CN101921136A - Raw material matting glaze - Google Patents
Raw material matting glaze Download PDFInfo
- Publication number
- CN101921136A CN101921136A CN 201010145245 CN201010145245A CN101921136A CN 101921136 A CN101921136 A CN 101921136A CN 201010145245 CN201010145245 CN 201010145245 CN 201010145245 A CN201010145245 A CN 201010145245A CN 101921136 A CN101921136 A CN 101921136A
- Authority
- CN
- China
- Prior art keywords
- glaze
- raw material
- percent
- matting
- material matting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Glass Compositions (AREA)
Abstract
The invention relates to ceramic glaze, in particular to lead-free raw material matting glaze used for producing high-quality matting bone china products. The lead-free raw material matting glaze comprises the following chemical components in percent by weight: 48-60 percent of SiO2, 12.0-22.0 percent of Al2O3, 5.0-12.0 percent of ZnO, 5-12 percent of CaO, 0.5-2.0 percent of MgO, 0.0-3 percent of BaO, 0.0-3.0 percent of ZrO2, 0.0-2.0 percent of TiO2 and 5.0-15.0 percent of K2O and Na2O. The raw material constituent of the raw material matting glaze does not contain any harmful heavy metal elemental constituent, such as lead, cadmium, and the like, and the feldspar of the mineral raw material is mainly introduced. The invention has simple, scientific and reasonable constituent and is the raw material glaze; and the glaze does not need to be made into frits, therefore, energy sources are largely saved; the blank glaze has good adaptability, low firing temperature and wide firing range; the fired finished-product ceramic glaze surface is fine, moist, smooth and soft and does not have strong reflect light; and the glaze surface has strong corrosion resistance, high mechanical strength and good thermal shock stability and is easy to clean, therefore, the glaze is especially suitable for tableware dish-washing machines. The invention thoroughly solves the problems of the gloss and the texture of high-grade bone china.
Description
Technical field
The present invention relates to ceramic glaze, especially a kind of unleaded raw material matting glaze that is used to produce high-grade mute light sclerotin porcelain products.
Technical background
The glaze of pottery is to pass through physics by the effect of fire---chemical reaction produces various variations and obtains, and is the glassy mass that is formed through complex physico-chemical in hot conditions by multi mineral raw material and inorganic chemical industry material.Glaze is a kind of silicate, orthosilicate SiO
2H
2O or H
2SiO
3Be dihydric acid and basic metal or alkaline-earth metal chemical combination, then generate the transparent vitreous glaze layer of gloss beauty, close the gloss [non-references 1] that can obtain beauty with the calorize in the metal.The sclerotin porcelain is universally acknowledged high-grade porcelain kind.For a long time, the enamel of production sclerotin porcelain all is to use the clear frit glaze of high gloss.
Dumb light glaze is the micro-crystallization glaze of matt glaze system, the crystal that is the very tiny granularity that produced by firing period brings out generation, the crystallization result makes glaze produce matt appearance, its Dumb ray machine reason, be in admixtion, to add the element that can cause the Dumb light action, generate countless small single crystal in certain firing temperature and suitable speed of cooling process, the countless small single crystal of this class reflect light, thus generation Dumb light effect.
Dumb light glaze is modernized ceramic flawless finish glaze, it is the up-to-date trend of world today's ceramic decoration material, because Dumb light glaze, glaze exquisiteness, moist, do not have reflective strongly, give a kind of soft, quiet, comfortable visual experience of people, use its decorating ceramic articles, have simplicity, nature, graceful artistic characteristics.Dumb light glaze has opaque Dumb optical surface, and the base substrate color and luster is had stronger opacifying power, therefore, is used to decorate high-quality sclerotin porcelain, can make product obtain special texture, aesthetic feeling and unique artistic charm [non-references 1].
High-grade matting glaze is plain quiet and not delicate and charming, smoothly and not bright, and finger touch is like suet, light such as wax, like satin, like thin,tough silk, and the dirt that bears dirty, under same case, thermostability and ultimate compression strength are all good than common quartzy glaze.The matting glaze product can make the people feel quiet, detailed and, body and mind is loosened, fatigue alleviates, and is happy.High-grade matting glaze product, with the psychology that its distinctive effect has been catered to people, the market of more and more selling well [non-references 2].
High-quality sclerotin porcelain all is to adopt to burn till i.e. high temperature biscuiting and low temperature glaze firing twice at present.The matting glaze material that the sclerotin porcelain is used also all is to utilize mute light fritted glaze to come processing, that is to say that the matting glaze frit that high temperature melting is made is pulverized again to make glaze slip.This is complex process not only, and the labor force consumes greatly, and causes the great waste of the energy.
