CN101284747A - Organic-inorganic slow-released fertilizer and method for preparing same - Google Patents

Organic-inorganic slow-released fertilizer and method for preparing same Download PDF

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CN101284747A
CN101284747A CNA2008100961696A CN200810096169A CN101284747A CN 101284747 A CN101284747 A CN 101284747A CN A2008100961696 A CNA2008100961696 A CN A2008100961696A CN 200810096169 A CN200810096169 A CN 200810096169A CN 101284747 A CN101284747 A CN 101284747A
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fertilizer
organic
inorganic
compost
slow
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CN101284747B (en
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徐培智
解开治
***
张发宝
唐拴虎
黄旭
杨少海
赵记军
严超
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GUANGDONG AAS SOIL AND FERTILIZER RESEARCH INSTITUTE
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GUANGDONG AAS SOIL AND FERTILIZER RESEARCH INSTITUTE
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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Abstract

The invention discloses a flower organic-inorganic slow-release fertilizer as well as the preparation method thereof. The slow-release fertilizer contains materials by weight percentage as follows: a primary fermentation product 45 to 70 percent, a fertilizer 2 to 35 percent, a conditioner 5 to 30 percent, coating materials 3 to 25 percent, an agglutinant 1 to 10 percent, active materials 0 to 15 percent and a sealant 0 to 12 percent; the primary fermentation product, the fertilizer and the conditioner are mixed for carrying out the secondary fermentation of composting, and then the products of the second fermentation are crushed for press molding; finally, compound fertilizer particles formed by the press molding are evenly sprayed with the coating materials and the agglutinant, thereby obtaining the flower organic-inorganic slow-release fertilizer; the flower organic-inorganic slow-release fertilizer of the invention has the advantages that the nutrition is rich, the composting process is fast, the rotten degree is good, the fertilizer is easy to be absorbed by flowers, the manufacturing process is simple, and the use is convenient.

Description

A kind of flowers organic and inorganic slow-release fertilizer and preparation method thereof
Technical field
The present invention relates to a kind of slow release fertilizer and preparation method thereof, particularly a kind of employed organic and inorganic slow-release fertilizer of floriculture and preparation method thereof that is used for.
Background technology
The fertilising of flowers is an a great problem, except that the demand that satisfies the most basic nitrogen, phosphorus, potassium three elements, also needs the collocation of various trace elements.Will really grasp the flowers fertilising and be not easy, be not that " Guan Ye, long root, result " is so simple.Although general feces of livestock and poultry fertilizer is the most comprehensively one of fertilizer of nutrition, plant is also compared safety, use extremely inconvenience, also unhygienic, be not suitable for the potted plant use of home flower; Secondly soya-bean cake, dish cake, numb cake etc. also are well suited for the ornamental flower use, all will also bother though fertilizer efficiency is good through re-using behind the dilute with water behind the system of fully macerating, the fermentation maturity.Though the chemical fertilizer of being processed into chemical process manufacturing or natural mineral matter has the nutrient content height, instant effect is easy to use, advantages such as sanitation and hygiene, and nutrition is single, and is strict to usage quantity, and general peasant household or family should not grasp.Producing and the use slow release fertilizer, is the most quick, easy, saving of labor, effective behave that can fundamentally solve the flower culture problem of fertilization.China's granted patent 02112384.5 has been announced a kind of organic slow-release fertilizer for soil-less culture, can be used as the fertilizer of using that part does not have native flower culture; China's granted patent 200310121951.6 has been announced the method for utilizing cattle manure to produce organic flowers fertilizers for potted flowers.Though final product also is tasteless, pollution-free and to have an organic fertilizer nutrient comprehensive, protect the characteristics of long-lasting for a long time, the compost cycle is long or become thoroughly decomposed not thoroughly, and processing efficiency is low.And in the practical application of flower culture, still there is the phenomenon of seriously taking off fertilizer a certain vegetative period, the advantage that does not have the organic and inorganic fertilizer combination of well performance to use.
Summary of the invention
The objective of the invention is the defective at above-mentioned prior art, provide a kind of comprehensive nutrition, composting process to accelerate, rotten degree increases, and production technique flowers organic and inorganic slow-release fertilizer simple, easy to use.
