CN101200845A - Processing method for cotton/hemp blended knitted fabric - Google Patents
Processing method for cotton/hemp blended knitted fabric Download PDFInfo
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- CN101200845A CN101200845A CNA2007101647305A CN200710164730A CN101200845A CN 101200845 A CN101200845 A CN 101200845A CN A2007101647305 A CNA2007101647305 A CN A2007101647305A CN 200710164730 A CN200710164730 A CN 200710164730A CN 101200845 A CN101200845 A CN 101200845A
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Abstract
The invention discloses a processing method of cotton/ramie blended knitting fabric which adopts processing equipment of a cotton mill and adds yarn boiling and demineralizing processes before a weaving process. The whole technological process is from yarn boiling, demineralizing, weaving, mercerizing, bleaching and boiling, biological enzyme washing, and dyeing, softening, dehydration, width opening, drying and setting to preshrinking. The yarn boiling temperature in the yarn boiling process is 80 to 130 DEG C and the time is 10-30m. The demineralizing temperature in the demineralizing process is 30 to 90 DEG C and the time is 10-30m. In the demineralizing treatment, acid demineralizing agent and refining agent are used to remove heavy metal ions in cotton/ramie blended yarn. The invention has the advantages of ensuring the neat surface of the knitting fabric, comfort handle, light shrinkage and distortion and good durability with the added yarn boiling and demineralizing processes, eliminating the internal stress of the cotton/ramie blended yarn through the yarn boiling process, improving the toughness and the weaving efficiency of the knitting fabric, improving the insurance coefficient of the boiling and bleaching process through the demineralizing process and providing a guarantee for the strength of the knitting fabric.
Description
Technical field
The present invention relates to a kind of processing method of knit fabric, especially relate to a kind of processing method of cotton/hemp blended knitted fabric.
Background technology
Cotton/hemp blended knitted fabric especially cotton/big hemp blended knitted fabric is smooth, ventilative well-pressed, comfortable and easy to wear owing to having feel, is popular on market.But because that the impurity of hemp itself is more, rigidity reaches pliability greatly is poor, and the whiteness of cotton/big linen blended yarn and brute force is also relatively poor, the fiber crops knot is more, make that relatively poor in vain at the bottom of cotton/big hemp blended knitted fabric, filoplume and fiber crops knot are more, and easily produce broken hole, this has brought certain difficulty for dyeing, arrangement processing; And such knit fabric is easy to generate deformation largely, shrink and distortion in washing process, and shape-retaining ability is relatively poor, has had a strong impact on the quality of knit fabric.
At cotton/big ubiquitous appearance poor of hemp blended knitted fabric, washing back shape-retaining ability is relatively poor and lining at the bottom of the white not high shortcoming that can not do light color, for satisfying consumers in general to the washability of such knit fabric and the requirements at the higher level of outward appearance proposition, many manufacturers are according to the condition of self, improve the performance of such knit fabric by improving processing method, improve the quality of such knit fabric.At present, the improved processing method that shortcoming adopted that exists at such knit fabric mainly can classify as following two kinds:
1, by boiling the pre-treatment processing of floating with bioenzyme washing, effectively remove the fiber crops knot, improved the white degree in the end of lining simultaneously, this method is usually used in the hemp cloth pre-treatment of low yarn count, but the loss in weight is more in its processing procedure;
2, by boiling and bleaching process, and in conjunction with mercerising processing, make the surface of cotton/big hemp blended knitted fabric brighter and cleaner, feel is more well-pressed, and size is more stable.
The processing method that domestic manufacturer adopted, major part are by improving bleaching process, improving the white and outward appearance in the end in conjunction with biopolishing technology; What have also processes filoplume, fiber crops knot and the DIMENSIONAL STABILITY of further improving knit fabric by mercerising, promptly the method that combines by bioenzyme washing and mercerising processing is improved the cloth cover effect of cotton/hemp knit fabric, its technological process is: weave → mercerising → boil and float → bioenzyme washing → dyeing → soft excessively → dehydration → open-width → oven dry → typing → preshrunk, but cotton/hemp knit fabric is when mercerising is handled, because the effect of concentrated base has destroyed pectin, make the bundle fiber cohesive force descend, thereby cause the brute force of knit fabric to descend; Again after biological (cellulase) enzyme is washed arrangement, though the surface smoothness of knit fabric, feel, drapability and capillary effect all increase, thereby, the hydrolysis of fiber ends molecule causes strength loss but making that power weakens between fiber molecule, the concentration of cellulase is high more, powerful decline is obvious more, easily produce broken hole, and concentration is crossed when hanging down, then do not have good effect, especially when some dark products of processing, dyeing, the time of soaping is longer, and knit fabric through behind the mechanical stretching and rubbing action of long period, makes that the removal effect of knit fabric finished product filoplume is relatively poor in cylinder; In addition, the typing in this technological process can not be crossed resin, but only resin will cause shrinking and twisting the standard of all not accomplishing, the durability that will cause knit fabric finished product feel and fabric quality is relatively poor, behind the cyclic washing, easy pilling, problems such as size distortion.
