CN104004481B - A kind of porcelain glass cement and preparation method thereof - Google Patents
A kind of porcelain glass cement and preparation method thereof Download PDFInfo
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Abstract
The invention discloses a kind of porcelain glass cement and preparation method thereof, belong to glass cement technical field, its technical essential comprises and being made up of first component and second component, and the weight ratio of first component and second component is: 1:0.4 ~ 1; Described first component forms primarily of the raw material of following weight parts: epoxy resin 80 ~ 100 parts, order number are thickening filler 10 ~ 60 parts and the auxiliary 0.8 ~ 10 part of more than 180 orders; Described second component is made up of the raw material of following weight parts: amine curing agent 30 ~ 60 parts, order number are thickening filler 5 ~ 30 parts and the auxiliary 0.3 ~ 6 part of more than 180 orders, and described thickening filler is the arbitrary combination of wilkinite or talcum powder or silicon powder or above-mentioned three; The present invention aims to provide a kind of waterproof mildew-resistant, to wide and ageing-resistant porcelain glass cement of thermal adaptation scope and preparation method thereof; For five metals, glass, timber, plastics, the bonding of the materials such as stone material is squeegeeed.
Description
Technical field
The present invention relates to a kind of glass cement, more particularly, particularly relate to a kind of porcelain glass cement.The invention still further relates to the preparation method of this porcelain glass cement.
Background technology
Current glass cement on the market, has pungent pungent odour in actual use procedure.Construction after fixing speed is slow, and not ageing-resistant, easily come off, working life is short.Meanwhile, existing glass cement, its construction after normal morphology be colloid, blackout of easily going mouldy in wet condition, grows health preserving fungi after going mouldy, affect attractive in appearance while also can threaten human health.Therefore, existing glass cement, under can only being applied to dry environment, and temperature can not be too high, otherwise affect work-ing life.Which limits the use field of glass cement.
Summary of the invention
The object of the invention is to for above-mentioned the deficiencies in the prior art, a kind of waterproof mildew-resistant, the porcelain glass cement wide and ageing-resistant to thermal adaptation scope are provided.
Another object of the present invention is to provide a kind of method preparing above-mentioned porcelain glass cement.
Last technical scheme of the present invention is achieved in that a kind of porcelain glass cement, is made up of first component and second component, and the weight ratio of first component and second component is: 1:0.4 ~ 1; Described first component forms primarily of the raw material of following weight parts: epoxy resin 80 ~ 100 parts, order number are thickening filler 10 ~ 60 parts and the auxiliary 0.8 ~ 10 part of more than 180 orders, and described thickening filler is the arbitrary combination of wilkinite or talcum powder or silicon powder or above-mentioned three; Described second component is made up of the raw material of following weight parts: amine curing agent 30 ~ 60 parts, order number are thickening filler 5 ~ 30 parts and the auxiliary 0.3 ~ 6 part of more than 180 orders, and described thickening filler is the arbitrary combination of wilkinite or talcum powder or silicon powder or above-mentioned three.
In above-mentioned a kind of porcelain glass cement, described first component also comprises weight part to be the pearlescence of 0.5 ~ 20 part or weight part the be titanium dioxide of 0.5 ~ 10 part.
In above-mentioned a kind of porcelain glass cement, the auxiliary in the auxiliary in first component and second component is the arbitrary combination of toughner or defoamer or softening agent or above-mentioned three; Further, described toughner is polypropylene glycol diglycidyl ether; Described defoamer is silicone antifoam agent; Described softening agent is dibutylester.
In above-mentioned a kind of porcelain glass cement, described amine curing agent is modified polyamine class solidifying agent.
In above-mentioned a kind of porcelain glass cement, described wilkinite is 180 order to 3000 object calcinated type wilkinites.
After of the present invention, a technical scheme is achieved in that a kind of preparation method of porcelain glass cement, comprises the steps:
(1) preparation of first component: take epoxy resin, thickening filler and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 ~ 8 DEG C/min, when temperature in the kettle reaches 65 ~ 80 DEG C, stop stirring, namely insulation reaction obtains epoxy glue finished product in 30 ~ 60 minutes; (2) preparation of second component: take amine curing agent, thickening wads and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 ~ 8 DEG C/min, when temperature in the kettle reaches 65 ~ 80 DEG C, stop stirring, namely insulation reaction obtains solidification glue finished product for 30 ~ 60 minutes; (3) when using by first component and second component be by weight: 1:0.4 ~ 1 mixes and obtain porcelain glass cement.
