DE60336812D1 - Npolymerisation - Google Patents

Npolymerisation

Info

Publication number: DE60336812D1
Authority: DE; Germany
Prior art keywords: aluminoxane; disclosed; support material; activators; heterocyclic compound
Prior art date: 2002-06-28
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

DE60336812T

Other languages

English (en)

Inventor

Matthew W Holtcamp

David A Cano

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

ExxonMobil Chemical Patents Inc

Original Assignee

ExxonMobil Chemical Patents Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2002-06-28

Filing date

2003-06-26

Publication date

2011-06-01

2003-06-26 Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc

2011-06-01 Application granted granted Critical

2011-06-01 Publication of DE60336812D1 publication Critical patent/DE60336812D1/de

2023-06-27 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000012190 activator Substances 0.000 abstract 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
150000002391 heterocyclic compounds Chemical class 0.000 abstract 2
239000000463 material Substances 0.000 abstract 2
125000005234 alkyl aluminium group Chemical group 0.000 abstract 1
229910052782 aluminium Inorganic materials 0.000 abstract 1
239000003054 catalyst Substances 0.000 abstract 1
238000000034 method Methods 0.000 abstract 1
239000002685 polymerization catalyst Substances 0.000 abstract 1
238000006116 polymerization reaction Methods 0.000 abstract 1
239000000377 silicon dioxide Substances 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Toxicology (AREA)
Materials Engineering (AREA)
Engineering & Computer Science (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Polymerisation Methods In General (AREA)
Indole Compounds (AREA)
Polyethers (AREA)
Tires In General (AREA)
Disintegrating Or Milling (AREA)
Superconductors And Manufacturing Methods Therefor (AREA)

DE60336812T 2002-06-28 2003-06-26 Npolymerisation Expired - Lifetime DE60336812D1 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US10/186,361 US6703338B2 (en)	2002-06-28	2002-06-28	Polymerization catalyst activators, method of preparing, and their use in polymerization processes
PCT/US2003/020199 WO2004003037A1 (en)	2002-06-28	2003-06-26	Halogen substituted catalyst system for olefin polymerization

Publications (1)

Publication Number	Publication Date
DE60336812D1 true DE60336812D1 (en)	2011-06-01

Family

ID=29999290

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE60336812T Expired - Lifetime DE60336812D1 (en)	2002-06-28	2003-06-26	Npolymerisation

Country Status (20)

Country	Link
US (2)	US6703338B2 (de)
EP (3)	EP1517930B1 (de)
JP (3)	JP4361862B2 (de)
KR (1)	KR100713748B1 (de)
CN (4)	CN1659193B (de)
AT (1)	ATE506381T1 (de)
AU (3)	AU2003238849B2 (de)
BR (3)	BR0305256A (de)
CA (3)	CA2488052C (de)
CZ (1)	CZ20041151A3 (de)
DE (1)	DE60336812D1 (de)
MX (1)	MXPA05000067A (de)
MY (1)	MY137541A (de)
NO (1)	NO20040872L (de)
PL (1)	PL373380A1 (de)
RU (1)	RU2293088C2 (de)
SG (1)	SG173215A1 (de)
TW (1)	TWI280252B (de)
WO (3)	WO2004003031A2 (de)
ZA (1)	ZA200409750B (de)

