CN105483703B - The preparation method that a kind of double-colored pattern crystal of inserted gold and silver is set a table - Google Patents

The preparation method that a kind of double-colored pattern crystal of inserted gold and silver is set a table Download PDF

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Publication number
CN105483703B
CN105483703B CN201510852401.4A CN201510852401A CN105483703B CN 105483703 B CN105483703 B CN 105483703B CN 201510852401 A CN201510852401 A CN 201510852401A CN 105483703 B CN105483703 B CN 105483703B
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China
Prior art keywords
gold
inner core
preparation
double
plated
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Expired - Fee Related
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CN201510852401.4A
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CN105483703A (en
Inventor
冯正元
冯育华
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Nantong Haohanbang New Material Technology Co ltd
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Suzhou Venus Craft Plating Decoration Co Ltd
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Priority to CN201510852401.4A priority Critical patent/CN105483703B/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/48Electroplating: Baths therefor from solutions of gold

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Electrochemistry (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

The present invention discloses the preparation method that a kind of double-colored pattern crystal of inserted gold and silver is set a table, and comprises the following steps:Crystal is processed into inner core and the outer shroud being set in outside inner core respectively;Core surface sputters one layer of bright copper;Inner core side sputtering silverskin;Silverskin surface coats photoresist, and upper hanger, the preceding surface of inner core and the progress of rear surface are gold-plated, obtain gold-plated film;Gold-plated inner core is put into acetone, ultrasound removes photoresist, cleans drying;Finally inner core is embedded on outer shroud.The preparation method is by setting the inner core side in the three-dimensional contouring that the structure lifting that inner core and outer shroud are inlayed is set a table, mosaic texture silver-plated, and front and rear surfaces difference is gold-plated, can improve the stereo admiring of color and luster contrast and goods of furniture for display rather than for use.The preparation method is simple and quick, reproducible.

