CA2300786A1 - Anionic surfactant granules - Google Patents

Anionic surfactant granules Download PDF

Info

Publication number: CA2300786A1
Authority: CA; Canada
Prior art keywords: granules; anionic surfactant; weight; acid; contain
Prior art date: 1999-03-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Abandoned

Application number

CA 2300786

Other languages

English (en)

French (fr)

Inventor

Wilfried Raehse

Guenter Kreienfeld

Georg Assmann

Martina Kihn-Botulinski

Dieter Jung

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Henkel AG and Co KGaA

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1999-03-16

Filing date

2000-03-16

Publication date

2000-09-16

2000-03-16 Application filed by Individual filed Critical Individual

2000-09-16 Publication of CA2300786A1 publication Critical patent/CA2300786A1/en

Status Abandoned legal-status Critical Current

Links

239000008187 granular material Substances 0.000 title claims abstract description 130
239000003945 anionic surfactant Substances 0.000 title claims abstract description 88
-1 fatty alcohol sulfate Chemical class 0.000 claims abstract description 48
150000008051 alkyl sulfates Chemical class 0.000 claims abstract description 47
238000000034 method Methods 0.000 claims abstract description 36
230000008569 process Effects 0.000 claims abstract description 33
238000004519 manufacturing process Methods 0.000 claims abstract description 18
238000005469 granulation Methods 0.000 claims abstract description 16
230000003179 granulation Effects 0.000 claims abstract description 16
239000002253 acid Substances 0.000 claims description 66
239000000203 mixture Substances 0.000 claims description 51
239000003599 detergent Substances 0.000 claims description 50
239000004094 surface-active agent Substances 0.000 claims description 39
239000010457 zeolite Substances 0.000 claims description 36
150000007513 acids Chemical class 0.000 claims description 33
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 30
229910021536 Zeolite Inorganic materials 0.000 claims description 26
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 26
150000004702 methyl esters Chemical class 0.000 claims description 19
238000012360 testing method Methods 0.000 claims description 18
239000000654 additive Substances 0.000 claims description 8
238000005054 agglomeration Methods 0.000 claims description 8
230000002776 aggregation Effects 0.000 claims description 8
229910052783 alkali metal Inorganic materials 0.000 claims description 7
229940077388 benzenesulfonate Drugs 0.000 claims description 7
230000002378 acidificating effect Effects 0.000 claims description 6
230000000996 additive effect Effects 0.000 claims description 6
239000008240 homogeneous mixture Substances 0.000 claims description 6
239000004615 ingredient Substances 0.000 claims description 6
239000000470 constituent Substances 0.000 claims description 5
238000002156 mixing Methods 0.000 claims description 5
230000015572 biosynthetic process Effects 0.000 claims description 4
239000007795 chemical reaction product Substances 0.000 claims description 4
239000007921 spray Substances 0.000 claims description 4
229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 2
150000008041 alkali metal carbonates Chemical class 0.000 claims description 2
229910052936 alkali metal sulfate Inorganic materials 0.000 claims description 2
WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 claims description 2
229910000342 sodium bisulfate Inorganic materials 0.000 claims description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 25
125000004432 carbon atom Chemical group C* 0.000 description 33
150000003839 salts Chemical class 0.000 description 25
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 23
150000001875 compounds Chemical class 0.000 description 20
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229920002245 Dextrose equivalent Polymers 0.000 description 17
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239000000047 product Substances 0.000 description 17
238000005406 washing Methods 0.000 description 16
125000000217 alkyl group Chemical group 0.000 description 15
239000002736 nonionic surfactant Substances 0.000 description 15
239000000969 carrier Substances 0.000 description 14
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230000000694 effects Effects 0.000 description 7
239000008103 glucose Substances 0.000 description 7
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RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 6
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
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239000001361 adipic acid Substances 0.000 description 6
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JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 6
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QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 5
DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 5
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
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KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 5
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
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150000002148 esters Chemical class 0.000 description 5
230000007062 hydrolysis Effects 0.000 description 5
238000006460 hydrolysis reaction Methods 0.000 description 5
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 5
239000000178 monomer Substances 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
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239000011975 tartaric acid Substances 0.000 description 5
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HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 4
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RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 4
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235000019387 fatty acid methyl ester Nutrition 0.000 description 4
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YPFNIPKMNMDDDB-UHFFFAOYSA-K 2-[2-[bis(carboxylatomethyl)amino]ethyl-(2-hydroxyethyl)amino]acetate;iron(3+) Chemical compound [Fe+3].OCCN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O YPFNIPKMNMDDDB-UHFFFAOYSA-K 0.000 description 3
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 3
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PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
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229920002125 Sokalan® Polymers 0.000 description 3
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WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
239000002304 perfume Substances 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
PATMLLNMTPIUSY-UHFFFAOYSA-N phenoxysulfonyl 7-methyloctanoate Chemical compound CC(C)CCCCCC(=O)OS(=O)(=O)OC1=CC=CC=C1 PATMLLNMTPIUSY-UHFFFAOYSA-N 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
150000003022 phthalic acids Chemical class 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
150000003077 polyols Chemical class 0.000 description 1
235000020777 polyunsaturated fatty acids Nutrition 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
230000008092 positive effect Effects 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 description 1
239000002243 precursor Substances 0.000 description 1
230000002028 premature Effects 0.000 description 1
238000003825 pressing Methods 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000006722 reduction reaction Methods 0.000 description 1
230000002829 reductive effect Effects 0.000 description 1
230000011514 reflex Effects 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
150000004671 saturated fatty acids Chemical class 0.000 description 1
150000003333 secondary alcohols Chemical class 0.000 description 1
238000007873 sieving Methods 0.000 description 1
235000002639 sodium chloride Nutrition 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
238000003892 spreading Methods 0.000 description 1
230000007480 spreading Effects 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
230000003068 static effect Effects 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
229940012831 stearyl alcohol Drugs 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
150000003470 sulfuric acid monoesters Chemical class 0.000 description 1
238000004381 surface treatment Methods 0.000 description 1
239000000725 suspension Substances 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
235000020357 syrup Nutrition 0.000 description 1
239000006188 syrup Substances 0.000 description 1
KUCOHFSKRZZVRO-UHFFFAOYSA-N terephthalaldehyde Chemical compound O=CC1=CC=C(C=O)C=C1 KUCOHFSKRZZVRO-UHFFFAOYSA-N 0.000 description 1
108010075550 termamyl Proteins 0.000 description 1
TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical class CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
238000005809 transesterification reaction Methods 0.000 description 1
150000003623 transition metal compounds Chemical class 0.000 description 1
150000003626 triacylglycerols Chemical class 0.000 description 1
150000003918 triazines Chemical class 0.000 description 1
150000003852 triazoles Chemical class 0.000 description 1
150000005691 triesters Chemical class 0.000 description 1
239000013638 trimer Substances 0.000 description 1
HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
229940038773 trisodium citrate Drugs 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
150000004670 unsaturated fatty acids Chemical class 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
238000009736 wetting Methods 0.000 description 1
239000002888 zwitterionic surfactant Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CA 2300786 1999-03-16 2000-03-16 Anionic surfactant granules Abandoned CA2300786A1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE1999111570 DE19911570A1 (de)	1999-03-16	1999-03-16	Aniontensid-Granulate
DE19911570.2		1999-03-16