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US6274684B1 (en)	1999-10-22	2001-08-14	Univation Technologies, Llc	Catalyst composition, method of polymerization, and polymer therefrom
US6841504B2 (en) *	2002-01-28	2005-01-11	Univation Technologies, Llc	Polymerization catalyst activator and its use in a polymerization process
US6559251B1 (en) *	2002-08-02	2003-05-06	Equistar Chemicals, Lp	Process for making low-density polyolefins
US7741417B2 (en) *	2004-01-07	2010-06-22	Exxonmobil Chemical Patents Inc.	Preparation of polymerization catalyst activators utilizing indole-modified silica supports
US7220695B2 (en) *	2004-01-07	2007-05-22	Exxonmobil Chemical Patents Inc.	Supported activator
WO2009061678A1 (en) *	2007-11-08	2009-05-14	Exxonmobil Chemicals Patents Inc.	Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8022005B2 (en) *	2007-11-08	2011-09-20	Exxonmobil Chemical Patents Inc.	Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8524846B1 (en)	2009-07-02	2013-09-03	The University Of Toledo	Trianionic ligand precursor compounds and uses thereof in constrained geometry catalysts
US9382349B2 (en)	2012-08-03	2016-07-05	Exxonmobil Chemical Patents Inc.	Polyalphaolefins prepared using modified Salan catalyst compounds
WO2014022013A1 (en)	2012-08-03	2014-02-06	Exxonmobil Chemical Patents Inc.	Polyalphaolefins prepared using modified salan catalyst compounds
EP2880006B1 (de)	2012-08-03	2017-12-20	ExxonMobil Chemical Patents Inc.	Unsymmetrische katalysatoren mit salan-liganden
US9045568B2 (en)	2012-08-03	2015-06-02	Exxonmobil Chemical Patents Inc.	Vinyl terminated polyethylene with long chain branching
EP2882810B1 (de) *	2012-08-03	2018-01-17	ExxonMobil Chemical Patents Inc.	Katalysatoren mit salanliganden
CN104364321A (zh)	2012-08-03	2015-02-18	埃克森美孚化学专利公司	含Salan 配体的卤化催化剂
EP2914636A4 (de)	2012-11-02	2016-07-06	Exxonmobil Chem Patents Inc	Geträgerte salankatalysatoren
US8937137B2 (en)	2013-03-13	2015-01-20	Exxonmobil Chemical Patents Inc.	Diphenylamine salan catalyst
WO2014204681A1 (en)	2013-06-20	2014-12-24	Exxonmobil Chemical Patents Inc.	Long-bridged salen catalyst
WO2014204625A1 (en)	2013-06-20	2014-12-24	Exxonmobil Chemical Patents Inc.	Salenol catalyst
CN105392776B (zh) *	2013-06-20	2019-02-12	埃克森美孚化学专利公司	硫代-Salalen催化剂
CN105814015B (zh)	2013-12-13	2019-04-02	埃克森美孚化学专利公司	环戊二烯基取代的Salan催化剂
CN106132924B (zh)	2014-03-31	2019-03-19	埃克森美孚化学专利公司	亚苯基桥连的salalen催化剂
US10351647B2 (en)	2015-05-29	2019-07-16	Exxonmobil Chemical Patents Inc.	Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports
US11812775B2 (en)	2015-07-31	2023-11-14	Cargill, Incorporated	Citrus fibers with optimized water binding characteristics

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2002
- 2002-06-28 US US10/186,361 patent/US6703338B2/en not_active Expired - Fee Related
2003
- 2003-05-29 AU AU2003238849A patent/AU2003238849B2/en not_active Ceased
- 2003-05-29 SG SG2006090062A patent/SG173215A1/en unknown
- 2003-05-29 WO PCT/US2003/017165 patent/WO2004003031A2/en active Application Filing
- 2003-05-29 PL PL03373380A patent/PL373380A1/xx unknown
- 2003-05-29 CZ CZ20041151A patent/CZ20041151A3/cs unknown
- 2003-05-29 JP JP2004517607A patent/JP4361862B2/ja not_active Expired - Fee Related
- 2003-05-29 EP EP03734308.4A patent/EP1517930B1/de not_active Expired - Lifetime
- 2003-05-29 CA CA2488052A patent/CA2488052C/en not_active Expired - Fee Related
- 2003-05-29 CN CN038126850A patent/CN1659193B/zh not_active Expired - Fee Related
- 2003-05-29 KR KR1020047019815A patent/KR100713748B1/ko not_active IP Right Cessation
- 2003-05-29 RU RU2005102068/04A patent/RU2293088C2/ru not_active IP Right Cessation
- 2003-05-29 BR BR0305256-7A patent/BR0305256A/pt not_active Application Discontinuation
- 2003-05-29 MX MXPA05000067A patent/MXPA05000067A/es active IP Right Grant
- 2003-06-23 TW TW092117000A patent/TWI280252B/zh not_active IP Right Cessation
- 2003-06-26 CN CNB038151561A patent/CN1302029C/zh not_active Expired - Fee Related
- 2003-06-26 BR BRPI0312210-7A patent/BR0312210A/pt unknown
- 2003-06-26 WO PCT/US2003/020320 patent/WO2004003032A2/en active Application Filing
- 2003-06-26 EP EP03742245A patent/EP1517931B1/de not_active Expired - Lifetime
- 2003-06-26 CA CA002489240A patent/CA2489240C/en not_active Expired - Fee Related
- 2003-06-26 JP JP2004517963A patent/JP2005531670A/ja not_active Withdrawn
- 2003-06-26 WO PCT/US2003/020199 patent/WO2004003037A1/en active Application Filing
- 2003-06-26 CA CA002488043A patent/CA2488043C/en not_active Expired - Fee Related
- 2003-06-26 BR BR0312263-8A patent/BR0312263A/pt not_active IP Right Cessation
- 2003-06-26 EP EP03742270A patent/EP1517932A2/de not_active Withdrawn
- 2003-06-26 AU AU2003280428A patent/AU2003280428A1/en not_active Abandoned
- 2003-06-26 DE DE60336812T patent/DE60336812D1/de not_active Expired - Lifetime
- 2003-06-26 JP JP2004517894A patent/JP2005530907A/ja not_active Withdrawn
- 2003-06-26 CN CNB038151197A patent/CN100339403C/zh not_active Expired - Fee Related
- 2003-06-26 AT AT03742245T patent/ATE506381T1/de not_active IP Right Cessation
- 2003-06-26 AU AU2003280424A patent/AU2003280424A1/en not_active Abandoned
- 2003-06-26 MY MYPI20032414A patent/MY137541A/en unknown
- 2003-06-26 CN CN200710102101XA patent/CN101054388B/zh not_active Expired - Fee Related
- 2003-12-12 US US10/734,871 patent/US6858689B2/en not_active Expired - Fee Related
2004
- 2004-02-27 NO NO20040872A patent/NO20040872L/no not_active Application Discontinuation
- 2004-12-01 ZA ZA200409750A patent/ZA200409750B/en unknown

