CN105483703A - Manufacturing method of embedded type gold and silver double-color pattern crystal standing table - Google Patents

Manufacturing method of embedded type gold and silver double-color pattern crystal standing table Download PDF

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Publication number
CN105483703A
CN105483703A CN201510852401.4A CN201510852401A CN105483703A CN 105483703 A CN105483703 A CN 105483703A CN 201510852401 A CN201510852401 A CN 201510852401A CN 105483703 A CN105483703 A CN 105483703A
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China
Prior art keywords
inner core
gold
double
making method
silver
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Granted
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CN201510852401.4A
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CN105483703B (en
Inventor
冯正元
冯育华
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Nantong Haohanbang New Material Technology Co ltd
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Suzhou Venus Craft Plating Decoration Co Ltd
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Priority to CN201510852401.4A priority Critical patent/CN105483703B/en
Publication of CN105483703A publication Critical patent/CN105483703A/en
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Publication of CN105483703B publication Critical patent/CN105483703B/en
Expired - Fee Related legal-status Critical Current
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/48Electroplating: Baths therefor from solutions of gold

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Electrochemistry (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

The invention discloses a manufacturing method of an embedded type gold and silver double-color pattern crystal standing table. The method comprises the following steps that crystals are machined into an inner core and an outer ring arranged outside the inner core in a sleeving manner; a layer of bright copper is sputtered on the surface of the inner core; a silver film is sputtered on the side face of the inner core; the surface of the silver film is coated with photoresist, a hanging tool is arranged, gold plating is carried out on the front surface and the rear surface of the inner core, and gold plating films are obtained; the gold plating inner core is placed in acetone, photoresist is removed in an ultrasound manner, and cleaning and drying are carried out; and finally, the inner core is embedded in the outer ring. According to the manufacturing method, the three-dimensional model of the standing table is improved through the structure that the inner core is embedded in the outer ring , silver plating is carried out on the side face of the inner core in the embedding structure, gold plating is carried out on the front surface and the rear surface, and the color contrast ratio and the three-dimensional ornamental value of the standing table can be increased. The manufacturing method is simple and fast, and repeatability is good.

