CN105734963B - Contain cotton knitted fabric and its preparation method with gloss as silk, feel and cool feeling - Google Patents

Contain cotton knitted fabric and its preparation method with gloss as silk, feel and cool feeling Download PDF

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Publication number
CN105734963B
CN105734963B CN201610270347.7A CN201610270347A CN105734963B CN 105734963 B CN105734963 B CN 105734963B CN 201610270347 A CN201610270347 A CN 201610270347A CN 105734963 B CN105734963 B CN 105734963B
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fabric
yarn
silk
cotton
circular knitting
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CN105734963A (en
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李桦
徐春川
周立明
张玉高
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Guangdong Esquel Textiles Co Ltd
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Guangdong Esquel Textiles Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04B—KNITTING
    • D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/10—Patterned fabrics or articles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C15/00—Calendering, pressing, ironing, glossing or glazing textile fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165—Ethers
    • D06M13/17—Polyoxyalkyleneglycol ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/06—Load-responsive characteristics
    • D10B2401/062—Load-responsive characteristics stiff, shape retention
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00—Physical properties
    • D10B2401/20—Physical properties optical

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention provides it is a kind of have gloss as silk, feel and cool feeling containing cotton knitted fabric and preparation method thereof.This method comprises the following steps：Yarn is made into fabric with circular knitting machine；Wherein, the pin number of the circular knitting machine is 18 40, and the yarn count of the yarn is 20S/1 80S/1, a length of 50C=90mm 200mm of yarn of the yarn, and the grammes per square metre of the fabric is 60 240g/m2, the institutional framework of the fabric with including plain weave, pearl, cotton wool, rib-loop, looped pile, ball woll or jacquard weave；Open width is alkali mercerized, kiering；Enzyme is washed；Dyeing, drying；Softness sizing is arranged；Preshrunk is handled, and is finally given and is contained cotton knitted fabric with gloss as silk, feel and cool feeling.The cotton knitted fabric that contains with gloss, feel and cool feeling as silk that the present invention is provided has the characteristics of smooth, well-pressed, drapability is good, while also having the advantages that crease-resistant, shrink is small, has accomplished smooth, well-pressed, crease-resistant comprehensive unification.

Description

Contain cotton knitted fabric and its preparation method with gloss as silk, feel and cool feeling
Technical field
It is more particularly to a kind of that there is gloss, feel as silk the present invention relates to a kind of preparation method containing cotton knitted fabric With cool feeling containing cotton knitted fabric and preparation method thereof.
Background technology
Cotton fiber is well received by consumers always because of its natural, soft, comfortable advantage.Recently as weaving dye Whole field process technology is continued to develop, and exploitation is trend of the times with high added value, the cotton product of particular appearance feel class. Wherein, bafta being accomplished to, gloss, smooth fabric as similar silk are exactly one of product of wherein great market focus.
In order that cotton fabrics obtain common practice in smooth, gloss as similar silk, pendency effect, industry be by Pure-cotton fabric is washed by mercerising, enzyme, soft heat treatment.Wherein：Mercerising be by concentrated base effect be bafta occur it is irreversible It is swelled, the gloss as providing cotton fabric silk, while increasing the stiffness of fabric；The effect that enzyme is washed is to cotton using cellulase Cellulosic molecule is catalytically decomposed, and is degraded to glucose, it is therefore an objective to remove the unnecessary filoplume of surface of cotton fabric, improves fabric table The cleanliness factor and gloss inverse degree in face, make bafta look more clean, light；The effect of softness sizing is to utilize macromolecular Silicone oil softening agent is arranged in fixating shape step to bafta, and the pliability and smooth degree of bafta are improved emphatically, and lifting is knitted The sense of touch of thing.
CN102505404A《A kind of trimming process of double-mercerized cotton knitted silk-like fabric》Disclose and pass through mercerized cotton looped fabric Cross and singe, mercerising, boil after drift, ferment treatment, pre- soft, Final finishing, obtain the mercerized cotton looped fabric of silk like fabric effect.This method knot Singeing, double mercerizations, cellulase treatment and postfinishing process have been closed, but has not been ground in terms of face weave is knitted Study carefully, if using too thick and heavy or result too loose fabric, the effect worked it out will not be highly desirable.In addition, mariages light also increases Production process and production cost.
