CN109281174A - A kind of anti pilling imitates woollen fabric and preparation method thereof - Google Patents

A kind of anti pilling imitates woollen fabric and preparation method thereof Download PDF

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Publication number
CN109281174A
CN109281174A CN201810991127.2A CN201810991127A CN109281174A CN 109281174 A CN109281174 A CN 109281174A CN 201810991127 A CN201810991127 A CN 201810991127A CN 109281174 A CN109281174 A CN 109281174A
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Prior art keywords
parts
fabric
yarn
preparation
pilling
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CN201810991127.2A
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Inventor
董勤霞
黄凯
潘玉明
潘豪炜
潘虹
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Shanghai Tiqiao Textile & Yarn Dyeing Co Ltd
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Shanghai Tiqiao Textile & Yarn Dyeing Co Ltd
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Priority to CN201810991127.2A priority Critical patent/CN109281174A/en
Publication of CN109281174A publication Critical patent/CN109281174A/en
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    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/10Patterned fabrics or articles
    • D04B1/102Patterned fabrics or articles with stitch pattern
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    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/10Patterned fabrics or articles
    • D04B1/12Patterned fabrics or articles characterised by thread material
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
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    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
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    • D06B3/00Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
    • D06B3/10Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
    • D06B3/18Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
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    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00Heating or cooling textile fabrics
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    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/165Ethers
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    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246Esters of unsaturated carboxylic acids
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    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256Sulfonated compounds esters thereof, e.g. sultones
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    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325Amines
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    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
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    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
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    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
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    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
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    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic
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    • D06M2101/16Synthetic fibres, other than mineral fibres
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    • D06M2101/22Polymers or copolymers of halogenated mono-olefins
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    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35Abrasion, pilling or fibrillation resistance
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    • D10B2201/00Cellulose-based fibres, e.g. vegetable fibres
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  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses a kind of anti pillings to imitate woollen fabric and preparation method thereof, which includes: that (1) prepares the first yarn and the second yarn;(2) fabric is weaved: being chosen the first yarn and the second yarn using thickness needle alternating structure and is carried out positive and negative intertexture weaving into fabric fabric by braider;(3) it dyes: above-mentioned fabric fabric being dyed using the dye of positive ion and reactive dye;(4) fabric after dyeing is first carried out anti pilling processing by Anti-Pilling Finishes again after soft treatment;(5) post-process: by the fabric after above-mentioned dyeing through tentering setting, perching, clot to get.The anti pilling of the method for the present invention preparation imitates woollen fabric, can imitate out the rough style of woollen sweater, while improving fabric elasticity using cotton yarn weaving, elastic good, reverse side exquisiteness, can wear next to the skin, improve pilling effects compared to wool fabric, and be not easy to fluff, it is at low cost.

Description

A kind of anti pilling imitates woollen fabric and preparation method thereof
Technical field
The invention belongs to textile technology fields, are related to a kind of imitative woollen fabric, and in particular to a kind of imitative hair needle of anti pilling Knitted fabric and preparation method thereof.
Background technique
Human use's wool can be traced to the Neolithic Age, be propagated from the Central Asia to Mediterranean and other parts of the world, then at For Asia-Europe main textile raw material.Important source material of the wool as textile industry, it has, and elasticity is good, hygroscopicity is strong, warmth retention property The advantages that good.Wool textile is famous with its luxurious graceful, natural style comfortable and easy to wear, and especially cashmere has " soft Huang The good name of gold ".
Because wool fiber is soft and flexible, warmth retention property is good, can be used for making the weaving such as woollen goods, knitting wool, woollen blanket, felting Product, wool product has the features such as good hand feeling, warmth retention property are good, comfortable and easy to wear, but the cost of wool textile is much larger than cotton system Product, and wool textile is not easy to maintain, has been easy small ball top, has damaged by worms, size is unstable, wool textile there is also yarn count compared with It is thick very thick and heavy, the problems such as wool product other than cashmere should not be worn next to the skin, also because of its natural protein fibre resource Limited, the relationship of weaving structure, there is also the problems such as elastic bad, taking is not high for woven wool fabric.