Description

The making method that the double-colored pattern crystal of a kind of inserted gold and silver is set a table
Technical field
The present invention relates to crystal works field, be specifically related to the making method that the double-colored pattern crystal of a kind of inserted gold and silver is set a table.
Background technology
Along with the lifting of people's consuming capacity, crystal works more and more comes into the life of people.Crystal works a great variety, different modeling, it is common one that crystal is set a table, and more can promote value at crystal surface after gold-plated or silver.At crystal surface, gold-plated/silver is too dull merely, does not also have stereoeffect, and people wish that crystal surface can have the demand of meticulous pattern and abundant color more and more stronger.
Summary of the invention
Goal of the invention: for overcoming the deficiencies in the prior art, the object of the present invention is to provide the making method that the double-colored pattern crystal of a kind of inserted gold and silver is set a table, outer shroud crystal being set a table by embedded structure and inner core form obvious shade deviation, promote stereoscopic sensation and the ornamental value of crystal works simultaneously.
Technical scheme: the invention provides the making method that the double-colored pattern crystal of a kind of inserted gold and silver is set a table, comprise the following steps:
(1) crystal is processed into respectively inner core and the outer shroud being set in inner core outside;
(2) core surface sputters one deck bright copper;
(3) inner core side sputtering silverskin;
(4) in the silverskin surface-coated photoresist material that step (3) obtains, upper hanger, the front surface of coating photoresist material inner core and rear surface are exposed to carries out gold-plated in electroplate liquid, obtain gold-plated film;
(5) the gold-plated inner core that step (4) obtains is put into acetone, ultrasonic removing photoresist material, clean and dry;
(6) inner core is embedded on outer shroud.
Preferably, the thickness of the bright copper described in step (2) is 50nm.
Preferably, described in step (3), the thickness of silverskin is 2 ~ 5 μm.
Preferably, in step (4), the processing parameter of electrogilding is: the electrolytic solution of electrogilding comprises sulfurous acid gold 30 ~ 50g/L, 2-sulfo--5,5-T10 10 ~ 120g/L, succimide 10 ~ 50g/L, Tripotassium Citrate 10 ~ 40g/L, citric acid 40 ~ 100g/L, antimonypotassium tartrate 1 ~ 3g/L, polyoxyethylene glycol 0.5 ~ 2g/L, S-WAT 20 ~ 150g/L, γ-picolinic acid 2 ~ 10g/L, the pH of this electroplate liquid is 4.1 ~ 5.4, and current density is 0.5 ~ 1A/dm 2.
Preferably, described in step (4), the thickness of gold-plated film is 20 ~ 50 μm.
Preferably, in step (6) inner core and outer shroud inlay when coordinating between gap be 0.05 ~ 0.1mm.
Preferably, inner core Ring current distribution outside in step (1), the geometrical shape of inner core is for revolving oar shape, regular polygon or irregular shape.
Beneficial effect: compared with prior art the present invention has the following advantages: compared with prior art, the making method that the double-colored pattern crystal of a kind of inserted gold and silver provided by the invention is set a table, the structure of inlaying by arranging inner core and outer shroud promotes the three-dimensional contouring of setting a table, inner core side in pattern structure is silver-plated, front and rear surfaces is gold-plated respectively, can improve the stereo admiring of color and luster contrast gradient and goods of furniture for display rather than for use.This making method is simple and quick, reproducible.
Embodiment
Below technical solution of the present invention is described in detail, but protection scope of the present invention is not limited to described embodiment.
Embodiment 1
One block of circular crystal is set a table after cleaning up, be processed into the inner core revolving oar shape and the outer shroud being set in inner core outside respectively, core surface sputters one deck bright copper, the thickness of this bright copper layers is 50nm, wherein, the side of inner core sputters 3 μm of silverskin and at its surface-coated photoresist material, upper hanger, the front surface of inner core and rear surface are exposed to carry out in electroplate liquid gold-plated, the electrolytic solution of electrogilding comprises sulfurous acid gold 50g/L, 2-sulfo--5, 5-T10 120g/L, succimide 50g/L, Tripotassium Citrate 40g/L, citric acid 70g/L, antimonypotassium tartrate 2g/L, polyoxyethylene glycol 1g/L, S-WAT 100g/L, γ-picolinic acid 6g/L, the pH of this electroplate liquid is 4.1, current density is 0.5A/dm 2, obtain 35 μm of thick gold-plated films.Then the inner core after gold-plated is put into acetone soln, ultrasonic 10min, remove photoresist material, clean and dry, be finally mounted on outer shroud by inner core, the gap between when both coordinate is 0.05mm.
Embodiment 2
One block of square crystal is set a table after cleaning up, be processed into the inner core revolving oar shape and the outer shroud being set in inner core outside respectively, core surface sputters one deck bright copper, the thickness of this bright copper layers is 50nm, wherein, the side of inner core sputters 2 μm of silverskin, and at its surface-coated photoresist material, upper hanger, the front surface of inner core and rear surface are exposed to carry out in electroplate liquid gold-plated, the electrolytic solution of electrogilding comprises sulfurous acid gold 30g/L, 2-sulfo--5, 5-T10 60g/L, succimide 30g/L, Tripotassium Citrate 20g/L, citric acid 100g/L, antimonypotassium tartrate 3g/L, polyoxyethylene glycol 2g/L, S-WAT 150g/L, γ-picolinic acid 10g/L, the pH of this electroplate liquid is 5.4, current density is 1.0A/dm 2, obtain 50 μm of thick gold-plated films.Then the inner core after gold-plated is put into acetone soln, ultrasonic 10min, remove photoresist material, clean and dry, be finally mounted on outer shroud by inner core, the gap between when both coordinate is 0.07mm.
Embodiment 3
One block of fan-shaped crystal is set a table after cleaning up, be processed into the inner core revolving oar shape and the outer shroud being set in inner core outside respectively, core surface sputters one deck bright copper, the thickness of this bright copper layers is 50nm, wherein, the side of inner core sputters 5 μm of silverskin and at its surface-coated photoresist material, upper hanger, the front surface of inner core and rear surface are exposed to carry out in electroplate liquid gold-plated, the electrolytic solution of electrogilding comprises sulfurous acid gold 30g/L, 2-sulfo--5, 5-T10 10g/L, succimide 10g/L, Tripotassium Citrate 10g/L, citric acid 40g/L, antimonypotassium tartrate 1g/L, polyoxyethylene glycol 1g/L, S-WAT 20g/L, γ-picolinic acid 2g/L, the pH of this electroplate liquid is 4.1, current density is 1.0A/dm 2, obtain 20 μm of thick gold-plated films.Then the inner core after gold-plated is put into acetone soln, ultrasonic 10min, remove photoresist material, clean and dry, be finally mounted on outer shroud by inner core, the gap between when both coordinate is 0.10mm.
Above embodiment just plays illustrated example effect to technical conceive of the present invention; can not limit the scope of the invention with this; those skilled in the art are not departing from the spirit and scope of technical solution of the present invention; modify and be equal to replacement, all should drop within protection scope of the present invention.

