CN106430956A - Lemon yellow crystal bead blank and preparation method thereof - Google Patents
Lemon yellow crystal bead blank and preparation method thereof Download PDFInfo
- Publication number
- CN106430956A CN106430956A CN201610757781.8A CN201610757781A CN106430956A CN 106430956 A CN106430956 A CN 106430956A CN 201610757781 A CN201610757781 A CN 201610757781A CN 106430956 A CN106430956 A CN 106430956A
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- parts
- bead blank
- lemon yellow
- crystal bead
- yellow color
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/10—Forming beads
- C03B19/1005—Forming solid beads
- C03B19/1035—Forming solid beads by pressing
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/0028—Compositions for glass with special properties for crystal glass, e.g. lead-free crystal glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/02—Compositions for glass with special properties for coloured glass
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Preparation Of Fruits And Vegetables (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Storage Of Fruits Or Vegetables (AREA)
Abstract
The invention discloses a lemon yellow crystal bead blank and a preparation method thereof. The lemon yellow crystal bead blank is prepared from, by weight, 100-150 parts of quartz sand, 20-60 parts of soda ash, 20-80 parts of potassium carbonate, 1-12 parts of calcium carbonate, 0.1-7 parts of table salt, 7-25 parts of boric acid, 0.4-13 parts of aluminum hydroxide, 2-30 parts of zinc oxide, 0.02-8 parts of activated carbon, 0.2-8 parts of sodium fluorophosphate and 0.9-4.5 parts of cadmium yellow. When the lemon yellow crystal bead blank is prepared, cadmium yellow is adopted as a colorant, and therefore the good colorability is achieved; sodium fluorophosphate is adopted to be mixed with all the raw materials, lead-containing raw materials are not adopted, and therefore the advantages that the color is good, bright, uniform and free of chromatic aberration, no pattern is generated, the yield is high, lead and dust pollution is not generated, the production benefit is good, and batched production can be achieved are achieved.
Description
Technical field
The present invention relates to a kind of lemon yellow color crystal bead blank and preparation method thereof.
Background technology
Lemon yellow color crystal bead blank is used to prepare the semi-finished product of lemon yellow color crystal product, existing lemon yellow face
Look crystal bead blank technique uses crucible manufacture, exists and yields poorly, and aberration, coloring instability, has decorative pattern, and product quality is unstable
Fixed, production efficiency is low, is not suitable for producing in enormous quantities continuously, additionally leaded, and burns with coal and cause environmental pollution.
Content of the invention
The technical problem to be solved be to provide one color reproduction good, solid colour no color differnece, without decorative pattern,
Unleaded, no dust pollution, constant product quality, production efficiency is high, can be suitable for the lemon yellow color of the production operation of continuous tank furnace
Crystal bead blank.
For solving the problems referred to above, the present invention is achieved through the following technical solutions：A kind of lemon yellow color crystal pearl
Embryo, this lemon yellow color crystal bead blank is made up of following weight composition:Quartz sand 100-150 part, soda ash 20-60
Part, potassium carbonate 20-80 part, calcium carbonate 1-12 part, salt 0.1-7 part, boric acid 7-25 part, aluminium hydroxide 0.4-13 part, zinc oxide
2-30 part, activated carbon 0.02-8 part, sodium fluoro phosphate 0.2-8 part and cadmium yellow 0.9-4.5 part.
