CN103709707A - Rat/ant-resistant environment-friendly PBT (polybutylece terephthalate)/PC (polycarbonate) plastic - Google Patents
Rat/ant-resistant environment-friendly PBT (polybutylece terephthalate)/PC (polycarbonate) plastic Download PDFInfo
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Abstract
The invention discloses rat/ant-resistant environment-friendly PBT (polybutylece terephthalate)/PC (polycarbonate) plastic which consists of the following components in parts by weight: 25 parts of PBT, 65 parts of PC, 3-7 parts of a compatilizer PS-g-PMMA (polystyrene-g-polymethyl methacrylate) and 3-5 parts of a biological rat/ant-resistant agent. The rat/ant-resistant environment-friendly PBT/PC plastic is high in heat resistance, stress-cracking resistant, high in abrasion performance and chemical corrosion property and high in ant and rat food pollution resistance.
Description
Technical field
The present invention relates to a kind of plastic material, relate in particular to a kind of rat-and-ant proof PBT/PC environmentally-friendly plastic.
Background technology
Mouse extensively lives in each area in the world as a kind of reproductivity and the very strong rodent of vitality, because its front tooth is very flourishing and constantly growth, so muroid has the object of nibbling to keep the habit that its tooth is sharp, the distinctive smell of plastics makes plastics become the muroid object that often bites.
Termite also claims that worm is luxuriant, is in the streets commonly called as flood ant (because conventionally occur, hence obtaining one's name) before raining, the general name of isoptera insect, approximately kind more than 2000.For the paurometabola of incomplete metamorphosis and be social insect, the termite individuality in each termitarium can reach more than 1,000,000.Termite damage building construction, reservoir dam, mountain forest orchard, vehicle ship etc., cause very large loss to national economy.The distinctive smell of plastics makes plastics become the termite object that often bites.
Existing plastic material in order to realize rat-and-ant proof, adds the poisoning agents such as Niran, aldrin conventionally in plastics, has very large environmental pollution, and very harmful to HUMAN HEALTH, not environmental protection of the utmost point.
Summary of the invention
For above shortcomings in prior art, technical problem to be solved by this invention is to provide a kind of rat-and-ant proof PBT/PC environmentally-friendly plastic.
Technical problem to be solved by this invention is achieved by the following technical solution:
A rat-and-ant proof PBT/PC environmentally-friendly plastic, consists of by weight following component: 25 parts of PBT, 65 parts of PC, 3-7 part compatilizer PS-g-PMMA, the biological rat-and-ant proof agent of 3-5 part.
Described biological rat-and-ant proof agent, consists of by weight following component: 5-15 part 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, 5-15 part Triptonide, 5-15 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.
11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, Triptonide, N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide are uniformly mixed, and can make biological rat-and-ant proof agent.
Can adopt industry universal method to be prepared rat-and-ant proof PBT/PC environmentally-friendly plastic of the present invention, for example: by proportioning, take each component, after mixing, melting mixing, extruding pelletization, obtain described rat-and-ant proof PBT/PC environmentally-friendly plastic.
Concrete, can be for take each component by proportioning, in mixing machine, under room temperature, control rotating speed at 300-400 rev/min, mix 2-10 minute, after taking-up, proceed in screw extrusion press, extruding pelletization at 220-250 ℃ of temperature, obtains described rat-and-ant proof PBT/PC environmentally-friendly plastic.
PC, polycarbonate, water white transparency, heat-resisting, shock resistance, fire-retardant BI level has good mechanical property in common use temperature.With performance, approach polymethylmethacrylate and compare, the impact resistance of polycarbonate is good, and specific refractory power is high, and good processability does not need additive just to have UL94V-0 level flame retardant properties.PBT, polybutylene terephthalate, has high heat resistance, toughness, resistance to fatigue, self-lubricating, low-friction coefficient.
Rat-and-ant proof PBT/PC environmentally-friendly plastic of the present invention, good heat resistance, stress crack resistant, have good wear-resisting, chemical resistance, and there is excellent preventing from being eaten by ant and mouse performance.
Embodiment
Embodiment 1
According to corresponding embodiment 1-4 data in table 1, take each raw material.Each component is joined in high-speed mixer, control rotating speed at 320 revs/min under room temperature, mix 8 minutes, proceed in screw extrusion press after taking-up, extruding pelletization at 240 ℃ of temperature, obtains rat-and-ant proof PBT/PC environmentally-friendly plastic.
Table 1: rat-and-ant proof PBT/PC environmentally-friendly plastic formula table unit: kilogram
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| PBT resin | 25 | 25 | 25 | 25 |
| PC resin | 65 | 65 | 65 | 65 |
| Compatilizer PS-g-PMMA | 5.2 | 5.2 | 5.2 | 5.2 |
| 11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone | 1.6 | 2.4 | 2.4 | / |
| Triptonide | 1.6 | 2.4 | / | 2.4 |
| N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide | 1.6 | / | 2.4 | 2.4 |
11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, No. CAS: 6882-66-2.Triptonide, No. CAS: 38647-11-9.N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide, No. CAS: 19408-84-5.