Another object of the present invention has provided a kind of method for preparing above-mentioned flowers organic and inorganic slow-release fertilizer.
The technical scheme taked of the present invention is to achieve these goals: a kind of flowers organic and inorganic slow-release fertilizer is provided, and this slow-release fertilizer contains the material of following weight percent:
One time fermentation product 45~70% chemical fertilizer 2~35%
Amendment 5~30% coated fertilizers 3~25%
Tackiness agent 1~10% active substance 0~15%
Sealing agent 0~12%;
Described one time fermentation product is prepared from as follows:
(1) with one or both and inorganic conditioner, organic amendment of cow dung or chicken manure, the promotor uniform mixing becomes thoroughly decomposed, mass ratio according to compost parameter p H 5.5~8.5, carbon nitrogen is 20~38: 1, makes its last composting mixture water ratio reach 40~65%.Its main component is by weight percentage:
Cow dung or chicken manure 55~70%
Inorganic conditioner 15~26%
Organic amendment 12~25%
The promotor 3~18% of becoming thoroughly decomposed
Described inorganic conditioner is at least a in flyash, soda-manufacturing waste residue, ground phosphate rock, the mineral K;
Described organic amendment is at least a in mushroom residue, crop material, dry branches and fallen leaves, wood chip, soy sauce slag, the humic acids;
The described promotor of becoming thoroughly decomposed is at least a in yeast waste liquor, vinasse, molasses, monosodium glutamate waste liquid, the granulated sugar;
(2) last composting mixture is packed into compost reactor is that 1~10: 1000 amount inserts microbial inoculant with microbial inoculant and composting mixture weight ratio; Compost temperature rises to 60 ℃~70 ℃, keeps beginning turning after 48 hours, and when temperature surpasses 70 ℃, turning immediately, uniform and complete is wanted in turning; By stirring and forced ventilation, the oxygen level in the heap body is remained between 5~15%, the temperature in the control compost reactor goes through obtaining the one time fermentation product in 6~13 days at 55~70 ℃;
Described microbial inoculant is one or both in enzymatic microorganism quick rotting agent, fertile soil 100 (VT-100), fertile soil 1000 (VT-1000) microbial inoculum;
Described chemical fertilizer is at least a in potassium primary phosphate, dipotassium hydrogen phosphate, diammonium phosphate, urea, ammonium sulfate, the vitriolate of tartar;
Described amendment is at least a in copper sulfate, zinc sulfate, ferrous sulfate, sal epsom, molybdenum trisulfate, flyash, terra alba, sulphur, meadow soil, xanthohumic acid, ammonium humate, humic acids magnesium, potassium humate, instantly-soluble humic acids, the bone meal;
Described coated fertilizer is two or more in wilkinite, zeolite, polysulfide, acrylic resin, Synolac, the ester gum;
Described tackiness agent is at least a in polyvinyl alcohol, attapulgite, kaolin, the urea-formaldehyde resin aqueous solution;
Described active substance is at least a in sucrose, fructose, glucose, glycine, asparagine ammonia, organized enzyme, the plant growth hormones;
Described sealing agent is at least a in paraffin, pitch, stearic acid, the compound ceresine.
Another technical scheme of the present invention has provided a kind of preparation method of flowers organic and inorganic slow-release fertilizer, comprises the steps:
1) with one time fermentation product, chemical fertilizer and amendment thorough mixing, change the storage bin that adopts hot a heatable brick bed system design over to, make the ground plate temperature remain on 35~50 ℃, carry out the evaporation of the Secondary Fermentation and the moisture of compost, every turning in 2~6 days once, behind the composting 15~20 days, the compost water content obtains tunning for the second time 10~18%; Described fertilizer amount is 80~95% of total consumption;
2) tunning was pulverized 50~210 mesh sieves for the second time, coarse fodder is back to storage bin, add 0~15% active substance, 1~10% tackiness agent and the abundant mixing of residue chemical fertilizer in the fines, in the effect dip mold moulding of tackiness agent, obtain bar-shaped organic-inorganic compound mixed fertilizer particle at last; Described bar-shaped diameter is 0.5cm ± 0.1cm, and long is 2cm~3cm;
3) organic-inorganic compound mixed fertilizer particle qualified after the moulded section is placed on even spraying coated fertilizer in the coating machine, coating is after the room temperature exhausting is dried, and sealing agent seals, and drying makes water content reach 10~15%, sorted and packaged promptly obtains described flowers organic and inorganic slow-release fertilizer.
