CN102050968B - 反式-1,4-聚二烯烃复合橡胶及其制备方法 - Google Patents
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- HPNMFZURTQLUMO-UHFFFAOYSA-O diethylammonium Chemical compound CC[NH2+]CC HPNMFZURTQLUMO-UHFFFAOYSA-O 0.000 claims description 2
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- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 4
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Abstract
Description
实施例 | 聚二烯烃复合胶,克 | 异戊二烯共聚物占复合橡胶的质量含量/% | 丁二烯占丁二烯-异戊二烯共聚物的质量含量/% | 聚二烯烃复合橡胶的重均分子量MW×10-4/(g/mol) | 聚二烯烃复合橡胶的分子量分布MW/Mn | 反-1,4-结构含量Mol% |
1 | 880 | 26 | 20 | 33 | 6.4 | 98 |
2 | 960 | 20 | 50 | 58 | 4.3 | 99 |
3 | 800 | 30 | 28 | 43 | 3.9 | 97 |
4 | 1530 | 50 | 27 | 25 | 4.2 | 96 |
5 | 1390 | 41 | 21 | 22 | 3.9 | 98 |
6 | 1470 | 72 | 20 | 19 | 3.5 | 95 |
7 | 25000 | 61 | 5 | 15 | 3.4 | 99 |
8 | 31000 | 85 | 10 | 26 | 2.9 | 99 |
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Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103059368A (zh) * | 2011-10-21 | 2013-04-24 | 黄宝琛 | 低分子反式-1,4-聚异戊二烯蜡的应用 |
CN103205030B (zh) * | 2012-01-12 | 2016-08-03 | 山东华聚高分子材料有限公司 | 反式-1,4-聚二烯烃复合橡胶在橡胶制品中的应用 |
CN103204973B (zh) * | 2012-01-12 | 2017-07-25 | 青岛科技大学 | 一种低分子量反式‑1,4‑聚二烯烃共聚物及其制备方法和用途 |
CN103387641B (zh) * | 2012-05-08 | 2016-04-06 | 青岛科技大学 | 一种反式-1,4-结构的丁二烯-异戊二烯共聚橡胶及其制备方法 |
CN103265654B (zh) * | 2013-05-29 | 2014-12-31 | 浙江大学 | 一种气相聚合制备高反式聚异戊二烯的方法及其催化剂 |
CN103275255B (zh) * | 2013-05-29 | 2014-12-31 | 浙江大学 | 一种利用气相聚合制备高反式聚丁二烯的方法及其催化剂 |
CN104479073B (zh) * | 2014-12-23 | 2017-05-17 | 中国科学院长春应用化学研究所 | 具有核壳结构的聚异戊二烯橡胶合金及其制备方法 |
CN104497209B (zh) * | 2014-12-23 | 2017-04-19 | 中国科学院长春应用化学研究所 | 一种低结晶度高反式‑1,4‑聚异戊二烯的制备方法 |
CN104629114A (zh) * | 2015-02-02 | 2015-05-20 | 柳州市同进汽车零部件制造有限公司 | 减震橡胶组合物 |
CN106699966B (zh) * | 2015-07-17 | 2019-03-26 | 中国石油化工股份有限公司 | 一种丁二烯-异戊二烯共聚橡胶及其制备方法 |
CN105601814B (zh) | 2016-03-24 | 2020-11-27 | 青岛科技大学 | 反式丁戊共聚橡胶的工业化生产方法及实施该方法的装置 |
CN106977638B (zh) * | 2017-03-30 | 2020-03-27 | 青岛竣翔科技有限公司 | 一种制备粒状反式异戊橡胶的连续化生产方法及装置 |
CN109181027B (zh) * | 2018-09-07 | 2021-10-26 | 山东华聚高分子材料有限公司 | 一种高性能轮胎胎面胶及其制备方法 |
CN110511300B (zh) * | 2019-09-18 | 2021-09-14 | 青岛科技大学 | 一种卤化的反式丁二烯-异戊二烯共聚橡胶及其制备方法和用途 |
CN111333762A (zh) * | 2019-12-20 | 2020-06-26 | 青岛竣翔科技有限公司 | 一种梳妆结构聚法尼烯橡胶及其制备方法 |
CN111607033B (zh) * | 2020-06-09 | 2022-03-29 | 山东京博中聚新材料有限公司 | 一种聚二烯烃类橡胶的制备方法 |
CN113087829B (zh) * | 2021-04-07 | 2023-08-29 | 青岛科技大学 | 一种端基官能化的合成橡胶及其制备方法与用途 |
CN114369296B (zh) * | 2021-04-19 | 2023-08-22 | 江苏东昊橡胶有限公司 | 一种电动车轮胎高抓性胎面胶及其制备工艺 |