Summary of the invention
Technical problem to be solved by this invention provides and a kind ofly can effectively guarantee cotton/numb knit fabric any surface finish, and shape-retaining ability and durability are good, and the processing method of the cotton/hemp blended knitted fabric of the light knit fabric of the higher suitable processing of end whiteness.
The present invention solves the problems of the technologies described above the technical scheme that is adopted: a kind of processing method of cotton/hemp blended knitted fabric, adopt the cotton mill process equipment, before weaving process, add and boil yarn and demineralization two procedures, make whole process flow be: to boil yarn → demineralization → weave → mercerising → boil and float → bioenzyme washing → dyeing → soft excessively → dehydration → open-width → oven dry → typing → preshrunk, describedly boil that to boil the yarn temperature in the yarn operation be 80～130 ℃ and to boil the yarn time be 10～30 minutes, the demineralization temperature is that 30～90 ℃ and demineralization time are 10～30 minutes in the described demineralization operation, during handling, demineralization use acid demineralization agent EMG (the good and manufacturing in Shanghai) and scouring agent DLF (the good and manufacturing in Shanghai) to remove the heavy metal ion in the cotton/hemp blended yarn, the content of described acid demineralization agent EMG in the demineralization treatment fluid is 1～10g/L, and the content of described scouring agent DLF in the demineralization treatment fluid is 0.5～5g/L.
Described weaving process is the cotton/hemp blended yarn after handling through described demineralization operation to be sent into weft-knitted large circle machine by conveyer with 130～140 meters/minute speed be processed into cotton/numb knit fabric.
Described mercerizing process is that the cotton of being processed into through described weaving process/numb knit fabric is carried out processing with 12～14 meters/minute processing speed with caustic lye of soda, and described caustic lye of soda concentration is that 18～30Be (baume) and caustic lye of soda temperature are 18～25 ℃.
Described boil to float boil in the operation that to float temperature be 90～130 ℃ and to boil the time of floating be 30～90 minutes, boiling to float in the processing uses clay finishing agent Aprotan APG (Guangzhou be full of earlier manufacturings) and hydrogen peroxide that the cotton/numb knit fabric after described mercerizing process processing is processed, the content of described clay finishing agent Aprotan APG in bleaching liquid is 1～5g/L, and concentration is that 27.5% the content of hydrogen peroxide in bleaching liquid is 3～18g/L.
To wash temperature be that 40～55 ℃ and the enzyme time of washing are 30～90 minutes to enzyme in the described bioenzyme washing operation, during handling, use bioenzyme washing cellulase RFW (international corporation of outstanding person's energy section makes) to processing through the described cotton/numb knit fabric that floats after operation is handled that boils, the content that described cellulase RFW washes in the treatment fluid at enzyme is 0.5～2g/L, and adding the weak acid buffer regulatory enzyme, to wash the pH value of treatment fluid be 4.5～5.5.
The concrete steps of the soft operation of described mistake are:
A. in overflow dyeing machine, be water inlet in 1: 8～1: 12 at first by the weight ratio of the cotton after the dyed processing/numb knit fabric and water;
B. in crossing supple-settlement liquid, add hydrophilic softener SIQ (manufacturing of Rudoiph's chemical industry) again after moving 5 minutes by 2～6g/L;
C. be warming up to 40～45 ℃ at last, and draining after being incubated 20～30 minutes.
Setting temperature is that 120～170 ℃ and typing speed are 12～30 meters/minute in the described shaping process, adds softener HIS (Bu Sai specialization worker manufacturings) by 30～50g/L and by 40～60g/L adding formaldehyde-free resins Arkofix NZF (manufacturing of Clariant chemical industry) in the typing working fluid.
