BRPI0709454B8 - complexo de haleto de magnésio, processo para preparar o complexo de olefínica, catalisador para a polimerização de uma olefina e processo para polimerizar olefinas - Google Patents
complexo de haleto de magnésio, processo para preparar o complexo de olefínica, catalisador para a polimerização de uma olefina e processo para polimerizar olefinasInfo
- Publication number
- BRPI0709454B8 BRPI0709454B8 BRPI0709454A BRPI0709454A BRPI0709454B8 BR PI0709454 B8 BRPI0709454 B8 BR PI0709454B8 BR PI0709454 A BRPI0709454 A BR PI0709454A BR PI0709454 A BRPI0709454 A BR PI0709454A BR PI0709454 B8 BRPI0709454 B8 BR PI0709454B8
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- magnesium halide
- olefin
- complex
- polymerization
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 6
- 239000003054 catalyst Substances 0.000 title abstract 6
- 229910052749 magnesium Inorganic materials 0.000 title abstract 5
- 239000011777 magnesium Substances 0.000 title abstract 5
- -1 magnesium halide Chemical class 0.000 title abstract 5
- 238000006116 polymerization reaction Methods 0.000 title abstract 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 230000000379 polymerizing effect Effects 0.000 title abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical group [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 125000004104 aryloxy group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001805 chlorine compounds Chemical group 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/02—Magnesium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
- B01J31/30—Halides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J25/00—Catalysts of the Raney type
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
complexo de haleto de magnésio, processo para preparar o complexo de haleto de magnésio, componente catalisador útil em polimerizaçao olefinica, catalisador para apolimerizaçao de uma olefina e processo para polimerizar olefinas. a invenção provê um complexo de haleto de magnésio, lendo uma composição representada pela fórmula (1) mgx~ 2~.mrohneph~ 2~o (1) na qual x é cloreto, brometo, ou um alcoxi ou ariloxi de c~ 1~-c~ 14~; r é alquila de c~ 1~-c~ 12~, cicloalquila de c~ 3~-c~ 10~ ou arila de c~ 6~-c~ 10~; e é hidrocarboneto com di-hidrocarbiloxigeminado representado pela fórmula (ii) na qual r~ 1~ e r~ 2~, que são idênticos ou diferentes, são hidrogênio ou alquila linear ou ramificado de c~ 1~-c~ 10~,cicloalquila de c~ 3~-c~ 10~, arila de c~ 6~-c~ 10~, alquilarila ou arilalquila de c~ 7~-c~ 10~, os ditos arila, alquilarila e arilalquila sendo opcionalmente substituidos por um ou mais átomos de halogênio no anel aromático; opcionalmente r~ 1~ e r~ 2~ ligam-se um ao outro para formar um anel ou sistema de anel fundido; r~ 3~ e r~ 4~ têm os mesmos significados definidos para r~ 1~ e r~ 2~ outros que não hidrogênio; m está na faixa de 1 a 5; n está na faixa de 0,005 a 1,0; e p está na faixa de o a 0,8. a invenção refere-se ainda a um componente catalisador esférico e a um catalisador preparado com o complexo de haleto de magnésio esférico, e ao uso do catalisador na polimerização de cx-olefinas ch~ 2~=chr ou uma mistura das mesmas, na qual r é h, ou alquila ou arila tendo de 1 a 12 átomos de carbono.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200610067177.9 | 2006-04-06 | ||
