CN106049091A - Dye paste composition for dye and pigment integrated dyeing and printing - Google Patents
Dye paste composition for dye and pigment integrated dyeing and printing Download PDFInfo
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- CN106049091A CN106049091A CN201610580279.4A CN201610580279A CN106049091A CN 106049091 A CN106049091 A CN 106049091A CN 201610580279 A CN201610580279 A CN 201610580279A CN 106049091 A CN106049091 A CN 106049091A
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- alkyl
- phenyl
- benzyl
- phenethyl
- alkoxyl
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
- D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a dye composition for disperse dye dyeing and printing. The dye composition is used for disperse dye and pigment integrated dyeing or printing and composed of azeo, anthraquinone or heterocycle disperse dye, auxiliaries and water. By refining of the composition, a disperse dye composition for dye and pigment integrated dyeing or printing is prepared and can be matched with dye and pigment integrated dyeing and printing auxiliaries, a thickening agent and water to prepare paste for dye and pigment integrated dyeing and printing. The paste used for dyeing and printing of hydrophobic textile materials integrates advantages of dye dyeing and printing and pigment dyeing and printing, high fastness to dry and wet rubbing, water washing and sublimation can be guaranteed while color brightness and softness are achieved; in addition, high-concentration color water generated in a traditional disperse dye dyeing and printing process can be avoided. Therefore, the product is a clean and environment-friendly product for dye dyeing and printing.
Description
Technical field
The present invention relates to textile dyeing, printing technique, specifically one dye is coated with one dyeing, printing dyes slurry
Shape compositions.
Background technology
Textile dyeing, stamp generally can be divided into two kinds of dyeing, stamp and pigment dyeing, stamp.Dyeing, print
Flower carries out dyeing typically by the molecular separating force of dyestuff itself or active group and fibration, stamp.Pigment dyeing, stamp
It is to combine with fabric by the way of the binding agent in pigment dyeing, printing paste is with physical adhesion.As a rule dye printing
After the dyeing that obtains, Printing more environmentally friendly, content of formaldehyde is low, bright, and color fastness is preferable, the most soft, stamp
Position is tack-free;Pigment printing technique is simple, and stamp low cost does not has the three wastes to produce substantially.
Conventional dyes dyeing, printing technology be generally: textile → stamp → drying → decatize → washing → reduction washes →
Soap → wash → dry → arrange → stamp finished product.Conventional dyes dyeing, printing paste typically require addition dye dosage 1-
The auxiliary agents such as the sodium alginate of 1.5 times amount, sodium lignin sulfonate, naphthalene sulfonic acid-formaldehyde condensation product, dispersant, levelling agent, penetrating agent produce
Product, these auxiliary agents need washing, reduction to wash after dyeing, stamp process complete and the step such as soap makes it shell from fiber surface
From, hence in dyeing, printing waste water.During conventional dyes dyeing simultaneously, stamp, the dye-uptake of dyestuff is generally
90-95%, the dyestuff of remaining 5-10% after dyeing, stamp complete presented in loose colour in fiber surface, wash, also
Former wash and soap during also can enter in dyeing waste water.These just enter into the auxiliary agent in dyeing, printing waste water and dyestuff
Causing high COD and the high chroma of dyeing waste water, intractability is relatively big, and processing cost is higher, according to authority's statistics, print works
Often processing a myriametre chemical fiber plus material it is necessary to water consumption about 250 tons, wherein 90% is color water, waste water.And present maximally effective measure
The most only rest on reduce discharging and color water, sewage post processing on, the most effectively eradicated.These dyeing waste waters become
Puzzlement China textile printing, the obstacle of the sustainable sustainable development of printing and dyeing industry.
Pigment printing technique relatively dye printing is simply a lot, generally textile → stamp → drying → baking → arrangement
→ stamp finished product, does not has water-washing step during stamp, dry and shrink control and cross contamination, naturally occurring or synthetic thickener
Removal, the existence of alkaline agent, surfactant and other pollutant all can be left in the basket, for environment protection type dye, printing technology.But
Being that the colouring component that pigment printing is selected is generally pigment, itself is not had affinity with fiber, needs to be adhered to by binding agent
In fiber surface, and color typically cannot penetrate into fibrous inside, and this has resulted in pigment printing product general color permeability
Poor, color is the most bright-coloured, color fastness is poor, not wash resistant, the shortcomings such as feel is partially hard, anti-yellowing property difference.
Dyeing, stamp are combined with pigment dyeing, stamp, takes into account its respective advantage, its defect is done simultaneously
Being complementary to one another, the new way of can yet be regarded as a kind of dyeing, stamp, the present invention is exactly to produce in such a situa-tion.
Summary of the invention
It is desirable to provide a kind of dye is coated with one dyeing, printing dyes paste composition.
For achieving the above object, the present invention uses the technical scheme to be:
A kind of dye is coated with one dyeing, printing dyes paste composition, compositions be formula (I), (II), (III), (IV),
(V), (VI), (VII), (VIII), one or more in the dyestuff shown in (IX) mix to obtain mixed slurry with auxiliary agent and water, then
Prepare dye by micronization processes and be coated with one dyeing, stamp disperse dye composition;
Wherein, each composition by weight percentage, dyestuff 20-60%, auxiliary agent 5-30% and water 10-75%;
Described formula (I) is:
R1、R2、R3It is respectively and independently selected from H, Cl, Br, I, CN, NO2、NHCO-X1、O-X1、NHSO2-X1Or OSO2-X1;X1For
C1-C6Alkyl, phenyl, benzyl or phenethyl;
R4、R5It is respectively and independently selected from H, quilt-CN, OCO-X2、-COO-X2、-COOCHCO-X2、-COOCHCO-X2Replace or
Unsubstituted C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl, X2For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl
Base or phenethyl;
R6Selected from C1—C6Alkyl;
R7Selected from C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl, phenethyl, CO-X3Or SO2-X3, X3For C1-C6Alkyl,
C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
Described formula (II) is:
A is selected from
In
A kind of;
R8、R9、R10、R11It is respectively and independently selected from H, Cl, Br, I, CN, NO2、NHCO-X4、O-X4、NHSO2-X4Or OSO2-X4,
X4For C1-C6Alkyl, phenyl, benzyl or phenethyl;
R12Selected from H, CN, the C that replaced by amide groups or amido derivatives1-C6Alkyl, C3-10Cycloalkyl, C7-C10Aralkyl
Base, aryl, carboxylic acid ester groups, sulfone derivative, sulfoamido derivant, acyl alkyl or halogen;
R13、R14It is respectively and independently selected from OH, Cl, Br, I, quilt-CN, OCO-X6、-COO-X6、-COOCHCO-X6Or-
COOCHCO-X6Replace or unsubstituted NH2、N-C1-C6Alkyl, N-C2-C6Thiazolinyl, N-phenyl, N-benzyl or N-phenethyl,
X6For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R15Selected from H, quilt-OSO2Ph or-COOC2H4Substituted or unsubstituted C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Alkene
Base, phenyl, benzyl or phenethyl;
R16Selected from C1-6Alkyl, C1-C6Alkoxyl, C1-C6Alkylamino, carboxyl, carboxylic propyl ester base, carbamyl, substituted ammonia
Base, hydroxyl, phenyl, cyano group, heterocyclic radical, CONH (CH2)3OMe or CH2In COOH;
R17Selected from OH or NH;
R18Selected from H, C1-C6Alkyl, C2-C6Alkenyl, phenyl, benzyl or phenethyl;
R19Selected from C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Alkenyl, phenyl, benzyl or phenethyl;
Described formula (III) is:
B is selected from
In
A kind of;
R20、R21It is respectively and independently selected from H, quilt-CN, OCO-X8、-COO-X8、-COOCHCO-X8Or-COOCHCO-X8Replace
Or unsubstituted C1-C6Alkyl, C2-C6-thiazolinyl, phenyl, benzyl or phenethyl, X8For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl,
Benzyl or phenethyl;
R22Selected from C1-C6Alkyl;
R23Selected from CO-X9Or SO2-X9, X9For C1-C6Alkyl, C2-C6Alkenyl, phenyl, benzyl or phenethyl;
R24、R25It is respectively and independently selected from H, Cl, Br, I, CN, NO2、COOX7、NHCO-X7、O-X7、NHSO2-X7Or OSO2-X7,
X7For C1-C6Alkyl, phenyl, benzyl, phenethyl;
Described formula (IV) is:
B-N=N-A
A is selected from
In
A kind of;
R12Selected from H, CN, the C that replaced by amide groups or amido derivatives1-C6Alkyl, C3-C10Cycloalkyl, C7-C10Virtue
Alkyl, aryl, carboxylic acid ester groups, sulfone derivative, sulfoamido derivant, acyl alkyl or halogen;
R13、R14It is respectively and independently selected from OH, Cl, Br, I, quilt-CN, OCO-X6、-COO-X6、-COOCHCO-X6Or-
COOCHCO-X6Replace or unsubstituted NH2、N-C1-C6Alkyl, N-C2-C6Thiazolinyl, N-phenyl, N-benzyl or N-phenethyl,
X6For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R15Selected from H, quilt-OSO2Ph or-COOC2H4Substituted or unsubstituted C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Alkene
Base, phenyl, benzyl or phenethyl;
R16Selected from C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Alkylamino, carboxyl, carboxylic propyl ester base, carbamyl, substituted ammonia
Base, hydroxyl, phenyl, cyano group, heterocyclic radical, CONH (CH2)3OMe or CH2COOH;
R17Selected from OH or NH;
R18Selected from H, C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R19Selected from C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
B is selected from
In
A kind of;
R24、R25It is respectively and independently selected from H, Cl, Br, I, CN, NO2、COOX7、NHCO-X7、O-X7、NHSO2-X7Or OSO2-X7,
X7For C1-C6Alkyl, phenyl, benzyl or phenethyl;
Described formula (V) is selected from:
R26、R27、R28、R29It is respectively and independently selected from H, NH2、OH、SH、NO2、NH-X8、O-X8、S-X8、NHCO-X8Or SO2NH-
X8, X8For by OH, CN, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl or C7-C10Aralkyl replace or
Unsubstituted C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl, phenethyl, C3-C10Cycloalkyl, C7-C10
Aralkyl or C2-C6Thiazolinyl;
R30、R31It is respectively and independently selected from H, Cl, Br, I, CN, SO2NH-X9、O-X9、O-(CH2CH2O)n-X9、O-X9-O-X9、
S-X9、S-(CH2CH2O)n-X9Or S-X9-O-X9, X9For by OH, CN, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-
C10Cycloalkyl or C7-C10Aralkyl replaces or unsubstituted C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl
Base, phenethyl, C3-C10Cycloalkyl, C7-C10Aralkyl or C2-C6Thiazolinyl;
Described logical formula (VI) is:
R32Selected from by OH, CN, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl, C7-C10Aralkyl
Replace or unsubstituted C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl, phenethyl, C3-C10Cycloalkyl,
C7-C10Aralkyl or C2-C6Alkenyl;
R33Selected from O or NH;
Described logical formula (VII) is:
R34Selected from H, Cl, Br, I, CN, NO2Or OH;
R35Selected from H, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl or C7-C10Aralkyl;
R36、R37Be respectively and independently selected from H, Cl, Br, I, by C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Ring
Alkyl, C7-C10The substituted or unsubstituted amide groups of aralkyl, sulfonyl or sulfoamido;
Described logical formula (VIII) is:
Y is selected from O, S or NH;
R38、R39It is respectively and independently selected from H, by C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl, C7-
C10Aralkyl is monosubstituted or one in disubstituted imido grpup;
R40、R41It is respectively and independently selected from H, Cl, Br, I, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkanes
Base or C7-C10Aralkyl;
Described logical formula (IX) is:
R42、R43It is respectively and independently selected from H, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl, phenethyl,
C3-C10Cycloalkyl, C7-C10Aralkyl, C2-C6Thiazolinyl, by C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Ester group, C1-C6Hydroxyalkyl,
C3-C10Cycloalkyl, C7-C10Aralkyl is monosubstituted or polysubstituted C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl,
Benzyl, phenethyl, C3-C10Cycloalkyl, C7-C10Aralkyl or C2-C6Thiazolinyl.