Publications (1)

Publication Number	Publication Date
CA2300786A1 true CA2300786A1 (en)	2000-09-16

Family

ID=7901090

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA 2300786 Abandoned CA2300786A1 (en)	1999-03-16	2000-03-16	Anionic surfactant granules

Country Status (5)

Country	Link
EP (1)	EP1163318A1 (de)
AU (1)	AU3287300A (de)
CA (1)	CA2300786A1 (de)
DE (1)	DE19911570A1 (de)
WO (1)	WO2000055289A1 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2009050026A2 (en) *	2007-10-17	2009-04-23	Unilever Nv	Laundry compositions
CN116328737A (zh) *	2023-01-10	2023-06-27	湖南大学	一种Fe/Mn-MOFs复合材料及制备方法与应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3632517A (en) *	1970-08-21	1972-01-04	Us Agriculture	Synergistic tallow-based detergent compositions
JPS59221391A (ja) *	1983-05-31	1984-12-12	ライオン株式会社	α−スルホ脂肪酸エステル塩含有粒状洗剤組成物
JPH02169696A (ja) *	1988-12-22	1990-06-29	Kao Corp	高密度粒状濃縮洗剤組成物
US5045238A (en) *	1989-06-09	1991-09-03	The Procter & Gamble Company	High active detergent particles which are dispersible in cold water
CA2017922C (en) *	1989-06-09	1995-07-11	Frank Joseph Mueller	Formation of discrete, high active detergent granules using a continuous neutralization system
DE4332373C2 (de) *	1993-09-23	2003-03-13	Cognis Deutschland Gmbh	Wasserfreie Detergensgemische
CA2173103A1 (en) *	1993-11-19	1995-05-26	Ronald Allen Swift	Detergent composition containing amine oxide and sulfonate surfactants
CA2192549A1 (en) *	1994-06-13	1995-12-21	Charles Louis Stearns	Detergent composition containing anionic surfactants and water-soluble saccharides
CN1085247C (zh) *	1996-03-08	2002-05-22	普罗格特-甘布尔公司	压密/涂覆法制备改进溶解度的仲烷基硫酸盐颗粒
DE19611013A1 (de) *	1996-03-21	1997-09-25	Henkel Kgaa	Festes Tensid- und Builder-haltiges Wasch- oder Reinigungsmittel mit hohem Schüttgewicht oder Compound hierfür
DE69632187T2 (de) *	1996-07-04	2005-03-17	The Procter & Gamble Company, Cincinnati	Verfahren zur Konditionierung von Tensidpasten zwecks Bildung hochaktiver Tensidgranulate

