CN108558442A - A kind of satin glaze and its preparation method and application - Google Patents
A kind of satin glaze and its preparation method and application Download PDFInfo
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- CN108558442A CN108558442A CN201810634622.8A CN201810634622A CN108558442A CN 108558442 A CN108558442 A CN 108558442A CN 201810634622 A CN201810634622 A CN 201810634622A CN 108558442 A CN108558442 A CN 108558442A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a kind of satin glazes and its preparation method and application, wherein according to mass parts meter, the glaze formula of the satin glaze includes：5 ~ 10 parts of barium carbonate, 40 ~ 50 parts of albite, burns 0.1 ~ 5 part of 5 ~ 10 parts of talcum, 10 ~ 20 parts of calcium carbonate, 5 ~ 15 parts of aluminium hydroxide, 5 ~ 10 parts of kaolin, 5 ~ 15 parts of titanium dioxide and additive at 5 ~ 10 parts of zirconium silicate.The present invention is by being added the substances such as titanium dioxide, so that a large amount of high rigidity crystal is precipitated in the chemical constituent of the satin glaze after high temperature firing, the overglaze surface Mohs' hardness of formation is increased to 5 grades, ensure its smooth, smooth, fine and smooth glazing effect simultaneously, solves the problems, such as that satin glaze glaze quality is softer in the prior art, case hardness is low.
Description
Technical field
The present invention relates to architectural pottery technical fields more particularly to a kind of satin glaze and its preparation method and application.
Background technology
Popular its formula system of satin glaze ceramic product is unglazed using sial as skeleton and with calcium barium magnesium currently on the market
The system of agent is prepared by the process of secondary glazing, i.e., first applies white high temperature ground-coat enamel on green body, then apply matt clear frit
Secondary glazing method, then do Spanish furnish under clear frit or on clear frit.Such surface of ceramic products gloss is at 15 degree
Hereinafter, the smooth exquisiteness of glaze, feel is splendid, and mainly anorthite is precipitated from matt clear frit in the glazing effect of fine and smooth satin glaze
Tiny crystals, part baryta fledspar crystalline phase and talcum crystalline phase and obtain, but this kind of formula system formed glaze Mohs' hardness only have
3-4 grades, the defect that glaze quality is softer, case hardness is low, glaze is extremely easy to wipe flower scuffing after being rubbed by hard object, causes to give birth to
The application range of the ceramic product of production is restricted.
Therefore, the existing technology needs to be improved and developed.
Invention content
In view of above-mentioned deficiencies of the prior art, the purpose of the present invention is to provide a kind of satin glaze and preparation method thereof and answer
With, it is intended to solve the problems, such as that satin glaze glaze quality is softer in the prior art, case hardness is low.
Technical scheme is as follows：
A kind of satin glaze, wherein according to mass parts meter, the glaze formula of the satin glaze includes：5 ~ 10 parts of barium carbonate, zirconium silicate
5 ~ 10 parts, 40 ~ 50 parts of albite, burn 5 ~ 10 parts of talcum, 10 ~ 20 parts of calcium carbonate, 5 ~ 15 parts of aluminium hydroxide, 5 ~ 10 parts of kaolin,
0.1 ~ 5 part of 5 ~ 15 parts of titanium dioxide and additive.
The satin glaze, wherein the additive is sodium tripolyphosphate and carboxymethyl cellulose.
The satin glaze, wherein in parts by mass, the ratio of the sodium tripolyphosphate and carboxymethyl cellulose is 1:1.
A kind of preparation method of satin glaze as described above, wherein including step：
In parts by mass, by 5 ~ 10 parts of barium carbonates, 5 ~ 10 parts of zirconium silicates, 40 ~ 50 parts of albites, 5 ~ 10 parts burn talcums, 10 ~ 20 parts
Calcium carbonate, 5 ~ 15 parts of aluminium hydroxides, 5 ~ 10 parts of kaolin, 5 ~ 15 parts of titanium dioxides and 0.1 ~ 5 part of additive mixing, are added 50 ~ 100
Part distilled water, then carry out ball milling, sieving and aging to get satin glaze.
The preparation method of the satin glaze, wherein the fineness of the ball-milling treatment to glaze slip is 325 mesh screen residue 0.3-
0.4%。
A kind of application of satin glaze as described above, wherein including step：
Ceramic body is provided；
The satin glaze is applied on ceramic body surface, then carries out heating firing processing to get product.
The application of the satin glaze, wherein the firing processing carries out in oxidizing atmosphere environment, firing temperature 1000
~ 1500 DEG C, firing time is 30 ~ 90 minutes.
The application of the satin glaze, wherein the step applies the satin glaze in ceramic body surface, using leaching glaze
Technique glazing.