Preferably dye is coated with one dyeing, printing dyes paste composition, by formula (I), (II), (III), (IV), (V),
(VI), (VII), (VIII), one or more in the dyestuff shown in (IX) mix to obtain mixed slurry with auxiliary agent and water, then pass through
Micronization processes makes mixed slurry particle diameter D90 be 0.1-2 μm, prepares dye and is coated with one dyeing, stamp disperse dye composition.
Preferably, the dyestuff shown in formula (I), (II), (III), (IV), (V), (VI), (VII), (VIII), (IX) is:
Described formula (I) is:
R1、R2、R3It is respectively and independently selected from H, Cl, Br, I, CN, NO2;
R4、R5It is respectively and independently selected from H, quilt-CN, OCO-X2、-COO-X2Replace or unsubstituted C1-C6Alkyl, benzene
Base, benzyl or phenethyl, X2For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R6It is respectively and independently selected from C1—C6Alkyl;
R7It is respectively and independently selected from CO-X3Or SO2-X3, X3For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
Described formula (II) is:
A is selected from
In
A kind of;
R8、R9、R10、R11It is respectively and independently selected from H, Cl, Br, I, CN, NO2、O-X4, X4For C1-C6Alkyl, phenyl, benzyl or
Phenethyl;
R12Selected from H, CN, the C that replaced by amide groups or amido derivatives1-C6Alkyl, C3-10Cycloalkyl, C7-C10Aralkyl
Base, aromatic radical;
R13、R14It is respectively and independently selected from OH, Cl, Br, I, quilt-CN, OCO-X6、-COO-X6Replace or unsubstituted
NH2、N-C1-C6Alkyl, N-phenyl, N-benzyl or N-phenethyl, X6For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or benzene second
Base;
R15Selected from C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R16Selected from C1-6Alkyl, C1-C6Alkoxyl, C1-C6Alkylamino, substituted amino, hydroxyl, phenyl, cyano group;
R17Selected from OH or NH;
R18Selected from H, C1-C6Alkyl, C2-C6Alkenyl, phenyl, benzyl or phenethyl;
R19Selected from C1-C6Alkyl, C1-C6Alkoxyl, C2-C6One in alkenyl, phenyl, benzyl or phenethyl;
Described formula (III) is:
B is selected from
In
A kind of;
R20、R21It is respectively and independently selected from H, quilt-CN, OCO-X8、-COO-X8、-COOCHCO-X8Or-COOCHCO-X8Replace
Or unsubstituted C1-C6Alkyl, C2-C6-thiazolinyl, phenyl, benzyl or phenethyl, X8For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl,
Benzyl or phenethyl;
R22Selected from C1-C6Alkyl;
R23Selected from CO-X9Or SO2-X9, X9For C1-C6Alkyl, C2-C6Alkenyl, phenyl, benzyl or phenethyl;
R24、R25It is respectively and independently selected from H, Cl, Br, I, CN, NO2、NHCO-X7、O-X7、NHSO2-X7Or OSO2-X7, X7For
C1-C6Alkyl, phenyl, benzyl, phenethyl;
Described formula (IV) is:
B-N=N-A
A is selected from
In
A kind of;
R12Selected from H, CN, the C that replaced by amide groups or amido derivatives1-C6Alkyl, C3-10Cycloalkyl, C7-C10Aralkyl
Base, aromatic radical;
R13、R14It is respectively and independently selected from OH, Cl, Br, I, quilt-CN, OCO-X6、-COO-X6Replace or unsubstituted
NH2、N-C1-C6Alkyl, N-phenyl, N-benzyl or N-phenethyl, X6For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or benzene second
Base;
R15Selected from C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R16Selected from C1-6Alkyl, C1-C6Alkoxyl, C1-C6Alkylamino, substituted amino, hydroxyl, phenyl, cyano group;
R17Selected from OH or NH;
R18Selected from H, C1-C6Alkyl, C2-C6Alkenyl, phenyl, benzyl or phenethyl;
R19Selected from C1-C6Alkyl, C1-C6Alkoxyl, C2-C6One in alkenyl, phenyl, benzyl or phenethyl;
B is selected from
In
A kind of;
R24、R25It is respectively and independently selected from H, Cl, Br, I, CN, NO2、NHCO-X7、O-X7、NHSO2-X7Or OSO2-X7, X7For
C1-C6Alkyl, phenyl, benzyl, phenethyl;
Described formula (V) is selected from:
R26、R27、R28、R29It is respectively and independently selected from H, NH2、OH、SH、NH-X8、O-X8Or S-X8, X8For by OH, CN, C1-C6
Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl or C7-C10Aralkyl replaces or unsubstituted C1-C6Alkyl,
C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl, phenethyl, C3-C10Cycloalkyl, C7-C10Aralkyl or C2-C6Thiazolinyl;
R30、R31It is respectively and independently selected from H, Cl, Br, I, CN, SO2NH-X9、O-X9、O-(CH2CH2O)n-X9、O-X9-O-X9、
S-X9、S-(CH2CH2O)n-X9Or S-X9-O-X9, X9For by OH, CN, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-
C10Cycloalkyl or C7-C10Aralkyl replaces or unsubstituted C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl
Base, phenethyl, C3-C10Cycloalkyl, C7-C10Aralkyl or C2-C6Thiazolinyl;
Described logical formula (VI) is:
R32Selected from by OH, CN, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl, C7-C10Aralkyl
Replace or unsubstituted C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl, phenethyl, C3-C10Cycloalkyl,
C7-C10Aralkyl or C2-C6Alkenyl;
R33Selected from O or NH;
Described logical formula (VII) is:
R34Selected from H, Cl, Br, I, CN or NO2;
R35Selected from H, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl or C7-C10Aralkyl;
R36、R37Be respectively and independently selected from H, Cl, Br, I, by C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Ring
Alkyl, C7-C10The substituted or unsubstituted amide groups of aralkyl, sulfonyl or sulfoamido;
Described logical formula (VIII) is:
Y is selected from O, S or NH;
R38、R39It is respectively and independently selected from H, by C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl, C7-
C10Aralkyl is monosubstituted or one in disubstituted imido grpup;
R40、R41It is respectively and independently selected from H, Cl, Br, I, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkanes
Base or C7-C10Aralkyl;
Described logical formula (IX) is:
R42、R43It is respectively and independently selected from H, C1-C6Alkyl, C1-C6Alkoxyl, phenyl, benzyl, phenethyl, by C1-C6Alkyl,
C1-C6Alkoxyl, C2-C6Ester group, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl, C7-C10Aralkyl is monosubstituted or polysubstituted C1-C6Alkane
Base, C1-C6Alkoxyl, phenyl, benzyl, phenethyl.
Dyestuff shown in formula (I), (II), (III), (IV), (V), (VI), (VII), (VIII), (IX) is preferred further
For:
Described formula (I) is:
R1、R2、R3It is respectively and independently selected from H, Cl, Br, I, CN, NO2;
R4、R5It is respectively and independently selected from H, quilt-CN, OCO-X2、-COO-X2Replace or unsubstituted C1-C4Alkyl, benzene
Base, benzyl or phenethyl, X2For C1-C4Alkyl, phenyl, benzyl or phenethyl;
R6It is respectively and independently selected from C1-C4Alkyl;
R7It is respectively and independently selected from CO-X3Or SO2-X3, X3For C1-C4Alkyl, phenyl, benzyl or phenethyl;
Described formula (II) is:
A is selected from
In one;
R8、R9、R10、R11It is respectively and independently selected from H, Cl, Br, I, CN, NO2、O-X4, X4For C1-C4Alkyl, phenyl, benzyl or
Phenethyl;
R12Selected from H, CN, the C that replaced by amide groups or amido derivatives1-C4Alkyl, C3-6Cycloalkyl, C7-C10Aralkyl
Base, aromatic radical;
R13、R14It is respectively and independently selected from OH, Cl, Br, I, quilt-CN, OCO-X6、-COO-X6Replace or unsubstituted
NH2、N-C1-C4Alkyl, N-phenyl, N-benzyl or N-phenethyl, X6For C1-C4Alkyl, phenyl, benzyl or phenethyl;
R15Selected from C1-C4Alkyl, C1-C4Alkoxyl, phenyl, benzyl or phenethyl;
R16Selected from C1-4Alkyl, C1-C4Alkoxyl, C1-C4Alkylamino, substituted amino, hydroxyl, phenyl, cyano group;
R17Selected from OH or NH;
R18Selected from H, C1-C4Alkyl, phenyl, benzyl or phenethyl;
R19Selected from C1-C4Alkyl, C1-C4One in alkoxyl, phenyl, benzyl or phenethyl;
Described formula (III) is:
B is selected from
In one;
R20、R21It is respectively and independently selected from H, quilt-CN, OCO-X8、-COO-X8、-COOCHCO-X8Or-COOCHCO-X8Replace
Or unsubstituted C1-C4Alkyl, phenyl, benzyl or phenethyl, X8For C1-C4Alkyl, phenyl, benzyl or phenethyl;
R22Selected from C1-C4Alkyl;
R23Selected from CO-X9Or SO2-X9, X9For C1-C4Alkyl, phenyl, benzyl or phenethyl;
R24、R25It is respectively and independently selected from H, Cl, Br, I, CN, NO2、NHCO-X7、O-X7、NHSO2-X7Or OSO2-X7, X7For
C1-C4Alkyl, phenyl, benzyl, phenethyl;
Described formula (IV) is:
B-N=N-A
A is selected from
In one;
R12Selected from H, CN, the C that replaced by amide groups or amido derivatives1-C4Alkyl, C3-6Cycloalkyl, C7-C10Aralkyl
Base, aromatic radical;
R13、R14It is respectively and independently selected from OH, Cl, Br, I, quilt-CN, OCO-X6、-COO-X6Replace or unsubstituted
NH2、N-C1-C4Alkyl, N-phenyl, N-benzyl or N-phenethyl, X6For C1-C4Alkyl, phenyl, benzyl or phenethyl;
R15Selected from C1-C4Alkyl, C1-C4Alkoxyl, phenyl, benzyl or phenethyl;
R16Selected from C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Alkylamino, substituted amino, hydroxyl, phenyl, cyano group;
R17Selected from OH or NH;
R18Selected from H, C1-C4Alkyl, phenyl, benzyl or phenethyl;
R19Selected from C1-C4Alkyl, C1-C4Alkoxyl, phenyl, benzyl or phenethyl;
B is selected from
In one;
R24、R25It is respectively and independently selected from H, Cl, Br, I, CN, NO2、NHCO-X7、O-X7、NHSO2-X7Or OSO2-X7, X7For
C1-C4Alkyl, phenyl, benzyl, phenethyl;
Described formula (V) is selected from:
R26、R27、R28、R29It is respectively and independently selected from H, NH2、OH、SH、NH-X8、O-X8Or S-X8, X8For by OH, CN, C1-C4
Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-C6Cycloalkyl or C7-C10Aralkyl replaces or unsubstituted C1-C4Alkyl,
C1-C4Alkoxyl, C1-C4Hydroxyalkyl, phenyl, benzyl, phenethyl, C3-C6Cycloalkyl, C7-C10Aralkyl;
R30、R31It is respectively and independently selected from H, Cl, Br, I, CN, SO2NH-X9、O-X9、O-(CH2CH2O)n-X9、O-X9-O-X9、
S-X9、S-(CH2CH2O)n-X9Or S-X9-O-X9, X9For by OH, CN, C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-
C6Cycloalkyl or C7-C10Aralkyl replaces or unsubstituted C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, phenyl, benzyl
Base, phenethyl, C3-C6Cycloalkyl, C7-C10Aralkyl;
Described logical formula (VI) is:
R32Selected from by OH, CN, C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-C6Cycloalkyl, C7-C10Aralkyl
Replace or unsubstituted C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, phenyl, benzyl, phenethyl, C3-C6Cycloalkyl,
C7-C10Aralkyl;
R33Selected from O or NH;
Described logical formula (VII) is:
R34Selected from H, Cl, Br, I, CN or NO2;
R35Selected from H, C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-C6Cycloalkyl or C7-C10Aralkyl;
R36、R37Be respectively and independently selected from H, Cl, Br, I, by C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-C6Ring
Alkyl, C7-C10The substituted or unsubstituted amide groups of aralkyl, sulfonyl or sulfoamido;
Described logical formula (VIII) is:
Y is selected from O, S or NH;
R38、R39It is respectively and independently selected from H, by C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-C6Cycloalkyl, C7-
C10Aralkyl is monosubstituted or one in disubstituted imido grpup;
R40、R41It is respectively and independently selected from H, Cl, Br, I, C1-C6Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-C6Cycloalkanes
Base or C7-C10Aralkyl;
Described logical formula (IX) is:
R42、R43It is respectively and independently selected from H, C1-C4Alkyl, C1-C4Alkoxyl, phenyl, benzyl, phenethyl, by C1-C4Alkyl,
C1-C4Alkoxyl, C2-C6Ester group, C1-C4Hydroxyalkyl, C3-C6Cycloalkyl, C7-C10Aralkyl is monosubstituted or polysubstituted C1-C4Alkane
Base, C1-C4Alkoxyl, phenyl, benzyl, phenethyl.
