BR0305627A - Sistema catalisador para a polimerização de olefinas - Google Patents

Sistema catalisador para a polimerização de olefinas

Info

Publication number
BR0305627A
BR0305627A BR0305627-9A BR0305627A BR0305627A BR 0305627 A BR0305627 A BR 0305627A BR 0305627 A BR0305627 A BR 0305627A BR 0305627 A BR0305627 A BR 0305627A
Authority
BR
Brazil
Prior art keywords
catalyst system
olefin polymerization
group
halogenated
halogen atoms
Prior art date
Application number
BR0305627-9A
Other languages
English (en)
Inventor
Luigi Resconi
Francesca Focante
Isabella Camurati
Simona Guidotti
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Publication of BR0305627A publication Critical patent/BR0305627A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/027—Organoboranes and organoborohydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

"SISTEMA CATALISADOR PARA A POLIMERIZAçãO DE OLEFINAS". Um composto organometálico que pode ser obtido pela colocação em contato de: um composto apresentando a seguinte fórmula (I) na qual: R^ a^ é um radical hidrocarbono; R^ b^, R^ c^ R^ d^ São átomos de hidrogênio, átomos de halogênio ou radicais hidrocarbónicos; com um ácido de Lewis de fórmula (II) MtR^ 1^~ 3~ (II) no qual Mt é um metal pertencente ao grupo 13 da Tabela Periódica dos Elementos; R^ 1~ é selecionado do grupo que consiste de átomos de halogênio, grupos aril C~ 6~-C~ 20~ halogenados e alquilaril C~ 7~-C~ 20~ halogenados.
BR0305627-9A 2002-07-09 2003-07-09 Sistema catalisador para a polimerização de olefinas BR0305627A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US39461402P 2002-07-09 2002-07-09
PCT/EP2003/007485 WO2004005360A2 (en) 2002-07-09 2003-07-09 Catalyst system for the polymerization of olefins

Publications (1)

Publication Number Publication Date
BR0305627A true BR0305627A (pt) 2004-09-08

Family

ID=30115746

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0305627-9A BR0305627A (pt) 2002-07-09 2003-07-09 Sistema catalisador para a polimerização de olefinas

Country Status (7)

Country Link
US (1) US7314903B2 (pt)
EP (1) EP1611167A2 (pt)
JP (1) JP2006508903A (pt)
CN (1) CN100532400C (pt)
AU (1) AU2003257448A1 (pt)
BR (1) BR0305627A (pt)
WO (1) WO2004005360A2 (pt)

