ITMI20041211A1 - Catalizzatori a base di complessi metallici per la sintesi di acido crisantemico otticamente attivo - Google Patents

Catalizzatori a base di complessi metallici per la sintesi di acido crisantemico otticamente attivo

Info

Publication number
ITMI20041211A1
ITMI20041211A1 IT001211A ITMI20041211A ITMI20041211A1 IT MI20041211 A1 ITMI20041211 A1 IT MI20041211A1 IT 001211 A IT001211 A IT 001211A IT MI20041211 A ITMI20041211 A IT MI20041211A IT MI20041211 A1 ITMI20041211 A1 IT MI20041211A1
Authority
IT
Italy
Prior art keywords
optically active
synthesis
metal complex
chrysanthemic acid
based catalysts
Prior art date
Application number
IT001211A
Other languages
English (en)
Inventor
Valerio Borzatta
Silvia Carloni
Raimondo Maggi
Leni Moroni
Giovanni Sartori
Giada Tanzi
Original Assignee
Endura Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Endura Spa filed Critical Endura Spa
Priority to IT001211A priority Critical patent/ITMI20041211A1/it
Publication of ITMI20041211A1 publication Critical patent/ITMI20041211A1/it
Priority to CN200580019749XA priority patent/CN1988954B/zh
Priority to AT05756849T priority patent/ATE473808T1/de
Priority to DE602005022312T priority patent/DE602005022312D1/de
Priority to EP05756849A priority patent/EP1765496B1/en
Priority to PCT/EP2005/052740 priority patent/WO2005123254A1/en
Priority to US11/629,182 priority patent/US7723539B2/en
Priority to US12/798,869 priority patent/US20100204038A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • B01J31/1625Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B01J31/1658Polymer immobilised coordination complexes, e.g. organometallic complexes immobilised by covalent linkages, i.e. pendant complexes with optional linking groups, e.g. on Wang or Merrifield resins
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00Asymmetric syntheses
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C251/00Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
    • C07C251/02Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
    • C07C251/24Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to carbon atoms of six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C07C45/298Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups with manganese derivatives
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/30Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C67/347Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by addition to unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D263/00Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/02Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
    • C07D263/08Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D263/10Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D263/14Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with radicals substituted by oxygen atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D263/00Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/52Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16Copper
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07BGENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00Indexing scheme relating to specific properties of organic compounds
    • C07B2200/11Compounds covalently bound to a solid support
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/02Systems containing only non-condensed rings with a three-membered ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
IT001211A 2004-06-16 2004-06-16 Catalizzatori a base di complessi metallici per la sintesi di acido crisantemico otticamente attivo ITMI20041211A1 (it)

Priority Applications (8)

Application Number Priority Date Filing Date Title
IT001211A ITMI20041211A1 (it) 2004-06-16 2004-06-16 Catalizzatori a base di complessi metallici per la sintesi di acido crisantemico otticamente attivo
CN200580019749XA CN1988954B (zh) 2004-06-16 2005-06-14 用于合成光学活性菊酸的金属络合物基催化剂
AT05756849T ATE473808T1 (de) 2004-06-16 2005-06-14 Katalysatoren auf basis von kupferkomplexen zur synthese von optisch aktiver chrysanthemsäure
DE602005022312T DE602005022312D1 (de) 2004-06-16 2005-06-14 Katalysatoren auf basis von kupferkomplexen zur synthese von optisch aktiver chrysanthemsäure
EP05756849A EP1765496B1 (en) 2004-06-16 2005-06-14 Catalysts based on copper complexes for the synthesis of optically active chrysanthemic acid
PCT/EP2005/052740 WO2005123254A1 (en) 2004-06-16 2005-06-14 Catalysts based on metal complexes for the synthesis of optically active chrysanthemic acid
US11/629,182 US7723539B2 (en) 2004-06-16 2005-06-14 Catalysts based on metal complexes for the synthesis of optically active chrysanthemic acid
US12/798,869 US20100204038A1 (en) 2004-06-16 2010-04-12 Catalysts based on metal complexes for the synthesis of optically active chrysanthemic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT001211A ITMI20041211A1 (it) 2004-06-16 2004-06-16 Catalizzatori a base di complessi metallici per la sintesi di acido crisantemico otticamente attivo

Publications (1)

Publication Number Publication Date
ITMI20041211A1 true ITMI20041211A1 (it) 2004-09-16

Family

ID=34972025

Family Applications (1)

Application Number Title Priority Date Filing Date
IT001211A ITMI20041211A1 (it) 2004-06-16 2004-06-16 Catalizzatori a base di complessi metallici per la sintesi di acido crisantemico otticamente attivo

Country Status (7)

