CN105496816A - Strippable fluorescent nail lacquer gel and preparation process thereof - Google Patents
Strippable fluorescent nail lacquer gel and preparation process thereof Download PDFInfo
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- CN105496816A CN105496816A CN201610038628.XA CN201610038628A CN105496816A CN 105496816 A CN105496816 A CN 105496816A CN 201610038628 A CN201610038628 A CN 201610038628A CN 105496816 A CN105496816 A CN 105496816A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/434—Luminescent, Fluorescent; Optical brighteners; Photosensitizers
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- Polymers & Plastics (AREA)
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
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Abstract
The invention discloses strippable fluorescent nail lacquer gel and a preparation process thereof. The strippable nail lacquer gel comprises 50-80 parts of UV curing resin A, 50-80 parts of UV curing resin B, 0.05-0.1 part of levelling agents, 1-10 parts of wetting agent, 0.2-1 part of defoaming agents, 0.1-10 parts of fluorescent UV color paste, 3-5 parts of photoinitiators A and 3-5 parts of photoinitiators B by weight. After being coated with a film, the strippable nail lacquer gel can be fast cured for 1-10 seconds through 365nm UV irradiation and can be widely used in the technical field of manicure of all kinds of crowds.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of peelable fluorescence nail polish glue and preparation technology thereof, this peelable nail polish glue is specially adapted to the solidification of 365nmUV-LED light source irradiation.
Background technology
Ms to manicure like come from one and have deep love for.Nail polish glue is applied to fingernail with instrument when using, and after common UV light source light source treatment with irradiation, cross-linking polymerization occurs, the nail polish adhesive curing thing of generation beautiful in colour, glittering and translucent full, change irregularly infinite, be the favorite of ladies.Compared with the light source curing mode of common UV, UV-LED light source has the plurality of advantages such as luminous efficiency is high, the life-span is long, response speed is fast, heat release is few, energy-saving and environmental protection, substitutes common UV light source gradually.Along with the quickening that the abundant of city life and rhythm of life convert, ladies have liked the fingernail of allegro conversion oneself.Peelable nail polish glue is easy to use, peels off when needing to take off without cleaner with regard to whole of energy, easily, is particularly suitable for child and uses.But current peelable nail polish glue is generally aqueous, transparent water of need arranging in pairs or groups or sealing water use; Not as oiliness nail polish glue in persistence, drying is comparatively slow, and peelable nail polish glue generally with the addition of peelable component in the formula of nail polish glue, makes troubles to the production of nail polish glue and use.
Based on above background, need to develop a kind of can fast setting, there is decorative effect simultaneously, have from peeling off that component, peeling effect are good, the peelable nail polish glue with fluorescent effect and preparation technology thereof.
Summary of the invention
One of the object of the invention provide a kind of can fast setting, there is decorative effect simultaneously, having from peeling off the peelable fluorescence nail polish glue that component, peeling effect are good, have fluorescent effect.
Two of the object of the invention provides the preparation technology of above-mentioned a kind of peelable fluorescence nail polish glue.
Technical scheme of the present invention is specifically described as follows.
The invention provides a kind of peelable fluorescence nail polish glue, calculate by weight, its raw material composition and content as follows:
Wherein:
The chemical constitution of described UV cured resin A is as follows:
Wherein: m is the integer within the scope of 1-50; N is the integer within the scope of 1-50;
Described fluorescence UV mill base is the fluorescence UV color slurry of shades of colour comprising sky blue, fluorescence green, raw white, phloxine, scarlet, ultramarine blue, cologne earth, black;
Described levelling agent is selected from one or more in enlightening height TegoGlide410, German BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347, BYK-348;
Described wetting agent is the NP-100 of LG-DOW company;
Described light trigger A is selected from one or more in BASF Irgacure1173, Irgacure184D, IrgacureTPO, Irgacure369, Irgacure651, Irgacure379, Irgacure819, Irgacure907 or macromolecular photoinitiator EsacureKIP150;
Described photoinitiator b is selected from one or more in BASF BASF light trigger Irgacure2959, IRGACURE500 or IRGACURE819DW.