《The silk like fabric for being knitted mercerized cotton is arranged》Disclose using cellulase pre-treatment and silicone oil postfinishing process, to enzyme Processing time, temperature, silicon oil dosage, bake time, baking temperature and be optimized, obtain the imitative of optimal knitting mercerized cotton Fabric has the soft smooth of similar silk broadcloth after silk technique, arrangement, but does not have mercerization finish, its gloss and silk in flow Still have a long way to go；And housekeeping liquid is not improved during silicone oil Final finishing, but uses single silicone oil Handled so that the drapability and smooth degree and silk of fabric also have certain gap.
The product that above-mentioned prior art can be obtained with gloss, smooth cotton fabrics as silk with having certain phase Like degree, but closer effect can not be obtained in terms of drapability, feel, gloss, cool feeling all the time.
The content of the invention
In order to solve the above technical problems, there is gloss, feel and cool feeling as silk it is an object of the invention to provide one kind Contain cotton knitted fabric, the fabric possesses gloss, feel and the cool feeling as silk.
To reach above-mentioned purpose, the invention provides a kind of knitted side containing cotton with gloss, feel and cool feeling as silk The preparation method of material, it comprises the following steps：
Step 1: yarn is made into fabric with circular knitting machine；Wherein, the pin number of the circular knitting machine is 18-40, the yarn Yarn count be 20S/1-80S/1, a length of 50C=90mm-200mm of yarn of the yarn, the grammes per square metre of the fabric is 60-240g/ m2, the institutional framework of the fabric with including plain weave, pearl, cotton wool, rib-loop, looped pile, ball woll or jacquard weave；
Step 2:, kiering alkali mercerized to fabric progress open width；
Washed Step 3: carrying out enzyme to the fabric after alkali mercerized using cellulase；
Step 4: the fabric after being washed to enzyme is dyed, dried, the cloth specimen after being dried；
Arranged Step 5: carrying out soft sizing to the cloth specimen after drying；Wherein, the raw material group of the soft sizing dressing liquid Into including resin, amido silicon oil and modified silicon oil；
Step 6: the cloth specimen after being arranged to soft sizing carries out preshrunk processing, obtain with gloss as silk, feel and cool That feels contains cotton knitted fabric.
Present invention research finds that suitable knitting and fabric design are most important to the sense of touch effect of finished product fabric：It is suitable Conjunction makees the fabric yarn count with silky handle and gloss for 20S/1-80S/1, and pin number too low (being less than 18 pins), yarn length are too big (50C>200mm), loop construction is loose, and the fabric being made into is excessively soft, is unfavorable for forming preferable well-pressed degree；Pin number is too high (being more than 40 pins), the too small (50C of yarn length<90mm), coil too closely, easily forms knitting broken hole fault, influences production efficiency, In addition, the institutional framework of fabric is also critically important, the institutional framework that the present invention is provided is beneficial to obtain the smooth fabric of cloth cover, makes final Fabric obtain preferable effect；The fabric that pin number, yarn count, yarn length and the fabric institutional framework provided using the present invention is obtained, Close structure, cloth cover is without fault and well-pressed degree is excellent；At the same time, the technical scheme that the present invention is provided is in actual production process Loom efficiency is disclosure satisfy that, possesses producing feasibility.
In the above-mentioned methods, it is preferable that in step one, when the institutional framework of the fabric is plain weave, the circular knitting machine Pin number be 20-40 pins, the yarn count of the yarn is 20S/1-80S/1, a length of 50C=90mm-200mm of yarn, the fabric Grammes per square metre is 60-200g/m2；It is highly preferred that the pin number of the circular knitting machine is 28-36 pins, the yarn count of the yarn is 30S/1- 60S/1, more preferably 30S/1-50S/1, a length of 50C=100mm-130mm of yarn, the grammes per square metre of the fabric is 110- 160g/m2。
In the above-mentioned methods, it is preferable that in step one, when the institutional framework of the fabric is jacquard weave, the circular knitting machine Pin number be 28-36 pins, the yarn count of the yarn is 30S/1-50S/1, a length of 50C=100mm-130mm of yarn, the fabric Grammes per square metre is 110-160g/m2。
In the above-mentioned methods, it is preferable that in step one, the institutional framework of the fabric be pearl when, the circular knitting machine Pin number be 18-28 pins, the yarn count of the yarn is 20S/1-50S/1, a length of 50C=100mm-170mm of yarn, the fabric Grammes per square metre is 90-200g/m2；It is highly preferred that the pin number of the circular knitting machine is 24-28 pins, the yarn count of the yarn is 30S/1- 40S/1, a length of 50C=110mm-130mm of yarn, the grammes per square metre of the fabric is 120-170g/m2。
In the above-mentioned methods, it is preferable that in step one, when the institutional framework of the fabric is cotton wool, the circular knitting machine Pin number be 18-40 pins, the yarn count of the yarn is 30S/1-80S/1, a length of 50C=105mm-200mm of yarn, the fabric Grammes per square metre is 90-240g/m2；Preferably, the pin number of the circular knitting machine is 24-36 pins, and the yarn count of the yarn is 40S/1-70S/ 1, a length of 50C=105mm-140mm of yarn, the grammes per square metre of the fabric is 130-190g/m2。
In the above-mentioned methods, it is preferable that in step one, the institutional framework of the fabric is plain weave, using the knot of tissue The well-pressed effect of fabric cloth cover that structure is made into is best, especially the best results of plain weave single jersey.
