CN101942568B - 一种从废旧计算机及其配件中回收贵金属的方法 - Google Patents
一种从废旧计算机及其配件中回收贵金属的方法 Download PDFInfo
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- CN101942568B CN101942568B CN2010105232204A CN201010523220A CN101942568B CN 101942568 B CN101942568 B CN 101942568B CN 2010105232204 A CN2010105232204 A CN 2010105232204A CN 201010523220 A CN201010523220 A CN 201010523220A CN 101942568 B CN101942568 B CN 101942568B
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- precious metal
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- 239000002699 waste material Substances 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 26
- 229910000510 noble metal Inorganic materials 0.000 title abstract 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 46
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052737 gold Inorganic materials 0.000 claims abstract description 32
- 239000010931 gold Substances 0.000 claims abstract description 32
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 27
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 27
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 23
- 229910052709 silver Inorganic materials 0.000 claims abstract description 19
- 239000004332 silver Substances 0.000 claims abstract description 19
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 18
- NICDRCVJGXLKSF-UHFFFAOYSA-N nitric acid;trihydrochloride Chemical compound Cl.Cl.Cl.O[N+]([O-])=O NICDRCVJGXLKSF-UHFFFAOYSA-N 0.000 claims abstract description 16
- 235000019270 ammonium chloride Nutrition 0.000 claims abstract description 12
- 238000002386 leaching Methods 0.000 claims abstract description 12
- 238000011084 recovery Methods 0.000 claims abstract description 12
- 238000000053 physical method Methods 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 39
- 239000010970 precious metal Substances 0.000 claims description 38
- 239000000706 filtrate Substances 0.000 claims description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 18
- 238000005868 electrolysis reaction Methods 0.000 claims description 17
- 239000008151 electrolyte solution Substances 0.000 claims description 15
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
- 239000010946 fine silver Substances 0.000 claims description 8
- 230000035484 reaction time Effects 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 7
- 229910001961 silver nitrate Inorganic materials 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- 229910003803 Gold(III) chloride Inorganic materials 0.000 claims description 6
- RJHLTVSLYWWTEF-UHFFFAOYSA-K gold trichloride Chemical compound Cl[Au](Cl)Cl RJHLTVSLYWWTEF-UHFFFAOYSA-K 0.000 claims description 6
- 229940076131 gold trichloride Drugs 0.000 claims description 6
- 230000005484 gravity Effects 0.000 claims description 6
- 238000007885 magnetic separation Methods 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000001556 precipitation Methods 0.000 claims description 5
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 3
- 238000005555 metalworking Methods 0.000 claims description 3
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 239000000356 contaminant Substances 0.000 claims 1
- 238000012216 screening Methods 0.000 claims 1
- ONVGIJBNBDUBCM-UHFFFAOYSA-N silver;silver Chemical compound [Ag].[Ag+] ONVGIJBNBDUBCM-UHFFFAOYSA-N 0.000 claims 1
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 238000006722 reduction reaction Methods 0.000 description 9
- 238000007670 refining Methods 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 4
- 229910000906 Bronze Inorganic materials 0.000 description 3
- 238000000862 absorption spectrum Methods 0.000 description 3
- 239000010974 bronze Substances 0.000 description 3
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000000247 postprecipitation Methods 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- -1 silver ions Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Manufacture And Refinement Of Metals (AREA)
Abstract
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Claims (5)
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CN2010105232204A CN101942568B (zh) | 2010-10-28 | 2010-10-28 | 一种从废旧计算机及其配件中回收贵金属的方法 |
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CN2010105232204A CN101942568B (zh) | 2010-10-28 | 2010-10-28 | 一种从废旧计算机及其配件中回收贵金属的方法 |
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CN101942568A CN101942568A (zh) | 2011-01-12 |
