BR112015019437A2 - complexo de bis(2-indenil) metaloceno - Google Patents

complexo de bis(2-indenil) metaloceno

Info

Publication number
BR112015019437A2
BR112015019437A2 BR112015019437A BR112015019437A BR112015019437A2 BR 112015019437 A2 BR112015019437 A2 BR 112015019437A2 BR 112015019437 A BR112015019437 A BR 112015019437A BR 112015019437 A BR112015019437 A BR 112015019437A BR 112015019437 A2 BR112015019437 A2 BR 112015019437A2
Authority
BR
Brazil
Prior art keywords
metallocene complex
indenyl
bis
hydrocabryl
groups
Prior art date
Application number
BR112015019437A
Other languages
English (en)
Inventor
Stephan Douglas
Al-Shammari Haif
Morton Jason
Original Assignee
Saudi Basic Ind Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Ind Corp filed Critical Saudi Basic Ind Corp
Publication of BR112015019437A2 publication Critical patent/BR112015019437A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/03—Narrow molecular weight distribution, i.e. Mw/Mn < 3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/09—Long chain branches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/10—Short chain branches
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

resumo patente de invenção: "complexo de bis(2-indenil) metaloceno". a invenção refere-se a um complexo de metaloceno de acordo com a seguinte fórmula (1) em que r1 e r2 são os mesmos ou diferentes e são selecionados de modo independente entre o grupo consistindo de grupamentos de hidrocabrila lineares e ramificados, substituídos e não substituídos compreendendo 1 a 30 átomos de carbono; m é titânio, zircônio, ou háfnio e x1 e x2 são os mesmos e são selecionados entre o grupo consistindo de halogênio e grupamentos de hidrocabrila compreendendo 1 a 20 átomos de carbono.
BR112015019437A 2013-03-12 2014-03-10 complexo de bis(2-indenil) metaloceno BR112015019437A2 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13001242 2013-03-12
US201461927084P 2014-01-14 2014-01-14
PCT/EP2014/054578 WO2014139949A1 (en) 2013-03-12 2014-03-10 Bis(2-indenyl) metallocene complex

Publications (1)

Publication Number Publication Date
BR112015019437A2 true BR112015019437A2 (pt) 2017-07-18

Family

ID=47877720

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015019437A BR112015019437A2 (pt) 2013-03-12 2014-03-10 complexo de bis(2-indenil) metaloceno

Country Status (7)

Country Link
US (1) US9156929B2 (pt)
EP (1) EP2970348A1 (pt)
JP (1) JP2016516019A (pt)
CN (1) CN105073764A (pt)
BR (1) BR112015019437A2 (pt)
RU (1) RU2015143202A (pt)
WO (1) WO2014139949A1 (pt)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9045568B2 (en) * 2012-08-03 2015-06-02 Exxonmobil Chemical Patents Inc. Vinyl terminated polyethylene with long chain branching
CN104411778B (zh) * 2012-08-03 2017-07-28 埃克森美孚化学专利公司 使用改性的Salan催化剂化合物制备的聚α烯烃
US9382349B2 (en) * 2012-08-03 2016-07-05 Exxonmobil Chemical Patents Inc. Polyalphaolefins prepared using modified Salan catalyst compounds
US10400048B2 (en) 2015-05-27 2019-09-03 Sabic Global Technologies B.V. Catalyst comprising a metallocene complex and a co-catalyst
WO2017118617A1 (en) 2016-01-05 2017-07-13 Sabic Global Technologies B.V. Catalyst comprising a metallocene complex and a co-catalyst
CN110650978B (zh) * 2017-04-04 2022-09-23 Sabic环球技术有限责任公司 用于烯烃聚合的二甲基-甲硅烷基-桥连的-1-取代-2-茚基茂金属复合物
EP3606930B1 (en) 2017-04-04 2021-03-31 SABIC Global Technologies B.V. Dihydrocarbyl-silyl-bridged-1.3 disubstituted-2-indenyl metallocene complexes for olefin polymerization
WO2020043815A1 (en) * 2018-08-30 2020-03-05 Sabic Global Technologies B.V. Substituted bis-2-indenyl metallocene compounds
WO2021052797A1 (en) 2019-09-20 2021-03-25 Sabic Global Technologies B.V. Compounds for use in catalyst compositions for the production of polyolefins
EP4110834B1 (en) * 2020-02-24 2024-04-03 ExxonMobil Chemical Patents Inc. Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2952697A (en) * 1958-10-07 1960-09-13 Ethyl Corp Cyclopentadienyl metal compounds
US4003712A (en) 1970-07-29 1977-01-18 Union Carbide Corporation Fluidized bed reactor
DE3743321A1 (de) * 1987-12-21 1989-06-29 Hoechst Ag 1-olefinpolymerwachs und verfahren zu seiner herstellung
DE3922546A1 (de) * 1989-07-08 1991-01-17 Hoechst Ag Verfahren zur herstellung von cycloolefinpolymeren
ATE136040T1 (de) * 1991-05-27 1996-04-15 Hoechst Ag Verfahren zur herstellung von polyolefinen mit breiter molmassenverteilung
DE4121368A1 (de) * 1991-06-28 1993-01-07 Hoechst Ag Katalysator und verfahren zur herstellung von hochmolekularen polyolefinen
JP3379172B2 (ja) 1993-11-11 2003-02-17 東ソー株式会社 エチレン・α−オレフィン共重合体
JPH08259619A (ja) * 1995-03-20 1996-10-08 Tokuyama Corp ポリオレフィンの製造方法および触媒
EP0830395B1 (en) 1995-05-09 2001-04-11 Fina Research S.A. Process for preparing and using a supported metallocene-alumoxane catalyst
EP0786466B1 (en) 1996-01-25 2003-04-16 Tosoh Corporation Olefin polymerisation process which comprises a transition metal catalyst.
EP0969019A1 (en) 1998-07-02 2000-01-05 Fina Research S.A. Polyolefin production
EP1179553B1 (en) * 2000-08-07 2005-06-08 Total Petrochemicals Research Feluy Polyolefin production
US20050137364A1 (en) 2003-12-23 2005-06-23 Univation Technologies, Llc Condensing mode operation of gas-phase polymerization reactor
CN1637023A (zh) * 2004-12-09 2005-07-13 中山大学 乙烯聚合单核及多核苊二亚胺镍催化剂及其制备方法