In the above-mentioned methods, it is preferable that in step 2, the concentration of the alkali is 20-32Be, the concentration of silkete penetrating agent For 1-5g/L, the speed of open width mercerizing machine is 5-20m/min；It is highly preferred that the concentration of the alkali is 24-32Be, mercerising infiltration The concentration of agent is 3-5g/L, and the speed of open width mercerizing machine is 10-15m/min.
Present invention research finds that the concentration of alkali in mercerization has vital shadow to the luster effect of finished product fabric Ring, the luster effect of the high-alkali dense relatively low dense acquisition of alkali more preferably, can make finished product fabric obtain this using the alkali of the invention provided is dense Invention desired gloss and well-pressed degree.Simultaneously the present invention further study show that, when the concentration of alkali is respectively 24Be and 30Be, Gloss, the well-pressed degree of both generations have significant difference, on the premise of abundant mercerising, and the concentration of alkali can make cotton when being 30Be Fiber is fully swelled, obtains optimal gloss and well-pressed degree, and when the concentration of alkali is more than 30Be, gloss and well-pressed degree will not be again Substantially increase.
In the above-mentioned methods, it is preferable that in step 3, the enzyme, which is washed, comprises the following steps：Fabric is placed in containing fibre In the working solution of the plain enzyme of dimension, it is 1 to control bath raio:(5-15), handles 50-100min in 50-70 DEG C, fabric then is placed in into 80 DEG C 10min is handled in water-bath；Wherein, the pH value of the working solution is 5-7, and the concentration of the cellulase is 0.5-3.0g/L；More Preferably, the pH value of the working solution is 5-6；It is further preferred that the working solution cellulase concentration is 2.0-3.0g/ L；It is further preferred that the bath raio is 1:(10-15).Enzyme washes the quality and the clean journey of final finished fabric cloth cover of effect Degree is directly proportional, and directly affects the sense of touch effect of finished product fabric cloth cover；The enzyme provided using the present invention, which washes technique, can make finished product Fabric cloth cover obtains clean, smooth, well-pressed effect.
In the above-mentioned methods, it is preferable that after step 4 terminates, before step (5) starts, this method also includes the step of calendering Suddenly, the calen-dering process is：Calendering face is the front of cloth specimen, and temperature is 60 DEG C -120 DEG C, and pressure is 6MPa-16MPa, and speed is 10-30m/min；Preferably, temperature is 80 DEG C -100 DEG C, and pressure is 8MPa-12MPa, and speed is 15-25m/min；The mesh of calendering Be further lifting cloth cover gloss.
In the above-mentioned methods, it is preferable that in step 5, the soft finish comprises the following steps：By the cloth after drying Sample pads soft sizing dressing liquid, then in 130-170 DEG C of drying；It is highly preferred that with the stereometer of soft dressing liquid of shaping, institute Stating the raw material composition of soft sizing dressing liquid includes 10-100g/L resins, 50-300g/L amido silicon oils, 10-100g/L modified silicons Oil, 1-5g/L bleeding agents, the anti-pin hole agent of 5-30g/L and 5-15g/L catalyst；It is further preferred that with softness sizing dressing liquid Stereometer, the dressing liquid raw material composition include 30-60g/L resins, 100-200g/L amido silicon oils, 30-60g/L modification The anti-pin hole agent of silicone oil, 1-3g/L bleeding agents, 5-10g/L and 6-12g/L catalyst.
In the above-mentioned methods, it is preferable that the resin is modified 2D resins.