In the present invention, UV cured resin B is double pentaerythritol methacrylate, diethylene glycol diacrylate, oxolane acrylate, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylate, two-trimethylolpropane tetra-acrylate, three (2-ethoxy) isocyanuric acid triacrylate, pentaerythritol triacrylate, ethoxyquin trimethylolpropane triacrylate, third oxidation trimethylolpropane triacrylate, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, Tricyclodecane Dimethanol diacrylate, third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane triacrylate, hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone acrylate, and one or more in vinyl ethers monomer.
In the present invention, described defoamer is selected from one or more in German BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044 or BYK-038.
In the present invention, described UV cured resin A calculates by weight, its composition and content as follows:
Described UV cured resin A is prepared as follows:
Methyl and phenyl hydrogen-containing silicon oil and trimethylolpropane triacrylate are joined in reaction vessel in proportion; add polymerization inhibitor again; pass into protective gas; stir and heat, being warming up to 60 ~ 80 DEG C, adding catalyst; stir lower constant temperature 3 ~ 5h; stop heating, treat that temperature drops to room temperature, obtain UV cured resin A.
The present invention also provides a kind of preparation technology of peelable fluorescence nail polish glue, and concrete steps are as follows:
According to formula, wetting agent, levelling agent, defoamer and fluorescence UV mill base is added in the high speed dispersor controlling rotating speed 300-1700r/min, after disperseing 60-120min under 600-800r/min rotating speed, rotating speed is down to 300r/min, add UV cured resin A, UV cured resin B and light trigger A, photoinitiator b, continue dispersion 30-150min, mix homogeneously, namely obtains peelable fluorescence nail polish glue.
Useful achievement of the present invention is as follows:
One of the present invention peelable fluorescence nail polish glue, containing numerous cross-linked acrylic acid ester structure, achieves fast setting under 365nmUV-LED irradiates.Through the surface of the microscope slide of the peelable nail polish glue of UV nail polish light irradiation precoating after the peelable nail polish glue film of gained of the present invention, according to the fingers-touch method (surface of the peelable nail polish glue of the cured a period of time that press...withes one's finger, using tack-free as completely crued standard, when solidifying completely with peelable nail polish glue, the shortest time used characterizes), after testing, the hardening time of quick-drying peelable nail polish glue of the present invention is 1-5s.
Further, one of the present invention peelable fluorescence nail polish glue, the UV cured resin A molecular structure as main film forming substance is organosilicon structures, there is very low surface energy, reduce the interaction between film and base material, make it to embody better rippability, do not need to add stripping auxiliary agent again.The CMT5104 electronic tension tester that peel strength adopts Shenzhen newly to think carefully company at room temperature carries out the stripping test of 180 ° by GB/T2790-1995 standard " adhesive 180 ° of peeling strength test methods ", draw speed 50mm/min; Recording peel strength is 0.21 ~ 0.26kN/m;
Further, peelable nail polish glue fluorescence UV mill base and peelable other components of nail polish glue of gained of the present invention have good dispersibility and stability, and after solidification, color is homogeneous, fluorescence intensity is high.
In sum, one of the present invention peelable fluorescence nail polish glue, has higher hardness of film, gloss after film.And its preparation method due to technique simple, easy to control, the maturation that therefore possesses skills, the feature such as quick, efficient, and be suitable for suitability for industrialized production.
Detailed description of the invention
Below by embodiment, the present invention is described in further detail, but do not limit the present invention.
In the raw material that various embodiments of the present invention are used except the special producer that shows and specification, other raw materials are commercially available, and specification is chemical pure.
The model of the various equipment that the present invention is used and the information of manufacturer as follows:
GFJ-0.4 type high speed dispersor, Shanghai Xin Nuo instrument and equipment company limited produces.
