CN104004481A - Porcelain glass glue and preparation method thereof - Google Patents
Porcelain glass glue and preparation method thereof Download PDFInfo
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Abstract
The invention discloses porcelain glass glue and a preparation method thereof, and belongs to the technical field of glass glue. The porcelain glass glue is technically characterized by being composed of a first component and a second component, wherein the weight ratio of the first component to the second component is 1:(0.4-1); the first component comprises, by weight, 80 parts to 100 parts of epoxy resin, 10 parts to 60 parts of thickening packing with the mesh number being more than 180, and 0.8 part to 10 parts of auxiliary agents; the second component comprises, by weight, 30 parts to 60 parts of amine curing agents, 5 parts to 30 parts of thickening packing with the mesh number being more than 180, and 0.3 part to 6 parts of auxiliary agents, wherein the thickening packing is bentonite or talcum powder or silica powder or the arbitrary combination of the bentonite, the talcum powder and the silica powder. The porcelain glass glue and the preparation method of the porcelain glass glue are water proof, mould proof, wide in temperature application range, and resistant to aging, and are used for splicing and gap filling for materials such as metals, glass, woods, plastic and stone.
Description
Technical field
The present invention relates to a kind of glass cement, more particularly, relate in particular to a kind of porcelain glass cement.The invention still further relates to the preparation method of this porcelain glass cement.
Background technology
Current glass cement on the market, has pungent pungent odour in actual use procedure.Construction after fixing speed is slow, not ageing-resistant, easily comes off, and working life is short.Meanwhile, existing glass cement, the normal morphology after its construction is colloid, the blackout of easily going mouldy under wet environment, grows health preserving fungi after going mouldy, and affects and also can threaten human health time attractive in appearance.Therefore, existing glass cement, can only be applied under dry environment, and temperature can not be too high, otherwise affects work-ing life.This has just limited the use field of glass cement.
Summary of the invention
The object of the invention is to for above-mentioned the deficiencies in the prior art, a kind of waterproof mildew-resistant, the porcelain glass cement wide and ageing-resistant to thermal adaptation scope are provided.
Another object of the present invention is to provide a kind of method of preparing above-mentioned porcelain glass cement.
Last technical scheme of the present invention is achieved in that a kind of porcelain glass cement, is made up of first component and second component, and the weight ratio of first component and second component is: 1:0.4～1; Described first component is mainly made up of the raw material of following weight parts: 80～100 parts of epoxy resin, order number are 0.8～10 part of more than 180 orders 10～60 parts of thickening fillers and auxiliary, and described thickening filler is wilkinite or talcum powder or silicon powder or above-mentioned three's arbitrary combination; Described second component is made up of the raw material of following weight parts: 30～60 parts of amine curing agents, order number are 0.3～6 part of more than 180 orders 5～30 parts of thickening fillers and auxiliary, and described thickening filler is wilkinite or talcum powder or silicon powder or above-mentioned three's arbitrary combination.
In above-mentioned a kind of porcelain glass cement, described first component also comprises that weight part is that the pearlescence of 0.5～20 part or weight part are the titanium dioxide of 0.5～10 part.
In above-mentioned a kind of porcelain glass cement, the auxiliary in the auxiliary in first component and second component is toughner or defoamer or softening agent or above-mentioned three's arbitrary combination; Further, described toughner is polypropylene glycol diglycidyl ether; Described defoamer is silicone antifoam agent; Described softening agent is dibutylester.
In above-mentioned a kind of porcelain glass cement, described amine curing agent is modified polyamine class solidifying agent.
In above-mentioned a kind of porcelain glass cement, described wilkinite is 180 order to 3000 object calcinated type wilkinites.
After of the present invention, a technical scheme is achieved in that a kind of preparation method of porcelain glass cement, comprises the steps:
(1) preparation of first component: take respectively by weight epoxy resin, thickening filler and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5～8 DEG C/min, in the time that temperature in the kettle reaches 65～80 DEG C, stop stirring, insulation reaction obtains epoxy glue finished product for 30～60 minutes; (2) preparation of second component: take respectively by weight amine curing agent, thickening wads and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5～8 DEG C/min, in the time that temperature in the kettle reaches 65～80 DEG C, stop stirring, insulation reaction obtains for 30～60 minutes solidifies glue finished product; (3) while use, by first component and second component be by weight: 1:0.4～1 mixes and obtain porcelain glass cement.