In the preparation method of above-mentioned a kind of porcelain glass cement, in step (1), to also added weight part be the pearlescence of 0.5 ~ 20 part or weight part is the titanium dioxide of 0.5 ~ 10 part.
The present invention adopts above-mentioned raw materials and the glass cement prepared as stated above, is mixed by suitable proportion by epoxy glue and solidification glue, under the effect of solidification glue, makes epoxy glue can fast setting, significantly improves speed of application; Simultaneously, the use of solidification glue, become very hard after glass cement can be made to construct, can waterproof, mildew-resistant, fungi-proofing, easy to clean, bondingly firmly, not to shrink, can scrub, resistance to bubble, resistance to greasy dirt, acid and alkali-resistance, the plurality of advantages such as ageing-resistant, high-low temperature resistant, non-stimulated smell.Further, after adding assorted pearlescence or titanium dioxide in the feed, make glass cement solidify rear surface and have ceramic texture, light is attractive in appearance, and working life can be very lasting.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail, but do not form any limitation of the invention.
A kind of porcelain glass cement of the present invention, is made up of first component and second component, and the weight ratio of first component and second component is: 1:0.4 ~ 1; Described first component forms primarily of the raw material of following weight parts: epoxy resin 80 ~ 100 parts, order number are thickening filler 10 ~ 60 parts and the auxiliary 0.8 ~ 10 part of more than 180 orders, and described thickening filler is the arbitrary combination of wilkinite or talcum powder or silicon powder or above-mentioned three; Wherein, epoxy resin has good physics, chemical property, and it has excellent bonding strength to the surface of metal and non-metallic material, dielectric properties are good, and set shrinking percentage is little, product size good stability, hardness is high, and snappiness is better, to soda acid and most of solvent-stable; Thickening filler can make epoxy resin increase bonding strength and hardness and prevent the flowing of epoxy resin;
Described second component is made up of the raw material of following weight parts: amine curing agent 30 ~ 60 parts, order number are thickening filler 5 ~ 30 parts and the auxiliary 0.3 ~ 6 part of more than 180 orders, and described thickening filler is the arbitrary combination of wilkinite or talcum powder or silicon powder or above-mentioned three.Wherein, amine curing agent has catalyzed epoxies solidification, the effect of stabilizing ring epoxy resin system.
The proportioning of above-mentioned each raw material is all closely related, epoxy resin and amine curing agent deal proportioning incorrect, many or few, can occur not solidify or solidify incomplete problem; Thickening filler is many that then finished product is really up to the mark can not use, and lacks then finished product in construction process, there will be trickling phenomenon.
Particularly, in the present embodiment, described amine curing agent is preferably modified polyamine class solidifying agent; Auxiliary in auxiliary in first component and second component is the arbitrary combination of toughner or defoamer or softening agent or above-mentioned three.In the present embodiment, described toughner is polypropylene glycol diglycidyl ether, has band just tough, make product embrittlement can not occur after can increasing products solidifying; Described defoamer is silicone antifoam agent; Described softening agent is dibutylester.Certainly, according to practical situation, other auxiliary agents similar with above-mentioned each auxiliary agent also can be adopted.
Meanwhile, wilkinite described in the present embodiment is 180 order to 3000 object calcinated type wilkinites, the wilkinite namely after calcining; Use talcous preferred order number to be 800 order ~ 3000 orders, silicon powder is 200 order to 4000 orders.Meanwhile, each thickening filler has different advantages again separately: the finished product after the wilkinite after calcining can make product use solidification can not be brittle after reaching the effect of light and finished product solidification; Talcum powder can increase the hardness after products solidifying and ultimate compression strength; Silicon powder fluid stopping effect clearly, makes material not easily trickle in construction process.
Preferably, first component can also comprise weight part to be the pearlescence of 0.5 ~ 20 part or weight part the be titanium dioxide of 0.5 ~ 10 part.Assorted pearlescence can make glass cement have shades of colour, and titanium dioxide then solely makes glass cement have white effect.