Claims (7)

1. an inserted gold and silver double-colored pattern crystal making method of setting a table, is characterized in that, comprise the following steps:
(1) crystal is processed into respectively inner core and the outer shroud being set in inner core outside;
(2) core surface sputters one deck bright copper;
(3) inner core side sputtering silverskin;
(4) in the silverskin surface-coated photoresist material that step (3) obtains, upper hanger, the front surface of coating photoresist material inner core and rear surface are exposed to carries out gold-plated in electroplate liquid, obtain gold-plated film;
(5) the gold-plated inner core that step (4) obtains is put into acetone, ultrasonic removing photoresist material, clean and dry;
(6) inner core is embedded on outer shroud.
2. the inserted gold and silver according to claim 1 double-colored pattern crystal making method of setting a table, it is characterized in that, the thickness of the bright copper described in step (2) is 50nm.
3. the inserted gold and silver according to claim 1 double-colored pattern crystal making method of setting a table, it is characterized in that, described in step (3), the thickness of silverskin is 2 ~ 5 μm.
4. the inserted gold and silver according to claim 1 double-colored pattern crystal making method of setting a table, it is characterized in that, in step (4), the processing parameter of electrogilding is: the electrolytic solution of electrogilding comprises sulfurous acid gold 30 ~ 50g/L, 2-sulfo--5, 5-T10 10 ~ 120g/L, succimide 10 ~ 50g/L, Tripotassium Citrate 10 ~ 40g/L, citric acid 40 ~ 100g/L, antimonypotassium tartrate 1 ~ 3g/L, polyoxyethylene glycol 0.5 ~ 2g/L, S-WAT 20 ~ 150g/L, γ-picolinic acid 2 ~ 10g/L, the pH of this electroplate liquid is 4.1 ~ 5.4, current density is 0.5 ~ 1A/dm 2.
5. the inserted gold and silver according to claim 1 double-colored pattern crystal making method of setting a table, it is characterized in that, described in step (4), the thickness of gold-plated film is 20 ~ 50 μm.
6. the inserted gold and silver according to claim 1 double-colored pattern crystal making method of setting a table, is characterized in that, the gap between when inner core and outer shroud are inlayed and coordinated in step (6) is 0.05 ~ 0.1mm.
7. the inserted gold and silver according to claim 1 double-colored pattern crystal making method of setting a table, is characterized in that, inner core Ring current distribution outside in step (1), the geometrical shape of inner core is for revolving oar shape, regular polygon or irregular shape.
CN201510852401.4A 2015-11-30 2015-11-30 The preparation method that a kind of double-colored pattern crystal of inserted gold and silver is set a table Expired - Fee Related CN105483703B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106086970A (en) * 2016-06-17 2016-11-09 钟福龙 A kind of processing method of natural jade spar class bijouterie

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1040225A (en) * 1989-06-23 1990-03-07 王宗英 Materials for imitating gold decorating film
GB2334558A (en) * 1995-03-31 1999-08-25 Honda Giken Kogyo Kabushiki Kaisha Slide surface member
CN2725048Y (en) * 2004-06-08 2005-09-14 陈志湘 Handicraft ornament
US20090305003A1 (en) * 2005-04-26 2009-12-10 Yoichi Nagashima False inlay decoration and method for producing the same
CN102161290A (en) * 2011-05-08 2011-08-24 王春林 Crystal glass brush holder
CN202603945U (en) * 2012-06-11 2012-12-19 浦江县玮瓒工贸有限公司 Crystal glass perfume bottle
CN204675999U (en) * 2015-06-16 2015-09-30 广东迪奥应用材料科技有限公司 A kind of colored coated article

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1040225A (en) * 1989-06-23 1990-03-07 王宗英 Materials for imitating gold decorating film
GB2334558A (en) * 1995-03-31 1999-08-25 Honda Giken Kogyo Kabushiki Kaisha Slide surface member
CN2725048Y (en) * 2004-06-08 2005-09-14 陈志湘 Handicraft ornament
US20090305003A1 (en) * 2005-04-26 2009-12-10 Yoichi Nagashima False inlay decoration and method for producing the same
CN102161290A (en) * 2011-05-08 2011-08-24 王春林 Crystal glass brush holder
CN202603945U (en) * 2012-06-11 2012-12-19 浦江县玮瓒工贸有限公司 Crystal glass perfume bottle
CN204675999U (en) * 2015-06-16 2015-09-30 广东迪奥应用材料科技有限公司 A kind of colored coated article

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106086970A (en) * 2016-06-17 2016-11-09 钟福龙 A kind of processing method of natural jade spar class bijouterie

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Effective date of registration: 20210426

Address after: No.999, South Renmin Road, Yudong Town, Haimen City, Nantong City, Jiangsu Province

Patentee after: NANTONG JINQING ART PATTERN DESIGN Co.,Ltd.

Address before: 215132 Huangqiao village, Huangqiao street, Suzhou, Jiangsu, Xiangcheng District

Patentee before: SUZHOU VENUS CRAFT PLATING DECORATION Co.,Ltd.

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Effective date of registration: 20220221

Address after: 226500 No. 77, Xuean Middle Road, Dongchen Town, Rugao City, Nantong City, Jiangsu Province

Patentee after: Nantong haohanbang New Material Technology Co.,Ltd.

Address before: No. 999, Renmin South Road, Yudong Town, Haimen City, Nantong City, Jiangsu Province, 226100

Patentee before: NANTONG JINQING ART PATTERN DESIGN CO.,LTD.

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Granted publication date: 20171027