China's patents such as light ceramic patent " a kind of matt glaze and manufacture method thereof--application number/patent No.: 200610138704 ", " china sanitary ware--application number/patent No.: 200420044393.8 ", " a kind of production technique of dummy porcelain polished tile and polishing thereof and grinding plant---application for a patent for invention number: cn200510035090.9 " of making mute, its production technique are to adopt mute light fritted glaze, mute light coating, use mute light to grind or utilize method such as chemical corrosion to reach the effect of mute light substantially.Research to raw material matting glaze does not also set foot in, and is especially still blank to the research of the daily sclerotin porcelain raw glaze of top grade.
Summary of the invention
The object of the present invention is to provide a kind of composition simple, energy consumption is little, is easy to produce the brand-new unleaded matting glaze of sclerotin porcelain that glaze is level and smooth, fine and smooth, moist.
Raw material matting glaze of the present invention, its chemical constitution (wt%) is: SiO
248~60.0%, Al
2O
312.0~22.0%, ZnO 5.0~12.0%, CaO 5~12, MgO 0.5~2.0%, BaO 0.0~3, ZrO
20.0~3.0%, TiO20.0~2.0%, K
2O+Na
2O 5.0~15.0%.
Raw material matting glaze of the present invention, its raw material is formed formulated by following weight percent: feldspar 60.0~75.0%, aluminum oxide 1.0~6.0%, zinc oxide 5.0~12.0%, Wingdale 5.0~15.0%, calcination of talc 0.0~3.0%, barium carbonate 0.0~3.0%, zirconium silicate 0.0~3.0%, titanium dioxide 0.0~2.0%, Suzhou soil 3.0~7.0%.
Its raw material of raw material matting glaze of the present invention does not contain deleterious heavy metal components such as any lead, cadmium in forming, and mainly introduces the feldspar of raw mineral materials.Form simple, scientific and reasonable; Be a kind of raw glaze, need not make frit, a large amount of save energy, easy to implement; Glaze fit is good, and firing temperature is low, and firing range is wide, is particularly suitable for the characteristics of domestic kiln excessive temperature differentials; Finished-product ceramic glaze surface exquisiteness after burning till, moist, smooth, soft, light transmission is strong, no strong reflect light presents and different texture of common porcelain and brightness, is distributing noble's noble makings from head to foot; The gloss and the texture problem of high-grade bone china have thoroughly been solved.
The preparation of glaze slurry: the raw material of at first pressing the proportioning weighing needs of design in advance; Secondly with a certain proportion of ball-milling medium---ballstone adds ball mill, simultaneously load weighted raw material is added ball mill; Secondly a certain proportion of water and other dispersion agent are added ball mill.Admixtion is carried out ball mill pulverizing, and it is standby after old 48 hours to make slip.
This research selects for use potassium felspar sand to introduce potassium oxide, zirconium silicate is introduced zirconium white, Wingdale is introduced calcium oxide, calcination of talc is introduced magnesium oxide, selecting for use of other raw materials with common identical, the chemical constitution that the raw materials used chemical constitution of the present invention sees Table raw mineral materials in the 1. above-mentioned raw materials components sees Table 1, and the purity of industrial chemicals is more than 98%.
Table 1 raw material chemistry weight is formed table (wt%)
The first step is by the various raw materials of prescription weighing of design.
In second step, by admixtion: ballstone: the ratio of water=1: 2: 1 is respectively with ballstone, and admixtion and water adding ball mill add certain amount of dispersant CMC again and grind and make glaze slip.The glaze slip granularity is controlled at the following size particles of 10 μ m and accounts for 80~87%.
Raw glaze slip of the present invention household china production technique and operating duty use routinely gets final product.Glaze slip imposes on the biscuit of biscuiting, fires under the glaze firing condition again, promptly obtains finished product.
For a long time, the enamel of production sclerotin porcelain all is to use the transparent of high gloss.Transparent bright glaze can make bright-coloured lucid and lively, the svelteness of ceramic surface, and porcelain is penetrating, the type light.
Along with the continuous lifting of people's living standard and quality, increasing human consumer wishes ceramic simplicity, nature, elegance gradually;--ceramic fashion trend---indication that the international pottery exhibition of Italy Bologna is set up a weathervane to ceramic industry " mute generation light time " arrive [non-references 3]." mute generation light time ", people are making every effort to life emotional affection, soft and living space.High-quality sclerotin porcelain is added matting glaze, has increased more temperament and interest and beautiful enjoyment for undoubtedly people's life.