Country Link
US (2) US7723539B2 (it)
EP (1) EP1765496B1 (it)
CN (1) CN1988954B (it)
AT (1) ATE473808T1 (it)
DE (1) DE602005022312D1 (it)
IT (1) ITMI20041211A1 (it)
WO (1) WO2005123254A1 (it)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006096131A1 (en) 2005-03-08 2006-09-14 Agency For Science, Technology And Research Chiral bisoxazoline catalysts
CN109692708A (zh) * 2017-10-24 2019-04-30 沈阳中化农药化工研发有限公司 一种不对称环丙化催化剂及其应用
CN109954516B (zh) * 2017-12-14 2021-12-21 中国科学院大连化学物理研究所 一种用于手性反式第一菊酸制备的Salen/Ru催化剂
CN109126878A (zh) * 2018-09-21 2019-01-04 深圳大学 金属配合手性催化剂

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5229306B2 (it) * 1972-06-08 1977-08-01
JPS5249472B2 (it) * 1973-02-14 1977-12-17
JPS5910336B2 (ja) * 1975-08-01 1984-03-08 住友化学工業株式会社 第一菊酸エステルの不斉合成法
HU210648B (en) * 1983-09-15 1995-06-28 Jozsef Muskovits Process for preparing cycloproane-carboxylic acid esters
FR2619808B1 (fr) * 1987-08-24 1989-12-29 Roussel Uclaf Procede enantioselectif pour preparer des derives de l'aldehyde hemicaronique de structure trans ou cis
FR2624511B1 (fr) * 1987-12-11 1990-09-21 Roussel Uclaf Procede enantioselectif pour preparer des derives de l'aldehyde hemicaronique de structure trans ou cis
US5175311A (en) * 1990-03-29 1992-12-29 Research Corporation Technologies, Inc. Method of enantioselective cyclopropanation using chiral catalysts
US5298623A (en) * 1991-11-08 1994-03-29 Massachusetts Institute Of Technology Cu complexes of bis-oxazolines and their use
JPH11514356A (ja) * 1995-10-13 1999-12-07 ザ ペン ステイト リサーチ ファウンデイション 新しいキラルリガンドを有する遷移金属錯体により触媒される不斉合成
JP3814857B2 (ja) * 1996-01-31 2006-08-30 住友化学株式会社 光学活性なシクロプロパンカルボン酸エステル類の製造方法
CA2244417C (en) * 1997-08-05 2006-07-18 Sumitomo Chemical Co., Ltd. Optically active bisoxazoline compounds, production and use thereof
US6268525B1 (en) * 1998-01-29 2001-07-31 Sumitomo Chemical Company, Limited Process for producing optically active chrysanthemic acid
DE69908840T2 (de) * 1998-03-13 2004-05-06 Sumitomo Chemical Co., Ltd. Übergangsmetallverbindungen, Katalysatorkomponenten und Katalysatoren für die Olefinpolymerisation und ein Verfahren zur Herstellung von Polyolefinen
WO2001018012A1 (en) * 1999-09-08 2001-03-15 Boehringer Ingelheim Pharmaceuticals, Inc. Electronically tuned ligands
US6369243B1 (en) * 2000-01-18 2002-04-09 The Regents Of The Univerisity Of California Chemical transformation of substrates using nonmetallic, organic catalyst compositions
WO2001053269A1 (en) * 2000-01-18 2001-07-26 The Regents Of The University Of California Acid addition salts of imidazolidinones as reaction catalysts
KR20010074549A (ko) * 2000-01-25 2001-08-04 고사이 아끼오 키랄 구리 착물, 이의 제조 방법 및 이를 이용한 비대칭합성
EP1236708A1 (en) * 2001-02-28 2002-09-04 Sumitomo Chemical Company, Limited Method for producing optically active chrysanthemic acid
DE60238367D1 (de) * 2001-04-27 2011-01-05 Sumitomo Chemical Co Asymmetrischer Kupferkomplex und dessen Verwendung in Cyclopropanierungsreaktion
FR2826298B1 (fr) * 2001-06-25 2003-09-26 Univ Claude Bernard Lyon Catalyseur heterogene de type bisoxazoline chirale, son procede de preparation et ses utilisations
JP4029671B2 (ja) * 2002-06-12 2008-01-09 住友化学株式会社 光学活性なサルドイミン銅錯体の製造方法
EP1593674B1 (en) * 2003-02-07 2011-07-20 Sumitomo Chemical Company, Limited Optically active bisoxazoline compounds, process for production of the same and use thereof
US20070185343A1 (en) * 2004-02-26 2007-08-09 Universiteit Gent Metal complexes for use in olefin metathesis and atom group transfer reactions

Also Published As

Publication number Publication date
US20100204038A1 (en) 2010-08-12
CN1988954B (zh) 2012-01-18
CN1988954A (zh) 2007-06-27
WO2005123254A1 (en) 2005-12-29
EP1765496B1 (en) 2010-07-14
US7723539B2 (en) 2010-05-25
EP1765496A1 (en) 2007-03-28
DE602005022312D1 (de) 2010-08-26
ATE473808T1 (de) 2010-07-15
US20080021237A1 (en) 2008-01-24

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