A preparation method for porcelain glass cement, comprises the steps:
(1) preparation of first component: take epoxy resin, thickening filler and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 ~ 8 DEG C/min, when temperature in the kettle reaches 65 ~ 80 DEG C, stop stirring, namely insulation reaction obtains epoxy glue finished product in 30 ~ 60 minutes; As required, can also to add weight part be in the feed the pearlescence of 0.5 ~ 20 part or weight part is the titanium dioxide of 0.5 ~ 10 part.
(2) preparation of second component: take amine curing agent, thickening wads and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 ~ 8 DEG C/min, when temperature in the kettle reaches 65 ~ 80 DEG C, stop stirring, namely insulation reaction obtains solidification glue finished product for 30 ~ 60 minutes;
(3) when using by first component and second component be by weight: 1:0.4 ~ 1 mixes and obtain porcelain glass cement.Particularly, first obtained epoxy glue and solidification glue are contained in respectively independently in container, then load in container together, container opening portion is provided with combining nozzle, and its use-pattern can be identical with existing glass cement, extruded by glue rifle, very easy to use.
Glass cement of the present invention, has following advantage:
After a, solidification, there is ceramic texture, and bright and clean as porcelain, easy to cleanly scrub dirt.
B, ageing-resistant, forever can not mouldyly turn black.
C, can to harden in water, bonding repairing.
D, strong adhesion, difficult drop-off.
Environmentally friendly after e, solidification, do not produce pollution, resistance to bubble.
F, use range are extensive, can be used on stone material, five metals, glass, timber, the materials such as plastics bonding, squeegee.
Embodiment 1
Formula:
First component: epoxy resin 80 parts, order number are 180 object wilkinite 10 parts, polypropylene glycol diglycidyl ether 0.8 part
Second component: amine curing agent 30 parts, order number are 800 order talcum powder 5 parts, silicone antifoam agent 0.3 part
Preparation method:
(1) preparation of first component: take epoxy resin, thickening filler and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 DEG C/min, when temperature in the kettle reaches 65 DEG C, stop stirring, namely insulation reaction obtains epoxy glue finished product in 60 minutes;
(2) preparation of second component: take amine curing agent, thickening wads and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 DEG C/min, when temperature in the kettle reaches 65 DEG C, stop stirring, namely insulation reaction obtains solidification glue finished product for 60 minutes;
(3) when using by first component and second component be by weight: 1:1 mixes and obtain porcelain glass cement.
Embodiment 2
Formula:
First component: epoxy resin 90 parts, order number are 200 object silicon powder 30 parts, dibutylester 9 parts, pearlescence 0.5 part
Second component: amine curing agent 45 parts, order number are 3000 order talcum powder 20 parts, silicone antifoam agent 3 parts
Preparation method:
(1) preparation of first component: take epoxy resin, thickening filler and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 DEG C/min, when temperature in the kettle reaches 70 DEG C, stop stirring, namely insulation reaction obtains epoxy glue finished product in 50 minutes;
(2) preparation of second component: take amine curing agent, thickening wads and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 6 DEG C/min, when temperature in the kettle reaches 65 DEG C, stop stirring, namely insulation reaction obtains solidification glue finished product for 40 minutes;
(3) when using by first component and second component be by weight: 1:0.8 mixes and obtain porcelain glass cement.
Embodiment 3
Formula:
First component: epoxy resin 100 parts, order number are 800 object talcum powder 60 parts, silicone antifoam agent 10 parts, titanium dioxide 10 parts
Second component: amine curing agent 60 parts, order number are 400 order wilkinite 30 parts, polypropylene glycol diglycidyl ether 6 parts
Preparation method:
(1) preparation of first component: take epoxy resin, thickening filler and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 8 DEG C/min, when temperature in the kettle reaches 80 DEG C, stop stirring, namely insulation reaction obtains epoxy glue finished product in 30 minutes;
(2) preparation of second component: take amine curing agent, thickening wads and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 8 DEG C/min, when temperature in the kettle reaches 80 DEG C, stop stirring, namely insulation reaction obtains solidification glue finished product for 30 minutes;
(3) when using by first component and second component be by weight: 1:0.4 mixes and obtain porcelain glass cement.