In the preparation method of above-mentioned a kind of porcelain glass cement, in the step (1), also add weight part and be the pearlescence of 0.5～20 part or weight part and be the titanium dioxide of 0.5～10 part.
The present invention adopts above-mentioned raw materials the glass cement of preparation as stated above, is mixed by suitable proportion by epoxy glue and curing glue, is solidifying under the effect of glue, makes the epoxy glue can fast setting, significantly improves speed of application; Simultaneously, solidify the use of glue, can make to become very hard after glass cement construction, can waterproof, mildew-resistant, fungi-proofing, easy to clean, bonding firmly, do not shrink, can scrub, the plurality of advantages such as water-fast bubble, oil resistant dirt, acid and alkali-resistance, ageing-resistant, high-low temperature resistant, non-stimulated smell.Further, add after pearlescence or titanium dioxide of all kinds in raw material, make glass cement solidify rear surface and have ceramic texture, light is attractive in appearance, and working life can be very lasting.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail, but do not form any limitation of the invention.
A kind of porcelain glass cement of the present invention, is made up of first component and second component, and the weight ratio of first component and second component is: 1:0.4～1; Described first component is mainly made up of the raw material of following weight parts: 80～100 parts of epoxy resin, order number are 0.8～10 part of more than 180 orders 10～60 parts of thickening fillers and auxiliary, and described thickening filler is wilkinite or talcum powder or silicon powder or above-mentioned three's arbitrary combination; Wherein, epoxy resin has good physics, chemical property, and it has excellent bonding strength to the surface of metal and non-metallic material, dielectric properties are good, and set shrinking percentage is little, product size good stability, hardness is high, and snappiness is better, to soda acid and most of solvent-stable; Thickening filler can make epoxy resin increase bonding strength and hardness and prevent flowing of epoxy resin;
Described second component is made up of the raw material of following weight parts: 30～60 parts of amine curing agents, order number are 0.3～6 part of more than 180 orders 5～30 parts of thickening fillers and auxiliary, and described thickening filler is wilkinite or talcum powder or silicon powder or above-mentioned three's arbitrary combination.Wherein, amine curing agent has catalysis epoxy resin cure, the effect of stabilizing ring epoxy resin system.
The proportioning of above-mentioned each raw material is all closely related, and epoxy resin and amine curing agent deal proportioning are incorrect, many or few, can occur not solidify or solidify incomplete problem; Thickening filler is many, and finished product is really up to the mark can not use, and has lacked finished product and in construction process, there will be trickling phenomenon.
Particularly, in the present embodiment, described amine curing agent is preferably modified polyamine class solidifying agent; Auxiliary in auxiliary in first component and second component is toughner or defoamer or softening agent or above-mentioned three's arbitrary combination.In the present embodiment, described toughner is polypropylene glycol diglycidyl ether, can increase to be with in having just after products solidifying toughly, makes product that embrittlement can not occur; Described defoamer is silicone antifoam agent; Described softening agent is dibutylester.Certainly,, according to practical situation, also can adopt other auxiliary agents similar with above-mentioned each auxiliary agent.
Meanwhile, wilkinite described in the present embodiment is 180 order to 3000 object calcinated type wilkinites, i.e. wilkinite after calcining; The talcous preferred order number that uses is 800 order～3000 orders, and silicon powder is 200 order to 4000 orders.Meanwhile, each thickening filler has advantages of again different separately: can embrittlement after the wilkinite after calcining can make product use finished product after solidifying to reach the effect of light and finished product to solidify; Talcum powder can increase hardness and the ultimate compression strength after products solidifying; Silicon powder fluid stopping effect is very obvious, makes material in construction process, be difficult for trickling.
Preferably, first component can also comprise that weight part is that the pearlescence of 0.5～20 part or weight part are the titanium dioxide of 0.5～10 part.Pearlescence of all kinds can make glass cement have shades of colour, and titanium dioxide solely makes glass cement have white effect.