CN114369294B (zh) * | 2022-01-12 | 2023-05-09 | 青岛科技大学 | 一种聚二烯烃釜内合金及其制备方法与用途 |
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JP3020143B2 (ja) * | 1997-01-13 | 2000-03-15 | 工業技術院長 | 脱硫剤の製造方法 |
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CN1847272A (zh) * | 2006-04-11 | 2006-10-18 | 青岛科大方泰材料工程有限公司 | 高反式-1,4-聚异戊二烯的工业合成方法 |
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JP3020143B2 (ja) * | 1997-01-13 | 2000-03-15 | 工業技術院長 | 脱硫剤の製造方法 |
CN1322772A (zh) * | 2001-02-19 | 2001-11-21 | 青岛化工学院 | 高反式-1,4-聚异戊二烯和高乙烯基聚丁二烯并用的高速节能轮胎胎面胶料 |
CN1847272A (zh) * | 2006-04-11 | 2006-10-18 | 青岛科大方泰材料工程有限公司 | 高反式-1,4-聚异戊二烯的工业合成方法 |
Non-Patent Citations (2)
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JP平3-210344A 1991.09.13 |
JP昭60-42412A 1985.03.06 |
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Owner name: WANG RIGUO ZHANG CHAO ZHANG HONGZHEN WU GUIZHONG Y Effective date: 20150422 |
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Effective date of registration: 20150422 Address after: 257091 Dongying Hongyuan Machinery & Equipment Co., Ltd. 99 Huzhou Road, Dongying District, Shandong, Dongying Patentee after: Zhang Guojie Patentee after: Liu Xuelan Patentee after: Sui Yanmin Patentee after: Shi Shaoyun Patentee after: He Aihua Patentee after: Wang Riguo Patentee after: Zhang Chao Patentee after: Zhang Hongzhen Patentee after: Wu Guizhong Patentee after: Yang Yang Patentee after: Liu Chenguang Patentee after: Shao Huafeng Patentee after: Liu Mengyu Address before: 257091 Dongying Hongyuan Machinery & Equipment Co., Ltd. 99 Huzhou Road, Dongying District, Shandong, Dongying Patentee before: Zhang Guojie |
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Effective date of registration: 20151026 Address after: Hu Zhen 256500 Shandong County of Boxing province Chen Jingbo Petrochemical Rubber Institute Patentee after: SHANDONG HUAJU HIGH POLYMER MATERIAL CO., LTD. Address before: 257091 Dongying Hongyuan Machinery & Equipment Co., Ltd. 99 Huzhou Road, Dongying District, Shandong, Dongying Patentee before: Zhang Guojie Patentee before: Liu Xuelan Patentee before: Sui Yanmin Patentee before: Shi Shaoyun Patentee before: He Aihua Patentee before: Wang Riguo Patentee before: Zhang Chao Patentee before: Zhang Hongzhen Patentee before: Wu Guizhong Patentee before: Yang Yang Patentee before: Liu Chenguang Patentee before: Shao Huafeng Patentee before: Liu Mengyu |