CN110373044A - A kind of dispersed deep blue dye composition and dye preparations - Google Patents
A kind of dispersed deep blue dye composition and dye preparations Download PDFInfo
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- CN110373044A CN110373044A CN201910496912.5A CN201910496912A CN110373044A CN 110373044 A CN110373044 A CN 110373044A CN 201910496912 A CN201910496912 A CN 201910496912A CN 110373044 A CN110373044 A CN 110373044A
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- component
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- deep blue
- blue dye
- dispersed deep
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Links
- 239000000203 mixture Substances 0.000 title claims abstract description 46
- 239000001045 blue dye Substances 0.000 title claims abstract description 45
- 239000000975 dye Substances 0.000 title claims abstract description 34
- 238000002360 preparation method Methods 0.000 title abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 34
- 238000004043 dyeing Methods 0.000 claims abstract description 20
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 11
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 7
- 239000002657 fibrous material Substances 0.000 claims abstract description 6
- 239000000047 product Substances 0.000 claims description 17
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- -1 quinone hydrazone Chemical class 0.000 claims description 7
- 239000007859 condensation product Substances 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 150000002431 hydrogen Chemical class 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- KTHUKEZOIFYPEH-UHFFFAOYSA-N 1-benzylnaphthalene Chemical compound C=1C=CC2=CC=CC=C2C=1CC1=CC=CC=C1 KTHUKEZOIFYPEH-UHFFFAOYSA-N 0.000 claims 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 19
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 12
- 229920000728 polyester Polymers 0.000 abstract description 9
- 229910021529 ammonia Inorganic materials 0.000 abstract description 6
- 238000007639 printing Methods 0.000 abstract description 5
- 238000005406 washing Methods 0.000 abstract description 5
- 238000000859 sublimation Methods 0.000 abstract description 3
- 230000008022 sublimation Effects 0.000 abstract description 3
- 229920000742 Cotton Polymers 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 10
- 239000000986 disperse dye Substances 0.000 description 9
- 239000002270 dispersing agent Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 229920002334 Spandex Polymers 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- 239000004759 spandex Substances 0.000 description 6
- 238000009826 distribution Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 229920004933 Terylene® Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000010017 direct printing Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- ZLCUIOWQYBYEBG-UHFFFAOYSA-N 1-Amino-2-methylanthraquinone Chemical compound C1=CC=C2C(=O)C3=C(N)C(C)=CC=C3C(=O)C2=C1 ZLCUIOWQYBYEBG-UHFFFAOYSA-N 0.000 description 1
- NMDKWAQVRNUKQH-UHFFFAOYSA-N 2-benzylnaphthalene-1-sulfonic acid formaldehyde Chemical compound C=O.C(C1=CC=CC=C1)C1=C(C2=CC=CC=C2C=C1)S(=O)(=O)O NMDKWAQVRNUKQH-UHFFFAOYSA-N 0.000 description 1
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- ZRXADTFMGYNRKV-UHFFFAOYSA-N [S].C1=CC=CC2=CC=CC=C21 Chemical compound [S].C1=CC=CC2=CC=CC=C21 ZRXADTFMGYNRKV-UHFFFAOYSA-N 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 229910052789 astatine Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
- C09B67/008—Preparations of disperse dyes or solvent dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/19—Nitro dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
- D06P3/8214—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing ester and amide groups
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of dispersed deep blue dye composition and dye preparations.The dispersed deep blue dye composition includes component A, component B and component C, the component A is selected from least one of formula (I) compound represented, the component B is selected from least one of compound shown in formula (II) and formula (III), and the component C is selected from least one of compound shown in formula (IV).The present invention also provides a kind of dispersed deep blue dye product, contain the dispersed deep blue dye composition and auxiliary agent, the weight ratio of auxiliary agent and dispersed deep blue dye composition is 0.2~5:1.Dispersed deep blue dye product application of the present invention is in hydrophobic fiber material dyeing or stamp, have the characteristics that low dyeing cost, washing fastness, crock fastness and sublimation reliability are good, is highly suitable for medium-to-high grade fabric such as super fine denier fabric, polyester cotton, washs the/printing and dyeing of the blended fabric such as ammonia.
Description
(1) technical field
The present invention relates to a kind of dispersed deep blue dye composition and dye preparations.
