CH625531A5 - - Google Patents

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Info

Publication number: CH625531A5
Authority: CH; Switzerland
Prior art keywords: carbon atoms; acid; halogen; radical; compounds
Prior art date: 1975-12-30

Application number

CH1635776A

Other languages

German (de)

English (en)

Inventor

Franz Dr Scheidl

Hans Dr Huber

Klaus Dr Ulm

Original Assignee

Hoechst Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1975-12-30

Filing date

1976-12-27

Publication date

1981-09-30

1976-12-27 Application filed by Hoechst Ag filed Critical Hoechst Ag

1981-09-30 Publication of CH625531A5 publication Critical patent/CH625531A5/de

Links

150000001875 compounds Chemical class 0.000 claims description 42
125000004432 carbon atom Chemical group C* 0.000 claims description 40
-1 mercapto acids Chemical class 0.000 claims description 36
239000003381 stabilizer Substances 0.000 claims description 20
229920000642 polymer Polymers 0.000 claims description 19
239000000203 mixture Substances 0.000 claims description 18
150000002367 halogens Chemical class 0.000 claims description 15
125000000217 alkyl group Chemical group 0.000 claims description 14
125000002947 alkylene group Chemical group 0.000 claims description 12
HDFRDWFLWVCOGP-UHFFFAOYSA-N carbonothioic O,S-acid Chemical compound OC(S)=O HDFRDWFLWVCOGP-UHFFFAOYSA-N 0.000 claims description 12
229910052736 halogen Inorganic materials 0.000 claims description 12
239000002253 acid Substances 0.000 claims description 11
150000002148 esters Chemical class 0.000 claims description 11
230000000087 stabilizing effect Effects 0.000 claims description 10
150000002118 epoxides Chemical class 0.000 claims description 9
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
229920006395 saturated elastomer Polymers 0.000 claims description 7
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
125000003700 epoxy group Chemical group 0.000 claims description 6
238000000034 method Methods 0.000 claims description 6
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
229920003023 plastic Polymers 0.000 claims description 6
239000004033 plastic Substances 0.000 claims description 6
150000003839 salts Chemical class 0.000 claims description 6
125000000753 cycloalkyl group Chemical group 0.000 claims description 5
238000002845 discoloration Methods 0.000 claims description 5
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
239000004593 Epoxy Chemical class 0.000 claims description 4
SSBKLYFUQNZPGD-UHFFFAOYSA-N OC(=O)CS.OC(=O)CS.CCCCCCCC[Sn]CCCCCCCC Chemical compound OC(=O)CS.OC(=O)CS.CCCCCCCC[Sn]CCCCCCCC SSBKLYFUQNZPGD-UHFFFAOYSA-N 0.000 claims description 4
CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 claims description 4
239000000654 additive Substances 0.000 claims description 4
150000001733 carboxylic acid esters Chemical class 0.000 claims description 4
239000000460 chlorine Substances 0.000 claims description 4
229910052801 chlorine Inorganic materials 0.000 claims description 4
229910052751 metal Chemical class 0.000 claims description 4
239000002184 metal Chemical class 0.000 claims description 4
230000008569 process Effects 0.000 claims description 4
150000003606 tin compounds Chemical class 0.000 claims description 4
229920002554 vinyl polymer Polymers 0.000 claims description 4
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 3
125000003118 aryl group Chemical group 0.000 claims description 3
125000000732 arylene group Chemical group 0.000 claims description 3
150000007942 carboxylates Chemical group 0.000 claims description 3
239000007795 chemical reaction product Substances 0.000 claims description 3
125000002993 cycloalkylene group Chemical group 0.000 claims description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
150000002989 phenols Chemical class 0.000 claims description 3
