CN102646740A - 胶带及由其制成的太阳能组件和制品 - Google Patents
胶带及由其制成的太阳能组件和制品 Download PDFInfo
- Publication number
- CN102646740A CN102646740A CN2011100426710A CN201110042671A CN102646740A CN 102646740 A CN102646740 A CN 102646740A CN 2011100426710 A CN2011100426710 A CN 2011100426710A CN 201110042671 A CN201110042671 A CN 201110042671A CN 102646740 A CN102646740 A CN 102646740A
- Authority
- CN
- China
- Prior art keywords
- glue
- line
- luminous energy
- layer
- adhesive tape
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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Images
Classifications
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Abstract
提供了一种无边框光能组件,其包括光能转换器,所述光能转换器的边缘被胶带密封,所述胶带包括:起粘结及减震作用的粘结层和耐老化的保护层,粘结层用于与所述物品边缘接触,其中所述粘结层包括:基材层;和相对地位于基材层两侧的任选的第一胶层和第二胶层,其中第一胶层与所述物品接触;所述保护层位于粘结层上,所述保护层包括:任选的底涂层,其位于所述粘结层上;和膜层,其位于底涂层或第二胶层或基材层上。还提供了一种胶带和由该组件制成的制品。
Description
技术领域
本发明涉及太阳能组件制造领域,尤其涉及一种太阳能组件边缘密封保护胶带及由其制成的太阳能组件和制品。
背景技术
现有的太阳能层压组件主要由以硅胶或双面泡绵胶带固定密封的铝型材边框进行安装和保护。现有太阳能组件是由多层结构层压而成,且绝大多数用铝合金边框和硅胶或双面泡绵胶带对组件的边缘进行密封和保护以保证在变化的气候下,比如雨雪天气的情况下不受影响而维持正常工作。但是在太阳能组件的使用中,现有的组件并不是都需要铝合金边框的,如在光电幕墙,屋顶光电,光电路灯等应用中。在一些应用中,铝合金边框增加了太阳能组件的重量和成本,而且安装操作比较复杂。
因此,需要提供一种能够代替边框对太阳能组件的边缘进行密封的产品,例如胶带。
发明内容
为解决该问题,本发明的发明人设计了一种胶带,其能够代替边框对太阳能组件的边缘进行密封,大大减轻了太阳能组件的重量,无需固化减少了出货时间,使用工具或设备粘贴胶带操作方便,并且降低了制造成本。
根据本发明的第一个方面,提供了一种无边框光能组件,其包括光能转换器,所述光能转换器的边缘被胶带密封,所述胶带包括一种用于密封物品边缘的胶带,其包括:
起粘结及减震作用的粘结层,其用于与所述物品边缘接触,其中所述粘结层包括:
基材层;
任选的,相对地位于基材层两侧的第一胶层和第二胶层,其中第一胶层与所述物品接触;和
耐老化的保护层,其位于所述粘结层上,所述保护层包括:
任选的底涂层,其位于所述粘结层上;和
膜层,其位于:
所述底涂层上,如果有底涂层的话;或
所述基材层上,前提是不存在底涂层、第一胶层和第二胶层;或
所述第二胶层上,前提是有第二胶层并且没有底涂层。
根据本发明的第二个方面,提供了一种太阳能制品,其具有如上述第一个方面的太阳能组件。
根据本发明的第三个方面,提供了一种用于密封物品边缘的胶带,其包括:
起粘结及减震作用的粘结层,其用于与所述物品边缘接触,其中所述粘结层包括:
基材层;
任选的,相对地位于基材层两侧的第一胶层和第二胶层,其中第一胶层与所述物品接触;和
耐老化的保护层,其位于所述粘结层上,所述保护层包括:
任选的底涂层,其位于所述粘结层上;和
膜层,其位于:
所述底涂层上,如果有底涂层的话;或
所述基材层上,前提是不存在底涂层、第一胶层和第二胶层;或
所述第二胶层上,前提是有第二胶层并且没有底涂层。
使用本发明胶带能够大大减轻太阳能组件的重量,密封时无需固化,从而减少了出货时间,可以非常方便地使用工具或设备粘贴胶带,并且降低了制造成本。根据需要,本发明的胶带的保护层材料可以具有各种功能,例如耐磨损性、耐候性、耐污性或装饰性等。另外,根据需要,本发明的胶带也可提供良好的抗震缓冲性能。
附图说明
图1是根据本发明实施例1的胶带的截面结构示意图;
图2是根据本发明实施例2的胶带的截面结构示意图;
图3是根据本发明实施例3的胶带的截面结构示意图;
图4是根据本发明实施例4的胶带的截面结构示意图;
图5是根据本发明实施例5的胶带的截面结构示意图;
图6是根据本发明实施例6的胶带的截面结构示意图;
图7是根据本发明实施例7的胶带的截面结构示意图;
图8是根据本发明实施例8的胶带的截面结构示意图;
图9是根据本发明实施例9的胶带的截面结构示意图;
图10是根据本发明实施例10的胶带的截面结构示意图;
图11是根据本发明实施例11的胶带的截面结构示意图;
图12是根据本发明实施例12的胶带的截面结构示意图;
图13是根据本发明实施例13的胶带的截面结构示意图;
图14是根据本发明实施例14的胶带的截面结构示意图;
图15是根据本发明实施例15的胶带的截面结构示意图;
图16是根据本发明实施例16的胶带的截面结构示意图;
图17是根据本发明实施例17的胶带的截面结构示意图;
图18是根据本发明实施例18的胶带的截面结构示意图;
图19是根据本发明实施例19的胶带的截面结构示意图;
图20是根据本发明实施例20的胶带的截面结构示意图;
图21是根据本发明实施例21的胶带的截面结构示意图;
图22是根据本发明实施例22的胶带的截面结构示意图;和
图23是根据本发明实施例23的胶带的截面结构示意图。
图24是根据本发明实施例24的胶带的截面结构示意图。
图中的参考标记分别表示:
1:基材层;
2:第一胶层;
3:第二胶层;
4:膜层;
5:底涂层;
6:离型膜;
7:顶层;
8:中间层;