Another technical problem to be solved by this invention is to provide the preparation method of a kind of lemon yellow color crystal bead blank,
The present invention is achieved through the following technical solutions：The preparation process of described lemon yellow color crystal bead blank is such as
Under：
1) quartz sand 100-150 part, soda ash 20-60 part, potassium carbonate 20-80 part, calcium carbonate 1-are extracted by weight ratio
12 parts, salt 0.1-7 part, boric acid 7-25 part, aluminium hydroxide 0.4-13 part, zinc oxide 2-30 part, activated carbon 0.02-8 part, fluorine phosphorus
Acid sodium 0.2-8 part and cadmium yellow 0.9-4.5 part mix；
2) the lemon yellow color crystal bead blank raw material mixing is granulated by comminutor；
3) granular lemon yellow color crystal bead blank raw material will be made put in glass quartz tank furnace and found, throw by several times
Enter, put into once per hour, when founding, keep oxidizing atmosphere and liquid level of solution stable；
4) crystal solution is molded into lemon yellow color crystal bead blank after the homogenizing cooling of material road；
5) shaping pearl embryo is put into fire and throws stove polishing, integer, uniform coloring, during polishing, first allow blank be stained with composite,
Allowing shaping pearl embryo at the uniform velocity enter stainless steel pipes, pipe temperature controls at 950 DEG C-1000 DEG C, rotating speed 150 revolutions per seconds, duct length
It is 7.5 meters, in pipeline 7 minutes；
6) pipeline out enters tank of giving a dinner of welcome, from tank of giving a dinner of welcome be exactly out through integer, uniform coloring, no color differnece, without decorative pattern
Lemon yellow color crystal bead blank.
Further, described in the preparation process 3 of lemon yellow color crystal bead blank, when founding, temperature controls 1350
℃-1400℃.
Further, described in the preparation process 4 of lemon yellow color crystal bead blank, chilling temperature control 800 DEG C-
1000℃.
Lemon yellow color crystal bead blank of the present invention provides the benefit that：Use when prepared by described lemon yellow color crystal bead blank
Cadmium yellow is colouring agent, thus obtains good coloring；Use sodium fluoro phosphate and the mixing of various raw material, do not use leaded former
Material, has color good, bright-colored, neat, no color differnece, and without decorative pattern, yield is high, and unleaded no dust pollution, productivity effect is good, can
The advantage of batch production.
Detailed description of the invention
Following example are used for illustrating the present invention, but are not limited to the scope of the present invention.
Embodiment 1
A kind of lemon yellow color crystal bead blank of the present invention, this lemon yellow color crystal bead blank is by following weight
Composition forms:Quartz sand 150 parts, soda ash 60 parts, 80 parts of potassium carbonate, 12 parts of calcium carbonate, salt 7 parts, boric acid 25 parts, aluminium hydroxide
13 parts, 30 parts of zinc oxide, activated carbon 8 parts, sodium fluoro phosphate 8 parts and cadmium yellow 4.5 parts.
The preparation process of described lemon yellow color crystal bead blank is as follows：
1) by weight ratio extract quartz sand 150 parts, soda ash 60 parts, 80 parts of potassium carbonate, 12 parts of calcium carbonate, salt 7 parts,
Boric acid 25 parts, 13 parts of aluminium hydroxide, 30 parts of zinc oxide, activated carbon 8 parts, sodium fluoro phosphate 8 parts and cadmium yellow 4.5 parts mix；
2) the lemon yellow color crystal bead blank raw material mixing is granulated by comminutor；
3) granular lemon yellow color crystal bead blank raw material will be made put in glass quartz tank furnace and found, throw by several times
Entering, putting into once per hour, keep oxidizing atmosphere and liquid level of solution stable when founding, temperature controls at 1350 DEG C-1400 DEG C；
4) by crystal solution through material road homogenizing cooling after be molded into lemon yellow color crystal bead blank, temperature control 800 DEG C-
1000℃；
5) shaping pearl embryo is put into fire and throws stove polishing, integer, uniform coloring, during polishing, first allow blank be stained with composite,
Allowing shaping pearl embryo at the uniform velocity enter stainless steel pipes, pipe temperature controls at 950 DEG C-1000 DEG C, rotating speed 150 revolutions per seconds, duct length
It is 7.5 meters, in pipeline 7 minutes；
6) pipeline out enters tank of giving a dinner of welcome, from tank of giving a dinner of welcome be exactly out through integer, uniform coloring, no color differnece, without decorative pattern
Lemon yellow color crystal bead blank.
