CN103709706B - Rat-and-ant proof PA/PC environmentally-friendly plastic - Google Patents

Abstract

The invention discloses a kind of rat-and-ant proof PA/PC environmentally-friendly plastic, be made up of by weight following component: 15 parts of PA, 75 parts of PC, 5-7 part Compatibilizer PP-g-MAHs, 3-5 part biology rat-and-ant proof agent. The rat-and-ant proof PA/PC environmentally-friendly plastic of the present invention, has higher thermostability and resistance to impact, and has the preventing from being eaten by ant and mouse performance of excellence.

Description

Rat-and-ant proof PA/PC environmentally-friendly plastic

Technical field

The present invention relates to a kind of plastic material, particularly relate to a kind of rat-and-ant proof PA/PC environmentally-friendly plastic.

Background technology

Mouse extensively lives in each area in the world as the rodent that a kind of reproductive capacity and vitality are very strong, owing to its front tooth is very flourishing and can constantly grow, so muroid has object of nibbling to be kept the habit that its tooth is sharp, the distinctive abnormal smells from the patient of plastics makes plastics become muroid often to bite object.

Coptotermes formosanus Shtrari. is luxuriant also known as worm, is in the streets commonly called as flood ant (because generally occurring before raining, hence obtain one's name), the general name of isoptera insect, about kind more than 2000. For incomplete metamorphosis manometavola and be social insect, Coptotermes formosanus Shtrari. in each termitarium is individual up to more than million. Termite damage building construction, reservoir dam, mountain forest orchard, vehicle ship etc., cause very big loss to national economy. The distinctive abnormal smells from the patient of plastics makes plastics become Coptotermes formosanus Shtrari. often to bite object.

Existing plastic material, in order to realize rat-and-ant proof, adds the poisoning agent such as Niran, drinox generally in the plastic, there is very big environmental pollution, and health is very harmful, and pole is not environmentally.

Summary of the invention

For above shortcomings in prior art, the technical problem to be solved is to provide a kind of rat-and-ant proof PA/PC environmentally-friendly plastic.

The technical problem to be solved is achieved by the following technical solution:

A kind of rat-and-ant proof PA/PC environmentally-friendly plastic, is made up of by weight following component: 15 parts of PA, 75 parts of PC, 5-7 part Compatibilizer PP-g-MAHs, 3-5 part biology rat-and-ant proof agent.

Described biological rat-and-ant proof agent, is made up of by weight following component: 10-15 part 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, 10-15 part Tripterygium wilfordii lactone ketone, 10-15 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.

11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, Tripterygium wilfordii lactone ketone, N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide are uniformly mixed, and can be prepared by biological rat-and-ant proof agent.

Industry universal method can be adopted to be prepared the rat-and-ant proof PA/PC environmentally-friendly plastic of the present invention, for instance: weigh each component by proportioning, after mix homogeneously, melting mixing, extruding pelletization, namely obtain described rat-and-ant proof PA/PC environmentally-friendly plastic.

Concrete, it is possible to for weighing each component by proportioning, in mixer, control rotating speed under room temperature at 300-400 rev/min, mix 2-10 minute, proceed to after taking-up in screw extruder, extruding pelletization at 130-150 DEG C of temperature, namely obtains described rat-and-ant proof PA/PC environmentally-friendly plastic.

PC, Merlon, water white transparency, heat-resisting, shock resistance, fire-retardant BI level, in commonly used temperature, there is good mechanical performance. Comparing close to polymethyl methacrylate with performance, the impact resistance of Merlon is good, and refractive index is high, good processability, it is not necessary to additive just has UL94V-0 level fire resistance.

The rat-and-ant proof PA/PC environmentally-friendly plastic of the present invention, has higher thermostability and resistance to impact, and has the preventing from being eaten by ant and mouse performance of excellence.