9:第三胶层
具体实施方式
除非特别指明,本发明中,下述术语具有如下的定义:
术语“光热或光伏组件”(本文中统称为“光能组件”)是指可利用光能如太阳能发电或发热的面板型组件,包括但不限于晶硅太阳能组件,非晶硅薄膜太阳能组件,CIGS[CuInxGa(1-x)Se2,即薄膜太阳能铜铟镓硒]等其他薄膜太阳能组件,和平板式太阳能集热器。
术语“太阳能制品”是指含有上述太阳能组件的产品,包括但不限于太阳能交通工具、太阳能热水器、太阳能路灯、太阳能幕墙等。
术语“无纺布”是指由定向的或无规的高分子纤维构成的材料。
术语“亚克力胶”是指丙烯酸酯类的压敏胶。
术语“热熔胶”是指如聚烯烃嵌段共聚物(SBS,SIS),乙烯-醋酸乙烯共聚物(EVA)等在室温下是固态,可在加热熔融成液态,并涂布在被粘物上后,经压合冷却在几秒钟内完成粘接的胶粘剂。
术语“结构胶”是指如环氧树脂,聚氨酯等强度高,能承受较大荷载,且耐老化、耐疲劳、耐腐蚀,在预期寿命内性能稳定,适用于承受强力的结构件粘接的胶粘剂。
术语“泡绵”和“发泡材料”在本发明中具有相同含义,是指如聚乙烯,聚氨酯,丙烯酸等经发泡后具有压缩性的材料。
术语“泡绵胶”是指以上述“泡绵”或“发泡材料”作为基材,对于“泡绵”或“发泡材料”的一面或两面赋予具有粘合性能的粘合剂层,形成具有压缩性和特定粘合功能的复合粘接材料。
术语”物品”是指利用所发明的胶带来密封的物品,如光能转换器、太阳能组件。
本发明的第一个方面提供了一种无边框光能组件,其包括光能转换器,所述光能转换器的边缘被胶带密封,所述胶带包括:
起粘结及减震作用的粘结层,其用于与所述物品边缘接触,其中所述粘结层包括:
基材层;和
任选的,相对地位于基材层两侧的第一胶层和第二胶层,其中第一胶层与所述物品接触;和
耐老化的保护层,其位于所述粘结层上,所述保护层包括:
任选的底涂层,其位于所述粘结层上;和
膜层,其位于:
所述底涂层上,如果有底涂层的话;或
所述基材层上,前提是不存在底涂层、第一胶层和第二胶层;或
所述第二胶层上,前提是有第二胶层并且没有底涂层。
本发明的光能组件可以为光伏或光热组件,包括但不限于光伏板、薄膜光伏板、光热板等。
根据本发明的第二个方面,提供了一种太阳能制品,其具有如上述第一个方面的太阳能组件。其包括但不限于太阳能交通工具、太阳能热水器、太阳能路灯、或太阳能幕墙等制品。
根据本发明的第三个方面,提供了一种用于密封物品边缘的胶带,其包括:
起粘结及减震作用的粘结层,其用于与所述物品边缘接触,其中所述粘结层包括:
基材层;
任选的,相对地位于基材层两侧的第一胶层和第二胶层,其中第一胶层与所述物品接触;和
耐老化的保护层,其位于所述粘结层上,所述保护层包括:
任选的底涂层,其位于所述粘结层上;和
膜层,其位于:
所述底涂层上,如果有底涂层的话;或
所述基材层上,前提是不存在底涂层、第一胶层和第二胶层;或
所述第二胶层上,前提是有第二胶层并且没有底涂层。
粘结层优选由具有良好粘接性能以及密封性能的粘结层胶粘剂制成。
根据某些优选的实施方案,用于本发明的胶带还包含位于所述保护层和粘结层之间的防水中间层。防水中间层和保护层之间可以使用粘合剂。可以采用上面列举的那些粘合剂。
根据某些优选的实施方案,用于本发明的胶带中所述粘结层包括:
基材层;
相对地位于基材层两侧的第一胶层和第二胶层,其中第一胶层与所述物品接触;
防水中间层,其位于所述第二胶层和所述保护层之间;
其中所述保护层包括:
底涂层,其位于所述粘结层上;和
膜层,其位于所述底涂层上。
本发明光能组件中的胶带的保护层具有耐老化性能,满足户外老化测试条件和加速老化测试条件,优选满足如下条件:
根据IEC60721-2-1规定的户外暴露条件,总辐射量为60kWh/m2;
根据IEC61215规定的:-40℃-+85℃高低温循环,200次;-40℃-+85℃/85%RH潮湿冷冻循环,10次;+85℃/85%RH高温高湿老化1000小时等等。
经过上述典型老化条件,保护层无破损,开裂,撕裂等外观缺陷,由此提供太阳能组件外观完整稳定,并且保持组件原有功能特性。
耐老化及外观保护层采用耐老化且柔韧性较好的膜或金属箔材料制成,优选具有良好水汽阻隔及耐候性能。例如,根据某些优选的实施方案,保护层中的膜层优选由选自未稳定化的PTFE,PVDF,PVF,ETFE,ECTFE,THV,和硅橡胶的材料制成。其它具有紫外和降解保护包的膜层包括:PVDF/PMMA共混物,嵌段(例如Kuraray Kurarity聚合物)或无规PMMA/丙烯酸酯共聚物,PMMA,抗冲击PMMA,聚乙烯-甲基丙烯酸离聚物(例如Dupont Surlyn),聚乙烯-丙烯酸离聚物(例如Dupont Nucrel),交联聚异丁烯,脂肪族聚氨酯,氢化苯乙烯类嵌段共聚物,热塑性硫化橡胶(如ExxonMobil Santoprene),交联乙烯丙烯三元共聚物,增塑或未增塑的聚氯乙烯,热塑性聚氨酯橡胶,聚酰亚胺、聚乙烯、聚丙烯、离聚物、或其混合物的材料制成。根据另外一些实施方案,膜层也可由金属箔如铝箔、铜箔制成。其中更优选聚氯乙烯、聚丙烯膜层,它们通过配方添加剂的使用,能够提供所需功能,如抗紫外性能,阻燃性能,抗冲击性能。膜层还可含有顶层,其能够提供所需功能,例如耐磨损性、耐候性、防水性、耐污性或装饰性等。顶层是一种表面硬化处理层,可通过将聚合物涂敷至基膜表面获得。涂布的实例可包括喷涂、辊涂、凹版涂布、和接触式凹版反向涂布(direct reverse gravure coating),任选配以紫外线光固化技术例如UV或电子束。根据某些进一步优选的实施方案,所述顶层选自耐磨损性涂层、耐候性涂层、防水性涂层、耐污性涂层或装饰性涂层。组成所述膜层的材料的耐老化性典型的能够通过IEC 61215老化测试或者在外部使用超过25年。所述保护层优选具有根据IEC60721-2-1规定的户外暴露条件,总辐射量为60kWh/m2,并符合IEC61215规定的耐候性能:-40℃-+85℃高低温循环,200次;-40℃-+85℃/85%RH潮湿冷冻循环,10次;+85℃/85%RH高温高湿老化1000小时等。
