CN106087464A - A kind of dyeing, printing technology - Google Patents
A kind of dyeing, printing technology Download PDFInfo
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- CN106087464A CN106087464A CN201610585630.9A CN201610585630A CN106087464A CN 106087464 A CN106087464 A CN 106087464A CN 201610585630 A CN201610585630 A CN 201610585630A CN 106087464 A CN106087464 A CN 106087464A
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- Prior art keywords
- dyeing
- stamp
- printing
- disperse
- printing technology
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
- D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
Abstract
The present invention relates to textile dyeing, printing technique, a kind of hydrophobic textile material dyeing, printing technology.This technical process is by pending textile successively through stamp → drying → color development → post processing, and then obtains stamp finished product；Wherein, color development can the most scrubbed and drying with arrangement interprocedual.Before stamp of the present invention, process is similar to conventional dyes stamp, can pass through cylinder, flat screen printing machine by paste composition printing in textile material surface.During high temperature color development, most disperse dyes are combined with hydrophobic fiber material by molecular separating force, the printing assistant in concentrator while disperse dyes high temperature color development, crosslinking curing film forming, make the loose colour not being combined with fiber adhere to fiber surface.Present invention dyeing, printing technology wash the wash water COD of textile between 30 2000ppm, part kind ＜ 200ppm, part kind ＜ 50ppm；Colourity (extension rate) ＜ 200, part kind colourity (extension rate) ＜ 80, part kind colourity (extension rate) ＜ 30.
Description
Technical field
The present invention relates to textile dyeing, printing technique, a kind of hydrophobic textile material dyeing, printer
Process.
Background technology
Textile dyeing, stamp generally can be divided into two kinds of dyeing, stamp and pigment dyeing, stamp.Dyeing, print
Flower carries out dyeing typically by the molecular separating force of dyestuff itself or active group and fibration, stamp.Pigment dyeing, stamp
It is to combine with fabric by the way of the binding agent in pigment dyeing, printing paste is with physical adhesion.As a rule dye printing
After the dyeing that obtains, Printing more environmentally friendly, content of formaldehyde is low, bright, and color fastness is preferable, the most soft, stamp
Position is tack-free；Pigment printing technique is simple, and stamp low cost does not has the three wastes to produce substantially.
Conventional dyes dyeing, printing technology be generally: textile → stamp → drying → decatize → washing → reduction washes →
Soap → wash → dry → arrange → stamp finished product.Conventional dyes dyeing, printing paste typically require addition dye dosage 1-
The auxiliary agents such as the sodium alginate of 1.5 times amount, sodium lignin sulfonate, naphthalene sulfonic acid-formaldehyde condensation product, dispersant, levelling agent, penetrating agent produce
Product, these auxiliary agents need washing, reduction to wash after dyeing, stamp process complete and the step such as soap makes it shell from fiber surface
From, hence in dyeing, printing waste water.During conventional dyes dyeing simultaneously, stamp, the dye-uptake of dyestuff is generally
90-95%, the dyestuff of remaining 5-10% after dyeing, stamp complete presented in loose colour in fiber surface, wash, also
Former wash and soap during also can enter in dyeing waste water.These just enter into the auxiliary agent in dyeing, printing waste water and dyestuff
Causing high COD and the high chroma of dyeing waste water, intractability is relatively big, and processing cost is higher, according to authority's statistics, print works
Often processing a myriametre chemical fiber plus material it is necessary to water consumption about 250 tons, wherein 90% is color water, waste water.And present maximally effective measure
The most only rest on reduce discharging and color water, sewage post processing on, the most effectively eradicated.These dyeing waste waters become
Puzzlement China textile printing, the obstacle of the sustainable sustainable development of printing and dyeing industry.
Pigment printing technique relatively dye printing is simply a lot, generally textile → stamp → drying → baking → arrangement
→ stamp finished product, does not has water-washing step during stamp, dry and shrink control and cross contamination, naturally occurring or synthetic thickener
Removal, the existence of alkaline agent, surfactant and other pollutant all can be left in the basket, for environment protection type dye, printing technology.But
Being that the colouring component that pigment printing is selected is generally pigment, itself is not had affinity with fiber, needs to be adhered to by binding agent
In fiber surface, and color typically cannot penetrate into fibrous inside, and this has resulted in pigment printing product general color permeability
Poor, color is the most bright-coloured, color fastness is poor, not wash resistant, the shortcomings such as feel is partially hard, anti-yellowing property difference.
Dyeing, stamp are combined with pigment dyeing, printing technology, takes into account its respective advantage, it is lacked simultaneously
Falling into and be complementary to one another, the new way of can yet be regarded as a kind of dyeing, stamp, the present invention is exactly to produce in such a situa-tion.