Embodiment 2
Its difference from Example 1 is, this lemon yellow color crystal bead blank is by following weight composition group
Become:Quartz sand 100 parts, soda ash 20 parts, 20 parts of potassium carbonate, 1 part of calcium carbonate, salt 0.1 part, boric acid 7 parts, 0.4 part of aluminium hydroxide,
2 parts of zinc oxide, activated carbon 0.02 part, sodium fluoro phosphate 0.2 part and cadmium yellow 0.9 part.
Embodiment 3
Its difference from Example 1 is, this lemon yellow color crystal bead blank is by following weight composition group
Become:Quartz sand 125 parts, soda ash 40 parts, 50 parts of potassium carbonate, 6 parts of calcium carbonate, salt 4 parts, boric acid 18 parts, 7 parts of aluminium hydroxide, oxygen
Change 16 parts of zinc, activated carbon 4 parts, sodium fluoro phosphate 4 parts and cadmium yellow 2 parts.
Embodiment 4
Its difference from Example 1 is, this lemon yellow color crystal bead blank is by following weight composition group
Become:Quartz sand 111 parts, soda ash 25 parts, 22 parts of potassium carbonate, 3 parts of calcium carbonate, salt 0.4 part, boric acid 9 parts, 0.7 part of aluminium hydroxide,
4 parts of zinc oxide, activated carbon 0.3 part, sodium fluoro phosphate 0.8 part and cadmium yellow 1.2 parts.
Embodiment 5
Its difference from Example 1 is, this lemon yellow color crystal bead blank is by following weight composition group
Become:Quartz sand 141 parts, soda ash 55 parts, 68 parts of potassium carbonate, 11 parts of calcium carbonate, salt 6 parts, boric acid 22 parts, 11 parts of aluminium hydroxide,
27 parts of zinc oxide, activated carbon 7 parts, sodium fluoro phosphate 6 parts and cadmium yellow 4 parts.
Embodiment 6
Its difference from Example 1 is, this lemon yellow color crystal bead blank is by following weight composition group
Become:Quartz sand 135 parts, soda ash 45 parts, 39 parts of potassium carbonate, 7 parts of calcium carbonate, salt 3 parts, boric acid 13 parts, 5 parts of aluminium hydroxide, oxygen
Change 16 parts of zinc, activated carbon 5 parts, sodium fluoro phosphate 0.9 part and cadmium yellow 3.2 parts.
Embodiment 7
Its difference from Example 1 is, this lemon yellow color crystal bead blank is by following weight composition group
Become:Quartz sand 100 parts, soda ash 30 parts, 33 parts of potassium carbonate, 3.2 parts of calcium carbonate, salt 0.7 part, boric acid 12 parts, aluminium hydroxide 2
Part, 15 parts of zinc oxide, activated carbon 0.1 part, sodium fluoro phosphate 1.9 parts and cadmium yellow 1.58 parts.
Embodiment 8
Its difference from Example 1 is, this lemon yellow color crystal bead blank is by following weight composition group
Become:Quartz sand 120 parts, soda ash 40 parts, 40 parts of potassium carbonate, 5 parts of calcium carbonate, salt 5 parts, boric acid 10 parts, 5 parts of aluminium hydroxide, oxygen
Change 10 parts of zinc, activated carbon 5 parts, sodium fluoro phosphate 6 parts and cadmium yellow 2.5 parts.
The present invention is not limited to above-mentioned preferred forms, anyone draw under the enlightenment of the present invention other any with
Product as the present invention is same or like, all falls within protection scope of the present invention.
Claims (4)
1. a lemon yellow color crystal bead blank, it is characterised in that：This lemon yellow color crystal bead blank is to be joined by following weight portion
Than composition composition:Quartz sand 100-150 part, soda ash 20-60 part, potassium carbonate 20-80 part, calcium carbonate 1-12 part, salt 0.1-7
Part, boric acid 7-25 part, aluminium hydroxide 0.4-13 part, zinc oxide 2-30 part, activated carbon 0.02-8 part, sodium fluoro phosphate 0.2-8 part and
Cadmium yellow 0.9-4.5 part.
