BR0312263A - Sistema catalìtico, bem como polìmero e processo de polimerização empregando o referido sistema - Google Patents
Sistema catalìtico, bem como polìmero e processo de polimerização empregando o referido sistemaInfo
- Publication number
- BR0312263A BR0312263A BR0312263-8A BR0312263A BR0312263A BR 0312263 A BR0312263 A BR 0312263A BR 0312263 A BR0312263 A BR 0312263A BR 0312263 A BR0312263 A BR 0312263A
- Authority
- BR
- Brazil
- Prior art keywords
- polymer
- well
- polymerization process
- process employing
- catalytic
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title 1
- 229920000642 polymer Polymers 0.000 title 1
- 239000012190 activator Substances 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 150000002391 heterocyclic compounds Chemical class 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 125000005234 alkyl aluminium group Chemical group 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Tires In General (AREA)
- Disintegrating Or Milling (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Indole Compounds (AREA)
- Polyethers (AREA)
Abstract
"SISTEMA CATALìTICO, BEM COMO POLìMERO E PROCESSO DE POLIMERIZAçãO EMPREGANDO O REFERIDO SISTEMA". A presente invenção refere-se a um sistema catalítico. Em um aspecto, o sistema catalítico inclui um ou mais catalisadores de polimerização e pelo menos um ativador. O ativador compreende um ou mais ligandos heterocíclicos contendo nitrogênio coordenados a um átomo do grupo 13, onde o ativador é um produto da reação de um ou mais compostos contendo um átomo do grupo 13 substituídos com alquila e um ou mais compostos heterocíclicos contendo nitrogênio, o um ou mais ligandos heterocíclicos contendo nitrogênio sendo representados por: onde cada substituinte X2, X3, X4, X5, X6 e X7 é independentemente selecionado do grupo que consiste em hidrogênio, cloro, flúor, iodo e bromo. O sistema catalítico pode ser suportado ou não-suportado.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/186,361 US6703338B2 (en) | 2002-06-28 | 2002-06-28 | Polymerization catalyst activators, method of preparing, and their use in polymerization processes |
PCT/US2003/020199 WO2004003037A1 (en) | 2002-06-28 | 2003-06-26 | Halogen substituted catalyst system for olefin polymerization |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0312263A true BR0312263A (pt) | 2005-04-26 |
Family
ID=29999290
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0305256-7A BR0305256A (pt) | 2002-06-28 | 2003-05-29 | Ativadores de catalizador de polimerização, método de preparação e seu uso em processo de polimerização |
BRPI0312210-7A BR0312210A (pt) | 2002-06-28 | 2003-06-26 | atividores e sistemas catalìticos heterocìclicos contendo nitrogênio para polimerização de olefina |
BR0312263-8A BR0312263A (pt) | 2002-06-28 | 2003-06-26 | Sistema catalìtico, bem como polìmero e processo de polimerização empregando o referido sistema |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0305256-7A BR0305256A (pt) | 2002-06-28 | 2003-05-29 | Ativadores de catalizador de polimerização, método de preparação e seu uso em processo de polimerização |
BRPI0312210-7A BR0312210A (pt) | 2002-06-28 | 2003-06-26 | atividores e sistemas catalìticos heterocìclicos contendo nitrogênio para polimerização de olefina |
Country Status (20)
Country | Link |
---|---|
US (2) | US6703338B2 (pt) |
EP (3) | EP1517930B1 (pt) |
JP (3) | JP4361862B2 (pt) |
KR (1) | KR100713748B1 (pt) |
CN (4) | CN1659193B (pt) |
AT (1) | ATE506381T1 (pt) |
AU (3) | AU2003238849B2 (pt) |