Above-mentioned part of compounds is commercially available, or clearance be now documented in prepare.
Described auxiliary agent is selected from polyvinyl alcohol, polyvinyl acetate, styrene and maleic anhydride multipolymer, gelatin, carboxylic first
Base cellulose, carboxyethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, ethylene glycol, propylene glycol, carbamide, diethylene glycol, sulfur
One or more in urea, mineral oils, high-carbon alcohols, polyethers or silicone defoamer and sodium alginate, polyacrylamide
Amine, N-methyl-N oleoyl taurine sodium, LOMAR PWA EINECS 246-676-2-formaldehyde condensation products, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol
Ethylene oxide condensate, triisopropylbenzene phenol ethylene oxide condensates, sodium lignin sulfonate, Oleum Ricini oleic alcohol, 12
Sodium alkyl benzene sulfonate, metacresol-formaldehyde-sodium sulfite condensation substance extension agent S S, diffusion agent N, dispersing agent MF, dispersing agent CNF, first
Base naphthalene sulfonic acid-formaldehyde condensation product, cresol (or phenol) sodium sulfonate formaldehyde condensation products, beta naphthal sulfonic formaldehyde condensation compound, phenolic resin
Sulfonated bodies, dispersing agent C S;Fatty acid salt form anion surfactant, sulfonate type anion surfactant, sulfate type
Anion surfactant, phosphate ester salt form anion surfactant, 2-Sulfosuccinic acid ester type anion surfactant, fat
Fat acid type anion surfactant, peptide condensation substance type anion surfactant;Ammonium salt type cationic surfactant, quaternary ammonium
Salt form cationic surfactant, oxidation ammonium type cationic surfactant, betaine type amphoteric ionic surface active agent, imidazoles
Quinoline type zwitterionic surfactant, amino acid type amphoteric ionic surface active agent, phosphatide type zwitterionic surfactant, fat
Fat alcohol ether type nonionic surfactant, alkyl phenol ether type nonionic surfactant, alkylamine ether type non-ionic surface active
Agent, polyether nonionic surfactant, fatty acid polyglycol alkoxide ester type nonionic surfactant, castor oil polyoxyethylene
Type nonionic surfactant, lanoline Determination of Polyoxyethylene Non-ionic Surfactants, sorbitol polyoxyethylene type nonionic table
Face activating agent, glycerol ester type nonionic surfactant, sorbitol ester type nonionic surfactant, fatty acid alkanamine type non-from
Sub-surface activating agent, alkylolamides type nonionic surfactant, alkyl polyglucoside type nonionic surfactant, alkyl pyrroles
Alkanone type nonionic surfactant, alcohol surfactants, acids surfactant, amine surfactants, amide-type table
Face activating agent, esters surface active agent, ether surfactant, ketone surfactant, polymer types of surfactants, Semen Ricini
Oils surfactant, Pilus Caprae seu Ovis lipid surfactant, three polyglyceryl laurate, four polyglyceryl laurate, six polyglycereol
The combination of one or more in laurate, Tripolyglycerol monostearates, three polyglycerol acrylate;
Described water is: one or more in tap water, deionized water, distilled water, high purity water, ultra-pure water compositions.
Described auxiliary agent preferably is selected from one or more in mineral oils, high-carbon alcohols, polyethers or silicone defoamer
With LOMAR PWA EINECS 246-676-2-formaldehyde condensation products, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol ethylene oxide condensate, sodium lignin sulfonate,
Oleum Ricini oleic alcohol, dodecylbenzene sodium sulfonate, extension agent S S, diffusion agent N, dispersing agent MF, dispersing agent CNF, methyl naphthalene
Sulfonic formaldehyde condensation compound, beta naphthal sulfonic formaldehyde condensation compound, dispersing agent C S, fatty acid salt form anion surfactant, sulfonic acid
Salt form anion surfactant, sulfate type anion surfactant, phosphate ester salt form anion surfactant, sulfo group
Live in succinic acid ester type anion surfactant, betaine type amphoteric ionic surface active agent, imidazoline type amphion surface
Property agent, amino acid type amphoteric ionic surface active agent, phosphatide type zwitterionic surfactant, fatty alcohol ether type non-ionic surface
Activating agent, alkyl phenol ether type nonionic surfactant, alkylamine ether type nonionic surfactant, polyether-type nonionic surface
Activating agent, fatty acid polyglycol alkoxide ester type nonionic surfactant, castor oil polyoxyethylene type nonionic surfactant,
Lanoline Determination of Polyoxyethylene Non-ionic Surfactants, sorbitol polyoxyethylene type nonionic surfactant, glycerol ester type are non-
Ionic surface active agent, sorbitol ester type nonionic surfactant, fatty acid alkanamine type nonionic surfactant, alkylol
Acid amide type nonionic surfactant, alkyl polyglucoside type nonionic surfactant, alkyl pyrrolidone type non-ionic surface are lived
The mixing of one or more in property agent, ethylene glycol, propylene glycol, carbamide, diethylene glycol.
Above-mentioned acquisition dyeing, thickening agent compositions are prepared, with other auxiliary agents and water, dyeing, the concentrator obtained;Its
In, other auxiliary agents are dyeing, printing assistant, auxiliary agent with slurry, thickening agent and pH value regulator;
Dyeing, concentrator particular make-up following (percentage by weight):
Dyeing described above, printing assistant form following (percentage by weight):
In described dyeing, printing assistant, binding agent glues selected from pure third binding agent, phenylpropyl alcohol binding agent, butylbenzene binding agent, butyronitrile
One or more in mixture, silicone adhesive, organosilicon modified acrylic ester binding agent, polyurethane binder etc. can be used for
Dye is coated with one dyeing, the binding agent of printing assistant;
In described dyeing, printing assistant, softening agent is selected from: quaternary, fatty acid ester type, right wax pattern, polyethylene, have
The cationic softeners such as machine silicone type, silicone softening agent, soap film class softening agent, double hexadecyldimethylamine
Ammonium chloride, ester based quaternary ammonium salt type softening agent, Cationic Gemini Surfactant, high-molecular polythene wax, poly dimethyl silicon
One or more in oxygen alkane, hydroxy-terminated polysiloxane, amino silicones etc. can be used for dye and are coated with one dyeing, printing assistant
Softening agent.
In described dyeing, printing assistant, cross-linking agent is selected from: JQ-1, JQ-1E, JQ-2E, JQ-4, JQ-5, JQ-6, PAPI, can
The cyanate cross-linking agent such as emulsifying MDI, tetraisocyanate, blocked isocyanate, Polyethylene Glycol, polypropylene glycol, trihydroxy methyl third
The polyalcohols cross-linking agent such as alkane, (+)-2,3-Epoxy-1-propanol ethers cross-linking agent, the inorganic matter such as zinc chloride, aluminum chloride, aluminum sulfate, sulfur, boric acid
Cross-linking agent, the crosslinking of the Organic substance such as styrene, α-methyl styrene, acrylonitrile, acrylic acid, methacrylic acid, Biformyl, aziridine
Agent, tetraethyl orthosilicate, methyl silicate, trimethicone, amino modified siloxanes, carboxy-modified siloxanes, hydroxyl modification
The silicone cross-linking agent such as siloxanes, vinylsiloxane, the benzenesulfonic acid class cross-linking agent such as p-methyl benzenesulfonic acid, paratoluensulfonyl chloride,
Diacrylate-1,4-butanediol ester, Ethylene glycol dimethacrylate, TAC, butyl acrylate, HEA, HPA, HPMA, MMA etc.
Acrylic ester cross-linking agent, cumyl peroxide, peroxidating 2, the organic peroxide cross-linking agent such as 4-dichloro-benzoyl, isopropyl
The metallo-organic compound cross-linking agent such as aluminium alcoholates, zinc acetate, titanium acetylacetone, in multi-functional polycarbodiimide class cross-linking agent etc.
One or more can be used for dye and are coated with one dyeing, the cross-linking agent of printing assistant.
In described dyeing, printing assistant, the auxiliary agent such as diffusant, emulsifying agent, defoamer is selected from: sodium alginate, polyacrylamide
Amine, N-methyl-N oleoyl taurine sodium, LOMAR PWA EINECS 246-676-2-formaldehyde condensation products, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol
Ethylene oxide condensate, triisopropylbenzene phenol ethylene oxide condensates, sodium lignin sulfonate, Oleum Ricini oleic alcohol, 12
Sodium alkyl benzene sulfonate, metacresol-formaldehyde-sodium sulfite condensation substance extension agent S S, diffusion agent N, dispersing agent MF, dispersing agent CNF, first
Base naphthalene sulfonic acid-formaldehyde condensation product, cresol (or phenol) sodium sulfonate formaldehyde condensation products, beta naphthal sulfonic formaldehyde condensation compound, phenolic resin
Sulfonated bodies, dispersing agent C S;Fatty acid salt form, sulfonate type, sulfate type, phosphate ester salt form, 2-Sulfosuccinic acid ester type, fat
Acid/peptide condensation substance type anion surfactant;Ammonium salt type, quaternary, oxidation ammonium type cationic surfactant;Glycine betaine
Type, imidazoline type, amino acid pattern, phosphatide type zwitterionic surfactant;Fatty alcohol ether type, alkyl phenol ether type, alkyl ether amine
Type, polyether-type, fatty acid polyglycol alkoxide ester type, castor oil polyoxyethylene type, lanoline polyoxyethylene-type, sorbitol polyoxy second
Ene-type, glycerol ester type, sorbitol ester type, fatty acid alkanamine type, alkylolamides type, alkyl polyglucoside type, alkyl pyrrolidone type
Nonionic surfactant;Alcohols, acids, amine, amide-type, esters, ethers, ketone, polymerization species, Semen Ricini oils, Pilus Caprae seu Ovis
Other surfactants such as lipid;Polyvinyl alcohol, polyvinyl acetate, styrene and maleic anhydride multipolymer, gelatin, carboxylic first
Base cellulose, carboxyethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, ethylene glycol, propylene glycol, carbamide, diethylene glycol, sulfur
Urea, organic silicon defoamer, mineral oil antifoam agent, polyethers defoamer, three polyglyceryl laurate, four polyglyceryl laurate,
One or more in six polyglyceryl laurate, Tripolyglycerol monostearates, three polyglycerol acrylate etc. can be used for dye and are coated with
One dyeing, other auxiliary agents of printing assistant;
In described dyeing, printing assistant, water is: tap water, deionized water, distilled water, high purity water, ultra-pure water etc. can be used for
Dyeing, stamp dye is coated with the water of one printing assistant;
In described dyeing, concentrator, thickening agent is selected from: white carbon, sodium bentonite, organobentonite, kieselguhr, recessed
The inorganic thickening agents such as convex rod stone soil, molecular sieve, Silica hydrogel, methylcellulose, ethyl cellulose, hydroxymethyl cellulose, ethoxy
The cellulose thickeners such as cellulose, hydroxypropyl cellulose, carboxymethyl cellulose, carboxyethyl cellulose, carboxy-propyl cellulose, form sediment
Powder, gelatin, sodium alginate, casein, guar gum, chitosan, Radix Acaciae senegalis, xanthan gum, soybean glue, natural rubber,
The natural polymer such as lanoline, agar and derivant thereof, polyacrylamide, polyvinyl alcohol, polyvinylpyrrolidone, polyoxy second
Alkene, modified paraffin resin, carbomer, polyacrylic acid, Polyacrylate Emulsion, butadiene rubber, butadiene-styrene rubber, poly-ammonia
The organic gold of solvay-type such as ester, modified polyurea, low-molecular polyethylene wax etc. synthesize macromolecule thickener, amino alcohol solvay-type titanate esters
Belong to one or more in compound thickener etc. can be used for dyeing, the thickening agent of concentrator, described dyeing, concentrator
Range of viscosities is selected from 500-30000 centipoise.
