CN104962140A - Coral sand stone-like coating and preparation method thereof - Google Patents
Coral sand stone-like coating and preparation method thereof Download PDFInfo
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- CN104962140A CN104962140A CN201510195578.1A CN201510195578A CN104962140A CN 104962140 A CN104962140 A CN 104962140A CN 201510195578 A CN201510195578 A CN 201510195578A CN 104962140 A CN104962140 A CN 104962140A
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Abstract
The invention discloses a coral sand stone-like coating, which comprises the following raw materials in part by mass: 1-750 parts of coral sand, 1-750 parts of quartz sand, 1-5 parts of cellulose, 5-30 parts of auxiliary agents, 2-5 parts of pigments, 1-20 parts of glycol, 30-250 parts of emulsions, and 80-200 parts of water. The oral sand stone-like coating provided by the invention is added with coral sand, because of abundant aperture structures, the oral sand stone-like coating has good moisture and air permeability, and can decompose harmful substances. The oral sand stone-like coating provided by the invention does not contain formaldehyde, and absorbs harmful substances in the air, has moisture and air permeability, and can kill bacteria and prevent bacteria breeding. In addition, the preparation method of the oral sand stone-like coating provided by the invention has the advantages of simple preparation method, construction convenience, safety and environmental protection.
Description
Technical field
The invention belongs to true mineral varnish field, be specifically related to true mineral varnish of a kind of coral sand and preparation method thereof.
Background technology
True mineral varnish is that a kind of decorative effect exactly likes marble, granitic coating, and the main natural stone-powder of shades of colour that adopts is formulated.Buildings after true mineral varnish finishing, has natural real natural colour, gives elegance, harmony, serious aesthetic feeling, be suitable for the indoor and outdoor decoration of all kinds of buildings, particularly decorate on curved-surface building thing, can receive vivid, effect of back to nature.True mineral varnish has fire prevention, waterproof, acid and alkali-resistance, anti-pollution.The features such as nontoxic, tasteless, bonding force is strong, will never fade, can stop extraneous severe environment to corrode buildings effectively, extend the life-span of buildings, because true mineral varnish possesses good sticking power and freeze-thaw resistance property, are therefore particularly suitable for using in cold district.True mineral varnish easy construction, easily dryly saves time, the advantages such as easy construction.But often breathable moisture permeability is poor for traditional true mineral varnish, and formaldehyde, cause very large harm to environmental and human health impacts.
Summary of the invention
For the deficiencies in the prior art, an object of the present invention is to provide a kind of coral sand true mineral varnish, and the true mineral varnish of this coral sand is antibacterial containing objectionable impurities in formaldehyde, moisture-penetrable ventilated, Absorbable rod air, sterilization.
For reaching this object, the present invention by the following technical solutions:
The true mineral varnish of a kind of coral sand, comprises following raw material by mass parts:
Coral sand 1-750 part, such as 1 part, 10 parts, 20 parts, 50 parts, 100 parts, 120 parts, 150 parts, 160 parts, 180 parts, 200 parts, 250 parts, 300 parts, 350 parts, 400 parts, 430 parts, 480 parts, 500 parts, 550 parts, 600 parts, 650 parts, 700 parts, 750 parts;
Quartz sand 1-750 part, such as 1 part, 10 parts, 20 parts, 50 parts, 100 parts, 120 parts, 150 parts, 160 parts, 180 parts, 200 parts, 250 parts, 300 parts, 350 parts, 400 parts, 430 parts, 480 parts, 500 parts, 550 parts, 600 parts, 650 parts, 700 parts, 750 parts;
Mierocrystalline cellulose 1-5 part, such as 1 part, 2 parts, 3 parts, 4 parts, 5 parts;
Auxiliary agent 5-30 part, such as 5 parts, 10 parts, 14 parts, 18 parts, 20 parts, 23 parts, 25 parts, 26 parts, 28 parts, 30 parts;
Pigment 2-5 part, such as 2 parts, 3 parts, 4 parts, 5 parts;
Ethylene glycol 1-20 part, such as 1 part, 2 parts, 4 parts, 6 parts, 8 parts, 10 parts, 13 parts, 15 parts, 17 parts, 20 parts;
Emulsion 30-250 part, such as 30 parts, 50 parts, 60 parts, 80 parts, 100 parts, 140 parts, 160 parts, 180 parts, 200 parts, 210 parts, 230 parts, 240 parts, 250 parts;
Water 80-200 part, such as 80 parts, 90 parts, 100 parts, 120 parts, 140 parts, 150 parts, 170 parts, 190 parts, 200 parts.
