CN1765836B - Ceramic glaze with metal sense of reality - Google Patents

Ceramic glaze with metal sense of reality Download PDF

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Publication number
CN1765836B
CN1765836B CN 200510037052 CN200510037052A CN1765836B CN 1765836 B CN1765836 B CN 1765836B CN 200510037052 CN200510037052 CN 200510037052 CN 200510037052 A CN200510037052 A CN 200510037052A CN 1765836 B CN1765836 B CN 1765836B
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CN
China
Prior art keywords
glaze
screen printing
ceramic
product
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN 200510037052
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Chinese (zh)
Other versions
CN1765836A (en
Inventor
毛海燕
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Individual
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN 200510037052 priority Critical patent/CN1765836B/en
Publication of CN1765836A publication Critical patent/CN1765836A/en
Application granted granted Critical
Publication of CN1765836B publication Critical patent/CN1765836B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/062—Glass compositions containing silica with less than 40% silica by weight
    • C03C3/07—Glass compositions containing silica with less than 40% silica by weight containing lead
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/062—Glass compositions containing silica with less than 40% silica by weight
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/097—Glass compositions containing silica with 40% to 90% silica, by weight containing phosphorus, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/102—Glass compositions containing silica with 40% to 90% silica, by weight containing lead
    • C03C3/105—Glass compositions containing silica with 40% to 90% silica, by weight containing lead containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses a ceramic glaze with metal texture effect, which comprises the basic metal surface glaze and the cover-printing glaze, both with constituents as: SiO2 5-60%, Al2O33-50%, P2O5 3-50%, CaO 0.5-20%, Fe2O3 0-50%, Na2O 0-30%, ZrO2 0-50%, BaO 0-50%, PbO 0-30%, and ZnO 0-30%. Wherein, the said glazes can has same or different said constituents. The product has various color, well quality, strong mechanical properties and high stability.

Description

A kind of ceramic glaze preparation method with metal-like
Technical field
The present invention relates to the technical field of ceramic production technology and products innovation, the glaze that a kind of pottery is used specifically relates to have the using method of the glaze preparation pottery of metal-like effect.
Background technology
The existing ceramic product that possesses technology content, it generally all is to adopt ceramic glaze to modify processing on the surface, and metal glaze belongs to more special product, except that presenting at surface energy the different metal gloss, the printing of can arranging in pairs or groups shows other and plants the style product, as series modelled after an antique, effects such as imitative stone material make ceramic tile effect field more colourful.For considering that this product can be in the general usefulness of production line, convenience is simple and easy again, does not need to put before interpolation equipment, and the production line of selecting present brick modelled after an antique and vitreous brick is main, and can produce in simple glazing mode is principle, with regard to positive metal-lustrous glaze of this emulation thereby birth.Though also the someone imagined the glaze of multiple function, as luminescent glaze, application number 99123083, the applying date are that December 15, denomination of invention in 1999 are the patent application of luminescent glaze, and this light-accumulating luminescent glaze is made up of different kinds of ions activated long after glow luminous material and basic flux.The weight ratio of long after glow luminous material and basic flux is: 45-2% can make luminescent ceramic, luminescent enamel and fluorescent glass goods than 55-98% with this luminescent glaze, has illumination effect, but can't embody the effect of metal-like equally.
Summary of the invention
The objective of the invention is to products innovation, increase existing ceramic product usability, a kind of market frontier that has is provided, the color variation, glaze quality is good, and mechanical property is strong, the preparation method of the ceramic glaze with metal-like that chemical stability is high.
Ceramic glaze preparation method with metal-like of the present invention is to be made of with covering screen printing glaze two portions underlying metal cover-coat enamel or underlying metal cover-coat enamel, and the component of basis overglaze and covering screen printing glaze is as follows: SiO 25-60% Al 2O 33-50% P 2O 53-50% CaO 0.5-20% Fe 2O 30-50% Na 2O 0-30% ZrO 20-50% BaO 0-50% PbO 0-30% ZnO 0-30%; Basis overglaze and cover screen printing glaze and can adopt identical or different above-mentioned component to prepare wherein sprays the underlying metal cover-coat enamel on the ceramic semi-finished product surface earlier or after covering screen printing glaze again, burns till to get final product.
When above-mentioned preparation, carry out ball milling after adding the CMC of 0.5-1%, increase the glaze viscosity, tail over and be controlled at≤1g/100ml/325mesh.
The present invention adopts the characteristic of above-mentioned prescription to be:
1, product surface has metalluster texture, has decorative effect preferably;
2, basis overglaze that can be by above-mentioned prescription and the collocation that covers screen printing glaze various combination and different ingredients and different deals can constitute multiple different metallic luster such as cuprous look, highlighted iron look, orichalceous, gold look, inferior light platinum look etc.;
3, adopt its glaze quality of product of above-mentioned prescription and technology good, mechanical property is strong, the chemical stability height;
4, the product after the glazing can carry out revenue stamp process equally, makes product more rich and varied; For considering the product usability, wall ground can be shared, so increase printing again at the metal glaze, reaches wear-resisting effect, makes the use field of metal glaze more extensive.
Embodiment
The present invention can be according to the collocation of various combination with different ingredients and different deals, can constitute multiple different metallic luster such as cuprous look, highlighted iron look, orichalceous, gold look, inferior light platinum look etc., below be example with the gold look: with the basis overglaze prescription is SiO 220% Al 2O 317% P 2O 510%CaO 5% Fe 2O 310% Na 2O 20% ZrO 2It is 1.5g/ml that 10% BaO5% PbO, 1% ZnO 2% is deployed into proportion, at 30 * 30cm 2The heavy 30-40g of ceramic tile face glazing.
Again the covering screen printing glaze of same recipe being deployed into proportion is 1.5g/ml, at above-mentioned 30 * 30cm 2The heavy 10-20g of ceramic tile face glazing; Burn till and promptly form the gold color and luster.
Above-mentioned covering screen printing glaze also can not need be prepared, and directly executes basis overglaze and burns till and get final product.