1999
- 1999-03-16 DE DE1999111570 patent/DE19911570A1/de not_active Ceased
2000
- 2000-03-08 WO PCT/EP2000/002015 patent/WO2000055289A1/de active Application Filing
- 2000-03-08 AU AU32873/00A patent/AU3287300A/en not_active Abandoned
- 2000-03-08 EP EP00910787A patent/EP1163318A1/de not_active Withdrawn
- 2000-03-16 CA CA 2300786 patent/CA2300786A1/en not_active Abandoned

Also Published As

Publication number	Publication date
WO2000055289A1 (de)	2000-09-21
AU3287300A (en)	2000-10-04
EP1163318A1 (de)	2001-12-19
DE19911570A1 (de)	2000-09-28

Legal Events

Date	Code	Title	Description
2003-03-17	FZDE	Dead

Publication	Publication Date	Title
US4849125A (en)	1989-07-18	Process for preparing a phosphate-reduced granular detergent
JP3889810B2 (ja)	2007-03-07	含浸無定形アルカリ金属ケイ酸塩の製造方法
US6329335B1 (en)	2001-12-11	Detergent tablets
JPH09507205A (ja)	1997-07-22	ケイ酸塩ビルダー及び洗濯又は洗浄剤におけるその使用並びに同分野において使用する多成分混合物
JP2008540813A (ja)	2008-11-20	洗剤組成物
CZ316894A3 (en)	1995-07-12	Process for preparing compact detergents
CA1153162A (en)	1983-09-06	Particulate bleach compositions
JP2001500557A (ja)	2001-01-16	粒状洗浄または清浄剤の製法
US20070225197A1 (en)	2007-09-27	Method for Producing Granules and the Use Thereof in Washing and/or Cleaning Agents
RU2168542C2 (ru)	2001-06-10	Состав аморфного силиката щелочного металла, полученного путем распылительной сушки, обладающего вторичной моющей способностью, моющее средство или детергент и экструдированное(ый) моющее средство или детергент, содержащие указанный состав
CA2248994C (en)	2001-05-15	Free-flowing agglomerated nonionic surfactant detergent composition and process for making same
CA2174321C (en)	2000-07-18	Process for the production of a detergent composition
JP3841431B2 (ja)	2006-11-01	噴霧乾燥洗剤またはその成分
CA2327968A1 (en)	2001-06-11	Nonionic surfactant granules by prilling
JP5559706B2 (ja)	2014-07-23	第二級パラフィンスルホン酸の固体のアルカリ土類金属塩の製造方法
CA2300786A1 (en)	2000-09-16	Anionic surfactant granules
US6841614B1 (en)	2005-01-11	Polymer granules produced by fluidized bed granulation
GB2053998A (en)	1981-02-11	Particulate bleach composition
KR19990028914A (ko)	1999-04-15	비결정성 알칼리 실리케이트 화합물
JPH08504864A (ja)	1996-05-28	粒状の洗浄剤および／または清浄化剤
US20020022584A1 (en)	2002-02-21	Process for the production of sugar surfactant granules
US6177397B1 (en)	2001-01-23	Free-flowing agglomerated nonionic surfactant detergent composition and process for making same
JPH07501564A (ja)	1995-02-16	粉末形態の界面活性剤混合物
JP2002509185A (ja)	2002-03-26	着色した洗剤および清浄剤の製造方法
JP2002529581A (ja)	2002-09-10	可溶性界面活性剤顆粒