Embodiment 4
Formula:
First component: epoxy resin 100 parts, order number be 3000 object wilkinite 50 parts, polypropylene glycol diglycidyl ether 3 parts, silicone antifoam agent 3 parts, dibutylester 4 parts, pearlescence 20 parts,
Second component: amine curing agent 60 parts, order number are 200 order silicon powder 30 parts, polypropylene glycol diglycidyl ether 1 part, silicone antifoam agent 2 parts, dibutylester 3 parts
Preparation method:
(1) preparation of first component: take epoxy resin, thickening filler and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 DEG C/min, when temperature in the kettle reaches 75 DEG C, stop stirring, namely insulation reaction obtains epoxy glue finished product in 60 minutes;
(2) preparation of second component: take amine curing agent, thickening wads and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 DEG C/min, when temperature in the kettle reaches 75 DEG C, stop stirring, namely insulation reaction obtains solidification glue finished product for 60 minutes;
(3) when using by first component and second component be by weight: 1:0.5 mixes and obtain porcelain glass cement.
Embodiment 5
Formula:
First component: epoxy resin 95 parts, order number be 3000 object talcum powder 55 parts, polypropylene glycol diglycidyl ether 2 parts, silicone antifoam agent 1 part, dibutylester 1 part, pearlescence 15 parts,
Second component: amine curing agent 55 parts, order number are 800 order wilkinite 25 parts, polypropylene glycol diglycidyl ether 0.8 part, silicone antifoam agent 3 parts, dibutylester 0.5 part
Preparation method:
(1) preparation of first component: take epoxy resin, thickening filler and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 7 DEG C/min, when temperature in the kettle reaches 60 DEG C, stop stirring, namely insulation reaction obtains epoxy glue finished product in 45 minutes;
(2) preparation of second component: take amine curing agent, thickening wads and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 6 DEG C/min, when temperature in the kettle reaches 70 DEG C, stop stirring, namely insulation reaction obtains solidification glue finished product for 35 minutes;
(3) when using by first component and second component be by weight: 1:0.8 mixes and obtain porcelain glass cement.
Embodiment 6
Formula:
First component: epoxy resin 85 parts, order number be 1000 object silicon powder 35 parts, polypropylene glycol diglycidyl ether 2 parts, silicone antifoam agent 4 parts, pearlescence 10 parts,
Second component: amine curing agent 50 parts, order number are 4000 order silicon powder 15 parts, polypropylene glycol diglycidyl ether 3 parts, dibutylester 1 part
Preparation method:
(1) preparation of first component: take epoxy resin, thickening filler and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 DEG C/min, when temperature in the kettle reaches 75 DEG C, stop stirring, namely insulation reaction obtains epoxy glue finished product in 60 minutes;
(2) preparation of second component: take amine curing agent, thickening wads and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 DEG C/min, when temperature in the kettle reaches 75 DEG C, stop stirring, namely insulation reaction obtains solidification glue finished product for 60 minutes;
(3) when using by first component and second component be by weight: 1:0.7 mixes and obtain porcelain glass cement.
Embodiment 7
Formula:
First component: epoxy resin 80 parts, order number are 800 object wilkinite 15 parts, order number is 400 order talcum powder 20 parts, silicone antifoam agent 4 parts, dibutylester 3 parts, titanium dioxide 0.5 part,
Second component: amine curing agent 35 parts, order number are 1000 order wilkinite 5 parts, order number is 1200 order talcum powder 15 parts, order number is 600 order silicon powder 5 parts, polypropylene glycol diglycidyl ether 0.5 part, silicone antifoam agent 1 part, dibutylester 1 part
Preparation method:
(1) preparation of first component: take epoxy resin, thickening filler and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 DEG C/min, when temperature in the kettle reaches 65 DEG C, stop stirring, namely insulation reaction obtains epoxy glue finished product in 50 minutes;
(2) preparation of second component: take amine curing agent, thickening wads and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 6 DEG C/min, when temperature in the kettle reaches 80 DEG C, stop stirring, namely insulation reaction obtains solidification glue finished product for 35 minutes;
(3) when using by first component and second component be by weight: 1:1 mixes and obtain porcelain glass cement.
