BR112015030657A2 - método e dispositivo para tratamento de gás pela injeção de um composto em pó e de uma fase aquosa - Google Patents

método e dispositivo para tratamento de gás pela injeção de um composto em pó e de uma fase aquosa

Info

Publication number
BR112015030657A2
BR112015030657A2 BR112015030657A BR112015030657A BR112015030657A2 BR 112015030657 A2 BR112015030657 A2 BR 112015030657A2 BR 112015030657 A BR112015030657 A BR 112015030657A BR 112015030657 A BR112015030657 A BR 112015030657A BR 112015030657 A2 BR112015030657 A2 BR 112015030657A2
Authority
BR
Brazil
Prior art keywords
injecting
aqueous phase
gas
powdered compound
treating gas
Prior art date
Application number
BR112015030657A
Other languages
English (en)
Other versions
BR112015030657B1 (pt
Inventor
Laudet Alain
Brasseur Alain
Nyssen Olivier
Pettiau Xavier
Original Assignee
Lhoist Rech Et Developpement Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lhoist Rech Et Developpement Sa filed Critical Lhoist Rech Et Developpement Sa
Publication of BR112015030657A2 publication Critical patent/BR112015030657A2/pt
Publication of BR112015030657B1 publication Critical patent/BR112015030657B1/pt

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes
    • B01D53/83Solid phase processes with moving reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/38Removing components of undefined structure
    • B01D53/40Acidic components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/504Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/80Semi-solid phase processes, i.e. by using slurries
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/003Arrangements of devices for treating smoke or fumes for supplying chemicals to fumes, e.g. using injection devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J7/00Arrangement of devices for supplying chemicals to fire
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/30Alkali metal compounds
    • B01D2251/304Alkali metal compounds of sodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/40Alkaline earth metal or magnesium compounds
    • B01D2251/404Alkaline earth metal or magnesium compounds of calcium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/602Oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/606Carbonates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/11Clays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/20Halogens or halogen compounds
    • B01D2257/204Inorganic halogen compounds
    • B01D2257/2045Hydrochloric acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/20Halogens or halogen compounds
    • B01D2257/204Inorganic halogen compounds
    • B01D2257/2047Hydrofluoric acid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/302Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/60Heavy metals or heavy metal compounds
    • B01D2257/602Mercury or mercury compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/12Methods and means for introducing reactants
    • B01D2259/126Semi-solid reactants, e.g. slurries
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • B01D53/10Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds with dispersed adsorbents
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00Treatment devices
    • F23J2219/50Sorption with semi-dry devices, e.g. with slurries

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

resumo da patente de invenção para: "método e dispositivo para tratamento de gás pela injeção de um composto em pó". a invenção se refere a um método para o tratamento de um gás compreendendo as seguintes etapas: injeção de um composto em pó para dentro da linha de gás, injeção de uma fase aquosa como gotas no interior da dita linha, capturando poluentes dos gases, e a recuperação do dito composto em pó separadamente. a etapa de injeção de uma fase aquosa na forma de gotas é feita de modo a umedecer as partículas de composto em pó na linha de gás, quando eles são injetados.
BR112015030657-8A 2013-06-25 2014-06-20 Método e dispositivo para tratamento de gás pela injeção de um composto em pó e de uma fase aquosa BR112015030657B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
BE20130435A BE1021596B9 (fr) 2013-06-25 2013-06-25 Procede et dispositif de traitement de gaz par injection de compose pulverulent.
BE2013/0435 2013-06-25
PCT/EP2014/063017 WO2014206880A1 (fr) 2013-06-25 2014-06-20 Procede et dispositif de traitement de gaz par injection de compose pulverulent et de phase aqueuse

Publications (2)

Publication Number Publication Date
BR112015030657A2 true BR112015030657A2 (pt) 2017-07-25
BR112015030657B1 BR112015030657B1 (pt) 2021-08-31

Family

ID=49110945

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015030657-8A BR112015030657B1 (pt) 2013-06-25 2014-06-20 Método e dispositivo para tratamento de gás pela injeção de um composto em pó e de uma fase aquosa

Country Status (17)