150000005846 sugar alcohols Polymers 0.000 claims description 3
150000003568 thioethers Chemical class 0.000 claims description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 2
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
125000003710 aryl alkyl group Chemical group 0.000 claims description 2
229910052788 barium Inorganic materials 0.000 claims description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
229910052793 cadmium Inorganic materials 0.000 claims description 2
229920001577 copolymer Polymers 0.000 claims description 2
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
238000002360 preparation method Methods 0.000 claims description 2
229910052725 zinc Inorganic materials 0.000 claims description 2
239000012760 heat stabilizer Substances 0.000 claims 2
150000007524 organic acids Chemical class 0.000 claims 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical class [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical class [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical class [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 1
239000011575 calcium Chemical class 0.000 claims 1
229910052791 calcium Inorganic materials 0.000 claims 1
230000015556 catabolic process Effects 0.000 claims 1
238000000354 decomposition reaction Methods 0.000 claims 1
238000006731 degradation reaction Methods 0.000 claims 1
239000004611 light stabiliser Substances 0.000 claims 1
230000007774 longterm Effects 0.000 claims 1
239000000463 material Substances 0.000 claims 1
150000007522 mineralic acids Chemical class 0.000 claims 1
238000010137 moulding (plastic) Methods 0.000 claims 1
235000005985 organic acids Nutrition 0.000 claims 1
238000004806 packaging method and process Methods 0.000 claims 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims 1
238000007493 shaping process Methods 0.000 claims 1
239000011701 zinc Chemical class 0.000 claims 1
229910052718 tin Inorganic materials 0.000 description 17
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 12
150000003254 radicals Chemical class 0.000 description 10
CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 9
229910052717 sulfur Inorganic materials 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
239000003054 catalyst Substances 0.000 description 6
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
239000000047 product Substances 0.000 description 6
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 5
ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
150000001735 carboxylic acids Chemical class 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
229910052739 hydrogen Inorganic materials 0.000 description 4
239000001257 hydrogen Substances 0.000 description 4
239000011593 sulfur Substances 0.000 description 4
XZYFHFYPGVWYDB-UHFFFAOYSA-N 2-methyl-3-prop-2-enyloxirane Chemical compound CC1OC1CC=C XZYFHFYPGVWYDB-UHFFFAOYSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 3
LQRUPWUPINJLMU-UHFFFAOYSA-N dioctyl(oxo)tin Chemical compound CCCCCCCC[Sn](=O)CCCCCCCC LQRUPWUPINJLMU-UHFFFAOYSA-N 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
238000009472 formulation Methods 0.000 description 3
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
239000007788 liquid Substances 0.000 description 3
238000000465 moulding Methods 0.000 description 3
239000004800 polyvinyl chloride Substances 0.000 description 3
238000005096 rolling process Methods 0.000 description 3
239000002904 solvent Substances 0.000 description 3
239000003549 soybean oil Substances 0.000 description 3
235000012424 soybean oil Nutrition 0.000 description 3
239000000126 substance Substances 0.000 description 3
RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
239000004711 α-olefin Substances 0.000 description 3
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
