绝缘水泥基材料 |
GB201420676D0 (en) | 2014-11-20 | 2015-01-07 | Bpb Ltd | Construction panel having improved fixing strength |
US20200207663A1 (en) * | 2017-05-19 | 2020-07-02 | Fpinnovations | Cellulose filaments reinforced cement composite board and method for the manufacture of the same |
US10844551B2 (en) * | 2018-03-17 | 2020-11-24 | Hindustan Zinc Limited | Method for manufacturing of paver blocks and bricks from industrial waste |
CN110041011A (zh) * | 2019-05-28 | 2019-07-23 | 四川益好优科环保科技有限公司 | 一种高无机物填充的辐射交联聚乙烯醇材料及制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4416695A (en) * | 1979-08-22 | 1983-11-22 | National Research Development Corporation | Hydraulic cements |
US6030446A (en) * | 1996-05-29 | 2000-02-29 | Peerless Block & Brick Co. | Cementitious compositions and lightweight structural units |
US20040258901A1 (en) * | 1998-04-20 | 2004-12-23 | Bpb Plc. | Gypsum plaster |
CN101351418A (zh) * | 2005-12-27 | 2009-01-21 | 日本油脂株式会社 | 用于挤出模塑的胶合剂基组合物、其制造方法和胶合剂产品 |
CN102712531A (zh) * | 2009-11-24 | 2012-10-03 | E·喀硕吉工业有限责任公司 | 具有类似木材的特性和超高强度的挤压成型的纤维增强水泥制品以及制造该制品的方法 |
Family Cites Families (275)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US570391A (en) | 1896-10-27 | Fireproof door | ||
US1048923A (en) | 1911-06-09 | 1912-12-31 | James A Wheeler | Fireproof door. |
GB1265471A (zh) | 1967-11-23 | 1972-03-01 | ||
US3517468A (en) | 1968-07-22 | 1970-06-30 | John Thomas Woods | Audiometric enclosure |
US3852083A (en) | 1972-03-30 | 1974-12-03 | J Yang | Manufacture of plaster of paris products containing latex |
GB1478964A (en) | 1973-06-21 | 1977-07-06 | Credelca Ag | Buildings |
US3908062A (en) | 1974-01-21 | 1975-09-23 | United States Gypsum Co | Fire-resistant, composite panel and method of making same |
CA1030705A (en) | 1974-01-30 | 1978-05-09 | Champion International Corporation | Asbestos-free fire resistant compositions and products therefrom |
JPS514216A (ja) | 1974-07-01 | 1976-01-14 | Mitsubishi Petrochemical Co | Setsukoseikeihinseizoyososeibutsu |
JPS5433722Y2 (zh) | 1974-10-11 | 1979-10-17 | ||
US3994110A (en) | 1975-04-10 | 1976-11-30 | Champion International Corporation | Three hour fire resistant door, panel or building element, and method of manufacturing the same |
US4159302A (en) | 1975-10-14 | 1979-06-26 | Georgia-Pacific Corporation | Fire door core |
US3987600A (en) | 1975-12-10 | 1976-10-26 | United States Gypsum Company | Fire resistant doors |
US4084571A (en) | 1976-09-20 | 1978-04-18 | The Tappan Company | See-through oven door with reticulated heat shield |
JPS5376458A (en) | 1976-12-17 | 1978-07-06 | Shikoku Kaken Kogyo Kk | Heat retaining and insulating plate |
MX147334A (es) | 1977-09-30 | 1982-11-17 | Walls Mycelo Jose | Composicion mejorada de arido ligero de particulas discretas porosas y expandidas |
US4343127A (en) | 1979-02-07 | 1982-08-10 | Georgia-Pacific Corporation | Fire door |
US4225357A (en) | 1979-03-09 | 1980-09-30 | Harry Hodson | Method of producing and distributing a pervious concrete product |
US4225247A (en) | 1979-03-09 | 1980-09-30 | Harry Hodson | Mixing and agitating device |
US4339487A (en) | 1979-05-16 | 1982-07-13 | Mullet Willis J | Door panel and manner of making same |
US4284119A (en) | 1979-07-23 | 1981-08-18 | Martin Overhead Door And Electronics Co. | Overhead door and overhead door section system and method |
US4347653A (en) | 1979-07-23 | 1982-09-07 | Martin Overhead Door And Electronics Company | Method of preparing a section for an overhead door |
US4302127A (en) | 1979-11-13 | 1981-11-24 | Harry Hodson | Applicator and distributor assembly |
IL61258A (en) | 1980-10-13 | 1983-12-30 | Mordechai Shechter | Method of prefabricated construction and building structure constructed in accordance with such method |
US4434899A (en) | 1980-11-17 | 1984-03-06 | Liberty Carton Co. | Adjustable wire tote for printed circuit boards |
US4398842A (en) | 1980-12-29 | 1983-08-16 | Harry Hodson | Method of overlay and sandwich formation of pervious concrete |
US4428775A (en) | 1981-02-11 | 1984-01-31 | National Gypsum Company | Reinforced cement sheet product containing no asbestos for fabricating on hatschek machine |
CA1176024A (en) | 1981-09-28 | 1984-10-16 | J. Douglas Dickson | Edge-to-edge panel connection |
CA1217680A (en) | 1983-01-13 | 1987-02-10 | John S. Luckanuck | Fire-resistant sandwich core assembly |
US4552463A (en) | 1984-03-15 | 1985-11-12 | Harry Hodson | Method and apparatus for producing a colloidal mixture |
AT380292B (de) | 1984-05-17 | 1986-05-12 | Atlas Blech Center Gmbh | Dichtung fuer gebaeudeteile |
US4664707A (en) | 1985-04-09 | 1987-05-12 | Georgia-Pacific Corporation | Fire resistant gypsum composition |
US4630420A (en) | 1985-05-13 | 1986-12-23 | Rolscreen Company | Door |