根据某些优选的实施方案,本发明的胶带中所述底涂层由选自硅烷偶联剂、聚烯烃、聚乙烯基、聚酰胺、异氰酸酯、卤化橡胶或金属薄膜的材料制成。根据某些更优选的实施方案,本发明的胶带中所述底涂层还含有第三胶层。根据某些进一步优选的实施方案,所述第三胶层由选自亚克力胶、热熔胶、结构胶、硅基胶或其组合的胶粘剂制成。第三胶层用于粘接膜层与基材层或者中间层。底涂层的作用可以为增强膜层与第三胶层的层间结合力。更优选地,底涂层一般由带有官能团(如羧基、酰胺基、羟基、叔胺基、酯基伯胺基、伯胺基)的高分子聚合物的混合溶液涂敷而成。根据某些更优选的实施方案,底涂层涂敷厚度小于0.05毫米。所述底涂层可由底涂剂例如POLYMENT NK-350(购自Nippon Shokubai Kogyo Co.,Ltd.的氨甲基改性的树脂)涂敷而成,所述膜层可由黑色PVC,例如NAN YA0.10mm黑色PVC制成。
本发明胶带中的粘结层能够提供良好的粘接性能以及密封性能。粘结层从太阳能组件表面(玻璃,THV背板材料,PVDF背板材料,PVF背板材料等)的90度剥离强度可高于1N/cm,能够有效地保持太阳能组件的功能特性。太阳能组件的一个或两个表面可以涂布合适的底涂剂以促进粘结。典型地,粘结层能够通过IEC61215-10-15规定的湿漏电测试。根据某些优选的实施方案,本发明的胶带中所述第一胶层由选自亚克力胶、热熔胶、结构胶或其组合的胶粘剂制成。根据某些优选的实施方案,本发明的胶带中所述第二胶层由选自亚克力胶、硅基胶、橡胶胶粘剂、热熔胶、结构胶或其组合的胶粘剂制成。根据这些方案,粘结层性能应当同时满足以下户外老化测试条件和加速老化测试条件,具体如:根据IEC60721-2-1规定的户外暴露条件,总辐射量为60kWh/m2。根据IEC61215规定的:-40℃-+85℃高低温循环,200次;-40℃-+85℃/85%RH潮湿冷冻循环,10次;+85℃/85%RH高温高湿老化1000小时等等。
经过上述典型老化条件,粘结层从太阳能组件表面(玻璃,THV背板材料,PVDF背板材料,PVF背板材料等)的90度剥离强度可大于1N/cm,由此提供太阳能组件完整稳定的密封效果,同时保持太阳能组件老化后的功能特性。典型的例如通过IEC61215-10-15规定的湿漏电测试。
根据某些优选方案,粘结层的第二胶层由选自亚克力胶、橡胶胶粘剂或其组合的胶粘剂制成。第二胶层与由底涂层形成的层之间的剥离力大于1N/cm。
所述粘结层与待密封物品的粘结强度,以90度剥离强度计,优选大于1N/cm。所述粘结层的基材层优选为亚克力泡绵,胶层优选由亚克力胶制成。例如,可以采用3M 4941VHB作为粘结层。
根据某些更优选的实施方案,本发明的胶带中所述基材层由选自发泡材料、丙烯酸树脂、聚氨酯、聚乙烯橡胶、无纺材料或其混合物的材料组成。例如,可采用具有一定减震作用的材料如具有粘弹性和压缩性的胶、泡绵、橡胶、无纺布等作为基材层。也可以采用具有高粘结性能的材料作为基材层,例如可以采用3M 2081丙烯酸泡绵胶带。
为了加强胶带的防水性能,产品中也可加入中间层。例如加入水气透过率在60g/m2/24hr(37.8℃)以下的材料层如金属层、丁基橡胶层、表面改性的PET(聚对苯二甲酸乙二醇酯)层、聚异丁烯层、和聚丙烯层等用作水气阻隔层。根据某些优选的实施方案,所述中间层由选自金属、橡胶和聚氨酯的材料制成。根据某些更优选的实施方案,所述金属选自铝、铜或其组合。根据某些更优选的实施方案,所述橡胶选自三元乙丙橡胶、含氟弹性体、聚异丁烯或其混合物。根据优选实施方案,防水中间层可通过IEC61215规定的浸水湿漏电测试:-40℃-+85℃/85%RH潮湿冷冻循环,10次;+85℃/85%RH高温高湿老化1000小时。所述防水中间层可由金属箔例如铝箔制成,其厚度优选为10-100μm。例如由美铝公司8011铝箔制成,其厚度为47μm。
各个材料层的厚度没有特别限制,可以根据具体产品的不同需求进行调整以同时实现上述材料层的功能。例如,厚度一般为0.01~100mm。
根据某些特别优选的实施方案,本发明的组件中采用的胶带与被密封物品的90度剥离强度大于1N/cm,具有如下耐候性能:根据IEC60721-2-1规定的户外暴露条件,总辐射量为60kWh/m2以及根据IEC61215规定的:-40℃-+85℃高低温循环,200次;-40℃-+85℃/85%RH潮湿冷冻循环,10次;+85℃/85%RH高温高湿老化1000小时。老化前后其防水性能均通过IEC61215规定的浸水湿漏电测试。其中,所述基材层优选由亚克力泡绵制成,厚度为0.2~2.0mm,所述第一和第二胶层由亚克力胶粘剂组成,厚度为10~100μm,所述防水中间层由美铝公司8011铝箔制成,厚度为47μm,所述底涂层由“POLYMENT 3M NK-350”底涂剂组成,厚度为0.005~0.05mm,所述膜层由Nan Ya黑色PVC制成,厚度为0.10~2mm。
本发明的胶带可以应用于光伏建筑一体化(BIPV)以及屋顶光伏,光伏路灯等不需要铝边框来固定的光伏组件中。例如,本发明的胶带可贴于太阳能组件四个边缘,形成一个包边的结构。粘结层泡绵胶粘剂具有一定的缓冲性能,保护层材料有较好的耐磨损性能,并且可有效地阻止水汽渗透。本发明胶带的应用大大减轻了太阳能组件的重量,无需固化从而缩短了出货时间,粘贴胶带时操作方便,并且降低了制造成本。
实例1
实例1的胶带的结构如图1所示。膜层4和离型膜6分别位于基材层1的两侧。各层的材质分别为:
膜层4:Huasu 0.06mm黑色PVC(聚氯乙烯)膜
基材层1:美国3M公司2081丙烯酸泡绵胶
离型膜6:日本三菱化学株式会社0.075mm PE离型膜
该胶带的制备过程如下:
3M 2081丙烯酸泡绵胶通过无溶剂涂布工艺涂布于三菱化学株式会社0.075mm PE(聚乙烯)离型膜上形成基材层。完成涂布后,基材层与Huasu0.06mm黑色PVC膜内表面贴合,即得到成品胶带。
实例2
实例2的胶带的结构如图2所示。基材层1的两面分别设置底涂层5和离型膜6,底涂层5的上面设置了膜层4。各层的材质分别为:
膜层4:Huasu 0.10mm黑色PVC膜
底涂层5:POLYMENT NK-350
基材层1:3M 2081丙烯酸泡绵胶
离型膜6:三菱化学株式会社0.075mm PP(聚丙烯)离型膜
该胶带的制备过程如下:
3M 2081丙烯酸泡绵胶通过无溶剂涂布工艺涂布于三菱化学株式会社0.075mm PE离型膜上形成基材层。在Huasu 0.10mm黑色PVC膜的粘结层上进行底涂层的涂布。完成涂布后,基材层与位于Huasu 0.10mm黑色PVC膜上的底涂层贴合,完成产品。
实例3
