CN102863667B - 一种吸水膨胀丁腈橡胶的制备方法 - Google Patents
一种吸水膨胀丁腈橡胶的制备方法 Download PDFInfo
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- CN102863667B CN102863667B CN201210385898.XA CN201210385898A CN102863667B CN 102863667 B CN102863667 B CN 102863667B CN 201210385898 A CN201210385898 A CN 201210385898A CN 102863667 B CN102863667 B CN 102863667B
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- water
- paracril
- preparation
- swelling
- agent
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 230000008961 swelling Effects 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 229920000459 Nitrile rubber Polymers 0.000 title abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 37
- 229920001971 elastomer Polymers 0.000 claims abstract description 28
- 239000005060 rubber Substances 0.000 claims abstract description 28
- 239000006229 carbon black Substances 0.000 claims abstract description 24
- 238000002156 mixing Methods 0.000 claims abstract description 23
- 238000004073 vulcanization Methods 0.000 claims abstract description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 12
- 239000011159 matrix material Substances 0.000 claims abstract description 10
- 229920013649 Paracril Polymers 0.000 claims description 80
- 235000019241 carbon black Nutrition 0.000 claims description 22
- 230000001737 promoting effect Effects 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical group C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 12
- 239000007864 aqueous solution Substances 0.000 claims description 10
- 238000007670 refining Methods 0.000 claims description 10
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 8
- 239000012752 auxiliary agent Substances 0.000 claims description 8
- 239000000243 solution Substances 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- 230000003078 antioxidant effect Effects 0.000 claims description 6
- 230000006835 compression Effects 0.000 claims description 6
- 238000007906 compression Methods 0.000 claims description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 5
- 235000021355 Stearic acid Nutrition 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- 239000005457 ice water Substances 0.000 claims description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 5
- 239000008117 stearic acid Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- YXIWHUQXZSMYRE-UHFFFAOYSA-N 1,3-benzothiazole-2-thiol Chemical compound C1=CC=C2SC(S)=NC2=C1 YXIWHUQXZSMYRE-UHFFFAOYSA-N 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- 239000008118 PEG 6000 Substances 0.000 claims description 4
- 229920002584 Polyethylene Glycol 6000 Polymers 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- 229920002594 Polyethylene Glycol 8000 Polymers 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 2
- 239000005864 Sulphur Substances 0.000 claims description 2
- 239000006231 channel black Substances 0.000 claims description 2
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- 239000003345 natural gas Substances 0.000 claims description 2
- 150000002825 nitriles Chemical class 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 4
- 238000003801 milling Methods 0.000 abstract 4
- 239000013543 active substance Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 6
- 238000009736 wetting Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 238000007789 sealing Methods 0.000 description 5
- 230000002745 absorbent Effects 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 4
- 125000003368 amide group Chemical group 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 230000007062 hydrolysis Effects 0.000 description 4
- 238000006460 hydrolysis reaction Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 3
- 125000002560 nitrile group Chemical group 0.000 description 3
- 239000003566 sealing material Substances 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 238000005987 sulfurization reaction Methods 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000002464 physical blending Methods 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- STSDHUBQQWBRBH-UHFFFAOYSA-N n-cyclohexyl-1,3-benzothiazole-2-sulfonamide Chemical compound N=1C2=CC=CC=C2SC=1S(=O)(=O)NC1CCCCC1 STSDHUBQQWBRBH-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- -1 pottery Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Sealing Material Composition (AREA)
Abstract
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Families Citing this family (8)
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CN105199168A (zh) * | 2015-10-29 | 2015-12-30 | 中国石油集团川庆钻探工程有限公司 | 耐高温遇水膨胀橡胶及其制备方法 |
CN105906886A (zh) * | 2016-06-23 | 2016-08-31 | 安徽荣达阀门有限公司 | 一种低溶失率遇水膨胀防水橡胶密封材料及其制备方法 |
CN105906874A (zh) * | 2016-06-23 | 2016-08-31 | 安徽荣达阀门有限公司 | 一种高性能的遇水膨胀防水橡胶密封材料及其制备方法 |
CN108707263B (zh) * | 2018-04-25 | 2020-10-23 | 武汉工程大学 | 一种亲水性纤维改性吸水膨胀水解丁腈橡胶的制备方法 |
CN108841054B (zh) * | 2018-04-25 | 2020-10-23 | 武汉工程大学 | 一种纤维改性吸水膨胀水解丁腈橡胶的制备方法 |
CN109666199A (zh) * | 2018-11-23 | 2019-04-23 | 陶伟珍 | 一种高强吸水橡胶及其制备方法 |
CN109970403A (zh) * | 2019-04-30 | 2019-07-05 | 陈蓉蓉 | 一种高抗水化矿用自膨胀封孔浆料的制备方法 |
CN116924747B (zh) * | 2023-09-15 | 2024-01-26 | 灌云县国家海域使用动态监管中心 | 一种适用于自然水体水处理的发泡颗粒、制备方法及应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5969051A (en) * | 1997-08-11 | 1999-10-19 | The Goodyear Tire & Rubber Company | Hydrophilic nitrile rubber |
CN101153102A (zh) * | 2006-09-30 | 2008-04-02 | 易会安 | 吸水膨胀组合物、吸水膨胀材料和吸水膨胀封隔器 |
CN101983980A (zh) * | 2010-10-29 | 2011-03-09 | 沈阳化工大学 | 一种提高吸水膨胀橡胶性能的方法 |
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- 2012-10-12 CN CN201210385898.XA patent/CN102863667B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5969051A (en) * | 1997-08-11 | 1999-10-19 | The Goodyear Tire & Rubber Company | Hydrophilic nitrile rubber |
CN101153102A (zh) * | 2006-09-30 | 2008-04-02 | 易会安 | 吸水膨胀组合物、吸水膨胀材料和吸水膨胀封隔器 |
CN101983980A (zh) * | 2010-10-29 | 2011-03-09 | 沈阳化工大学 | 一种提高吸水膨胀橡胶性能的方法 |
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Application publication date: 20130109 Assignee: Zhongnan Rubber Group Co., Ltd. Assignor: Wuhan Institute of Technology Contract record no.: 2014420000191 Denomination of invention: Preparation method for water swelling nitrile butadiene rubber Granted publication date: 20140430 License type: Exclusive License Record date: 20141218 |
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Effective date of registration: 20160902 Address after: 430079 999 hi tech Avenue, East Lake New Technology Development Zone, Wuhan, Hubei Patentee after: Wuhan Hua Yuan Science and Technology Ltd. Address before: 430074 Wuhan, Hongshan Province District, hung Chu street, No. 693 Patentee before: Wuhan Institute of Technology |