In described dyeing, concentrator, pH adjusting agent is selected from: citric acid, adipic acid, potassium citrate, lactic acid, fumaric acid, phosphorus
The acidity regulators such as acid hydrogen trisodium, tartaric acid, sodium dihydrogen citrate, malic acid, phosphoric acid, acetic acid, hydrochloric acid, 2-amino-2-methyl-1-
Propanol, N-methylethanolamine, monoethanolamine, diethanolamine, triethanolamine, butylethanolamine, N-aminopropyl-methylethanolamine,
APED, butyl diethanolamine etc. have alkanolamine, ammonia, sodium hydroxide, potassium hydroxide, carbonic acid
One or more in the inorganic base regulators such as sodium, potassium carbonate, sodium bicarbonate, potassium bicarbonate etc. can be used for dyeing, concentrator
PH adjusting agent, described dyeing, concentrator pH scope selected from 4-10.
In described dyeing, concentrator, auxiliary agent with slurry is selected from: sodium alginate, polyacrylamide, N-methyl-N oleoyl ammonia
Base ethyl sulfonic acid sodium, LOMAR PWA EINECS 246-676-2-formaldehyde condensation products, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol ethylene oxide condensate, three different
Propylphenol ethylene oxide condensate, sodium lignin sulfonate, Oleum Ricini oleic alcohol, dodecylbenzene sodium sulfonate, metacresol-
Formaldehyde-sodium sulfite condensation substance extension agent S S, diffusion agent N, dispersing agent MF, dispersing agent CNF, condensation compound of methyl naphthalene sulfonic acid and formaldehyde,
Cresol (or phenol) sodium sulfonate formaldehyde condensation products, beta naphthal sulfonic formaldehyde condensation compound, phenolic resin sulfonated bodies, dispersing agent C S;Fat
Fat hydrochlorate type, sulfonate type, sulfate type, phosphate ester salt form, 2-Sulfosuccinic acid ester type, fatty acid/peptide condensation substance type anion
Surfactant;Ammonium salt type, quaternary, oxidation ammonium type cationic surfactant;Betaine type, imidazoline type, aminoacid
Type, phosphatide type zwitterionic surfactant;Fatty alcohol ether type, alkyl phenol ether type, alkylamine ether type, polyether-type, fatty acid polyglycol
Alkoxide ester type, castor oil polyoxyethylene type, lanoline polyoxyethylene-type, sorbitol polyoxyethylene type, glycerol ester type, Pyrusussuriensis
Alcohol ester type, fatty acid alkanamine type, alkylolamides type, alkyl polyglucoside type, alkyl pyrrolidone type nonionic surfactant;Alcohol
Other surface activitys such as class, acids, amine, amide-type, esters, ethers, ketone, polymerization species, Semen Ricini oils, Pilus Caprae seu Ovis lipid
Agent;Polyvinyl alcohol, polyvinyl acetate, styrene and maleic anhydride multipolymer, gelatin, carboxymethyl cellulose, carboxyethyl fibre
Dimension element, hydroxymethyl cellulose, hydroxyethyl cellulose, ethylene glycol, propylene glycol, carbamide, diethylene glycol, thiourea, organic silicon defoamer, ore deposit
Thing oil defoamer, polyethers defoamer, three polyglyceryl laurate, four polyglyceryl laurate, six polyglyceryl laurate, three
One or more in polyglycereol monostearate, three polyglycerol acrylate etc. can be used for dye be coated with one dyeing, printing paste its
His auxiliary agent.
By being coated with according to the dye of above-mentioned acquisition, one dyes, concentrator compositions is applied in dyeing, printing technology;Technique
Middle color development process one in decatize or baking;Color development temperature is 160-210 DEG C;The color development time is 1-30 minute;Color development
After textile can wash, soap, wash again, it is possible to directly wash post-drying, or without washing, process of soaping;Specifically
Technique is selected from: textile → stamp → drying → decatize → wash → soap → wash → dry → arrange → stamp finished product;Spin
Fabric → stamp → drying → decatize → washing → drying → arrangement → stamp finished product;Textile → stamp → drying → decatize →
Drying → arrangement → stamp finished product;Textile → stamp → dry → bakee → wash → soap → wash → dry → arrange →
Stamp finished product;Textile → stamp → drying → baking → washing → drying → arrangement → stamp finished product;Textile → stamp →
One in dyeing, the printing technologies such as drying → baking → arrangement → stamp finished product.
Concrete: hydrophobic textile material dyeing, printing technology method, technical process is successively through print by pending textile
Flower → drying → color development → post processing, and then obtain stamp finished product;Wherein, color development can the most scrubbed and baking with arrangement interprocedual
Dry;Described color development temperature is 160-210 DEG C;The color development time is 1-30 minute;Described last handling process can use and wash → soap
→ wash → dry → arrange, wash → dry → arrange or individually arrange.Described color development uses decatize or the mode of baking;Institute
State washing and can use washing repeatedly and/or mode of soaping.
A kind of hydrophobic textile material dyeing, printing technology method, described technique is that pending textile is successively through stamp
→ drying → decatize → wash → soap → wash → dry → arrange, and then obtain stamp finished product.
Wherein steam temperature is 160-210 DEG C, and steaming time is 1-30 minute;
A kind of hydrophobic textile material dyeing, printing technology method, described technique is that pending textile is successively through stamp
→ drying → decatize → washing → drying → arrangement, and then obtain stamp finished product.
Wherein steam temperature is 160-210 DEG C, and steaming time is 1-30 minute;
A kind of hydrophobic textile material dyeing, printing technology method, described technique is that pending textile is successively through stamp
→ drying → decatize → arrangement, and then obtain stamp finished product.Wherein steam temperature is 160-210 DEG C, and steaming time is that 1-30 divides
Clock;
A kind of hydrophobic textile material dyeing, printing technology method, described technique is that pending textile is successively through stamp
→ dry → bakee → wash → soap → wash → dry → arrange, and then obtain stamp finished product.Wherein stoving temperature is
160-210 DEG C, the baking time is 1-30 minute;
A kind of hydrophobic textile material dyeing, printing technology method, described technique is that pending textile is successively through stamp
→ dry → bakee → washing → dry → arrange, and then obtain stamp finished product.Wherein stoving temperature is 160-210 DEG C, bakees
Time is 1-30 minute;
A kind of hydrophobic textile material dyeing, printing technology method, described technique is that pending textile is successively through stamp
→ dry → bakee → arrange, and then obtain stamp finished product.Wherein stoving temperature is 160-210 DEG C, and the baking time is that 1-30 divides
Clock.
Advantage for present invention:
Present invention dyeing, stamp disperse dyes paste composition are coated with one dyeing or stamp for disperse dyes dye;Logical
Cross and one or more disperse dyes of the apoplexy due to endogenous wind such as azo, anthraquinone or heterocycle are made into dispersion pulp, by carefully together with auxiliary agent and water
Change processes, and can prepare dye and be coated with one dyeing, stamp disperse dyes paste composition.Said composition and dye are coated with one print
Flower auxiliary agent, thickening agent and water can be prepared and obtain dye painting one printing paste.This printing paste is used to enter for hydrophobic textile material
During row stamp, before stamp, process is similar to conventional dyes stamp, can pass through cylinder, flat screen printing machine by paste composition printing in
Textile material surface.During high temperature color development, most disperse dyes are combined with hydrophobic fiber material by molecular separating force, print
Flower slurry in printing assistant while disperse dyes high temperature color development, crosslinking curing film forming, make the loose colour not being combined with fiber
Adhere to fiber surface.Disperse dye composition of the present invention can take into account dyes for dyeing and the stamp of hydrophobic textile materials
Color, stamp and pigment dyeing, the advantage of stamp, ensureing height distillation, washing and do, while fastness to wet rubbing, have again fresh
Gorgeous color, soft feel, the most also can avoid the generation of high concentration color water during tradition disperse dyeing, stamp,
It is the disperse dyeing of a kind of clean environment firendly, Printing.
If carrying out dyeing by above-mentioned dyeing, stamp disperse dyes paste composition, printing technology selects washing, soaps
Etc. process, wash the wash water COD of textile between 30-2000ppm, part kind < 200ppm, part kind < 50ppm;
Colourity (extension rate) < 200, part kind colourity (extension rate) < 80, part kind colourity (extension rate) < 30.
Specific implementation method
Below example can make those of ordinary skill in the art that the present invention is more fully understood, but not with any side
Formula limits the present invention.The raw materials used specification of following example is as follows: dyestuff used is the former powder of commercial dispersants dyestuff, sulfomethylated lignin
Acid sodium, dodecylbenzene sodium sulfonate, lauryl alcohol polyethylene glycol oxide carboxylic acid sodium, dodecyl polyoxyethylene sodium sulfate, dispersing agent NNO,
Dispersing agent MF, dispersing agent CNF, surfactant B C-50, surfactant LS-60, surfactant LS-70, organic-silicon-modified
Acrylic ester adhesive SY-8001, ethylene glycol are commercially available industrial goods, and water used is deionized water.Device therefor includes:Test-type dispersion machine, Netzsch (Shanghai) Machinery Equipment Co., LTD., LHP-0.4 type pottery laboratory Horizontal sand entirely
Grinding machine, Shanghai De Yu mechanical & electronic equipment corporation, Ltd, APV2000 test-type high pressure homogenizer, Shanghai are along the limited public affairs of instrument experimental facilities
Department, H-TS-III high temperature evaporates baking oven, Ya Nuo precision optical machinery Manufacturing Co., Ltd of Foshan City, and DH6-9070 electric heating constant temperature air blast is done
Dry case, Yuhua Instrument Co., Ltd., Gongyi City.Every application performance detection method is with reference to following national standard:
The generic condition regulation that GB/T 2374-2007 dyeing measures
GB/T 4841.1-2006 dyeing standard depth colour atla 1/1
GB/T 2394-2013 disperse dyes coloured light and the mensuration of intensity
The mensuration of GB/T 2397-2012 disperse dyes lifting force
GB/T 3921-2008 textile color stability test fastness to soaping
GB/T 3920-2008 textile color stability test colour fastness to rubbing
GB/T 6152-1997 textile color stability test color fastness to hot pressing
The GB/T 8427-2008 textile color stability test color fastness of resistance to artificial light: xenon arc
Embodiment 1
(1) dye is coated with one dyeing, the preparation of thickening agent compositions 1
Surfactant LS-70 45g, sodium lignin sulfonate 50g, ethylene glycol 30g and water 525g are joined dispersion tank
In, dispersion is after stirring makes it the most molten, is added thereto to following structure dyestuff 350g:
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding, during grinding by high speed dispersion
Between 10 hours, slurry grinding obtained after grinding homogenizes 2 times through high pressure homogenizer, obtain dyes be coated with one dye
Color, thickening agent compositions 1,1000g, fineness d50≤0.5 μm, pH=6.8.
(2) dye is coated with one dyeing, the preparation of printing assistant
By deionized water 227g, join in dispersion tank, open dispersion machine, under stirring at low speed, add in dispersion tank successively
Enter surfactant FC-1 15g, penetrating agent SA-50 30g, diffusant WAX 28g, silicone softening agent 208C 55g, crosslinking
Agent CLA-80 45g, organosilicon modified acrylic ester binding agent SY-800 600g, add each raw material, dispersion stirring 30 minutes.?
Being coated with one dyeing, printing assistant Z-1 1000g, pH=6.7 to dye, (NDJ-1 type rotor viscometer, 2# turns viscosity 1300mPa.S
Son, 12r/min).