实例3的胶带的结构如图3所示。基材层1的两面分别设置膜层4和离型膜6,膜层4的上面设置了顶层7。各层的材质分别为:
顶层7:MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”
膜层4:Huasu 0.10mm黑色PVC膜
基材层1:3M 2081丙烯酸泡绵胶
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
3M 2081丙烯酸泡绵胶通过无溶剂涂布工艺涂布于通利0.150mm PE离型膜上形成基材层。在Huasu 0.10mm黑色PVC膜的的外表面层进行底表面硬化层MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”的涂布。完成涂布后,基材层与Huasu 0.10mm黑色PVC膜的内表面贴合,完成产品。
实例4
实例4的胶带的结构如图4所示。各层的材质分别为:
顶层7:MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”
膜层4:Huasu 0.10mm黑色PVC膜
底涂层5:3M“ADHESION PROMOTER N-200”底涂剂
基材层1:美国3M公司的3M“SOLAR ACRYLIC FOAM TAPE FB80”丙烯酸泡绵胶
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
美国3M公司的3M FB80丙烯酸泡绵胶通过无溶剂涂布工艺涂布于通利0.150mm PE离型膜形成基材层,在Huasu 0.10mm黑色PVC膜的外表面层涂布MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”的固化层。然后在Huasu 0.10mm黑色PVC膜的内表面涂布3M“ADHESION PROMOTER N-200”底涂剂。完成涂布后,基材层与Huasu0.10mm黑色PVC膜贴合,完成产品。
实例5
实例5的胶带的结构如图5所示。各层的材质分别为:
膜层4:Renolit 0.10mm黑色PVC膜
第三胶层9:3M CSA3050丙烯酸胶
中间层8:镁铝8011铝箔
基材层1:3M 2081丙烯酸泡绵胶
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
3M 2081丙烯酸泡绵胶通过无溶剂涂布工艺涂布于通利0.150mm PE离型膜上形成基材层,另一面贴合美铝8011铝箔,完成后作为半成品I;在Huasu 0.10mm黑色PVC膜的内表面层涂布3M CSA3050胶,作为半成品II;将半成品I与半成品II的贴合,完成产品。
实例6
实例6的胶带的结构如图6所示。各层的材质分别为:
膜层4:Renolit 0.10mm黑色PVC膜
第三胶层9:3M CSA3050丙烯酸胶
中间层8:仪化东丽0.05mm透明PET膜
基材层1:3M 2081丙烯酸泡绵胶
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
3M 2081丙烯酸泡绵胶通过无溶剂涂布工艺涂布于通利0.150mm PE离型膜上形成基材层,另一面贴合仪化东丽0.05mm透明PET膜,完成后作为半成品I;在Huasu 0.10mm黑色PVC膜的内表面层涂布3MCSA3050胶,作为半成品II;将半成品I与半成品II贴合,完成产品。
实例7
实例7的胶带的结构如图7所示。各层的材质分别为:
顶层7:MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”
膜层4:NAN YA 0.10mm黑色PVC膜
第三胶层9:3M CSA3050丙烯酸胶
中间层8:镁铝8011铝箔
基材层1:3M 2081丙烯酸泡绵胶
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
3M 2081丙烯酸泡绵胶通过无溶剂涂布工艺涂布于通利0.150mm PE离型膜,另一面贴合镁铝8011铝箔,完成后作为半成品I;在NAN YA0.10mm黑色PVC膜的外表面涂布MOMENTIVE PERFORMANCEMATERIALS“UVHC8558”硬化涂层,内表面层涂布3M CSA3050胶,作为半成品II;将半成品I与半成品II贴合,完成产品。
实例8
实例8的胶带的结构如图8所示。各层的材质分别为:
顶层7:MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”
膜层4:NAN YA 0.10mm黑色PVC膜
第三胶层9:3M CSA3050丙烯酸胶
中间层8:仪化东丽0.05mm透明PET膜
基材层1:3M 2081丙烯酸泡绵胶
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
3M 2081丙烯酸泡绵胶通过无溶剂涂布工艺涂布于通利0.150mm PE离型膜上形成基材层,另一面贴合仪化东丽0.05mm透明PET膜,完成后作为半成品I;在NAN YA 0.10mm黑色PVC膜的外表面涂布MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”硬化涂层,内表面层涂布3M CSA3050胶,作为半成品II;将半成品I与半成品II贴合,完成产品。
实例9
实例9的胶带的结构如图9所示。各层的材质分别为:
膜层4:NAN YA 0.10mm黑色PVC膜
底涂层5:3M“ADHENSION PROMOTER N-200”底涂剂
第三胶层9:3M CSA3050丙烯酸胶
中间层8:美铝8011铝箔
基材层1:3M 2081丙烯酸泡绵胶
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
3M 2081丙烯酸泡绵胶通过无溶剂涂布工艺涂布于通利0.150mm PE离型膜上形成基材层,另一面贴合美铝8011铝箔,完成后作为半成品I;在NAN YA 0.10mm黑色PVC膜的内表面层先涂布3M“ADHENSIONPROMOTER N-200”底涂剂,再涂布3M CSA3050胶,作为半成品II;将半成品I与与半成品II贴合,完成产品。
实例10
实例10的胶带的结构如图10所示。各层的材质分别为:
膜层4:NAN YA 0.10mm黑色PVC膜
底涂层5:3M“ADHENSION PROMOTER N-200”底涂剂
第三胶层9:3M CSA3050丙烯酸胶
中间层8:仪化东丽0.05mm透明PET膜
基材层1:3M 2081丙烯酸泡绵胶
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
3M 2081丙烯酸泡绵胶通过无溶剂涂布工艺涂布于通利0.150mm PE离型膜形成基材层,另一面贴合仪化东丽0.05mm透明PET膜,完成后作为半成品I;在NAN YA 0.10mm黑色PVC膜的内表面层涂布先涂布3M“ADHENSION PROMOTER N-200”底涂剂,再涂布3M CSA3050胶,作为半成品II;将半成品I与半成品II贴合,完成产品。
实例11
实例11的胶带的结构如图11所示。各层的材质分别为:
顶层7:MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”
膜层4:NAN YA 0.10mm黑色PVC膜
底涂层5:3M“ADHENSION PROMOTER N-200”底涂剂
第三胶层9:3M CSA3050丙烯酸胶
中间层8:镁铝8011铝箔
基材层1:3M 2081丙烯酸泡绵胶
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
3M 2081丙烯酸泡绵胶通过无溶剂涂布工艺涂布于通利0.150mm PE离型膜上形成基材层,另一面贴合以镁铝8011铝箔,完成后作为半成品I;在NAN YA 0.10mm黑色PVC膜的外表面涂布MOMENTIVEPERFORMANCE MATERIALS“UVHC8558”硬化涂层,内表面层先涂布3M“ADHENSION PROMOTER N-200”底涂剂,再涂布3M CSA3050胶,作为半成品II;将半成品I与半成品II贴合,完成产品。
实例12
实例12的胶带的结构如图12所示。各层的材质分别为:
顶层7:MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”
膜层4:NAN YA 0.10mm黑色PVC膜
底涂层5:3M“ADHENSION PROMOTER N-200”底涂剂
第三胶层9:3M CSA3050丙烯酸胶
中间层8:仪化东丽0.05mm透明PET膜
基材层1:3M 2081丙烯酸泡绵胶
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
3M 2081丙烯酸泡绵胶通过无溶剂涂布工艺涂布于通利0.150mm PE离型膜上形成基材层,另一面贴合仪化东丽0.05mm透明PET膜,完成后作为半成品I;在NAN YA 0.10mm黑色PVC膜的外表面涂布MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”硬化涂层,内表面层先涂布3M“ADHENSION PROMOTER N-200”底涂剂,再涂布3MCSA3050胶,作为半成品II;将半成品I与半成品II贴合,完成产品。
实例13
实例13的胶带的结构如图13所示。各层的材质分别为:
膜层4:NAN YA 0.10mm黑色PVC膜
第一胶层2+基材层1+第二胶层3:3M 4941 VHB胶带
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
将3M 4941 VHB胶带的第一胶层贴合到通利0.150mm PE离型膜,第二胶层与NAN YA 0.10mm黑色PVC膜贴合,完成产品。
实例14
实例14的胶带的结构如图14所示。各层的材质分别为:
膜层4:NAN YA 0.10mm黑色PVC膜
底涂层5:3M“ADHENSION PROMOTER N-200”底涂剂
第一胶层2+基材层1+第二胶层3:3M 4941 VHB胶带
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
将3M 4941 VHB胶带的第一胶层贴合到通利0.150mm PE离型膜,在NAN YA 0.10mm黑色PVC膜的内表面层先涂布3M“ADHENSIONPROMOTER N-200”底涂剂,然后与4941 VHB的第二胶层贴合,完成产品。
实例15
实例15的胶带的结构如图15所示。各层的材质分别为:
顶层7:MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”
膜层4:Renolit 0.10mm黑色PVC膜
底涂层5:3M“ADHENSION PROMOTER N-200”底涂剂
第一胶层2+基材层1+第二胶层3:3M 4941 VHB胶带
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
将3M 4941 VHB胶带的第一胶层贴合到通利0.150mm PE离型膜,在NAN YA 0.10mm黑色PVC膜的外表面涂布MOMENTIVEPERFORMANCE MATERIALS“UVHC8558”硬化涂层,内表面层先涂布3M“ADHENSION PROMOTER N-200”底涂剂,然后与4941 VHB的第二胶层贴合,完成产品。
实例16
实例16的胶带的结构如图16所示。各层的材质分别为:
膜层4:Renolit 0.10mm黑色PVC膜
第三胶层9:3M CSA3060丙烯酸胶
中间层8:美铝8011铝箔
第一胶层2+基材层1+第二胶层3:3M 4941 VHB胶带
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
将3M 4941 VHB胶带的第一胶层贴合到通利0.150mm PE离型膜,第二胶层贴合到美铝8011铝箔的一个表面,完成后作为半成品I;在NAN YA0.10mm黑色PVC膜的内表面层涂布3M CSA3060胶,作为半成品II;将半成品I位于铝箔的另一个表面与半成品II涂胶的那个表面贴合,完成产品。
实例17
实例17的胶带的结构如图17所示。各层的材质分别为:
膜层4:Renolit 0.10mm黑色PVC膜
第三胶层9:3M CSA3060丙烯酸胶
中间层8:大华0.05mm透明PET膜
