CN102050968A - 反式-1,4-聚二烯烃复合橡胶及其制备方法 - Google Patents
反式-1,4-聚二烯烃复合橡胶及其制备方法 Download PDFInfo
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- CN102050968A CN102050968A CN2009101744944A CN200910174494A CN102050968A CN 102050968 A CN102050968 A CN 102050968A CN 2009101744944 A CN2009101744944 A CN 2009101744944A CN 200910174494 A CN200910174494 A CN 200910174494A CN 102050968 A CN102050968 A CN 102050968A
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- isoprene
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- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 3
- 229910000086 alane Inorganic materials 0.000 claims description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 2
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- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 claims description 2
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- 229920000642 polymer Polymers 0.000 description 4
- 229920003051 synthetic elastomer Polymers 0.000 description 4
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- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
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- 235000021355 Stearic acid Nutrition 0.000 description 1
- VLLYOYVKQDKAHN-UHFFFAOYSA-N buta-1,3-diene;2-methylbuta-1,3-diene Chemical compound C=CC=C.CC(=C)C=C VLLYOYVKQDKAHN-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
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- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
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- 229910052747 lanthanoid Inorganic materials 0.000 description 1
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- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
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CN2009101744944A CN102050968B (zh) | 2009-11-06 | 2009-11-06 | 反式-1,4-聚二烯烃复合橡胶及其制备方法 |
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Cited By (19)
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CN103059368A (zh) * | 2011-10-21 | 2013-04-24 | 黄宝琛 | 低分子反式-1,4-聚异戊二烯蜡的应用 |
CN103205030A (zh) * | 2012-01-12 | 2013-07-17 | 东营格瑞橡塑新材料有限公司 | 反式-1,4-聚二烯烃复合橡胶在橡胶制品中的应用 |
CN103204973A (zh) * | 2012-01-12 | 2013-07-17 | 青岛科技大学 | 一种低分子量反式-1,4-聚二烯烃共聚物及其制备方法和用途 |
CN103265654A (zh) * | 2013-05-29 | 2013-08-28 | 浙江大学 | 一种气相聚合制备高反式聚异戊二烯的方法及其催化剂 |
CN103275255A (zh) * | 2013-05-29 | 2013-09-04 | 浙江大学 | 一种利用气相聚合制备高反式聚丁二烯的方法及其催化剂 |
CN103387641A (zh) * | 2012-05-08 | 2013-11-13 | 青岛科技大学 | 一种反式-1,4-结构的丁二烯-异戊二烯共聚橡胶及其制备方法 |
CN104479073A (zh) * | 2014-12-23 | 2015-04-01 | 中国科学院长春应用化学研究所 | 具有核壳结构的聚异戊二烯橡胶合金及其制备方法 |
CN104629114A (zh) * | 2015-02-02 | 2015-05-20 | 柳州市同进汽车零部件制造有限公司 | 减震橡胶组合物 |
CN104497209B (zh) * | 2014-12-23 | 2017-04-19 | 中国科学院长春应用化学研究所 | 一种低结晶度高反式‑1,4‑聚异戊二烯的制备方法 |
CN106699966A (zh) * | 2015-07-17 | 2017-05-24 | 中国石油化工股份有限公司 | 一种丁二烯-异戊二烯共聚橡胶及其制备方法 |
CN106977638A (zh) * | 2017-03-30 | 2017-07-25 | 青岛竣翔新材料有限公司 | 一种制备粒状反式异戊橡胶的连续化生产方法及装置 |
WO2017161898A1 (zh) * | 2016-03-24 | 2017-09-28 | 青岛科技大学 | 反式丁戊共聚橡胶的工业化生产方法及实施该方法的装置 |
CN109181027A (zh) * | 2018-09-07 | 2019-01-11 | 山东华聚高分子材料有限公司 | 一种高性能轮胎胎面胶及其制备方法 |
CN110511300A (zh) * | 2019-09-18 | 2019-11-29 | 青岛科技大学 | 一种卤化的反式丁二烯-异戊二烯共聚橡胶及其制备方法和用途 |
CN111333762A (zh) * | 2019-12-20 | 2020-06-26 | 青岛竣翔科技有限公司 | 一种梳妆结构聚法尼烯橡胶及其制备方法 |
CN111607033A (zh) * | 2020-06-09 | 2020-09-01 | 山东京博中聚新材料有限公司 | 一种聚二烯烃类橡胶的制备方法 |
CN113087829A (zh) * | 2021-04-07 | 2021-07-09 | 青岛科技大学 | 一种端基官能化的合成橡胶及其制备方法与用途 |
