CN105884427A - Improved acidified soil water-retention compound fertilizer and preparation method thereof - Google Patents

Improved acidified soil water-retention compound fertilizer and preparation method thereof Download PDF

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Publication number
CN105884427A
CN105884427A CN201610249665.5A CN201610249665A CN105884427A CN 105884427 A CN105884427 A CN 105884427A CN 201610249665 A CN201610249665 A CN 201610249665A CN 105884427 A CN105884427 A CN 105884427A
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parts
water
compound fertilizer
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张楚沁
张朝晖
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C9/00Fertilisers containing urea or urea compounds
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/30Layered or coated, e.g. dust-preventing coatings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Soil Sciences (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses an improved acidified soil water-retention compound fertilizer and a preparation method thereof. The improved acidified soil water-retention compound fertilizer is prepared from, by weight, 20-23 parts of urea, 3-4 parts of an EM fungicide, 20-22 parts of biogas residues, 6-8 parts of silkworm excrement, 8-10 parts of lignite, 18-22 parts of sodium humate, 12-15 parts of potassium dihydrogen phosphate, 12-13 parts of chitosan, 8-10 parts of smoke slag, 20-30 parts of tea tree waste, 1-2 parts of antibiotics, 6-8 parts of bentonite, 4-6 parts of boron mud, 6-8 parts of blast furnace slag, 6-9 parts of polylactic acid, 8-12 parts of rosin pentaerythritol ester, 0.5-1 part of N,N-methylene bisacrylamide and a proper amount of water. The boron mud, the bentonite and other ingredients are added to the improved acidified soil water-retention compound fertilizer, alkaline ingredients are increased, meanwhile the power of hydrogen is isolated and buffered, the acid-base equilibrium of soil is regulated, accordingly acidified soil can be effectively improved, and soil fertility is improved.