第一胶层2+基材层1+第二胶层3:3M 4941 VHB胶带
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
将3M 4941 VHB胶带的第一胶层贴合到通利0.150mm PE离型膜,第二胶层贴合到大华0.05mm透明PET膜的一个表面,完成后作为半成品I;在NAN YA 0.10mm黑色PVC膜的内表面层涂布3M CSA3060胶,作为半成品II;将半成品I位于PET膜上的另一个表面与半成品II涂胶的那个表面贴合,完成产品。
实例18
实例18的胶带的结构如图18所示。各层的材质分别为:
膜层4:Renolit 0.10mm黑色PVC膜
底涂层5:3M“ADHENSION PROMOTER N-200”底涂剂
第三胶层9:3M CSA3060丙烯酸胶
中间层8:美铝公司8011铝箔
第一胶层2+基材层1+第二胶层3:3M 4941 VHB胶带
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
将3M 4941 VHB胶带的第一胶层贴合到通利0.150mm PE离型膜,第二胶层贴合到美铝8011铝箔的一个表面,完成后作为半成品I;在NAN YA0.10mm黑色PVC膜的内表面层先涂布3M“ADHENSION PROMOTERN-200”底涂剂,再涂布3M CSA3060胶,作为半成品II;将半成品I位于铝箔的另一个表面与半成品II涂胶的那个表面贴合,完成产品。
实例19
实例19的胶带的结构如图19所示。各层的材质分别为:
膜层4:Renolit 0.10mm黑色PVC膜
底涂层5:POLYMENT NK-350底涂剂
第三胶层9:3M CSA3060丙烯酸胶
中间层8:大华0.05mm透明PET膜
第一胶层2+基材层1+第二胶层3:3M 4941 VHB胶带
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
将3M 4941 VHB胶带的第一胶层贴合到通利0.150mm PE离型膜,第二胶层贴合到大华0.05mm透明PET膜的一个表面,完成后作为半成品I;在NAN YA 0.10mm黑色PVC膜的内表面层先涂布3M“ADHENSIONPROMOTER N-200”底涂剂,再涂布3M CSA3060胶,作为半成品II;将半成品I位于PET膜的另一个表面与半成品II涂胶的那个表面贴合,完成产品。
实例20
实例20的胶带的结构如图20所示。各层的材质分别为:
顶层7:MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”
膜层4:Renolit 0.10mm黑色PVC膜
第三胶层9:3M CSA3060丙烯酸胶
中间层8:美铝8011铝箔
第一胶层2+基材层1+第二胶层3:3M 4941 VHB胶带
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
将3M 4941 VHB胶带的第一胶层贴合到通利0.150mm PE离型膜,第二胶层贴合到美铝8011铝箔的一个表面,完成后作为半成品I;在NAN YA0.10mm黑色PVC膜的外表面涂布MOMENTIVE PERFORMANCEMATERIALS“UVHC8558”硬化涂层,内表面层涂布3M CSA3060胶,作为半成品II;将半成品I位于铝箔的另一个表面与半成品II涂胶的那个表面贴合,完成产品。
实例21
实例21的胶带的结构如图21所示。各层的材质分别为:
顶层7:MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”
膜层4:NAN YA 0.10mm黑色PVC膜
第三胶层9:3M CSA3060丙烯酸胶
中间层8:大华0.05mm透明PET膜
第一胶层2+基材层1+第二胶层3:3M 4941 VHB胶带
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
将3M 4941 VHB胶带的第一胶层贴合到通利0.150mm PE离型膜,第二胶层贴合到大华0.05mm透明PET膜的一个表面,完成后作为半成品I;在NAN YA 0.10mm黑色PVC膜的外表面涂布MOMENTIVEPERFORMANCE MATERIALS“UVHC8558”硬化涂层,内表面层涂布3MCSA3060胶,作为半成品II;将半成品I位于PET膜的另一个表面与半成品II涂胶的那个表面贴合,完成产品。
实例22
实例22的胶带的结构如图22所示。各层的材质分别为:
顶层7:MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”
膜层4:Renolit 0.10mm黑色PVC膜
底涂层5:POLYMENT NK-350底涂剂
第三胶层9:3M CSA3060丙烯酸胶
中间层8:美铝8011铝箔
第一胶层2+基材层1+第二胶层3:3M 4941 VHB胶带
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
将3M 4941 VHB胶带的第一胶层贴合到通利0.150mm PE离型膜,第二胶层贴合到美铝8011铝箔的一个表面,完成后作为半成品I;在NAN YA0.10mm黑色PVC膜的外表面涂布MOMENTIVE PERFORMANCEMATERIALS“UVHC8558”硬化涂层,内表面层先涂布3M“ADHENSIONPROMOTER N-200”底涂剂,再涂布3M CSA3060胶作为半成品II;将半成品I位于铝箔的另一个表面与半成品II涂胶的那个表面贴合,完成产品。
实例23
实例23的胶带的结构如图23所示。各层的材质分别为:
顶层7:MOMENTIVE PERFORMANCE MATERIALS“UVHC8558”
膜层4:Renolit 0.10mm黑色PVC膜
底涂层5:POLYMENT NK-350底涂剂
第三胶层9:3M CSA3060丙烯酸胶
中间层8:三菱0.05mm PET膜
第一胶层2+基材层1+第二胶层3:3M 4941 VHB胶带
离型膜6:通利0.150mm PE离型膜
该胶带的制备过程如下:
将3M 4941 VHB胶带的第一胶层贴合到通利0.150mm PE离型膜,第二胶层贴合到大华0.05mm透明PET膜的一个表面,完成后作为半成品I;在NAN YA 0.10mm黑色PVC膜的外表面涂布MOMENTIVEPERFORMANCE MATERIALS“UVHC8558”硬化涂层,内表面层先涂布3M“ADHENSION PROMOTER N-200”底涂剂,再涂布3M CSA3060胶作为半成品II;将半成品I位于PET膜的另一个表面与半成品II涂胶的那个表面贴合,完成产品。
实例24
实例24的胶带的结构如图24所示。本实施例中采用了商购32mils(0.8mm)“3M SEMITRANSPARENT MATERIAL RIVET TACKY TAPESEAL 4422B”(3M/住友,日本)。
该胶带由三层组成:
膜层4:6mils(0.15mm)厚,离聚物/亚克力;
基材层1:24mils(0.6mm)厚,贴合性强的多用途亚克力;
离型膜6:2mils(0.05mm)厚聚酯薄膜。
将光能组件的玻璃表面底涂上“3M SILANE GLASS TREATMENTAP115”(美国明尼苏达州St.Paul的3M公司),并且光能组件的聚酯背板表面涂以“3M TAPE PRIMER 94”(美国明尼苏达州St.Paul的3M公司)。
测试:
对保护层和防水中间层的测试:
实施例1-24中保护层的材料均分别通过了IEC61215规定的如下耐候性能测试:在-40℃-+85℃高低温循环至少200次;-40℃-+85℃/85%RH潮湿冷冻循环至少10次;+85℃/85%RH高温高湿老化至少1000小时。
实施例1-24中防水中间层的材料均分别通过了IEC61215规定的如下浸水湿漏电测试:-40℃-+85℃/85%RH潮湿冷冻循环,10次;+85℃/85%RH高温高湿老化1000小时条件下。
对胶带的测试:
耐老化性能的测试按照IEC61215的规定进行。上面的实施例中,按照IEC61215进行如下各项老化测试各1000小时:85%湿度85℃老化;UV辐照15Kwh/m2老化;热循环200次;潮湿冷冻循环10次。结果显示:老化前后,胶带表面没有老化开裂或破损,90度剥离粘接强度不低于1N/mm。
各实施例胶带的测试结果概括于下表:
由表中所列测试数据可见,各实施例的样品都顺利通过了各项测试。
Claims (27)
1.一种无边框光能组件,其包括光能转换器,所述光能转换器的边缘被胶带密封,所述胶带包括:
起粘结及减震作用的粘结层,其用于与物品边缘接触,其中所述粘结层包括:
基材层;
任选的,相对地位于基材层两侧的第一胶层和第二胶层,其中第一胶层与所述物品接触;和
耐老化的保护层,其位于所述粘结层上,所述保护层包括:
任选的底涂层,其位于所述粘结层上;和
膜层,其位于:
所述底涂层上,如果有底涂层的话;或
所述基材层上,前提是不存在底涂层、第一胶层和第二胶层;或
所述第二胶层上,前提是有第二胶层并且没有底涂层。
2.根据权利要求1的无边框光能组件,还包含防水中间层,其位于所述第二胶层和所述保护层之间。
3.根据权利要求1的无边框光能组件,其中所述基材层由选自发泡材料、丙烯酸树脂、聚氨酯、聚乙烯橡胶、无纺材料或其混合物的材料组成。
4.根据权利要求1的无边框光能组件,其中所述第一胶层由选自亚克力胶、热熔胶、结构胶或其组合的胶粘剂制成。
5.根据权利要求1的无边框光能组件,其中所述第二胶层由选自亚克力胶、硅基胶、橡胶胶粘剂、热熔胶、结构胶或其组合的胶粘剂制成。
6.根据权利要求1的无边框光能组件,其中所述中间层由选自金属、橡胶、聚氨酯或其组合的材料制成。
7.根据权利要求6的无边框光能组件,其中所述金属选自铝、铜或其组合。
8.根据权利要求6的无边框光能组件,其中所述橡胶选自三元乙丙橡胶、氟橡胶、聚异丁烯、或其混合物。
9.根据权利要求1的无边框光能组件,其中所述膜层由选自聚氯乙烯、聚丙烯、聚乙烯、聚四氟乙烯、尼龙、离聚物或其混合物的材料制成。
10.根据权利要求1的无边框光能组件,其中所述底涂层由选自聚氯乙烯、聚丙烯、聚乙烯基、聚四氟乙烯、尼龙或金属箔的材料制成。
11.根据权利要求1的无边框光能组件,其中所述底涂层还含有第三胶层,第三胶层位于底涂层的靠近基材层的那一侧。
12.根据权利要求11的无边框光能组件,其中所述第三胶层由选自亚克力胶、热熔胶、结构胶、硅基胶或其组合的胶粘剂制成。
13.根据权利要求1的无边框光能组件,其中所述膜层还含有顶层。
14.根据权利要求13的无边框光能组件,其中所述顶层选自耐磨损性涂层、耐候性涂层、防水性涂层、耐污性涂层或装饰性涂层。
15.根据权利要求1的无边框光能组件,所述粘结层与待密封物品的粘结强度,按90度剥离强度计,大于1N/cm。
16.根据权利要求15的无边框光能组件,所述粘结层的胶层为亚克力胶层,所述粘结层的基材层由亚克力泡绵制成。
17.根据权利要求1的无边框光能组件,所述保护层和所述胶带具有如下耐候性能:在IEC61215规定的-40℃-+85℃高低温循环至少200次;-40℃-+85℃/85%RH潮湿冷冻循环至少10次;+85℃/85%RH高温高湿老化至少1000小时。
18.根据权利要求17的无边框光能组件,所述保护层包括底涂层和膜层,其中所述膜层由黑色聚氯乙烯制成。
19.根据权利要求2的无边框光能组件,所述防水中间层能通过IEC61215规定的如下条件下的浸水湿漏电测试:-40℃-+85℃/85%RH潮湿冷冻循环,10次;+85℃/85%RH高温高湿老化1000小时。
20.根据权利要求19的无边框光能组件,所述防水中间层由铝箔制成。
21.根据权利要求1的无边框光能组件,其中,所述基材层由亚克力泡绵制成,厚度为0.2~2.0mm;所述第一、第二胶层由亚克力胶粘剂组成,厚度为10~100μm;所述防水中间层由铝箔制成,厚度为10~100μm;所述底涂层由底涂剂组成,厚度为0.005~0.05mm;所述膜层由黑色聚氯乙烯制成,厚度为0.10~2mm,
所述组件从被密封物品的90度剥离强度大于1N/cm,并且具备如下耐候性能:
根据IEC60721-2-1规定的户外暴露条件,总辐射量为60kWh/m2;
根据IEC61215规定的:
-40℃-+85℃高低温循环,200次;
-40℃-+85℃/85%RH潮湿冷冻循环,10次;
+85℃/85%RH高温高湿老化1000小时,
其中老化前后,所述组件的防水性能均通过IEC61215规定的浸水湿漏电测试。
22.根据权利要求1的无边框光能组件,其中所述基材层由泡绵胶制成。