In the above-mentioned methods, it is preferable that the amido silicon oil includes the SILYOUINV0161 of Dongguan Jiahe Chemical Manufacture And/or the OFX-8040A of Dow Corning Corporation's production, but not limited to this.
In the above-mentioned methods, it is preferable that the modified silicon oil includes what Dongguan, Guangdong Pacific Ocean Chemical Co., Ltd. produced KDM-C18A and/or the 8221 of the production of east Qi Chemical Co., Ltd.s, but not limited to this, the modified silicon oil that the present invention is provided be containing The emulsion of high response functional group.
In the above-mentioned methods, it is preferable that the bleeding agent is polyethenoxy ether class, the anti-pin hole agent is polyethylene or stone Wax, the catalyst is magnesium chloride.
The modification 2D resins that the present invention is provided can improve the shrink problem of fabric, improve the ironing-free performance of fabric and then carry The appearance after laundering of high cloth cover；Amido silicon oil can be aligned in cloth cover formation, and uniform fold fiber surface makes fabric obtain most Lubrication well, soft effect；Modified silicon oil can help amido silicon oil to form the crosslinking of certain density with cellulose hydroxyl group, be to knit Thing reaches well-pressed and bony finishing effect, and is resistant to multiple family's wash water；The bleeding agent can promote cellulose fibre pair The absorption of softness sizing dressing liquid；The agent of anti-pin hole can improve the smoothness of fabric, the risk that reduction pin hole is produced.
Traditional handicraft carries out simple group when carrying out soft sizing arrangement using single consistent lubricant or simply by consistent lubricant Close, it is impossible to realize smooth, well-pressed, wrinkle resistance unification；And the soft sizing dressing liquid that the present invention is provided is by resin, amino silicone Oil, modified silicon oil compounding use, can not only ensure that final fabric is more smooth, well-pressed, drapability is good, and can also make most Whole fabric has the advantages that crease-resistant, shrink is small.
In the above-mentioned methods, it is preferable that in step 6, the preshrunk processing uses close blanket preshrinking machine, described pre- The temperature of contracting processing is 80-100 DEG C, more preferably 90-100 DEG C；The time of the preshrunk processing is 1-3min, more preferably 1.5-2min.The pliability and smooth degree of fabric can further be improved using preshrunk processing, while improving the contracting of knitting fabric Water problems.
In the above-mentioned methods, it is preferable that in step one, the fabric is that the yarn for being more than 50% by cotton content is made into 's；It is highly preferred that the fabric be by Quality Pure Cotton Yarn Production, polyester (terylene and the scribbled of cotton) or cotton-silk yarn (cotton and silk it is mixed Yarn) be made into.
Beneficial effects of the present invention：
1) present invention research finds that suitable knitting and fabric design are most important to the sense of touch effect of finished product fabric, By the way that to being designed including yarn count, pin number, yarn length, the institutional framework of fabric, the fabric being made into is more preferably close, well-pressed, simultaneous While turning round and look at actual production feasibility, it can be ensured that fabric finally results in feel, gloss and the cool feeling effect as silk, most Whole actual effect is close to ideal effect；
2) technical scheme that the present invention is provided is improved the raw material composition of soft dressing liquid of shaping, using the softness Dressing liquid of shaping is carried out after soft sizing arrangement, and not only more smooth, well-pressed, drapability is good for fabric, but also with crease-resistant, contracting The small advantage of water, has accomplished smooth, well-pressed, crease-resistant comprehensive unification；
3) with traditional similar products, design and weaving of the present invention to fabric, and the finisher such as mercerising, cellulase treatment Skill is studied and improved, and especially coordinates suitable yarns length closely to knit base using high pin count with circular knitting machine, in shaping process It is middle to be handled using soft sizing dressing liquid, the well-pressed effect and glossiness of fabric are not only increased, the cunning of fabric is added Refreshing, ice-cold sense of touch style, but also be that fabric has preferable dimensional stability, wrinkle resistance and washes rear feel, it is final to obtain Fabric there is style characteristic as silk.
Embodiment
In order to which technical characteristic, purpose and beneficial effect to the present invention are more clearly understood from, now to the skill of the present invention Art scheme carry out it is described further below, but it is not intended that to the present invention can practical range restriction.
Embodiment 1
Present embodiments provide it is a kind of there is gloss as silk, feel and cool feeling contain cotton knitted fabric, the system of the fabric Preparation Method is as described below：
1) yarn is made into two kinds of different fabrics (being respectively labeled as fabric 1 and fabric 2) respectively with circular knitting machine：Two kinds The yarn that different fabrics is used is 100% cotton yarn, and the institutional framework of fabric is also plain weave, and fabric designs and knits base Parameter is as shown in table 1.