Summary of the invention
It is desirable to provide a kind of hydrophobic textile material dyeing, printing technology method.
For achieving the above object, the present invention uses the technical scheme to be:
A kind of hydrophobic textile material dyeing, printing technology method, technical process is successively through print by pending textile
Flower → drying → color development → post processing, and then obtain stamp finished product；Wherein, color development can the most scrubbed and baking with arrangement interprocedual
Dry；Described color development temperature is 160-210 DEG C；The color development time is 1-30 minute；Described last handling process can use and wash → soap
→ wash → dry → arrange, wash → dry → arrange or individually arrange.Described color development uses decatize or the mode of baking；Institute
State washing and can use washing repeatedly and/or mode of soaping.
A kind of hydrophobic textile material dyeing, printing technology method, described technique is that pending textile is successively through stamp
→ drying → decatize → wash → soap → wash → dry → arrange, and then obtain stamp finished product.
Wherein steam temperature is 160-210 DEG C, and steaming time is 1-30 minute；
A kind of hydrophobic textile material dyeing, printing technology method, described technique is that pending textile is successively through stamp
→ drying → decatize → washing → drying → arrangement, and then obtain stamp finished product.
Wherein steam temperature is 160-210 DEG C, and steaming time is 1-30 minute；
A kind of hydrophobic textile material dyeing, printing technology method, described technique is that pending textile is successively through stamp
→ drying → decatize → arrangement, and then obtain stamp finished product.Wherein steam temperature is 160-210 DEG C, and steaming time is that 1-30 divides
Clock；
A kind of hydrophobic textile material dyeing, printing technology method, described technique is that pending textile is successively through stamp
→ dry → bakee → wash → soap → wash → dry → arrange, and then obtain stamp finished product.Wherein stoving temperature is
160-210 DEG C, the baking time is 1-30 minute；
A kind of hydrophobic textile material dyeing, printing technology method, described technique is that pending textile is successively through stamp
→ dry → bakee → washing → dry → arrange, and then obtain stamp finished product.Wherein stoving temperature is 160-210 DEG C, bakees
Time is 1-30 minute；
A kind of hydrophobic textile material dyeing, printing technology method, described technique is that pending textile is successively through stamp
→ dry → bakee → arrange, and then obtain stamp finished product.Wherein stoving temperature is 160-210 DEG C, and the baking time is that 1-30 divides
Clock；
The dyeing of described employing, printing paste, its composition by weight percentage, dyeing, stamp concentrated pulp 1-25%, thickening
Agent 0.5-10%, pH value regulator 0.05-3% and water 62-98.45%.
Described dyeing, stamp concentrated pulp by weight percentage, the dye of the dyeing of 20-80%, print paste and 20-80%
Color, printing assistant；Described dyeing, print paste are by the filter cake of dyestuff or dry powder are made into together with water slurry with auxiliary agent,
Again by refinement, it is prepared into.
Dyeing, each composition of print paste by weight percentage, disperse dyes (filter cake or dry powder) 20-60%, auxiliary agent 5-
30% and water 10-75%.
Described disperse dyes are selected from: C.I. disperse yellow 3, C.I. disperse yellow 5, C.I. disperse yellow 7, C.I. disperse yellow 11,
C.I. disperse yellow 23, C.I. Disperse Yellow 42, C.I. disperse yellow 49, C.I. disperse yellow 50, C.I. disperse yellow 54, C.I. disperse yellow
56, C.I. disperse yellow 60, C.I. disperse yellow 61, C.I. dispersion yellow 64, C.I. disperse yellow 71, C.I. disperse yellow 79, C.I. dispersion
Huang 82, C.I. disperse yellow 93, C.I. disperse yellow 97, C.I. disperse yellow 104, C.I. disperse yellow 114, C.I. disperse yellow 119, C.I.
Disperse yellow 124, C.I. disperse yellow 126, C.I. disperse yellow 134, C.I. disperse yellow 163, C.I. disperse yellow 182, C.I. disperse yellow
184, C.I. disperse yellow 201, C.I. DISPERSE Yellow 211, C.I. disperse yellow 235, C.I. disperse yellow 241, C.I. disperse orange 3, C.I.