US4889428A (en) | 1985-07-29 | 1989-12-26 | Concrete Technology Corporation | Rotary mill |
US4800538A (en) | 1986-03-31 | 1989-01-24 | Refraction Technology, Inc. | Method of and systems for seismic exploration |
US4704834A (en) | 1986-11-24 | 1987-11-10 | Turner Terry A | Raised panel-style door |
US4695494A (en) | 1986-11-25 | 1987-09-22 | Georgia-Pacific Corporation | Fire-resistant article and method of manufacture |
US4811538A (en) | 1987-10-20 | 1989-03-14 | Georgia-Pacific Corporation | Fire-resistant door |
US4864789A (en) | 1988-06-02 | 1989-09-12 | Therma-Tru Corp. | Compression molded door assembly |
US4922674A (en) | 1988-06-15 | 1990-05-08 | Therma-Tru Corp. | Compression molded door assembly |
US4944595A (en) | 1988-08-19 | 1990-07-31 | Simon Hodson | Apparatus for producing cement building material |
US5061319A (en) | 1988-08-19 | 1991-10-29 | Concrete Technology Corporation | Process for producing cement building material |
US4946504A (en) | 1988-08-19 | 1990-08-07 | Concrete Technology Corporation | Cement building material |
US5232496A (en) | 1988-08-19 | 1993-08-03 | E. Khashoggi Industries | Process for producing improved building material and product thereof |
US5108677A (en) | 1988-10-17 | 1992-04-28 | John Ayres | Method of forming a sand base article using a decomposable binder and the article formed thereby |
US5317119A (en) | 1988-10-17 | 1994-05-31 | Nu-Tech & Engineering, Inc. | Oven safe disposable food container |
US5066080A (en) | 1988-11-14 | 1991-11-19 | National Products, Inc. | Tambour door and method of making |
US4896471A (en) | 1989-01-23 | 1990-01-30 | Truline Manufacturing Inc. | Fire roof panel door |
US4998598A (en) | 1989-05-30 | 1991-03-12 | The Ceco Corporation | Acoustical door |
US5505987A (en) | 1989-10-10 | 1996-04-09 | Jennings; Hamlin M. | Processes for improving the bond between hydrating cement-based materials and existing cement-based substrates |
US5695811A (en) | 1989-10-10 | 1997-12-09 | E. Khashoggi Industries | Methods and compositions for bonding a cement-based overlay on a cement-based substrate |
US5305577A (en) | 1989-10-12 | 1994-04-26 | Georgia-Pacific Corporation | Fire-resistant structure containing gypsum fiberboard |
US5171366A (en) | 1989-10-12 | 1992-12-15 | Georgia-Pacific Corporation | Gypsum building product |
US5155959A (en) | 1989-10-12 | 1992-10-20 | Georgia-Pacific Corporation | Firedoor constructions including gypsum building product |
US5347780A (en) | 1989-10-12 | 1994-09-20 | Georgia-Pacific Corporation | Gypsum fiberboard door frame |
WO1991012186A1 (de) | 1990-02-06 | 1991-08-22 | Biopac Biologische Verpackungssysteme Gesellschaftm.B.H. | Verfahren zur herstellung von verrottbaren, dünnwandigen formkörpern auf stärkebasis |
US5356579A (en) | 1990-05-18 | 1994-10-18 | E. Khashoggi Industries | Methods of manufacture and use for low density hydraulically bonded cement compositions |
WO1991017875A1 (en) | 1990-05-18 | 1991-11-28 | E. Khashoggi Industries | Hydraulically bonded cement compositions and their methods of manufacture and use |
US5169566A (en) | 1990-05-18 | 1992-12-08 | E. Khashoggi Industries | Engineered cementitious contaminant barriers and their method of manufacture |
US5637412A (en) | 1990-05-18 | 1997-06-10 | E. Khashoggi Industries | Compressed hydraulically bonded composite articles |
US5100586A (en) | 1990-07-20 | 1992-03-31 | E. Khashoggi Industries | Cementitious hazardous waste containers and their method of manufacture |
US5074087A (en) | 1990-10-10 | 1991-12-24 | Pease Industries, Inc. | Doors of composite construction |
KR930001645B1 (ko) | 1991-02-13 | 1993-03-08 | 삼성전자주식회사 | 자동 트랙킹 방법 |
US5154358A (en) | 1991-03-05 | 1992-10-13 | Nordson Corporation | Repulsion device for low capacitance electrostatic painting systems |
US5339522A (en) | 1991-06-10 | 1994-08-23 | Groupe Herve Pomerleau Inc. | Method for constructing modular doors |
US5250578A (en) | 1991-07-05 | 1993-10-05 | Cornwell Charles E | Foamed cementitious composition and method of making |
JP3131701B2 (ja) | 1991-08-26 | 2001-02-05 | リグナイト株式会社 | 耐火性ドア |
US5239799A (en) | 1991-08-28 | 1993-08-31 | The Stanley Works | Insulated door with synthetic resin skins |
ZA926178B (en) | 1991-08-30 | 1993-04-26 | Plascon Tech | Method of making a building board. |
US5242078A (en) | 1991-10-01 | 1993-09-07 | Franz Haas Waffelmaschinen Industriegesellschaft M.B.H. | Biodegradable ribbed dish |
JP2986986B2 (ja) | 1991-10-09 | 1999-12-06 | 浅野スレート株式会社 | 高強度石膏板の製造方法 |
WO1993022115A1 (en) | 1992-04-23 | 1993-11-11 | Rivdal Developments Limited | A panel and a method for producing the panel |
CA2084494C (en) | 1992-04-28 | 1997-06-24 | Peter Paul Roosen | Plasticised gypsum composition |
US5810961A (en) | 1993-11-19 | 1998-09-22 | E. Khashoggi Industries, Llc | Methods for manufacturing molded sheets having a high starch content |