PBT resin is selected the PBT resin of husky uncle basis (former GE) trade mark VIC4350 of company; PC resin is selected the injection grade PC resin of the basic trade mark 241R of company of husky uncle.
Test case 1
Adopt GB/T2951.38-1986 electric wire termite test method, knock down method test.
Test piece: 50mm * 50mm * 1mm.
Table 2: anti-ant performance test table
| ? | Termite is knocked down time KT50, min |
| Embodiment 1 | 144 |
| Embodiment 2 | 170 |
| Embodiment 3 | 165 |
| Embodiment 4 | 158 |
Visible, by 11,12, composite use, synergy are carried out in 13,14-, tetra-dehydrogenation matridinde-15-ketone, Triptonide, N-(4-hydroxyl-3-methoxybenzy)-biological rat-and-ant proof agent of three kinds of 8-methyl pelargonamides, the termite time of knocking down obviously reduces, and anti-ant performance is good.
Test case 2
Adopt GB/T2951.38-1986 electric wire termite test method, the rat-and-ant proof PBT/PC environmentally-friendly plastic of embodiment 1 is carried out to Colony test test.Test piece: 80mm * 25mm * 1mm.
Test result: termite moth erosion grade is 1 grade.
Test case 3
Test materials film-making: sample is made to the test piece that specification is 150mm * 20mm * 3mm according to GB/T8815-2002 pilot scale piece preparation method.
Testing installation and experimental animal: weight 250-300 gram of SD male rat PP plastics casing stainless steel square mouse cage, mouse cage specification is high 250mm, long is 600mm, wide is 400mm, at the bottom of mouse cage and wall be PP plastics, top is stainless steel square, and is furnished with waterer.
Testing sequence: choose SD male rat, mouse cage is put in stochastic sampling, 5, every cage; Test piece is stretched in cage from mouse cage top, with thin copper wire tightly colligation at the stainless (steel) wire near feeding place, cover, the part that test piece is exposed at beyond mouse cage is no more than 20mm, a cage hangs three test pieces, test piece is evenly arranged on mouse cage width, and interval is approximately 80mm.Rat is at duration of test regular supply drink ArsenazoⅢ (be that every day changed clear water by waterer, feeding place has remained food).Observe the activity of rat and diet situation and test period every day and finish the situation that rear sample is bitten by rat.Test period is 7 days.
The rat-and-ant proof PBT/PC environmentally-friendly plastic of embodiment 1: area 2% bites.
Claims (2)
1. a rat-and-ant proof PBT/PC environmentally-friendly plastic, is characterized in that, following component, consists of by weight: 25 parts of PBT, 65 parts of PC, 3-7 part compatilizer PS-g-PMMA, the biological rat-and-ant proof agent of 3-5 part.
2. rat-and-ant proof PBT/PC environmentally-friendly plastic as claimed in claim 1, it is characterized in that, described biological rat-and-ant proof agent, by following component, formed by weight: 5-15 part 11,12,13,14-, tetra-dehydrogenation matridinde-15-ketone, 5-15 part Triptonide, 5-15 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102746547A (en) * | 2012-04-23 | 2012-10-24 | 深圳市鑫康沃科技开发有限公司 | Capillary penetration micro irrigation material and preparation method thereof |
| CN103351593A (en) * | 2013-07-14 | 2013-10-16 | 上海秋橙新材料科技有限公司 | Aging-resistant PC (Polycarbonate) -PBT (Polybutylene Terephthalate) plastic alloy |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102746547A (en) * | 2012-04-23 | 2012-10-24 | 深圳市鑫康沃科技开发有限公司 | Capillary penetration micro irrigation material and preparation method thereof |
| CN103351593A (en) * | 2013-07-14 | 2013-10-16 | 上海秋橙新材料科技有限公司 | Aging-resistant PC (Polycarbonate) -PBT (Polybutylene Terephthalate) plastic alloy |
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Inventor after: Yang Yuebin Inventor before: Ding Yonghua |
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Effective date of registration: 20170426 Address after: 511335 Guangdong City, Zengcheng District, the town of fairy village on the Village Development Zone Patentee after: Guangzhou Ding Hong Plastic Industry Co., Ltd. Address before: 201107 Shanghai city Minhang District Minhang Road 88 Lane No. 1-30 building twenty-second room T157 Patentee before: Shanghai Yuemeng Environmental Protection Technology Co., Ltd. |
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Effective date of registration: 20211129 Address after: 529000 No. 13 Chuangye Road, Jianghai District, Jiangmen City, Guangdong Province Patentee after: Guangdong senhong Technology Co.,Ltd. Address before: 511335 Baotian Development Zone, Shangjing village, Xiancun Town, Zengcheng District, Guangzhou City, Guangdong Province Patentee before: Guangzhou Ding Hong Plastic Industry Co.,Ltd. |