Disperse orange 5, C.I. disperse orange 13, C.I. disperse orange 20, C.I. disperse orange 25, C.I. disperse orange 25: 1, C.I. disperse orange 29,
C.I. disperse orange 30, C.I. disperse orange 31, C.I. disperse orange 32, C.I. disperse orange 37, C.I. disperse orange 38:2, C.I. disperse orange
41, C.I. disperse orange 44, C.I. disperse orange 61, C.I. disperse orange 62, C.I. disperse orange 73, C.I. disperse orange 76, C.I. dispersion
Orange 97, C.I. disperse orange 127, C.I. disperse orange 288, C.I. Red-1 200, C.I. disperse red 4, C.I. disperse red 5, C.I. dispersion
Red 9, C.I. dispersion red 11, C.I. DISPERSE Red 13, C.I. disperse red 50, C.I. disperse red 53, C.I. disperse red 54, C.I. dispersion
Red 54:1, C.I. disperse red 60, C.I. disperse red 65, C.I. disperse red 72, C.I. disperse red 73, C.I. disperse red 74, C.I.
Disperse red 82, C.I. disperse red 86, C.I. disperse red 91, C.I. disperse red 92, C.I. dispersion red 11 8, C.I. DISPERSE Red 13 5,
C.I. Red-1 200 45, C.I. Red-1 200 52, C.I. Red-1 200 53, C.I. Red 167, C.I. Red 167: 1, C.I.
Red-1 200 77, C.I. Red-1 200 79, C.I. disperse red 200, C.I. disperse red 210, C.I. disperse red 220, C.I. disperse red
277, C.I. Disperse Red 278, C.I. Disperse Red 343, C.I. disperse red 356, C.I. disperse violet 1, C.I. disperse violet 8, C.I. divide
Dissipate purple 17, C.I. disperse violet 26, C.I. disperse violet 27, C.I. disperse violet 28, C.I. disperse violet 33, C.I. disperse violet 38, C.I.
Disperse violet 43, C.I. disperse violet 63, C.I. disperse violet 77, C.I. disperse violet 93, C.I. disperse violet 93:1, C.I. disperse blue 3,
C.I. disperse blue 14, C.I. disperse blue 20, C.I. disperse blue 26, C.I. disperse blue 27, C.I. Disperse Blue-56, C.I. disperse blue
56:1, C.I. Disperse Blue-56: 2, C.I. Disperse Blue-56: 3, C.I. disperse blue 58, C.I. disperse blue 60, C.I. disperse blue 73,
C.I. disperse blue 77, C.I. Disperse Blue-79, C.I. Disperse Blue-79: 1, C.I. Disperse Blue-79: 2, C.I. disperse blue 81, C.I. dispersion
Blue 82, C.I. disperse blue 87, C.I. disperse blue 102, C.I. disperse blue 104, C.I. disperse blue 106, C.I. disperse blue 118,
C.I. disperse blue 143, C.I. disperse blue 148, C.I. disperse blue 165, C.I. disperse blue 165:1, C.I. disperse blue 165:2,
C.I. disperse blue 165:3, C.I. disperse blue 183, C.I. disperse blue 183:1, C.I. disperse blue 225, C.I. disperse blue 257,
C.I. disperse blue 270, C.I. disperse blue 281, C.I. disperse blue 291, C.I. disperse blue 291:1, C.I. disperse blue 301, C.I.
Disperse blue 354, C.I. disperse blue 359, C.I. disperse blue 366, C.I. disperse blue 367, C.I. disperse brown 1, C.I. disperse brown 1:
1, one or more in C.I. disperse brown 19, C.I. dispersion black 1 etc. can be used for dyeing, the dyestuff of print paste；
Auxiliary agent is selected from polyvinyl alcohol, polyvinyl acetate, styrene and maleic anhydride multipolymer, gelatin, carboxymethyl fibre
Dimension element, carboxyethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, ethylene glycol, propylene glycol, carbamide, diethylene glycol, thiourea, ore deposit
One or more in thing oils, high-carbon alcohols, polyethers or silicone defoamer and sodium alginate, polyacrylamide, N-
Methyl-N oleoyl taurine sodium, LOMAR PWA EINECS 246-676-2-formaldehyde condensation products, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol epoxy
Oxide condensate, triisopropylbenzene phenol ethylene oxide condensates, sodium lignin sulfonate, Oleum Ricini oleic alcohol, dodecyl
Benzene sulfonic acid sodium salt, metacresol-formaldehyde-sodium sulfite condensation substance extension agent S S, diffusion agent N, dispersing agent MF, dispersing agent CNF, methyl naphthalene
Sulfonic formaldehyde condensation compound, cresol (or phenol) sodium sulfonate formaldehyde condensation products, beta naphthal sulfonic formaldehyde condensation compound, phenolic resin sulfonation
Thing, dispersing agent C S；Fatty acid salt form anion surfactant, sulfonate type anion surfactant, sulfate type cloudy from
Sub-surface activating agent, phosphate ester salt form anion surfactant, 2-Sulfosuccinic acid ester type anion surfactant, fatty acid
Type anion surfactant, peptide condensation substance type anion surfactant；Ammonium salt type cationic surfactant, quaternary
Cationic surfactant, oxidation ammonium type cationic surfactant, betaine type amphoteric ionic surface active agent, imidazoline type