The application of the satin glaze, wherein the glaze volume is 200 ~ 750g/m2。
The application of the satin glaze, wherein further include step before the step carries out heating firing processing：In satin
Light glaze surface carries out surface color and polish decoration.
Advantageous effect：The present invention provides a kind of satin glaze and preparation method thereof, applications, by the way that the objects such as titanium dioxide are added
Matter so that a large amount of high rigidity crystal is precipitated in the chemical constituent of the satin glaze after high temperature firing, by the overglaze surface of formation
Mohs' hardness is increased to 5 grades, while ensureing its smooth, smooth, fine and smooth glazing effect, solves satin glaze glaze in the prior art
The problem that face quality is softer, case hardness is low.
Specific implementation mode
The present invention provides a kind of satin glaze of high rigidity and its preparation method and application, to make the purpose of the present invention, technology
Scheme and effect are clearer, clear, and the present invention is described in more detail below.It should be appreciated that described herein specific
Embodiment is only used to explain the present invention, is not intended to limit the present invention.
The present invention provides a kind of satin glaze, being suitable for preparing has high rigidity satin glaze Ceramic Tiles, wherein according to mass parts
Meter, the glaze formula of the satin glaze include：5 ~ 10 parts of barium carbonate, 5 ~ 10 parts of zirconium silicate, 40 ~ 50 parts of albite, burning talcum 5 ~
0.1 ~ 5 part of 10 parts, 10 ~ 20 parts of calcium carbonate, 5 ~ 15 parts of aluminium hydroxide, 5 ~ 10 parts of kaolin, 5 ~ 15 parts of titanium dioxide and additive,
In additive can make the satin glaze glaze slip fluid have preferable water-retaining property, inhibition and high temperature resistant and lower temperature resistance,
Conducive to the implementation of follow-up printing technology.Preferably, the additive is sodium tripolyphosphate and carboxymethyl cellulose.More preferably,
In parts by mass, the ratio of the sodium tripolyphosphate and carboxymethyl cellulose is 1:1 so that the water-retaining property of glaze slip fluid inhibits
Property, high temperature resistant and lower temperature resistance it is further preferred that.
Specifically, in parts by mass, the glaze formula chemical constituent of the satin glaze includes：SiO240 ~ 60 parts, Al2O3
15 ~ 30 parts, Fe2O30.1 ~ 1 part, 5 ~ 10 parts of CaO, 1 ~ 5 part of MgO, K20.1 ~ 5 part of O, ZrO21 ~ 10 part, Na2O 1~10
Part, 1 ~ 10 part of BaO, TiO21 ~ 10 part and 0.05 ~ 2.5 part of sodium tripolyphosphate and 0.05 ~ 2.5 part of carboxymethyl cellulose.
In addition, in parts by mass, in above-mentioned glaze formula, sial quality compares range：SiO2/Al2O3=2.50 ~ 3.00,
CaO content range：6% ~ 10%, TiO2Content range：3%~20%.
It is higher can to generate a large amount of hardness in high temperature firing by introducing the novel substances such as titanium dioxide for above-mentioned glaze formula
Perovskite crystalline phase, aspidelite, anatase phase and rutile phase, ensure that product glaze Mohs' hardness be not less than 5 grades；And
And when using the glaze slip of satin glaze provided by the present invention, above-mentioned crystal and glass phase refractive index difference are larger, have risen preferably
Opaque effect, it is only necessary to glazing can once complete glaze manufacturing process, there is no need to apply primary white ground-coat enamel more, without
As original technique, first applies primary white ground-coat enamel and apply primary transparent overglaze again, simplify technological process, reduce defect
The possibility of generation.Meanwhile by adjusting silica alumina ratio, calcium content and the Ti content in formula, product glaze is set to obtain fine and smooth, flat
The effect of sliding texture and matt.
A kind of preparation method of satin glaze as described above, wherein including step：
In parts by mass, by 5 ~ 10 parts of barium carbonates, 5 ~ 10 parts of zirconium silicates, 40 ~ 50 parts of albites, 5 ~ 10 parts burn talcums, 10 ~ 20 parts
Calcium carbonate, 5 ~ 15 parts of aluminium hydroxides, 5 ~ 10 parts of kaolin, 5 ~ 15 parts of titanium dioxides and 0.1 ~ 5 part of additive mixing, are added 50 ~ 100
Part distilled water, then carry out ball milling, sieving and aging to get satin glaze.The satin glaze material that this method obtains is applied suitable for glaze pouring
Glaze.
Preferably, in the preparation method of the satin glaze, during the ball-milling treatment, in parts by mass, ball：It is former
Material：Water=1:1.5:0.7, and be milled to glaze slip fineness be 325 mesh screen residue 0.3-0.4%, then carry out blowing, it is aging to get
Product satin glaze.It is particularly preferred that the aging time should be greater than for 24 hours.