Compared with prior art, the invention has the advantages that before weaving process, to have added and boil yarn and demineralization two procedures, by boiling the yarn operation, eliminated the internal stress of cotton/hemp blended yarn effectively, the pliability and the woven efficient of knit fabric have been improved, reduced content of beary metal in the cotton ramie blended spinning yarn by acid demineralization agent and scouring agent in the demineralization operation, improved the safety factor that boils the process of floating, for the brute force of knit fabric provides assurance, the adding of this two procedures has guaranteed the knit fabric any surface finish effectively, comfortable feel, shrink and twist little and have good persistence; Owing in the weaving process the cotton/hemp blended yarn after demineralization is sent into weft-knitted large circle machine by high-quality conveyer with 130～140 meters/minute speed, makes the knit fabric that weaves have good bar and do and lower internal stress; In mercerizing process,, improved the surface smoothness and the DIMENSIONAL STABILITY of cotton/numb knit fabric, and obtained feel preferably owing to the effect of fiber and high alkali liquid; Boil to float in the operation and float stabilizing agent and scouring agent by using the conduct of clay finishing agent to boil, not only environmental protection, and improved bleaching effect; In the bioenzyme washing operation since the biopolishing enzyme RFW that uses be will enzyme with the surperficial fine hair of knit fabric between react targetedly, not only removed fine hair and improved the fineness of knit fabric, and reduced strength damage, improved the feel of knit fabric; Because SIQ is a kind of alkaline-resisting season of special height amino silicon oil emulsion, SIQ can significantly improve the feel of knit fabric, but also have good hydrophily when the dyeing machine intensive amount reaches 6g/L when soft crossing; Use preferred softener HIS in the shaping process and do RESIN FINISH simultaneously, can make the knit fabric surface become soft, smooth, low-shrinkage water twist song, and have good hydrophilicity; In addition, because the knit fabric after handling has good surface appearance, brute force and hydrophily, the present invention can also be applied on other crudefiber crop and the diablement fort kind, has widened range of application greatly.
The specific embodiment
Embodiment describes in further detail the present invention below in conjunction with accompanying drawing.
Embodiment one: a kind of processing method of cotton/hemp blended knitted fabric, cotton/big hemp blended knitted fabric that processing is dark, before weaving process, add and boil yarn and demineralization two procedures, make whole process flow be: boil yarn → demineralization → weave → mercerising → boil and float → bioenzyme washing → dyeing → soft excessively → dehydration → open-width → oven dry → typing → preshrunk, specific embodiment is as follows:
A. 20S cotton/hemp blending bobbin yarn is boiled yarn and handle, boil the yarn temperature and be 110 ℃ and to boil the yarn time be 15 minutes, cotton/hemp blending bobbin yarn is fully expanded;
B. cotton/big the linen blended yarn through over-cooking after yarn is handled is carried out the demineralization processing, demineralization treatment fluid temperature is that 50 ℃ and demineralization time are 10 minutes, during handling, demineralization uses the heavy metal ion in acid demineralization agent EMG and the scouring agent DLF removal cotton/big linen blended yarn, acid demineralization agent EMG consumption is 2g/L, and scouring agent DLF consumption is 0.5g/L;
C. will through demineralization handle the back cotton/big linen blended yarn sends into weft-knitted large circle machine by conveyer with 130 meters/minute speed and weaves and be processed into cotton/hemp knit fabric;
D. will weave the cotton/hemp knit fabric that is processed into and in mercerizing range, carry out the mercerising processing with caustic lye of soda with 12 meters/minute processing speed, caustic lye of soda concentration is that 26Be and caustic lye of soda temperature are 20 ℃, the first rinsing bowl washing temperature in the mercerizing range is 70 ℃, and the second rinsing bowl washing temperature is 60 ℃;
E. use green clay finishing agent Aprotan APG of a kind of natural mineral matter and hydrogen peroxide that the cotton/hemp knit fabric after handling through mercerising is boiled and float processing, boil that to float temperature be 98 ℃ and to boil the time of floating be 45 minutes, the green clay finishing agent of natural mineral matter AprotanAPG consumption is 1g/L, and concentration is that 27.5% hydrogen peroxide consumption is 5g/L in bleaching liquid;
F. use a kind of biopolishing enzyme RFW that the cotton/hemp knit fabric through over-cooking after floating processing is carried out the bioenzyme washing processing, the bioenzyme washing temperature is that 55 ℃ and the enzyme time of washing are 50 minutes, biopolishing enzyme RFW consumption is 0.75g/L, and is 5 with the pH value that acetic acid and the composite weak acid buffer regulatory enzyme of sodium acetate are washed treatment fluid;
G. in overflow dyeing machine to the processing of dyeing of the cotton/hemp knit fabric after handling through bioenzyme washing;
H. cotton/hemp the knit fabric after the dyeing was carried out supple-settlement, weight ratio by cotton/hemp knit fabric and water is water inlet in 1: 10, move and in crossing supple-settlement liquid, press 6g/L adding hydrophilic softener SIQ after 5 minutes again, be warming up to 45 ℃ at last, and draining after being incubated 30 minutes;
I. to cross after the supple-settlement cotton/the hemp knit fabric dewaters, open-width and oven dry processing;
J. on the setting machine to the processing of finalizing the design through the cotton/hemp knit fabric after the above-mentioned processing, during handling, typing uses a kind of softener HIS and a kind of formaldehyde-free resins Arkofix NZF, softener HIS consumption is 50g/L, formaldehyde-free resins Arkofix NZF consumption is 60g/L, and setting temperature is that 150 ℃ and typing speed are 18 meters/minute;
K. with routine techniques the cotton/hemp knit fabric after handling through typing is carried out the preshrunk processed, obtain cotton/hemp knit fabric finished product.