The method of producing matting glaze generally is to add some oxide compound in transparent glaze formula, as zinc oxide, and aluminum oxide or alkaline earths (magnesium, calcium, strontium, barium) oxide compound.The small crystallization that generates in the Dumb light glaze has lime feldspar, wollastonite, celsian-felspar, tridymite, mullite etc.Though different types of Dumb light glaze all can produce good Dumb light effect, good Dumb light glaze glaze should light such as wax, level and smooth, fine and smooth, moisten, the sense of touch of silk quality.As the tableware porcelain, then crystal should small more densification be good, so than easy cleaning, and also can be lower with the friction destruction of metalic tableware.But through regular meeting the higher or dry and astringent coarse problem of glaze of gloss appears aborning.The quality of Dumb light glaze Dumb light effect is by the chemical constitution and the firing temperature of glaze, burns till the speed decision.It is higher that firing temperature is crossed high gloss, and temperature is crossed low glaze injustice, when having determined ceramic batch, firing temperature, burn till speed, can only solve the problem of its mutual restriction, and the mole chemical constitution ratio of Si and Ca should be between 4.5-5.5 in this proportioning by the chemical constitution of adjusting glaze.
Based on above theory, selected for use feldspar as solvent in the composition proportioning of this research; Do mute photo etching with zinc oxide, the cooling rate when adjusting cooling makes zinc oxide separate out the micro crystal of a large amount of densifications in process of cooling; Add barium carbonate simultaneously to improve mute light effect; In addition, the consumption of controlled oxidation aluminium and calcium oxide reaches the purpose of high-quality mute light effect when making product surface produce the silk quality sense of touch.
[non-references 1]: Su Jicheng; " popular science and technology " 2008. (3).
[non-references 2]: Yu Guoming; " Chinese pottery industry " 2002.Vol.9, No.3.
[non-references 3]: http://www.fstaoci.com/news/200811/1510017.htm
The invention will be further described below in conjunction with embodiment.
Embodiment 1
Embodiment 1 described raw material matting glaze is formed by the preparation of raw material of following weight percent:
Feldspar 64.0%, aluminum oxide 4.5%, zinc oxide 8.0%, Wingdale 14.0%, calcination of talc 1.5%, titanium dioxide 1.0%, zirconium silicate 1.5%, barium carbonate 1.5%, Suzhou soil 4.0%.
At first by the above-mentioned various raw materials of proportioning weighing; Secondly by admixtion: ballstone: the ratio of water=1: 2: 1 adds ball mill respectively, adds 0.05% dispersing agent C MC grinding again and makes glaze slip.The glaze slip granularity is controlled at the following size particles of 10 μ m and accounts for 80~87%, and it is standby to make old 48 hours of slip.
The glaze slip that makes is imposed on unglazed sclerotin porcelain biscuit, under 1120-1150 ℃ temperature, burn till, obtain high-quality mute light sclerotin porcelain products.The porcelain facing light such as the wax of product, and sense of touch level and smooth, fine and smooth, moist, silk quality.Simultaneously, through experiment confirm, the lead of product and cadmium content are zero; The glaze surface corrosive is strong, is difficult for loss of gloss, non-scaling, easy cleaning; The physical strength height, good thermal shock stability is adapted to the use in the tableware dishwasher especially.
Embodiment 2
Embodiment 2 described raw material matting glazes are formed by the preparation of raw material of following weight percent:
Feldspar 64.5%, aluminum oxide 4.0%, zinc oxide 9.0%, Wingdale 14.0%, calcination of talc 1.0%, titanium dioxide 1.0%, zirconium silicate 1.0%, barium carbonate 1.0%, Suzhou soil 4.5%.
At first by the above-mentioned various raw materials of proportioning weighing; Secondly by admixtion: ballstone: the ratio of water=1: 2: 1 adds ball mill respectively, adds 0.05% dispersing agent C MC grinding again and makes glaze slip.The glaze slip granularity is controlled at the following size particles of 10 μ m and accounts for 80~87%, and it is standby to make old 48 hours of slip.
The glaze slip that makes is imposed on unglazed sclerotin porcelain biscuit, under 1130-1170 ℃ temperature, burn till, obtain high-quality mute light sclerotin porcelain products.The porcelain facing light such as the wax of product, and sense of touch level and smooth, fine and smooth, moist, silk quality.Simultaneously, through experiment confirm, the lead of product and cadmium content are zero; The glaze surface corrosive is strong, is difficult for loss of gloss, non-scaling, easy cleaning; The physical strength height, good thermal shock stability is adapted to the use in the tableware dishwasher especially.