Embodiment 1
A kind of peelable fluorescence nail polish glue, calculates by weight, its raw material composition and content as follows:
Wherein: described UV cured resin A calculates by weight, its composition and content as follows:
Described UV cured resin A is prepared as follows:
10 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of trimethylolpropane triacrylates are joined in the there-necked flask of 500ml; add the polymerization inhibitor of 0.01 part again; pass into protective gas; stir and heat, being warming up to 60 DEG C, adding 0.03 part of catalyst; stir lower constant temperature 3h; stop heating, treat that flask temperature drops to room temperature, obtain UV cured resin A.
UV cured resin B be double pentaerythritol methacrylate, diethylene glycol diacrylate, isobornyl acrylate in mass ratio 1:1:1 composition mixture;
Described levelling agent is enlightening height TegoGlide410;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the mixture of German BYK-035, BYK-037 1:1 in mass ratio;
Described fluorescence UV mill base is fluorescence green fluorescence UV color slurry;
Described light trigger A be BASF BASF light trigger Irgacure1173, IrgacureTPO, Irgacure907 in mass ratio 1:1:1 composition mixture;
Described photoinitiator b be BASF BASF light trigger Irgacure2959, IRGACURE500 in mass ratio 1:1 composition mixture;
In the present embodiment, a kind of preparation technology of peelable fluorescence nail polish glue, specifically comprises the steps:
According to formula, 1 part of wetting agent, 0.05 part of levelling agent, 0.2 part of defoamer and 1 part of fluorescence UV mill base is added in the GFJ-0.4 type high speed dispersor (Shanghai Xin Nuo instrument and equipment company limited) controlling rotating speed 300r/min, after disperseing 60min under 600r/min rotating speed, rotating speed is down to 300r/min, add 50 parts of UV cured resin A, 50 parts of UV cured resin B, 3 parts of light trigger A and 3 part photoinitiator bs, continue dispersion 30min, mix homogeneously, namely obtains peelable fluorescence nail polish glue.
Through the surface of the microscope slide of the peelable nail polish glue of UV-LED light irradiation precoating through 365nm after the peelable fluorescence nail polish glue film of the present embodiment gained, according to the fingers-touch method (surface of the peelable nail polish glue of the cured a period of time that press...withes one's finger, using tack-free as completely crued standard, when solidifying completely with peelable nail polish glue, the shortest time used characterizes), after testing, the hardening time of quick-drying peelable nail polish glue of the present invention is 5s.Film still sends green fluorescence at night.
The CMT5104 electronic tension tester that peel strength adopts Shenzhen newly to think carefully company at room temperature carries out the stripping test of 180 ° by GB/T2790-1995 standard " adhesive 180 ° of peeling strength test methods ", draw speed 50mm/min; Recording peel strength is 0.26kN/m;
After the peelable nail polish glue film of embodiment 1 invention gained, there is curing rate faster, easily peel off.
Embodiment 2
A kind of peelable fluorescence nail polish glue, calculates by weight, its raw material composition and content as follows:
Wherein: described UV cured resin A calculates by weight, its composition and content as follows:
Described UV cured resin A is prepared as follows: join in the there-necked flask of 500ml by 20 parts of methyl and phenyl hydrogen-containing silicon oils and 40 parts of trimethylolpropane triacrylates; add the polymerization inhibitor of 0.02 part again; pass into protective gas; stir and heat, being warming up to 80 DEG C, adding 0.05 part of catalyst; stir lower constant temperature 5h; stop heating, treat that flask temperature drops to room temperature, obtain UV cured resin A.