(2) background technique
In recent years, since the fabric containing spandex has excellent resilience performance, soft, dress is comfortable, to obtain
More and more applications, such as/ammonia stockinette is combined and washed with terylene.Currently, washing the/main use of ammonia stockinette dyeing
Disperse dyes, due to the design feature of spandex, disperse dyes are easy upper dye spandex, while being also easy desorption, so reducing this
Every color fastness of class product.In addition, in order to avoid spandex performance is injury-free, the high temperature of terylene contaminates due to the presence of spandex
Color is restricted, and low temperature dyeing often prevents disperse dyes from contaminating terylene, the dye-uptake of terylene component and promotion thoroughly well
Rate cannot adequately be embodied, and especially when upper dye is dark blue dark to black etc., be infected with seriously spandex, color fastness is very not
Ideal is extremely difficult to 3~4 grades of market demands so as to the demanding product of color fastness in dyeing process exist compared with
Big problem.ZL201010263434.2 has developed the dyestuff that can meet above-mentioned requirements, but still has improved space.
(3) summary of the invention
To solve the above problems, being answered it is an object of that present invention to provide a kind of dispersed deep blue dye composition and dye preparations
For in hydrophobic fiber material printing and dyeing, having the characteristics that color fastness is excellent and dyeing economy is good.
The technical solution adopted by the present invention is that:
A kind of dispersed deep blue dye composition, including component A, component B and component C, the component A are selected from formula (I) institute
At least one of compound shown, the component B are selected from least one of compound shown in formula (II) and formula (III),
The component C is selected from least one of compound shown in formula (IV), in the dye composite, the quality percentage of component A
Content is 50%~90%, and the mass percentage of component B is 5%~35%, the mass percentage of component C is 1%~
20%；
In formula (I):
X1For halogen；
R1、R2Respectively stand alone as C1~C4Alkyl；
R3、R4Respectively stand alone as-CH2COOK1Or-C2H4COOK2, wherein K1、K2Respectively stand alone as C1~C4Alkyl；
In formula (II):
R5For hydrogen, C1~C4Alkyl or-NHCOK3, wherein K3For C1~C4Alkyl；
R6、R7Respectively stand alone as hydrogen ,-OCOCH3Or-OCOCH2CH3；
In formula (III):
R8For hydrogen or C1~C4Alkoxy；
R9For hydrogen, hydroxyl or-NHCOK4, wherein K4For C1~C4Alkyl；
R10、R11Respectively stand alone as C1~C4Alkyl, allyl ,-CH2- Ph ,-C2H4CN、-CH2COOK5Or-C2H4COOK6,
Wherein K5、K6Respectively stand alone as C1~C4Alkyl, Ph are phenyl；
N is 1 or 2；
In formula (IV):
R12、R13Respectively stand alone as C1~C18Alkyl.
In above-mentioned formula (I)~(IV), the C1~C18Alkyl can be methyl, ethyl, linear chain or branched chain propyl, straight
The butyl of chain or branch, the hexyl of linear chain or branched chain, the octyl of linear chain or branched chain, the dodecyl of linear chain or branched chain, straight chain or
The octadecyl etc. of branch.The C1~C4Alkyl can be methyl, ethyl, the propyl of linear chain or branched chain, linear chain or branched chain
Butyl.The C1~C4Alkoxy can be methoxyl group, ethyoxyl, the propoxyl group of linear chain or branched chain, linear chain or branched chain fourth oxygen
Base.The halogen can be F, Cl, Br, I.
Preferably, the component A is selected from the mixture of one of following formula or in which two or more arbitrary proportions:
Preferably, the component B is selected from the mixture of one of following formula or in which two or more arbitrary proportions:
Wherein, Ph represents phenyl.
Preferably, the component C is selected from the mixture of one of following formula or in which two or more arbitrary proportions:
As a further preference, in dispersed deep blue dye composition of the present invention:
Component A is at least one of formula (I-1)~(I-4)；
Component B is at least one of formula (II-1)~(II-4), (III-1)~(III-14)；
Component C is at least one of formula (IV-1)~(IV-7).
As it is further preferably, in the dispersed deep blue dye composition:
Component A is selected from formula (I-2)；
Component B is selected from least one of formula (II-1), (III-1), (III-10)；
Component C is selected from formula (IV-1).