The present invention also provides another preparation methods of satin glaze, wherein including step：In parts by mass, by 5 ~ 10
Part barium carbonate, 5 ~ 10 parts of zirconium silicates, 40 ~ 50 parts of albites, 5 ~ 10 parts of burning talcums, 10 ~ 20 parts of calcium carbonate, 5 ~ 15 parts of hydroxides
Aluminium, 5 ~ 10 parts of kaolin, 5 ~ 15 parts of titanium dioxides and the mixing of 0.1 ~ 5 part of additive, are added 50 ~ 100 parts of stamp-pad ink, then carry out ball milling,
It is sieved and aging to get satin glaze.The satin glaze material that this method obtains is suitable for rubber roller or lithography process glazing.
The present invention also provides a kind of applications of satin glaze as described above, wherein including step：
S1, ceramic body is provided；
S2, the satin glaze is applied on ceramic body surface, then carries out heating firing processing to get product.
It in the step S1, is dried ceramic body compression moulding and in roller kilns, preferably, the roller kilns
Interior maximum temperature be 160 DEG C, arid cycle be 30 ~ 90 minutes, for example, 58 minutes, and the temperature of kiln discharge adobe be 80 ~ 100
DEG C, the ceramic body enabled to is easier to satin glaze and is applied in surface.
In the step S2, the satin glaze is applied in by ceramic body surface using glaze pouring, then passes through high temperature
Firing is to get to the ceramic product of the satin glaze glaze of high rigidity, and specifically, the ceramic body can be ceramic adobe.
In the step S2, the glaze volume when satin glaze to be applied in ceramic body surface is with 200 ~ 750g/m2For
It is good, dissolve each other symbiosis and the presence of compression between crystal can be coped with, effectively provides hardness of glaze surface, and convenient for being dried to
Type.
Preferably, in the step S2, firing processing carries out in oxidizing atmosphere environment, and firing temperature is 1000 ~ 1500
DEG C, firing time is 30 ~ 90 minutes.
The application of the satin glaze, wherein further include step before the step carries out heating firing processing：In satin
Light glaze surface carries out surface color and polish decoration.By carrying out Spanish furnish on satin glaze surface, pattern with different color can be obtained
Satin glaze ceramic product.
Below by embodiment, the invention will be further described：
Embodiment 1
In parts by mass, 7 parts of barium carbonates, 7 parts of zirconium silicates, 46 parts of albites, 7 parts are burnt into talcum, 12 parts of calcium carbonate, 9 parts of hydrogen-oxygens
Change aluminium, 7 parts of kaolin, 5 parts of titanium dioxides and 0.3 part of sodium tripolyphosphate and 0.3 part of carboxymethyl cellulose, 70 parts of water are added in mixing,
It counts in mass ratio again, ball：Material：Water=1:1.5:0.7 ratio carries out the fineness for being milled to glaze slip：325 mesh screen residues 0.3% ~ 0.4%,
Then aging 24 hours to get satin glaze.
By glaze pouring it is 1.75g/mL by proportion by satin glaze material that this method obtains, glaze volume 500g/m2's
Standard is applied on Ceramic Tiles green body, and then sample is put into kiln and is burnt into 58 minutes at a temperature of 1230 DEG C, it is hard to obtain Mohs
The high rigidity satin glaze ceramics brick product that degree is 6.
Embodiment 2
In parts by mass, 6 parts of barium carbonates, 6 parts of zirconium silicates, 46 parts of albites, 6 parts are burnt into talcum, 12 parts of calcium carbonate, 9 parts of hydrogen-oxygens
Change aluminium, 6 parts of kaolin, 9 parts of titanium dioxides and 0.3 part of sodium tripolyphosphate and 0.3 part of carboxymethyl cellulose, 70 parts of water are added in mixing,
It counts in mass ratio again, ball：Material：Water=1:1.5:0.7 ratio carries out the fineness for being milled to glaze slip：325 mesh screen residues 0.3% ~ 0.4%,
Then aging 24 hours to get satin glaze.
By glaze pouring it is 1.75g/mL by proportion by satin glaze material that this method obtains, glaze volume 500g/m2's
Standard is applied on Ceramic Tiles green body, and then sample is put into kiln and is burnt into 58 minutes at a temperature of 1230 DEG C, it is hard to obtain Mohs
The high rigidity satin glaze ceramics brick product that degree is 6.
Embodiment 3
In parts by mass, 7 parts of barium carbonates, 7 parts of zirconium silicates, 46 parts of albites, 7 parts are burnt into talcum, 12 parts of calcium carbonate, 9 parts of hydrogen-oxygens
Change aluminium, 7 parts of kaolin, 5 parts of titanium dioxides and 0.3 part of sodium tripolyphosphate and 0.3 part of carboxymethyl cellulose, 70 parts of prints are added in mixing
Oil, then count in mass ratio, ball：Material：Stamp-pad ink=1:1.5:0.7 ratio carries out the fineness for being milled to glaze slip：325 mesh screen residues 0%, so
Aging 24 hours to get satin glaze afterwards.