In this regard, having had developed a variety of wool-like fabrics at present, but most of wool-like fabrics all have the following problems: 1) using Yarn count it is thicker, should not wear next to the skin, and very thick and heavy;2) fine because of component ratio, the relationship of spinning system that it uses yarn Property relationship is tieed up, anti pilling index is bad, and easily fluffing;3) because of the relationship of its weaving structure, fabric elasticity is bad, it is difficult to beat Reason, taking are poor.Therefore, it for current wool-like fabric, is improved up for further.
Summary of the invention
The technical problem to be solved by the present invention is to be directed to the above problem in the prior art, propose that a kind of anti pilling imitates hair It is knitted fabric and preparation method thereof.
The present invention is directed to by yarn than, spinning system, weaving technology, dyeing and finishing technology, dyeing and finishing post-processing grind Study carefully and research of technique, and be aided with the alternate structure of thickness needle, captures wool-like fabric in raw material, spinning, weaving, dyeing and final finishing All technical problems and key problem in technology in the process, the fabric for promoting imitative wool style for textile industry provide technical branch It holds, expands the application range of its product.
To achieve the above object, the invention adopts the following technical scheme:
The first aspect of the invention is to provide a kind of preparation method of imitative woollen fabric of anti pilling, specifically includes as follows Step:
(1) prepare yarn: using polyester fiber for the covering yarn of yarn core outsourcing cotton fiber is the first yarn;With 20-30tex Cotton fiber and polytetrafluoroethylene fibre and twist, be then coated on spinning machine and viscose rayon carries out wraping spinning using two-way Obtain the second yarn;
(2) it weaves: choosing the first yarn and the second yarn using thickness needle alternating structure and reciprocal cross is carried out by braider At fabric, the fineness of positive and negative yarn is different for weaving, wherein odd number needle successively by flotation line, lower tuck, upper tuck, flotation line, Flotation line, upper lopping 6 weaving structures composition circulation, even number needle successively by lower lopping, lower lopping, flotation line, lower lopping, lower lopping, 6 weaving structure composition circulations of flotation line;
(3) dye: above-mentioned fabric is dyed using the dye of positive ion and reactive dye, first at 60-70 DEG C into Anti- adding soda ash 4-12g/L is added in row pre-treatment 5-10min, after operating 8-10 minutes, carries out the dye of positive ion and reactive dye are same One-bath two-step process dyeing;It reuses the compound dyeing auxiliaries of 10-50% and does fixation treatment, in 50-85 DEG C of dipping 15-25min, hot water wash- Cold water is washed, drying;
(4) Anti-Pilling Finishes: by the fabric after dyeing first after soft treatment, it is placed in that bath raio is 1:5-10, temperature is Anti pilling auxiliary agent is added with the amount of 30~70g/L in 50-70 DEG C of solution, an immersing and rolling carries out Anti-Pilling Finishes, pick-up 60 ~70%, 13~17m/min of speed;
(5) it post-processes: the fabric after above-mentioned dyeing is imitated into knitting woollen face through tentering setting, perching, clot to get anti pilling Material.
Further, the thickness ratio of positive and negative yarn described in step (2) is in 1:1-3:1.
Further, it needs fabric losing hair, unhairing processing by carrying out ferment enzyme before step (3) dyeing.
Further, compound dyeing auxiliaries described in step (3) is by 10-15 parts of cetylpyridinium chlorides, 5-10 parts of bromines Change cetyl pyridinium, 8-12 parts of dodecyl trimethyl ammonium sulfates, 6-7 parts of γ-glycidyl ether trimethoxy silanes, 15-25 parts of Sodium Polyacrylates, 14-20 parts of diethylenetriamines, 4-5 parts of polyoxyethylene stearic acid esters, 3-9 parts of vinylsiloxanes, 7-8 parts of zinc stearates, 2-4 parts of ammonium molybdates and 6-7 parts of dodecanedioic acid compositions.