The present invention compares with close product with prior art, has following advantage:
(1), by using compost reactor, the easier demand that satisfies the compost parameter makes the composting process accelerate, rotten degree is better, has realized innoxious, rapid, the resource utilization of agricultural wastes preferably.
(2), flowers organic and inorganic slow-release fertilizer comprehensive nutrition of the present invention, be easy to absorb, that can satisfy flowers a certain periods needs fertilely in a large number, also can provide the nutrient of whole growing to continue to discharge.
(3) compare with fertilizer with simple composite fertilizer, flowers organic and inorganic slow-release fertilizer of the present invention has the two advantage of composite fertilizer and fertilizer.
(4), flowers organic and inorganic slow-release fertilizer of the present invention adopts coated fertilizers such as polysulfide, has the obvious sterilization anthelminthic effect.
(5), life-time service flowers organic and inorganic of the present invention slow-release fertilizer, the grass cultivation matrix of can fostering and apply fertilizer can improve matrix structure again; Ghost after its nutrient has discharged both can be retained and conserved soil moisture, and can play ventilation again and protect fertile function, can make flower culture matrix become loose.
(6), flowers organic and inorganic slow-release fertilizer preparation method of the present invention is simple, product is easy to use, saving of work and time, result of use are remarkable, has tangible economic benefit, social benefit and ecological benefits.
Description of drawings
Fig. 1 is a process flow diagram of the present invention.
Referring to Fig. 1, (1) is with one or both and inorganic conditioner, organic conditioner of cow dung or chicken manure, the promotion of becoming thoroughly decomposed Agent evenly mixes, and is 20~38: 1 according to the mass ratio of compost parameter p H 5.5~8.5, carbon nitrogen, makes its last composting The mixture moisture content reaches 40~65%.
(2) last composting mixture is packed into compost reactor adds microbial inoculant, again at compost reactor Carry out the fermentation first time, go through and finished one time fermentation in 6~13 days, obtain the one time fermentation product.
(3) chemical fertilizer and the conditioner with one time fermentation product, chemical fertilizer total amount 80~95% fully mixes, and changes storage bin over to, Carry out the evaporation of secondary fermentation and the moisture of compost, every turning in 2~6 days once, composting finished two after 15~20 days Inferior fermentation obtains for the second time tunning;
(4) tunning was pulverized 50~210 mesh sieves for the second time, and coarse fodder is back to storage bin, added in the fines and lived The property material, sticker and residue chemical fertilizer fully mix, last moulded section obtains bar-shaped organic-inorganic compound mixed fertilizer Particle, substandard product reflux and pulverize, sieve, and repeat this step;
(5) with qualified products after the moulded section, the spraying coated fertilizer, with sealant sealing, dry, sorted and packaged, Namely obtain described organic-inorganic slow-released fertilizer product.
Embodiment
The invention will be further described to enumerate specific embodiment below, but not as a limitation of the invention.