Description

A kind of improvement acidified soil water-holding compound fertilizer material is fertile and preparation method thereof
Technical field
The present invention relates to slow release fertilizer technical field, particularly relate to a kind of improvement acidified soil water-holding compound fertilizer material fertilizer and preparation method thereof.
Background technology
At present, China market agricultural fertilizer material, substantially there are three kinds: a kind of fertile for industrial chemicals, one is fertilizer, also having one is industrial chemicals and organic fertilizer mixing fertilizer;The shortcoming of industrial chemicals: life-time service can cause soil soil property to harden, and affects plant growth, causes the progressively underproduction;The shortcoming of organic fertilizer is: needed for plant, nutrient is not enough, can not meet the demand of production estimation;Affect crop yield;The shortcoming that mixing is fertile: organic matter and full nutrient in fertilizer formula are conflicting, this is high, and that are low, such as organic too high levels, produce granule difficulty.Additionally; China's Arid&semi-arid area gross area accounts for the 50% of territory total area; China's agricultural is again to use water rich and influential family; Water Consumption in Agriculture exceedes the 70% of total water consumption; and production efficiency is the lowest; China's annual agricultural water breach is about at 30,000,000,000 m 3, and agricultural water crisis presents and constantly aggravates situation.Water-loss reducer of soil is used alone not only increases work number of times and cost, and because water-loss reducer of soil consumption is the most less, it is difficult to be fully contacted with fertilizer so that received moisture is difficult to and nutritional labeling generation reciprocal action, largely reduces effect of water-retaining agent.Additionally, the common fertilizer water solublity used at present is the highest, rate of release is very fast, and the release phase is shorter, and uses totally basal dressing techniques more, make fertilizer nutrient rate of release poor with crop regulation of fertilizer requirement synchronicity, fertilizer nutrient loss is very big, and fertilizer nutrient utilization is relatively low, though and split application method can improve crop different growing nutrient demand, but time-consuming, it is not suitable with the requirement of modern agriculture high-efficient development.And, the fertilizer efficiency height in being manured into soil is in close relations with soil water regime, and " with fertile water transfer, promoting fertilizer with water " is highly important rich water control technique in agricultural production.
Mulch film has the effects such as insulation, water conservation, frost protection to crop, the application of ground membrane technology improves and yield and the benefit adding crops greatly, but tradition mulch film is the macromolecular compound of a kind of synthetic, degradable the most hardly, after using, place to go is not comprehended soil environment is caused the biggest pollution, affects crop root growth, and the mulch film processed is because of moist, damaged, the most not reusable edible, only as garbage reclamation, work consuming is time-consuming.
Therefore, being modified fertilizer, improving fertilizer efficiency is to reduce fertilizer use, the effective way increased operation rate.Slow-release or control-release fertilizer is exactly one of effective measures improving chemical fertilizer utilization ratio such as at present, slow-release or control-release fertilizer can efficiently control the release of nutrient, extend fertilizer efficiency period, meets utilization rate that the whole period of duration of crop to the needs of fertilizer nutrient, can improve fertilizer to greatest extent, reduces the wasting of resources and environmental pollution, to promoting agriculture and forestry volume increase, increasing peasant income, agriculture and forestry sustainable development important role, it it is the important development direction of 21 century fertilizer industry.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of improvement acidified soil water-holding compound fertilizer material is fertile and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of improvement acidified soil water-holding compound fertilizer material, it is prepared by the raw materials in: carbamide 20-23, EM microbial inoculum 3-4, biogas residue 20-22, Bombyx mori L. 6-8, brown coal 8-10, sodium humate 18-22, potassium dihydrogen phosphate 12-15, chitosan 12-13, scarp 8-10, Camellia sinensis waste residue 20-30, antibiotics 1-2, bentonite 6-8, boron mud 4-6, blast-furnace cinder 6-8, polylactic acid 6-9, pentalyn 8-12, N,N methylene bis acrylamide 0.5-1, water are appropriate.
The preparation method of described improvement acidified soil water-holding compound fertilizer material, comprises the following steps:
(1), brown coal, biogas residue are dried and be ground to the mixing of 150-200 mesh, the 1.5-2 times of water taking mixed-powder weight adds in reactor, add mixed-powder and appropriate potassium permanganate is formulated as 4-8% potassium permanganate solution, stirring oxidation 40-60 minute, is heated to 90-100 DEG C, adds the potassium hydroxide of solution weight part 0.2-0.5%, stir 25-40 minute at 2000-2200rpm high speed machine, centrifugation, it is 50-60% that filtrate is concentrated into moisture content, and filtering residue is stand-by;
(2), by step (1) concentrated solution and pentalyn, N, N-methylene-bisacrylamide mix and blend, react 20-30 minute at being heated with stirring to 40-50 DEG C, by carbamide, antibiotics mixed grinding to 60-80 mesh, add suitable quantity of water stirring and melt, with reactant liquor mix and blend, join in drying oven, drying 1-2 hour at 80-88 DEG C, cooling crush crosses 200 mesh sieves, standby;
(3), filtering residue, bentonite, blast-furnace cinder mixed grinding are crossed 200 mesh sieves, put into 1-2 hour processed of stirring leaching in the citric acid solution of 0.1-0.2mol/L, standing removes liquid, oven drying at low temperature, bakes 40-60 minute at 350-400 DEG C, and discharging spray profit steam extinguishes cooling to powder body, add 3-5 times of water stirring to suspended shape, adding polylactic acid, high pressure homogenize stirs, and obtains coating liquid;
(4), sodium humate, boron mud, potassium dihydrogen phosphate are mixed, and add the water mixing and stirring of gross weight 3-4 times, obtain nutritional solution;
(5), by Bombyx mori L., scarp, Camellia sinensis waste residue co-grinding, add after the water of nutritional solution, EM microbial inoculum and gross weight 0.3-0.5 times stirs afterwards, fermentation 30-40 days of banking up at 32-38 DEG C, stand-by;