It is further preferred that the compound dyeing auxiliaries preparation method includes: by 10-15 parts of cetylpyridinium chlorides, 5- 10 parts of brocides, 8-12 parts of dodecyl trimethyl ammonium sulfates, 6-7 parts of γ-glycidyl ether trimethoxy Silane, 15-25 part Sodium Polyacrylate, 14-20 parts of diethylenetriamine mixing, are then slowly added to 4-5 parts of stearic acid polyoxies simultaneously Vinyl acetate, 3-9 part vinylsiloxane, 7-8 parts of zinc stearates, 2-4 parts of ammonium molybdates, 6-7 parts of dodecanedioic acids are thrown in 5-7 minutes Material finishes, and continuess to mix 10-15 minutes, compound dyeing auxiliaries is made.
Further, anti pilling auxiliary agent described in step (4) is by 3-6 parts of polyethylene glycol, hydroxyethyl methacrylate 5-11 Part, 4-7 parts of allyl glycidyl ether, N- oleoyl -4-9 parts of N methyl taurine sodium, 2-3 parts of γ-glycidyl ether three Methoxy silane, 15-25 part Sodium Polyacrylate and 14-20 parts of diethylenetriamine compositions.
Further, tentering described in step (4) shapes specifically comprises the processes of: and 120 DEG C -160 DEG C of temperature, fixing time 40-100 seconds, overfeed ratio 20-50%.
Further, soft treatment described in step (4) is handled fabric in overflow dyeing machine, technique are as follows: have Machine silicone softener: 0.5%-2%;Citric acid: 0.5-1g/L;Bath raio: 1:8-1:12;Temperature: 40 DEG C -50 DEG C;Time: 15- 30min。
Further, in tentering setting process described in step (5) shaping liquid contain 6-8g/L hydrophilic silicone oil T718, The moisture absorbing and sweat releasing agent PSR of 4g/L, setting temperature are 165-185 DEG C, speed 10-15m/min.
The anti pilling that the second aspect of the invention is to provide a kind of above method preparation imitates woollen fabric.
The anti pilling imitates woollen fabric, by special weaving process by polyester fiber fiber and cotton fiber cladding, friendship It knits to form the fabric with wool style, while avoiding the deficiency of previous wool fabric, for example wool fabric elasticity is bad, easy Pilling fluffing can not be worn next to the skin;Using 2 different one threads of positive and negative thickness of yarn degree, thickness needle is used in weaving The method of alternating structure forms the style that front is rough, reverse side is fine and smooth by the different coil length in two sides;Fabric outer layer with Woollen sweater style is similar, and inner layer is fine and smooth, can wear next to the skin.
The present invention by adopting the above technical scheme, compared with prior art, has the following technical effect that
Compared with prior art, the beneficial effects of the present invention are: wool can be imitated out according to the fabric that this method weaves The rough style of shirt, while fabric Comfortable elastic is improved using cotton yarn weaving, elasticity is good, reverse side is fine and smooth, it can wear next to the skin, Improve pilling effects compared to wool fabric, and is not easy to fluff.In addition, by using special anti pilling auxiliary agent and compound dyeing auxiliaries The style of dyeing fabric performance and easy pilling can not only be improved well, and feel fabric with good hair, it is at low cost.
Specific embodiment
The present invention is described in more detail below by specific embodiment, for a better understanding of the present invention, But following embodiments, it is not intended to limit the scope of the invention.
1 anti pilling of embodiment imitates the preparation of woollen fabric
(1) prepare yarn: using polyester fiber for the covering yarn of yarn core outsourcing cotton fiber is the first yarn;With 20-30tex Cotton fiber and polytetrafluoroethylene fibre and twist, be then coated on spinning machine and viscose rayon carries out wraping spinning using two-way Obtain the second yarn;
(2) it weaves: choosing the first yarn and the second yarn using thickness needle alternating structure and reciprocal cross is carried out by braider At fabric, the fineness of positive and negative yarn is different for weaving, wherein odd number needle successively by flotation line, lower tuck, upper tuck, flotation line, Flotation line, upper lopping 6 weaving structures composition circulation, even number needle successively by lower lopping, lower lopping, flotation line, lower lopping, lower lopping, 6 weaving structure composition circulations of flotation line;The thickness ratio of positive and negative yarn is in 1:1.