DKIDEFUBRARXTE-UHFFFAOYSA-N 3-mercaptopropanoic acid Chemical compound OC(=O)CCS DKIDEFUBRARXTE-UHFFFAOYSA-N 0.000 description 2
FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
230000001476 alcoholic effect Effects 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
150000005840 aryl radicals Chemical class 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
230000008901 benefit Effects 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
235000019438 castor oil Nutrition 0.000 description 2
239000004359 castor oil Substances 0.000 description 2
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
239000000314 lubricant Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 description 2
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
239000003921 oil Substances 0.000 description 2
235000019198 oils Nutrition 0.000 description 2
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 2
239000004014 plasticizer Substances 0.000 description 2
229920000915 polyvinyl chloride Polymers 0.000 description 2
239000007787 solid Substances 0.000 description 2
230000003068 static effect Effects 0.000 description 2
VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
125000003944 tolyl group Chemical group 0.000 description 2
HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
GJEZBVHHZQAEDB-SYDPRGILSA-N (1s,5r)-6-oxabicyclo[3.1.0]hexane Chemical compound C1CC[C@H]2O[C@H]21 GJEZBVHHZQAEDB-SYDPRGILSA-N 0.000 description 1
125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
GIIFOPDECXGBBS-UHFFFAOYSA-N 1,5,6,6,7,7-hexachloro-3-oxatricyclo[3.2.1.02,4]oct-2(4)-ene Chemical compound ClC1(Cl)C(Cl)(Cl)C2(Cl)C(O3)=C3C1(Cl)C2 GIIFOPDECXGBBS-UHFFFAOYSA-N 0.000 description 1
HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
KXSWSFNGQCBWQA-UHFFFAOYSA-N 1a,2,7,7a-tetrahydronaphtho[2,3-b]oxirene Chemical compound C1C2=CC=CC=C2CC2C1O2 KXSWSFNGQCBWQA-UHFFFAOYSA-N 0.000 description 1
VGWMANKEPYEWNK-UHFFFAOYSA-N 2,2,3,3-tetraphenyloxirane Chemical compound C=1C=CC=CC=1C1(C=2C=CC=CC=2)OC1(C=1C=CC=CC=1)C1=CC=CC=C1 VGWMANKEPYEWNK-UHFFFAOYSA-N 0.000 description 1
DROPRKMIAJEDNC-UHFFFAOYSA-N 2,2-dimethyl-3-(3-methylpentylidene)oxirane Chemical compound CC1(C)C(=CCC(CC)C)O1 DROPRKMIAJEDNC-UHFFFAOYSA-N 0.000 description 1
GULTUCLJTHJGKP-UHFFFAOYSA-N 2,3-dimethyl-3-sulfanylbutanoic acid Chemical compound OC(=O)C(C)C(C)(C)S GULTUCLJTHJGKP-UHFFFAOYSA-N 0.000 description 1
WISUILQECWFZCN-UHFFFAOYSA-N 2-(oxiran-2-ylmethylsulfanylmethyl)oxirane Chemical class C1OC1CSCC1CO1 WISUILQECWFZCN-UHFFFAOYSA-N 0.000 description 1
CMCOFAYLDYIEBR-UHFFFAOYSA-L 2-[carboxymethylsulfanyl(dioctyl)stannyl]sulfanylacetic acid Chemical class [O-]C(=O)CS.[O-]C(=O)CS.CCCCCCCC[Sn+2]CCCCCCCC CMCOFAYLDYIEBR-UHFFFAOYSA-L 0.000 description 1
WHNBDXQTMPYBAT-UHFFFAOYSA-N 2-butyloxirane Chemical compound CCCCC1CO1 WHNBDXQTMPYBAT-UHFFFAOYSA-N 0.000 description 1
BCJPEZMFAKOJPM-UHFFFAOYSA-N 2-ethyl-3-methyloxirane Chemical compound CCC1OC1C BCJPEZMFAKOJPM-UHFFFAOYSA-N 0.000 description 1
CFPHMAVQAJGVPV-UHFFFAOYSA-N 2-sulfanylbutanoic acid Chemical compound CCC(S)C(O)=O CFPHMAVQAJGVPV-UHFFFAOYSA-N 0.000 description 1
REFZTFPICLNNPM-UHFFFAOYSA-N 2-sulfanyldodecanoic acid Chemical compound CCCCCCCCCCC(S)C(O)=O REFZTFPICLNNPM-UHFFFAOYSA-N 0.000 description 1
PLEHXTMHOJLNKD-UHFFFAOYSA-N 2-sulfanylheptanedioic acid Chemical compound OC(=O)CCCCC(S)C(O)=O PLEHXTMHOJLNKD-UHFFFAOYSA-N 0.000 description 1
NTKCAHRZWRIYFH-UHFFFAOYSA-N 2-sulfanyloctadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(S)C(O)=O NTKCAHRZWRIYFH-UHFFFAOYSA-N 0.000 description 1
BYEDCPUIOUBOTF-UHFFFAOYSA-N 2-sulfanyloctanedioic acid Chemical compound OC(=O)CCCCCC(S)C(O)=O BYEDCPUIOUBOTF-UHFFFAOYSA-N 0.000 description 1
IMGGANUNCHXAQF-UHFFFAOYSA-N 2-sulfanylpentanoic acid Chemical compound CCCC(S)C(O)=O IMGGANUNCHXAQF-UHFFFAOYSA-N 0.000 description 1