BR (3) | BR0305256A (pt) |
CA (3) | CA2488052C (pt) |
CZ (1) | CZ20041151A3 (pt) |
DE (1) | DE60336812D1 (pt) |
MX (1) | MXPA05000067A (pt) |
MY (1) | MY137541A (pt) |
NO (1) | NO20040872L (pt) |
PL (1) | PL373380A1 (pt) |
RU (1) | RU2293088C2 (pt) |
SG (1) | SG173215A1 (pt) |
TW (1) | TWI280252B (pt) |
WO (3) | WO2004003031A2 (pt) |
ZA (1) | ZA200409750B (pt) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6274684B1 (en) * | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
US6841504B2 (en) * | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
US6559251B1 (en) * | 2002-08-02 | 2003-05-06 | Equistar Chemicals, Lp | Process for making low-density polyolefins |
US7220695B2 (en) * | 2004-01-07 | 2007-05-22 | Exxonmobil Chemical Patents Inc. | Supported activator |
US7741417B2 (en) * | 2004-01-07 | 2010-06-22 | Exxonmobil Chemical Patents Inc. | Preparation of polymerization catalyst activators utilizing indole-modified silica supports |
CN101903414A (zh) * | 2007-11-08 | 2010-12-01 | 埃克森美孚化学专利公司 | 金属茂的卤素取代的杂环型含杂原子的配体-铝氧烷活化 |
US8022005B2 (en) * | 2007-11-08 | 2011-09-20 | Exxonmobil Chemical Patents Inc. | Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes |
US8524846B1 (en) | 2009-07-02 | 2013-09-03 | The University Of Toledo | Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts |
WO2014022012A1 (en) | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Vinyl terminated polyethylene with long chain branching |
US9382349B2 (en) | 2012-08-03 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified Salan catalyst compounds |
EP2880006B1 (en) | 2012-08-03 | 2017-12-20 | ExxonMobil Chemical Patents Inc. | Non-symmetric catalysts comprising salan ligands |
WO2014022011A1 (en) | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Halogenated catalysts comprising salan ligands |
US9365661B2 (en) | 2012-08-03 | 2016-06-14 | Exxonmobil Chemical Patents Inc. | Polyalphaolefins prepared using modified salan catalyst compounds |
WO2014022008A1 (en) * | 2012-08-03 | 2014-02-06 | Exxonmobil Chemical Patents Inc. | Catalysts comprising salan ligands |
CN104428324B (zh) | 2012-11-02 | 2018-08-17 | 埃克森美孚化学专利公司 | 负载型Salan催化剂 |
WO2014143202A1 (en) | 2013-03-13 | 2014-09-18 | Exxonmobil Chemical Patents Inc. | Diphenylamine salan catalyst |
US9200099B2 (en) | 2013-06-20 | 2015-12-01 | Exxonmobil Chemical Patents Inc. | Salenol catalyst |
WO2014204681A1 (en) | 2013-06-20 | 2014-12-24 | Exxonmobil Chemical Patents Inc. | Long-bridged salen catalyst |
CN105392776B (zh) * | 2013-06-20 | 2019-02-12 | 埃克森美孚化学专利公司 | 硫代-Salalen催化剂 |
US9290589B2 (en) | 2013-12-13 | 2016-03-22 | Exxonmobil Chemical Patents Inc. | Cyclopentadienyl-substituted salan catalysts |
EP3126325B1 (en) | 2014-03-31 | 2019-04-24 | ExxonMobil Chemical Patents Inc. | Phenylene-bridged salalen catalysts |
WO2016195824A1 (en) | 2015-05-29 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports |
EP3328209B2 (en) | 2015-07-31 | 2023-09-20 | Cargill, Incorporated | Method for preparing citrus fibres with optimised water binding characteristics |
Family Cites Families (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL277898A (pt) * | 1961-05-02 | |||
JPS5421391B1 (pt) * | 1969-07-10 | 1979-07-30 | ||
US4224181A (en) * | 1979-03-07 | 1980-09-23 | Exxon Research & Engineering Co. | Ziegler type catalyst system |
US4271060A (en) | 1979-09-17 | 1981-06-02 | Phillips Petroleum Company | Solution polymerization process |
US4434313A (en) * | 1981-12-14 | 1984-02-28 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