Detailed description of the invention

Embodiment 1

Each raw material is weighed according to embodiment 1-4 data corresponding in table 1. Each component is joined in high-speed mixer, controls rotating speed under room temperature at 320 revs/min, mix 8 minutes, proceed to after taking-up in screw extruder, extruding pelletization at 140 DEG C of temperature, it is thus achieved that rat-and-ant proof PA/PC environmentally-friendly plastic.

Table 1: rat-and-ant proof PA/PC environmental-friendplastic plastic formula list position: kilogram

	Embodiment 1	Embodiment 2	Embodiment 3	Embodiment 4
					PA resin	15	15	15	15
PC resin	75	75	75	75
					Compatibilizer PP-g-MAH	5.2	5.2	5.2	5.2
11,12,13,14-tetra-dehydrogenation matridinde-15-ketone	1.6	2.4	2.4	/
					Tripterygium wilfordii lactone ketone	1.6	2.4	/	2.4
N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide	1.6	/	2.4	2.4

11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, No. CAS: 6882-66-2. Tripterygium wilfordii lactone ketone, No. CAS: 38647-11-9. N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide, No. CAS: 19408-84-5.

The PA66 resin of du pont company trade mark 101L selected by PA resin; The injection grade PC resin of toray company trade mark 1250Y selected by PC resin.

Test case 1

Adopt GB/T2951.38-1986 electric wire Coptotermes formosanus Shtrari. test method, carry out knocking down method test.

Test piece: 50mm × 50mm × 1mm.

Table 2: anti-ant performance test table

	Coptotermes formosanus Shtrari. knockdown time KT50, min
		Embodiment 1	155
Embodiment 2	172
		Embodiment 3	182
Embodiment 4	163

Visible, by 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, Tripterygium wilfordii lactone ketone, the three kinds of biological rat-and-ant proof agent of N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide carry out composite use, Synergistic, Coptotermes formosanus Shtrari. knockdown time substantially reduces, and anti-ant performance is good.

Test case 2

Adopt GB/T2951.38-1986 electric wire Coptotermes formosanus Shtrari. test method, the rat-and-ant proof PA/PC environmentally-friendly plastic of embodiment 1 is carried out Colony test test. Test piece: 80mm × 25mm × 1mm.

Test result: Coptotermes formosanus Shtrari. moth erosion grade is 1 grade.

Test case 3

Test material film-making: sample is made, according to GB/T8815-2002 pilot scale piece preparation method, the test piece that specification is 150mm × 20mm × 3mm.

Testing equipment and experimental animal: weight 250-300 gram of SD male rat PP plastic casing rustless steel square mouse cage, mouse cage specification is high 250mm, long for 600mm, wide for 400mm, at the bottom of mouse cage and four walls be PP plastics, top is rustless steel square, and is furnished with waterer.

Test procedure: choose SD male rat, stochastic sampling puts into mouse cage, 5, every cage; Test piece is stretched in cage from mouse cage top, with thin copper wire tightly colligation on the stainless (steel) wire lid at feeding place, test piece is exposed at the part beyond mouse cage less than 20mm, and a cage hangs three test pieces, test piece is uniformly arranged on mouse cage width, and interval is approximately 80mm. Rat is regular supply drinking-water and food (namely every day changed clear water by waterer, and feeding place has remained food) during testing. Observe the activity of rat and diet situation every day and the test period terminates the situation that rear sample is bitten by rat. Test period is 7 days.

The rat-and-ant proof PA/PC environmentally-friendly plastic of embodiment 1: the area that bites is less than 5%.

Claims (1)

1. a rat-and-ant proof PA/PC environmentally-friendly plastic, it is characterised in that be made up of by weight following component: 15 parts of PA, 75 parts of PC, 5-7 part Compatibilizer PP-g-MAHs, 3-5 part biology rat-and-ant proof agent;

Described biological rat-and-ant proof agent, is made up of by weight following component: 10-15 part 11,12,13,14-tetra-dehydrogenation matridinde-15-ketone, 10-15 part Tripterygium wilfordii lactone ketone, 10-15 part N-(4-hydroxyl-3-methoxybenzy)-8-methyl pelargonamide.