Described UV cured resin B be double pentaerythritol methacrylate, diethylene glycol diacrylate, isobornyl acrylate in mass ratio 1:2:2 composition mixture;
Described levelling agent be German BYK-345, BYK-346 in mass ratio 1:1 composition mixture;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is German BYK Bi Ke BYK-024, BYK-025, BYK-035 is the mixture of 1:1:1 composition in mass ratio;
Described fluorescence UV mill base is phloxine fluorescence UV color slurry;
Described light trigger A be BASF BASF light trigger IrgacureTPO, Irgacure369, Irgacure819 in mass ratio 2:1:1 composition mixture;
Described photoinitiator b be BASF BASF light trigger Irgacure2959, IRGACURE500 in mass ratio 2:1 composition mixture;
In the present embodiment, a kind of preparation technology of peelable fluorescence nail polish glue, specifically comprises the steps:
According to formula, 10 parts of wetting agent, 0.1 part of levelling agent, 1 part of defoamer and 10 parts of fluorescence UV mill bases are added in the GFJ-0.4 type high speed dispersor (Shanghai Xin Nuo instrument and equipment company limited) controlling rotating speed 1700r/min, after disperseing 120min under 800r/min rotating speed, rotating speed is down to 300r/min, add 80 parts of UV cured resin A, 80 parts of UV cured resin B, 5 parts of light trigger A and 5 part photoinitiator bs, continue dispersion 150min, mix homogeneously, namely obtains peelable fluorescence nail polish glue.
Through the surface of the microscope slide of the peelable nail polish glue of UV-LED light irradiation precoating of 365nm after the peelable fluorescence nail polish glue film of the present embodiment gained, according to the fingers-touch method (surface of the peelable nail polish glue of the cured a period of time that press...withes one's finger, using tack-free as completely crued standard, when solidifying completely with peelable nail polish glue, the shortest time used characterizes), after testing, the hardening time of quick-drying peelable nail polish glue of the present invention is 1s.Film still sends pink fluorescence at night.
The CMT5104 electronic tension tester that peel strength adopts Shenzhen newly to think carefully company at room temperature carries out the stripping test of 180 ° by GB/T2790-1995 standard " adhesive 180 ° of peeling strength test methods ", draw speed 50mm/min; Recording peel strength is 0.21kN/m;
After the peelable fluorescence nail polish glue film of embodiment 2 invention gained, there is curing rate faster, there is good fissility and there is fluorescent effect.
In sum, containing numerous cross-linked structure after one of the present invention peelable fluorescence nail polish glue curing of coating, achieve fast setting on the one hand, the high speed curable of UV improves its curing rate, only has 1-5s; Easy stripping, peel strength is 0.21 ~ 0.26kN/m; Peelable nail polish glue fluorescence UV mill base and peelable other components of nail polish glue of gained have good dispersibility and stability, and after solidification, color is homogeneous, fluorescence intensity is high; Increase the intention function of goods.
Above said content be only the present invention conceive under basic explanation, and according to any equivalent transformation that technical scheme of the present invention is done, all should protection scope of the present invention be belonged to.
Claims (5)
1. a peelable fluorescence nail polish glue, is characterized in that, calculate by weight, its raw material composition and content as follows:
Wherein: the chemical constitution of described UV cured resin A is as follows:
Wherein: m is the integer within the scope of 1-50; N is the integer within the scope of 1-50;
Described fluorescence UV mill base is the fluorescence UV color slurry of shades of colour comprising sky blue, fluorescence green, raw white, phloxine, scarlet, ultramarine blue, cologne earth, black;
Described levelling agent is selected from one or more in enlightening height TegoGlide410, German BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347, BYK-348;
Described wetting agent is the NP-100 of LG-DOW company;
Described light trigger A is selected from one or more in BASF Irgacure1173, Irgacure184D, IrgacureTPO, Irgacure369, Irgacure651, Irgacure379, Irgacure819, Irgacure907 or macromolecular photoinitiator EsacureKIP150;
Described photoinitiator b is selected from one or more in BASF BASF light trigger Irgacure2959, IRGACURE500 or IRGACURE819DW.