(3) it dyes: above-mentioned fabric being dyed using the dye of positive ion and reactive dye, before being carried out first at 70 DEG C 8min is handled, anti-adding soda ash 8g/L is added and carries out the dye of positive ion and the same one-bath two-step process dyeing of reactive dye after operating 8 minutes; It reuses 30% compound dyeing auxiliaries and does fixation treatment, in 80-85 DEG C of dipping 25min, hot water wash-cold water is washed, drying;In addition, dye Need to carry out fabric ferment enzyme erosion hair, unhairing processing before color;The compound dyeing auxiliaries by 12 parts of cetylpyridinium chlorides, 8 parts of brocides, 10 parts of dodecyl trimethyl ammonium sulfates, 6 parts of γ-glycidyl ether trimethoxy silanes, 15 parts of Sodium Polyacrylates, 16 parts of diethylenetriamines, 4 parts of polyoxyethylene stearic acid esters, 5 parts of vinylsiloxanes, 8 parts of stearic acid Zinc, 3 parts of ammonium molybdates and 6 parts of dodecanedioic acid compositions.
(4) Anti-Pilling Finishes: by the fabric after dyeing first after soft treatment, it is placed in that bath raio is 1:10, temperature is 70 DEG C Solution in handle, anti pilling auxiliary agent, an immersing and rolling, pick-up 70%, 13~17m/ of speed are added with the amount of 30~70g/L min;The anti pilling auxiliary agent is by 3 parts of polyethylene glycol, 11 parts of hydroxyethyl methacrylate, 4-7 parts of allyl glycidyl ether, N- Oleoyl -9 parts of N methyl taurine sodium, 3 parts of γ-glycidyl ether trimethoxy silanes, 25 parts of Sodium Polyacrylates and 20 parts Diethylenetriamine composition;
(5) it post-processes: the fabric after above-mentioned dyeing is imitated into knitting woollen face through tentering setting, perching, clot to get anti pilling Material.
The soft treatment is handled fabric in overflow dyeing machine, technique are as follows: silicone softening agent: 2%;Lemon Acid: 0.8g/L;Bath raio: 1:12;Temperature: 40 DEG C;Time: 25min.The tentering setting specifically comprises the processes of: 160 DEG C of temperature, The preboarding time 100 seconds, overfeed ratio 30%.Shaping liquid contains hydrophilic silicone oil T718,4g/ of 8g/L in the tentering setting process The moisture absorbing and sweat releasing agent PSR of L, setting temperature are 170 DEG C, speed 15m/min.
2 anti pilling of embodiment imitates the preparation of woollen fabric
(1) prepare yarn: using polyester fiber for the covering yarn of yarn core outsourcing cotton fiber is the first yarn;With 20-30tex Cotton fiber and polytetrafluoroethylene fibre and twist, be then coated on spinning machine and viscose rayon carries out wraping spinning using two-way Obtain the second yarn;
(2) it weaves: choosing the first yarn and the second yarn using thickness needle alternating structure and reciprocal cross is carried out by braider At fabric, the fineness of positive and negative yarn is different for weaving, wherein odd number needle successively by flotation line, lower tuck, upper tuck, flotation line, Flotation line, upper lopping 6 weaving structures composition circulation, even number needle successively by lower lopping, lower lopping, flotation line, lower lopping, lower lopping, 6 weaving structure composition circulations of flotation line;The thickness ratio of positive and negative yarn is in 1.5:1.
