CN103694668A - PPO/PPS (Polyphenylene Oxide/Polyphenylene Sulfide) environmental-friendly plastics capable of resisting mice and ants - Google Patents
PPO/PPS (Polyphenylene Oxide/Polyphenylene Sulfide) environmental-friendly plastics capable of resisting mice and ants Download PDFInfo
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- CN103694668A CN103694668A CN201310694402.1A CN201310694402A CN103694668A CN 103694668 A CN103694668 A CN 103694668A CN 201310694402 A CN201310694402 A CN 201310694402A CN 103694668 A CN103694668 A CN 103694668A
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Abstract
The invention discloses PPO/PPS (Polyphenylene Oxide/Polyphenylene Sulfide) environmental-friendly plastics capable of resisting mice and ants. The PPO/PPS environmental-friendly plastics are prepared from the following ingredients in parts by weight: 70 parts of PPO, 20 parts of PPS, 3-7 parts of compatibilizer PS-g-PMMA and 3-5 parts of biological mouse/ant resisting agent. The PPO/PPS environmental-friendly plastics capable of resisting mice and ants, disclosed by the invention, have excellent mechanical properties, heat resistance and flame retardance and have excellent mouse/ant eating damage resistance.
Description
Technical field
The present invention relates to a kind of plastic material, relate in particular to a kind of rat-and-ant proof PPO/PPS environmentally-friendly plastic.
Background technology
Mouse extensively lives in each area in the world as a kind of reproductivity and the very strong rodent of vitality, because its front tooth is very flourishing and constantly growth, so muroid has the object of nibbling to keep the habit that its tooth is sharp, the distinctive smell of plastics makes plastics become the muroid object that often bites.
Termite also claims that worm is luxuriant, is in the streets commonly called as flood ant (because conventionally occur, hence obtaining one's name) before raining, the general name of isoptera insect, approximately kind more than 2000.For the paurometabola of incomplete metamorphosis and be social insect, the termite individuality in each termitarium can reach more than 1,000,000.Termite damage building construction, reservoir dam, mountain forest orchard, vehicle ship etc., cause very large loss to national economy.The distinctive smell of plastics makes plastics become the termite object that often bites.
Existing plastic material in order to realize rat-and-ant proof, adds the poisoning agents such as Niran, aldrin conventionally in plastics, has very large environmental pollution, and very harmful to HUMAN HEALTH, not environmental protection of the utmost point.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide a kind of rat-and-ant proof PPO/PPS environmentally-friendly plastic.
Technical problem to be solved by this invention is achieved by the following technical solution:
A rat-and-ant proof PPO/PPS environmentally-friendly plastic, consists of by weight following component: 70 parts of PPO, 20 parts of PPS, 3-7 part compatilizer PS-g-PMMA, the biological rat-and-ant proof agent of 3-5 part.
Described biological rat-and-ant proof agent, consists of by weight following component: 5-15 part 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, 5-15 part Triptonide, 5-15 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.
11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, Triptonide, N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide are uniformly mixed, and can make biological rat-and-ant proof agent.
Can adopt industry universal method to be prepared rat-and-ant proof PPO/PPS environmentally-friendly plastic of the present invention, for example: by proportioning, take each component, after mixing, melting mixing, extruding pelletization, obtain described rat-and-ant proof PPO/PPS environmentally-friendly plastic.
Concrete, can be for take each component by proportioning, in mixing machine, under room temperature, control rotating speed at 300-400 rev/min, mix 2-10 minute, after taking-up, proceed in screw extrusion press, extruding pelletization at 290-310 ℃ of temperature, obtains described rat-and-ant proof PPO/PPS environmentally-friendly plastic.
PPS, polyphenylene sulfide, has hard and crisp, the advantage such as degree of crystallinity is high, difficult combustion, Heat stability is good, physical strength is higher, electrical property is good.PPO, polyphenylene oxide, has that rigidity is large, thermotolerance is high, difficult combustion, intensity be compared with advantages such as high electrical performance are good.
Rat-and-ant proof PPO/PPS environmentally-friendly plastic of the present invention, has good mechanical property, thermotolerance and flame retardant resistance, and has excellent preventing from being eaten by ant and mouse performance.
Embodiment
Embodiment 1
According to corresponding embodiment 1-4 data in table 1, take each raw material.Each component is joined in high-speed mixer, control rotating speed at 320 revs/min under room temperature, mix 8 minutes, proceed in screw extrusion press after taking-up, extruding pelletization at 300 ℃ of temperature, obtains rat-and-ant proof PPO/PPS environmentally-friendly plastic.
Table 1: rat-and-ant proof PPO/PPS environmentally-friendly plastic formula table unit: kilogram
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| PPO resin | 70 | 70 | 70 | 70 |
| PPS resin | 20 | 20 | 20 | 20 |
| Compatilizer PS-g-PMMA | 5.2 | 5.2 | 5.2 | 5.2 |
| 11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone | 1.6 | 2.4 | 2.4 | / |
| Triptonide | 1.6 | 2.4 | / | 2.4 |
| N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide | 1.6 | / | 2.4 | 2.4 |
11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, No. CAS: 6882-66-2.Triptonide, No. CAS: 38647-11-9.N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide, No. CAS: 19408-84-5.
PPS resin is selected the PPS resin of the trade mark 6165A6 of Ticona company; PPO resin adopts the PPO resin that the basic company of the husky uncle trade mark is V03550-701.