Embodiment 3
Embodiment 3 described raw material matting glazes are formed by the preparation of raw material of following weight percent:
Feldspar 65.0%, aluminum oxide 4.0%, zinc oxide 10.0%, Wingdale 13.5%, calcination of talc 1.0%, titanium dioxide 0.5%, zirconium silicate 0.5%, barium carbonate 0.5%, Suzhou soil 5.0%.
At first by the above-mentioned various raw materials of proportioning weighing; Secondly by admixtion: ballstone: the ratio of water=1: 2: 1 adds ball mill respectively, adds 0.05% dispersing agent C MC grinding again and makes glaze slip.The glaze slip granularity is controlled at the following size particles of 10 μ m and accounts for 80~87%, and it is standby to make old 48 hours of slip.
The glaze slip that makes is imposed on unglazed sclerotin porcelain biscuit, under 1140-1180 ℃ temperature, burn till, obtain high-quality mute light sclerotin porcelain products.The porcelain facing light such as the wax of product, and sense of touch level and smooth, fine and smooth, moist, silk quality.Simultaneously, through experiment confirm, the lead of product and cadmium content are zero; The glaze surface corrosive is strong, is difficult for loss of gloss, non-scaling, easy cleaning; The physical strength height, good thermal shock stability is adapted to the use in the tableware dishwasher especially.
The chemical constitution of each embodiment sees Table 2.
The chemical weight percentage composition table (wt%) of table 2 embodiment
Claims (6)
1. a raw material matting glaze is characterized in that, the chemical constitution of this raw material matting glaze (wt%) is:
SiO
2?48~60.0%、Al
2O
3?12.0~22.0%、ZnO?5.0~12.0%、CaO?5~12、MgO?0.5~2.0%、BaO?0.0~3、ZrO
2?0.0~3.0%,TiO2?0.0~2.0%,K
2O+Na
2O?5.0~15.0%。
2. the raw material matting glaze of narrating according to claim 1 is characterized in that feed composition and weight percent consist of:
Feldspar 60.0~75.0%, aluminum oxide 1.0~6.0%, zinc oxide 5.0~12.0%, Wingdale 5.0~15.0%, calcination of talc 0.0~3.0%, barium carbonate 0.0~3.0%, zirconium silicate 0.0~3.0%, titanium dioxide 0.0~2.0%, Suzhou soil 3.0~7.0%.
3. according to claim 1 or 2 raw material matting glazes of being narrated, it is characterized in that this matting glaze is a kind of raw glaze that is directly formed through preparation, ball milling by raw mineral materials and Inorganic Chemicals.
4. according to claim 1 or 2 raw material matting glazes of being narrated, it is characterized in that this raw material matting glaze is a kind of lead-free raw material matting glaze.
5. according to claim 1 or 2 raw material matting glazes of being narrated, be a kind of unleaded raw material matting glaze, it is characterized in that this raw material matting glaze is used to produce mute light sclerotin porcelain products.
6. the unleaded raw material matting glaze of being narrated according to claim 1 or 2 is characterized in that its firing range is between 1120-1180 ℃.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201010145245 CN101921136B (en) | 2010-04-13 | 2010-04-13 | Raw material matting glaze |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 201010145245 CN101921136B (en) | 2010-04-13 | 2010-04-13 | Raw material matting glaze |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101921136A true CN101921136A (en) | 2010-12-22 |
CN101921136B CN101921136B (en) | 2013-01-02 |
Family
ID=43336382
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 201010145245 Expired - Fee Related CN101921136B (en) | 2010-04-13 | 2010-04-13 | Raw material matting glaze |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101921136B (en) |
Cited By (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102503576A (en) * | 2011-11-02 | 2012-06-20 | 广东博德精工建材有限公司 | Method for producing base coat being matched with blank and having excellent glazing effect |