CNB2006100671779A CN100491410C (zh) | 2006-04-06 | 2006-04-06 | 一种卤化镁加合物及其制备方法和应用 |
CN200610113864XA CN101165074B (zh) | 2006-10-20 | 2006-10-20 | 用于烯烃聚合的催化剂组分及其催化剂 |
CN200610113864.X | 2006-10-20 | ||
PCT/CN2007/001123 WO2007112700A1 (en) | 2006-04-06 | 2007-04-06 | Magnesium halide adduct, olefins polymerization catalyst component and catalyst made therefrom |
Publications (4)
Publication Number | Publication Date |
---|---|
BRPI0709454A2 BRPI0709454A2 (pt) | 2011-07-12 |
BRPI0709454B1 BRPI0709454B1 (pt) | 2017-11-07 |
BRPI0709454A8 BRPI0709454A8 (pt) | 2018-01-30 |
BRPI0709454B8 true BRPI0709454B8 (pt) | 2018-02-27 |
Family
ID=38563120
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0709454A BRPI0709454B8 (pt) | 2006-04-06 | 2007-04-06 | complexo de haleto de magnésio, processo para preparar o complexo de olefínica, catalisador para a polimerização de uma olefina e processo para polimerizar olefinas |
Country Status (7)
Country | Link |
---|---|
US (1) | US20100099833A1 (pt) |
EP (1) | EP2036928B1 (pt) |
KR (1) | KR101173267B1 (pt) |
BR (1) | BRPI0709454B8 (pt) |
MY (1) | MY151043A (pt) |
SG (1) | SG189559A1 (pt) |
WO (1) | WO2007112700A1 (pt) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2478017T3 (es) | 2009-07-15 | 2014-07-18 | China Petroleum&Chemical Corporation | Aducto de haluro de magnesio esférico, componente de catalizador y catalizador para la polimerización de olefinas preparado a partir del mismo |
CN102796127B (zh) * | 2011-05-27 | 2015-02-11 | 中国石油化工股份有限公司 | 一种球形卤化镁加合物及其制备方法和应用 |
CN103788244B (zh) * | 2012-10-29 | 2016-03-30 | 中国石油化工股份有限公司 | 一种烯烃聚合催化剂载体及其应用 |
CN103788246B (zh) * | 2012-10-29 | 2015-10-21 | 中国石油化工股份有限公司 | 一种烯烃聚合催化剂载体及其制备方法和应用 |
CN103788249B (zh) * | 2012-10-29 | 2016-01-13 | 中国石油化工股份有限公司 | 一种烯烃聚合催化剂载体及其应用 |
EP4057244A1 (en) | 2019-09-11 | 2022-09-14 | Brink's Network Inc. | Self-service modular drop safes |
EP4190822A1 (en) * | 2021-12-06 | 2023-06-07 | Clariant International Ltd | Process for the preparation of a spherical support for ziegler-natta catalyst |
KR20230138188A (ko) | 2022-03-23 | 2023-10-05 | 숭실대학교산학협력단 | 차량통과 높이판별 장치 및 그 제어방법 |
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IT1114822B (it) * | 1977-07-04 | 1986-01-27 | Montedison Spa | Componenti di catalizzatori per la polimerizzazione delle alfa-olefine |
IT1096661B (it) * | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
US4442277A (en) * | 1981-03-09 | 1984-04-10 | Phillips Petroleum Company | Process and catalyst for olefin polymerization |
IT1136627B (it) | 1981-05-21 | 1986-09-03 | Euteco Impianti Spa | Catalizzatore supportato per la polimerizzazione di etilene |
FI80055C (fi) | 1986-06-09 | 1990-04-10 | Neste Oy | Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner. |
JP2816700B2 (ja) | 1989-04-25 | 1998-10-27 | 株式会社福原精機製作所 | 丸編機における電磁選針装置 |
JP2879347B2 (ja) | 1989-10-02 | 1999-04-05 | チッソ株式会社 | オレフィン重合用触媒の製法 |
JP3205001B2 (ja) * | 1990-03-30 | 2001-09-04 | ベイセル、ノース、アメリカ、インコーポレーテッド | 超純粋プロピレン重合体 |