(3) dye is coated with one dyeing, the preparation of printing paste 1
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into 10g dye painting one dyeing, thickening agent compositions 1 and dye that step (1) prepares
Being coated with one dyeing, printing assistant Z1 10g, dispersion obtains dye and is coated with one dyeing, printing paste 1,1000g, viscosity after stirring
2520mPa.S (NDJ-1 rotating cylinder viscometer, 3# rotor, 30r/min)
The requirement measured according to GB/T 2374-2007 dyeing, use the above-mentioned dye prepared painting one to dye,
Printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp → drying → baking → arrangement → stamp finished product, wherein:
Drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 minutes.Every detection data of stamp finished product are as follows:
Embodiment 2-22
Prepare dye according to the preparation process of above-described embodiment 1 (step 1) and be coated with one dyeing, thickening agent compositions (2-
22), it is only by the dyestuff in above-described embodiment 1, uses the dyestuff of the different structure described in following table to be replaced.And laggard one
Step obtains to contaminate and is coated with one dyeing, printing paste 2 22, utilizes acquisition dyeing, printing paste to carry out PLATE SCREAM PRINTING, then to stamp finished product
Properties carries out detecting dye structure used and performance data such as following table:
Embodiment 23
Dye is coated with one dyeing, the preparation of printing paste 23
Deionized water 960g is added to dispersion machine dispersion tank, starts and be slowly added to thickening under dispersion machine, high-speed stirred
Agent PF20g, is stirring evenly and then adding into dye and is coated with one dyeing, thickening agent compositions 1 (embodiment 1 prepares), 20g, dispersion
Obtaining dye after stirring and be coated with one dyeing, printing paste 23,1000g, (NDJ-1 rotating cylinder viscometer, 3# turns viscosity 2320mPa.S
Son, 30r/min)
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Embodiment 24
Dye is coated with one dyeing, the preparation of printing paste 24
Deionized water 960g is added to dispersion machine dispersion tank, starts and be slowly added to thickening under dispersion machine, high-speed stirred
Agent PF20g, is stirring evenly and then adding into dye and is coated with one dyeing, stamp compositions 3 (embodiment 3 prepares), 20g, dispersion stirring
Obtain after Jun Yun dye be coated with one dyeing, printing paste 24,1000g, viscosity 2300mPa.S (NDJ-1 rotating cylinder viscometer, 3# rotor,
30r/min)
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Embodiment 25
Dye is coated with one dyeing, the preparation of printing paste 25
Deionized water 960g is added to dispersion machine dispersion tank, starts and be slowly added to thickening under dispersion machine, high-speed stirred
Agent PF20g, is stirring evenly and then adding into dye and is coated with one dyeing, stamp compositions 17 (embodiment 17 prepares), and 20g, dispersion is stirred
Mix and obtain dye after uniformly and be coated with one dyeing, printing paste 25,1000g, viscosity 2250mPa.S (NDJ-1 rotating cylinder viscometer, 3# rotor,
30r/min)
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Embodiment 26
(1) dye is coated with one dyeing, the preparation of thickening agent compositions 26
Surfactant LS-70 45g, sodium lignin sulfonate 50g, ethylene glycol 30g and water 525g are joined dispersion tank
In, dispersion is after stirring makes it the most molten, is separately added into following structure dyestuff wherein:
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding, during grinding by high speed dispersion
Between 10 hours, slurry grinding obtained after grinding homogenizes 2 times through high pressure homogenizer, obtain dyes be coated with one dye
Color, thickening agent compositions 26,1000g, fineness d50≤0.5 μm, pH=6.8.
(2) dye is coated with one dyeing, the preparation (with embodiment 1) of printing assistant Z-1
(3) dye is coated with one dyeing, the preparation of printing paste 26
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into 10g dye painting one dyeing, thickening agent compositions 26 and that step (1) prepares
Dye be coated with one dyeing, printing assistant Z1 (preparation method is with embodiment 1) 10g, dispersion stir after obtain dye be coated with one dyeing,
Printing paste 26,1000g, viscosity 1450mPa.S (NDJ-1 type rotating cylinder viscometer, 2# rotor, 12r/min).
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Embodiment 27
Dye is coated with one dyeing, the preparation of printing paste 27
By in deionized water 955g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dye and is coated with one dyeing, thickening agent compositions 26 (preparation method is with embodiment 26),
25g, dispersion obtains dye and is coated with one dyeing, thickening agent compositions 27,1000g, viscosity 2250mPa.S (NDJ-1 after stirring
Rotating cylinder viscometer, 3# rotor, 30r/min)
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Embodiment 28
(1) dye is coated with one dyeing, the preparation of stamp compositions 28
Surfactant B C-50 50g, alkalescence sodium lignin sulfonate 50g, ethylene glycol 30g and water 525g are joined dispersion
In tank, dispersion is after stirring makes it the most molten, is added thereto to following structure dyestuff 345g:
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding, during grinding by high speed dispersion
Between 10 hours, slurry grinding obtained after grinding homogenizes 2 times through high pressure homogenizer, obtain dyes be coated with one dye
Color, stamp compositions 28,1000g, fineness d50≤0.7 μm, pH=7.2.
(2) dye is coated with one dyeing, the preparation of printing assistant Z-1, with embodiment 1
(3) dye is coated with one dyeing, the preparation of printing paste 28
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dye and is coated with one dyeing, thickening agent compositions 28,10g, and dye is coated with one dyeing, stamp
Auxiliary agent Z-1,10g, dispersion obtains dye and is coated with one dyeing, thickening agent compositions 28,1000g, viscosity after stirring
1500mPa.S (NDJ-1 rotating cylinder viscometer, 3# rotor, 30r/min).
Use the dye prepared to be coated with one dyeing, printing paste 28 carries out PLATE SCREAM PRINTING, and printing technology is: textile → print
Flower → drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, stoving temperature is 180 DEG C, 3
Minute.Every detection data of stamp finished product are as follows:
Embodiment 24-34
Prepare dyeing, printing paste according to the preparation process of above-described embodiment 28, be only by the dyestuff in above-described embodiment 28,
The dyestuff of employing different structure described in following table.Then utilize or dyeing, printing paste carries out PLATE SCREAM PRINTING, then becomes stamp
The properties of product carries out detecting dye structure used and performance data such as following table:
Embodiment 39
Dye is coated with one dyeing, the preparation of printing paste 39
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dye and is coated with one dyeing, stamp compositions 29 (embodiment 29 prepares), 20g, dispersion
Obtaining dye after stirring and be coated with one dyeing, printing paste 39,1000g, (NDJ-1 rotating cylinder viscometer, 3# turns viscosity 2500mPa.S
Son, 30r/min)
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Embodiment 40
(1) dye is coated with one dyeing, the preparation of stamp compositions 40
Surfactant LS-60 45g, dispersing agent MF 50g, ethylene glycol 30g and water 525g are joined in dispersion tank, point
After scattered stirring makes it the most molten, it is added thereto to following structure dyestuff 350g:
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding, during grinding by high speed dispersion
Between 10 hours, slurry grinding obtained after grinding homogenizes 2 times through high pressure homogenizer, obtain dyes be coated with one dye
Color, stamp compositions 40,1000g, fineness d50≤0.5 μm, pH=6.8.
(2) dye is coated with one dyeing, the preparation of printing assistant
By deionized water 227g, join in dispersion tank, open dispersion machine, under stirring at low speed, add in dispersion tank successively
Enter surfactant EL-40 15g, penetrating agent SA-60 30g, diffusant RPG 28g, silicone softening agent RM-1 55g, crosslinking
Agent TAC 45g, organosilicon modified acrylic ester binding agent SY-800 600g, add each raw material, dispersion stirring 30 minutes.Obtain
Dye is coated with one dyeing, printing assistant Z-2, and 1000g, pH=6.7, (NDJ-1 type rotor viscometer, 2# turns viscosity 1350mPa.S
Son, 12r/min).
(3) dye is coated with one dyeing, the preparation of printing paste 40
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dye painting one dyeing, stamp compositions 10g that step (1) prepares, step (2)
The dye prepared is coated with one dyeing, printing assistant Z-2,10g, and dispersion obtains dye and is coated with one dyeing, printing paste after stirring
40,1000g, viscosity 2500mPa.S (NDJ-1 type rotating cylinder viscometer, 3# rotor, 30r/min).
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Embodiment 41-43
Prepare dyeing, printing paste according to the preparation process of above-described embodiment 40, be only by the dyestuff in above-described embodiment 40,
The dyestuff of employing different structure described in following table.Then utilize or dyeing, printing paste carries out PLATE SCREAM PRINTING, then becomes stamp
The properties of product detects, dye structure used and performance data such as following table:
Embodiment 44
Dye is coated with one dyeing, the preparation of printing paste 44
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dye and is coated with one dyeing, stamp compositions 40 (embodiment 40 prepares), 20g, dispersion
Obtaining dye after stirring and be coated with one dyeing, printing paste 44,1000g, (NDJ-1 rotating cylinder viscometer, 3# turns viscosity 2350mPa.S
Son, 30r/min)
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Embodiment 45
(1) dye is coated with one dyeing, the preparation of stamp compositions 45
Surfactant LS-60 45g, dispersing agent MF 50g, ethylene glycol 30g and water 525g are joined in dispersion tank, point
After scattered stirring makes it the most molten, it is separately added into following structure dyestuff:
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding, during grinding by high speed dispersion
Between 10 hours, slurry grinding obtained after grinding homogenizes 2 times through high pressure homogenizer, obtain dyes be coated with one dye
Color, thickening agent compositions 45,1000g, fineness d50≤0.6 μm, pH=6.7.
(2) dye is coated with one dyeing, the preparation of printing paste 45
By in deionized water 970g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into 10g dye painting one dyeing, thickening agent compositions 45 that step (1) prepares, point
Dissipate and after stirring, obtain dye painting one dyeing, printing paste 45,1000g, viscosity 2320mPa.S (NDJ-1 rotating cylinder viscometer, 3#
Rotor, 30r/min).
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Embodiment 46
(1) dye is coated with one dyeing, the preparation of stamp compositions 46
Surfactant LS-60 45g, dispersing agent CNF 50g, ethylene glycol 30g and water 530g are joined in dispersion tank,
Dispersion is after stirring makes it the most molten, is added thereto to the dyestuff 345g of following structure:
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding, during grinding by high speed dispersion
Between 10 hours, slurry grinding obtained after grinding homogenizes 2 times through high pressure homogenizer, obtain dyes be coated with one dye
Color, stamp compositions 46,1000g, fineness d50≤0.7 μm, pH=7.2.
(2) dye is coated with one dyeing, the preparation of printing assistant Z-2, with embodiment 40
(3) dye is coated with one dyeing, the preparation of printing paste 46
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dye painting one dyeing, stamp compositions 10g that step (1) prepares, and dye is coated with integrally
Dyeing, printing assistant Z-2,10g, dispersion obtains dye and is coated with one dyeing, printing paste 46,1000g, viscosity after stirring
2520mPa.S (NDJ-1 type rotating cylinder viscometer, 3# rotor, 30r/min).
Use the dye prepared to be coated with one dyeing, printing paste 46 carries out PLATE SCREAM PRINTING, and printing technology is: textile → print
Flower → drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, stoving temperature is 180 DEG C, 3
Minute.Every detection data of stamp finished product are as follows:
Embodiment 47-50
Prepare dyeing, printing paste according to the preparation process of above-described embodiment 46, be only by the dyestuff in above-described embodiment 46,
The dyestuff of employing different structure described in following table.Then utilize or dyeing, printing paste carries out PLATE SCREAM PRINTING, then becomes stamp
The properties of product detects, dye structure used and performance data such as following table:
Embodiment 51
(1) dye is coated with one dyeing, the preparation of stamp compositions 51
Surfactant LS-60 45g, diffusion agent N 50g, ethylene glycol 30g and water 530g are joined in dispersion tank, point
After scattered stirring makes it the most molten, it is added thereto to following structure dyestuff 345g:
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding, during grinding by high speed dispersion
Between 10 hours, slurry grinding obtained after grinding homogenizes 2 times through high pressure homogenizer, obtain dyes be coated with one dye
Color, stamp compositions 51,1000g, fineness d50≤0.7 μm, pH=7.2.
(2) dye is coated with one dyeing, the preparation of printing assistant Z-2, with embodiment 40
(3) dye is coated with one dyeing, the preparation of printing paste 51
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dye painting one dyeing, stamp compositions 10g that step (1) prepares, and dye is coated with integrally
Dyeing, printing assistant Z-2,10g, dispersion obtains dye and is coated with one dyeing, printing paste 51,1000g, viscosity after stirring
2520mPa.S (NDJ-1 type rotating cylinder viscometer, 3# rotor, 30r/min).