Above-mentioned hydrophilic softener SIQ is a kind of alkaline-resisting season of special height amino silicon oil emulsion.
Embodiment two: the cotton of processing light color/big hemp blended knitted fabric, and its whole process flow and embodiment one are basic identical, and specific embodiment is as follows:
A. 20S cotton/hemp blending bobbin yarn is boiled yarn and handle, boil the yarn temperature and be 130 ℃ and to boil the yarn time be 20 minutes, cotton/hemp blending bobbin yarn is fully expanded;
B. cotton/big the linen blended yarn through over-cooking after yarn is handled is carried out the demineralization processing, demineralization treatment fluid temperature is that 60 ℃ and demineralization time are 20 minutes, during handling, demineralization uses the heavy metal ion in acid demineralization agent EMG and the scouring agent DLF removal cotton/big linen blended yarn, acid demineralization agent EMG consumption is 2g/L, and scouring agent DLF consumption is 1.5g/L;
C. will through demineralization handle the back cotton/big linen blended yarn sends into weft-knitted large circle machine by conveyer with 140 meters/minute speed and weaves and be processed into cotton/hemp knit fabric;
D. will weave the cotton/hemp knit fabric that is processed into and in mercerizing range, carry out the mercerising processing with caustic lye of soda with 14 meters/minute processing speed, caustic lye of soda concentration is that 30Be and caustic lye of soda temperature are 19 ℃, the first rinsing bowl washing temperature of mercerizing range is 75 ℃, and the second rinsing bowl washing temperature is 65 ℃;
E. use green clay finishing agent Aprotan APG of a kind of natural mineral matter and hydrogen peroxide that the cotton/hemp knit fabric after handling through mercerising is boiled and float processing, boil that to float temperature be 110 ℃ and to boil the time of floating be 30 minutes, the green clay finishing agent of natural mineral matter Aprotan APG consumption is 1.5g/L, and concentration is that 27.5% hydrogen peroxide consumption is 10g/L in bleaching liquid;
F. use a kind of biopolishing enzyme RFW that the cotton/hemp knit fabric through over-cooking after floating processing is carried out the bioenzyme washing processing, the bioenzyme washing temperature is that 50 ℃ and the enzyme time of washing are 60 minutes, biopolishing enzyme RFW consumption is 1g/L, and is 4.8 with the pH value that acetic acid and the composite weak acid buffer regulatory enzyme of sodium acetate are washed treatment fluid;
G. in overflow dyeing machine to the processing of dyeing of the cotton/hemp knit fabric after handling through bioenzyme washing;
H. cotton/hemp the lining after the dyeing was carried out supple-settlement, weight ratio by cotton/hemp knit fabric and water is water inlet in 1: 10, move and in crossing supple-settlement liquid, press 6g/L adding hydrophilic softener SIQ after 5 minutes again, be warming up to 45 ℃ at last, and draining after being incubated 20 minutes;
I. to cross after the supple-settlement cotton/the hemp knit fabric dewaters, open-width and oven dry processing;
J. on the setting machine to the processing of finalizing the design through the cotton/hemp knit fabric after the above-mentioned processing, during handling, typing uses a kind of softener HIS and a kind of formaldehyde-free resins Arkofix NZF, softener HIS consumption is 30g/L, formaldehyde-free resins Arkofix NZF consumption is 60g/L, and setting temperature is that 130 ℃ and typing speed are 22 meters/minute;
K. with routine techniques the cotton/hemp knit fabric after handling through typing is carried out the preshrunk processed, obtain cotton/hemp knit fabric finished product.