FI90248C (fi) | 1991-11-29 | 1994-01-10 | Borealis As | Menetelmä hiukkasmaisen kantajan valmistamiseksi olefiinipolymerointikatalyyttiä varten |
TW400342B (en) * | 1994-09-06 | 2000-08-01 | Chisso Corp | A process for producing a solid catalyst component for olefin polymerization and a process for producing an olefin polymer |
EP0717053B1 (en) * | 1994-11-25 | 2001-03-14 | Japan Polyolefins Co., Ltd. | Catalyst for olefin polymerization and process for producing polyolefin using the same |
IT1274250B (it) | 1995-02-21 | 1997-07-15 | Himont Inc | Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta |
US6323152B1 (en) | 1998-03-30 | 2001-11-27 | Basell Technology Company Bv | Magnesium dichloride-alcohol adducts process for their preparation and catalyst components obtained therefrom |
HUP0001557A3 (en) * | 1997-03-29 | 2010-01-28 | Montell Technology Company Bv | Magnesium dichloride-alcohol adducts, process for their preparation and catalyst components obtained therefrom |
CN1151183C (zh) | 2000-06-15 | 2004-05-26 | 中国石油化工股份有限公司 | 用于烯烃聚合或共聚合的球形催化剂组分及其催化剂 |
CN100441561C (zh) | 2002-02-07 | 2008-12-10 | 中国石油化工股份有限公司 | 用于制备烯烃聚合催化剂的多酯化合物 |
CN1169845C (zh) | 2002-02-07 | 2004-10-06 | 中国石油化工股份有限公司 | 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用 |
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CA2456951A1 (en) * | 2002-06-13 | 2003-12-24 | Basell Poliolefine Italia S.P.A. | Process for the preparation of ethylene copolymers |
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WO2005063832A1 (en) * | 2003-12-23 | 2005-07-14 | Basell Poliolefine Italia S.R.L. | Magnesium dichloride-ethanol adducts and atalyst components obtained therefrom |
CN1286863C (zh) | 2004-03-25 | 2006-11-29 | 浙江大学 | 球形MgCl2-醇-有机络合剂载体负载的烯烃聚合催化剂及制备方法 |
CN1289542C (zh) * | 2004-07-05 | 2006-12-13 | 中国石油化工股份有限公司 | 用于烯烃聚合反应的球形催化剂组分及其催化剂 |
CN1670043A (zh) * | 2005-03-07 | 2005-09-21 | 营口市向阳催化剂有限责任公司 | 烯烃聚合用催化剂及其制备和聚合方法 |
-
2007
- 2007-04-06 MY MYPI20083967 patent/MY151043A/en unknown
- 2007-04-06 WO PCT/CN2007/001123 patent/WO2007112700A1/zh active Application Filing
- 2007-04-06 EP EP07720696.9A patent/EP2036928B1/en active Active
- 2007-04-06 KR KR1020087026783A patent/KR101173267B1/ko active IP Right Grant
- 2007-04-06 US US12/294,980 patent/US20100099833A1/en not_active Abandoned
- 2007-04-06 BR BRPI0709454A patent/BRPI0709454B8/pt active IP Right Grant
- 2007-04-06 SG SG2011072808A patent/SG189559A1/en unknown
Also Published As
Publication number | Publication date |
---|---|
KR101173267B1 (ko) | 2012-08-10 |
BRPI0709454B1 (pt) | 2017-11-07 |
US20100099833A1 (en) | 2010-04-22 |
SG189559A1 (en) | 2013-05-31 |
BRPI0709454A8 (pt) | 2018-01-30 |
BRPI0709454A2 (pt) | 2011-07-12 |
EP2036928A1 (en) | 2009-03-18 |
KR20080112360A (ko) | 2008-12-24 |
WO2007112700A1 (en) | 2007-10-11 |
EP2036928B1 (en) | 2015-12-23 |
EP2036928A4 (en) | 2014-10-08 |
MY151043A (en) | 2014-03-31 |
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Legal Events
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B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 07/11/2017, OBSERVADAS AS CONDICOES LEGAIS. |
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B16C | Correction of notification of the grant [chapter 16.3 patent gazette] |