US5453310A (en) | 1992-08-11 | 1995-09-26 | E. Khashoggi Industries | Cementitious materials for use in packaging containers and their methods of manufacture |
US5545450A (en) | 1992-08-11 | 1996-08-13 | E. Khashoggi Industries | Molded articles having an inorganically filled organic polymer matrix |
US5928741A (en) | 1992-08-11 | 1999-07-27 | E. Khashoggi Industries, Llc | Laminated articles of manufacture fashioned from sheets having a highly inorganically filled organic polymer matrix |
US5683772A (en) | 1992-08-11 | 1997-11-04 | E. Khashoggi Industries | Articles having a starch-bound cellular matrix reinforced with uniformly dispersed fibers |
US5660903A (en) | 1992-08-11 | 1997-08-26 | E. Khashoggi Industries | Sheets having a highly inorganically filled organic polymer matrix |
US5545297A (en) | 1992-08-11 | 1996-08-13 | E. Khashoggi Industries | Methods for continuously placing filaments within hydraulically settable compositions being extruded into articles of manufacture |
US5709827A (en) | 1992-08-11 | 1998-01-20 | E. Khashoggi Industries | Methods for manufacturing articles having a starch-bound cellular matrix |
US5582670A (en) | 1992-08-11 | 1996-12-10 | E. Khashoggi Industries | Methods for the manufacture of sheets having a highly inorganically filled organic polymer matrix |
US5830305A (en) | 1992-08-11 | 1998-11-03 | E. Khashoggi Industries, Llc | Methods of molding articles having an inorganically filled organic polymer matrix |
US5665439A (en) | 1992-08-11 | 1997-09-09 | E. Khashoggi Industries | Articles of manufacture fashioned from hydraulically settable sheets |
AU677231B2 (en) | 1992-08-11 | 1997-04-17 | E. Khashoggi Industries, Llc | Hydraulically settable containers |
US5631097A (en) * | 1992-08-11 | 1997-05-20 | E. Khashoggi Industries | Laminate insulation barriers having a cementitious structural matrix and methods for their manufacture |
US5527387A (en) | 1992-08-11 | 1996-06-18 | E. Khashoggi Industries | Computer implemented processes for microstructurally engineering cementious mixtures |
US5506046A (en) | 1992-08-11 | 1996-04-09 | E. Khashoggi Industries | Articles of manufacture fashioned from sheets having a highly inorganically filled organic polymer matrix |
US5830548A (en) | 1992-08-11 | 1998-11-03 | E. Khashoggi Industries, Llc | Articles of manufacture and methods for manufacturing laminate structures including inorganically filled sheets |
US5660900A (en) | 1992-08-11 | 1997-08-26 | E. Khashoggi Industries | Inorganically filled, starch-bound compositions for manufacturing containers and other articles having a thermodynamically controlled cellular matrix |
US5641584A (en) | 1992-08-11 | 1997-06-24 | E. Khashoggi Industries | Highly insulative cementitious matrices and methods for their manufacture |
US5508072A (en) | 1992-08-11 | 1996-04-16 | E. Khashoggi Industries | Sheets having a highly inorganically filled organic polymer matrix |
US5580624A (en) | 1992-08-11 | 1996-12-03 | E. Khashoggi Industries | Food and beverage containers made from inorganic aggregates and polysaccharide, protein, or synthetic organic binders, and the methods of manufacturing such containers |
US5549859A (en) | 1992-08-11 | 1996-08-27 | E. Khashoggi Industries | Methods for the extrusion of novel, highly plastic and moldable hydraulically settable compositions |
US5800647A (en) | 1992-08-11 | 1998-09-01 | E. Khashoggi Industries, Llc | Methods for manufacturing articles from sheets having a highly inorganically filled organic polymer matrix |
US5679145A (en) | 1992-08-11 | 1997-10-21 | E. Khashoggi Industries | Starch-based compositions having uniformly dispersed fibers used to manufacture high strength articles having a fiber-reinforced, starch-bound cellular matrix |
US5618341A (en) | 1992-08-11 | 1997-04-08 | E. Khashoggi Industries | Methods for uniformly dispersing fibers within starch-based compositions |
US5658603A (en) | 1992-08-11 | 1997-08-19 | E. Khashoggi Industries | Systems for molding articles having an inorganically filled organic polymer matrix |
US5662731A (en) | 1992-08-11 | 1997-09-02 | E. Khashoggi Industries | Compositions for manufacturing fiber-reinforced, starch-bound articles having a foamed cellular matrix |
US5851634A (en) | 1992-08-11 | 1998-12-22 | E. Khashoggi Industries | Hinges for highly inorganically filled composite materials |
US5580409A (en) | 1992-08-11 | 1996-12-03 | E. Khashoggi Industries | Methods for manufacturing articles of manufacture from hydraulically settable sheets |
US5720913A (en) | 1992-08-11 | 1998-02-24 | E. Khashoggi Industries | Methods for manufacturing sheets from hydraulically settable compositions |
JPH0656497A (ja) | 1992-08-13 | 1994-03-01 | Sansou:Kk | アルミナセメント複合材料 |