A preparation method for porcelain glass cement, comprises the steps:
(1) preparation of first component: take respectively by weight epoxy resin, thickening filler and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5～8 DEG C/min, in the time that temperature in the kettle reaches 65～80 DEG C, stop stirring, insulation reaction obtains epoxy glue finished product for 30～60 minutes; As required, can also in raw material, add weight part is that the pearlescence of 0.5～20 part or weight part are the titanium dioxide of 0.5～10 part.
(2) preparation of second component: take respectively by weight amine curing agent, thickening wads and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5～8 DEG C/min, in the time that temperature in the kettle reaches 65～80 DEG C, stop stirring, insulation reaction obtains for 30～60 minutes solidifies glue finished product;
(3) while use, by first component and second component be by weight: 1:0.4～1 mixes and obtain porcelain glass cement.Particularly, first the epoxy glue making and curing glue are contained in respectively independently in container, then pack into together in container, container peristome is provided with combining nozzle, and its use-pattern can be identical with existing glass cement, pushes by glue rifle, very easy to use.
Glass cement of the present invention, has advantages of following:
A, there is ceramic texture after solidifying, and bright and clean as porcelain, the dirt of scrubbing easy to clean.
B, ageing-resistant, forever can mouldyly not turn black.
C, can in water, harden, bonding repairing.
D, strong adhesion, difficult drop-off.
E, curing rear environmentally friendly, does not produce pollution, water-fast bubble.
F, use range are extensive, can be used on stone material, five metals, and glass, timber, the materials such as plastics bonding, squeegees.
Embodiment 1
Formula:
First component: 80 parts of epoxy resin, order number are 10 parts of 180 object wilkinites, 0.8 part of polypropylene glycol diglycidyl ether
Second component: 30 parts of amine curing agents, order number are 5 parts of 800 order talcum powder, 0.3 part of silicone antifoam agent
Preparation method:
(1) preparation of first component: take respectively by weight epoxy resin, thickening filler and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5 DEG C/min, in the time that temperature in the kettle reaches 65 DEG C, stop stirring, insulation reaction obtains epoxy glue finished product for 60 minutes;
(2) preparation of second component: take respectively by weight amine curing agent, thickening wads and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5 DEG C/min, in the time that temperature in the kettle reaches 65 DEG C, stop stirring, insulation reaction obtains for 60 minutes solidifies glue finished product;
(3) while use, by first component and second component be by weight: 1:1 mixes and obtain porcelain glass cement.
Embodiment 2
Formula:
First component: 90 parts of epoxy resin, order number are 30 parts of 200 object silicon powders, 9 parts of dibutylesters, 0.5 part of pearlescence
Second component: 45 parts of amine curing agents, order number are 20 parts of 3000 order talcum powder, 3 parts of silicone antifoam agents
Preparation method:
(1) preparation of first component: take respectively by weight epoxy resin, thickening filler and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5 DEG C/min, in the time that temperature in the kettle reaches 70 DEG C, stop stirring, insulation reaction obtains epoxy glue finished product for 50 minutes;
(2) preparation of second component: take respectively by weight amine curing agent, thickening wads and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 6 DEG C/min, in the time that temperature in the kettle reaches 65 DEG C, stop stirring, insulation reaction obtains for 40 minutes solidifies glue finished product;
(3) while use, by first component and second component be by weight: 1:0.8 mixes and obtain porcelain glass cement.
Embodiment 3
Formula:
First component: 100 parts of epoxy resin, order number are 60 parts of 800 object talcum powder, 10 parts of silicone antifoam agents, 10 parts of titanium dioxides
Second component: 60 parts of amine curing agents, order number are 30 parts of 400 order wilkinites, 6 parts of polypropylene glycol diglycidyl ethers
Preparation method:
(1) preparation of first component: take respectively by weight epoxy resin, thickening filler and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 8 DEG C/min, in the time that temperature in the kettle reaches 80 DEG C, stop stirring, insulation reaction obtains epoxy glue finished product for 30 minutes;
(2) preparation of second component: take respectively by weight amine curing agent, thickening wads and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 8 DEG C/min, in the time that temperature in the kettle reaches 80 DEG C, stop stirring, insulation reaction obtains for 30 minutes solidifies glue finished product;
(3) while use, by first component and second component be by weight: 1:0.4 mixes and obtain porcelain glass cement.