(3) it dyes: above-mentioned fabric being dyed using the dye of positive ion and reactive dye, before being carried out first at 70 DEG C 8min is handled, anti-adding soda ash 8g/L is added, operating after ten minutes, carries out the dye of positive ion and reactive dye and contaminates with one-bath two-step process Color;It reuses the compound dyeing auxiliaries of 10-50% and does fixation treatment, in 95 DEG C of dipping 15min, hot water wash-cold water is washed, drying;This Outside, need to carry out fabric ferment enzyme erosion hair, unhairing processing before dyeing;The compound dyeing auxiliaries is same as Example 1;
(4) Anti-Pilling Finishes: by the fabric after dyeing first after soft treatment, be placed in bath raio be 1:10, temperature 50 DEG C solution in handle, anti pilling auxiliary agent, an immersing and rolling, pick-up 70%, speed 17m/min are added with the amount of 30g/L;It is described Anti pilling auxiliary agent is by 6 parts of polyethylene glycol, 10 parts of hydroxyethyl methacrylate, 6 parts of allyl glycidyl ether, N- oleoyl-N- 6 parts, 2 parts γ-glycidyl ether trimethoxy silanes of N-methyltaurine sodium, 20 parts of Sodium Polyacrylates and 18 parts of diethylenetriamines Composition.
(5) it post-processes: the fabric after above-mentioned dyeing is imitated into knitting woollen face through tentering setting, perching, clot to get anti pilling Material.
The soft treatment is handled fabric in overflow dyeing machine, technique are as follows: silicone softening agent: 1.2%;Lemon Lemon acid: 1g/L;Bath raio: 1:12;Temperature: 50 DEG C;Time: 20min.The tentering setting specifically comprises the processes of: 150 DEG C of temperature, The preboarding time 60 seconds, overfeed ratio 40%.Shaping liquid contains hydrophilic silicone oil T718,4g/L of 6g/L in the tentering setting process Moisture absorbing and sweat releasing agent PSR, setting temperature be 185 DEG C, speed 12m/min.
3 anti pilling of embodiment imitates the preparation of woollen fabric
(1) prepare yarn: using polyester fiber for the covering yarn of yarn core outsourcing cotton fiber is the first yarn;With 20-30tex Cotton fiber and polytetrafluoroethylene fibre and twist, be then coated on spinning machine and viscose rayon carries out wraping spinning using two-way Obtain the second yarn;
(2) it weaves: choosing the first yarn and the second yarn using thickness needle alternating structure and reciprocal cross is carried out by braider At fabric, the fineness of positive and negative yarn is different for weaving, wherein odd number needle successively by flotation line, lower tuck, upper tuck, flotation line, Flotation line, upper lopping 6 weaving structures composition circulation, even number needle successively by lower lopping, lower lopping, flotation line, lower lopping, lower lopping, 6 weaving structure composition circulations of flotation line;The thickness ratio of positive and negative yarn is in 2:1.
(3) it dyes: above-mentioned fabric being dyed using the dye of positive ion and reactive dye, before being carried out first at 70 DEG C 8min is handled, anti-adding soda ash 8g/L is added, operating after ten minutes, carries out the dye of positive ion and reactive dye and contaminates with one-bath two-step process Color;It reuses 50% compound dyeing auxiliaries and does fixation treatment, in 85 DEG C of dipping 15min, hot water wash-cold water is washed, drying;In addition, dye Need to carry out fabric ferment enzyme erosion hair, unhairing processing before color;The compound dyeing auxiliaries is same as Example 1;
(4) Anti-Pilling Finishes: by the fabric after dyeing first after soft treatment, it is placed in that bath raio is 1:5, temperature is 50 DEG C It is handled in solution, anti pilling auxiliary agent, an immersing and rolling, pick-up 70%, speed 15m/min is added with the amount of 40g/L;It is described to resist Ball auxiliary agent is by 3 parts of polyethylene glycol, 8 parts of hydroxyethyl methacrylate, 6 parts of allyl glycidyl ether, N- oleoyl-N- methyl ox 5 parts, 3 parts γ-glycidyl ether trimethoxy silanes of sodium sulfonate, 22 parts of Sodium Polyacrylates and 15 parts of diethylenetriamine compositions.