Also Published As

Publication number	Publication date
CN101054388A (zh)	2007-10-17
CN1665850A (zh)	2005-09-07
CA2488052A1 (en)	2004-01-08
JP2005527695A (ja)	2005-09-15
AU2003280424A1 (en)	2004-01-19
PL373380A1 (en)	2005-08-22
NO20040872L (no)	2004-04-27
CA2488043C (en)	2009-12-08
KR20050008796A (ko)	2005-01-21
RU2005102068A (ru)	2005-10-27
SG173215A1 (en)	2011-08-29
CA2488043A1 (en)	2004-01-08
US20040167016A1 (en)	2004-08-26
RU2293088C2 (ru)	2007-02-10
BR0312263A (pt)	2005-04-26
CA2489240C (en)	2009-09-22
MY137541A (en)	2009-02-27
ATE506381T1 (de)	2011-05-15
WO2004003031A3 (en)	2004-07-08
BR0305256A (pt)	2004-10-05
ZA200409750B (en)	2005-09-29
AU2003238849B2 (en)	2007-02-15
AU2003280428A1 (en)	2004-01-19
US20040005983A1 (en)	2004-01-08
JP4361862B2 (ja)	2009-11-11
BR0312210A (pt)	2007-05-29
CN100339403C (zh)	2007-09-26
CZ20041151A3 (cs)	2005-08-17
EP1517931B1 (de)	2011-04-20
AU2003280428A8 (en)	2004-01-19
CN1302029C (zh)	2007-02-28
WO2004003032A2 (en)	2004-01-08
JP2005531670A (ja)	2005-10-20
CN1659193B (zh)	2012-06-20
WO2004003031A2 (en)	2004-01-08
KR100713748B1 (ko)	2007-05-04
US6858689B2 (en)	2005-02-22
CN1665849A (zh)	2005-09-07
WO2004003032A3 (en)	2004-07-29
TWI280252B (en)	2007-05-01
JP2005530907A (ja)	2005-10-13
EP1517930B1 (de)	2016-11-02
MXPA05000067A (es)	2005-04-08
EP1517931A1 (de)	2005-03-30
US6703338B2 (en)	2004-03-09
CN101054388B (zh)	2012-09-26
WO2004003037A1 (en)	2004-01-08
EP1517932A2 (de)	2005-03-30
TW200403264A (en)	2004-03-01
EP1517930A2 (de)	2005-03-30
CA2488052C (en)	2010-08-03
CA2489240A1 (en)	2004-01-08
CN1659193A (zh)	2005-08-24
AU2003238849A1 (en)	2004-01-19

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