Use the dye prepared to be coated with one dyeing, printing paste 51 carries out PLATE SCREAM PRINTING, and printing technology is: textile → print
Flower → drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, stoving temperature is 180 DEG C, 3
Minute.Every detection data of stamp finished product are as follows:
Embodiment 52-55
Prepare dyeing, printing paste according to the preparation process of above-described embodiment 51, be only by the dyestuff in above-described embodiment 51,
The dyestuff of employing different structure described in following table.Then utilize or dyeing, printing paste carries out PLATE SCREAM PRINTING, then becomes stamp
The properties of product detects, dye structure used and performance data such as following table:
Embodiment 56
Dye is coated with one dyeing, the preparation of printing paste 51
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dye and is coated with one dyeing, stamp compositions 52 (embodiment 52 prepares), 20g, dispersion
Obtaining dye after stirring and be coated with one dyeing, printing paste 56,1000g, (NDJ-1 rotating cylinder viscometer, 3# turns viscosity 2400mPa.S
Son, 30r/min)
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Embodiment 57
(1) dye is coated with one dyeing, the preparation of stamp compositions 57
Surfactant B C-50 45g, sodium lignin sulfonate 50g, ethylene glycol 30g and water 525g are joined dispersion tank
In, dispersion is after stirring makes it the most molten, is added thereto to following structure dyestuff 350g:
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding, during grinding by high speed dispersion
Between 10 hours, slurry grinding obtained after grinding homogenizes 2 times through high pressure homogenizer, obtain dyes be coated with one dye
Color, stamp compositions 57,1000g, fineness d50≤0.5 μm, pH=6.8.
(2) dye is coated with one dyeing, the preparation of printing assistant
By deionized water 227g, join in dispersion tank, open dispersion machine, under stirring at low speed, add in dispersion tank successively
Enter surfactant FM 15g, penetrating agent FN-2 30g, diffusant PBE 28g, high-molecular polythene wax PEC-1 55g, crosslinking
Agent CTA 45g, organosilicon modified acrylic ester binding agent SY-800 600g, add each raw material, dispersion stirring 30 minutes.Obtain
Dye is coated with one dyeing, printing assistant Z-3 1000g, pH=6.7, and (NDJ-1 type rotating cylinder viscometer, 2# turns viscosity 1350mPa.S
Son, 12r/min).
(3) dye is coated with one dyeing, the preparation of printing paste 57
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dye painting one dyeing, stamp compositions 10g that step (1) prepares, step (2)
The dye prepared is coated with one dyeing, printing assistant Z-3,10g, and dispersion obtains dye and is coated with one dyeing, printing paste after stirring
57,1000g, viscosity 2480mPa.S (NDJ-1 type rotating cylinder viscometer, 3# rotor, 30r/min).
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Embodiment 58-59
Prepare dyeing, printing paste according to the preparation process of above-described embodiment 57, be only by the dyestuff in above-described embodiment 57,
The dyestuff of employing different structure described in following table.Then utilize or dyeing, printing paste carries out PLATE SCREAM PRINTING, then becomes stamp
The properties of product detects, dye structure used and performance data such as following table:
Embodiment 60
(1) dye is coated with one dyeing, the preparation of stamp compositions 60
Surfactant LS-60 45g, alkalescence sodium lignin sulfonate 50g, ethylene glycol 30g and water 530g are joined dispersion
In tank, after dispersion stirring makes it the most molten, it is added thereto to following structure dyestuff 345g,
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding, during grinding by high speed dispersion
Between 10 hours, slurry grinding obtained after grinding homogenizes 2 times through high pressure homogenizer, obtain dyes be coated with one dye
Color, stamp compositions 60,1000g, fineness d50≤0.7 μm, pH=7.2.
(2) dye is coated with one dyeing, the preparation of printing assistant Z-3, with embodiment 57
(3) dye is coated with one dyeing, the preparation of printing paste 57
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dye painting one dyeing, stamp compositions 10g that step (1) prepares, and dye is coated with integrally
Dyeing, printing assistant Z-3,10g, dispersion obtains dye and is coated with one dyeing, printing paste 60,1000g, viscosity after stirring
2480mPa.S (NDJ-1 type rotating cylinder viscometer, 3# rotor, 30r/min).
Use the dye prepared to be coated with one dyeing, printing paste 60 carries out PLATE SCREAM PRINTING, and printing technology is: textile → print
Flower → drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, stoving temperature is 180 DEG C, 3
Minute.Every detection data of stamp finished product are as follows:
Embodiment 61
Prepare dyeing, printing paste according to the preparation process of above-described embodiment 60, be only by the dyestuff in above-described embodiment 60,
The dyestuff of employing different structure described in following table.Then utilize or dyeing, printing paste carries out PLATE SCREAM PRINTING, then becomes stamp
The properties of product detects, dye structure used and performance data such as following table:
Embodiment 62
Dye is coated with one dyeing, the preparation of printing paste 62
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dye and is coated with one dyeing, stamp compositions 60 (embodiment 60 prepares), 20g, dispersion
Obtaining dye after stirring and be coated with one dyeing, printing paste 62,1000g, (NDJ-1 rotating cylinder viscometer, 3# turns viscosity 2250mPa.S
Son, 30r/min)
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Embodiment 63
(1) dye is coated with one dyeing, the preparation of stamp compositions 63
Surfactant LS-60 45g, alkalescence sodium lignin sulfonate 50g, ethylene glycol 30g and water 530g are joined dispersion
In tank, dispersion is after stirring makes it the most molten, is added thereto to following structure dyestuff 345g:
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding, during grinding by high speed dispersion
Between 10 hours, slurry grinding obtained after grinding homogenizes 2 times through high pressure homogenizer, obtain dyes be coated with one dye
Color, stamp compositions 63,1000g, fineness d50≤0.7 μm, pH=7.2.
(2) dye is coated with one dyeing, the preparation of printing assistant Z-3, with embodiment 57
(3) dye is coated with one dyeing, the preparation of printing paste 63
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dye painting one dyeing, stamp compositions 10g that step (1) prepares, and dye is coated with integrally
Dyeing, printing assistant Z-3,10g, dispersion obtains dye and is coated with one dyeing, printing paste 63,1000g, viscosity after stirring
2520mPa.S (NDJ-1 type rotating cylinder viscometer, 3# rotor, 30r/min).
Use the dye prepared to be coated with one dyeing, printing paste 63 carries out PLATE SCREAM PRINTING, and printing technology is: textile → print
Flower → drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, stoving temperature is 180 DEG C, 3
Minute.Every detection data of stamp finished product are as follows:
Embodiment 64-65
Prepare dyeing, printing paste according to the preparation process of above-described embodiment 63, be only by the dyestuff in above-described embodiment 63,
The dyestuff of employing different structure described in following table.Then utilize or dyeing, printing paste carries out PLATE SCREAM PRINTING, then becomes stamp
The properties of product detects, dye structure used and performance data such as following table:
Embodiment 66
By surfactant LS-70 25g, surfactant LS-60 20g, sodium lignin sulfonate 50g, ethylene glycol 30g and
Water 500g joins in dispersion tank, and dispersion is after stirring makes it the most molten, is separately added into following structure dyestuff wherein:
Starting dispersion machine, dispersion pulp, after 2 hours, is squeezed into horizontal sand mill and is circulated grinding, during grinding by high speed dispersion
Between 10 hours, slurry grinding obtained after grinding homogenizes 2 times through high pressure homogenizer, obtain dyes be coated with one dye
Color, thickening agent compositions 66,1000g, fineness d50≤0.5 μm, pH=6.8.
(2) dye is coated with one dyeing, the preparation of printing assistant Z-1, with embodiment 1
(3) dye is coated with one dyeing, the preparation of printing paste 66
By deionized water 960g, add in dispersion machine dispersion tank, start and be slowly added to thickening agent under dispersion machine, high-speed stirred
PF20g, is stirring evenly and then adding into 10g dye painting one dyeing, thickening agent compositions 66 and dye painting one that step (1) prepares
Body dyeing, printing assistant Z1 (preparation method is with embodiment 1) 10g, dispersion obtains dye and is coated with one dyeing, printing paste after stirring
66,1000g, viscosity 1450mPa.S (NDJ-1 type rotating cylinder viscometer, 2# rotor, 12r/min).
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Embodiment 67
Dye is coated with one dyeing, the preparation of printing paste 67
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dye and is coated with one dyeing, stamp compositions 66 (preparation method is with embodiment 66) 20g, point
Dissipate and after stirring, obtain dye painting one dyeing, printing paste 67,1000g, viscosity 2250mPa.S (NDJ-1 type rotating cylinder viscometer,
3# rotor, 30r/min).