CN102515774A (en) * | 2011-11-02 | 2012-06-27 | 广东博德精工建材有限公司 | Method for producing transparent glass and overglazed color ceramic sandwich by single firing |
CN102531679A (en) * | 2011-11-21 | 2012-07-04 | 佛山市百田建材实业有限公司 | Novel glaze and manufacture process thereof |
CN102701792A (en) * | 2012-06-19 | 2012-10-03 | 卡罗比亚釉料(昆山)有限公司 | Black glaze for preparing ceramic |
CN102718471A (en) * | 2012-05-31 | 2012-10-10 | 福建省德化县锦福陶瓷有限公司 | Green body of red soil ceramic and formula of transmutation glaze of red soil ceramic |
CN102976796A (en) * | 2012-12-21 | 2013-03-20 | 广东顺祥陶瓷有限公司 | Household porcelain glaze with far infrared ray function and preparation method of household porcelain glaze |
CN103224736A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Matte glaze ink for ceramic jet printing and preparation method thereof |
CN103304272A (en) * | 2013-06-08 | 2013-09-18 | 浙江工业大学之江学院工业研究院 | Matt green glaze and firing method |
CN103910538A (en) * | 2014-04-04 | 2014-07-09 | 辉煌水暖集团有限公司 | Matte glaze for ceramics |
CN103922806A (en) * | 2014-04-03 | 2014-07-16 | 安徽溢彩玻璃器皿有限公司 | Ceramic wine bottle colored glaze and glaze spraying method |
CN104945018A (en) * | 2014-12-23 | 2015-09-30 | 广西师范学院 | Earthy yellow raw glaze special for Nixing ceramics |
CN105315016A (en) * | 2014-12-23 | 2016-02-10 | 广西师范学院 | Transparent raw glaze special for nixing pottery |
CN106116150A (en) * | 2016-06-30 | 2016-11-16 | 安徽省德邦瓷业有限公司 | A kind of ceramic glaze and preparation method thereof |
CN106698940A (en) * | 2016-11-15 | 2017-05-24 | 广东荣高陶瓷有限公司 | Subdued light glaze of subdued light archaized brick and use method of subdued light glaze |
CN107226619A (en) * | 2017-06-02 | 2017-10-03 | 佛山石湾华鹏陶瓷有限公司 | A kind of acidproof Buddha's warrior attendant glaze and preparation method, acidproof Buddha's warrior attendant glaze Ceramic Tiles preparation method |
CN107417117A (en) * | 2017-05-09 | 2017-12-01 | 东莞市唯美陶瓷工业园有限公司 | A kind of ceramic glaze and preparation method thereof |
CN107586023A (en) * | 2017-10-18 | 2018-01-16 | 禹州市锦丰源瓷业有限公司 | A kind of high rigidity matt yellowish pea green glaze and preparation method thereof |
CN107601875A (en) * | 2017-10-18 | 2018-01-19 | 禹州市锦丰源瓷业有限公司 | A kind of high rigidity matt celeste glaze and preparation method thereof |
CN108033682A (en) * | 2017-12-08 | 2018-05-15 | 惠达卫浴股份有限公司 | The sheen glaze and glaze noodle producing method of glazed tile |
CN108178514A (en) * | 2018-01-19 | 2018-06-19 | 佛山科学技术学院 | A kind of building ceramic tiles gentle eye protection matting glaze and its preparation process |
CN108218236A (en) * | 2016-12-22 | 2018-06-29 | Toto株式会社 | Dumb light formula surface structural body |
CN108383382A (en) * | 2018-03-04 | 2018-08-10 | 邢映明 | A kind of ultrawhite brilliant glossy glaze and preparation method thereof |
CN108455857A (en) * | 2018-01-19 | 2018-08-28 | 佛山科学技术学院 | A kind of gentle glaze of sanitary ceramic ware sheen and its preparation process |
CN108545939A (en) * | 2018-05-11 | 2018-09-18 | 河南城建学院 | A kind of purplish blue matt glaze and preparation method thereof, purplish blue Sub-shine glaze and preparation method thereof |
CN108558442A (en) * | 2018-06-20 | 2018-09-21 | 东莞市唯美陶瓷工业园有限公司 | A kind of satin glaze and its preparation method and application |
CN108751962A (en) * | 2018-06-27 | 2018-11-06 | 福建省德化县陶缘茗陶瓷文化有限公司 | A kind of white jade porcelain pot and preparation method thereof for rotation of soaring aloft |
CN109250914A (en) * | 2018-11-13 | 2019-01-22 | 广东三水大鸿制釉有限公司 | A kind of glaze and preparation method and ceramic tile having silk glazing effect for ceramic tile surface |
CN109504179A (en) * | 2018-10-31 | 2019-03-22 | 佛山市色千新材料有限公司 | A kind of matte effect ink and preparation method thereof for Ceramic glaze |
CN109928778A (en) * | 2019-04-24 | 2019-06-25 | 佛山市东鹏陶瓷有限公司 | A kind of antifouling glaze of dumb light and glaze slip preparation method, Ceramic Tiles and preparation method |