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WO2004022613A1 (en) 2002-09-06 2004-03-18 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
EP1549688A2 (en) * 2002-10-10 2005-07-06 Basell Polyolefine GmbH Process for the copolymerization of ethylene
US7741417B2 (en) 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
WO2005105865A1 (en) 2004-05-04 2005-11-10 Basell Polyolefine Gmbh Process for the preparation of atactic 1-butene polymers
EP1794197A4 (en) 2004-09-16 2009-07-01 Lg Chemical Ltd CATALYST SYSTEM FOR POLYMERIZATION OF CYCLIC OLEFIN HAVING POLAR FUNCTIONAL GROUP, POLYMERIZATION METHOD USING THE CATALYST SYSTEM, OLEFIN POLYMER PRODUCED THEREBY, AND OPTICAL ANISOTROPIC FILM COMPRISING THE OLEFIN POLYMER
EP1805231B1 (en) * 2004-10-18 2010-03-31 Basell Poliolefine Italia S.r.l. Butene-1 (co)polymers having low isotacticity
CN101044172B (zh) * 2004-10-21 2010-09-29 巴塞尔聚烯烃股份有限公司 1-丁烯聚合物及其制备方法
EP1655314A1 (en) * 2004-11-09 2006-05-10 Basell Polyolefine GmbH Process for the preparation of 1-butene/propylene copolymers
KR20070093058A (ko) * 2004-11-22 2007-09-17 바젤 폴리올레핀 게엠베하 프로필렌 기재 삼중합체
EP1825036A1 (en) * 2004-12-13 2007-08-29 Basell Poliolefine Italia S.r.l. Polyolefin composition, fibres and nonwoven fabrics
WO2006082176A1 (en) * 2005-02-03 2006-08-10 Basell Polyolefine Gmbh Process for producing thermoformed articles
WO2006097497A1 (en) * 2005-03-18 2006-09-21 Basell Polyolefine Gmbh Metallocene compounds
JP2008536813A (ja) * 2005-03-18 2008-09-11 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物
JP2008534705A (ja) 2005-03-23 2008-08-28 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィン類の重合法
EP1861436B1 (en) * 2005-03-23 2014-04-16 Basell Polyolefine GmbH Process for the polymerization of olefins
EP1877453A1 (en) * 2005-05-03 2008-01-16 Basell Polyolefine GmbH Process for the polymerization of alpha olefins
JP2008540752A (ja) 2005-05-11 2008-11-20 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ポリオレフィンブレンドを製造するための重合方法
US8051611B2 (en) * 2005-06-24 2011-11-08 Dryvit Systems, Inc. Exterior insulation and finish system and method and tool for installing same
US20090118451A1 (en) * 2005-10-21 2009-05-07 Basell Polyolefine Gmbh Polypropylene Random Copolymers Having High Melt Flow Rates for Injection Molding and Melt Blown Applications
WO2007045603A1 (en) * 2005-10-21 2007-04-26 Basell Polyolefine Gmbh Propylene polymers
US8394907B2 (en) * 2005-10-21 2013-03-12 Basell Polyolefine Gmbh Polypropylene for injection molding
WO2007065816A2 (en) * 2005-12-06 2007-06-14 Basell Poliolefine Italia S.R.L. Catalyst components for the polymerization of olefins
WO2007088204A2 (en) * 2006-02-02 2007-08-09 Basell Polyolefine Gmbh Propylene melt blown resins, propylene melt blown resin fibers and non-woven fabric made from the same, and methods of making the same
ATE461244T1 (de) * 2006-02-23 2010-04-15 Basell Poliolefine Srl Propylenpolymere für spritzgiessanwendungen
JP5295098B2 (ja) * 2006-04-21 2013-09-18 バーゼル・ポリオレフィン・ゲーエムベーハー エチレンコポリマーの製造方法
EP2010579A1 (en) * 2006-04-21 2009-01-07 Basell Polyolefine GmbH Process for the preparation of ethylene propylene copolymers
US8022005B2 (en) * 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
US7799879B2 (en) 2008-08-01 2010-09-21 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
SG195587A1 (en) 2008-08-01 2013-12-30 Exxonmobil Chem Patents Inc Catalyst system and process for olefin polymerization
CN103857706B (zh) 2011-09-30 2016-09-28 埃克森美孚化学专利公司 金属茂催化剂的动力学调制
WO2015009480A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
EP3022233B1 (en) 2013-07-17 2019-05-01 ExxonMobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
WO2015009472A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemcal Patents Inc. Metallocenes and catalyst compositions derived therefrom
JP2016531978A (ja) 2013-07-17 2016-10-13 エクソンモービル ケミカル パテンツ インコーポレイテッド 置換メタロセン触媒
WO2015009471A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
US10759886B2 (en) 2015-06-05 2020-09-01 Exxonmobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
CN107922537B (zh) 2015-06-05 2021-07-27 埃克森美孚化学专利公司 气相或淤浆相中多相聚合物的制备
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
WO2016196331A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
EP3464390A1 (en) 2016-05-27 2019-04-10 ExxonMobil Chemical Patents Inc. Metallocene catalyst compositions and polymerization process therewith
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Also Published As

Publication number Publication date
US7314903B2 (en) 2008-01-01
CN100532400C (zh) 2009-08-26
AU2003257448A8 (en) 2004-01-23
WO2004005360A3 (en) 2005-11-10
AU2003257448A1 (en) 2004-01-23
JP2006508903A (ja) 2006-03-16
EP1611167A2 (en) 2006-01-04
WO2004005360A2 (en) 2004-01-15
US20060094840A1 (en) 2006-05-04
CN1832970A (zh) 2006-09-13

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B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

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