Use the dye prepared to be coated with one dyeing, printing paste carries out PLATE SCREAM PRINTING, and printing technology is: textile → stamp
→ drying → baking → arrangement → stamp finished product, wherein: drying temperature is 100 DEG C, 10 minutes, and stoving temperature is 180 DEG C, 3 points
Clock.Every detection data of stamp finished product are as follows:
Claims (6)
1. one kind dye be coated with one dyeing, printing dyes paste composition, it is characterised in that: compositions be formula (I), (II),
(III), one or more in the dyestuff shown in (IV), (V), (VI), (VII), (VIII), (IX) mix with auxiliary agent and water
Mixed slurry, then prepare dye painting one dyeing, stamp disperse dye composition by micronization processes;
Wherein, each composition by weight percentage, dyestuff 20-60%, auxiliary agent 5-30% and water 10-75%;
Described formula (I) is:
R1、R2、R3It is respectively and independently selected from H, Cl, Br, I, CN, NO2、NHCO-X1、O-X1、NHSO2-X1Or OSO2-X1;X1For C1-C6
Alkyl, phenyl, benzyl or phenethyl;
R4、R5It is respectively and independently selected from H, quilt-CN, OCO-X2、-COO-X2、-COOCHCO-X2、-COOCHCO-X2Replace or not by
Substituted C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl, X2For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or
Phenethyl;
R6Selected from C1—C6Alkyl;
R7Selected from C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl, phenethyl, CO-X3Or SO2-X3, X3For C1-C6Alkyl, C2-C6Alkene
Base, phenyl, benzyl or phenethyl;
Described formula (II) is:
A is selected from
In one;
R8、R9、R10、R11It is respectively and independently selected from H, Cl, Br, I, CN, NO2、NHCO-X4、O-X4、NHSO2-X4Or OSO2-X4, X4For
C1-C6Alkyl, phenyl, benzyl or phenethyl;
R12Selected from H, CN, the C that replaced by amide groups or amido derivatives1-C6Alkyl, C3-10Cycloalkyl, C7-C10Aralkyl, virtue
Base, carboxylic acid ester groups, sulfone derivative, sulfoamido derivant, acyl alkyl or halogen;
R13、R14It is respectively and independently selected from OH, Cl, Br, I, quilt-CN, OCO-X6、-COO-X6、-COOCHCO-X6Or-COOCHCO-
X6Replace or unsubstituted NH2、N-C1-C6Alkyl, N-C2-C6Thiazolinyl, N-phenyl, N-benzyl or N-phenethyl, X6For C1-C6
Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R15Selected from H, quilt-OSO2Ph or-COOC2H4Substituted or unsubstituted C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Thiazolinyl, benzene
Base, benzyl or phenethyl;
R16Selected from C1-6Alkyl, C1-C6Alkoxyl, C1-C6Alkylamino, carboxyl, carboxylic propyl ester base, carbamyl, substituted amino, hydroxyl
Base, phenyl, cyano group, heterocyclic radical, CONH (CH2)3OMe or CH2In COOH;
R17Selected from OH or NH;
R18Selected from H, C1-C6Alkyl, C2-C6Alkenyl, phenyl, benzyl or phenethyl;
R19Selected from C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Alkenyl, phenyl, benzyl or phenethyl;
Described formula (III) is:
B is selected from being:
In one;
R20、R21It is respectively and independently selected from H, quilt-CN, OCO-X8、-COO-X8、-COOCHCO-X8Or-COOCHCO-X8Replace or not
The C being replaced1-C6Alkyl, C2-C6-thiazolinyl, phenyl, benzyl or phenethyl, X8For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl
Or phenethyl;
R22Selected from C1-C6Alkyl;
R23Selected from CO-X9Or SO2-X9, X9For C1-C6Alkyl, C2-C6Alkenyl, phenyl, benzyl or phenethyl;
R24、R25It is respectively and independently selected from H, Cl, Br, I, CN, NO2、COOX7、NHCO-X7、O-X7、NHSO2-X7Or OSO2-X7, X7For
C1-C6Alkyl, phenyl, benzyl, phenethyl;
Described formula (IV) is:
B-N=N-A
A is selected from being:
In one;
R12Selected from H, CN, the C that replaced by amide groups or amido derivatives1-C6Alkyl, C3-C10Cycloalkyl, C7-C10Aralkyl,
Aryl, carboxylic acid ester groups, sulfone derivative, sulfoamido derivant, acyl alkyl or halogen;
R13、R14It is respectively and independently selected from OH, Cl, Br, I, quilt-CN, OCO-X6、-COO-X6、-COOCHCO-X6Or-COOCHCO-
X6Replace or unsubstituted NH2、N-C1-C6Alkyl, N-C2-C6Thiazolinyl, N-phenyl, N-benzyl or N-phenethyl, X6For C1-C6
Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R15Selected from H, quilt-OSO2Ph or-COOC2H4Substituted or unsubstituted C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Thiazolinyl, benzene
Base, benzyl or phenethyl;
R16Selected from C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Alkylamino, carboxyl, carboxylic propyl ester base, carbamyl, substituted amino,
Hydroxyl, phenyl, cyano group, heterocyclic radical, CONH (CH2)3OMe or CH2COOH;
R17Selected from OH or NH;
R18Selected from H, C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R19Selected from C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
B is selected from being
In one;
R24、R25It is respectively and independently selected from H, Cl, Br, I, CN, NO2、COOX7、NHCO-X7、O-X7、NHSO2-X7Or OSO2-X7, X7For
C1-C6Alkyl, phenyl, benzyl or phenethyl;
Described formula (V) is selected from:
R26、R27、R28、R29It is respectively and independently selected from H, NH2、OH、SH、NO2、NH-X8、O-X8、S-X8、NHCO-X8Or SO2NH-X8, X8
For by OH, CN, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl or C7-C10Aralkyl replace or not by
Substituted C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl, phenethyl, C3-C10Cycloalkyl, C7-C10Aralkyl
Base or C2-C6Thiazolinyl;
R30、R31It is respectively and independently selected from H, Cl, Br, I, CN, SO2NH-X9、O-X9、O-(CH2CH2O)n-X9、O-X9-O-X9、S-X9、
S-(CH2CH2O)n-X9Or S-X9-O-X9, X9For by OH, CN, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Ring
Alkyl or C7-C10Aralkyl replaces or unsubstituted C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl, benzene
Ethyl, C3-C10Cycloalkyl, C7-C10Aralkyl or C2-C6Thiazolinyl;
Described logical formula (VI) is:
R32Selected from by OH, CN, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl, C7-C10Aralkyl replaces
Or unsubstituted C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl, phenethyl, C3-C10Cycloalkyl, C7-
C10Aralkyl or C2-C6Alkenyl;
R33Selected from O or NH;
Described logical formula (VII) is:
R34Selected from H, Cl, Br, I, CN, NO2Or OH;
R35Selected from H, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl or C7-C10Aralkyl;
R36、R37Be respectively and independently selected from H, Cl, Br, I, by C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl,
C7-C10The substituted or unsubstituted amide groups of aralkyl, sulfonyl or sulfoamido;
Described logical formula (VIII) is:
Y is selected from O, S or NH;
R38、R39It is respectively and independently selected from H, by C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl, C7-C10Virtue
Alkyl is monosubstituted or one in disubstituted imido grpup;
R40、R41It is respectively and independently selected from H, Cl, Br, I, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl or
C7-C10Aralkyl;
Described logical formula (IX) is:
R42、R43It is respectively and independently selected from H, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl, phenethyl, C3-C10
Cycloalkyl, C7-C10Aralkyl, C2-C6Thiazolinyl, by C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Ester group, C1-C6Hydroxyalkyl, C3-C10
Cycloalkyl, C7-C10Aralkyl is monosubstituted or polysubstituted C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl,
Phenethyl, C3-C10Cycloalkyl, C7-C10Aralkyl or C2-C6Thiazolinyl.
2. the dye as described in claim 1 is coated with one dyeing, printing dyes paste composition, it is characterised in that: auxiliary agent is selected from
Polyvinyl alcohol, polyvinyl acetate, styrene and maleic anhydride multipolymer, gelatin, carboxymethyl cellulose, carboxyethylcellulose
Element, hydroxymethyl cellulose, hydroxyethyl cellulose, ethylene glycol, propylene glycol, carbamide, diethylene glycol, thiourea, mineral oils, higher alcohols
One or more in class, polyethers or silicone defoamer and sodium alginate, polyacrylamide, N-methyl-N oleoyl ammonia
Base ethyl sulfonic acid sodium, LOMAR PWA EINECS 246-676-2-formaldehyde condensation products, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol ethylene oxide condensate, three different
Propylphenol ethylene oxide condensate, sodium lignin sulfonate, Oleum Ricini oleic alcohol, dodecylbenzene sodium sulfonate, metacresol-
Formaldehyde-sodium sulfite condensation substance extension agent S S, diffusion agent N, dispersing agent MF, dispersing agent CNF, condensation compound of methyl naphthalene sulfonic acid and formaldehyde,
Cresol (or phenol) sodium sulfonate formaldehyde condensation products, beta naphthal sulfonic formaldehyde condensation compound, phenolic resin sulfonated bodies, dispersing agent C S;Fat
Fat hydrochlorate type anion surfactant, sulfonate type anion surfactant, sulfate type anion surfactant, phosphorus
Acid esters salt form anion surfactant, 2-Sulfosuccinic acid ester type anion surfactant, fatty acid type anionic surface are lived
Property agent, peptide condensation substance type anion surfactant;Ammonium salt type cationic surfactant, quaternary ammonium salt type cationic surface active
Live in agent, oxidation ammonium type cationic surfactant, betaine type amphoteric ionic surface active agent, imidazoline type amphion surface
Property agent, amino acid type amphoteric ionic surface active agent, phosphatide type zwitterionic surfactant, fatty alcohol ether type non-ionic surface
Activating agent, alkyl phenol ether type nonionic surfactant, alkylamine ether type nonionic surfactant, polyether-type nonionic surface
Activating agent, fatty acid polyglycol alkoxide ester type nonionic surfactant, castor oil polyoxyethylene type nonionic surfactant,
Lanoline Determination of Polyoxyethylene Non-ionic Surfactants, sorbitol polyoxyethylene type nonionic surfactant, glycerol ester type are non-
Ionic surface active agent, sorbitol ester type nonionic surfactant, fatty acid alkanamine type nonionic surfactant, alkylol
Acid amide type nonionic surfactant, alkyl polyglucoside type nonionic surfactant, alkyl pyrrolidone type non-ionic surface are lived
Property agent, alcohol surfactants, acids surfactant, amine surfactants, amide surfactants, esters surface live
Property agent, ether surfactant, ketone surfactant, polymer types of surfactants, Semen Ricini oils surfactant, Pilus Caprae seu Ovis
Lipid surfactant, three polyglyceryl laurate, four polyglyceryl laurate, six polyglyceryl laurate, three polyglycereol lists
The combination of one or more in stearate, three polyglycerol acrylate;
Described water is: one or more in tap water, deionized water, distilled water, high purity water, ultra-pure water compositions.
3. dye as described in claim 1 is coated with one dyeing, printing dyes paste composition, it is characterised in that: by formula (I),
(II), one or more in the dyestuff shown in (III), (IV), (V), (VI), (VII), (VIII), (IX) and auxiliary agent and water
Mix to obtain mixed slurry, then make mixed slurry particle diameter D90 be 0.1-2 μm by micronization processes, prepare dye be coated with one dyeing,
Stamp disperse dye composition.
4. the dye as described in claim 1 is coated with one dyeing, printing dyes paste composition, it is characterised in that:
Described formula (I) is:
R1、R2、R3It is respectively and independently selected from H, Cl, Br, I, CN, NO2;
R4、R5It is respectively and independently selected from H, quilt-CN, OCO-X2、-COO-X2Replace or unsubstituted C1-C6Alkyl, phenyl, benzyl
Base or phenethyl, X2For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R6It is respectively and independently selected from C1—C6Alkyl;
R7It is respectively and independently selected from CO-X3Or SO2-X3, X3For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
Described formula (II) is:
A is selected from
In one;
R8、R9、R10、R11It is respectively and independently selected from H, Cl, Br, I, CN, NO2、O-X4, X4For C1-C6Alkyl, phenyl, benzyl or benzene second
Base;
R12Selected from H, CN, the C that replaced by amide groups or amido derivatives1-C6Alkyl, C3-10Cycloalkyl, C7-C10Aralkyl, virtue
Perfume base;
R13、R14It is respectively and independently selected from OH, Cl, Br, I, quilt-CN, OCO-X6、-COO-X6Replace or unsubstituted NH2、N-
C1-C6Alkyl, N-phenyl, N-benzyl or N-phenethyl, X6For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R15Selected from C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R16Selected from C1-6Alkyl, C1-C6Alkoxyl, C1-C6Alkylamino, substituted amino, hydroxyl, phenyl, cyano group;
R17Selected from OH or NH;
R18Selected from H, C1-C6Alkyl, C2-C6Alkenyl, phenyl, benzyl or phenethyl;
R19Selected from C1-C6Alkyl, C1-C6Alkoxyl, C2-C6One in alkenyl, phenyl, benzyl or phenethyl;
Described formula (III) is:
B is selected from
In one;
R20、R21It is respectively and independently selected from H, quilt-CN, OCO-X8、-COO-X8、-COOCHCO-X8Or-COOCHCO-X8Replace or not
The C being replaced1-C6Alkyl, C2-C6-thiazolinyl, phenyl, benzyl or phenethyl, X8For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl
Or phenethyl;
R22Selected from C1-C6Alkyl;
R23Selected from CO-X9Or SO2-X9, X9For C1-C6Alkyl, C2-C6Alkenyl, phenyl, benzyl or phenethyl;
R24、R25It is respectively and independently selected from H, Cl, Br, I, CN, NO2、NHCO-X7、O-X7、NHSO2-X7Or OSO2-X7, X7For C1-C6Alkane
Base, phenyl, benzyl, phenethyl;
Described formula (IV) is:
B-N=N-A
A is selected from being:
In one;
R12Selected from H, CN, the C that replaced by amide groups or amido derivatives1-C6Alkyl, C3-10Cycloalkyl, C7-C10Aralkyl, virtue
Perfume base;
R13、R14It is respectively and independently selected from OH, Cl, Br, I, quilt-CN, OCO-X6、-COO-X6Replace or unsubstituted NH2、N-
C1-C6Alkyl, N-phenyl, N-benzyl or N-phenethyl, X6For C1-C6Alkyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R15Selected from C1-C6Alkyl, C1-C6Alkoxyl, C2-C6Thiazolinyl, phenyl, benzyl or phenethyl;
R16Selected from C1-6Alkyl, C1-C6Alkoxyl, C1-C6Alkylamino, substituted amino, hydroxyl, phenyl, cyano group;
R17Selected from OH or NH;
R18Selected from H, C1-C6Alkyl, C2-C6Alkenyl, phenyl, benzyl or phenethyl;
R19Selected from C1-C6Alkyl, C1-C6Alkoxyl, C2-C6One in alkenyl, phenyl, benzyl or phenethyl;
B is selected from
In one;
R24、R25It is respectively and independently selected from H, Cl, Br, I, CN, NO2、NHCO-X7、O-X7、NHSO2-X7Or OSO2-X7, X7For C1-C6Alkane
Base, phenyl, benzyl, phenethyl;
Described formula (V) is selected from:
R26、R27、R28、R29It is respectively and independently selected from H, NH2、OH、SH、NH-X8、O-X8Or S-X8, X8For by OH, CN, C1-C6Alkyl,
C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl or C7-C10Aralkyl replaces or unsubstituted C1-C6Alkyl, C1-C6
Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl, phenethyl, C3-C10Cycloalkyl, C7-C10Aralkyl or C2-C6Thiazolinyl;
R30、R31It is respectively and independently selected from H, Cl, Br, I, CN, SO2NH-X9、O-X9、O-(CH2CH2O)n-X9、O-X9-O-X9、S-X9、
S-(CH2CH2O)n-X9Or S-X9-O-X9, X9For by OH, CN, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Ring
Alkyl or C7-C10Aralkyl replaces or unsubstituted C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl, benzene
Ethyl, C3-C10Cycloalkyl, C7-C10Aralkyl or C2-C6Thiazolinyl;
Described logical formula (VI) is:
R32Selected from by OH, CN, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl, C7-C10Aralkyl replaces
Or unsubstituted C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, phenyl, benzyl, phenethyl, C3-C10Cycloalkyl, C7-
C10Aralkyl or C2-C6Alkenyl;
R33Selected from O or NH;
Described logical formula (VII) is:
R34Selected from H, Cl, Br, I, CN or NO2;
R35Selected from H, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl or C7-C10Aralkyl;
R36、R37Be respectively and independently selected from H, Cl, Br, I, by C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl,
C7-C10The substituted or unsubstituted amide groups of aralkyl, sulfonyl or sulfoamido;
Described logical formula (VIII) is:
Y is selected from O, S or NH;
R38、R39It is respectively and independently selected from H, by C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl, C7-C10Virtue
Alkyl is monosubstituted or one in disubstituted imido grpup;
R40、R41It is respectively and independently selected from H, Cl, Br, I, C1-C6Alkyl, C1-C6Alkoxyl, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl or
C7-C10Aralkyl;
Described logical formula (IX) is:
R42、R43It is respectively and independently selected from H, C1-C6Alkyl, C1-C6Alkoxyl, phenyl, benzyl, phenethyl, by C1-C6Alkyl, C1-C6
Alkoxyl, C2-C6Ester group, C1-C6Hydroxyalkyl, C3-C10Cycloalkyl, C7-C10Aralkyl is monosubstituted or polysubstituted C1-C6Alkyl,
C1-C6Alkoxyl, phenyl, benzyl, phenethyl.