Description

The preparation method that a kind of double-colored pattern crystal of inserted gold and silver is set a table
Technical field
The present invention relates to crystal works field, and in particular to the making that a kind of inserted double-colored pattern crystal of gold and silver is set a table Method.
Background technology
With the lifting of people's consuming capacity, crystal works more and more come into the life of people.Crystal works A great variety, different modeling, it is common one kind that crystal, which is set a table, crystal surface is gold-plated or silver after can more lift value.In water Simple gold-plated/the silver in brilliant surface is excessively dull, also without stereoeffect, can have fine pattern and rich it is desirable to crystal surface The demand of rich color is more and more stronger.
The content of the invention
Goal of the invention:To overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of inserted gold and silver is double-colored The preparation method that pattern crystal is set a table, makes the outer shroud that crystal is set a table form obvious shade deviation with inner core by embedded structure It is different, while lifting the third dimension and ornamental value of crystal works.
Technical scheme:The present invention provides the preparation method that a kind of inserted double-colored pattern crystal of gold and silver is set a table, including following Step:
(1) crystal is processed into inner core and the outer shroud being set in outside inner core respectively;
(2) core surface sputters one layer of bright copper;
(3) inner core side sputtering silverskin;
(4) the silverskin surface obtained in step (3) coats photoresist, upper hanger, coat photoresist inner core preceding surface and Surface is exposed to afterwards carries out gold-plated in electroplate liquid, obtains gold-plated film;
(5) the gold-plated inner core for obtaining step (4) is put into acetone, and ultrasound removes photoresist, cleans drying;
(6) inner core is embedded on outer shroud.
Preferably, the thickness of the bright copper described in step (2) is 50nm.
Preferably, the thickness of silverskin described in step (3) is 2~5 μm.
Preferably, the technological parameter of plating gold is in step (4):The electrolyte of plating gold includes 30~50g/ of sulfurous acid gold L, 2- be thio -5,5- dimethyl hydantoins, 10~120g/L, 10~50g/L of succimide, 10~40g/L of potassium citrate, 40~100g/L of citric acid, 1~3g/L of potassium antimony tartrate, 0.5~2g/L of polyethylene glycol, 20~150g/L of sodium sulfite, different cigarette 2~10g/L of acid, the pH of the electroplate liquid is 4.1~5.4, and current density is 0.5~1A/dm2
Preferably, the thickness of gold-plated film described in step (4) is 20~50 μm.
Preferably, the gap between when inner core and outer shroud inlay cooperation in step (6) is 0.05~0.1mm.
Preferably, inner core is at the center of outer shroud in step (1), and the geometry of inner core is rotation oar shape or regular polygon Shape.
Beneficial effect:The present invention has advantages below compared with prior art:Compared with prior art, the present invention is provided The preparation method that a kind of double-colored pattern crystal of inserted gold and silver is set a table, is set a table by the structure lifting for setting inner core and outer shroud to inlay Three-dimensional contouring, the inner core side in mosaic texture is silver-plated, and front and rear surfaces difference is gold-plated, can improve color and luster contrast and pendulum The stereo admiring of part.The preparation method is simple and quick, reproducible.
Embodiment
Technical solution of the present invention is described in detail below, but protection scope of the present invention is not limited to the implementation Example.
Embodiment 1
One block of circular crystal is set a table after cleaning up, the inner core of rotation oar shape is processed into respectively and is set in outside inner core Outer shroud;Core surface sputters one layer of bright copper, and the thickness of the bright copper layers is 50nm, wherein, the side of inner core sputters 3 μm of silver Film simultaneously coats photoresist on its surface, and the preceding surface and rear surface of inner core are exposed in electroplate liquid and carry out gold-plated, electricity by upper hanger Gold-plated electrolyte include sulfurous acid gold 50g/L, 2- it is thio -5,5- dimethyl hydantoins 120g/L, succimide 50g/ L, potassium citrate 40g/L, citric acid 70g/L, potassium antimony tartrate 2g/L, polyethylene glycol 1g/L, sodium sulfite 100g/L, isonicotinic acid 6g/L, the pH of the electroplate liquid is 4.1, and current density is 0.5A/dm2, obtain the gold-plated film of 35 μ m-thicks.Then in after will be gold-plated Core is put into acetone soln, ultrasonic 10min, removes photoresist, is cleaned drying, finally inner core is mounted on outer shroud, Liang Zhepei Gap between during conjunction is 0.05mm.
Embodiment 2
One block of square crystal is set a table after cleaning up, the inner core of rotation oar shape is processed into respectively and is set in outside inner core Outer shroud;Core surface sputters one layer of bright copper, and the thickness of the bright copper layers is 50nm, wherein, the side of inner core sputters 2 μm of silver Film, and its surface coat photoresist, upper hanger, by the preceding surface and rear surface of inner core be exposed to electroplate liquid in carry out it is gold-plated, Plating gold electrolyte include sulfurous acid gold 30g/L, 2- it is thio -5,5- dimethyl hydantoins 60g/L, succimide 30g/ L, potassium citrate 20g/L, citric acid 100g/L, potassium antimony tartrate 3g/L, polyethylene glycol 2g/L, sodium sulfite 150g/L, different cigarette Sour 10g/L, the pH of the electroplate liquid is 5.4, and current density is 1.0A/dm2, obtain the gold-plated film of 50 μ m-thicks.Then after will be gold-plated Inner core be put into acetone soln, ultrasonic 10min, remove photoresist, clean drying, finally inner core is mounted on outer shroud, two Gap between when person coordinates is 0.07mm.
Embodiment 3
One block of fan-shaped crystal is set a table after cleaning up, the inner core of rotation oar shape is processed into respectively and is set in outside inner core Outer shroud;Core surface sputters one layer of bright copper, and the thickness of the bright copper layers is 50nm, wherein, the side of inner core sputters 5 μm of silver Film simultaneously coats photoresist on its surface, and the preceding surface and rear surface of inner core are exposed in electroplate liquid and carry out gold-plated, electricity by upper hanger Gold-plated electrolyte include sulfurous acid gold 30g/L, 2- it is thio -5,5- dimethyl hydantoins 10g/L, succimide 10g/L, Potassium citrate 10g/L, citric acid 40g/L, potassium antimony tartrate 1g/L, polyethylene glycol 1g/L, sodium sulfite 20g/L, isonicotinic acid 2g/ L, the pH of the electroplate liquid is 4.1, and current density is 1.0A/dm2, obtain the gold-plated film of 20 μ m-thicks.Then the inner core after will be gold-plated It is put into acetone soln, ultrasonic 10min, removes photoresist, clean drying, finally inner core is mounted on outer shroud, both coordinates When between gap be 0.10mm.
Above example is that explanation example effect is played to the technical concept of the present invention, can not limit the present invention with this Protection domain, those skilled in the art modify and are equal in the spirit and scope for not departing from technical solution of the present invention Replace, all should fall within the scope and spirit of the invention.