US5716675A (en) | 1992-11-25 | 1998-02-10 | E. Khashoggi Industries | Methods for treating the surface of starch-based articles with glycerin |
US5401588A (en) | 1992-12-23 | 1995-03-28 | Georgia-Pacific Resins Inc. | Gypsum microfiber sheet material |
DE4244578C2 (de) | 1992-12-31 | 1996-05-09 | Langenhorst Eva | Revisionsabdeckung |
DK169728B1 (da) | 1993-02-02 | 1995-01-23 | Stein Gaasland | Fremgangsmåde til frigørelse af cellulosebaserede fibre fra hinanden i vand og støbemasse til plastisk formning af celluloseholdige fiberprodukter |
US5543186A (en) | 1993-02-17 | 1996-08-06 | E. Khashoggi Industries | Sealable liquid-tight, thin-walled containers made from hydraulically settable materials |
US5738921A (en) | 1993-08-10 | 1998-04-14 | E. Khashoggi Industries, Llc | Compositions and methods for manufacturing sealable, liquid-tight containers comprising an inorganically filled matrix |
US5482551A (en) | 1993-09-20 | 1996-01-09 | Armstrong World Industries, Inc. | Extruded fire resistant construction and building products |
US5417024A (en) | 1993-10-23 | 1995-05-23 | The Maiman Company | Fire resistant panel door |
US5522195A (en) | 1993-11-15 | 1996-06-04 | Bargen; Theodore J. | Energy-efficient fire door |
US6083586A (en) | 1993-11-19 | 2000-07-04 | E. Khashoggi Industries, Llc | Sheets having a starch-based binding matrix |
US5736209A (en) | 1993-11-19 | 1998-04-07 | E. Kashoggi, Industries, Llc | Compositions having a high ungelatinized starch content and sheets molded therefrom |
ES2123942T3 (es) | 1993-12-06 | 1999-01-16 | Khashoggi E Ind | Procedimiento para la obtencion de cuerpos moldeables degradables de pared delgada, a base de almidon. |
WO1995021050A1 (en) | 1994-02-01 | 1995-08-10 | Northwestern University | Extruded fiber-reinforced cement matrix composites |
US5705203A (en) | 1994-02-07 | 1998-01-06 | E. Khashoggi Industries | Systems for molding articles which include a hinged starch-bound cellular matrix |
US5843544A (en) | 1994-02-07 | 1998-12-01 | E. Khashoggi Industries | Articles which include a hinged starch-bound cellular matrix |
US5776388A (en) | 1994-02-07 | 1998-07-07 | E. Khashoggi Industries, Llc | Methods for molding articles which include a hinged starch-bound cellular matrix |
US5433189A (en) | 1994-02-17 | 1995-07-18 | Maytag Corporation | Oven door heat dissipation system |
CA2139373C (en) | 1994-05-12 | 2002-06-25 | Therese A. Espinoza | Ready-mixed, setting type joint compound |
CA2140162A1 (en) | 1995-01-13 | 1996-07-14 | Materiaux De Construction 2 Plus 2 Inc. | Modular anti-warping door structure |
US5740635A (en) | 1995-01-24 | 1998-04-21 | Gil; Maria Desamparados Mateu | Enclosure fire-resistive for a predetermined time |
US5601888A (en) | 1995-02-14 | 1997-02-11 | Georgia-Pacific Corporation | Fire-resistant members containing gypsum fiberboard |
US6067699A (en) | 1995-04-19 | 2000-05-30 | Jeld-Wen, Inc. | Method for assembling a multi-panel door |
US5887402A (en) | 1995-06-07 | 1999-03-30 | Masonite Corporation | Method of producing core component, and product thereof |
US6161363A (en) | 1995-06-07 | 2000-12-19 | Herbst; Walter B. | Molded door frame and method |
US5644870A (en) | 1995-06-14 | 1997-07-08 | Nan Ya Plastics Corporation | Compression molded door assembly |
US5720142A (en) | 1995-12-29 | 1998-02-24 | Wayne-Dalton Corp. | Foam-filled door and method of manufacture |
US5792427A (en) | 1996-02-09 | 1998-08-11 | Forma Scientific, Inc. | Controlled atmosphere incubator |
US5653075A (en) | 1996-02-26 | 1997-08-05 | Smartdoor Fiberglass Systems, Inc. | Field alterable, glass reinforced plastic door panel |
US5786080A (en) | 1996-04-03 | 1998-07-28 | E. Khashoggi Industries | Compositions and methods for manufacturing ettringite coated fibers and aggregates |
US6168857B1 (en) | 1996-04-09 | 2001-01-02 | E. Khashoggi Industries, Llc | Compositions and methods for manufacturing starch-based compositions |
US5749178A (en) | 1996-08-06 | 1998-05-12 | Garmong; Victor H. | Shielded enclosure |
US5782055A (en) | 1996-11-22 | 1998-07-21 | Crittenden; Jerry G. | Door Apparatus and method of making door |
US5916077A (en) | 1997-02-20 | 1999-06-29 | Chuan Mau Products, Ltd. | Composite fire-proof, heat-barrier door |
RU2132829C1 (ru) | 1997-09-25 | 1999-07-10 | Александров Юрий Юрьевич | Способ получения листового теплоизоляционного материала на основе волластонита |
JPH11147777A (ja) | 1997-11-14 | 1999-06-02 | Kanegafuchi Chem Ind Co Ltd | 軽量硬化物及びその製造方法 |
GB2336585B (en) * | 1998-04-20 | 2002-06-26 | Bpb Plc | Gypsum plaster |
US6119411A (en) | 1998-09-08 | 2000-09-19 | Mateu Gil; Maria Desamparados | Enclosure which is fire-resistive for a predetermined period of time |
US6311454B1 (en) | 1999-02-18 | 2001-11-06 | Globe Door, L.L.C. | Door construction |