The satin glaze material that this method is obtained by rubber roller or the technique of offset printing by proportion be 1.50 ~ 1.70g/mL,
Glaze volume is 500g/m2Standard apply on Ceramic Tiles green body, then sample is put into kiln and is burnt at a temperature of 1230 DEG C
58 minutes, obtain the high rigidity satin glaze ceramics brick product that Mohs' hardness is 5.
In conclusion satin glaze provided by the invention and preparation method thereof, application are made by the way that the substances such as titanium dioxide are added
A large amount of high rigidity crystal is precipitated in the chemical constituent for obtaining the satin glaze after high temperature firing, and the overglaze surface Mohs of formation is hard
Degree is increased to 5 grades, while ensureing its smooth, smooth, fine and smooth glazing effect, solves satin glaze glaze quality in the prior art
Problem softer, case hardness is low.
It should be understood that the application of the present invention is not limited to the above for those of ordinary skills can
With improvement or transformation based on the above description, all these modifications and variations should all belong to the guarantor of appended claims of the present invention
Protect range.
Claims (10)
1. a kind of satin glaze, which is characterized in that according to mass parts meter, the glaze formula of the satin glaze includes：Barium carbonate 5 ~ 10
Part, burns 5 ~ 10 parts of talcum, 10 ~ 20 parts of calcium carbonate, 5 ~ 15 parts of aluminium hydroxide, kaolinite at 5 ~ 10 parts of zirconium silicate, 40 ~ 50 parts of albite
0.1 ~ 5 part of 5 ~ 10 parts of soil, 5 ~ 15 parts of titanium dioxide and additive.
2. satin glaze according to claim 1, which is characterized in that the additive is sodium tripolyphosphate and carboxymethyl cellulose
Element.
3. satin glaze according to claim 2, which is characterized in that in parts by mass, the sodium tripolyphosphate and carboxymethyl
The ratio of cellulose is 1:1.
4. a kind of preparation method of satin glaze as described in claim 1 ~ 3 is any, which is characterized in that including step：
In parts by mass, by 5 ~ 10 parts of barium carbonates, 5 ~ 10 parts of zirconium silicates, 40 ~ 50 parts of albites, 5 ~ 10 parts burn talcums, 10 ~ 20 parts
Calcium carbonate, 5 ~ 15 parts of aluminium hydroxides, 5 ~ 10 parts of kaolin, 5 ~ 15 parts of titanium dioxides and 0.1 ~ 5 part of additive mixing, are added 50 ~ 100
Part distilled water, then carry out ball milling, sieving and aging to get satin glaze.
5. the preparation method of satin glaze according to claim 4, which is characterized in that the fineness of the ball-milling treatment to glaze slip
For 325 mesh screen residue 0.3-0.4%.
6. a kind of application of satin glaze as described in claim 1 ~ 3 is any, which is characterized in that including step：
Ceramic body is provided；
The satin glaze is applied on ceramic body surface, then carries out heating firing processing to get product.
7. the application of satin glaze according to claim 6, which is characterized in that firing processing in oxidizing atmosphere environment into
Row, firing temperature are 1000 ~ 1500 DEG C, and firing time is 30 ~ 90 minutes.
8. the application of satin glaze according to claim 6, which is characterized in that the step applies the satin glaze in ceramic blank
In body surface face, using glaze pouring glazing.
9. the application of satin glaze according to claim 8, which is characterized in that the glaze volume is 200 ~ 750g/m2。
10. the application of satin glaze according to claim 6, which is characterized in that carry out heating firing processing in the step
Before, further include step：Surface color and polish decoration is carried out on satin glaze surface.
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| CN201810634622.8A CN108558442A (en) | 2018-06-20 | 2018-06-20 | A kind of satin glaze and its preparation method and application |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109336390A (en) * | 2018-12-15 | 2019-02-15 | 醴陵陶润实业发展有限公司 | White is unglazed crystal glaze and its preparation process |
| CN113912294A (en) * | 2021-10-22 | 2022-01-11 | 广东清远蒙娜丽莎建陶有限公司 | Satin glaze, satin glazed tile and preparation method thereof |
| CN116986815A (en) * | 2023-08-25 | 2023-11-03 | 高安常莹新型材料有限公司 | Surface glaze with good color development, preparation method thereof and glazed tile |
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| CN109336390A (en) * | 2018-12-15 | 2019-02-15 | 醴陵陶润实业发展有限公司 | White is unglazed crystal glaze and its preparation process |
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| CN116986815B (en) * | 2023-08-25 | 2024-02-13 | 高安常莹新型材料有限公司 | Surface glaze with good color development, preparation method thereof and glazed tile |
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