Claims (7)

1. the preparation method that a kind of double-colored pattern crystal of inserted gold and silver is set a table, it is characterised in that comprise the following steps:
(1) crystal is processed into inner core and the outer shroud being set in outside inner core respectively;
(2) core surface sputters one layer of bright copper;
(3) inner core side sputtering silverskin;
(4) the silverskin surface obtained in step (3) coats photoresist, and upper hanger coats the preceding surface of photoresist inner core and rear table Face is exposed to carry out gold-plated in electroplate liquid, obtains gold-plated film;
(5) the gold-plated inner core for obtaining step (4) is put into acetone, and ultrasound removes photoresist, cleans drying;
(6) inner core is embedded on outer shroud.
2. the preparation method that the double-colored pattern crystal of inserted gold and silver according to claim 1 is set a table, it is characterised in that step (2) thickness of the bright copper described in is 50nm.
3. the preparation method that the double-colored pattern crystal of inserted gold and silver according to claim 1 is set a table, it is characterised in that step (3) thickness of silverskin described in is 2~5 μm.
4. the preparation method that the double-colored pattern crystal of inserted gold and silver according to claim 1 is set a table, it is characterised in that step (4) technological parameter of plating gold is in:Plating gold electrolyte include 30~50g/L of sulfurous acid gold, 2- it is thio -5,5- dimethyl 10~120g/L of hydantoins, 10~50g/L of succimide, 10~40g/L of potassium citrate, 40~100g/L of citric acid, wine 1~3g/L of stone acid antimony potassium, 0.5~2g/L of polyethylene glycol, 20~150g/L of sodium sulfite, 2~10g/L of isonicotinic acid, the electroplate liquid PH be 4.1~5.4, current density be 0.5~1A/dm2
5. the preparation method that the double-colored pattern crystal of inserted gold and silver according to claim 1 is set a table, it is characterised in that step (4) thickness of gold-plated film described in is 20~50 μm.
6. the preparation method that the double-colored pattern crystal of inserted gold and silver according to claim 1 is set a table, it is characterised in that step (6) gap between when inner core and outer shroud inlay cooperation in is 0.05~0.1mm.
7. the preparation method that the double-colored pattern crystal of inserted gold and silver according to claim 1 is set a table, it is characterised in that step (1) inner core is at the center of outer shroud in, and the geometry of inner core is rotation oar shape or regular polygon.
CN201510852401.4A 2015-11-30 2015-11-30 The preparation method that a kind of double-colored pattern crystal of inserted gold and silver is set a table Expired - Fee Related CN105483703B (en)

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106086970A (en) * 2016-06-17 2016-11-09 钟福龙 A kind of processing method of natural jade spar class bijouterie

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1040225A (en) * 1989-06-23 1990-03-07 王宗英 Materials for imitating gold decorating film
GB2334558A (en) * 1995-03-31 1999-08-25 Honda Giken Kogyo Kabushiki Kaisha Slide surface member
CN2725048Y (en) * 2004-06-08 2005-09-14 陈志湘 Handicraft ornament
CN102161290A (en) * 2011-05-08 2011-08-24 王春林 Crystal glass brush holder
CN202603945U (en) * 2012-06-11 2012-12-19 浦江县玮瓒工贸有限公司 Crystal glass perfume bottle
CN204675999U (en) * 2015-06-16 2015-09-30 广东迪奥应用材料科技有限公司 A kind of colored coated article

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101166635B (en) * 2005-04-26 2010-06-16 长岛工艺株式会社 False inlay decorator producing method

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1040225A (en) * 1989-06-23 1990-03-07 王宗英 Materials for imitating gold decorating film
GB2334558A (en) * 1995-03-31 1999-08-25 Honda Giken Kogyo Kabushiki Kaisha Slide surface member
CN2725048Y (en) * 2004-06-08 2005-09-14 陈志湘 Handicraft ornament
CN102161290A (en) * 2011-05-08 2011-08-24 王春林 Crystal glass brush holder
CN202603945U (en) * 2012-06-11 2012-12-19 浦江县玮瓒工贸有限公司 Crystal glass perfume bottle
CN204675999U (en) * 2015-06-16 2015-09-30 广东迪奥应用材料科技有限公司 A kind of colored coated article

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Effective date of registration: 20210426

Address after: No.999, South Renmin Road, Yudong Town, Haimen City, Nantong City, Jiangsu Province

Patentee after: NANTONG JINQING ART PATTERN DESIGN Co.,Ltd.

Address before: 215132 Huangqiao village, Huangqiao street, Suzhou, Jiangsu, Xiangcheng District

Patentee before: SUZHOU VENUS CRAFT PLATING DECORATION Co.,Ltd.

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Effective date of registration: 20220221

Address after: 226500 No. 77, Xuean Middle Road, Dongchen Town, Rugao City, Nantong City, Jiangsu Province

Patentee after: Nantong haohanbang New Material Technology Co.,Ltd.

Address before: No. 999, Renmin South Road, Yudong Town, Haimen City, Nantong City, Jiangsu Province, 226100

Patentee before: NANTONG JINQING ART PATTERN DESIGN CO.,LTD.

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Granted publication date: 20171027