BR9810488A - Novos catalisadores. - Google Patents
Novos catalisadores.Info
- Publication number
- BR9810488A BR9810488A BR9810488-8A BR9810488A BR9810488A BR 9810488 A BR9810488 A BR 9810488A BR 9810488 A BR9810488 A BR 9810488A BR 9810488 A BR9810488 A BR 9810488A
- Authority
- BR
- Brazil
- Prior art keywords
- new catalysts
- catalysts
- new
- metaphase
- isomerization
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 150000001336 alkenes Chemical group 0.000 abstract 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006317 isomerization reaction Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 230000031864 metaphase Effects 0.000 abstract 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052762 osmium Inorganic materials 0.000 abstract 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000006798 ring closing metathesis reaction Methods 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1825—Ligands comprising condensed ring systems, e.g. acridine, carbazole
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0013—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/002—Osmium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
- B01J2231/14—Other (co) polymerisation, e.g. of lactides, epoxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/825—Osmium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Patende de Invenção: <B>"NOVOS CATALISADORES"<D>. A invenção refere-se a novos catalisadores de rutênio e ósmio carbeno com ligantes doadores de e^ -^ em ponte coordenados no metal, a sua preparação e a seu uso para a síntese de polímeros, para metátase de fechamento de anel de olefinas e para isomerização de olefinas.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH156297 | 1997-06-27 | ||
PCT/EP1998/003781 WO1999000397A1 (en) | 1997-06-27 | 1998-06-20 | Ruthenium and osmium catalysts |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9810488A true BR9810488A (pt) | 2000-09-12 |
Family
ID=4213330
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9810488-8A BR9810488A (pt) | 1997-06-27 | 1998-06-20 | Novos catalisadores. |
Country Status (11)
Country | Link |
---|---|
US (1) | US6306987B1 (pt) |
EP (1) | EP0993466B1 (pt) |
JP (1) | JP2002506455A (pt) |
KR (1) | KR100569620B1 (pt) |
AU (1) | AU8800498A (pt) |
BR (1) | BR9810488A (pt) |
CA (1) | CA2289709A1 (pt) |
DE (1) | DE69819501T2 (pt) |
ES (1) | ES2209185T3 (pt) |
MX (1) | MX210210B (pt) |
WO (1) | WO1999000397A1 (pt) |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7507854B2 (en) | 1998-09-01 | 2009-03-24 | Materia, Inc. | Impurity reduction in Olefin metathesis reactions |
US6696597B2 (en) | 1998-09-01 | 2004-02-24 | Tilliechem, Inc. | Metathesis syntheses of pheromones or their components |
US6900347B2 (en) | 1998-09-01 | 2005-05-31 | Tilliechem, Inc. | Impurity inhibition in olefin metathesis reactions |
DE19840107A1 (de) * | 1998-09-03 | 2000-03-09 | Bayer Ag | Verfahren zur Synthese alpha-substituierter Ringsysteme |
IT1314204B1 (it) * | 1999-10-28 | 2002-12-06 | Sigea Srl | Complessi di rutenio con elevata attivita' antitumorale |
