CN103709586A - Rat and termite prevention PA/ABS (polyamide/acrylonitrile-butadiene-styrene) environmentally-friendly plastic - Google Patents
Rat and termite prevention PA/ABS (polyamide/acrylonitrile-butadiene-styrene) environmentally-friendly plastic Download PDFInfo
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- CN103709586A CN103709586A CN201310738080.6A CN201310738080A CN103709586A CN 103709586 A CN103709586 A CN 103709586A CN 201310738080 A CN201310738080 A CN 201310738080A CN 103709586 A CN103709586 A CN 103709586A
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Abstract
The invention discloses a rat and termite prevention PA/ABS (polyamide/acrylonitrile-butadiene-styrene) environmentally-friendly plastic. The rat and termite prevention PA/ABS environmentally-friendly plastic comprises the following components in parts by weight: 25 parts of PA, 70 parts of ABS, 2-4 parts of compatilizer ABS-g-MAH and 3-5 parts of biological rat and termite prevention agent. The rat and termite prevention PA/ABS environmentally-friendly plastic has excellent rat and termite biting prevention performance.
Description
Technical field
The present invention relates to a kind of plastic material, relate in particular to a kind of rat-and-ant proof PA/ABS environmentally-friendly plastic.
Background technology
Mouse extensively lives in each area in the world as a kind of reproductivity and the very strong rodent of vitality, because its front tooth is very flourishing and constantly growth, so muroid has the object of nibbling to keep the habit that its tooth is sharp, the distinctive smell of plastics makes plastics become the muroid object that often bites.
Termite also claims that worm is luxuriant, is in the streets commonly called as flood ant (because conventionally occur, hence obtaining one's name) before raining, the general name of isoptera insect, approximately kind more than 2000.For the paurometabola of incomplete metamorphosis and be social insect, the termite individuality in each termitarium can reach more than 1,000,000.Termite damage building construction, reservoir dam, mountain forest orchard, vehicle ship etc., cause very large loss to national economy.The distinctive smell of plastics makes plastics become the termite object that often bites.
Existing plastic material in order to realize rat-and-ant proof, adds the poisoning agents such as Niran, aldrin conventionally in plastics, has very large environmental pollution, and very harmful to HUMAN HEALTH, not environmental protection of the utmost point.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide a kind of rat-and-ant proof PA/ABS environmentally-friendly plastic.
Technical problem to be solved by this invention is achieved by the following technical solution:
A rat-and-ant proof PA/ABS environmentally-friendly plastic, consists of by weight following component: 25 parts of PA, 70 parts of ABS, 2-4 part compatilizer ABS-g-MAH, the biological rat-and-ant proof agent of 3-5 part.
Described biological rat-and-ant proof agent, consists of by weight following component: 10-30 part 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, 10-30 part Triptonide, 10-30 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.
11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, Triptonide, N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide are uniformly mixed, and can make biological rat-and-ant proof agent.
Can adopt industry universal method to be prepared rat-and-ant proof PA/ABS environmentally-friendly plastic of the present invention, for example: by proportioning, take each component, after mixing, melting mixing, extruding pelletization, obtain described rat-and-ant proof PA/ABS environmentally-friendly plastic.
Concrete, can be for take each component by proportioning, in mixing machine, under room temperature, control rotating speed at 300-400 rev/min, mix 2-10 minute, after taking-up, proceed in screw extrusion press, extruding pelletization at 180-200 ℃ of temperature, obtains described rat-and-ant proof PA/ABS environmentally-friendly plastic.
Rat-and-ant proof PA/ABS environmentally-friendly plastic of the present invention, has excellent preventing from being eaten by ant and mouse performance.
Embodiment
Embodiment 1
According to corresponding embodiment 1-4 data in table 1, take each raw material.Each component is joined in high-speed mixer, control rotating speed at 320 revs/min under room temperature, mix 6 minutes, proceed in screw extrusion press after taking-up, extruding pelletization at 190 ℃ of temperature, obtains rat-and-ant proof PA/ABS environmentally-friendly plastic.
Table 1: rat-and-ant proof PA/ABS environmentally-friendly plastic formula table unit: kilogram
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| PA resin | 25 | 25 | 25 | 25 |
| ABS resin | 70 | 70 | 70 | 70 |
| Compatilizer ABS-g-MAH | 3 | 3 | 3 | 3 |
| 11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone | 1.6 | 2.4 | 2.4 | / |
| Triptonide | 1.6 | 2.4 | / | 2.4 |
| N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide | 1.6 | / | 2.4 | 2.4 |
11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, No. CAS: 6882-66-2.Triptonide, No. CAS: 38647-11-9.N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide, No. CAS: 19408-84-5.
PA resin is selected the PA66 resin of the trade mark 101L of du pont company; ABS resin is selected the ABS resin of the trade mark 0215A of Jilin Petrochemical company.
Test case 1
Adopt GB/T2951.38-1986 electric wire termite test method, knock down method test.
Test piece: 50mm * 50mm * 1mm.