Embodiment 4
Formula:
First component: 100 parts of epoxy resin, order number be 50 parts of 3000 object wilkinites, 3 parts of polypropylene glycol diglycidyl ethers, 3 parts of silicone antifoam agents, 4 parts of dibutylesters, 20 parts of pearlescences,
Second component: 60 parts of amine curing agents, order number are 30 parts of 200 order silicon powders, 1 part of polypropylene glycol diglycidyl ether, 2 parts of silicone antifoam agents, 3 parts of dibutylesters
Preparation method:
(1) preparation of first component: take respectively by weight epoxy resin, thickening filler and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5 DEG C/min, in the time that temperature in the kettle reaches 75 DEG C, stop stirring, insulation reaction obtains epoxy glue finished product for 60 minutes;
(2) preparation of second component: take respectively by weight amine curing agent, thickening wads and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5 DEG C/min, in the time that temperature in the kettle reaches 75 DEG C, stop stirring, insulation reaction obtains for 60 minutes solidifies glue finished product;
(3) while use, by first component and second component be by weight: 1:0.5 mixes and obtain porcelain glass cement.
Embodiment 5
Formula:
First component: 95 parts of epoxy resin, order number be 55 parts of 3000 object talcum powder, 2 parts of polypropylene glycol diglycidyl ethers, 1 part of silicone antifoam agent, 1 part of dibutylester, 15 parts of pearlescences,
Second component: 55 parts of amine curing agents, order number are 25 parts of 800 order wilkinites, 0.8 part of polypropylene glycol diglycidyl ether, 3 parts of silicone antifoam agents, 0.5 part of dibutylester
Preparation method:
(1) preparation of first component: take respectively by weight epoxy resin, thickening filler and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 7 DEG C/min, in the time that temperature in the kettle reaches 60 DEG C, stop stirring, insulation reaction obtains epoxy glue finished product for 45 minutes;
(2) preparation of second component: take respectively by weight amine curing agent, thickening wads and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 6 DEG C/min, in the time that temperature in the kettle reaches 70 DEG C, stop stirring, insulation reaction obtains for 35 minutes solidifies glue finished product;
(3) while use, by first component and second component be by weight: 1:0.8 mixes and obtain porcelain glass cement.
Embodiment 6
Formula:
First component: 85 parts of epoxy resin, order number be 35 parts of 1000 object silicon powders, 2 parts of polypropylene glycol diglycidyl ethers, 4 parts of silicone antifoam agents, 10 parts of pearlescences,
Second component: 50 parts of amine curing agents, order number are 15 parts of 4000 order silicon powders, 3 parts of polypropylene glycol diglycidyl ethers, 1 part of dibutylester
Preparation method:
(1) preparation of first component: take respectively by weight epoxy resin, thickening filler and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5 DEG C/min, in the time that temperature in the kettle reaches 75 DEG C, stop stirring, insulation reaction obtains epoxy glue finished product for 60 minutes;
(2) preparation of second component: take respectively by weight amine curing agent, thickening wads and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5 DEG C/min, in the time that temperature in the kettle reaches 75 DEG C, stop stirring, insulation reaction obtains for 60 minutes solidifies glue finished product;
(3) while use, by first component and second component be by weight: 1:0.7 mixes and obtain porcelain glass cement.
Embodiment 7
Formula:
First component: 80 parts of epoxy resin, order number be 15 parts of 800 object wilkinites, order number be 20 parts of 400 order talcum powder, 4 parts of silicone antifoam agents, 3 parts of dibutylesters, 0.5 part of titanium dioxide,
Second component: 35 parts of amine curing agents, order number are that 5 parts of 1000 order wilkinites, order number are that 15 parts of 1200 order talcum powder, order number are 5 parts of 600 order silicon powders, 0.5 part of polypropylene glycol diglycidyl ether, 1 part of silicone antifoam agent, 1 part of dibutylester
Preparation method:
(1) preparation of first component: take respectively by weight epoxy resin, thickening filler and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5 DEG C/min, in the time that temperature in the kettle reaches 65 DEG C, stop stirring, insulation reaction obtains epoxy glue finished product for 50 minutes;
(2) preparation of second component: take respectively by weight amine curing agent, thickening wads and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 6 DEG C/min, in the time that temperature in the kettle reaches 80 DEG C, stop stirring, insulation reaction obtains for 35 minutes solidifies glue finished product;
(3) while use, by first component and second component be by weight: 1:1 mixes and obtain porcelain glass cement.