Experimental example
Guangdong product quality supervision and inspection research institute is sent by glass cement of the present invention to test, test basis reference: GB/T1735 ~ 2009 " mensuration of paint and varnish thermotolerance ", GB/T9268 ~ 2008 " mensuration of emulsion paint freeze-thaw resistance ", HG/T3828 ~ 2006 " indoor aqueous wooden ware paint vehicle ", GB/T9274 ~ 1988 " mensuration of paint and varnish resistant to liquid medium ", GB/T1728 ~ 1979 " paint film, putty membrane assay method time of drying ", assay is as following table:
Can be proved, glass cement of the present invention to there is good anti-high and low temperature anti acid alkali performance energy, and be obviously better than existing glass cement set time by above-mentioned experiment.
Claims (8)
1. a porcelain glass cement, is characterized in that, is made up of first component and second component, and the weight ratio of first component and second component is: 1:0.4 ~ 1; Described first component forms primarily of the raw material of following weight parts: epoxy resin 80 ~ 100 parts, order number are thickening filler 10 ~ 60 parts and the auxiliary 0.8 ~ 10 part of more than 180 orders, and described thickening filler is the arbitrary combination of wilkinite or talcum powder or silicon powder or above-mentioned three; Described second component is made up of the raw material of following weight parts: amine curing agent 30 ~ 60 parts, order number are thickening filler 5 ~ 30 parts and the auxiliary 0.3 ~ 6 part of more than 180 orders, and described thickening filler is the arbitrary combination of wilkinite or talcum powder or silicon powder or above-mentioned three.
2. a kind of porcelain glass cement according to claim 1, is characterized in that, described first component also comprises weight part to be the pearlescence of 0.5 ~ 20 part or weight part the be titanium dioxide of 0.5 ~ 10 part.
3. a kind of porcelain glass cement according to claim 1 and 2, is characterized in that, the auxiliary in the auxiliary in first component and second component is the arbitrary combination of toughner or defoamer or softening agent or above-mentioned three.
4. a kind of porcelain glass cement according to claim 3, is characterized in that, described toughner is polypropylene glycol diglycidyl ether; Described defoamer is silicone antifoam agent; Described softening agent is dibutylester.
5. a kind of porcelain glass cement according to claim 1, is characterized in that, described amine curing agent is modified polyamine class solidifying agent.
6. a kind of porcelain glass cement according to claim 1, is characterized in that, described wilkinite is 180 order to 3000 object calcinated type wilkinites.
7. prepare a method for porcelain glass cement described in claim 1, it is characterized in that, comprise the steps:
(1) preparation of first component: take epoxy resin, thickening filler and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 ~ 8 DEG C/min, when temperature in the kettle reaches 65 ~ 80 DEG C, stop stirring, namely insulation reaction obtains epoxy glue finished product in 30 ~ 60 minutes; (2) preparation of second component: take amine curing agent, thickening filler and auxiliary by weight respectively, each raw material is put into reactor under room temperature environment, intensification limit, limit is stirred, heat-up rate is 5 ~ 8 DEG C/min, when temperature in the kettle reaches 65 ~ 80 DEG C, stop stirring, namely insulation reaction obtains solidification glue finished product for 30 ~ 60 minutes; (3) when using by first component and second component be by weight: 1:0.4 ~ 1 mixes and obtain porcelain glass cement.
8. the preparation method of a kind of porcelain glass cement according to claim 7, is characterized in that, in step (1), to also added weight part be the pearlescence of 0.5 ~ 20 part or weight part is the titanium dioxide of 0.5 ~ 10 part.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101284979A (en) * | 2007-04-12 | 2008-10-15 | 张建杉 | Water-proofing material for adhesive joint between solid objects |
| CN103320071A (en) * | 2013-06-28 | 2013-09-25 | 上海悍马建筑科技有限公司 | Modified epoxy transparent crack sealing compound |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101284979A (en) * | 2007-04-12 | 2008-10-15 | 张建杉 | Water-proofing material for adhesive joint between solid objects |
| CN103320071A (en) * | 2013-06-28 | 2013-09-25 | 上海悍马建筑科技有限公司 | Modified epoxy transparent crack sealing compound |
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