CN109970343A (en) * | 2019-04-24 | 2019-07-05 | 佛山市东鹏陶瓷有限公司 | A kind of antifouling dry granular glaze of dumb light and glaze slip preparation method, ceramic tile and preparation method |
CN110885189A (en) * | 2019-11-13 | 2020-03-17 | 蒙娜丽莎集团股份有限公司 | Zirconium-free mutton tallow glaze and positioning crystal pattern ceramic tile prepared from same |
CN111233329A (en) * | 2020-02-21 | 2020-06-05 | 湖南省醴陵市湘强陶瓷制造有限公司 | Matte transmutation glaze and preparation method thereof |
CN111548016A (en) * | 2020-05-20 | 2020-08-18 | 蒙娜丽莎集团股份有限公司 | Matt protection glaze with glossiness of below 3 degrees for thin ceramic tile, thin ceramic tile and preparation method thereof |
CN112225454A (en) * | 2020-09-30 | 2021-01-15 | 广东清远蒙娜丽莎建陶有限公司 | Low-glossiness high-stain-resistance composite glaze, granite ceramic tile using composite glaze and preparation method of granite ceramic tile |
CN113511922A (en) * | 2021-08-04 | 2021-10-19 | 佛山东鹏洁具股份有限公司 | Matte glaze for sanitary ceramics and preparation method of sanitary ceramics |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101177353A (en) * | 2006-11-10 | 2008-05-14 | 霍炳祥 | Matt glaze and method for manufacturing same |
CN101585717A (en) * | 2009-06-22 | 2009-11-25 | 张垠 | Lead and cadmium free fritted glaze for bone China with high acid resistance and alkali resistance |
-
2010
- 2010-04-13 CN CN 201010145245 patent/CN101921136B/en not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101177353A (en) * | 2006-11-10 | 2008-05-14 | 霍炳祥 | Matt glaze and method for manufacturing same |
CN101585717A (en) * | 2009-06-22 | 2009-11-25 | 张垠 | Lead and cadmium free fritted glaze for bone China with high acid resistance and alkali resistance |
Non-Patent Citations (1)
Title |
---|
《大众科技》 20080331 苏继承 高档陶艺哑光釉的研制 77-78 1-6 , 第3期 * |
Cited By (51)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102515774B (en) * | 2011-11-02 | 2014-04-09 | 广东博德精工建材有限公司 | Method for producing transparent glass and overglazed color ceramic sandwich by single firing |
CN102515774A (en) * | 2011-11-02 | 2012-06-27 | 广东博德精工建材有限公司 | Method for producing transparent glass and overglazed color ceramic sandwich by single firing |
CN102503576A (en) * | 2011-11-02 | 2012-06-20 | 广东博德精工建材有限公司 | Method for producing base coat being matched with blank and having excellent glazing effect |
CN102531679A (en) * | 2011-11-21 | 2012-07-04 | 佛山市百田建材实业有限公司 | Novel glaze and manufacture process thereof |
CN102718471A (en) * | 2012-05-31 | 2012-10-10 | 福建省德化县锦福陶瓷有限公司 | Green body of red soil ceramic and formula of transmutation glaze of red soil ceramic |
CN102701792A (en) * | 2012-06-19 | 2012-10-03 | 卡罗比亚釉料(昆山)有限公司 | Black glaze for preparing ceramic |
CN102701792B (en) * | 2012-06-19 | 2014-02-05 | 卡罗比亚釉料(昆山)有限公司 | Black glaze for preparing ceramic |
CN102976796A (en) * | 2012-12-21 | 2013-03-20 | 广东顺祥陶瓷有限公司 | Household porcelain glaze with far infrared ray function and preparation method of household porcelain glaze |
CN103224736A (en) * | 2013-04-08 | 2013-07-31 | 佛山市道氏科技有限公司 | Matte glaze ink for ceramic jet printing and preparation method thereof |
CN103304272A (en) * | 2013-06-08 | 2013-09-18 | 浙江工业大学之江学院工业研究院 | Matt green glaze and firing method |
CN103304272B (en) * | 2013-06-08 | 2015-04-22 | 浙江工业大学之江学院工业研究院 | Matt green glaze and firing method |
CN103922806A (en) * | 2014-04-03 | 2014-07-16 | 安徽溢彩玻璃器皿有限公司 | Ceramic wine bottle colored glaze and glaze spraying method |
CN103922806B (en) * | 2014-04-03 | 2015-08-05 | 安徽溢彩玻璃器皿有限公司 | Ceramic wine bottle colored glaze and glaze spraying method |
CN103910538A (en) * | 2014-04-04 | 2014-07-09 | 辉煌水暖集团有限公司 | Matte glaze for ceramics |
CN104945018A (en) * | 2014-12-23 | 2015-09-30 | 广西师范学院 | Earthy yellow raw glaze special for Nixing ceramics |
CN105315016A (en) * | 2014-12-23 | 2016-02-10 | 广西师范学院 | Transparent raw glaze special for nixing pottery |
CN104945018B (en) * | 2014-12-23 | 2019-01-15 | 广西师范学院 | A kind of dedicated khaki raw glaze of Nixing pottery |