Zwitterionic surfactant, amino acid type amphoteric ionic surface active agent, phosphatide type zwitterionic surfactant, fatty alcohol
Ether type nonionic surfactant, alkyl phenol ether type nonionic surfactant, alkylamine ether type nonionic surfactant, poly-
Ether type nonionic surfactant, fatty acid polyglycol alkoxide ester type nonionic surfactant, castor oil polyoxyethylene type are non-
Ionic surface active agent, lanoline Determination of Polyoxyethylene Non-ionic Surfactants, sorbitol polyoxyethylene type non-ionic surface are lived
Property agent, glycerol ester type nonionic surfactant, sorbitol ester type nonionic surfactant, fatty acid alkanamine type nonionic table
Face activating agent, alkylolamides type nonionic surfactant, alkyl polyglucoside type nonionic surfactant, alkyl pyrrolidone
Live in type nonionic surfactant, alcohol surfactants, acids surfactant, amine surfactants, amide-type surface
Property agent, esters surface active agent, ether surfactant, ketone surfactant, polymer types of surfactants, Semen Ricini oils
Surfactant, Pilus Caprae seu Ovis lipid surfactant, three polyglyceryl laurate, four polyglyceryl laurate, six polyglycereol Laurels
The combination of one or more in acid esters, Tripolyglycerol monostearates, three polyglycerol acrylate；
Described water is: one or more in tap water, deionized water, distilled water, high purity water, ultra-pure water etc. can be used for contaminating
Color, the water of print paste；
Described micronization processes includes: disperse, roughly grind, fine grinding, the process such as homogenize, and device therefor includes: high speed dispersor,
One or more in vertical or horizontal sand mill, high pressure homogenizer etc. can be used for dyeing, the equipment of print paste；
The fineness scope that described dyeing, print paste processing are ground to is: D90=0.1-2 μm；
Described dyeing, printing assistant form following (percentage by weight):
Described binding agent is selected from pure third binding agent, phenylpropyl alcohol binding agent, butylbenzene binding agent, butyronitrile binding agent, silicone adhesive
One or more in agent, organosilicon modified acrylic ester binding agent, polyurethane binder etc. can be used for dyeing, printing assistant
Binding agent；
Described softening agent is selected from: quaternary, fatty acid ester type, right wax pattern, polyethylene, organic siliconresin type etc. sun from
Subtype softening agent, silicone softening agent, soap film class softening agent, dioctadecyl dimethyl ammonium chloride, ester group season
Ammonium salt type softening agent, Cationic Gemini Surfactant, the poly-silicon of high-molecular polythene wax, polydimethylsiloxane, terminal hydroxy group
One or more in oxygen alkane, amino silicones etc. can be used for dyeing, the softening agent of printing assistant.
Described cross-linking agent is selected from: cyanate cross-linking agent (JQ-1, JQ-1E, JQ-2E, JQ-4, JQ-5, JQ-6, PAPI, can
Emulsifying MDI, tetraisocyanate, blocked isocyanate etc.), polyalcohols cross-linking agent (Polyethylene Glycol, polypropylene glycol, trihydroxy methyl
Propane etc.), (+)-2,3-Epoxy-1-propanol ethers cross-linking agent, inorganic matter cross-linking agent (zinc chloride, aluminum chloride, aluminum sulfate, sulfur, boric acid etc.), have
Machine monomer class cross-linking agent (styrene, α-methyl styrene, acrylonitrile, acrylic acid, methacrylic acid, Biformyl, aziridine etc.),
Silicone cross-linking agent (tetraethyl orthosilicate, methyl silicate, trimethicone, amino modified siloxanes, carboxy-modified silica
Alkane, hydroxyl modification siloxanes, vinylsiloxane etc.), benzenesulfonic acid class cross-linking agent (p-methyl benzenesulfonic acid, paratoluensulfonyl chloride etc.),
Acrylic ester cross-linking agent (diacrylate-1,4-butanediol ester, Ethylene glycol dimethacrylate, TAC, butyl acrylate,
HEA, HPA, HPMA, MMA etc.), organic peroxide cross-linking agent (cumyl peroxide, peroxidating 2,4-dichloro-benzoyl
Deng), metallo-organic compound cross-linking agent (aluminum isopropylate., zinc acetate, titanium acetylacetone etc.), multi-functional polycarbodiimide class is handed over
One or more in connection agent can be used for dyeing, the cross-linking agent of printing assistant.