The fabric of table 1 designs and knitted base parameter
Numbering Yarn count The long 50C of yarn Pin number Door width Grammes per square metre
Fabric 1 40S/1 115mm 32 56 inches 135g/m2
Fabric 2 40S/1 120mm 24 54 inches 120g/m2
2) mercerising：Mercerising, speed are carried out using open width mercerizing machine respectively to above two fabric：15m/min, temperature：Room 20 DEG C of temperature, the composition of mercerising working solution is as shown in table 2.
3) kiering：Kiering is carried out using common process.
The composition of the mercerising working solution of table 2
Component Consumption Manufacturer
Alkali NaOH 30Be Build surging (Hengyang) Industrial Co., Ltd.
Silkete penetrating agent Floranit 4028-A 5g/L Ke Kai Fine Chemical Co., Ltd
4) enzyme is washed：Fabric is placed in into enzyme to wash in working solution (pH value is 5-7), it is 1 to control bath raio:15,55 DEG C of processing 60min, is then placed in processing 10min in 80 DEG C of water-baths by fabric and kills enzyme；The composition that enzyme washes working solution is as shown in table 3.
The enzyme of table 3 washes the composition of working solution
Component Consumption Manufacturer
HAC 0.3g/L Jinan Lu Yuan Chemical Co., Ltd.s
NaAC 0.5g/L Taizhou City Xinghua Chemical Company
Cellulase Super GX plus 2g/L Bio tech ltd of Jie Neng sections
5) dyeing, drying is common process.
6) soft sizing is carried out on forming machine to the cloth specimen after drying to arrange, treatment temperature is 150 DEG C, the time is 2min, the composition of softness sizing dressing liquid is as shown in table 4.
7) preshrunk：Preshrunk processing is carried out using close blanket preshrinking machine, preshrunk number of times is once, and temperature is 100 DEG C, the time is 1min, finally gives 40S/1 finished product fabric, and it is finished product fabric 1 that wherein fabric 1 is corresponding, and corresponding fabric 2 is finished product fabric 2, both fabrics are respectively provided with gloss and feel as silk.
The composition of the soft sizing dressing liquid of table 4
Component Consumption Manufacturer
Amido silicon oil OFX-8040A 150g/L Dow Corning Corporation
Modified silicon oil KDM-C18A 50g/L Dongguan City, Guangdong Province Tai Yang Chemical Co., Ltd.s
Resin PCLN 30g/L Ang Gao Chemical Co., Ltd.s
Catalyst MgCl2 5g/L The trade Co., Ltd of Guangzhou good fortune million
Penetrating agent JFC 1g/L Dongguan Jiahong Silicone Technology Co., Ltd.
Performance test is carried out respectively to finished product fabric 1 and finished product fabric 2, test result is as shown in table 5.
The test result of table 5
Note：1st, (Stiffness), smooth (Smoothness), soft (Softness) value are endured with all one's will by Nu Cybertek, The product of Inc companies productionSystem (Chinese is translated into " magic weapon instrument " or " magic weapon system ") is measured, these three The absolute value of parameter is bigger, represents more stiffening, more smooth, more soft respectively；2nd, the result of cool feeling test is to test public by Boken What department provided, wherein, the bigger expression of Q-MAX values feels more nice and cool；3rd, test is shunk according to the A of AATCC135 III, washes 1 time-baking 1 time A circulation is calculated, three circulations are carried out altogether.
As can be seen from Table 5, both fabrics that the present invention is provided are respectively provided with gloss, feel and cool feeling as silk；Phase Compared with for, the absolute value of stiffening (Stiffness), smooth (Smoothness) of finished product fabric 1 is larger, and cool feeling test result Q-MAX values are larger, illustrate that the final style of finished product fabric 1 is better compared with finished product fabric 2, because fabric is more close, so The shrink performance of fabric 1 is also better compared with fabric 2.Illustrate the timing of institutional framework one when yarn count and fabric, pin number is higher, and yarn is long Smaller, the finished product fabric that finally obtains is more well-pressed, smooth, skeleton sense is stronger, and cool feeling effect is also more preferable, shrinks smaller.