Table 2: anti-ant performance test table
| ? | Termite is knocked down time KT50, min |
| Embodiment 1 | 168 |
| Embodiment 2 | 182 |
| Embodiment 3 | 186 |
| Embodiment 4 | 175 |
Visible, by 11,12, composite use, synergy are carried out in 13,14-, tetra-dehydrogenation matridinde-15-ketone, Triptonide, N-(4-hydroxyl-3-methoxybenzy)-biological rat-and-ant proof agent of three kinds of 8-methyl pelargonamides, the termite time of knocking down obviously reduces, and anti-ant performance is good.
Test case 2
Adopt GB/T2951.38-1986 electric wire termite test method, the rat-and-ant proof PA/ABS environmentally-friendly plastic of embodiment 1 is carried out to Colony test test.Test piece: 80mm * 25mm * 1mm.
Test result: termite moth erosion grade is 1 grade.
Test case 3
Test materials film-making: sample is made to the test piece that specification is 150mm * 20mm * 3mm according to GB/T8815-2002 pilot scale piece preparation method.
Testing installation and experimental animal: weight 250-300 gram of SD male rat PP plastics casing stainless steel square mouse cage, mouse cage specification is high 250mm, long is 600mm, wide is 400mm, at the bottom of mouse cage and wall be PP plastics, top is stainless steel square, and is furnished with waterer.
Testing sequence: choose SD male rat, mouse cage is put in stochastic sampling, 5, every cage; Test piece is stretched in cage from mouse cage top, with thin copper wire tightly colligation at the stainless (steel) wire near feeding place, cover, the part that test piece is exposed at beyond mouse cage is no more than 20mm, a cage hangs three test pieces, test piece is evenly arranged on mouse cage width, and interval is approximately 80mm.Rat is at duration of test regular supply drink ArsenazoⅢ (be that every day changed clear water by waterer, feeding place has remained food).Observe the activity of rat and diet situation and test period every day and finish the situation that rear sample is bitten by rat.Test period is 7 days.
The rat-and-ant proof PA/ABS environmentally-friendly plastic of embodiment 1: area 2.5% bites.
Claims (2)
1. a rat-and-ant proof PA/ABS environmentally-friendly plastic, is characterized in that, following component, consists of by weight: 25 parts of PA, 70 parts of ABS, 2-4 part compatilizer ABS-g-MAH, the biological rat-and-ant proof agent of 3-5 part.
2. rat-and-ant proof PA/ABS environmentally-friendly plastic as claimed in claim 1, it is characterized in that, described biological rat-and-ant proof agent, by following component, formed by weight: 10-30 part 11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, 10-30 part Triptonide, 10-30 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.
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| CN201310738080.6A CN103709586B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PA/ABS environmentally-friendly plastic |
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| CN201310738080.6A CN103709586B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PA/ABS environmentally-friendly plastic |
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| CN103709586A true CN103709586A (en) | 2014-04-09 |
| CN103709586B CN103709586B (en) | 2017-01-04 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105295358A (en) * | 2015-12-05 | 2016-02-03 | 淄博夸克医药技术有限公司 | Ratproof and anti-termite PA-ABS environment-friendly plastic |
| CN110467810A (en) * | 2019-08-13 | 2019-11-19 | 江门市凯生工程塑料有限公司 | A kind of preparation method of the rat-and-ant proof PA environmentally-friendly plastic of high impact |
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| JPH09219116A (en) * | 1996-02-13 | 1997-08-19 | Yazaki Corp | Ant-proof and rat-proof covered wire |
| CN101798417A (en) * | 2010-03-26 | 2010-08-11 | 华南理工大学 | Anti-termite and coloring functional master batch for plastic and preparation method thereof |
| CN103360719A (en) * | 2013-07-15 | 2013-10-23 | 上海秋橙新材料科技有限公司 | Anti-aging PA-ABS plastic alloy |
| CN103371169A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Sophoramine insect-preventing missible oil, sophoramine insect-preventing fabric and preparation method of fabric |
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2013
- 2013-12-15 CN CN201310738080.6A patent/CN103709586B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09219116A (en) * | 1996-02-13 | 1997-08-19 | Yazaki Corp | Ant-proof and rat-proof covered wire |
| CN101798417A (en) * | 2010-03-26 | 2010-08-11 | 华南理工大学 | Anti-termite and coloring functional master batch for plastic and preparation method thereof |
| CN103371169A (en) * | 2012-04-16 | 2013-10-30 | 上海韬鸿化工科技有限公司 | Sophoramine insect-preventing missible oil, sophoramine insect-preventing fabric and preparation method of fabric |
| CN103360719A (en) * | 2013-07-15 | 2013-10-23 | 上海秋橙新材料科技有限公司 | Anti-aging PA-ABS plastic alloy |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105295358A (en) * | 2015-12-05 | 2016-02-03 | 淄博夸克医药技术有限公司 | Ratproof and anti-termite PA-ABS environment-friendly plastic |
| CN110467810A (en) * | 2019-08-13 | 2019-11-19 | 江门市凯生工程塑料有限公司 | A kind of preparation method of the rat-and-ant proof PA environmentally-friendly plastic of high impact |
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| CN103709586B (en) | 2017-01-04 |
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Effective date of registration: 20170510 Address after: Changning Lotus Village town of Chenghai District of Shantou city in Guangdong province 515800 Patentee after: SHANTOU GUANGLONG PLASTIC CO.,LTD. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T157 Patentee before: SHANGHAI YUEMENG ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. |
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Granted publication date: 20170104 Termination date: 20211215 |