CN105315016B (en) * | 2014-12-23 | 2019-01-15 | 广西师范学院 | A kind of Nixing pottery dedicated transparent raw glaze |
CN106116150A (en) * | 2016-06-30 | 2016-11-16 | 安徽省德邦瓷业有限公司 | A kind of ceramic glaze and preparation method thereof |
CN106698940A (en) * | 2016-11-15 | 2017-05-24 | 广东荣高陶瓷有限公司 | Subdued light glaze of subdued light archaized brick and use method of subdued light glaze |
CN108218236A (en) * | 2016-12-22 | 2018-06-29 | Toto株式会社 | Dumb light formula surface structural body |
CN108218236B (en) * | 2016-12-22 | 2021-04-06 | Toto株式会社 | Matte surface structure |
CN107417117A (en) * | 2017-05-09 | 2017-12-01 | 东莞市唯美陶瓷工业园有限公司 | A kind of ceramic glaze and preparation method thereof |
CN107417117B (en) * | 2017-05-09 | 2020-08-18 | 东莞市唯美陶瓷工业园有限公司 | Ceramic glaze and preparation method thereof |
CN107226619A (en) * | 2017-06-02 | 2017-10-03 | 佛山石湾华鹏陶瓷有限公司 | A kind of acidproof Buddha's warrior attendant glaze and preparation method, acidproof Buddha's warrior attendant glaze Ceramic Tiles preparation method |
CN107601875A (en) * | 2017-10-18 | 2018-01-19 | 禹州市锦丰源瓷业有限公司 | A kind of high rigidity matt celeste glaze and preparation method thereof |
CN107586023A (en) * | 2017-10-18 | 2018-01-16 | 禹州市锦丰源瓷业有限公司 | A kind of high rigidity matt yellowish pea green glaze and preparation method thereof |
CN108033682A (en) * | 2017-12-08 | 2018-05-15 | 惠达卫浴股份有限公司 | The sheen glaze and glaze noodle producing method of glazed tile |
CN108178514A (en) * | 2018-01-19 | 2018-06-19 | 佛山科学技术学院 | A kind of building ceramic tiles gentle eye protection matting glaze and its preparation process |
CN108455857A (en) * | 2018-01-19 | 2018-08-28 | 佛山科学技术学院 | A kind of gentle glaze of sanitary ceramic ware sheen and its preparation process |
CN108455857B (en) * | 2018-01-19 | 2020-11-27 | 佛山科学技术学院 | Soft and warm moist glaze for sanitary ceramic sanitary ware and preparation process thereof |
CN108383382B (en) * | 2018-03-04 | 2021-05-14 | 陕西火凤凰艺术陶瓷有限责任公司 | Ultra-white high-gloss glaze and preparation method thereof |
CN108383382A (en) * | 2018-03-04 | 2018-08-10 | 邢映明 | A kind of ultrawhite brilliant glossy glaze and preparation method thereof |
CN108545939A (en) * | 2018-05-11 | 2018-09-18 | 河南城建学院 | A kind of purplish blue matt glaze and preparation method thereof, purplish blue Sub-shine glaze and preparation method thereof |
CN108558442A (en) * | 2018-06-20 | 2018-09-21 | 东莞市唯美陶瓷工业园有限公司 | A kind of satin glaze and its preparation method and application |
CN108751962A (en) * | 2018-06-27 | 2018-11-06 | 福建省德化县陶缘茗陶瓷文化有限公司 | A kind of white jade porcelain pot and preparation method thereof for rotation of soaring aloft |
CN109504179A (en) * | 2018-10-31 | 2019-03-22 | 佛山市色千新材料有限公司 | A kind of matte effect ink and preparation method thereof for Ceramic glaze |
CN109504179B (en) * | 2018-10-31 | 2021-10-26 | 广东道氏技术股份有限公司 | Matte effect printing ink for ceramic glaze and preparation method thereof |
CN109250914A (en) * | 2018-11-13 | 2019-01-22 | 广东三水大鸿制釉有限公司 | A kind of glaze and preparation method and ceramic tile having silk glazing effect for ceramic tile surface |
CN109928778A (en) * | 2019-04-24 | 2019-06-25 | 佛山市东鹏陶瓷有限公司 | A kind of antifouling glaze of dumb light and glaze slip preparation method, Ceramic Tiles and preparation method |
CN109970343A (en) * | 2019-04-24 | 2019-07-05 | 佛山市东鹏陶瓷有限公司 | A kind of antifouling dry granular glaze of dumb light and glaze slip preparation method, ceramic tile and preparation method |
CN109970343B (en) * | 2019-04-24 | 2021-11-02 | 佛山市东鹏陶瓷有限公司 | Matte antifouling dry-particle glaze and glaze slip preparation method, ceramic tile and preparation method |
CN109928778B (en) * | 2019-04-24 | 2021-11-30 | 佛山市东鹏陶瓷有限公司 | Matte antifouling glaze, glaze slurry preparation method, ceramic tile and preparation method |