Preferably, the mass percentage of component A is 55~90%, group in the dispersed deep blue dye composition
The mass percentage for dividing B is 5~30%, and the mass percentage of component C is 1~15%.
Preferably, the dispersed deep blue dye composition is made of component A, component B and component C.
As a further preference, dispersed deep blue dye composition of the present invention is by component A, component B, component C group
At, in which:
Component A is at least one of formula (I-1)~(I-4)；
Component B is at least one of formula (II-1)~(II-4), (III-1)~(III-14)；
Component C is at least one of formula (IV-1)~(IV-7).
The particularly preferred dispersed deep blue dye composition is made of component A, component B and component C, in which:
Component A is selected from formula (I-2)；
Component B is selected from least one of formula (II-1), (III-1), (III-10)；
Component C is selected from formula (IV-1).
It is emphasized that dispersed deep blue dye composition of the present invention, in the dye of pyridone hydroxyl ortho position coupling
Material exists usually in the form of quinone hydrazone body, that is, the dyestuff of logical formula (IV) substantially has quinone hydrazone body structure shown in following formula (IVa), examines
The writing style for considering those skilled in the art still uses the written form of azo body in summary of the invention and embodiment part,
This has no effect on essence of the invention:
Wherein R12、R13It is identical as the definition in above-mentioned formula (IV) compound.
Dispersed deep blue dye composition of the present invention usually requires in commercialization that conven-tional adjuvants are added.Cause
This contains the dispersed deep blue dye composition and auxiliary agent, helps the present invention also provides a kind of dispersed deep blue dye product
The weight ratio of agent and dispersed deep blue dye composition is 0.2~5:1.Preferably, the dispersed deep blue dye product is by institute
Dispersed deep blue dye composition and the auxiliary agent composition stated.The auxiliary agent is common dispersing agent, diffusion when disperse dyes compound
Agent and other surfactants etc. preferably are selected from one of following or in which two or more mixture: lignosulfonates (lignin
85A, lignin 83A etc.), alkyl naphthalene sulfonic acid formaldehyde condensation products (such as condensation compound of methyl naphthalene sulfonic acid and formaldehyde (Dispersant MF)), naphthalene sulphur
Sour formaldehyde condensation products (dispersing agent NNO), benzyl naphthalene sulfonic acid-formaldehyde condensation product (dispersing agent CNF) etc..
Dispersed deep blue dye product of the present invention the preparation method is as follows: dispersed deep blue dye composition will be formed
After dye monomer compound (former dyestuff) mixes according to the ratio, the pulverizers such as sand mill or grinder in the presence of auxiliary agent, water
Carry out corpusculed；In addition can also by dye monomer compound sand mill or grinder etc. in the presence of auxiliary agent, water respectively
Pulverizer is mixed in proportion after carrying out corpusculed processing.Dark blue disperse dye product of the present invention, with sand milling
It is liquid after machine or grinder grinding, can is powdery, graininess after spray drying, this is well known to those skilled in the art preparation
Method, due to can not be by the removing of moisture 100%, so even being powdery or granular dyestuff system in spray-drying process
In product, still allow that there are a certain amount of moisture, preferably more than the 10% of dye preparations gross weight.
In addition, it is necessary to which explanation makes the promotion of dyeing effect when dye preparations are applied to the printing and dyeing of textile fabric
Contribution is technically characterized in that dye component contained in the product and ratio.
Dispersed deep blue dye composition of the present invention also allows to be made with the further compound synergic of other dyestuffs new
The compositions such as red, blue or orange.
In the present invention, formula (I), (II), (III), dye composition is convenient to by those skilled in the art shown in (IV)
Mode known to member synthesizes, and can also use commercial goods.
The present invention provides application of the dispersed deep blue dye product in hydrophobic fiber material dyeing or stamp.
It, can be by ways customary in industry to hydrophobic fibre material using dye preparations made of dye composite of the invention
Material (such as ultra-fine polyester, polyester and its blended fabric such as wash/ammonia intertexture) is dyed, and common dip method or height are such as used
High temperature pressure dyeing method is dyed, it can also be used to direct printing.Wherein, common dip method such as carries out hydrophobic fiber material pre-
Processing, is put into dye vat and is disseminated, and dye finishes, and cold water wash to neutrality squeezes out, and restores again cleaning, dries；Direct printing
Fabric is such as subjected to dye pre-treatment, is dried, setting prints disperse dyes mill base on printing machine, then evaporated, and utilizes decatize side
Formula makes the dye fixing on fabric, finally washes, stentering forming.