Wherein, coral sand is powdery or particulate state.
Coral sand is coral or shell fragment, the characteristic of tool sustained release calcium carbonate, and not etc., specification is not varied for granular size; Belong to marine natural filter material, maximum feature is that micropore enriches, suitable a large amount of biochemical bacteria live, can be used as down (interior) layer and lays filter material.Because it is containing abundant pore texture, permeability is good, also can be used as the carrier of biological filter system, and can decomposing harmful substances.
Quartz sand is the quartz particles that quartzite processes through fragmentation, it is a kind of silicate minerals of hard, wear-resisting, stable chemical performance, its main mineral constituent is SiO2, the color of quartz sand is oyster white or semi-transparent clear shape, Mohs' hardness 7, quartz sand is important industrial mineral raw material, and non-chemically hazardous substance are widely used in the industry such as glass, casting, pottery and refractory materials, smelting duriron, flux for metallurgy, metallurgy, building, chemical industry, plastics, rubber, abrasive material, filtrate.
Benzene emulsion (styrene-acrylate emulsion) is obtained through emulsion copolymerization by vinylbenzene and acrylate monomer.It is water-fast, alkaline-resisting, scrub resistance can be good, and resistance to outdoor aging is widely used in the field such as tackiness agent, coating.Preferably, benzene emulsion is benzene emulsion 992.
Filmogen in coating can dissolve or be separated into uniform liquid state by ethylene glycol, in addition can also as frostproofer.
In addition; the effect of Mierocrystalline cellulose in coating is have good thickening, suspension, dispersion, emulsification, bonding, film forming, protection moisture and provide protective colloid etc., and Mierocrystalline cellulose can be selected from lignocellulose, hydroxypropylcellulose, carboxymethyl cellulose, sodium benzene emulsion, Polyanionic Cellulose, polyvinyl alcohol propylene glycol, sodium polyacrylate ethyl cellulose, Natvosol etc.Preferably, Mierocrystalline cellulose is Natvosol 100,000.
Auxiliary agent comprises sterilant, dispersion agent, wetting agent, defoamer, film coalescence aid and multifunctional assistant, and described sterilant, dispersion agent, wetting agent, defoamer, film coalescence aid and multifunctional assistant are commercially available usual auxiliaries.
Preferably, described multifunctional assistant is multifunctional assistant AMP-95; Multifunctional assistant AMP-95 contains the moisture content-2-amino-2-methyl-1-propanol of 5%, is that current minority has one of lower molecular weight and overbasic industrial amine.AMP-95 as the multifunctional assistant of all kinds emulsion paint, can be divided into powder with AMP-95 as brute force and can prevent pigment from re-uniting in formula.Meanwhile, all properties of multifunctional assistant AMP-95 to enamelled coating contributes significant superiority.
Dispersion agent is a kind of interfacial agent simultaneously in molecule with lipophilicity and wetting ability two kinds of opposite nature, can homogeneous dispersion and be insoluble in the solid particulate of inorganic, the pigment dyestuff of liquid, also can prevent sedimentation and the cohesion of solid particulate simultaneously, form stable medicament needed for suspension.In coating, use pigment dispersing agent, the gloss of film can be increased, improve levelling property, improve the painted and opacifying power of coating, prevent loose colour, sedimentation, enhance productivity and the package stability of coating.Preferably, described dispersion agent is dispersion agent PDA.
Preferably, described wetting agent is wetting agent 486.
Preferably, described defoamer is defoamer NXZ.
Preferably, described film coalescence aid is film coalescence aid C-12.
Preferably, described sterilant is sterilant LXZ.