DE19933410B4 (de) | 1999-07-21 | 2005-12-15 | Dorma Gmbh + Co. Kg | Brandschutztür oder -fenster |
DE19933406A1 (de) | 1999-07-21 | 2001-03-01 | Dorma Gmbh & Co Kg | Brandschutztür mit einem diese umfassenden Türstock |
US6268022B1 (en) | 1999-09-03 | 2001-07-31 | Morton International, Inc. | Process for coating cabinet doors |
US6115976A (en) | 1999-09-20 | 2000-09-12 | Wood Door Products, Inc. | Door edge assembly for creating a smoke seal about a closed door mounted within a door frame |
US6475275B1 (en) | 1999-10-21 | 2002-11-05 | Isolatek International | Cement composition |
US6231970B1 (en) | 2000-01-11 | 2001-05-15 | E. Khashoggi Industries, Llc | Thermoplastic starch compositions incorporating a particulate filler component |
US20020078659A1 (en) | 2000-12-21 | 2002-06-27 | Hunt Christopher M. | Methods of manufacturing and constructing a habitable, cementitious structure |
US6485561B1 (en) | 2000-03-03 | 2002-11-26 | Clinton D. Dattel | Low density cellular concrete with accelerators for rapid hardening |
WO2001068547A1 (en) | 2000-03-14 | 2001-09-20 | James Hardie Research Pty Limited | Fiber cement building materials with low density additives |
JP4407779B2 (ja) | 2000-03-27 | 2010-02-03 | 信越化学工業株式会社 | 押出成形用の水硬性組成物用バインダー及び水硬性組成物並びに押出成形品の製造方法 |
US6494704B1 (en) | 2000-03-31 | 2002-12-17 | E. Khashoggi Industries, Llc | Mold apparatus |
US6379446B1 (en) | 2000-04-03 | 2002-04-30 | E. Khashoggi Industries, Llc. | Methods for dispersing fibers within aqueous compositions |
US6327821B1 (en) | 2000-04-14 | 2001-12-11 | Wen Fu Chang | Structure of a fire-proof refuge shelter |
US6347934B1 (en) | 2000-05-10 | 2002-02-19 | E. Khashoggi Industries, Llc. | System for metering and delivering a moldable composition into a mold |
US6773500B1 (en) | 2000-05-31 | 2004-08-10 | Isg Resources, Inc. | Fiber reinforced aerated concrete and methods of making same |
US20030115817A1 (en) | 2000-06-22 | 2003-06-26 | New Horizons Shutters, Inc. | Reinforced window shutter |
DE10036030B4 (de) | 2000-07-24 | 2004-05-13 | Rational Ag | Garraum-Isolierglastür für ein Gargerät |
US6688063B1 (en) | 2000-07-25 | 2004-02-10 | Larson Manufacturing Company | Wood core exterior door with mortise lock |
US6584667B1 (en) | 2000-07-25 | 2003-07-01 | Gregory Frumkin | Panel door construction and method of making same |
NZ524479A (en) | 2000-08-07 | 2004-09-24 | Lafarge Platres | Lightweight gypsum board product and method of manufacture |
DE10042071C1 (de) | 2000-08-16 | 2002-03-21 | Mattig & Lindner Gmbh | Poröses silikatisches Granulat und Verfahren zu dessen Herstellung |
US6573340B1 (en) | 2000-08-23 | 2003-06-03 | Biotec Biologische Naturverpackungen Gmbh & Co. Kg | Biodegradable polymer films and sheets suitable for use as laminate coatings as well as wraps and other packaging materials |
US6961998B2 (en) | 2000-09-29 | 2005-11-08 | Salzgitter Antriebstechnik Gmbh & Co. Kg | Method for producing a hollow shaft, in particular a camshaft and a camshaft produced according to said method |
US6572355B1 (en) | 2000-10-03 | 2003-06-03 | Libbey-Owens-Ford Co. | Window sash construction and method and apparatus for manufacture thereof |
WO2002031306A1 (en) | 2000-10-12 | 2002-04-18 | Mdf, Inc. | Fire door and method of assembly |
US6643991B1 (en) | 2000-10-12 | 2003-11-11 | Premdor International, Inc. | Fire door and method of assembly |
GB2368364B (en) | 2000-10-12 | 2004-06-02 | Mdf Inc | Fire door and method of assembly |
US6402830B1 (en) | 2000-11-20 | 2002-06-11 | Randy C. Schaffer | Lightweight concrete composition |
US20020053757A1 (en) | 2001-01-11 | 2002-05-09 | Andersen Per Just | Methods and systems for removing flashing and other irregularities from molded starch-bound articles |
DE60222245T2 (de) | 2001-03-02 | 2008-05-29 | James Hardie International Finance B.V. | Spritzvorrichtung |
AU2002302913B2 (en) | 2001-03-05 | 2008-01-24 | James Hardie Technology Limited | Low density calcium silicate hydrate strength accelerant additive for cementitious products |
US6743830B2 (en) | 2001-03-07 | 2004-06-01 | Innovative Construction And Building Materials | Construction board materials with engineered microstructures |
US6866081B1 (en) | 2001-03-09 | 2005-03-15 | Larson Manufacturing Company Of South Dakota, Inc. | Exterior door or window having extruded composite frame |
US6434899B1 (en) | 2001-03-12 | 2002-08-20 | Skamol A/S | Fire resistant door edge construction comprising a stile with groove, high density strip in the groove, an intumescent strip seal, covered by an edge lipping |
US7297394B2 (en) | 2002-03-01 | 2007-11-20 | Bio-Tec Biologische Naturverpackungen Gmbh & Co. Kg | Biodegradable films and sheets suitable for use as coatings, wraps and packaging materials |