CN110885189A (en) * | 2019-11-13 | 2020-03-17 | 蒙娜丽莎集团股份有限公司 | Zirconium-free mutton tallow glaze and positioning crystal pattern ceramic tile prepared from same |
CN110885189B (en) * | 2019-11-13 | 2021-12-03 | 蒙娜丽莎集团股份有限公司 | Zirconium-free mutton tallow glaze and positioning crystal pattern ceramic tile prepared from same |
CN111233329A (en) * | 2020-02-21 | 2020-06-05 | 湖南省醴陵市湘强陶瓷制造有限公司 | Matte transmutation glaze and preparation method thereof |
CN111548016A (en) * | 2020-05-20 | 2020-08-18 | 蒙娜丽莎集团股份有限公司 | Matt protection glaze with glossiness of below 3 degrees for thin ceramic tile, thin ceramic tile and preparation method thereof |
CN111548016B (en) * | 2020-05-20 | 2022-02-11 | 蒙娜丽莎集团股份有限公司 | Matt protection glaze with glossiness of below 3 degrees for thin ceramic tile, thin ceramic tile and preparation method thereof |
CN112225454A (en) * | 2020-09-30 | 2021-01-15 | 广东清远蒙娜丽莎建陶有限公司 | Low-glossiness high-stain-resistance composite glaze, granite ceramic tile using composite glaze and preparation method of granite ceramic tile |
CN113511922A (en) * | 2021-08-04 | 2021-10-19 | 佛山东鹏洁具股份有限公司 | Matte glaze for sanitary ceramics and preparation method of sanitary ceramics |
CN113511922B (en) * | 2021-08-04 | 2023-06-13 | 江西东鹏卫浴有限公司 | Matte glaze for sanitary ceramic and preparation method of sanitary ceramic |
Also Published As
Publication number | Publication date |
---|---|
CN101921136B (en) | 2013-01-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101921136B (en) | Raw material matting glaze | |
CN1765836B (en) | Ceramic glaze with metal sense of reality | |
CN104529553B (en) | The surface of manufacturing with ceramic refuse is as glazed tile and the preparation of broken brill sand flicker starlight | |
CN108129027B (en) | Devitrified glazed tile with surface having golden star stone effect, base glaze and preparation method thereof | |
CN109049300B (en) | Negative ion carved brick and preparation method thereof | |
CN114735935B (en) | 5-degree low-light diffuse reflection ceramic rock plate and preparation method thereof | |
CN101898887B (en) | Semitransparent ceramic material, imitation jadeite ceramic sheet and preparation method thereof | |
CN107555790B (en) | Production process of 16-degree matte marble tile | |
CN102020461B (en) | High-temperature bright red ceramic and preparation method thereof | |
CN1887811A (en) | Glaze material for surface of ceramic tile | |
CN101659567A (en) | Furnace transmutation decoration glazed brick and production technology | |
CN111732453B (en) | Ceramic tile with metallic luster decorative effect and preparation method thereof | |
CN102731169A (en) | Fully glazed ceramic chip and preparation method thereof | |
CN102249739A (en) | Preparation method of carbon-golden metallic luster crystalline glaze | |
CN102674899A (en) | Production method of matte underglazed color polished and glazed bricks | |
CN102001864A (en) | Heat-resistant porcelain glaze | |
CN106699146A (en) | Semi-polished ceramic glazed tile having fluorescent effect and manufacturing method thereof | |
CN102491791A (en) | Antique matte glaze with delicate texture and using method thereof | |
CN102503583A (en) | Preparation method of bright red glaze bone china | |
CN107098588A (en) | A kind of transparent glass-ceramics glaze and its preparation method and application | |
CN101898891A (en) | Semi-transparency ceramic material, ceramic sheet and preparation method thereof | |
CN111995382A (en) | Mutton tallow jade ceramic tile and preparation method thereof | |
CN111204979A (en) | Ivory white ceramic glaze with self-cleaning function and preparation method thereof | |
CN110342820A (en) | A kind of manufacturing method of copper system furnace transmutation glaze | |
CN107601880A (en) | A kind of ceramic opaque glaze and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130102 Termination date: 20150413 |
|
EXPY | Termination of patent right or utility model |