Other auxiliary agents described (diffusant, emulsifying agent, defoamer etc.) are selected from: sodium alginate, polyacrylamide, N-methyl-N
Oleoyl taurine sodium, LOMAR PWA EINECS 246-676-2-formaldehyde condensation products, Oleum Ricini ethylene oxide condensate, Cortex cocois radicis oleyl alcohol oxirane contract
Compound, triisopropylbenzene phenol ethylene oxide condensates, sodium lignin sulfonate, Oleum Ricini oleic alcohol, DBSA
Sodium, metacresol-formaldehyde-sodium sulfite condensation substance extension agent S S, diffusion agent N, dispersing agent MF, dispersing agent CNF, methyl naphthalene sulfonic acid first
Aldehyde condensate, cresol (or phenol) sodium sulfonate formaldehyde condensation products, beta naphthal sulfonic formaldehyde condensation compound, phenolic resin sulfonated bodies, point
Powder CS；Fatty acid salt form, sulfonate type, sulfate type, phosphate ester salt form, 2-Sulfosuccinic acid ester type, fatty acid/peptide condensation substance
Type anion surfactant；Ammonium salt type, quaternary, oxidation ammonium type cationic surfactant；Betaine type, imidazoline
Type, amino acid pattern, phosphatide type zwitterionic surfactant；Fatty alcohol ether type, alkyl phenol ether type, alkylamine ether type, polyether-type,
Fatty acid polyglycol alkoxide ester type, castor oil polyoxyethylene type, lanoline polyoxyethylene-type, sorbitol polyoxyethylene type, glycerol
Ester type, sorbitol ester type, fatty acid alkanamine type, alkylolamides type, alkyl polyglucoside type, alkyl pyrrolidone type non-ionic surface
Activating agent；Alcohols, acids, amine, amide-type, esters, ethers, ketone, polymerization species, Semen Ricini oils, Pilus Caprae seu Ovis lipid etc. other
Surfactant；Polyvinyl alcohol, polyvinyl acetate, styrene and maleic anhydride multipolymer, gelatin, carboxymethyl cellulose,
Carboxyethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, ethylene glycol, propylene glycol, carbamide, diethylene glycol, thiourea, organosilicon
Defoamer, mineral oil antifoam agent, polyethers defoamer, three polyglyceryl laurate, four polyglyceryl laurate, the six polyglycereol moons
One or more in cinnamic acid ester, Tripolyglycerol monostearates, three polyglycerol acrylate etc. can be used for dyeing, printing assistant
Other auxiliary agents；
Described water is: tap water, deionized water, distilled water, high purity water, ultra-pure water etc. can be used for dyeing, printing assistant
Water；
In described dyeing, printing paste, thickening agent is selected from: white carbon, sodium bentonite, organobentonite, kieselguhr, concavo-convex
The inorganic thickening agents such as rod stone soil, molecular sieve, Silica hydrogel, methylcellulose, ethyl cellulose, hydroxymethyl cellulose, ethoxy are fine
The cellulose thickeners such as dimension element, hydroxypropyl cellulose, carboxymethyl cellulose, carboxyethyl cellulose, carboxy-propyl cellulose, form sediment
Powder, gelatin, sodium alginate, casein, guar gum, chitosan, Radix Acaciae senegalis, xanthan gum, soybean glue, natural rubber,
The natural polymer such as lanoline, agar and derivant thereof, polyacrylamide, polyvinyl alcohol, polyvinylpyrrolidone, polyoxy second
Alkene, modified paraffin resin, carbomer, polyacrylic acid, Polyacrylate Emulsion, butadiene rubber, butadiene-styrene rubber, poly-ammonia
The organic gold of solvay-type such as ester, modified polyurea, low-molecular polyethylene wax etc. synthesize macromolecule thickener, amino alcohol solvay-type titanate esters
Belong to one or more in compound thickener etc. can be used for dyeing, the thickening agent of printing paste, described dyeing, the viscosity of printing paste
Scope is selected from 500-30000 centipoise.
In described dyeing, printing paste, pH adjusting agent is selected from: citric acid, adipic acid, potassium citrate, lactic acid, fumaric acid, phosphoric acid
The acidity regulators such as hydrogen trisodium, tartaric acid, sodium dihydrogen citrate, malic acid, phosphoric acid, acetic acid, hydrochloric acid, 2-amino-2-methyl-1-third
Alcohol, N-methylethanolamine, monoethanolamine, diethanolamine, triethanolamine, butylethanolamine, N-aminopropyl-methylethanolamine, 2-
Amino-2-ethyl-1,3-PD, butyl diethanolamine etc. has alkanolamine, ammonia, sodium hydroxide, potassium hydroxide, carbonic acid
One or more in the inorganic base regulators such as sodium, potassium carbonate, sodium bicarbonate, potassium bicarbonate etc. can be used for dyeing, printing paste
PH adjusting agent, described dyeing, the pH scope of printing paste are selected from 4-10.