IT1178466B (it) * | 1984-03-20 | 1987-09-09 | Montedison Spa | Catalizzatori per la omo e copolimerizzazione dell'etilene e polimeri ottenuti |
US5001205A (en) | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
US5236998A (en) | 1991-03-07 | 1993-08-17 | Occidental Chemical Corporation | Process for the manufacture of linear polyethylene containing α-alkene commonomers |
US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
US5221761A (en) * | 1992-04-29 | 1993-06-22 | Instituto Guido Donegani | Melt transesterification process for the production of polycarbonates |
US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
US5804678A (en) | 1993-07-13 | 1998-09-08 | Mitsui Petrochemical Industries, Ltd. | Process for gas phase polymerization of olefin |
EP0649992B1 (de) | 1993-10-23 | 1997-07-30 | WABCO GmbH | Betätigungseinrichtung für eine Scheibenbremse |
US5763543A (en) | 1994-09-14 | 1998-06-09 | Exxon Chemical Patents Inc. | Olefin polymerization process with little or no scavenger present |
JP3830513B2 (ja) | 1994-10-13 | 2006-10-04 | エクソンモービル・ケミカル・パテンツ・インク | 重合触媒系、それらの製造及び使用 |
US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
GB9522859D0 (en) * | 1995-11-08 | 1996-01-10 | Borealis As | Compounds |
US5665818A (en) | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
US5627242A (en) | 1996-03-28 | 1997-05-06 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling gas phase fluidized bed polymerization reactor |
US5693727A (en) | 1996-06-06 | 1997-12-02 | Union Carbide Chemicals & Plastics Technology Corporation | Method for feeding a liquid catalyst to a fluidized bed polymerization reactor |
JP2000035973A (ja) * | 1996-06-11 | 2000-02-02 | Masanobu Kujirada | 遠隔匂い発生システム |
JP3889881B2 (ja) * | 1997-07-10 | 2007-03-07 | 三井化学株式会社 | オレフィン重合用触媒成分、オレフィン重合用触媒およびオレフィンの重合方法 |
EP1042373B1 (en) | 1997-12-23 | 2004-04-14 | The Dow Chemical Company | Finishing design to increase the polymer content in an olefin solution polymerization process |
ES2196835T3 (es) * | 1998-02-20 | 2003-12-16 | Dow Global Technologies Inc | Activadores cataliticos que comprenden aniones expandidos. |
CA2330529A1 (en) * | 1998-06-12 | 1999-12-16 | Univation Technologies Llc | Olefin polymerization process using activated lewis acid-base complexes |
US7354880B2 (en) | 1998-07-10 | 2008-04-08 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
CA2344170C (en) * | 1998-10-08 | 2009-02-24 | The Dow Chemical Company | Bridged metal complexes |
US6500949B2 (en) * | 1998-10-08 | 2002-12-31 | Dow Global Technologies Inc. | Bridged metal complexes |
US6147173A (en) * | 1998-11-13 | 2000-11-14 | Univation Technologies, Llc | Nitrogen-containing group 13 anionic complexes for olefin polymerization |
EP1054914B1 (de) * | 1998-12-12 | 2004-03-03 | Basell Polyolefine GmbH | Zwitterionische, neutrale übergansmetallverbindung |
KR100656109B1 (ko) * | 1999-07-29 | 2006-12-12 | 다우 글로벌 테크놀로지스 인크. | 개선된 실란 관능화 올레핀 인터폴리머 및 이의 유도체 |
WO2001023442A1 (en) * | 1999-09-27 | 2001-04-05 | The Dow Chemical Company | Supported catalyst comprising expanded anions |
AU2302001A (en) * | 1999-11-26 | 2001-06-04 | Sasol Technology (Pty) Ltd. | Hydrocarbon conversion process |
KR20010112459A (ko) | 2000-02-24 | 2001-12-20 | 간디 지오프레이 에이치. | 올레핀 중합용 조촉매로서 유용한 유기금속 화합물 |
AU2001263526A1 (en) * | 2000-05-04 | 2001-11-12 | Sasol Technology (Pty) Ltd. | A halopyrrole ligand for use in a catalyst system |
US6627573B2 (en) * | 2000-07-20 | 2003-09-30 | The Dow Chemical Company | Expanded anionic compounds comprising hydroxyl or quiescent reactive functionality and catalyst activators therefrom |