(5) it post-processes: by the fabric after above-mentioned dyeing through soft treatment, tentering setting, perching, clot to get anti pilling Imitative woollen fabric.
The soft treatment is handled fabric in overflow dyeing machine, technique are as follows: silicone softening agent: 0.5%;Lemon Lemon acid: 0.6g/L;Bath raio: 1:8;Temperature: 50 DEG C;Time: 23min.The tentering setting specifically comprises the processes of: 155 DEG C of temperature, The preboarding time 100 seconds, overfeed ratio 50%.Shaping liquid contains hydrophilic silicone oil T718,4g/ of 8g/L in the tentering setting process The moisture absorbing and sweat releasing agent PSR of L, setting temperature are 170 DEG C, speed 15m/min.
Anti pilling made from 1-3 of the embodiment of the present invention imitates woollen fabric, by special weaving process by polyester fiber Fiber and cotton fiber interweave with forming the fabric with wool style, while avoiding the deficiency of previous wool fabric, such as wool Fabric elasticity is bad, easy pilling fluffing, can not wear next to the skin;Using 2 different one threads of positive and negative thickness of yarn degree, knitting The wind that front is rough, reverse side is fine and smooth is formed by the different coil length in two sides using the method for thickness needle alternating structure when making Lattice;Fabric outer layer is similar to woollen sweater style, and inner layer is fine and smooth, can wear next to the skin.
Every conventional index of woollen fabric is imitated anti pilling made from above-described embodiment 1, embodiment 2 and embodiment 3 It is tested, test result is as follows for specific each embodiment:
1) washing shrinkage: directly to -2.4%, lateral -1%;
2) color fastness 4-5 grades of washing, it is 4-5 grades of fastness to perspiration, 4-5 grades of color fastness to water, 4 grades of dry friction color fastness, wet 3 grades of crock fastness, 4 grades of fastness to light;
3) rupture strength 80psi, 4 grades of anti pilling, PH6.9;
4) water imbibition 1 second, moisture content residual 10% in rapid-drying properties 30 minutes;
5) content of formaldehyde :≤25mg/kg.
Specific embodiments of the present invention are described in detail above, but it is merely an example, the present invention is simultaneously unlimited It is formed on particular embodiments described above.To those skilled in the art, any couple of present invention carries out equivalent modifications and Substitution is also all among scope of the invention.Therefore, without departing from the spirit and scope of the invention made by equal transformation and Modification, all should be contained within the scope of the invention.

Claims (10)

1. the preparation method that a kind of anti pilling imitates woollen fabric, which is characterized in that comprising steps of
(1) prepare yarn: using polyester fiber for the covering yarn of yarn core outsourcing cotton fiber is the first yarn;With the cotton of 20-30tex Fiber and polytetrafluoroethylene fibre are simultaneously twisted, and are then carried out wraping spinning using two-way be coated on spinning machine with viscose rayon and are obtained the Two yarns;
(2) fabric is weaved: being chosen the first yarn and the second yarn using thickness needle alternating structure and is carried out reciprocal cross by braider At fabric, the fineness of positive and negative yarn is different for weaving, wherein odd number needle successively by flotation line, lower tuck, upper tuck, flotation line, Flotation line, upper lopping 6 weaving structures composition circulation, even number needle successively by lower lopping, lower lopping, flotation line, lower lopping, lower lopping, 6 weaving structure composition circulations of flotation line;
(3) it dyes: above-mentioned fabric being dyed using the dye of positive ion and reactive dye, before being carried out first at 60-70 DEG C 5-10min is handled, anti-adding soda ash 4-12g/L is added, after operating 8-10 minutes, carries out the dye of positive ion and reactive dye with bath two Footwork dyeing;It reuses the compound dyeing auxiliaries of 10-50% and does fixation treatment, in 50-85 DEG C of dipping 15-25min, hot water wash-cold water It washes, dries;
(4) Anti-Pilling Finishes: by the fabric after dyeing first after soft treatment, be placed in bath raio be 1:5-10, temperature 50-70 DEG C solution in anti pilling auxiliary agent added with the amount of 30~70g/L, an immersing and rolling carries out Anti-Pilling Finishes, pick-up 60~ 70%, 13~17m/min of speed;
(5) it post-processes: the fabric after above-mentioned dyeing is imitated into woollen fabric through tentering setting, perching, clot to get anti pilling.