Dispersed deep blue dye composition and dye preparations provided by the invention, when being applied to hydrophobic fiber material dyeing,
Have the characteristics that low dyeing cost, washing fastness, crock fastness and sublimation reliability are good, it is for example ultra-fine to be highly suitable for medium-to-high grade fabric
Denier fabric, polyester cotton wash the/printing and dyeing of the blended fabric such as ammonia.
(4) specific embodiment
The present invention is described further combined with specific embodiments below, but protection scope of the present invention is not limited in
This:
Embodiment 1:
By 75 grams of formula (I-2) compounds, 5 grams of formula (II-1) compounds, 15 grams of formula (III-1) compounds, 5 grams of formulas (IV-1)
Compound, 150 grams of Dispersant MF, after adding 600 grams of water blendings, grinding distribution is spray-dried to get finished product, which can mention
For polyester and its blended fabric navy blue tone.
Embodiment 2:
By 80 grams of formula (I-2) compounds, 14 grams of formula (II-1) compounds, 6 grams of formula (IV-1) compounds, 150 grams of dispersion
Agent MF, after adding 650 grams of water blendings, grinding distribution is spray-dried to get finished product, which can provide polyester and its blended fabric
Navy blue tone.
Embodiment 3:
By 90 grams of formula (I-2) compounds, 2 grams of formula (II-1) compounds, 5 grams of formula (III-10) compounds, 3 grams of formulas (IV-1)
Compound, 150 grams of Dispersant MF, after adding 600 grams of water blendings, grinding distribution is spray-dried to get finished product, which can mention
For polyester and its blended fabric navy blue tone.
Embodiment 4~30
According to method described in embodiment 1-3, unlike using component A in table 1, component B, the structure of component C and again
Amount is added 200 grams of auxiliary agent (Dispersant MF is 150 grams, and sodium lignin sulfonate is 50 grams), slurries is made after adding 600 grams of blendings of water,
Grinding distribution, dry, finished product, the dyestuff can be supplied to polyester and its excellent navy blue of blended fabric items fastness ability
Tone.
Table 1
Embodiment 31:
By 70 grams of formula (I-2) compounds, 5 grams of formula (II-1) compounds, 15 grams of formula (III-1) compounds, 5 grams of formulas (IV-1)
Compound, 5 grams 288,250 grams of C.I. disperse orange of Dispersant MF, after adding 200 grams of water blendings, grinding distribution, spray drying, i.e.,
Finished product is obtained, which can provide polyester and its blended fabric navy blue tone.
Comparative example 1:
By embodiment 1 in CN 101955691A as a comparison case 1.
Dyeing Example:
The dyestuff for weighing disperse dyes made from 2 grams of Examples 1 to 31, comparative example 1 respectively, is padded using conventional high temperature height
Color method, which is handled, washs/ammonia intertexture, in treatment process, controls dye level (o.w.f) 4.0%, bath raio 1: 50 adjusts Value in Dyeing Process 4
~5, room temperature enters dye, is warming up to 130 DEG C with 1 DEG C/min, keeps the temperature 45min, restores washing, washing, drying by well-established law, is cooled to 70
DEG C take out.Sample cloth coloured light is observed, the ISO105-X12 that adopts international standards, AATCC 61-2A, ISO 105-P01 test it respectively
Rub resistance, water-fastness, color fastness to sublimation can provide uniformly and the good navy blue dyeing and weaving object of fastness ability, specifically be shown in Table 2:
Table 2
Dispersed deep blue dye composition provided by the present invention, low in cost compared to the disperse dyes of comparative example 1, dye
One ton of fabric can reduce cost 400-500 member, produce apparent economic benefit, and be applied to wash/polyurethane fabric dyeing when, this
The fastness ability of invention dyestuff is more excellent, can further compound with pinkish red, dark blue disperse dyes, enrich dye species.