(6), fermentation material is crushed to 80-100 mesh; add chitosan mix and blend; adjustment moisture is gross weight 42-45%; the ball-type fertiliser granulates of granulator granulation diameter 1-1.2mm; that places band high-pressure nozzle and air cooking rolls on fluid bed at high temperature; coating liquid step (3) obtained repeats to be sprayed at ball-type fertiliser granulates uniformly 3-5 time by high-pressure nozzle; send into tumbling disk granulator; it is simultaneously introduced step (2) and bakes powder; after granulating and forming; within dry 8-10 hour, cool down at 48-50 DEG C, packed and get final product.
The invention have the advantage that
(1) present invention improves the acidified soil water-holding compound fertilizer material interpolation composition such as boron mud, bentonite, improves alkaline components, simultaneously isolation buffer acid-base value, regulates soil acid-base equilibrium such that it is able to effectively improve acidified soil, increase soil fertility.
(2) present invention improves acidified soil water-holding compound fertilizer material and is also added with conventional bacterial manure and inorganic fertilizer works in coordination with microbial activity composition, use multilayer coating structure release structures, external sheath liquid-state mulch film functional component, not only there is the sustained release performance of nutrition release, serve again water retention, can be that soil provides carbon after degraded, the multiple resources such as nitrogen, stimulate growth and development of plants simultaneously, increase the resistance of crop, improve effect of the nutriture of plant, collaborative internal layer bioactive ingredients, improve Soil structure further, give full play to fertilizer efficiency, promote plant growing, improve crop yield.
Detailed description of the invention
Embodiment 1
A kind of improvement acidified soil water-holding compound fertilizer material, it is made up of the raw material of following weight (kg): carbamide 20, EM microbial inoculum 3, biogas residue 20, Bombyx mori L. 6, brown coal 8, sodium humate 18, potassium dihydrogen phosphate 12, chitosan 12, scarp 8, Camellia sinensis waste residue 20, antibiotics 1, bentonite 6, boron mud 4, blast-furnace cinder 6, polylactic acid 6, pentalyn 8, N,N methylene bis acrylamide 0.5, water are appropriate.
The preparation method of described improvement acidified soil water-holding compound fertilizer material, comprises the following steps:
(1), brown coal, biogas residue are dried and be ground to 200 mesh mixing, the 2 times of water taking mixed-powder weight add in reactor, add mixed-powder and appropriate potassium permanganate is formulated as 6% potassium permanganate solution, stirring oxidation 60 minutes, is heated to 90 DEG C, adds the potassium hydroxide of solution weight part 0.5%, stir 30 minutes at 2200rpm high speed machine, centrifugation, it is 50% that filtrate is concentrated into moisture content, and filtering residue is stand-by;
(2), by step (1) concentrated solution and pentalyn, N, N-methylene-bisacrylamide mix and blend, it is heated with stirring at 50 DEG C reaction 30 minutes, by carbamide, antibiotics mixed grinding to 80 mesh, add suitable quantity of water stirring and melt, with reactant liquor mix and blend, join in drying oven, drying 2 hours at 88 DEG C, cooling crush crosses 200 mesh sieves, standby;
(3), filtering residue, bentonite, blast-furnace cinder mixed grinding are crossed 200 mesh sieves, put into stirring leaching system 2 hours in the citric acid solution of 0.1mol/L, standing removes liquid, oven drying at low temperature, bakes 50 minutes at 360 DEG C, and discharging spray profit steam extinguishes cooling to powder body, add 5 times of water stirrings to suspended shape, adding polylactic acid, high pressure homogenize stirs, and obtains coating liquid;
(4), sodium humate, boron mud, potassium dihydrogen phosphate are mixed, and add the water mixing and stirring of gross weight 3 times, obtain nutritional solution;
(5), by Bombyx mori L., scarp, Camellia sinensis waste residue co-grinding, add after the water of nutritional solution, EM microbial inoculum and gross weight 0.3-times stirs afterwards, fermentation 40 days of banking up at 35 DEG C, stand-by;
(6), fermentation material is crushed to 100 mesh; add chitosan mix and blend; adjusting moisture is gross weight 45%, the ball-type fertiliser granulates of granulator granulation diameter 1.2mm, and that places band high-pressure nozzle and air cooking rolls on fluid bed at high temperature; coating liquid step (3) obtained is repeated 5 times by high-pressure nozzle and is sprayed at ball-type fertiliser granulates uniformly; send into tumbling disk granulator, be simultaneously introduced step (2) and bake powder, after granulating and forming; it is dried cooling in 10 hours at 50 DEG C, packed and get final product.
Embodiment 2
A kind of improvement acidified soil water-holding compound fertilizer material, it is made up of the raw material of following weight (kg): carbamide 22, EM microbial inoculum 3, biogas residue 21, Bombyx mori L. 7, brown coal 9, sodium humate 20, potassium dihydrogen phosphate 14, chitosan 12, scarp 9, Camellia sinensis waste residue 25, antibiotics 2, bentonite 7, boron mud 5, blast-furnace cinder 7, polylactic acid 8, pentalyn 10, N,N methylene bis acrylamide 0.8, water are appropriate.
The preparation method of described improvement acidified soil water-holding compound fertilizer material, with embodiment 1.
Embodiment 3
A kind of improvement acidified soil water-holding compound fertilizer material, it is made up of the raw material of following weight (kg): carbamide 23, EM microbial inoculum 4, biogas residue 22, Bombyx mori L. 8, brown coal 10, sodium humate 22, potassium dihydrogen phosphate 15, chitosan 13, scarp 10, Camellia sinensis waste residue 30, antibiotics 2, bentonite 8, boron mud 6, blast-furnace cinder 8, polylactic acid 6-9, pentalyn 12, N,N methylene bis acrylamide 1, water are appropriate.
The preparation method of described improvement acidified soil water-holding compound fertilizer material, with embodiment 1.
Take the wheat paddock that two pieces of areas are 5 mu, be divided into matched group and experimental group.Matched group uses commercially available common slow-release fertilizer, use Wheat in Field good luster, plant health that the improvement acidified soil water-holding compound fertilizer material of the present invention is fertile, the speed of growth is the most very fast, wheat grain after maturation is golden yellow full, yield increases, compared with the farmland not using product of the present invention, every mu is increased production 106 kilograms, and uses the pest and disease damage in the farmland of product of the present invention also to greatly reduce.
From the above-mentioned improvement acidified soil water-holding compound fertilizer material fertilizer that the present invention can be described can not only preventing disease and pest effectively, and this Fertilizer nutrient equilibrium, it is possible to promote that crops more preferably grow, improve soil environment, improve crop yield.