Advantage for present invention:
Present invention dyeing, printing technology technology, use dyeing, printing paste, and the dyes carrying out hydrophobic textile material is coated with
One dyeing or stamp, from source reduce high concentration, the generation of high chroma dyeing waste water, for environmental protection printing and dyeing new product,
New technique.Before stamp the most of the present invention, process is similar to conventional dyes stamp, can pass through cylinder, flat screen printing machine by pulpous state group
Compound printing is in textile material surface.During high temperature color development, most disperse dyes are by molecular separating force and hydrophobic fiber
Material combine, the printing assistant in concentrator while disperse dyes high temperature color development, crosslinking curing film forming, make not with fiber
In conjunction with loose colour adhere to fiber surface.Present invention dyeing, the slurry of printing paste are used for dyeing and the print of hydrophobic textile materials
Spend the advantage that can take into account dyeing, stamp and pigment dyeing, stamp, ensure height distillation, wash and do, fastness to wet rubbing
While, there is again gay colours, soft feel, high during the most also can avoiding tradition disperse dyeing, stamp
The generation of concentration color water, is the disperse dyeing of a kind of clean environment firendly, printing technology.
Present invention dyeing, printing technology wash the wash water COD of textile between 30-2000ppm, part kind ＜
200ppm, part kind ＜ 50ppm；Colourity (extension rate) ＜ 200, part kind colourity (extension rate) ＜ 80, part product
Plant colourity (extension rate) ＜ 30.
Specific implementation method
Below example can make those of ordinary skill in the art that the present invention is more fully understood, but not with any side
Formula limits the present invention.The raw materials used specification of following example is as follows: dyestuff C.I. Disperse Blue-56 is the former powder of commercial dispersants dyestuff, wood
Quality sodium sulfonate, surfactant B C-50, organosilicon modified acrylic ester binding agent SY-8001, ethylene glycol are commercially available industry
Product, water used is deionized water.Device therefor includes:Test-type dispersion machine, resistance to (Shanghai) mechanical device of speeding
Company limited, LHP-0.4 type pottery laboratory horizontal sand mill, Shanghai De Yu mechanical & electronic equipment corporation, Ltd entirely, APV2000 tests
Type high pressure homogenizer, Shanghai are along instrument experimental facilities company limited, and H-TS-III high temperature evaporates baking oven, Asia, Foshan City promise precision optical machinery
Manufacturing Co., Ltd, DH6-9070 electric heating constant-temperature blowing drying box, Yuhua Instrument Co., Ltd., Gongyi City.
The generic condition regulation that stamp process measures according to GB/T 2374-2007 dyeing is carried out, and the process of soaping depends on
Carry out according to GB/T 3921-2008 textile color stability test fastness to soaping, wash as 80 DEG C of water of 1:100-200 bath raio
Washing 5 minutes, dry and use 85 DEG C to dry 10 minutes, decatize employing high temperature evaporates baking oven to be carried out, and bakees and uses electric heating forced air drying
Case is carried out.
Dyeing, printing paste preparation process as follows:
(1) dyeing, the preparation of print paste B-1
Surfactant B C-50 45g, sodium lignin sulfonate 50g, ethylene glycol 30g and water 525g are joined dispersion tank
In, after dispersion stirring makes it the most molten, it is added thereto to C.I. Disperse Blue-56 former powder 350g, starts dispersion machine, high speed dispersion 2 hours
After, dispersion pulp is squeezed into horizontal sand mill and is circulated grinding, milling time 10 hours, slurry grinding obtained after grinding
Material homogenize 2 times through high pressure homogenizer, obtain blue dyes dyeing, print paste B-1 1000g, fineness d50≤0.5 μm,
PH=6.8.
(2) dyeing, the preparation of printing assistant
By deionized water 227g, join in dispersion tank, open dispersion machine, under stirring at low speed, add in dispersion tank successively
Enter surfactant FC-1 15g, penetrating agent SA-50 30g, diffusant WAX 28g, silicone softening agent 208C 55g, crosslinking
Agent CLA-80 45g, organosilicon modified acrylic ester binding agent SY-800 600g, add each raw material, dispersion stirring 30 minutes.?
To dyeing, printing assistant Z-1 1000g, pH=6.7, viscosity 1300mPa.S (NDJ-1 type rotor viscometer, 2# rotor, 12r/
min)。
(3) dyeing, the preparation of stamp concentrated pulp B-1
The dyeing, the print paste 500g that step (1) are prepared join in dispersion machine dispersion tank, slowly add under stirring
Enter dyeing, printing assistant Z1 500g, dyeed after stirring, stamp concentrated pulp B-1, pH=6.7, viscosity 1550mPa.S
(NDJ-1 type rotating cylinder viscometer, 2# rotor, 12r/min).