Embodiment 1
1, prepares the one time fermentation product as follows: with cow dung, 300kg chicken manure, 200kg flyash, 90kg soy sauce slag, 60kg crop material, the 50kg yeast waste liquor uniform mixing of 300kg, according to compost parameter p H be 6, the mass ratio of carbon nitrogen is 20: 1, makes its last composting mixture water ratio reach 65%; With the last composting mixture compost reactor of packing into, be that 1: 1000 amount inserts the enzymatic microorganism quick rotting agent with enzymatic microorganism quick rotting agent and composting mixture weight ratio; Compost temperature rises to 60 ℃, keeps beginning turning after 48 hours, by stirring and forced ventilation, makes the oxygen level in the heap body remain on 5%, and the temperature in the control compost reactor goes through obtaining the one time fermentation product in 10 days at 60 ℃;
2, with 45kg one time fermentation product, 18.25kg potassium primary phosphate, 15kg diammonium phosphate and 10kg copper sulfate thorough mixing, change the storage bin that adopts hot a heatable brick bed system design over to, make the ground plate temperature remain on 35 ℃, carry out the evaporation of the Secondary Fermentation and the moisture of compost, every turning in 2 days once, behind the composting 15 days, the compost water content is 10%, obtains tunning for the second time;
3, tunning was pulverized 50 mesh sieves for the second time, add 2kg sucrose mixing, coarse fodder is back to storage bin, add 1kg tackiness agent and the abundant mixing of 1.75kg potassium primary phosphate in the fines, last effect dip mold moulding at tackiness agent, obtain bar-shaped organic-inorganic compound mixed fertilizer particle, bar-shaped: diameter is 0.5cm ± 0.1, and long is 2cm;
4, bar-shaped organic-inorganic compound mixed fertilizer particle qualified after the moulded section is placed on even spraying 4kg wilkinite and 4kg zeolite in the coating machine, coating is after the oven dry of room temperature exhausting, make water content reach 15%, sorted and packaged promptly obtains described flowers organic and inorganic slow-release fertilizer.
Embodiment 2
1, prepares the one time fermentation product as follows: with the cow dung of 700kg and 70kg ground phosphate rock, 80kg soda-manufacturing waste residue, 120kg dry branches and fallen leaves, 10kg molasses, 20kg yeast waste liquor uniform mixing, according to compost parameter p H be 5.5, the mass ratio of carbon nitrogen is 25: 1, makes its last composting mixture water ratio reach 40%; With the last composting mixture compost reactor of packing into, be that 1: 500 amount inserts the enzymatic microorganism quick rotting agent with enzymatic microorganism quick rotting agent and composting mixture weight ratio; When compost temperature rises to 65 ℃, keep beginning turning after 48 hours, by stirring and forced ventilation, make the oxygen level in the heap body remain on 15%, the temperature in the control compost reactor goes through obtaining the one time fermentation product in 6 days at 55 ℃;
2, with 50kg one time fermentation product, 1.6kg urea and 6kg terra alba thorough mixing, change the storage bin that adopts hot a heatable brick bed system design over to, make the ground plate temperature remain on 40 ℃, carry out the evaporation of the Secondary Fermentation and the moisture of compost, every turning in 4 days once, behind the composting 18 days, the compost water content is 18%, obtains tunning for the second time;
3, tunning was pulverized 100 mesh sieves for the second time, and coarse fodder is back to storage bin, added 5kg tackiness agent and the abundant mixing of 0.4kg urea in the fines, last effect dip mold moulding at tackiness agent, obtain bar-shaped organic-inorganic compound mixed fertilizer particle, bar-shaped: diameter is 0.5cm ± 0.1, and long is 3cm;
4, bar-shaped organic-inorganic compound mixed fertilizer particle qualified after the moulded section is placed on even spraying 2kg zeolite, 1kg acrylic resin, 5kg kaolin in the coating machine, coating is after the oven dry of room temperature exhausting, seal as sealing agent with 5kg paraffin, drying makes water content reach 10%, sorted and packaged promptly obtains described flowers organic and inorganic slow-release fertilizer.