Claims (2)

1. an improvement acidified soil water-holding compound fertilizer material, it is characterized in that, it is prepared by the raw materials in: carbamide 20-23, EM microbial inoculum 3-4, biogas residue 20-22, Bombyx mori L. 6-8, brown coal 8-10, sodium humate 18-22, potassium dihydrogen phosphate 12-15, chitosan 12-13, scarp 8-10, Camellia sinensis waste residue 20-30, antibiotics 1-2, bentonite 6-8, boron mud 4-6, blast-furnace cinder 6-8, polylactic acid 6-9, pentalyn 8-12, N,N methylene bis acrylamide 0.5-1, water are appropriate.
2. the preparation method of an improvement acidified soil water-holding compound fertilizer material as claimed in claim 1, it is characterised in that comprise the following steps:
(1), brown coal, biogas residue are dried and be ground to the mixing of 150-200 mesh, the 1.5-2 times of water taking mixed-powder weight adds in reactor, add mixed-powder and appropriate potassium permanganate is formulated as 4-8% potassium permanganate solution, stirring oxidation 40-60 minute, is heated to 90-100 DEG C, adds the potassium hydroxide of solution weight part 0.2-0.5%, stir 25-40 minute at 2000-2200rpm high speed machine, centrifugation, it is 50-60% that filtrate is concentrated into moisture content, and filtering residue is stand-by;
(2), by step (1) concentrated solution and pentalyn, N, N-methylene-bisacrylamide mix and blend, react 20-30 minute at being heated with stirring to 40-50 DEG C, by carbamide, antibiotics mixed grinding to 60-80 mesh, add suitable quantity of water stirring and melt, with reactant liquor mix and blend, join in drying oven, drying 1-2 hour at 80-88 DEG C, cooling crush crosses 200 mesh sieves, standby;
(3), filtering residue, bentonite, blast-furnace cinder mixed grinding are crossed 200 mesh sieves, put into 1-2 hour processed of stirring leaching in the citric acid solution of 0.1-0.2mol/L, standing removes liquid, oven drying at low temperature, bakes 40-60 minute at 350-400 DEG C, and discharging spray profit steam extinguishes cooling to powder body, add 3-5 times of water stirring to suspended shape, adding polylactic acid, high pressure homogenize stirs, and obtains coating liquid;
(4), sodium humate, boron mud, potassium dihydrogen phosphate are mixed, and add the water mixing and stirring of gross weight 3-4 times, obtain nutritional solution;
(5), by Bombyx mori L., scarp, Camellia sinensis waste residue co-grinding, add after the water of nutritional solution, EM microbial inoculum and gross weight 0.3-0.5 times stirs afterwards, fermentation 30-40 days of banking up at 32-38 DEG C, stand-by;
(6), fermentation material is crushed to 80-100 mesh; add chitosan mix and blend; adjustment moisture is gross weight 42-45%; the ball-type fertiliser granulates of granulator granulation diameter 1-1.2mm; that places band high-pressure nozzle and air cooking rolls on fluid bed at high temperature; coating liquid step (3) obtained repeats to be sprayed at ball-type fertiliser granulates uniformly 3-5 time by high-pressure nozzle; send into tumbling disk granulator; it is simultaneously introduced step (2) and bakes powder; after granulating and forming; within dry 8-10 hour, cool down at 48-50 DEG C, packed and get final product.
CN201610249665.5A 2016-04-21 2016-04-21 Improved acidified soil water-retention compound fertilizer and preparation method thereof Pending CN105884427A (en)

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CN106433650A (en) * 2016-09-27 2017-02-22 吉林农业大学 Acid soil conditioner
CN106748327A (en) * 2017-03-06 2017-05-31 宿州瑞泰农业发展有限公司 A kind of vegetable cultivation fertilizer suitable for acidified soil
CN108218613A (en) * 2017-12-21 2018-06-29 南京信息工程大学 A kind of compound fertilizer and its preparation and application of long-acting type improvement acidified soil

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106433650A (en) * 2016-09-27 2017-02-22 吉林农业大学 Acid soil conditioner
CN106748327A (en) * 2017-03-06 2017-05-31 宿州瑞泰农业发展有限公司 A kind of vegetable cultivation fertilizer suitable for acidified soil
CN108218613A (en) * 2017-12-21 2018-06-29 南京信息工程大学 A kind of compound fertilizer and its preparation and application of long-acting type improvement acidified soil

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Application publication date: 20160824