(4) dyeing, the preparation of printing paste B-1
By in deionized water 960g water, add in dispersion machine dispersion tank, start and be slowly added under dispersion machine, high-speed stirred increase
Thick dose of PF 20g, is stirring evenly and then adding into dyeing, stamp concentrated pulp B-1 20g, and dispersion is dyeed after stirring, printing paste
B-1 1000g, viscosity 2520mPa.S (NDJ-1 rotating cylinder viscometer, 3# rotor, 30r/min)
The dyeing of other heterogeneity, printing paste, according to the composition of above-mentioned record, prepare according to above-mentioned preparation process.
Embodiment 1
Using the dyes prepared to be coated with one dyeing and printing mill base B-1 and carry out stamp, specific embodiment is as follows:
The work of textile → stamp → drying → decatize → wash → soap → wash → dry → arrange → stamp finished product
Skill process, wherein steam temperature is 180 DEG C, and steaming time is 5 minutes；
Embodiment 2
Using the dyes prepared to be coated with one dyeing and printing mill base B-1 and carry out stamp, specific embodiment is as follows:
The technical process of textile → stamp → drying → decatize → washing → drying → arrangement → stamp finished product, wherein vapour
Steaming temperature is 180 DEG C, and steaming time is 5 minutes；
Embodiment 3
Using the dyes prepared to be coated with one dyeing and printing mill base B-1 and carry out stamp, specific embodiment is as follows:
The technical process of textile → stamp → drying → decatize → arrangement → stamp finished product, wherein steam temperature is 180
DEG C, steaming time is 5 minutes；
Embodiment 4
Using the dyes prepared to be coated with one dyeing and printing mill base B-1 and carry out stamp, specific embodiment is as follows:
The work of textile → stamp → dry → bakee → wash → soap → wash → dry → arrange → stamp finished product
Skill process, wherein stoving temperature is 180 DEG C, and the baking time is 5 minutes；
Embodiment 5
Using the dyes prepared to be coated with one dyeing and printing mill base B-1 and carry out stamp, specific embodiment is as follows:
The technical process of textile → stamp → drying → baking → washing → drying → arrangement → stamp finished product, wherein dries
Roasting temperature is 180 DEG C, and the baking time is 5 minutes；
Embodiment 6
Using the dyes prepared to be coated with one dyeing and printing mill base B-1 and carry out stamp, specific embodiment is as follows:
The technical process of textile → stamp → drying → baking → arrangement → stamp finished product, wherein stoving temperature is 180
DEG C, the baking time is 5 minutes；
Embodiment 7-24
Using the dyes prepared to be coated with one dyeing and printing mill base B-1 and carry out stamp, specific embodiment is as follows:
The work of textile → stamp → drying → decatize → wash → soap → wash → dry → arrange → stamp finished product
Skill process, wherein steam temperature and steaming time such as following table；
Each embodiment stamp to stamp finished product to carry out every application test result as follows:
The washing of each embodiment, soap water COD and colourity:
Claims (10)
1. a dyeing, printing technology method, it is characterised in that: technical process is successively through stamp → baking by pending textile
Dry → color development → post processing, and then obtain stamp finished product；Wherein, color development can the most scrubbed and drying with arrangement interprocedual；Described
Color development temperature is 160-210 DEG C；The color development time is 1-30 minute；
Described color development uses decatize or the mode of baking；Described washing can use washing repeatedly and/or mode of soaping；After described
Processing procedure can use wash → soap → wash → dry → arrange, wash → dry → arrange or individually arrange.
2. a kind of dyeing, printing technology method as described in claim 1, it is characterised in that: described technique is pending textile
Successively through stamp → drying → decatize → wash → soap → wash → dry → arrange, and then obtain stamp finished product；Wherein vapour
Steaming temperature and be 160-210 DEG C, steaming time is 1-30 minute.
3. a kind of dyeing, printing technology method as described in claim 1, it is characterised in that: described technique is pending textile
Successively through stamp → drying → decatize → washing → drying → arrangement, and then obtain stamp finished product；Wherein steam temperature is 160-
210 DEG C, steaming time is 1-30 minute.
4. a kind of dyeing, printing technology method as described in claim 1, it is characterised in that: described technique is pending textile
Successively through stamp → drying → decatize → arrangement, and then obtaining stamp finished product, wherein steam temperature is 160-210 DEG C, during decatize
Between be 1-30 minute.