CN102146031B (zh) * | 2001-03-26 | 2014-08-06 | 陶氏环球技术有限责任公司 | 不饱和脂肪酸酯或不饱和脂肪酸与低级烯烃的置换方法 |
ATE409581T1 (de) * | 2001-08-30 | 2008-10-15 | Materia Inc | Infusion von zyklischen olefinharzen in poröse materialien |
JP4138417B2 (ja) * | 2001-09-28 | 2008-08-27 | 積水化学工業株式会社 | 有機金属化合物の合成方法 |
WO2003044060A2 (en) | 2001-11-15 | 2003-05-30 | Materia, Inc. | Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts |
EP1501784B1 (en) | 2002-04-29 | 2019-03-13 | Dow Global Technologies LLC | Integrated chemical processes for industrial utilization of seed oils |
US6844409B2 (en) * | 2002-05-06 | 2005-01-18 | Kerr Corporation | Composition curable by metathesis reaction |
US7060769B2 (en) * | 2003-05-06 | 2006-06-13 | Kerr Corporation | Method of curing composition by metathesis reaction using reaction control agent |
US7060770B2 (en) * | 2003-05-06 | 2006-06-13 | Kerr Corporation | Metathesis-curable composition with a reaction control agent |
US7173097B2 (en) | 2003-05-06 | 2007-02-06 | Kerr Corporation | Metathesis-curable composition with a reaction control agent |
US7683148B2 (en) | 2003-05-06 | 2010-03-23 | Kerr Corporation | Metathesis-curable composition with a reaction control agent |
JP4779121B2 (ja) | 2003-10-09 | 2011-09-28 | ダウ グローバル テクノロジーズ エルエルシー | 不飽和アルコールの改良合成方法 |
US7109344B2 (en) * | 2003-12-04 | 2006-09-19 | Boehringer Ingelheim International Gmbh | Ruthenium catalyst |
JP2007513200A (ja) * | 2003-12-08 | 2007-05-24 | ベーリンガー インゲルハイム インターナショナル ゲゼルシャフト ミット ベシュレンクテル ハフツング | 超臨界流体処理によるルテニウム副生物の除去 |
DE102004002178A1 (de) | 2004-01-15 | 2005-08-11 | Ivoclar Vivadent Ag | Dentalmeterialien auf der Basis von RÖMP-Kompositen |
AU2011205218B2 (en) * | 2004-03-29 | 2015-12-17 | California Institute Of Technology | Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand |
US20050261451A1 (en) * | 2004-03-29 | 2005-11-24 | California Institute Of Technology | Latent, high-activity olefin metathesis catalysts containing an N-heterocyclic carbene ligand |
US7645443B2 (en) * | 2004-11-15 | 2010-01-12 | Kerr Corporation | Polyether-based composition curable by metathesis reaction |
US7001590B1 (en) | 2004-11-15 | 2006-02-21 | Kerr Corporation | Metathesis-curable composition |
US7625551B2 (en) * | 2004-11-15 | 2009-12-01 | Kerr Corporation | Polyether-based dental impression material curable by metathesis reaction |
US7608614B2 (en) | 2005-03-08 | 2009-10-27 | Boehringer Ingelheim International Gmbh | Process for preparing macrocyclic compounds |
JP5190364B2 (ja) | 2005-09-09 | 2013-04-24 | ベーリンガー インゲルハイム インターナショナル ゲゼルシャフト ミット ベシュレンクテル ハフツング | 大環状ペプチドの調製の為の閉環メタセシス工程 |
ES2349861T3 (es) * | 2005-11-09 | 2011-01-12 | Boehringer Ingelheim International Gmbh | Preparación de catalizadores. |
KR20080090390A (ko) | 2005-11-16 | 2008-10-08 | 에스*바이오 피티이 리미티드 | 헤테로알킬이 결합된 피리미딘 유도체 |
JP2007246900A (ja) * | 2006-02-21 | 2007-09-27 | Kerr Corp | 官能性オレフィン基で末端封止されたアルコキシ−シロキサンポリエーテルカルボキシレートの製造方法 |
PL379879A1 (pl) | 2006-06-07 | 2007-12-10 | Umicore Ag & Co.Kg. | Kompleksy rutenu i osmu, sposób ich wytwarzania oraz ich zastosowanie jako (pre)katalizatorów reakcji metatezy |