2. peelable fluorescence nail polish glue according to claim 1, it is characterized in that, UV cured resin B is double pentaerythritol methacrylate, diethylene glycol diacrylate, oxolane acrylate, tetramethylol methane tetraacrylate, ethoxylated bisphenol A dimethylacrylate, two-trimethylolpropane tetra-acrylate, three (2-ethoxy) isocyanuric acid triacrylate, pentaerythritol triacrylate, ethoxyquin trimethylolpropane triacrylate, third oxidation trimethylolpropane triacrylate, ethoxyquin tetramethylol methane tetraacrylate, isobornyl acrylate, Tricyclodecane Dimethanol diacrylate, third oxidation neopentylglycol diacrylate, ethoxyquin trimethylolpropane triacrylate, hyperbranched polyester acrylic ester, alkoxy acrylic ester, carbonic acid mono acrylic ester, imidazole radicals mono acrylic ester, cyclic carbonate ester mono acrylic ester, epoxy silicone monomer, silicone acrylate, and one or more in vinyl ethers monomer.
3. peelable fluorescence nail polish glue according to claim 1, is characterized in that, described defoamer is selected from one or more in German BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044 or BYK-038.
4. peelable fluorescence nail polish glue according to claim 1, is characterized in that, described UV cured resin A calculates by weight, its composition and content as follows:
Described UV cured resin A is prepared as follows:
Methyl and phenyl hydrogen-containing silicon oil and trimethylolpropane triacrylate are joined in reaction vessel in proportion; add polymerization inhibitor again; pass into protective gas; stir and heat, being warming up to 60 ~ 80 DEG C, adding catalyst; stir lower constant temperature 3 ~ 5h; stop heating, treat that temperature drops to room temperature, obtain UV cured resin A.
5. a preparation technology for peelable fluorescence nail polish glue, it is characterized in that, concrete steps are as follows:
According to formula, wetting agent, levelling agent, defoamer and fluorescence UV mill base is added in the high speed dispersor controlling rotating speed 300-1700r/min, after disperseing 60-120min under 600-800r/min rotating speed, rotating speed is down to 300r/min, add UV cured resin A, UV cured resin B and light trigger A, photoinitiator b, continue dispersion 30-150min, mix homogeneously, namely obtains peelable fluorescence nail polish glue.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610038628.XA CN105496816B (en) | 2016-01-20 | 2016-01-20 | Peelable fluorescence nail polish glue and its preparation process |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610038628.XA CN105496816B (en) | 2016-01-20 | 2016-01-20 | Peelable fluorescence nail polish glue and its preparation process |
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| CN105496816A true CN105496816A (en) | 2016-04-20 |
| CN105496816B CN105496816B (en) | 2019-03-19 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108586754A (en) * | 2018-05-14 | 2018-09-28 | 中科广化（重庆）新材料研究院有限公司 | A kind of hyperbranched silicone acrylic resin and the preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0597630A (en) * | 1991-10-11 | 1993-04-20 | Kao Corp | Water-based nail enamel |
| JP2006327941A (en) * | 2005-05-23 | 2006-12-07 | Daito Kasei Kogyo Kk | Aqueous nail polish |
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
-
2016
- 2016-01-20 CN CN201610038628.XA patent/CN105496816B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0597630A (en) * | 1991-10-11 | 1993-04-20 | Kao Corp | Water-based nail enamel |
| JP2006327941A (en) * | 2005-05-23 | 2006-12-07 | Daito Kasei Kogyo Kk | Aqueous nail polish |
| CN105125421A (en) * | 2015-09-29 | 2015-12-09 | 上海应用技术学院 | UV solidified water-based strippable polish gum and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108586754A (en) * | 2018-05-14 | 2018-09-28 | 中科广化（重庆）新材料研究院有限公司 | A kind of hyperbranched silicone acrylic resin and the preparation method and application thereof |
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| CN105496816B (en) | 2019-03-19 |
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