Embodiment 2
Present embodiments provide it is a kind of there is gloss as silk, feel and cool feeling contain cotton knitted fabric, the system of the fabric Preparation Method is as described below：
1) yarn is made into fabric with circular knitting machine：The yarn used is for 100% cotton yarn, the institutional framework of fabric Interlock fabric, fabric design is as shown in table 6 with knitting base parameter.
The fabric of table 6 designs and knitted base parameter
Yarn count The long 50C of yarn Pin number Door width Grammes per square metre
60S/1 130mm 32 60 inches 170g/m2
2) mercerising：Mercerising, speed are carried out to fabric using open width mercerizing machine：15m/min, temperature：20 DEG C of room temperature, mercerizer The composition for making liquid is as shown in table 7.
3) kiering：Kiering is carried out using common process.
The composition of the mercerising working solution of table 7
Component Consumption Manufacturer
Alkali NaOH 30Be Build surging (Hengyang) Industrial Co., Ltd.
Silkete penetrating agent Floranit 4028-A 5g/L Ke Kai Fine Chemical Co., Ltd
4) enzyme is washed：Fabric is placed in into enzyme to wash in working solution (pH value is 5-7), it is 1 to control bath raio:15,55 DEG C of processing 60min, is then placed in processing 10min in 80 DEG C of water-baths by fabric and kills enzyme；The composition that enzyme washes working solution is as shown in table 8.
The enzyme of table 8 washes the composition of working solution
Component Consumption Manufacturer
HAC 0.3g/L Jinan Lu Yuan Chemical Co., Ltd.s
NaAC 0.5g/L Taizhou City Xinghua Chemical Company
Cellulase Super GX plus 2g/L Bio tech ltd of Jie Neng sections
5) kiering, dyeing, drying are common process.
6) soft sizing is carried out on forming machine to the cloth specimen after drying to arrange, treatment temperature is 150 DEG C, the time is 2min, the composition of softness sizing dressing liquid is as shown in table 9.
7) preshrunk：Preshrunk processing is carried out using close blanket preshrinking machine, preshrunk number of times is once, and temperature is 100 DEG C, the time is 1min, finally giving 60S/1 has the pure cotton cotton wool fabric finished product of gloss as silk, feel and cool feeling.
The composition of the soft sizing dressing liquid of table 9
Component Consumption Manufacturer
Amido silicon oil OFX-8040A 150g/L Dow Corning Corporation
Modified silicon oil KDM-C18A 50g/L Dongguan City, Guangdong Province Tai Yang Chemical Co., Ltd.s
Resin PCLN 30g/L Ang Gao Chemical Co., Ltd.s
Catalyst MgCl2 5g/L The trade Co., Ltd of Guangzhou good fortune million
Penetrating agent JFC 1g/L Dongguan Jiahong Silicone Technology Co., Ltd.
Embodiment 3
1) yarn is made into fabric with circular knitting machine：The yarn used is for 100% cotton yarn, the institutional framework of fabric Pearl ground cloth, fabric is designed and to knit base parameter as shown in table 10.
The fabric of table 10 designs and knitted base parameter
Yarn count The long 50C of yarn Pin number Door width Grammes per square metre
36S/1 120mm 24 60 inches 150g/m2
2) mercerising：Mercerising, speed are carried out to fabric using open width mercerizing machine：15m/min, temperature：20 DEG C of room temperature, mercerizer The composition for making liquid is as shown in table 11.
3) kiering：Kiering is carried out using common process.
The composition of the mercerising working solution of table 11
Component Consumption Manufacturer
Alkali NaOH 30Be Build surging (Hengyang) Industrial Co., Ltd.
Silkete penetrating agent Floranit 4028-A 5g/L Ke Kai Fine Chemical Co., Ltd
4) fabric is placed in into enzyme to wash in working solution (pH value is 5-7), it is 1 to control bath raio:15,55 DEG C of processing 60min, then Fabric is placed in processing 10min in 80 DEG C of water-baths and kills enzyme；The composition that enzyme washes working solution is as shown in table 12.
The enzyme of table 12 washes the composition of working solution
Component Consumption Manufacturer
HAC 0.3g/L Jinan Lu Yuan Chemical Co., Ltd.s
NaAC 0.5g/L Taizhou City Xinghua Chemical Company
Cellulase Super GX plus 2g/L Bio tech ltd of Jie Neng sections
5) kiering, dyeing, drying are common process.
6) soft sizing is carried out on forming machine to the cloth specimen after drying to arrange, treatment temperature is 150 DEG C, the time is 2min, the composition of softness sizing dressing liquid is as shown in table 13.