Also Published As

Publication number Publication date
EP2970348A1 (en) 2016-01-20
US9156929B2 (en) 2015-10-13
JP2016516019A (ja) 2016-06-02
CN105073764A (zh) 2015-11-18
US20140275455A1 (en) 2014-09-18
RU2015143202A (ru) 2017-04-17
WO2014139949A1 (en) 2014-09-18

Similar Documents

Publication Publication Date Title
BR112015019437A2 (pt) complexo de bis(2-indenil) metaloceno
TN2018000262A1 (en) Substituted piperidine compound and use there of.
BR112016007427A2 (pt) compostos de pirazol-amida e usos dos mesmos
EA201600091A1 (ru) 4-членные кольцевые карбоксамиды, применяемые в качестве нематоцидов
BR112015011528A2 (pt) películas que compreendem polímeros à base de etileno e métodos para produzir as mesmas
UA113643C2 (xx) N-цикліламіди як нематоциди
RS54873B1 (sr) Policiklična-karbamoilpiridonska jedinjenja i njihova farmaceutska upotreba
BR112016004919A2 (pt) Inibidores de polimerase de hcv
BR112012013201A2 (pt) derivado de azol, composto intermediário, métodos para produzir o derivado de azol e o composto intermediário, e, agente de agro-horticultura ou um agente protetor de material industrial.
BR112016007757A8 (pt) Derivados antibacterianos de 2h-indazol
BR112014006660A2 (pt) novos derivados de dihidroquinolina-2-ona bicíclicos
MA39152B1 (fr) Cyclopentanes substitués en 1,2 utilisés comme antagonistes du récepteur d&#39;orexine
BR112015021794A2 (pt) fibras finas feitas a partir de aditivos de reação
BR112012029133A2 (pt) abrilhantadores óticos e composições compreendendo os mesmos
BR112015023829A2 (pt) composto de amidina e seu uso
BR112013004624A2 (pt) &#34;derivados de furopiridina&#34;
BR112015017740A2 (pt) composto heterocíclico condensado
BR112017011883A2 (pt) composição de organosiloxano com alto índice de refração e aplicações contendo a mesma
RS54716B1 (en) HETEROCYCLIC COMPOUNDS AND THEIR APPLICATIONS
BR112018005742A2 (pt) composição tópica, método para desinfecção de uma superfície, utilização da composição e utilizações de uma composição
CR20150417A (es) Compuestos de azetidiniloxifenilpirrolidina
TR201819155T4 (tr) Yeni izoindolin veya izokinolin bileşikleri, bunların hazırlanması için bir yöntem ve bunları içeren farmasötik bileşimler.
BR112016007460A2 (pt) processo para a preparação de xanthohumol
BR112015020834A2 (pt) novos derivados hidroquinolina-2-ona como inibidores de aldosterona sintetase (cyp1 1 b2 ou cyp1 1 b1)
MA39305A3 (fr) Dérivés d&#39;éthynyle

Legal Events

Date Code Title Description
B08F Application fees: application dismissed [chapter 8.6 patent gazette]

Free format text: REFERENTE A 5A ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2506 DE 15-01-2019 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.