2. preparation method according to claim 1, which is characterized in that the thickness ratio of positive and negative yarn described in step (2) exists 1:1-3:1.
3. preparation method according to claim 1, which is characterized in that need fabric carrying out ferment before step (3) dyeing Enzyme loses hair, unhairing processing.
4. preparation method according to claim 1, which is characterized in that compound dyeing auxiliaries described in step (3) is by 10-15 Part cetylpyridinium chloride, 5-10 parts of brocides, 8-12 parts of dodecyl trimethyl ammonium sulfates, 6-7 parts of γ- Glycidyl ether trimethoxy silane, 15-25 part Sodium Polyacrylate, 14-20 parts of diethylenetriamines, 4-5 parts of stearic acid polyoxies Vinyl acetate, 3-9 part vinylsiloxane, 7-8 parts of zinc stearates, 2-4 parts of ammonium molybdates and 6-7 parts of dodecanedioic acid compositions.
5. the preparation method according to claim 4, which is characterized in that the compound dyeing auxiliaries preparation method includes: by 10- 15 parts of cetylpyridinium chlorides, 5-10 parts of brocides, 8-12 parts of dodecyl trimethyl ammonium sulfates, 6-7 parts γ-glycidyl ether trimethoxy silane, 15-25 part Sodium Polyacrylate, 14-20 parts of diethylenetriamine mixing, then simultaneously It is slowly added to 4-5 parts of polyoxyethylene stearic acid esters, 3-9 parts of vinylsiloxanes, 7-8 parts of zinc stearates, 2-4 parts of ammonium molybdates, 6-7 Part dodecanedioic acid, feeds intake in 5-7 minutes and finishes, continues to mix 10-15 minutes, compound dyeing auxiliaries is made.
6. preparation method according to claim 1, which is characterized in that anti pilling auxiliary agent described in step (4) is by poly- second two 3-6 parts of alcohol, 5-11 parts of hydroxyethyl methacrylate, 4-7 parts of allyl glycidyl ether, N- oleoyl-N methyl taurine sodium 4-9 parts, 2-3 parts of γ-glycidyl ether trimethoxy silanes, 15-25 parts of Sodium Polyacrylates and 14-20 parts of diethylenetriamine groups At.
7. preparation method according to claim 1, which is characterized in that the concrete technology of the setting of tentering described in step (4) Are as follows: 120 DEG C -160 DEG C of temperature, the preboarding time 40-100 seconds, overfeed ratio 20-50%.
8. preparation method according to claim 1, which is characterized in that soft treatment described in step (4) is in overflow dyeing Fabric is handled in machine, technique are as follows: silicone softening agent: 0.5%-2%;Citric acid: 0.5-1g/L;Bath raio: 1:8-1: 12;Temperature: 40 DEG C -50 DEG C;Time: 15-30min.
9. preparation method according to claim 1, which is characterized in that shape in tentering setting process described in step (5) Liquid contains the moisture absorbing and sweat releasing agent PSR of hydrophilic silicone oil T718,4g/L of 6-8g/L, and setting temperature is 165-185 DEG C, speed 10- 15m/min。
10. as the anti pilling of any one of claim 1-9 the method preparation imitates woollen fabric.
CN201810991127.2A 2018-08-28 2018-08-28 A kind of anti pilling imitates woollen fabric and preparation method thereof Pending CN109281174A (en)

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CN115559051A (en) * 2022-09-29 2023-01-03 宁波大千纺织品有限公司 Cellulose acetylated diacetate super-soft light anti-pilling knitted fabric and preparation method thereof

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