Experimental example
Send Guangdong product quality supervision and inspection research institute to test glass cement of the present invention, test basis reference: GB/T 1735～2009 " the stable on heating mensuration of paint and varnish ", GB/T 9268～2008 " mensuration of emulsion paint freeze-thaw resistance ", HG/T 3828～2006 " indoor aqueous wooden ware paint vehicle ", GB/T 9274～1988 " mensuration of the resistance to liquid medium of paint and varnish ", GB/T 1728～1979 " paint films, putty membrane assay method time of drying ", assay is as following table:
Can be proved that by above-mentioned experiment glass cement of the present invention has good anti-high and low temperature anti acid alkali performance energy, and is obviously better than existing glass cement set time.
Claims (8)
1. a porcelain glass cement, is characterized in that, is made up of first component and second component, and the weight ratio of first component and second component is: 1:0.4～1; Described first component is mainly made up of the raw material of following weight parts: 80～100 parts of epoxy resin, order number are 10～60 parts of thickening fillers and 0.8～10 part of parts of auxiliary more than 180 orders, and described thickening filler is wilkinite or talcum powder or silicon powder or above-mentioned three's arbitrary combination; Described second component is made up of the raw material of following weight parts: 30～60 parts of amine curing agents, order number are 0.3～6 part of more than 180 orders 5～30 parts of thickening fillers and auxiliary, and described thickening filler is wilkinite or talcum powder or silicon powder or above-mentioned three's arbitrary combination.
2. a kind of porcelain glass cement according to claim 1, is characterized in that, described first component also comprises that weight part is that the pearlescence of 0.5～20 part or weight part are the titanium dioxide of 0.5～10 part.
3. a kind of porcelain glass cement according to claim 1 and 2, is characterized in that, the auxiliary in the auxiliary in first component and second component is toughner or defoamer or softening agent or above-mentioned three's arbitrary combination.
4. a kind of porcelain glass cement according to claim 3, is characterized in that, described toughner is polypropylene glycol diglycidyl ether; Described defoamer is silicone antifoam agent; Described softening agent is dibutylester.
5. a kind of porcelain glass cement according to claim 1, is characterized in that, described amine curing agent is modified polyamine class solidifying agent.
6. a kind of porcelain glass cement according to claim 1, is characterized in that, described wilkinite is 180 order to 3000 object calcinated type wilkinites.
7. a method of preparing porcelain glass cement described in claim 1, is characterized in that, comprises the steps:
(1) preparation of first component: take respectively by weight epoxy resin, thickening filler and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5～8 DEG C/min, in the time that temperature in the kettle reaches 65～80 DEG C, stop stirring, insulation reaction obtains epoxy glue finished product for 30～60 minutes; (2) preparation of second component: take respectively by weight amine curing agent, thickening wads and auxiliary, each raw material is put into reactor under room temperature environment, stir on intensification limit, limit, heat-up rate is 5～8 DEG C/min, in the time that temperature in the kettle reaches 65～80 DEG C, stop stirring, insulation reaction obtains for 30～60 minutes solidifies glue finished product; (3) while use, by first component and second component be by weight: 1:0.4～1 mixes and obtain porcelain glass cement.
8. the preparation method of a kind of porcelain glass cement according to claim 7, is characterized in that, in the step (1), has also added weight part and be the pearlescence of 0.5～20 part or weight part and be the titanium dioxide of 0.5～10 part.
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| CN115305015A (en) * | 2022-08-30 | 2022-11-08 | 共享智能装备有限公司 | Gap filler for 3D printing product and preparation method |
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| CN101284979A (en) * | 2007-04-12 | 2008-10-15 | 张建杉 | Water-proofing material for adhesive joint between solid objects |
| CN103320071B (en) * | 2013-06-28 | 2015-08-12 | 上海悍马建筑科技有限公司 | The transparent Crack Sealing chewing-gum of modified epoxy |
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