Test case 1
Adopt GB/T2951.38-1986 electric wire termite test method, knock down method test.
Test piece: 50mm * 50mm * 1mm.
Table 2: anti-ant performance test table
| ? | Termite is knocked down time KT50, min |
| Embodiment 1 | 135 |
| Embodiment 2 | 166 |
| Embodiment 3 | 152 |
| Embodiment 4 | 145 |
Visible, by 11,12, composite use, synergy are carried out in 13,14-, tetra-dehydrogenation matridinde-15-ketone, Triptonide, N-(4-hydroxyl-3-methoxybenzy)-biological rat-and-ant proof agent of three kinds of 8-methyl pelargonamides, the termite time of knocking down obviously reduces, and anti-ant performance is good.
Test case 2
Adopt GB/T2951.38-1986 electric wire termite test method, the rat-and-ant proof PPO/PPS environmentally-friendly plastic of embodiment 1 is carried out to Colony test test.Test piece: 80mm * 25mm * 1mm.
Test result: termite moth erosion grade is 1 grade.
Test case 3
Test materials film-making: sample is made to the test piece that specification is 150mm * 20mm * 3mm according to GB/T8815-2002 pilot scale piece preparation method.
Testing installation and experimental animal: weight 250-300 gram of SD male rat PP plastics casing stainless steel square mouse cage, mouse cage specification is high 250mm, long is 600mm, wide is 400mm, at the bottom of mouse cage and wall be PP plastics, top is stainless steel square, and is furnished with waterer.
Testing sequence: choose SD male rat, mouse cage is put in stochastic sampling, 5, every cage; Test piece is stretched in cage from mouse cage top, with thin copper wire tightly colligation at the stainless (steel) wire near feeding place, cover, the part that test piece is exposed at beyond mouse cage is no more than 20mm, a cage hangs three test pieces, test piece is evenly arranged on mouse cage width, and interval is approximately 80mm.Rat is at duration of test regular supply drink ArsenazoⅢ (be that every day changed clear water by waterer, feeding place has remained food).Observe the activity of rat and diet situation and test period every day and finish the situation that rear sample is bitten by rat.Test period is 7 days.
The rat-and-ant proof PPO/PPS environmentally-friendly plastic of embodiment 1: area 0% bites.
Claims (2)
1. a rat-and-ant proof PPO/PPS environmentally-friendly plastic, is characterized in that, following component, consists of by weight: 70 parts of PPO, 20 parts of PPS, 3-7 part compatilizer PS-g-PMMA, the biological rat-and-ant proof agent of 3-5 part.
2. rat-and-ant proof PPO/PPS environmentally-friendly plastic as claimed in claim 1, it is characterized in that, described biological rat-and-ant proof agent, by following component, formed by weight: 5-15 part 11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, 5-15 part Triptonide, 5-15 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.
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| CN201310694402.1A CN103694668B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PPO/PPS environmentally-friendly plastic |
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| CN201310694402.1A CN103694668B (en) | 2013-12-15 | 2013-12-15 | Rat-and-ant proof PPO/PPS environmentally-friendly plastic |
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| CN103694668A true CN103694668A (en) | 2014-04-02 |
| CN103694668B CN103694668B (en) | 2016-08-17 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1275588A (en) * | 1999-06-01 | 2000-12-06 | 周宝茂 | Plastics for preventing cable from being eaten by ant and mouse |
| CN101587759A (en) * | 2009-06-29 | 2009-11-25 | 深圳市联嘉祥科技股份有限公司 | Environmental cable for preventing white ant |
| CN102746547A (en) * | 2012-04-23 | 2012-10-24 | 深圳市鑫康沃科技开发有限公司 | Capillary penetration micro irrigation material and preparation method thereof |
| CN103351600A (en) * | 2013-07-15 | 2013-10-16 | 上海秋橙新材料科技有限公司 | Aging-resistant PPO (Polyphenylene Oxide) - PPS (Polyphenylene Sulfite) plastic alloy |
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2013
- 2013-12-15 CN CN201310694402.1A patent/CN103694668B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1275588A (en) * | 1999-06-01 | 2000-12-06 | 周宝茂 | Plastics for preventing cable from being eaten by ant and mouse |
| CN101587759A (en) * | 2009-06-29 | 2009-11-25 | 深圳市联嘉祥科技股份有限公司 | Environmental cable for preventing white ant |
| CN102746547A (en) * | 2012-04-23 | 2012-10-24 | 深圳市鑫康沃科技开发有限公司 | Capillary penetration micro irrigation material and preparation method thereof |
| CN103351600A (en) * | 2013-07-15 | 2013-10-16 | 上海秋橙新材料科技有限公司 | Aging-resistant PPO (Polyphenylene Oxide) - PPS (Polyphenylene Sulfite) plastic alloy |
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| CN103694668B (en) | 2016-08-17 |
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Inventor after: Pan Xiaozhong Inventor before: Ding Yonghua |
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Effective date of registration: 20170428 Address after: 515000 Guangdong city in Shantou province road by Huaneng thermal power plant industrial workshop 1 102 Patentee after: GUANGDONG HAPPYHOME PLASTIC CO., LTD. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T157 Patentee before: Shanghai Yuemeng Environmental Protection Technology Co., Ltd. |
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