MTMDLUFMACHNQR-UHFFFAOYSA-N 3-methyl-2-sulfanylbutanoic acid Chemical compound CC(C)C(S)C(O)=O MTMDLUFMACHNQR-UHFFFAOYSA-N 0.000 description 1
RQPNXPWEGVCPCX-UHFFFAOYSA-N 3-sulfanylbutanoic acid Chemical compound CC(S)CC(O)=O RQPNXPWEGVCPCX-UHFFFAOYSA-N 0.000 description 1
XLFFYDFFAKJIEN-UHFFFAOYSA-N 3-sulfanylnaphthalene-2-carboxylic acid Chemical compound C1=CC=C2C=C(S)C(C(=O)O)=CC2=C1 XLFFYDFFAKJIEN-UHFFFAOYSA-N 0.000 description 1
GCDFODQNNFXERB-UHFFFAOYSA-N 4,5-dimethyl-3-sulfanylhexanoic acid Chemical compound CC(C)C(C)C(S)CC(O)=O GCDFODQNNFXERB-UHFFFAOYSA-N 0.000 description 1
HMKPBPAJTBLNLH-UHFFFAOYSA-N 4-hydroxy-3-sulfanylbutanoic acid Chemical compound OCC(S)CC(O)=O HMKPBPAJTBLNLH-UHFFFAOYSA-N 0.000 description 1
229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
DTRIDVOOPAQEEL-UHFFFAOYSA-N 4-sulfanylbutanoic acid Chemical compound OC(=O)CCCS DTRIDVOOPAQEEL-UHFFFAOYSA-N 0.000 description 1
QXNCUGXEZGTWHK-UHFFFAOYSA-N 4-sulfanylhexanoic acid Chemical compound CCC(S)CCC(O)=O QXNCUGXEZGTWHK-UHFFFAOYSA-N 0.000 description 1
FAEAERQPRQJZOC-UHFFFAOYSA-N 8-(3-octyloxiran-2-yl)octan-1-ol Chemical compound CCCCCCCCC1OC1CCCCCCCCO FAEAERQPRQJZOC-UHFFFAOYSA-N 0.000 description 1
IMYZYCNQZDBZBQ-UHFFFAOYSA-N 9,10-epoxyoctadecanoic acid Chemical class CCCCCCCCC1OC1CCCCCCCC(O)=O IMYZYCNQZDBZBQ-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
239000004709 Chlorinated polyethylene Substances 0.000 description 1
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
LXXNWCFBZHKFPT-UHFFFAOYSA-N Ethyl 2-mercaptopropionate Chemical compound CCOC(=O)C(C)S LXXNWCFBZHKFPT-UHFFFAOYSA-N 0.000 description 1
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Natural products OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
239000004609 Impact Modifier Substances 0.000 description 1
229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
JVTAAEKCZFNVCJ-UHFFFAOYSA-N Lactic Acid Natural products CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 1
239000005639 Lauric acid Substances 0.000 description 1
PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
229920001756 Polyvinyl chloride acetate Polymers 0.000 description 1
240000000528 Ricinus communis Species 0.000 description 1
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
MKYQPGPNVYRMHI-UHFFFAOYSA-N Triphenylethylene Chemical compound C=1C=CC=CC=1C=C(C=1C=CC=CC=1)C1=CC=CC=C1 MKYQPGPNVYRMHI-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
238000006853 Ziegler synthesis reaction Methods 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
238000004026 adhesive bonding Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
238000004220 aggregation Methods 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
RMRFFCXPLWYOOY-UHFFFAOYSA-N allyl radical Chemical compound [CH2]C=C RMRFFCXPLWYOOY-UHFFFAOYSA-N 0.000 description 1
OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229940056585 ammonium laurate Drugs 0.000 description 1
VJCJAQSLASCYAW-UHFFFAOYSA-N azane;dodecanoic acid Chemical compound [NH4+].CCCCCCCCCCCC([O-])=O VJCJAQSLASCYAW-UHFFFAOYSA-N 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
150000001558 benzoic acid derivatives Chemical class 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
239000004305 biphenyl Substances 0.000 description 1
235000010290 biphenyl Nutrition 0.000 description 1
VCCBEIPGXKNHFW-UHFFFAOYSA-N biphenyl-4,4'-diol Chemical group C1=CC(O)=CC=C1C1=CC=C(O)C=C1 VCCBEIPGXKNHFW-UHFFFAOYSA-N 0.000 description 1
BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
150000003842 bromide salts Chemical class 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
150000001805 chlorine compounds Chemical class 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
125000000068 chlorophenyl group Chemical group 0.000 description 1
125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
150000005690 diesters Chemical class 0.000 description 1