Emulsion is benzene emulsion, and preferably, described benzene emulsion is 992 benzene emulsions.
Two of object of the present invention is the preparation method providing the true mineral varnish of a kind of coral sand, comprise the steps: to take the mixing of coral sand, quartz sand and water by proportioning, put into auxiliary agent, emulsion while stirring, add pigment colouring after mixing, obtain the true mineral varnish of described coral sand.This preparation method's technique is simple, convenient operation.
Compared with prior art, beneficial effect of the present invention is: the true mineral varnish of a kind of coral sand, comprises following raw material by mass parts: 1-750 part coral sand, 1-750 part quartz sand, 1-5 part Mierocrystalline cellulose, 5-30 part auxiliary agent, 2-5 part pigment, 1-20 part ethylene glycol, 30-250 part emulsion, 80-200 part water.The true mineral varnish of coral sand of the present invention adds coral sand, because it is containing abundant pore texture, makes the moisture-penetrable ventilated functional of the true mineral varnish of coral sand of the present invention, and can decomposing harmful substances.The true mineral varnish of coral sand of the present invention is antibacterial containing objectionable impurities in formaldehyde, moisture-penetrable ventilated, Absorbable rod air, sterilization.In addition, the true mineral varnish preparation method of coral sand of the present invention is simple, easy construction, safety and environmental protection.
Embodiment
Technical scheme of the present invention is further illustrated below by embodiment.
As no specific instructions, various raw material of the present invention all can commercially availablely be buied, or prepares according to the ordinary method of this area.
Embodiment 1
Take 500 parts of coral sands, 500 quartz sands and 150 parts of water, 15 parts of ethylene glycol mixing, put into 1 part of Natvosol, 100,000,2 parts of multifunctional assistant AMP-95,3 parts of dispersion agent PDA, 5 parts of wetting agents, 486,3 parts of defoamer NXZ, 4 parts of film coalescence aid C-12,3 parts of sterilant LXZ, 100 part of 992 benzene emulsion while stirring, 3 parts of pigment colourings are added after mixing, obtain the true mineral varnish of coral sand, the true mineral varnish condition in container obtained is normal, and application property is good.
Embodiment 2
Take 350 parts of coral sands, 350 quartz sands and 180 parts of water, 10 parts of ethylene glycol mixing, put into 3 parts of Natvosols, 100,000,3 parts of multifunctional assistant AMP-95,3 parts of dispersion agent PDA, 6 parts of wetting agents, 486,2 parts of defoamer NXZ, 5 parts of film coalescence aid C-12,2 parts of sterilant LXZ, 150 part of 992 benzene emulsion while stirring, 4 parts of pigment colourings are added after mixing, obtain the true mineral varnish of coral sand, the true mineral varnish condition in container obtained is normal, and application property is good.
Embodiment 3
Take 600 parts of coral sands, 600 quartz sands and 100 parts of water, 15 parts of ethylene glycol mixing, put into 5 parts of Natvosols, 100,000,4 parts of multifunctional assistant AMP-95,4 parts of dispersion agent PDA, 5 parts of wetting agents, 486,3 parts of defoamer NXZ, 4 parts of film coalescence aid C-12,8 parts of sterilant LXZ, 120 part of 992 benzene emulsion while stirring, 3 parts of pigment colourings are added after mixing, obtain the true mineral varnish of coral sand, the true mineral varnish condition in container obtained is normal, and application property is good.
Above embodiment is only used for method detailed of the present invention is described, the present invention is not limited to above-mentioned method detailed, does not namely mean that the present invention must rely on above-mentioned method detailed and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of ancillary component, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.
Claims (10)
1. the true mineral varnish of coral sand, is characterized in that, comprises following raw material by mass parts:
2. the true mineral varnish of a kind of coral sand according to claim 1, is characterized in that, comprise following raw material by mass parts:
3. the true mineral varnish of a kind of coral sand according to claim 1, is characterized in that, described coral sand is powdery or particulate state.
4. the true mineral varnish of a kind of coral sand according to claim 1, it is characterized in that, described auxiliary agent comprises sterilant, dispersion agent, wetting agent, defoamer, film coalescence aid and multifunctional assistant.
