CN106220520A - 一种甜菜碱盐酸盐钙法生产工艺废母液的处理方法 - Google Patents
一种甜菜碱盐酸盐钙法生产工艺废母液的处理方法 Download PDFInfo
- Publication number
- CN106220520A CN106220520A CN201610629991.9A CN201610629991A CN106220520A CN 106220520 A CN106220520 A CN 106220520A CN 201610629991 A CN201610629991 A CN 201610629991A CN 106220520 A CN106220520 A CN 106220520A
- Authority
- CN
- China
- Prior art keywords
- waste liquor
- calcium
- beet alkali
- alkali hydrochlorate
- production technology
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 61
- 235000016068 Berberis vulgaris Nutrition 0.000 title claims abstract description 55
- 241000335053 Beta vulgaris Species 0.000 title claims abstract description 55
- 239000003513 alkali Substances 0.000 title claims abstract description 55
- 239000002699 waste material Substances 0.000 title claims abstract description 47
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 37
- 239000011575 calcium Substances 0.000 title claims abstract description 37
- 238000005516 engineering process Methods 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 19
- 238000003672 processing method Methods 0.000 title claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 38
- 238000000926 separation method Methods 0.000 claims abstract description 31
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 20
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 20
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 20
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 20
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000001117 sulphuric acid Substances 0.000 claims abstract description 14
- 235000011149 sulphuric acid Nutrition 0.000 claims abstract description 14
- 238000002425 crystallisation Methods 0.000 claims abstract description 13
- 230000008025 crystallization Effects 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000001816 cooling Methods 0.000 claims abstract description 3
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 51
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 16
- 239000012535 impurity Substances 0.000 claims description 16
- 239000000047 product Substances 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 11
- 239000000376 reactant Substances 0.000 claims description 11
- 238000004062 sedimentation Methods 0.000 claims description 7
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 5
- OLBJZJZARFENTH-UHFFFAOYSA-L calcium;2-chloroacetate Chemical compound [Ca+2].[O-]C(=O)CCl.[O-]C(=O)CCl OLBJZJZARFENTH-UHFFFAOYSA-L 0.000 claims description 3
- 238000005119 centrifugation Methods 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract description 15
- 239000010413 mother solution Substances 0.000 abstract description 13
- 238000003786 synthesis reaction Methods 0.000 abstract description 13
- 230000015572 biosynthetic process Effects 0.000 abstract description 11
- 230000018044 dehydration Effects 0.000 abstract description 10
- 238000006297 dehydration reaction Methods 0.000 abstract description 10
- 238000006243 chemical reaction Methods 0.000 abstract description 9
- 230000008901 benefit Effects 0.000 abstract description 4
- 230000004044 response Effects 0.000 abstract description 3
- 239000010808 liquid waste Substances 0.000 abstract description 2
- 235000011132 calcium sulphate Nutrition 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 238000001914 filtration Methods 0.000 description 7
- -1 amine salt Chemical class 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000000292 calcium oxide Substances 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- 230000006837 decompression Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 150000001447 alkali salts Chemical class 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000011027 product recovery Methods 0.000 description 3
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 3
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 3
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- HOPSCVCBEOCPJZ-UHFFFAOYSA-N carboxymethyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC(O)=O HOPSCVCBEOCPJZ-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- SZYJELPVAFJOGJ-UHFFFAOYSA-N trimethylamine hydrochloride Chemical compound Cl.CN(C)C SZYJELPVAFJOGJ-UHFFFAOYSA-N 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000005703 Trimethylamine hydrochloride Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005576 amination reaction Methods 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 229960004275 glycolic acid Drugs 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000009518 sodium iodide Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/38—Separation; Purification; Stabilisation; Use of additives
- C07C227/40—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C227/38—Separation; Purification; Stabilisation; Use of additives
- C07C227/40—Separation; Purification
- C07C227/42—Crystallisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Removal Of Specific Substances (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (8)
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CN201610629991.9A CN106220520B (zh) | 2016-08-04 | 2016-08-04 | 一种甜菜碱盐酸盐钙法生产工艺废母液的处理方法 |
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CN201610629991.9A CN106220520B (zh) | 2016-08-04 | 2016-08-04 | 一种甜菜碱盐酸盐钙法生产工艺废母液的处理方法 |
Publications (2)
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CN106220520A true CN106220520A (zh) | 2016-12-14 |
CN106220520B CN106220520B (zh) | 2018-05-15 |
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CN201610629991.9A Active CN106220520B (zh) | 2016-08-04 | 2016-08-04 | 一种甜菜碱盐酸盐钙法生产工艺废母液的处理方法 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108440321A (zh) * | 2018-04-25 | 2018-08-24 | 山东祥维斯生物科技股份有限公司 | 一种处理甜菜碱盐酸盐钠法生产工艺废母液的方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103524364A (zh) * | 2013-10-22 | 2014-01-22 | 潍坊祥维斯化学品有限公司 | 一种三甲基甘氨酸盐酸盐母液处理工艺 |
CN105367432A (zh) * | 2015-12-02 | 2016-03-02 | 山东祥维斯生物科技股份有限公司 | 一种制备钙法甜菜碱的方法 |
-
2016
- 2016-08-04 CN CN201610629991.9A patent/CN106220520B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103524364A (zh) * | 2013-10-22 | 2014-01-22 | 潍坊祥维斯化学品有限公司 | 一种三甲基甘氨酸盐酸盐母液处理工艺 |
CN105367432A (zh) * | 2015-12-02 | 2016-03-02 | 山东祥维斯生物科技股份有限公司 | 一种制备钙法甜菜碱的方法 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108440321A (zh) * | 2018-04-25 | 2018-08-24 | 山东祥维斯生物科技股份有限公司 | 一种处理甜菜碱盐酸盐钠法生产工艺废母液的方法 |
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CN106220520B (zh) | 2018-05-15 |
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EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20161214 Assignee: SHANDONG IFT SCIENCE & TECHNOLOGY CO.,LTD. Assignor: CHEMICAL TECHNOLOGY ACADEMY OF SHANDONG PROVINCE Contract record no.: 2018370000038 Denomination of invention: Method for treating waste mother liquor in calcium-based method production process of betaine hydrochloride Granted publication date: 20180515 License type: Common License Record date: 20180907 |
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TR01 | Transfer of patent right |
Effective date of registration: 20240718 Address after: No. 80 Wenhua East Road, Lixia District, Jinan City, Shandong Province, China 250101 Patentee after: QINGDAO University OF SCIENCE AND TECHNOLOGY Country or region after: China Address before: 250014 No. 80, Wenhua East Road, Lixia District, Shandong, Ji'nan Patentee before: CHEMICAL TECHNOLOGY ACADEMY OF SHANDONG PROVINCE Country or region before: China |