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
238000007046 ethoxylation reaction Methods 0.000 description 1
230000007717 exclusion Effects 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229940051250 hexylene glycol Drugs 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
125000004464 hydroxyphenyl group Chemical group 0.000 description 1
230000006872 improvement Effects 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
239000004310 lactic acid Substances 0.000 description 1
235000014655 lactic acid Nutrition 0.000 description 1
229910052745 lead Inorganic materials 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
150000004702 methyl esters Chemical class 0.000 description 1
239000000178 monomer Substances 0.000 description 1
235000013872 montan acid ester Nutrition 0.000 description 1
239000012170 montan wax Substances 0.000 description 1
125000002819 montanyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 description 1
125000001624 naphthyl group Chemical group 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
229940038384 octadecane Drugs 0.000 description 1
QJAOYSPHSNGHNC-UHFFFAOYSA-N octadecane-1-thiol Chemical compound CCCCCCCCCCCCCCCCCCS QJAOYSPHSNGHNC-UHFFFAOYSA-N 0.000 description 1
VLFLYIUFLKXQMS-UHFFFAOYSA-M octadecanoate;tetraethylazanium Chemical compound CC[N+](CC)(CC)CC.CCCCCCCCCCCCCCCCCC([O-])=O VLFLYIUFLKXQMS-UHFFFAOYSA-M 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
KZCOBXFFBQJQHH-UHFFFAOYSA-N octane-1-thiol Chemical compound CCCCCCCCS KZCOBXFFBQJQHH-UHFFFAOYSA-N 0.000 description 1
229920000620 organic polymer Polymers 0.000 description 1
150000004707 phenolate Chemical class 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
125000005498 phthalate group Chemical class 0.000 description 1
DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
239000004300 potassium benzoate Substances 0.000 description 1
235000010235 potassium benzoate Nutrition 0.000 description 1
229940103091 potassium benzoate Drugs 0.000 description 1
229940114930 potassium stearate Drugs 0.000 description 1
ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
239000001294 propane Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
239000013558 reference substance Substances 0.000 description 1
150000003902 salicylic acid esters Chemical class 0.000 description 1
239000000344 soap Substances 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
235000017281 sodium acetate Nutrition 0.000 description 1
229960004249 sodium acetate Drugs 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000003756 stirring Methods 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
125000005346 substituted cycloalkyl group Chemical group 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
239000003784 tall oil Substances 0.000 description 1
ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
NJRXVEJTAYWCQJ-UHFFFAOYSA-N thiomalic acid Chemical compound OC(=O)CC(S)C(O)=O NJRXVEJTAYWCQJ-UHFFFAOYSA-N 0.000 description 1
NBOMNTLFRHMDEZ-UHFFFAOYSA-N thiosalicylic acid Chemical compound OC(=O)C1=CC=CC=C1S NBOMNTLFRHMDEZ-UHFFFAOYSA-N 0.000 description 1
229940103494 thiosalicylic acid Drugs 0.000 description 1
ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical compound C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 description 1
238000010792 warming Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000008096 xylene Substances 0.000 description 1
125000005023 xylyl group Chemical group 0.000 description 1
238000004383 yellowing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/56—Organo-metallic compounds, i.e. organic compounds containing a metal-to-carbon bond
- C08K5/57—Organo-tin compounds
- C08K5/58—Organo-tin compounds containing sulfur
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/22—Tin compounds
- C07F7/226—Compounds with one or more Sn-S linkages