CN114369296A (zh) * | 2021-04-19 | 2022-04-19 | 江苏东昊橡胶有限公司 | 一种电动车轮胎高抓性胎面胶及其制备工艺 |
CN114369294A (zh) * | 2022-01-12 | 2022-04-19 | 青岛科技大学 | 一种聚二烯烃釜内合金及其制备方法与用途 |
Family Cites Families (3)
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JP3020143B2 (ja) * | 1997-01-13 | 2000-03-15 | 工業技術院長 | 脱硫剤の製造方法 |
CN1137190C (zh) * | 2001-02-19 | 2004-02-04 | 青岛化工学院 | 高反式-1,4-聚异戊二烯和高乙烯基聚丁二烯并用的轮胎胎面胶料 |
CN100494229C (zh) * | 2006-04-11 | 2009-06-03 | 青岛科大方泰材料工程有限公司 | 高反式-1,4-聚异戊二烯的工业合成方法 |
-
2009
- 2009-11-06 CN CN2009101744944A patent/CN102050968B/zh active Active
Cited By (30)
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CN103059368A (zh) * | 2011-10-21 | 2013-04-24 | 黄宝琛 | 低分子反式-1,4-聚异戊二烯蜡的应用 |
CN103205030A (zh) * | 2012-01-12 | 2013-07-17 | 东营格瑞橡塑新材料有限公司 | 反式-1,4-聚二烯烃复合橡胶在橡胶制品中的应用 |
CN103204973A (zh) * | 2012-01-12 | 2013-07-17 | 青岛科技大学 | 一种低分子量反式-1,4-聚二烯烃共聚物及其制备方法和用途 |
CN103205030B (zh) * | 2012-01-12 | 2016-08-03 | 山东华聚高分子材料有限公司 | 反式-1,4-聚二烯烃复合橡胶在橡胶制品中的应用 |
CN103387641B (zh) * | 2012-05-08 | 2016-04-06 | 青岛科技大学 | 一种反式-1,4-结构的丁二烯-异戊二烯共聚橡胶及其制备方法 |
CN103387641A (zh) * | 2012-05-08 | 2013-11-13 | 青岛科技大学 | 一种反式-1,4-结构的丁二烯-异戊二烯共聚橡胶及其制备方法 |
CN103265654A (zh) * | 2013-05-29 | 2013-08-28 | 浙江大学 | 一种气相聚合制备高反式聚异戊二烯的方法及其催化剂 |
CN103275255A (zh) * | 2013-05-29 | 2013-09-04 | 浙江大学 | 一种利用气相聚合制备高反式聚丁二烯的方法及其催化剂 |
CN104479073A (zh) * | 2014-12-23 | 2015-04-01 | 中国科学院长春应用化学研究所 | 具有核壳结构的聚异戊二烯橡胶合金及其制备方法 |
CN104497209B (zh) * | 2014-12-23 | 2017-04-19 | 中国科学院长春应用化学研究所 | 一种低结晶度高反式‑1,4‑聚异戊二烯的制备方法 |
CN104479073B (zh) * | 2014-12-23 | 2017-05-17 | 中国科学院长春应用化学研究所 | 具有核壳结构的聚异戊二烯橡胶合金及其制备方法 |
CN104629114A (zh) * | 2015-02-02 | 2015-05-20 | 柳州市同进汽车零部件制造有限公司 | 减震橡胶组合物 |
CN106699966A (zh) * | 2015-07-17 | 2017-05-24 | 中国石油化工股份有限公司 | 一种丁二烯-异戊二烯共聚橡胶及其制备方法 |
CN106699966B (zh) * | 2015-07-17 | 2019-03-26 | 中国石油化工股份有限公司 | 一种丁二烯-异戊二烯共聚橡胶及其制备方法 |
WO2017161898A1 (zh) * | 2016-03-24 | 2017-09-28 | 青岛科技大学 | 反式丁戊共聚橡胶的工业化生产方法及实施该方法的装置 |
US10988561B2 (en) | 2016-03-24 | 2021-04-27 | Qingdao University Of Science And Technology | Method for industrial production of trans-butadiene-isoprene copolymer rubber and apparatus therefor |
RU2705220C1 (ru) * | 2016-03-24 | 2019-11-06 | Циндао Юниверсити Оф Сайенс Энд Текнолоджи | Способ промышленного получения транс-бутадиен-изопренового сополимерного каучука и установка для него |
CN106977638A (zh) * | 2017-03-30 | 2017-07-25 | 青岛竣翔新材料有限公司 | 一种制备粒状反式异戊橡胶的连续化生产方法及装置 |
CN106977638B (zh) * | 2017-03-30 | 2020-03-27 | 青岛竣翔科技有限公司 | 一种制备粒状反式异戊橡胶的连续化生产方法及装置 |
CN109181027A (zh) * | 2018-09-07 | 2019-01-11 | 山东华聚高分子材料有限公司 | 一种高性能轮胎胎面胶及其制备方法 |
CN110511300B (zh) * | 2019-09-18 | 2021-09-14 | 青岛科技大学 | 一种卤化的反式丁二烯-异戊二烯共聚橡胶及其制备方法和用途 |
CN110511300A (zh) * | 2019-09-18 | 2019-11-29 | 青岛科技大学 | 一种卤化的反式丁二烯-异戊二烯共聚橡胶及其制备方法和用途 |
CN111333762A (zh) * | 2019-12-20 | 2020-06-26 | 青岛竣翔科技有限公司 | 一种梳妆结构聚法尼烯橡胶及其制备方法 |
CN111607033A (zh) * | 2020-06-09 | 2020-09-01 | 山东京博中聚新材料有限公司 | 一种聚二烯烃类橡胶的制备方法 |
CN111607033B (zh) * | 2020-06-09 | 2022-03-29 | 山东京博中聚新材料有限公司 | 一种聚二烯烃类橡胶的制备方法 |
CN113087829A (zh) * | 2021-04-07 | 2021-07-09 | 青岛科技大学 | 一种端基官能化的合成橡胶及其制备方法与用途 |
CN113087829B (zh) * | 2021-04-07 | 2023-08-29 | 青岛科技大学 | 一种端基官能化的合成橡胶及其制备方法与用途 |
CN114369296A (zh) * | 2021-04-19 | 2022-04-19 | 江苏东昊橡胶有限公司 | 一种电动车轮胎高抓性胎面胶及其制备工艺 |
CN114369296B (zh) * | 2021-04-19 | 2023-08-22 | 江苏东昊橡胶有限公司 | 一种电动车轮胎高抓性胎面胶及其制备工艺 |
CN114369294A (zh) * | 2022-01-12 | 2022-04-19 | 青岛科技大学 | 一种聚二烯烃釜内合金及其制备方法与用途 |
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