The composition of the soft qualitative dressing liquid of table 13
Component Consumption Manufacturer
Amido silicon oil OFX-8040A 150g/L Dow Corning Corporation
Modified silicon oil KDM-C18A 50g/L Dongguan City, Guangdong Province Tai Yang Chemical Co., Ltd.s
Resin PCLN 30g/L Ang Gao Chemical Co., Ltd.s
Catalyst MgCl2 5g/L The trade Co., Ltd of Guangzhou good fortune million
Penetrating agent JFC 1g/L Dongguan Jiahong Silicone Technology Co., Ltd.
7) preshrunk：Preshrunk processing is carried out using close blanket preshrinking machine, preshrunk number of times is once, and temperature is 100 DEG C, the time is 1min, finally giving 36S/1 has the cotton pearl ground cloth finished product of gloss as silk, feel and cool feeling.
Comparative example 1
With reference to the production procedure of finished product fabric 1 in embodiment 1, this comparative example is only to the softness in soft sizing finishing technique Sizing dressing liquid is adjusted, specific as shown in table 14, production of remaining production procedure all with finished product fabric 1 in embodiment 1 Flow is identical, finally gives contrast fabric 1.
The raw material ancestral composition of the soft sizing dressing liquid of table 14
Component Consumption Manufacturer
Softening agent JSS 200g/L Step figure chemical industry
Resin PCLN 30g/L Ang Gao Chemical Co., Ltd.s
Catalyst MgCl2 5g/L The trade Co., Ltd of Guangzhou good fortune million
Penetrating agent JFC 1g/L Dongguan Jiahong Silicone Technology Co., Ltd.
The comparing result of table 15
The contrast fabric 1 that the finished product fabric 1 and comparative example 1 provided embodiment 1 is provided carries out performance test, after test Comparing result is as shown in Table 15.
As can be seen from Table 15：The absolute value of stiffening (Stiffness) of finished product fabric 1 is larger, smooth (smoothness) absolute value is larger, and the absolute value of soft (Softness) is smaller, and cool feeling test result is also more preferable；Explanation Compared with dressing liquid made from single softening agent in comparative example 1, after the soft sizing dressing liquid processing provided using the present invention Fabric is more well-pressed, smooth, skeleton sense is stronger, cool feeling is better.

Claims (23)

1. a kind of preparation method containing cotton knitted fabric with gloss, feel and cool feeling as silk, it comprises the following steps：
Step 1: yarn is made into fabric with circular knitting machine；Wherein, the pin number of the circular knitting machine is 18-40, the yarn of the yarn Branch is 20S/1-80S/1, a length of 50C=90mm-200mm of yarn of the yarn, and the grammes per square metre of the fabric is 60-240g/m2, institute State the institutional framework of fabric for plain weave, pearl, cotton wool, rib-loop, looped pile, ball woll or jacquard weave；
Step 2:, kiering alkali mercerized to fabric progress open width；
Washed Step 3: carrying out enzyme to the fabric after alkali mercerized using cellulase；
Step 4: the fabric after being washed to enzyme is dyed, dried, the cloth specimen after being dried；
Arranged Step 5: carrying out soft sizing to the cloth specimen after drying；Wherein, the raw material composition bag of the soft sizing dressing liquid Include resin, amido silicon oil and modified silicon oil；
Step 6: the cloth specimen after being arranged to soft sizing carries out preshrunk processing, obtain with gloss as silk, feel and cool feeling Containing cotton knitted fabric.