KR101461682B1 (ko) * | 2006-06-30 | 2014-11-13 | 에프. 호프만-라 로슈 아게 | 메타세시스 반응용 촉매로서의 신규한 루테늄 착체 |
DE102007020694A1 (de) | 2007-05-03 | 2008-11-06 | Evonik Degussa Gmbh | Schwefelhaltige Metathesekatalysatoren |
US8241575B2 (en) | 2008-01-28 | 2012-08-14 | The Johns Hopkins University | Molecularly imprinted polymer sensor device |
JP5365625B2 (ja) * | 2008-03-31 | 2013-12-11 | 日本ゼオン株式会社 | 重合性組成物、樹脂成形体、及び架橋樹脂成形体 |
US8436110B2 (en) | 2008-10-31 | 2013-05-07 | Dow Global Technologies Llc | Olefin metathesis process employing bimetallic ruthenium complex with bridging hydrido ligands |
KR20110124310A (ko) | 2009-02-18 | 2011-11-16 | 헨켈 코포레이션 | 열적으로 전환가능한 루테늄 개시제 |
ES2391340B1 (es) | 2010-05-11 | 2013-09-30 | Melchor Daumal Castellón | Conjunto soporte multifuncion para columna de direccion |
KR101297431B1 (ko) * | 2011-04-18 | 2013-08-19 | 주식회사 폴리사이언텍 | 폴리프로필렌계 수지조성물 및 이로부터 제조된 스크래치 자기재생성 성형품 |
PL220408B1 (pl) * | 2011-09-26 | 2015-10-30 | Inst Chemii Organicznej Polskiej Akademii Nauk | Kompleks rutentu, sposób jego wytwarzania oraz zastosowanie |
WO2017135638A1 (ko) * | 2016-02-01 | 2017-08-10 | 서울대학교산학협력단 | 설폰아미드기 또는 아미드기를 포함하는 올레핀 복분해 반응용 전이금속 착물 및 이의 응용 |
WO2018075479A1 (en) | 2016-10-19 | 2018-04-26 | Materia, Inc. | Synthesis and characterization of ru alkylidene complexes |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996004289A1 (en) * | 1992-04-03 | 1996-02-15 | California Institute Of Technology | High activity ruthenium or osmium metal carbene complexes for olefin metathesis reactions and synthesis thereof |
-
1998
- 1998-06-20 AU AU88004/98A patent/AU8800498A/en not_active Abandoned
- 1998-06-20 WO PCT/EP1998/003781 patent/WO1999000397A1/en active IP Right Grant
- 1998-06-20 KR KR19997012334A patent/KR100569620B1/ko not_active IP Right Cessation
- 1998-06-20 BR BR9810488-8A patent/BR9810488A/pt not_active Application Discontinuation
- 1998-06-20 EP EP98939522A patent/EP0993466B1/en not_active Expired - Lifetime
- 1998-06-20 ES ES98939522T patent/ES2209185T3/es not_active Expired - Lifetime
- 1998-06-20 US US09/446,052 patent/US6306987B1/en not_active Expired - Lifetime
- 1998-06-20 JP JP50526299A patent/JP2002506455A/ja not_active Withdrawn
- 1998-06-20 DE DE69819501T patent/DE69819501T2/de not_active Expired - Fee Related
- 1998-06-20 CA CA002289709A patent/CA2289709A1/en not_active Abandoned
- 1998-06-20 MX MX9911931A patent/MX210210B/es not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
MX210210B (es) | 2002-09-06 |
ES2209185T3 (es) | 2004-06-16 |
EP0993466B1 (en) | 2003-11-05 |
DE69819501D1 (de) | 2003-12-11 |
KR20010014234A (ko) | 2001-02-26 |
AU8800498A (en) | 1999-01-19 |
DE69819501T2 (de) | 2004-09-23 |
JP2002506455A (ja) | 2002-02-26 |
MX9911931A (es) | 2000-03-31 |
US6306987B1 (en) | 2001-10-23 |
KR100569620B1 (ko) | 2006-04-11 |
EP0993466A1 (en) | 2000-04-19 |
WO1999000397A1 (en) | 1999-01-07 |
CA2289709A1 (en) | 1999-01-07 |
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