23.根据权利要求22的无边框光能组件,其不含有第一胶层和第二胶层。
24.根据权利要求1的无边框光能组件,其为选自光伏板、薄膜光伏板、光热板的组件。
25.一种胶带,其如权利要求1-23中任一项所限定。
26.一种太阳能制品,其具有如权利要求1-24中任一项所述的光能组件。
27.根据权利要求26的制品,其为选自太阳能交通工具、太阳能热水器、太阳能路灯、或太阳能幕墙的制品。
Priority Applications (11)
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CN201410250754.2A CN104051557B (zh) | 2011-02-18 | 2011-02-18 | 胶带及由其制成的太阳能组件和制品 |
CN201110042671.0A CN102646740B (zh) | 2011-02-18 | 2011-02-18 | 胶带及由其制成的太阳能组件和制品 |
US13/985,604 US9310102B2 (en) | 2011-02-18 | 2012-02-08 | Adhesive tape and solar assembly and article made thereof |
KR1020137024118A KR20140021560A (ko) | 2011-02-18 | 2012-02-08 | 접착 테이프 및 태양광 조립체 및 그로부터 제조된 물품 |
JP2013554484A JP6034308B2 (ja) | 2011-02-18 | 2012-02-08 | 接着テープ及び太陽電池組立体、並びにそれらから作成される物品 |
MYPI2013003004A MY163349A (en) | 2011-02-18 | 2012-02-08 | Adhesive tape and solar assembly and article made thereof |
PCT/US2012/024335 WO2012112361A2 (en) | 2011-02-18 | 2012-02-08 | Adhesive tape and solar assembly and article made thereof |
MX2013009447A MX345174B (es) | 2011-02-18 | 2012-02-08 | Cinta adhesiva y ensamble solar y articulo hecho de los mismos. |
EP12706151.3A EP2675857B1 (en) | 2011-02-18 | 2012-02-08 | Adhesive tape and solar assembly and article made thereof |
TW101105339A TWI553086B (zh) | 2011-02-18 | 2012-02-17 | 膠帶和太陽能組裝及以其製作而成之物品 |
US15/330,948 US10026858B2 (en) | 2011-02-18 | 2016-04-11 | Adhesive tape and solar assembly and article made thereof |
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EP (1) | EP2675857B1 (zh) |
JP (1) | JP6034308B2 (zh) |
KR (1) | KR20140021560A (zh) |
CN (1) | CN102646740B (zh) |
MX (1) | MX345174B (zh) |
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CN102797297A (zh) * | 2012-08-24 | 2012-11-28 | 北京立高防水工程有限公司 | 太阳能发电复合防水自粘卷材及其施工方法 |
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CN108034382B (zh) * | 2017-12-28 | 2021-02-19 | 张家港康得新光电材料有限公司 | 阻水泡棉胶带、其制备方法及电子设备 |
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CN114555742B (zh) * | 2019-10-18 | 2024-05-24 | 3M创新有限公司 | 粘合剂膜 |
Also Published As
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CN102646740B (zh) | 2015-06-10 |
US20130333692A1 (en) | 2013-12-19 |
EP2675857A2 (en) | 2013-12-25 |
US20170222079A1 (en) | 2017-08-03 |
MX345174B (es) | 2017-01-19 |
TW201241137A (en) | 2012-10-16 |
KR20140021560A (ko) | 2014-02-20 |
MY163349A (en) | 2017-09-15 |
JP2014512668A (ja) | 2014-05-22 |
EP2675857B1 (en) | 2020-01-22 |
US10026858B2 (en) | 2018-07-17 |
MX2013009447A (es) | 2013-10-01 |
TWI553086B (zh) | 2016-10-11 |
US9310102B2 (en) | 2016-04-12 |
WO2012112361A2 (en) | 2012-08-23 |
WO2012112361A3 (en) | 2012-12-27 |
JP6034308B2 (ja) | 2016-11-30 |
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