US6872844B2 (en) * | 2001-03-19 | 2005-03-29 | The Dow Chemical Company | Metal complexes containing acetylenic ligands, polymerization catalysts and addition polymerization process |
DE60202524T2 (de) * | 2001-05-21 | 2005-06-30 | Basell Polyolefine Gmbh | Katalysatorsystem für die polymerisierung von olefinen |
WO2002102863A1 (en) * | 2001-06-15 | 2002-12-27 | Dow Global Technologies Inc. | Alpha-olefin based branched polymer |
US6841504B2 (en) * | 2002-01-28 | 2005-01-11 | Univation Technologies, Llc | Polymerization catalyst activator and its use in a polymerization process |
-
2002
- 2002-06-28 US US10/186,361 patent/US6703338B2/en not_active Expired - Fee Related
-
2003
- 2003-05-29 MX MXPA05000067A patent/MXPA05000067A/es active IP Right Grant
- 2003-05-29 SG SG2006090062A patent/SG173215A1/en unknown
- 2003-05-29 EP EP03734308.4A patent/EP1517930B1/en not_active Expired - Lifetime
- 2003-05-29 CZ CZ20041151A patent/CZ20041151A3/cs unknown
- 2003-05-29 WO PCT/US2003/017165 patent/WO2004003031A2/en active Application Filing
- 2003-05-29 KR KR1020047019815A patent/KR100713748B1/ko not_active IP Right Cessation
- 2003-05-29 CA CA2488052A patent/CA2488052C/en not_active Expired - Fee Related
- 2003-05-29 JP JP2004517607A patent/JP4361862B2/ja not_active Expired - Fee Related
- 2003-05-29 CN CN038126850A patent/CN1659193B/zh not_active Expired - Fee Related
- 2003-05-29 AU AU2003238849A patent/AU2003238849B2/en not_active Ceased
- 2003-05-29 RU RU2005102068/04A patent/RU2293088C2/ru not_active IP Right Cessation
- 2003-05-29 BR BR0305256-7A patent/BR0305256A/pt not_active Application Discontinuation
- 2003-05-29 PL PL03373380A patent/PL373380A1/xx unknown
- 2003-06-23 TW TW092117000A patent/TWI280252B/zh not_active IP Right Cessation
- 2003-06-26 JP JP2004517894A patent/JP2005530907A/ja not_active Withdrawn
- 2003-06-26 EP EP03742245A patent/EP1517931B1/en not_active Expired - Lifetime
- 2003-06-26 AT AT03742245T patent/ATE506381T1/de not_active IP Right Cessation
- 2003-06-26 CA CA002488043A patent/CA2488043C/en not_active Expired - Fee Related
- 2003-06-26 CN CNB038151197A patent/CN100339403C/zh not_active Expired - Fee Related
- 2003-06-26 BR BRPI0312210-7A patent/BR0312210A/pt unknown
- 2003-06-26 DE DE60336812T patent/DE60336812D1/de not_active Expired - Lifetime
- 2003-06-26 MY MYPI20032414A patent/MY137541A/en unknown
- 2003-06-26 WO PCT/US2003/020199 patent/WO2004003037A1/en active Application Filing
- 2003-06-26 BR BR0312263-8A patent/BR0312263A/pt not_active IP Right Cessation
- 2003-06-26 AU AU2003280424A patent/AU2003280424A1/en not_active Abandoned
- 2003-06-26 CN CNB038151561A patent/CN1302029C/zh not_active Expired - Fee Related
- 2003-06-26 CA CA002489240A patent/CA2489240C/en not_active Expired - Fee Related
- 2003-06-26 WO PCT/US2003/020320 patent/WO2004003032A2/en active Application Filing
- 2003-06-26 CN CN200710102101XA patent/CN101054388B/zh not_active Expired - Fee Related
- 2003-06-26 AU AU2003280428A patent/AU2003280428A1/en not_active Abandoned
- 2003-06-26 EP EP03742270A patent/EP1517932A2/en not_active Withdrawn
- 2003-06-26 JP JP2004517963A patent/JP2005531670A/ja not_active Withdrawn
- 2003-12-12 US US10/734,871 patent/US6858689B2/en not_active Expired - Fee Related
-
2004
- 2004-02-27 NO NO20040872A patent/NO20040872L/no not_active Application Discontinuation
- 2004-12-01 ZA ZA200409750A patent/ZA200409750B/en unknown
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