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Compositions Of Macromolecular Compounds (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

CH1635776A 1975-12-30 1976-12-27 CH625531A5 (nl)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE2559201A DE2559201B2 (de)	1975-12-30	1975-12-30	Organozinnverbindungen und ihre Verwendung als Stabilisatoren

Publications (1)

Publication Number	Publication Date
CH625531A5 true CH625531A5 (nl)	1981-09-30

Family

ID=5965893

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CH1635776A CH625531A5 (nl)	1975-12-30	1976-12-27

Country Status (13)

Country	Link
US (1)	US4122064A (nl)
JP (1)	JPS5283337A (nl)
AT (1)	AT344728B (nl)
BE (1)	BE850003A (nl)
CA (1)	CA1080733A (nl)
CH (1)	CH625531A5 (nl)
DE (1)	DE2559201B2 (nl)
DK (1)	DK586176A (nl)
FR (1)	FR2337138A1 (nl)
GB (1)	GB1560586A (nl)
IT (1)	IT1070435B (nl)
LU (1)	LU76484A1 (nl)
NL (1)	NL7614406A (nl)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6919392B1 (en)	1978-08-29	2005-07-19	Arkema Inc.	Stabilization of vinyl halide polymers
US4327016A (en) *	1979-05-07	1982-04-27	Ciba-Geigy Corporation	Organotin compounds, and their use
US4396552A (en) *	1980-02-08	1983-08-02	Ciba-Geigy Corporation	Novel metal mercaptides of esters of β-mercaptoalkanols
US4701486A (en) *	1981-02-26	1987-10-20	Morton Thiokol, Inc.	Stabilizer compositions for PVC resins
US4988750A (en) *	1981-07-17	1991-01-29	Schering Ag	Non-toxic stabilizer for halogenated polymer
JPS58105994A (ja) *	1981-12-04	1983-06-24	チバ−ガイギ−・アクチエンゲゼルシヤフト	アルキル錫チオカルボン酸エステルの連続製造方法
US4576984A (en) *	1982-02-04	1986-03-18	Morton Thiokol, Inc.	Stabilizer compositions for PVC resins
US4617334A (en) *	1982-08-09	1986-10-14	Morton Thiokol, Inc.	Stabilizer compositions for PVC
US5340862A (en) *	1988-10-07	1994-08-23	Elf Atochem North America, Inc.	Stabilizers for halogen containing polymers
US5284886A (en) *	1989-10-31	1994-02-08	Elf Atochem North America, Inc.	Non-toxic polymeric compositions stabilized with organosulfide antioxidants
US5686025A (en) *	1996-01-05	1997-11-11	Witco Corporation	Stabilizer and blowing agent useful for rigid foamed PVC
ES2342997B1 (es) *	2008-12-09	2011-06-06	Universitat De Les Illes Balears	Alpha derivados de acidos grasos cis-monoinsaturados para ser usados como medicamento.

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US2648650A (en) *	1951-06-21	1953-08-11	Metal & Thermit Corp	Organo tin compounds and compositions containing same
US3565931A (en) *	1967-12-19	1971-02-23	Lawrence Robert Brecker	Process for preparing organotin mercapto carboxylic acid ester sulfides containing more than 18% tin
GB1233036A (nl) *	1968-11-22	1971-05-26
US3640953A (en) *	1969-01-23	1972-02-08	Argus Chem	Stabilization of polyvinyl chloride resins
US3931262A (en) *	1972-08-04	1976-01-06	Ciba-Geigy Corporation	Hydrophilic and difficultly volatile biocidal triorganotin compounds
US3845017A (en) *	1973-01-16	1974-10-29	Albright & Wilson	Polymers stabilized with terpene alcohols and an organotin compound
DE2558729A1 (de) *	1975-12-24	1977-07-14	Hoechst Ag	Neue mercaptocarbonsaeureester und verfahren zu deren herstellung

1975
- 1975-12-30 DE DE2559201A patent/DE2559201B2/de not_active Withdrawn
1976
- 1976-12-20 US US05/752,428 patent/US4122064A/en not_active Expired - Lifetime
- 1976-12-24 NL NL7614406A patent/NL7614406A/nl not_active Application Discontinuation
- 1976-12-27 JP JP15662576A patent/JPS5283337A/ja active Pending
- 1976-12-27 CH CH1635776A patent/CH625531A5/de not_active IP Right Cessation
- 1976-12-28 IT IT30919/76A patent/IT1070435B/it active
- 1976-12-28 LU LU76484A patent/LU76484A1/xx unknown
- 1976-12-29 CA CA268,841A patent/CA1080733A/en not_active Expired
- 1976-12-29 DK DK586176A patent/DK586176A/da unknown
- 1976-12-29 AT AT976076A patent/AT344728B/de not_active IP Right Cessation
- 1976-12-29 GB GB54253/76A patent/GB1560586A/en not_active Expired
- 1976-12-30 FR FR7639583A patent/FR2337138A1/fr active Granted
- 1976-12-30 BE BE173759A patent/BE850003A/xx unknown