5. the dye as described in claim 4 is coated with one dyeing, printing dyes paste composition, it is characterised in that:
Described formula (I) is:
R1、R2、R3It is respectively and independently selected from H, Cl, Br, I, CN, NO2;
R4、R5It is respectively and independently selected from H, quilt-CN, OCO-X2、-COO-X2Replace or unsubstituted C1-C4Alkyl, phenyl, benzyl
Base or phenethyl, X2For C1-C4Alkyl, phenyl, benzyl or phenethyl;
R6It is respectively and independently selected from C1-C4Alkyl;
R7It is respectively and independently selected from CO-X3Or SO2-X3, X3For C1-C4Alkyl, phenyl, benzyl or phenethyl;
Described formula (II) is:
A is selected from
In one;
R8、R9、R10、R11It is respectively and independently selected from H, Cl, Br, I, CN, NO2、O-X4, X4For C1-C4Alkyl, phenyl, benzyl or benzene second
Base;
R12Selected from H, CN, the C that replaced by amide groups or amido derivatives1-C4Alkyl, C3-6 cycloalkyl, C7-C10Aralkyl, virtue
Perfume base;
R13、R14It is respectively and independently selected from OH, Cl, Br, I, quilt-CN, OCO-X6、-COO-X6Replace or unsubstituted NH2、N-
C1-C4Alkyl, N-phenyl, N-benzyl or N-phenethyl, X6For C1-C4Alkyl, phenyl, benzyl or phenethyl;
R15Selected from C1-C4Alkyl, C1-C4Alkoxyl, phenyl, benzyl or phenethyl;
R16Selected from C1-4Alkyl, C1-C4Alkoxyl, C1-C4Alkylamino, substituted amino, hydroxyl, phenyl, cyano group;
R17Selected from OH or NH;
R18Selected from H, C1-C4Alkyl, phenyl, benzyl or phenethyl;
R19Selected from C1-C4Alkyl, C1-C4One in alkoxyl, phenyl, benzyl or phenethyl;
Described formula (III) is:
B is selected from
In one;
R20、R21It is respectively and independently selected from H, quilt-CN, OCO-X8、-COO-X8、-COOCHCO-X8Or-COOCHCO-X8Replace or not
The C being replaced1-C4Alkyl, phenyl, benzyl or phenethyl, X8For C1-C4Alkyl, phenyl, benzyl or phenethyl;
R22Selected from C1-C4Alkyl;
R23Selected from CO-X9Or SO2-X9, X9For C1-C4Alkyl, phenyl, benzyl or phenethyl;
R24、R25It is respectively and independently selected from H, Cl, Br, I, CN, NO2、NHCO-X7、O-X7、NHSO2-X7Or OSO2-X7, X7For C1-C4Alkane
Base, phenyl, benzyl, phenethyl;
Described formula (IV) is:
B-N=N-A
A is selected from
In one;
R12Selected from H, CN, the C that replaced by amide groups or amido derivatives1-C4Alkyl, C3-6 cycloalkyl, C7-C10Aralkyl, virtue
Perfume base;
R13、R14It is respectively and independently selected from OH, Cl, Br, I, quilt-CN, OCO-X6、-COO-X6Replace or unsubstituted NH2、N-
C1-C4Alkyl, N-phenyl, N-benzyl or N-phenethyl, X6For C1-C4Alkyl, phenyl, benzyl or phenethyl;
R15Selected from C1-C4Alkyl, C1-C4Alkoxyl, phenyl, benzyl or phenethyl;
R16Selected from C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Alkylamino, substituted amino, hydroxyl, phenyl, cyano group;
R17Selected from OH or NH;
R18Selected from H, C1-C4Alkyl, phenyl, benzyl or phenethyl;
R19Selected from C1-C4Alkyl, C1-C4Alkoxyl, phenyl, benzyl or phenethyl;
B is selected from:
In one;
R24、R25It is respectively and independently selected from H, Cl, Br, I, CN, NO2、NHCO-X7、O-X7、NHSO2-X7Or OSO2-X7, X7For C1-C4Alkane
Base, phenyl, benzyl, phenethyl;
Described formula (V) is selected from:
R26、R27、R28、R29It is respectively and independently selected from H, NH2、OH、SH、NH-X8、O-X8Or S-X8, X8For by OH, CN, C1-C4Alkyl,
C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-C6Cycloalkyl or C7-C10Aralkyl replaces or unsubstituted C1-C4Alkyl, C1-C4
Alkoxyl, C1-C4Hydroxyalkyl, phenyl, benzyl, phenethyl, C3-C6Cycloalkyl, C7-C10Aralkyl;
R30、R31It is respectively and independently selected from H, Cl, Br, I, CN, SO2NH-X9、O-X9、O-(CH2CH2O)n-X9、O-X9-O-X9、S-X9、
S-(CH2CH2O)n-X9Or S-X9-O-X9, X9For by OH, CN, C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-C6Cycloalkanes
Base or C7-C10Aralkyl replaces or unsubstituted C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, phenyl, benzyl, benzene second
Base, C3-C6Cycloalkyl, C7-C10Aralkyl;
Described logical formula (VI) is:
R32Selected from by OH, CN, C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-C6Cycloalkyl, C7-C10Aralkyl replaces
Or unsubstituted C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, phenyl, benzyl, phenethyl, C3-C6Cycloalkyl, C7-C10
Aralkyl;
R33Selected from O or NH;
Described logical formula (VII) is:
R34Selected from H, Cl, Br, I, CN or NO2;
R35Selected from H, C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-C6Cycloalkyl or C7-C10Aralkyl;
R36、R37Be respectively and independently selected from H, Cl, Br, I, by C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-C6Cycloalkyl,
C7-C10The substituted or unsubstituted amide groups of aralkyl, sulfonyl or sulfoamido;
Described logical formula (VIII) is:
Y is selected from O, S or NH;
R38、R39It is respectively and independently selected from H, by C1-C4Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-C6Cycloalkyl, C7-C10Virtue
Alkyl is monosubstituted or one in disubstituted imido grpup;
R40、R41It is respectively and independently selected from H, Cl, Br, I, C1-C6Alkyl, C1-C4Alkoxyl, C1-C4Hydroxyalkyl, C3-C6Cycloalkyl or
C7-C10Aralkyl;
Described logical formula (IX) is:
R42、R43It is respectively and independently selected from H, C1-C4Alkyl, C1-C4Alkoxyl, phenyl, benzyl, phenethyl, by C1-C4Alkyl, C1-C4
Alkoxyl, C2-C6Ester group, C1-C4Hydroxyalkyl, C3-C6Cycloalkyl, C7-C10Aralkyl is monosubstituted or polysubstituted C1-C4Alkyl,
C1-C4Alkoxyl, phenyl, benzyl, phenethyl.
6. the dye as described in claim 2 is coated with one dyeing, printing dyes paste composition, it is characterised in that: described auxiliary agent
One or more in mineral oils, high-carbon alcohols, polyethers or silicone defoamer and LOMAR PWA EINECS 246-676-2-formaldehyde condensation
Thing, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol ethylene oxide condensate, sodium lignin sulfonate, Oleum Ricini oleic alcohol,
Dodecylbenzene sodium sulfonate, extension agent S S, diffusion agent N, dispersing agent MF, dispersing agent CNF, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, 2-
Naphtholsulfonic acid formaldehyde condensation products, dispersing agent C S, fatty acid salt form anion surfactant, sulfonate type anion surface active
Agent, sulfate type anion surfactant, phosphate ester salt form anion surfactant, 2-Sulfosuccinic acid ester type anion table
Face activating agent, betaine type amphoteric ionic surface active agent, imidazoline type zwitterionic surfactant, amino acid type amphoteric from
Sub-surface activating agent, phosphatide type zwitterionic surfactant, fatty alcohol ether type nonionic surfactant, alkyl phenol ether type are non-
Ionic surface active agent, alkylamine ether type nonionic surfactant, polyether nonionic surfactant, fatty acid polyglycol alcoxyl
Compound ester type nonionic surfactant, castor oil polyoxyethylene type nonionic surfactant, lanoline polyoxyethylene-type are non-
Ionic surface active agent, sorbitol polyoxyethylene type nonionic surfactant, glycerol ester type nonionic surfactant, Pyrusussuriensis
Alcohol ester type nonionic surfactant, fatty acid alkanamine type nonionic surfactant, alkylolamides type non-ionic surface are lived
Property agent, alkyl polyglucoside type nonionic surfactant, alkyl pyrrolidone type nonionic surfactant, ethylene glycol, propylene glycol,
The mixing of one or more in carbamide, diethylene glycol.
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CN106977980A (en) * | 2017-05-24 | 2017-07-25 | 上海贝通色彩科技有限公司 | A kind of alkali resistance disperse dye composition |
CN107090193A (en) * | 2017-06-07 | 2017-08-25 | 杭州维昂化工有限公司 | A kind of dye composite, dye preparations and its preparation method and application |
CN108049203A (en) * | 2017-12-29 | 2018-05-18 | 沈阳化工研究院有限公司 | A kind of dye applies integral weld paste composition and its application |
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CN109457505A (en) * | 2018-10-24 | 2019-03-12 | 江苏华东纺织产品检测有限公司 | A kind of square screen printing process of fleece |
CN110373044A (en) * | 2019-06-10 | 2019-10-25 | 浙江龙盛染料化工有限公司 | A kind of dispersed deep blue dye composition and dye preparations |
CN110643198A (en) * | 2019-10-17 | 2020-01-03 | 上海贝通色彩科技有限公司 | Disperse blue dye composition |
CN110643198B (en) * | 2019-10-17 | 2020-10-13 | 上海贝通色彩科技有限公司 | Disperse blue dye composition |
CN111019393A (en) * | 2019-12-25 | 2020-04-17 | 沈阳化工研究院有限公司 | Yellow liquid dye composition for dyeing and printing and application thereof |
CN111019393B (en) * | 2019-12-25 | 2022-02-11 | 沈阳化工研究院有限公司 | Yellow liquid dye composition for dyeing and printing and application thereof |
CN111235910A (en) * | 2020-03-31 | 2020-06-05 | 南通纺织丝绸产业技术研究院 | Water-based nano disperse dye for soft finishing and application thereof |
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