Embodiment 3
1, prepares the one time fermentation product as follows: with chicken manure and 50kg ground phosphate rock, 80kg soda-manufacturing waste residue, 20kg mineral K, 180kg soy sauce slag, 20kg dry branches and fallen leaves, 50kg humic acids, 20kg vinasse and the 20kg monosodium glutamate waste liquid uniform mixing of 560kg, according to compost parameter p H be 8.5, the mass ratio of carbon nitrogen is 30: 1, makes its last composting mixture water ratio reach 60%; With the last composting mixture compost reactor of packing into, be that 1: 10 amount inserts the VT-1000 microbial inoculum with VT-1000 microbial inoculum and composting mixture weight ratio; Compost temperature rises to more than 70 ℃, keeps beginning turning after 48 hours, when temperature surpasses 70 ℃, turning immediately by stirring and forced ventilation, makes the oxygen level in the heap body remain on 8%, temperature in the control compost reactor goes through obtaining the one time fermentation product in 8 days at 65 ℃;
2, with 60kg one time fermentation product, 4kg diammonium phosphate, 5kg vitriolate of tartar and 20kg ammonium humate thorough mixing, change the storage bin that adopts hot a heatable brick bed system design over to, make the ground plate temperature remain on 45 ℃, carry out the evaporation of the Secondary Fermentation and the moisture of compost, every turning in 5 days once, behind the composting 20 days, the compost water content is 13%, obtains tunning for the second time;
3, tunning was pulverized 150 mesh sieves for the second time, coarse fodder is back to storage bin, add 8kg tackiness agent, 1kg vitriolate of tartar, 5kg glucose and 4kg glycine mixing in the fines, last effect dip mold moulding at tackiness agent, obtain bar-shaped organic-inorganic compound mixed fertilizer particle, bar-shaped: diameter is 0.5cm ± 0.1, and long is 3cm;
4, bar-shaped organic-inorganic compound mixed fertilizer particle qualified after the moulded section is placed on even spraying 2kg zeolite, 8kg polysulfide, 5kg acrylic resin and 8kg attapulgite in the coating machine, coating is after the oven dry of room temperature exhausting, seal as sealing agent with 4kg paraffin, 6kg stearic acid and 2kg pitch, drying makes water content reach 14%, sorted and packaged promptly obtains described flowers organic and inorganic slow-release fertilizer.
Embodiment 4
1, prepares the one time fermentation product as follows: with cow dung and 30kg ground phosphate rock, 130kg flyash, 10kg mineral K, 80kg mushroom residue, 50kg wood chip, 30kg yeast waste liquor, 50kg vinasse, 60kg monosodium glutamate waste liquid and the 10kg granulated sugar uniform mixing of 550kg, according to compost parameter p H be 7, the mass ratio of carbon nitrogen is 38: 1, makes its last composting mixture water ratio reach 60%; With the last composting mixture compost reactor of packing into, be that 1: 100 amount inserts the VT-100 microbial inoculum with VT-1000 microbial inoculum and composting mixture weight ratio; Compost temperature rises to 60 ℃, keeps beginning turning after 48 hours, by stirring and forced ventilation, makes the oxygen level in the heap body remain on 10%, and the temperature in the control compost reactor goes through obtaining the one time fermentation product in 12 days at 70 ℃;
2, with 70kg one time fermentation product, 4kg dipotassium hydrogen phosphate, 7kg diammonium phosphate, 6kg urea and 30kg sulphur thorough mixing, change the storage bin that adopts hot a heatable brick bed system design over to, make the ground plate temperature remain on 50 ℃, carry out the evaporation of the Secondary Fermentation and the moisture of compost, every turning in 6 days once, behind the composting 16 days, the compost water content is 18%, obtains tunning for the second time;
3, tunning was pulverized 200 mesh sieves for the second time, coarse fodder is back to storage bin, add 10kg tackiness agent, 3kg diammonium phosphate, 7kg sucrose, 4kg fructose, 4kg asparagine ammonia mixing in the fines, last effect dip mold moulding at tackiness agent, obtain bar-shaped organic-inorganic compound mixed fertilizer particle, bar-shaped: diameter is 0.5cm ± 0.1, and long is 2cm;
4, bar-shaped organic-inorganic compound mixed fertilizer particle qualified after the moulded section is placed on even spraying 10kg wilkinite, 15kg acrylic resin, 6kg attapulgite and 4kg kaolin in the coating machine, coating is after the oven dry of room temperature exhausting, seal as sealing agent with the 10kg stearic acid, drying makes water content reach 15%, sorted and packaged promptly obtains described flowers organic and inorganic slow-release fertilizer.