5. a kind of dyeing, printing technology method as described in claim 1, it is characterised in that: described technique is pending textile
Successively through stamp → dry → bakee → wash → soap → wash → dry → arrange, and then obtain stamp finished product, wherein dry
Roasting temperature is 160-210 DEG C, and the baking time is 1-30 minute.
6. a kind of dyeing, printing technology method as described in claim 1, it is characterised in that: described technique is pending textile
Successively through stamp → drying → baking → washing → drying → arrangement, and then obtaining stamp finished product, stoving temperature is 160-210
DEG C, the baking time is 1-30 minute.
7. a kind of dyeing, printing technology method as described in claim 1, it is characterised in that: described technique is pending textile
Successively through stamp → drying → baking → arrangement, and then obtaining stamp finished product, wherein stoving temperature is 160-210 DEG C, during baking
Between be 1-30 minute.
8. dyeing as described in claim 1-7 any one, printing technology method, it is characterised in that: described decatize or baking
Temperature is 160-190 DEG C, and decatize or baking time are 1-10 minute.
9. dyeing as described in claim 1-7 any one, printing technology method, it is characterised in that: described color development uses
Dyeing, printing paste, its composition by weight percentage, adjust by dyeing, stamp concentrated pulp 1-25%, thickening agent 0.5-10%, pH value
Joint agent 0.05-3% and water 62-98.45%.
10. dyeing as described in claim 9, printing technology method, it is characterised in that: described dyeing, stamp concentrated pulp are by weight
Amount percentages, the dyeing of the dyeing of 20-80%, print paste and 20-80%, printing assistant；Described dyeing, print paste are
By the filter cake of disperse dyes or dry powder are made into slurry with auxiliary agent together with water, then by refinement, it is prepared into.
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| CN106498771A (en) * | 2016-11-17 | 2017-03-15 | 无锡奔牛生物科技有限公司 | A kind of human body affinity fabric dyeing toner |
| CN107227615A (en) * | 2017-08-07 | 2017-10-03 | 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 | A kind of needlework and preparation method thereof |
| CN107385718A (en) * | 2017-08-07 | 2017-11-24 | 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 | A kind of Miao ethnic group's embroidery dress ornament and preparation method thereof |
| KR101926624B1 (en) | 2017-11-07 | 2018-12-07 | 태흥디앤씨주식회사 | Blue dye composition having high color fastness for modificated polypropylene fabrics |
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| CN111019393A (en) * | 2019-12-25 | 2020-04-17 | 沈阳化工研究院有限公司 | Yellow liquid dye composition for dyeing and printing and application thereof |
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| CN106498771A (en) * | 2016-11-17 | 2017-03-15 | 无锡奔牛生物科技有限公司 | A kind of human body affinity fabric dyeing toner |
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| CN107385718A (en) * | 2017-08-07 | 2017-11-24 | 贵州凯里经济开发区鑫田民族服饰工艺品发展有限公司 | A kind of Miao ethnic group's embroidery dress ornament and preparation method thereof |
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| KR101926624B1 (en) | 2017-11-07 | 2018-12-07 | 태흥디앤씨주식회사 | Blue dye composition having high color fastness for modificated polypropylene fabrics |
| CN109457505A (en) * | 2018-10-24 | 2019-03-12 | 江苏华东纺织产品检测有限公司 | A kind of square screen printing process of fleece |
| CN110777549B (en) * | 2019-11-11 | 2022-05-17 | 佛山市乐印涂料有限公司 | Microcapsule slow-release cross-linking agent mucilage and preparation method and application thereof |
| CN110777549A (en) * | 2019-11-11 | 2020-02-11 | 佛山市乐印涂料有限公司 | Microcapsule slow-release cross-linking agent mucilage and preparation method and application thereof |
| CN111019393A (en) * | 2019-12-25 | 2020-04-17 | 沈阳化工研究院有限公司 | Yellow liquid dye composition for dyeing and printing and application thereof |
| CN111019393B (en) * | 2019-12-25 | 2022-02-11 | 沈阳化工研究院有限公司 | Yellow liquid dye composition for dyeing and printing and application thereof |
| WO2021196103A1 (en) * | 2020-04-01 | 2021-10-07 | 南通纺织丝绸产业技术研究院 | Water-based nano disperse dye useful for softening finishing and use thereof |
| CN112981983A (en) * | 2021-04-01 | 2021-06-18 | 浙江大能纺织印染有限公司 | Liquid disperse dye capable of reducing COD (chemical oxygen demand) discharge and preparation method and dyeing method thereof |
| CN113683904A (en) * | 2021-08-31 | 2021-11-23 | 沈阳化工研究院有限公司 | Red dye composition for dyeing and printing |
| CN113683904B (en) * | 2021-08-31 | 2023-06-13 | 沈阳化工研究院有限公司 | Red dye composition for dyeing and printing |
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