Claims (8)
1. the processing method of a cotton/hemp blended knitted fabric, it is characterized in that adopting the cotton mill process equipment, before weaving process, add and boil yarn and demineralization two procedures, make whole process flow be: to boil yarn → demineralization → weave → mercerising → boil and float → bioenzyme washing → dyeing → soft excessively → dehydration → open-width → oven dry → typing → preshrunk, describedly boil that to boil the yarn temperature in the yarn operation be 80～130 ℃ and to boil the yarn time be 10～30 minutes, the demineralization temperature is that 30～90 ℃ and demineralization time are 10～30 minutes in the described demineralization operation, acid demineralization agent EMG of use and scouring agent DLF removed the heavy metal ion in the cotton/hemp blended yarn during demineralization was handled, the content of described acid demineralization agent EMG in the demineralization treatment fluid is 1～10g/L, and the content of described scouring agent DLF in the demineralization treatment fluid is 0.5～5g/L.
2. the processing method of a kind of cotton/hemp blended knitted fabric as claimed in claim 1 is characterized in that described weaving process is the cotton/hemp blended yarn after handling through described demineralization operation to be sent into weft-knitted large circle machine by conveyer with 130～140 meters/minute speed be processed into cotton/numb knit fabric.
3. the processing method of a kind of cotton/hemp blended knitted fabric as claimed in claim 2, it is characterized in that described mercerizing process is that the cotton/numb knit fabric that is processed into through described weaving process is carried out processing with 12～14 meters/minute processing speed with caustic lye of soda, described caustic lye of soda concentration is that 18～30Be and caustic lye of soda temperature are 18～25 ℃.
4. the processing method of a kind of cotton/hemp blended knitted fabric as claimed in claim 3, it is characterized in that described boil to float boil in the operation that to float temperature be 90～130 ℃ and to boil the time of floating be 30～90 minutes, boiling to float uses clay finishing agent AprotanAPG and hydrogen peroxide that the cotton/numb knit fabric after handling through described mercerizing process is processed in the processing, the content of described clay finishing agent Aprotan APG in bleaching liquid is 1～5g/L, and concentration is that 27.5% the content of hydrogen peroxide in bleaching liquid is 3～18g/L.
5. the processing method of a kind of cotton/hemp blended knitted fabric as claimed in claim 4, it is characterized in that in the described bioenzyme washing operation that it is that 40～55 ℃ and the enzyme time of washing are 30～90 minutes that enzyme is washed temperature, during handling, use bioenzyme washing cellulase RFW to processing through the described cotton/numb knit fabric that floats after operation is handled that boils, the content that described cellulase RFW washes in the treatment fluid at enzyme is 0.5～2g/L, and adding the weak acid buffer regulatory enzyme, to wash the pH value of treatment fluid be 4.5～5.5.
6. the processing method of a kind of cotton/hemp blended knitted fabric as claimed in claim 5 is characterized in that the concrete steps of the soft operation of described mistake are:
A. in overflow dyeing machine, be water inlet in 1: 8～1: 12 at first by the weight ratio of the cotton after the dyed processing/numb knit fabric and water;
B. in crossing supple-settlement liquid, add hydrophilic softener again after moving 5 minutes by 2～6g/L;
C. be warming up to 40～45 ℃ at last, and draining after being incubated 20～30 minutes.
7. the processing method of a kind of cotton/hemp blended knitted fabric as claimed in claim 6, it is characterized in that in the described shaping process that setting temperature is that 120～170 ℃ and typing speed are 12～30 meters/minute, adds softener HIS and adds formaldehyde-free resins Arkofix NZF by 40～60g/L by 30～50g/L in the typing working fluid.
8. the processing method of a kind of cotton/hemp blended knitted fabric as claimed in claim 6 is characterized in that described hydrophilic softener is SIQ.
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| CNA2007101647305A CN101200845A (en) | 2007-12-10 | 2007-12-10 | Processing method for cotton/hemp blended knitted fabric |
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