US7241832B2 (en) | 2002-03-01 | 2007-07-10 | bio-tec Biologische Naturverpackungen GmbH & Co., KG | Biodegradable polymer blends for use in making films, sheets and other articles of manufacture |
US6886306B2 (en) | 2001-05-04 | 2005-05-03 | Greencor Composites, Llc | Fire-resistant material and method of manufacture |
JP3891256B2 (ja) | 2001-06-13 | 2007-03-14 | 信越化学工業株式会社 | 押出成形用水硬性組成物及びその硬化体 |
WO2003001637A1 (en) | 2001-06-22 | 2003-01-03 | Ramesh Roahan | A weather proof enclosure with a modular structure |
US6648965B2 (en) | 2001-07-06 | 2003-11-18 | G-P Gypsum Corporation | Fire door components and fire doors comprising the components |
US20030033786A1 (en) | 2001-08-17 | 2003-02-20 | Leon Yulkowski | Fire door assembly |
US20030084980A1 (en) | 2001-11-06 | 2003-05-08 | Seufert James F | Lightweight gypsum wallboard and method of making same |
US6665997B2 (en) | 2002-02-05 | 2003-12-23 | Kuei Yung Wang Chen | Edge inserts for stiles of molded doors |
AU2003217720A1 (en) | 2002-02-26 | 2003-09-09 | Washington Hardwoods Co., Llc | Fire-resistant wood assemblies for building |
US6696979B2 (en) | 2002-03-06 | 2004-02-24 | Howard Manten | Double door security system for aircraft and the like |
US6764625B2 (en) | 2002-03-06 | 2004-07-20 | Masonite Corporation | Method of producing core component, and product thereof |
US6779859B2 (en) | 2002-03-15 | 2004-08-24 | Maytag Corporation | Freezer door assembly |
US8163081B2 (en) | 2002-04-04 | 2012-04-24 | Kirby Wayne Beard | Composite materials using novel reinforcements |
US6619005B1 (en) | 2002-04-16 | 2003-09-16 | Kuei Yung Wang Chen | Molded doors with large glass insert |
US6823810B2 (en) | 2002-05-01 | 2004-11-30 | Harris Acoustic Products Corporation | Wireless ballast water monitoring and reporting system and marine voyage data recorder system |
US6766621B2 (en) | 2002-05-13 | 2004-07-27 | Snavely Forest Products | Reinforced door stile |
US20030209403A1 (en) | 2002-05-13 | 2003-11-13 | Daniels Evan R. | Method and process for loading and unloading parts |
US20030211251A1 (en) | 2002-05-13 | 2003-11-13 | Daniels Evan R. | Method and process for powder coating molding |
US20030211252A1 (en) | 2002-05-13 | 2003-11-13 | Daniels Evan R. | Method and apparatus for horizontal powder coating |
US6890604B2 (en) | 2002-05-13 | 2005-05-10 | Trio Industries Holdings, Llc | Method and system for powder coating passage doors |
US7311964B2 (en) | 2002-07-30 | 2007-12-25 | Saint-Gobain Technical Fabrics Canada, Ltd. | Inorganic matrix-fabric system and method |
US6964722B2 (en) | 2002-08-07 | 2005-11-15 | Trio Industries Holdings, L.L.C. | Method for producing a wood substrate having an image on at least one surface |
US7185468B2 (en) | 2002-10-31 | 2007-03-06 | Jeld-Wen, Inc. | Multi-layered fire door and method for making the same |
US7284352B2 (en) | 2002-11-12 | 2007-10-23 | Masonite Corporation | Door skin, method of manufacturing a door produced therewith, and door produced therefrom |
US6745526B1 (en) | 2003-04-16 | 2004-06-08 | Enrico Autovino | Fire retardant wooden door with intumescent materials |
JP2004332401A (ja) | 2003-05-08 | 2004-11-25 | Sekisui Chem Co Ltd | 防・耐火パネル及び木製防火戸 |
US7328539B2 (en) | 2003-05-22 | 2008-02-12 | Jeld-Wen, Inc. | Door and method of making same |
US20070157537A1 (en) | 2003-07-28 | 2007-07-12 | Dave Nicolson | Molded stone architectural product having a foam core |
US7617606B2 (en) | 2003-08-21 | 2009-11-17 | Inno-Tech Plastics, Inc. | Composite door, door core and method of manufacture |
US7090897B2 (en) | 2003-10-10 | 2006-08-15 | Hardesty Jon H | Electrically conductive MDF surface |
US7621102B2 (en) | 2003-10-14 | 2009-11-24 | E.M.E.H., Inc. | Door edge construction |
US7886501B2 (en) | 2003-10-14 | 2011-02-15 | Construction Specialties, Inc. | Door edge construction |
US20050227006A1 (en) | 2004-04-08 | 2005-10-13 | Segall Ronald H | Methods for preparing an imaged composite |
US20050241541A1 (en) | 2004-04-27 | 2005-11-03 | Wilfried Hohn | Gypsum-based mortars using water retention agents prepared from raw cotton linters |
US20050241543A1 (en) | 2004-04-27 | 2005-11-03 | Wolfgang Hagen | Cement-based systems using plastification/extrusion auxiliaries prepared from raw cotton linters |
US20050284030A1 (en) | 2004-06-14 | 2005-12-29 | Enrico Autovino | Fire retardant panel door and door frame having intumescent materials therein |
US20060070321A1 (en) | 2004-09-29 | 2006-04-06 | R E P Technologies Ltd. | Fire-resistant panel and method of manufacture |
US20060096240A1 (en) | 2004-10-26 | 2006-05-11 | Industries 3F, Inc. | Fire door core assembly |
US7279437B2 (en) | 2004-12-02 | 2007-10-09 | Richard H Kai | Rated fire door core and method of making |
US7849650B2 (en) | 2005-01-27 | 2010-12-14 | United States Gypsum Company | Non-combustible reinforced cementitious lightweight panels and metal frame system for a fire wall and other fire resistive assemblies |