2. the preparation method of the lemon yellow color crystal bead blank that a kind is prepared described in claim 1, it is characterised in that：The method bag
Include following steps：
1) by weight ratio extract quartz sand 100-150 part, soda ash 20-60 part, potassium carbonate 20-80 part, calcium carbonate 1-12 part,
Salt 0.1-7 part, boric acid 7-25 part, aluminium hydroxide 0.4-13 part, zinc oxide 2-30 part, activated carbon 0.02-8 part, sodium fluoro phosphate
0.2-8 part and cadmium yellow 0.9-4.5 part mix；
2) the lemon yellow color crystal bead blank raw material mixing is granulated by comminutor；
3) granular lemon yellow color crystal bead blank raw material will be made put in glass quartz tank furnace and found, put into by several times, often
Hour puts into once, keeps oxidizing atmosphere and liquid level of solution stable when founding；
4) crystal solution is molded into lemon yellow color crystal bead blank after the homogenizing cooling of material road；
5) shaping pearl embryo is put into fire and throw stove polishing, integer, uniform coloring, first allow blank be stained with composite during polishing, allow into
Type pearl embryo at the uniform velocity enters stainless steel pipes, and pipe temperature controls at 950 DEG C-1000 DEG C, and rotating speed 150 revolutions per seconds, duct length is
7.5 meters, in pipeline 7 minutes；
6) pipeline out enters tank of giving a dinner of welcome, and is exactly out through integer, uniform coloring, no color differnece, the lemon without decorative pattern from tank of giving a dinner of welcome
The yellow color crystal bead blank of lemon.
3. lemon yellow color crystal bead blank preparation method according to claim 2, it is characterised in that：Described in lemon yellow face
In the preparation process 3 of look crystal bead blank, when founding, temperature controls at 1350 DEG C-1400 DEG C.
4. lemon yellow color crystal bead blank preparation method according to claim 2, it is characterised in that：Described in lemon yellow face
In the preparation process 4 of look crystal bead blank, chilling temperature controls at 800 DEG C-1000 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610757781.8A CN106430956A (en) | 2016-08-29 | 2016-08-29 | Lemon yellow crystal bead blank and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610757781.8A CN106430956A (en) | 2016-08-29 | 2016-08-29 | Lemon yellow crystal bead blank and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106430956A true CN106430956A (en) | 2017-02-22 |
Family
ID=58090063
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610757781.8A Pending CN106430956A (en) | 2016-08-29 | 2016-08-29 | Lemon yellow crystal bead blank and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106430956A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080041103A1 (en) * | 2006-08-21 | 2008-02-21 | 3M Innovative Properties Company | Method of making inorganic, metal oxide spheres using microstructured molds |
| CN103922594A (en) * | 2014-03-20 | 2014-07-16 | 浙江伟兴水晶有限公司 | Bright red color crystal pearl blank and preparation method thereof |
| CN104556698A (en) * | 2015-01-06 | 2015-04-29 | 浙江伟兴水晶有限公司 | Smoke yellow crystal bead blank and preparation method thereof |
-
2016
- 2016-08-29 CN CN201610757781.8A patent/CN106430956A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080041103A1 (en) * | 2006-08-21 | 2008-02-21 | 3M Innovative Properties Company | Method of making inorganic, metal oxide spheres using microstructured molds |
| CN103922594A (en) * | 2014-03-20 | 2014-07-16 | 浙江伟兴水晶有限公司 | Bright red color crystal pearl blank and preparation method thereof |
| CN104556698A (en) * | 2015-01-06 | 2015-04-29 | 浙江伟兴水晶有限公司 | Smoke yellow crystal bead blank and preparation method thereof |
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Application publication date: 20170222 |
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