The quality examination such as the table 1 of the flowers organic and inorganic slow-release fertilizer of the present invention's preparation:
The technical indicator of table 1 flowers organic and inorganic slow-release fertilizer product
Figure A20081009616900101

Claims (2)

1. flowers organic and inorganic slow-release fertilizer, it is characterized in that: this slow-release fertilizer contains the material of following weight percent:
One time fermentation product 45~70%; Chemical fertilizer 2~35%; Amendment 5~30%; Coated fertilizer 3~25%; Tackiness agent 1~10%; Active substance 0~15%; Sealing agent 0~12%;
Described one time fermentation product is prepared from as follows:
(1) with one or both and inorganic conditioner, organic amendment of cow dung or chicken manure, the promotor uniform mixing becomes thoroughly decomposed, mass ratio according to compost parameter p H 5.5~8.5, carbon nitrogen is 20~38: 1, make its last composting mixture water ratio reach 40~65%, its main component is by weight percentage:
Cow dung or chicken manure 55~70%
Inorganic conditioner 15~26%
Organic amendment 12~25%
The promotor 3~18% of becoming thoroughly decomposed;
Described inorganic conditioner is at least a in flyash, soda-manufacturing waste residue, ground phosphate rock, the mineral K;
Described organic amendment is at least a in mushroom residue, crop material, dry branches and fallen leaves, wood chip, soy sauce slag, the humic acids;
The described promotor of becoming thoroughly decomposed is at least a in yeast waste liquor, vinasse, molasses, monosodium glutamate waste liquid, the granulated sugar;
(2) last composting mixture is packed into compost reactor is that 1~10: 1000 amount inserts microbial inoculant with microbial inoculant and composting mixture weight ratio; Compost temperature rises to 60 ℃~70 ℃, keeps beginning turning after 48 hours, and when temperature surpasses 70 ℃, turning immediately, uniform and complete is wanted in turning; By stirring and forced ventilation, the oxygen level in the heap body is remained between 5~15%, the temperature in the control compost reactor goes through obtaining the one time fermentation product in 6~13 days at 55~70 ℃;
Described microbial inoculant is one or both in enzymatic microorganism quick rotting agent, VT-100, the VT-1000 microbial inoculum;
Described chemical fertilizer is at least a in potassium primary phosphate, dipotassium hydrogen phosphate, diammonium phosphate, urea, ammonium sulfate, the vitriolate of tartar;
Described amendment is at least a in copper sulfate, zinc sulfate, ferrous sulfate, sal epsom, molybdenum trisulfate, flyash, terra alba, sulphur, meadow soil, xanthohumic acid, ammonium humate, humic acids magnesium, potassium humate, instantly-soluble humic acids, the bone meal;
Described coated fertilizer is two or more in wilkinite, zeolite, polysulfide, acrylic resin, Synolac, the ester gum;
Described tackiness agent is at least a in polyvinyl alcohol, attapulgite, kaolin, the urea-formaldehyde resin aqueous solution;
Described active substance is at least a in sucrose, fructose, glucose, glycine, asparagine ammonia, organized enzyme, the plant growth hormones;
Described sealing agent is at least a in paraffin, pitch, stearic acid, the compound ceresine.
2. the preparation method of a kind of flowers organic and inorganic slow-release fertilizer according to claim 1 is characterized in that: comprise the steps:
1) with one time fermentation product, chemical fertilizer and amendment thorough mixing, change the storage bin that adopts hot a heatable brick bed system design over to, make the ground plate temperature remain on 35~50 ℃, carry out the evaporation of the Secondary Fermentation and the moisture of compost, every turning in 2~6 days once, behind the composting 15~20 days, the compost water content obtains tunning for the second time 10~18%; Described fertilizer amount is 80~95% of total consumption;
2) tunning was pulverized 50~210 mesh sieves for the second time, coarse fodder is back to storage bin, add 0~15% active substance, 1~10% tackiness agent and the abundant mixing of residue chemical fertilizer in the fines, in the effect dip mold moulding of tackiness agent, obtain bar-shaped organic-inorganic compound mixed fertilizer particle at last; Described bar-shaped organic-inorganic compound mixed fertilizer particulate diameter is 0.5cm ± 0.1cm, and long is 2cm~3cm;
3) organic-inorganic compound mixed fertilizer particle qualified after the moulded section is placed on even spraying coated fertilizer in the coating machine, coating is after the room temperature exhausting is dried, and sealing agent seals, and drying makes water content reach 10~15%, sorted and packaged promptly obtains described flowers organic and inorganic slow-release fertilizer.
CN2008100961696A 2008-05-09 2008-05-09 Organic-inorganic slow-released fertilizer and method for preparing same Expired - Fee Related CN101284747B (en)

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