US7669383B2 (en) | 2005-02-15 | 2010-03-02 | Warm Springs Composite Products | Fire door |
CN101132999A (zh) | 2005-03-01 | 2008-02-27 | 登纳特波拉沃有限公司 | 制备泡沫玻璃颗粒的方法 |
WO2006102634A2 (en) | 2005-03-22 | 2006-09-28 | Nova Chemicals, Inc. | Lightweight concrete compositions |
EP1899776A4 (en) | 2005-06-17 | 2011-03-30 | Icrete Llc | METHODS AND SYSTEMS FOR RECONCEPTING TYPES OF PREEXISTENT CONCRETE MIXTURES AND MANUFACTURING PLANTS AND OPTIMIZING DESIGN AND MANUFACTURING OF CONCRETE |
US20070021515A1 (en) | 2005-07-19 | 2007-01-25 | United States (as represented by the Secretary of Agriculture) | Expandable starch-based beads and method of manufacturing molded articles therefrom |
JP4861416B2 (ja) | 2005-07-27 | 2012-01-25 | ミルウォーキー・コンポジッツ・インコーポレーテッド | 難燃性パネル装置並びにその製造及び使用方法 |
US20070092712A1 (en) | 2005-10-25 | 2007-04-26 | Hodson Simon K | Articles having a moisture-resistant protective coating and methods of manufacturing such articles |
US7598460B2 (en) | 2005-10-28 | 2009-10-06 | Roberts Iv Leonard Pascal | Radiation shielding wood or laminate faced door having a high fire rating and method for making same |
CN101346321A (zh) | 2005-11-01 | 2009-01-14 | E.卡休基工业有限公司 | 具有类木性质的粘结性组合物及其制备方法 |
US20080099122A1 (en) | 2006-11-01 | 2008-05-01 | E. Khashoggi Industries Llc | Cementitious composites having wood-like properties and methods of manufacture |
WO2007081685A2 (en) | 2006-01-04 | 2007-07-19 | Masonite Corporation | Method of forming a core component |
CN101405462B (zh) | 2006-02-21 | 2012-08-29 | 聚合木技术公司 | 生产防火门的***、方法和设备 |
DE102006015644A1 (de) | 2006-03-27 | 2007-10-04 | Frank Ripplinger | Mineralschaumgranulat, Verfahren und Anlage zu dessen Herstellung |
US8037820B2 (en) | 2006-03-30 | 2011-10-18 | William Daniels | Decorative, wood fire-rated door and method |
US8011165B2 (en) | 2006-06-07 | 2011-09-06 | Integritect Consulting, Inc. | Composite assembly with saturated bonding mass and process of reinforced attachment |
JP2008036549A (ja) | 2006-08-08 | 2008-02-21 | Hitachi Plant Technologies Ltd | 建築板の塗装方法 |
US20080086982A1 (en) | 2006-09-19 | 2008-04-17 | Martin Parenteau | Insulating panel and process of making same |
WO2008058161A1 (en) | 2006-11-07 | 2008-05-15 | Insulastics, Inc. | Recycled material insulation |
EP2106391A2 (en) | 2006-12-06 | 2009-10-07 | Construction Research and Technology GmbH | Rheology modifying additive for cementitious compositions |
US20080152945A1 (en) | 2006-12-20 | 2008-06-26 | David Paul Miller | Fiber reinforced gypsum panel |
DE102007035851A1 (de) | 2007-01-13 | 2008-08-14 | Vacuum Walls Ag | Vakuum-Isolationspaneel und Herstellungsverfahren dafür |
CN101239838B (zh) | 2007-02-05 | 2011-05-04 | 山东理工大学 | 粉煤灰陶瓷水洗球的制备方法 |
JP5223205B2 (ja) | 2007-02-19 | 2013-06-26 | 信越化学工業株式会社 | 押出成形用水硬性組成物 |
US20080286519A1 (en) | 2007-05-18 | 2008-11-20 | E. Khashoggi Industries, Llc | Molded cementitious architectural products having a polished stone-like surface finish |
US8070878B2 (en) * | 2007-07-05 | 2011-12-06 | United States Gypsum Company | Lightweight cementitious compositions and building products and methods for making same |
CN101113077B (zh) | 2007-07-20 | 2010-09-01 | 内蒙古自治区建筑材料工业科学研究设计院 | 一种泡沫玻璃的制备方法 |
WO2009038621A1 (en) | 2007-08-10 | 2009-03-26 | Construction Research & Technology Gmbh | Rheology modifying additive for dry cast cementitious compositions |
US8221542B2 (en) | 2007-12-13 | 2012-07-17 | Georgia-Pacific Gypsum Llc | Non-cement fire door core |
US7927420B2 (en) | 2007-12-13 | 2011-04-19 | Georgia-Pacific Gypsum Llc | Light weight metal fire door core |
US20130008115A1 (en) | 2007-12-28 | 2013-01-10 | Timm Bierman | Building construction sheathing composites, structures and related methods of use |
US8097544B2 (en) | 2008-04-01 | 2012-01-17 | Kenneth Majors | Rated fire frame and door frame / jamb |
US8366823B2 (en) | 2008-09-25 | 2013-02-05 | United States Gypsum Company | Fly ash based lightweight cementitious composition with high compressive strength and fast set |
GB2465430B8 (en) | 2008-11-24 | 2014-01-29 | Nanya Plastics Corp | A fireproof door panel structure |
US7803723B2 (en) | 2008-12-16 | 2010-09-28 | Saint-Gobain Technical Fabrics America, Inc. | Polyolefin coated fabric reinforcement and cementitious boards reinforced with same |
EP2230075A1 (en) | 2009-03-17 | 2010-09-22 | Lafarge Gypsum International | Surface-treated nonwoven facer for gypsum wallboard |
JP2012522916A (ja) | 2009-04-03 | 2012-09-27 | ジェイムズ ハーディー テクノロジー リミテッド | セメント系物品、配合物、作製方法、および使用方法 |
US8277556B2 (en) | 2009-06-05 | 2012-10-02 | W. R. Grace & Co.-Conn. | Articles made from cementitious foam and slurry |
PL2314462T3 (pl) | 2009-10-21 | 2013-04-30 | Falquon Gmbh | Sposób wytwarzania spajanej cementem płyty, wyposażonej w nadrukowaną warstwę dekoracyjną |