2. according to the method described in claim 1, wherein, it is described when the institutional framework of the fabric is plain weave in step one The pin number of circular knitting machine is 20-40 pins, and the yarn count of the yarn is 20S/1-80S/1, yarn a length of 50C=90mm-200mm, described The grammes per square metre of fabric is 60-200g/m2。
3. method according to claim 1 or 2, wherein, in step one, when the institutional framework of the fabric is plain weave, The pin number of the circular knitting machine is 28-36 pins, and the yarn count of the yarn is 30S/1-50S/1, a length of 50C=100mm-130mm of yarn, The grammes per square metre of the fabric is 110-160g/m2。
4. according to the method described in claim 1, wherein, it is described when the institutional framework of the fabric is jacquard weave in step one The pin number of circular knitting machine is 28-36 pins, and the yarn count of the yarn is 30S/1-50S/1, yarn a length of 50C=100mm-130mm, described The grammes per square metre of fabric is 110-160g/m2。
5. according to the method described in claim 1, wherein, in step one, the institutional framework of the fabric for pearl when, it is described The pin number of circular knitting machine is 18-28 pins, and the yarn count of the yarn is 20S/1-50S/1, yarn a length of 50C=100mm-170mm, described The grammes per square metre of fabric is 90-200g/m2。
6. method according to claim 1 or 5, wherein, in step one, the institutional framework of the fabric for pearl when, The pin number of the circular knitting machine is 24-28 pins, and the yarn count of the yarn is 30S/1-40S/1, a length of 50C=110mm-130mm of yarn, The grammes per square metre of the fabric is 120-170g/m2。
7. according to the method described in claim 1, wherein, it is described when the institutional framework of the fabric is cotton wool in step one The pin number of circular knitting machine is 18-40 pins, and the yarn count of the yarn is 30S/1-80S/1, yarn a length of 50C=105mm-200mm, described The grammes per square metre of fabric is 90-240g/m2。
8. the method according to claim 1 or 7, wherein, in step one, when the institutional framework of the fabric is cotton wool, The pin number of the circular knitting machine is 24-36 pins, and the yarn count of the yarn is 40S/1-70S/1, a length of 50C=105mm-140mm of yarn, The grammes per square metre of the fabric is 130-190g/m2。
9. according to the method described in claim 1, wherein, in step 2, the concentration of the alkali is 20-32Be, mercerising infiltration The concentration of agent is 1-5g/L, and the speed of open width mercerizing machine is 5-20m/min.
10. the method according to claim 1 or 9, wherein, in step 2, the concentration of the alkali is 24-32Be, mercerising The concentration of bleeding agent is 3-5g/L, and the speed of open width mercerizing machine is 10-15m/min.
11. according to the method described in claim 1, wherein, in step 3, the enzyme, which is washed, to be comprised the following steps：
Fabric is placed in the working solution containing cellulase, it is 1 to control bath raio:(5-15), 50- is handled in 50-70 DEG C Fabric, is then placed in 80 DEG C of water-baths and handles 10min by 100min；Wherein, the pH value of the working solution is 5-7, the fiber The concentration of plain enzyme is 0.5-3.0g/L.
12. method according to claim 11, wherein, the pH value of the working solution is 5-6.
13. method according to claim 11, wherein, the working solution cellulase concentration is 2.0-3.0g/L.
14. method according to claim 11, wherein, the bath raio is 1:(10-15).
15. according to the method described in claim 1, wherein, in step 5, the soft finish comprises the following steps：
Cloth specimen after drying is padded into soft sizing dressing liquid, then in 130-170 DEG C of drying.
16. method according to claim 15, wherein, with the stereometer of soft dressing liquid of shaping, the soft sizing is whole The raw material composition of reason liquid includes 10-100g/L resins, 50-300g/L amido silicon oils, 10-100g/L modified silicon oils, 1-5g/L and oozed Saturating agent, the anti-pin hole agent of 5-30g/L and 5-15g/L catalyst.
17. method according to claim 16, wherein, with the stereometer of soft dressing liquid of shaping, the original of the dressing liquid Material composition includes 30-60g/L resins, 100-200g/L amido silicon oils, 30-60g/L modified silicon oils, 1-3g/L bleeding agents, 5- The anti-pin hole agent of 10g/L and 6-12g/L catalyst.
18. the method according to claim 16 or 17, wherein, the resin is modified 2D resins.
19. the method according to claim 16 or 17, wherein, the amido silicon oil is Dongguan Jiahe Chemical Manufacture The SILYOUINV0161 and/or OFX-8040A of Dow Corning Corporation's production；The modified silicon oil is Dongguan, Guangdong Pacific Ocean chemical industry The KDM-C18A of Co., Ltd's production and/or the 8221 of the production of east Qi Chemical Co., Ltd.s.
20. the method according to claim 16 or 17, wherein, the bleeding agent is polyethenoxy ether class, the anti-pin hole Agent is polyethylene or paraffin class material, and the catalyst is magnesium chloride.
21. according to the method described in claim 1, wherein, in step one, the fabric be by cotton content be more than 50% yarn What line was made into.
22. method according to claim 21, wherein, the fabric is made into by Quality Pure Cotton Yarn Production, polyester or cotton-silk yarn.
23. it is a kind of there is gloss as silk, feel and cool feeling contain cotton knitted fabric, it is by any one of claim 1-22 institutes Made from the method stated.
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