5. the true mineral varnish of a kind of coral sand according to claim 1, is characterized in that, described emulsion is benzene emulsion, and preferably, described benzene emulsion is 992 benzene emulsions.
6. the true mineral varnish of a kind of coral sand according to claim 1, is characterized in that, described Mierocrystalline cellulose is Natvosol 100,000.
7. the true mineral varnish of a kind of coral sand according to claim 4, is characterized in that, described multifunctional assistant is multifunctional assistant AMP-95.
8. the true mineral varnish of a kind of coral sand according to claim 4, is characterized in that, described sterilant is sterilant LXZ.
9. the true mineral varnish of a kind of coral sand according to claim 4, is characterized in that, described dispersion agent is dispersion agent PDA;
Preferably, described wetting agent is wetting agent 486;
Preferably, described defoamer is defoamer NXZ;
Preferably, described film coalescence aid is film coalescence aid C-12.
10. the preparation method of the true mineral varnish of a kind of coral sand as claimed in claim 1, it is characterized in that, comprise the steps: by mass parts, take the mixing of 1-750 part coral sand, 1-750 part quartz sand and 80-200 part water, put into 1-5 part Mierocrystalline cellulose, 5-30 part auxiliary agent, 1-20 part ethylene glycol, 30-250 part emulsion while stirring, add the colouring of 2-5 part pigment after mixing, obtain the true mineral varnish of described coral sand.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111499261A (en) * | 2020-05-22 | 2020-08-07 | 河南兴安新型建筑材料有限公司 | Colorful real stone paint and preparation method thereof |
CN115181376A (en) * | 2022-07-11 | 2022-10-14 | 重庆大学 | Coral island reef building decoration prefabricated plate and preparation method thereof |
CN115651430A (en) * | 2022-10-17 | 2023-01-31 | 重庆大学 | Coating for coral island reef building and preparation method thereof |
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CN102977695A (en) * | 2012-12-04 | 2013-03-20 | 中国科学院烟台海岸带研究所 | Environment-friendly interior wall coating material with calcined shell powder as base stock and preparation method of environment-friendly interior wall coating material |
CN103450767A (en) * | 2013-08-14 | 2013-12-18 | 青岛益群漆业集团有限公司 | Super-weather-resistant anti-fouling real stone paint |
CN103525212A (en) * | 2013-09-28 | 2014-01-22 | 青岛益群漆业集团有限公司 | Internal wall environment-friendly coating capable of releasing negative air ions |
CN104513527A (en) * | 2013-09-30 | 2015-04-15 | 青岛兴国涂料有限公司 | Vintage texture coating |
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2015
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2008115351A (en) * | 2006-11-02 | 2008-05-22 | D Trip:Kk | Interior material having deodorizing, antibacterial, and humidity-conditioning properties |
CN102977695A (en) * | 2012-12-04 | 2013-03-20 | 中国科学院烟台海岸带研究所 | Environment-friendly interior wall coating material with calcined shell powder as base stock and preparation method of environment-friendly interior wall coating material |
CN103450767A (en) * | 2013-08-14 | 2013-12-18 | 青岛益群漆业集团有限公司 | Super-weather-resistant anti-fouling real stone paint |
CN103525212A (en) * | 2013-09-28 | 2014-01-22 | 青岛益群漆业集团有限公司 | Internal wall environment-friendly coating capable of releasing negative air ions |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN111499261A (en) * | 2020-05-22 | 2020-08-07 | 河南兴安新型建筑材料有限公司 | Colorful real stone paint and preparation method thereof |
CN115181376A (en) * | 2022-07-11 | 2022-10-14 | 重庆大学 | Coral island reef building decoration prefabricated plate and preparation method thereof |
CN115651430A (en) * | 2022-10-17 | 2023-01-31 | 重庆大学 | Coating for coral island reef building and preparation method thereof |
CN115651430B (en) * | 2022-10-17 | 2024-04-02 | 重庆大学 | Coating for coral island reef building and preparation method thereof |
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