Claims (10)
1. a kind of dispersed deep blue dye composition, it is characterised in that: the dispersed deep blue dye composition includes component A, component B
Be selected from least one of formula (I) compound represented with component C, the component A, the component B be selected from formula (II) and
At least one of compound shown in formula (III), the component C are selected from least one of compound shown in formula (IV), institute
It states in dye composite, the mass percentage of component A is 50%~90%, the mass percentage of component B is 5%~
The mass percentage of 35%, component C are 1%~20%；
In formula (I):
X1For halogen；
R1、R2Respectively stand alone as C1~C4Alkyl；
R3、R4Respectively stand alone as-CH2COOK1Or-C2H4COOK2, wherein K1、K2Respectively stand alone as C1~C4Alkyl；
In formula (II):
R5For hydrogen, C1~C4Alkyl or-NHCOK3, wherein K3For C1~C4Alkyl；
R6、R7Respectively stand alone as hydrogen ,-OCOCH3Or-OCOCH2CH3；
In formula (III):
R8For hydrogen or C1~C4Alkoxy；
R9For hydrogen, hydroxyl or-NHCOK4, wherein K4For C1~C4Alkyl；
R10、R11Respectively stand alone as C1~C4Alkyl, allyl ,-CH2- Ph ,-C2H4CN、-CH2COOK5Or-C2H4COOK6, wherein
K5、K6Respectively stand alone as C1~C4Alkyl, Ph are phenyl；
N is 1 or 2；
In formula (IV):
R12、R13Respectively stand alone as C1~C18Alkyl.
2. dispersed deep blue dye composition as described in claim 1, it is characterised in that: the dispersed deep blue dye composition
It is made of component A, component B and component C.
3. dispersed deep blue dye composition as claimed in claim 1 or 2, it is characterised in that: the component A is selected from one of following formula
Or in which the mixture of two or more arbitrary proportions:
4. dispersed deep blue dye composition as claimed in claim 1 or 2, it is characterised in that: the component B is selected from one of following formula
Or in which the mixture of two or more arbitrary proportions:
Wherein, Ph represents phenyl.
5. dispersed deep blue dye composition as claimed in claim 1 or 2, it is characterised in that: the component C is selected from one of following formula
Or in which the mixture of two or more arbitrary proportions:
6. dispersed deep blue dye composition as claimed in claim 1 or 2, it is characterised in that: the dispersed deep blue dye combination
In object:
Component A is selected from formula (I-2)；
Component B is selected from least one of formula (II-1), (III-1), (III-10)；
Component C is selected from formula (IV-1)；
7. dispersed deep blue dye composition as claimed in claim 1 or 2, it is characterised in that: formula (IV) compound represented tool
There is quinone hydrazone body structure shown in following formula (IVa),
Wherein R12、R13It is identical as the definition in formula (IV) compound.
8. a kind of dispersed deep blue dye product, contains dispersed deep blue dye composition described in claim 1 and auxiliary agent, auxiliary agent
Weight ratio with dispersed deep blue dye composition is 0.2~5:1.
9. dispersed deep blue dye product as claimed in claim 8, it is characterised in that: the auxiliary agent be selected from it is one of following or its
In two or more mixture: lignosulfonates, alkyl naphthalene sulfonic acid formaldehyde condensation products, naphthalene sulfonic acid-formaldehyde condensation product, benzyl naphthalene
Sulfonic formaldehyde condensation compound.
10. application of the dispersed deep blue dye product as described in claim 1 in hydrophobic fiber material dyeing or stamp.
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| CN111334087A (en) * | 2020-04-15 | 2020-06-26 | 浙江龙盛集团股份有限公司 | Dark blue to black dye composition and dye product |
| CN111423745A (en) * | 2020-04-30 | 2020-07-17 | 约克夏(浙江)染化有限公司 | Black disperse dye composition, black disperse dye and preparation method and application thereof |
| CN114316628A (en) * | 2022-01-13 | 2022-04-12 | 上海青石化学有限公司 | High-lifting-force monoazo disperse dye, and preparation and application methods thereof |
| CN114395272A (en) * | 2022-01-13 | 2022-04-26 | 上海青石化学有限公司 | High-fastness monoazo disperse dye, preparation and application method thereof |
| CN114773877A (en) * | 2022-05-20 | 2022-07-22 | 上海鸿源鑫创材料科技有限公司 | Disperse blue dye composition and product thereof |
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| CN114395272B (en) * | 2022-01-13 | 2024-02-06 | 上海青石化学有限公司 | High-fastness monoazo disperse dye, preparation and application methods |
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