US20110120349A1 (en) | 2009-11-24 | 2011-05-26 | E. Khashoggi Industries, Llc | Extruded fiber reinforced cementitious products having stone-like properties and methods of making the same |
US20110131921A1 (en) | 2009-12-08 | 2011-06-09 | Kuei Yung Wang Chen | Synthetic door with improved fire resistance |
RU2411218C1 (ru) | 2010-01-11 | 2011-02-10 | Государственное образовательное учреждение высшего профессионального образования "Астраханский государственный университет" (АГУ) | Сырьевая смесь для изготовления газобетона |
US8528212B2 (en) | 2010-01-13 | 2013-09-10 | Quanex Corporation | Method of manufacturing a frame assembly having stile and rail tabs for coupling stile and rail members together |
CN102510848A (zh) | 2010-04-27 | 2012-06-20 | 世联株式会社 | 装饰混凝土砌块和装饰混凝土砌块的制造方法 |
DE102010021532A1 (de) | 2010-05-26 | 2011-12-01 | Evonik Goldschmidt Gmbh | Granularer Bims sowie Verfahren zur Herstellung von granularem Bims |
CH703868B1 (de) | 2010-09-16 | 2016-06-15 | Creabeton Matériaux Sa | Baustoff und Bausystem-Element sowie Verfahren zur Herstellung derselben. |
CN102001832B (zh) | 2010-11-18 | 2012-01-25 | 陕西科技大学 | 一种泡沫玻璃颗粒的制备方法 |
EP2468695A1 (en) | 2010-12-21 | 2012-06-27 | Mapei S.p.A. | Method for recycling concrete |
CN102167619B (zh) | 2011-01-25 | 2013-05-08 | 河海大学 | 低导热加气混凝土及其制备方法 |
CN102220829A (zh) | 2011-06-09 | 2011-10-19 | 支亮 | 一种防火门 |
US8881494B2 (en) | 2011-10-11 | 2014-11-11 | Polymer-Wood Technologies, Inc. | Fire rated door core |
PT105937A (pt) | 2011-10-17 | 2013-04-17 | Secil Martinganca Aglomerantes E Novos Materiais Para A Construcao S A | Argamassa leve preparada com granulado de cortiça |
CA2854366A1 (en) | 2011-11-30 | 2013-06-06 | James Hardie Technology Limited | Lightweight extruded cementitious material and method of making the same |
US9249053B2 (en) | 2012-02-21 | 2016-02-02 | Nano And Advanced Materials Institute Limited | Composite wall panel with low thermal conductivity and sufficient strength for structural use |
CN102643013B (zh) | 2012-04-28 | 2014-01-29 | 浙江德和绝热科技有限公司 | 一种利用废弃玻纤增强酚醛树脂模塑料生产泡沫玻璃的方法 |
US9243444B2 (en) * | 2012-06-29 | 2016-01-26 | The Intellectual Gorilla Gmbh | Fire rated door |
US9375899B2 (en) | 2012-06-29 | 2016-06-28 | The Intellectual Gorilla Gmbh | Gypsum composites used in fire resistant building components |
US8915033B2 (en) | 2012-06-29 | 2014-12-23 | Intellectual Gorilla B.V. | Gypsum composites used in fire resistant building components |
US9890083B2 (en) | 2013-03-05 | 2018-02-13 | The Intellectual Gorilla Gmbh | Extruded gypsum-based materials |
US9475732B2 (en) | 2013-04-24 | 2016-10-25 | The Intellectual Gorilla Gmbh | Expanded lightweight aggregate made from glass or pumice |
-
2015
- 2015-06-05 BR BR112016028409-7A patent/BR112016028409B1/pt active IP Right Grant
- 2015-06-05 CN CN201580033711.1A patent/CN106715356A/zh active Pending
- 2015-06-05 AU AU2015269315A patent/AU2015269315A1/en not_active Abandoned
- 2015-06-05 WO PCT/US2015/034397 patent/WO2015188054A1/en active Application Filing
- 2015-06-05 US US15/315,536 patent/US10538459B2/en active Active
- 2015-06-05 CA CA2985505A patent/CA2985505C/en active Active
- 2015-06-05 EP EP15803724.2A patent/EP3157884A4/en not_active Ceased
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2019
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2021
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2023
- 2023-07-14 AU AU2023204681A patent/AU2023204681A1/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4416695A (en) * | 1979-08-22 | 1983-11-22 | National Research Development Corporation | Hydraulic cements |
US6030446A (en) * | 1996-05-29 | 2000-02-29 | Peerless Block & Brick Co. | Cementitious compositions and lightweight structural units |
US20040258901A1 (en) * | 1998-04-20 | 2004-12-23 | Bpb Plc. | Gypsum plaster |
CN101351418A (zh) * | 2005-12-27 | 2009-01-21 | 日本油脂株式会社 | 用于挤出模塑的胶合剂基组合物、其制造方法和胶合剂产品 |
CN102712531A (zh) * | 2009-11-24 | 2012-10-03 | E·喀硕吉工业有限责任公司 | 具有类似木材的特性和超高强度的挤压成型的纤维增强水泥制品以及制造该制品的方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115636649A (zh) * | 2022-10-24 | 2023-01-24 | 上海镎素工业技术有限公司 | 可挤出加工水泥基材料及其制备方法 |
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CA2985505C (en) | 2021-05-25 |
AU2023204681A1 (en) | 2023-08-10 |
AU2015269315A1 (en) | 2017-01-19 |
AU2021203346B2 (en) | 2023-08-03 |
AU2019202740A1 (en) | 2019-05-16 |
WO2015188054A1 (en) | 2015-12-10 |
EP3157884A4 (en) | 2018-02-28 |
US20170113971A1 (en) | 2017-04-27 |
EP3157884A1 (en) | 2017-04-26 |
US10538459B2 (en) | 2020-01-21 |
BR112016028409B1 (pt) | 2022-09-20 |
BR112016028409A2 (pt) | 2018-07-03 |
CA2985505A1 (en) | 2015-12-10 |
AU2021203346A1 (en) | 2021-06-24 |
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