CN101942568B true CN101942568B (zh) | 2013-07-24 |
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Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103343231A (zh) * | 2013-07-10 | 2013-10-09 | 吉林化工学院 | 从废电脑中回收有用金属的方法 |
CN103397186B (zh) * | 2013-07-12 | 2014-12-17 | 湖南省同力电子废弃物回收拆解利用有限公司 | 一种从电子废弃物中回收稀贵金属的再生方法及工艺 |
CN103436701A (zh) * | 2013-08-21 | 2013-12-11 | 上海市闵行第二中学 | 一种废弃cpu金属回收方法 |
CN105274337B (zh) * | 2014-10-06 | 2017-11-03 | 建昇电子科技(惠州)有限公司 | 废旧电路板回收贵金属的方法 |
CN105219967A (zh) * | 2015-10-14 | 2016-01-06 | 云龙县铂翠贵金属科技有限公司 | 一种铜基镀钯电子废料退钯及提铜的方法 |
CN105385854A (zh) * | 2015-12-11 | 2016-03-09 | 励福(江门)环保科技股份有限公司 | 首饰加工打磨粉中回收贵金属金、铂和钯的方法 |
CN107400780A (zh) * | 2017-07-18 | 2017-11-28 | 四川长虹电器股份有限公司 | 一种从手机线路板中提取金银铜的方法 |
CN108070722B (zh) * | 2017-12-18 | 2019-12-13 | 郴州市金贵银业股份有限公司 | 一种从银电解母液沉铜渣中回收有价金属的方法 |
CN109402402B (zh) * | 2018-12-11 | 2020-08-18 | 西安诺博尔稀贵金属材料股份有限公司 | 一种回收金银铜合金废料中金和银的方法 |
CN110484744B (zh) * | 2019-08-26 | 2020-07-24 | 珠海格力电器股份有限公司 | 一种从废旧贴片电容中回收贵金属的方法 |
EP4103755A1 (en) | 2020-02-12 | 2022-12-21 | Bromine Compounds Ltd. | A process for recovering metals from recycled rechargeable batteries |
CN113528849B (zh) * | 2021-06-02 | 2022-12-23 | 云南滇金投资有限公司 | 一种从含钯银合质金中提取精炼金的方法 |
CN115491512A (zh) * | 2021-06-17 | 2022-12-20 | 江苏宁达环保股份有限公司 | 一种阴极射线管荧光粉中贵金属的提取回收方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101230421A (zh) * | 2007-12-26 | 2008-07-30 | 东华大学 | 一种从废电路板中提金的方法 |
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Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101230421A (zh) * | 2007-12-26 | 2008-07-30 | 东华大学 | 一种从废电路板中提金的方法 |
Non-Patent Citations (1)
Title |
---|
黎鼎鑫等.贵金属提取与精炼.《贵金属提取与精炼》.中南大学出版社,2003,451-463,511-516,524-528,551-556,592-593. * |
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GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: GUANGDONG BRUNP RECYCLING CO., LTD. Free format text: FORMER NAME: FOSHAN BRUNP NICKEL COBALT TECHNOLOGY CO., LTD. |
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CP01 | Change in the name or title of a patent holder |
Address after: Nanhai District of Guangdong water town on the 528244 city of Foshan Province, Foshan City Industrial Zone Chung brunp nickel cobalt Technology Co. Ltd. Patentee after: Guangdong Brunp Recycling Technology Co., Ltd. Address before: Nanhai District of Guangdong water town on the 528244 city of Foshan Province, Foshan City Industrial Zone Chung brunp nickel cobalt Technology Co. Ltd. Patentee before: Foshan Brunp Nickel Cobalt Technology Co., Ltd. |
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C56 | Change in the name or address of the patentee |
Owner name: GUANGDONG BANGPU CIRCULATION TECHNOLOGY CO., LTD. Free format text: FORMER NAME: GUANGDONG BRUNP RECYCLING CO., LTD. |
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CP01 | Change in the name or title of a patent holder |
Address after: Nanhai District of Guangdong water town on the 528244 Foshan Bay Industrial Zone Patentee after: GUANGDONG BRUNP RECYCLING TECHNOLOGY CO., LTD. Address before: Nanhai District of Guangdong water town on the 528244 Foshan Bay Industrial Zone Patentee before: Guangdong Brunp Recycling Technology Co., Ltd. |
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Effective date of registration: 20171129 Address after: 528248 Guangdong province Lishui Town Nanhai District Foshan City Industrial Zone, Sha Co-patentee after: Hunan Brunp Circulation Technology Co., Ltd. Patentee after: GUANGDONG BRUNP RECYCLING TECHNOLOGY CO., LTD. Address before: Nanhai District of Guangdong water town on the 528244 city of Foshan Province, Foshan City Industrial Zone Chung brunp nickel cobalt Technology Co. Ltd. Patentee before: GUANGDONG BRUNP RECYCLING TECHNOLOGY CO., LTD. |
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Address after: No.6 Zhixin Avenue, Leping Town, Sanshui District, Foshan City, Guangdong Province Patentee after: GUANGDONG BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Patentee after: HUNAN BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Address before: 528248 Guangdong province Lishui Town Nanhai District Foshan City Industrial Zone, Sha Patentee before: GUANGDONG BRUNP RECYCLING TECHNOLOGY Co.,Ltd. Patentee before: HUNAN BRUNP RECYCLING TECHNOLOGY Co.,Ltd. |
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