Claims (1)

1. glaze with metal-like of a use prepares the method for pottery, it is characterized in that, at first prepares the underlying metal cover-coat enamel and covers screen printing glaze, underlying metal cover-coat enamel and to cover the chemical composition of screen printing glaze as follows: SiO 220%Al 2O 317%P 2O 510%CaO 5%Fe 2O 310%Na 2O20%ZrO 210%BaO5%PbO 1%ZnO 2%; Carry out ball milling after adding the CMC of 0.5-1% again, tail over and be controlled at≤the 1g/100ml/325 order; The underlying metal cover-coat enamel is inserted the ceramic semi-finished product surface, and then coat the covering screen printing glaze, burn till and get final product.
CN 200510037052 2005-09-07 2005-09-07 Ceramic glaze with metal sense of reality Expired - Fee Related CN1765836B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200510037052 CN1765836B (en) 2005-09-07 2005-09-07 Ceramic glaze with metal sense of reality

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200510037052 CN1765836B (en) 2005-09-07 2005-09-07 Ceramic glaze with metal sense of reality

Publications (2)

Publication Number Publication Date
CN1765836A CN1765836A (en) 2006-05-03
CN1765836B true CN1765836B (en) 2010-05-12

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200510037052 Expired - Fee Related CN1765836B (en) 2005-09-07 2005-09-07 Ceramic glaze with metal sense of reality

Country Status (1)

Country Link
CN (1) CN1765836B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101265941B1 (en) * 2010-11-30 2013-05-21 한국세라믹기술원 Manufacturing method of glaze

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101148369B (en) * 2006-09-20 2010-06-23 毛海燕 Glaze material with metal texture for ceramic and ceramic prepared from the same
CN100410197C (en) * 2007-02-02 2008-08-13 南安协进建材有限公司 Method for producing metal enamel
CN101880178B (en) * 2010-07-13 2012-03-28 广东道氏技术股份有限公司 Ceramic glazed tile with gold metal effect and preparation method thereof
CN102515865B (en) * 2011-12-14 2014-02-05 广东长城集团股份有限公司 Glaze with golden luster and preparation method thereof
CN105110643A (en) * 2015-07-24 2015-12-02 福建省德化环宇陶瓷有限公司 Formula for metal glaze with high-gloss copper golden effect, preparation and usage method
CN105440796A (en) * 2015-12-10 2016-03-30 广东道氏技术股份有限公司 Low-temperature metal glaze printing ink for ink-jet printing of ceramics and preparation method thereof
CN105646009B (en) * 2016-02-23 2018-01-09 中国科学院上海硅酸盐研究所 A kind of composite decoration glaze prepared using plant ass as raw material and preparation method thereof
CN110357429A (en) * 2019-08-09 2019-10-22 信益陶瓷(中国)有限公司 A kind of metal-like Imitation Rock Porcelain Tiles and preparation method thereof
CN111499396B (en) * 2020-04-27 2022-04-01 德清诺贝尔陶瓷有限公司 Metal texture porcelain plate with prominent bright/matte contrast
CN111689759A (en) * 2020-06-29 2020-09-22 河北岳如信息科技有限公司 Ceramic product with metallic bronze wear-resistant glaze and preparation method thereof
CN111792844B (en) * 2020-08-11 2022-05-27 鲁山花瓷股份有限公司 Gold glaze material and glazing method thereof
CN115340414B (en) * 2022-10-18 2023-03-24 陶丽西(苏州)陶瓷釉色料有限公司 Metal particle for ceramic tile and preparation method and application thereof

Citations (1)

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US5393714A (en) * 1992-12-30 1995-02-28 Ferro Italia S.R.L. Free-flowing, chemically resistant color granulates, their preparation and use

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5393714A (en) * 1992-12-30 1995-02-28 Ferro Italia S.R.L. Free-flowing, chemically resistant color granulates, their preparation and use

Non-Patent Citations (4)

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刘强.所甲基纤维在釉料中的使用.陶瓷工程 3.2000,(3),32-33.
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李晓池等.金光釉产生金黄色金属光泽的机理研究.西安科技学院学报24 2.2004,24(2),193-195.
李晓池等.金光釉产生金黄色金属光泽的机理研究.西安科技学院学报24 2.2004,24(2),193-195. *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101265941B1 (en) * 2010-11-30 2013-05-21 한국세라믹기술원 Manufacturing method of glaze

Also Published As

Publication number Publication date
CN1765836A (en) 2006-05-03

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C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Assignee: Foshan Mingzhao Technology Development Co., Ltd.

Assignor: Mao Haiyan

Contract record no.: 2012440000281

Denomination of invention: Ceramic glaze with metal sense of reality

Granted publication date: 20100512

License type: Exclusive License

Open date: 20060503

Record date: 20120601

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20100512

Termination date: 20200907