Also Published As

Publication number	Publication date
BE850003A (fr)	1977-06-30
AT344728B (de)	1978-08-10
NL7614406A (nl)	1977-07-04
FR2337138A1 (fr)	1977-07-29
DE2559201B2 (de)	1978-06-15
US4122064A (en)	1978-10-24
ATA976076A (de)	1977-12-15
GB1560586A (en)	1980-02-06
IT1070435B (it)	1985-03-29
JPS5283337A (en)	1977-07-12
LU76484A1 (nl)	1977-07-05
FR2337138B1 (nl)	1982-12-03
DE2559201A1 (de)	1977-07-07
DK586176A (da)	1977-07-01
CA1080733A (en)	1980-07-01

Legal Events

Date	Code	Title	Description
1983-08-31	PL	Patent ceased

Publication	Publication Date	Title
EP0062813B1 (de)	1989-08-16	Stabilisiertes Polyvinylchlorid-Formmassen
EP0051788B1 (de)	1985-08-28	Stabilisatorkombination für Thermoplaste, insbesondere Polymerisate auf Basis von Vinylchlorid sowie Verfahren zur Warmverformung derartiger Polymerisate
DE2728862C3 (de)	1986-10-23	Stabilisierte Formmassen auf der Basis von Vinylchlorid-Polymerisaten
US4963594A (en)	1990-10-16	Heat/color stabilized polymers of vinyl chloride
DE2915439A1 (de)	1979-10-25	Antivergilbungszusammensetzung
CH625531A5 (nl)	1981-09-30
DE1813174B2 (de)	1971-04-08	Fluessiges stabilisatorgemisch zur verminderung der frueh verfaerbung von vinylchloridpolymerisaten beim erhitzen und stabilisierte vinylchloridpolymerisat massen
EP0751175A2 (de)	1997-01-02	Dispersionspulver mit erhöhter Selbstentzündungstemperatur
DE2623985A1 (de)	1977-12-08	Neue organische phosphite und ihre verwendung als stabilisatoren
DE3717838A1 (de)	1987-12-03	Mit laurylzinnverbindungen stabilisierte pvc-zusammensetzungen
US3346536A (en)	1967-10-10	Pvc resin containing a keto acetic (a) acid ester or (b) anhydride, and a metal (a) phenolate or (b) carboxylic acid salt
DE2802531C2 (nl)	1987-07-23
EP0012107A1 (de)	1980-06-11	Flammgeschützte, plastifizierte PVC-Mischung
DE3332003A1 (de)	1985-03-21	Stabilisierte polyvinylchlorid-formmassen
EP0000746B1 (de)	1981-01-28	Neue Organozinnverbindungen, ihre Herstellung und ihre Verwendung
DE2546900A1 (de)	1976-05-13	Fluessige stabilisatormischung und damit stabilisierte chlorhaltige thermoplaste
US4340514A (en)	1982-07-20	Non-toxic liquid stabilizer for halogenated hydrocarbon resins and process for stabilizing such resins
JPS587438A (ja)	1983-01-17	安定化されたエチレン／塩化三フツ化エチレン共重合組成物
DE2652458B2 (de)	1978-09-07	Hitzestabilisierte Formmassen auf der Basis von Vinylchlorid Homo- oder Copolymerisaten
DE1593821B1 (de)	1971-08-05	Verfahren zur Herstellung von Dialkylhydroxybenzylsulfiden
EP0001421A1 (de)	1979-04-18	Verwendung von Mercaptanen zur Wärmestabilisierung chlorhaltiger Thermoplaste
DE2359346A1 (de)	1974-06-06	Organozinnverbindungen, deren herstellung und deren verwendung als stabilisatoren fuer halogenhaltige harze
DE2061019C3 (de)	1982-02-04	Gemische von 2-Hydroxy-4-iso-alkoxybezophenonen und deren Verwendung zum Stabilisieren von Polymeren gegen Zersetzung
EP0157795B1 (de)	1988-07-20	Stabilisierte polyvinylchlorid-formmassen
DE1224924B (de)	1966-09-15	Verfahren zum Stabilisieren von Polyolefinen