Country Link
US (1) US9579601B2 (pt)
EP (1) EP3013459B1 (pt)
JP (1) JP6059828B2 (pt)
AU (1) AU2014301338B2 (pt)
BE (1) BE1021596B9 (pt)
BR (1) BR112015030657B1 (pt)
CA (1) CA2913240C (pt)
CL (1) CL2015003573A1 (pt)
DK (1) DK3013459T3 (pt)
ES (1) ES2615804T3 (pt)
FR (1) FR3007297A1 (pt)
MY (1) MY164819A (pt)
PL (1) PL3013459T3 (pt)
PT (1) PT3013459T (pt)
SG (1) SG11201510356TA (pt)
WO (1) WO2014206880A1 (pt)
ZA (1) ZA201509110B (pt)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7827032B2 (en) 2005-02-04 2010-11-02 Vocollect, Inc. Methods and systems for adapting a model for a speech recognition system
US8914290B2 (en) 2011-05-20 2014-12-16 Vocollect, Inc. Systems and methods for dynamically improving user intelligibility of synthesized speech in a work environment
US9978395B2 (en) 2013-03-15 2018-05-22 Vocollect, Inc. Method and system for mitigating delay in receiving audio stream during production of sound from audio stream
WO2018095553A1 (en) 2016-11-28 2018-05-31 S.A. Lhoist Recherche Et Developpement Process for pneumatically conveying a powdery material
TW201825375A (zh) 2016-11-28 2018-07-16 比利時商耐斯赤理查發展公司 氣動傳送粉狀材料之方法
CN108392946A (zh) * 2018-04-13 2018-08-14 河南科技大学第附属医院 一种双极电凝钳的烟气净化处理装置
WO2020208000A1 (en) * 2019-04-09 2020-10-15 S.A. Lhoist Recherche Et Developpement Device and method to disperse sorbent particles in a flue gas duct
CN110102171A (zh) * 2019-04-26 2019-08-09 核工业北京化工冶金研究院 一种锂云母矿预处理尾气吸收装置及方法
CN112696680A (zh) * 2020-12-26 2021-04-23 浙江大学 利用磷基耦合碱性材料抑制固废焚烧生成二噁英的方法
CN113385027A (zh) * 2021-08-17 2021-09-14 佛山赛因迪环保科技有限公司 一种脱硫剂及其制备方法和应用
CN115624862B (zh) * 2022-10-13 2023-08-18 大唐长春第三热电厂 一种自动化喷氨格栅

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5239382B2 (pt) * 1972-05-24 1977-10-05
US4456181A (en) * 1982-04-19 1984-06-26 Bete Fog Nozzle, Inc. Gas liquid mixing nozzle
JPS61287419A (ja) * 1985-04-24 1986-12-17 オサケ イフテイオ タンペラ ア−ベ− 炉の煙道ガスから気体硫黄化合物を除去する方法
US4670238A (en) * 1986-01-15 1987-06-02 Conoco Inc. Recycled sorbent flue gas desulfurization
JPH0611119Y2 (ja) * 1987-12-09 1994-03-23 三井造船株式会社 粉体噴霧用ノズル
US5223239A (en) * 1990-07-24 1993-06-29 Research Corporation Technologies, Inc. Method of preparing hydrated lime
JP3308286B2 (ja) * 1990-11-10 2002-07-29 バブコック日立株式会社 乾式排煙脱硫装置および方法
JPH06182145A (ja) * 1992-12-21 1994-07-05 Babcock Hitachi Kk 排ガス脱硫装置
JPH06312118A (ja) * 1993-04-28 1994-11-08 Babcock Hitachi Kk 乾式排ガス脱硫方法および装置
JPH07241437A (ja) * 1994-03-08 1995-09-19 Babcock Hitachi Kk 乾式排ガス脱硫装置
US5603453A (en) * 1994-12-30 1997-02-18 Lab S.A. Dual fluid spray nozzle
WO1997009110A1 (fr) * 1995-09-08 1997-03-13 Hitachi Zosen Corporation Procede et dispositif de traitement des gaz d'echappement
BE1009692A3 (fr) 1995-10-19 1997-07-01 Lhoist Rech & Dev Sa PARTICULES DE Ca(OH)2.
JPH09173766A (ja) * 1995-12-25 1997-07-08 Ishikawajima Harima Heavy Ind Co Ltd 高濃度硫黄酸化物処理システム
US5795548A (en) * 1996-03-08 1998-08-18 Mcdermott Technology, Inc. Flue gas desulfurization method and apparatus
JP3340329B2 (ja) * 1996-10-30 2002-11-05 日立造船株式会社 脱硫・脱塩用粉末薬剤供給ノズル
JP3306329B2 (ja) * 1997-02-10 2002-07-24 日本碍子株式会社 噴霧ノズル
US5965095A (en) * 1997-05-05 1999-10-12 Electric Power Research Inst. Flue gas humidification and alkaline sorbent injection for improving vapor phase selenium removal efficiency across wet flue gas desulfurization systems
US6451281B1 (en) * 2001-05-30 2002-09-17 Mississippi Lime Company Methods of manufacturing micro-particulated hydrate slurries
US6818043B1 (en) * 2003-01-23 2004-11-16 Electric Power Research Institute, Inc. Vapor-phase contaminant removal by injection of fine sorbent slurries
JP2005012197A (ja) * 2003-05-26 2005-01-13 Sumitomo Heavy Ind Ltd エアロゾル洗浄方法及び装置
BE1016661A3 (fr) 2005-06-28 2007-04-03 Lhoist Rech & Dev Sa Composition de chaux pulverulente, son procede de fabrication et son utilisation.
CN201168568Y (zh) * 2008-01-22 2008-12-24 上海中芬电气工程有限公司 水-石灰粉组合喷枪
US8313555B2 (en) * 2008-11-21 2012-11-20 Allied Environmental Solutions, Inc. Method and apparatus for circulating fluidized bed scrubber automated temperature setpoint control
US8961912B2 (en) * 2011-03-28 2015-02-24 Mississippi Lime Company Methods for reducing the acidic gas content of effluent gases
JP5993351B2 (ja) * 2013-06-25 2016-09-14 株式会社エーアンドエーマテリアル 吹付けノズル

Also Published As

Publication number Publication date
JP6059828B2 (ja) 2017-01-11
AU2014301338B2 (en) 2016-08-25
CA2913240A1 (fr) 2014-12-31
JP2016530981A (ja) 2016-10-06
US20160129394A1 (en) 2016-05-12
BE1021596B9 (fr) 2018-06-18
EP3013459B1 (fr) 2017-01-11
BE1021596B1 (fr) 2015-12-17
WO2014206880A1 (fr) 2014-12-31
AU2014301338A1 (en) 2015-12-24
DK3013459T3 (en) 2017-02-27
ES2615804T3 (es) 2017-08-25
ZA201509110B (en) 2017-11-29
PT3013459T (pt) 2017-02-17
CA2913240C (fr) 2016-11-22
CL2015003573A1 (es) 2016-07-15
BR112015030657B1 (pt) 2021-08-31
SG11201510356TA (en) 2016-01-28
FR3007297A1 (fr) 2014-12-26
MY164819A (en) 2018-01-30
EP3013459A1 (fr) 2016-05-04
US9579601B2 (en) 2017-02-28
PL3013459T3 (pl) 2017-07-31

Similar Documents

Publication Publication Date Title
BR112015030657A2 (pt) método e dispositivo para tratamento de gás pela injeção de um composto em pó e de uma fase aquosa
IL289016A (en) Methods and medical preparation for the treatment and prevention of cardiomyopathy resulting from energy failure
HRP20181863T1 (hr) Derivati sulfamoiltiofenamida i njihova uporaba kao lijekova za liječenje hepatitisa b
HK1217326A1 (zh) 經乙醛酰胺取代的吡咯酰胺衍生物及其作為藥物用於治療乙型肝炎的用途
MY185221A (en) New thienopyrimidine derivatives, a process for their preparation and pharmaceutical compositions containing them
GB2513061B (en) Method, composition and apparatus for functionalization of aerosols from non combustible smoking articles
HK1218117A1 (zh) 氨磺酰基吡咯酰胺衍生物及其作爲藥物用於治療乙型肝炎的用途
HK1217330A1 (zh) -苯基-氨甲酰衍生物及其作爲藥物用於治療乙型肝炎的用途
PL2986304T3 (pl) Kompozycja farmaceutyczna, sposoby leczenia i jej zastosowania
IL245112A0 (en) A compressed heterocyclic compound, a method for its preparation, a pharmaceutical preparation and its uses
ME02635B (me) Novi derivati pirola, postupak njihove priprave i farmaceutski pripravci koji ih sadrže
EP2947084A4 (en) 5-CHAIN HETEROCYCLIC COMPOUND, PREPARATION METHOD, PHARMACEUTICAL COMPOSITION AND APPLICATION THEREOF
HK1201536A1 (zh) 新的磷酸酯化合物、它們的製備方法和包含它們的藥物組合物
ZA201401613B (en) Method for producing highly pure platinum powder, as well as platinum powder that can be obtained according to said method, and use thereof
EP2990433A4 (en) INORGANIC FINE PARTICLE BODY, METHOD FOR THE PRODUCTION THEREOF, COMPOSITION AND CURED PRODUCT
EP2917224A4 (en) METAL-ORGANIC MATERIALS (MOMS) FOR ADSORPTION OF POLARIZABLE GASES AND METHOD FOR THE USE OF MOMS
HK1211021A1 (en) 2-substituted-6-biarylmethylamino-9-cyclopentyl-9h-purine derivatives, use thereof as medicaments, and pharmaceutical compositions 2--6--9--9h-
PT2964694T (pt) Método de tratamento de materiais carbonáceos por vapotermólise
EP3042913A4 (en) CYCLIC PEPTIDE COMPOUND, AND PREPARATION METHOD, PHARMACEUTICAL COMPOSITION AND USE THEREOF
IL236562A0 (en) A pharmaceutical preparation with an improved flow capacity, a medical agent, and a method for its production and use
EP2949657A4 (en) CYCLIC OCTAPEPTIDE, A RADIOPHARMACEUTICAL PRODUCT BASED ON THE SAME AND METHOD OF USING THE RADIOPHARMACEUTICAL PRODUCT FOR OBTAINING MEDICINAL PRODUCTS (PHARMACEUTICALS) FOR TREATING NEOPLASMS EXPRESSING SOMATOSTATIN RECEPTORS
AR087582A1 (es) Composicion para inhalacion de polvo seco, proceso, metodo

Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B350 Update of information on the portal [chapter 15.35 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 20/06/2014, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 9A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2727 DE 11-04-2023 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.