AU622923B2 - Method and burner for melting copper - Google Patents

Description

OPI DATE 02/04/90 P n APPLN. ID 39899 /89 S" AUJ IuJ DATE 10/05/90 PCT NUMBER PCT/US89/03268 INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (51) International Patent Classification 4 (11) International Publication Number: WO 90/02909 F23D 14/62 A (43) Intern I ica DQ 2 M 1990 (22.03.90) (21) International Application Number: PCT/US89/03268 IT (European patent), JP, KR, LU (European patent), NL (European patent), NO, RO, SE (European patent), SU.

(22) International Filing Date: 26 July 1989 (26.07.89) Published Priority data: With international search report.

241,173 6 S.ptember 1988 (06.09.88) US With amended claims.

(71) Applicant: ASARCO INCORPORATED [US/US]; 180 Maiden Lane, New York, NY 10038 (US).

(72) Inventor: HUGENS, John, Richmond, Jr. 525 7th Avenue, Salt Lake City, UT 84103 (US).

(74) Agents: HANDELMAN, Joseph, H. et al.; Ladas Parry, 26 West 61 Street, New York, NY 10023 (US).

(81) Designated States: AT (European patent), AU, BE (European patent), BG, BR, CH (European patent), DE (European patent), DK, FI, FR (European patent), GB (European patent), HU, (54)Title: METHOD AND BURNER FOR MELTING COPPER (57) Abstract Burners with a flame observation mixer (71, 72) providing substantially complete combustion and a uniform flame composition using a wide variety of fuels including low pressure gaseous and liquid fuels and a method for using these burners to melt copper cathodes in a vertical shaft furnace are disclosed.

4 S WO 90/02909 PCT/US89/03268 1 METHOD AND BURNER FOR MELTING COPPER BACKGROUND OF THE INVENTION This invention relates to burners which provide substantially complete combustion and a uniform flame composition using a wide variety of fuels including low pressure gaseous and liquid fuels and to a method for using these burners to effectively and efficiently melt copper cathodes in a vertical shaft furnace without incorporating unwanted amounts of oxygen into the copper.

The need for burners providing efficient heating and melting is a very important industrial concern, especially today when energy costs are rising, supplies of fuel are decreasing and the types of fuels available for use are changing. The melting of copper cathodes in a vertical fuel-fired furnace is one example of the need for new burners capable of using liquid fuels and fuels such as Blue water gas, carburetted water gas, reformed natural gas, natural gas, coke oven gas, oil gas, producer gas and other natural and manufactured gases. These gaseous fuels are usually taken directly from low pressure city gas systems and because pressure boosters are not usually permitted, existing burners employing high pressure gases cannot be effectively used for these applications.

As is well-known in the art and'as discussed i WO 90/02909 PCF/L~iS89/03268 2 in U.S. Patent No. 3,199,977 issued to A. J. Phillips et al. on August 10, 1965, the disclosure of which is incorporated by reference, copper cathodes are produced industrially by electrolytic processes. The cathodes are commercially pure copper and are generally flat rectangular shapes about one inch thick by about inches to 40 inches, although larger or smaller sizes may be produced.

Although the cathodically deposited copper is commercially pure except for the usual impurities and unavoidable minor, amounts of electrolyte (sulphates) physically present on the surface of the cathodes or occluded therein, the copper cathodes generally are not used per se because of their shape and physical properties, especially the grain structure of the deposited copper. To place them in more useful form, the cathodes must be melted and the molten metal cast into one or more semi-finished forms--for example, cakes, ingots, bars such as wire bars, billets and rods and similar shapes from which finished products are produced, such as for example, sheets, wire, tubes, and the many other commercial products fabricated of commercially pure copper. Moreover, if the copper becomes contaminated with commercially unacceptable amounts of oxygen and sulphur during the melting, it is essential that the sulphur and oxygen in the molten copper be rediced to acceptable amounts by blowing and poling before the molten metal is cast. From a comme.cial standpoint however, the melted copper is essentially ruined and cannot be used and must be reprocessed through a series of steps to form a new cathode. This is a costly and time consuming procedure.

It is essential therefore, that the burners used to melt the copper not contaminate the copper with, for example unwanted oxygen. In general, the fueloxygen (air) mixture is proportioned to contain insufficient oxygen to completely burn the fuel and the WO "0/02909 PCT/US89/03268 resulting melting flame is a reducing flame. The critical nature of the melting stream (flame) requires however, that even though the total stream is reducing, unwanted oxidizing effects caused by the presence of unburned oxygen in the flame must be avoided. For most industrial uses, the predetermined reducing conditions should be such that any oxygen incorporated into the copper is less than .05% by weight of the copper during the melting. Preferably, the predetermined reducing conditions are such that less than .035% and most preferably less than .01% by weight of oxygen are incorporated into the molten copper.

The burners described in Phillips et al. supra and U.S. Patent No. 4,536,152 to Little et al. were specially designed to provide such a uniform reducing flame and a commercially pure melted copper product with the burner being shown in Fig. 1. The disclosure of U.S. Patent No. 4,536,152 is hereby incorporated by reference.

The prior art burner body 3 shown in Fig. 1 is comprised of a mixing section 50 for uniting a stream of fuel and a stream of an oxygen-containing gas (air) to form a unit stream and for introducing the unit stream into flame holder section 51. The burner body is also provided with a combustion chamber section 52 and is mounted on flange 53 against shoulder 54 of flame holder section 51. Igniter bar 58 may be disposed in the throat, and a conventional electrically activated spark plug 59 for igniting the unit stream is mounted on the side of section 51 with the inner end of the spark plug disposed adjacent bar 58. The combination of the throat and bar 58 are especially useful in maintaining combustion of the unit stream in combustion chamber 52, particularly at high fuel velocities. Section 51 is also provided with openings 65 and 70 for taking samples of the unit stream.

Section 50 has an annular maniqfld portion k f -4sleeve 61, bend or elbow portion 62, orifice plate 63 and observation port 64 provided with transparent eyepiece 65. Sleeve 61, which abuts shoulder 66 and the left end of section 50, cooperates with annular portion 60 to provide a manifold for introducing the smaller of the two streams to be united (usually the fuel stream) from pipe 36 through openings 67 into uniting chamber 68; the size and distribution of openings 67 about the periphery of the sleeve being selected to control entry to the fluid into the chamber. The larger stream is introduced to chamber 68 from pipe 29 through the orifice in plate 63 and bend portion 62. Pipe 36 conducts the smaller stream (fuel) to the burner body and is provided with a valve 39 for controlling the amount of fuel delivered at positive pressure to the burner body. Pipe 36 is provided with a conventional diaphragm controlled valve 38 having tube 37 leading from inside pipe 29 to the space above the diaphragm in the diaphragm means so 'as to communicate the pressure of the air in pipe 29 to the diaphragm.

Normal operating pressures,for the fuel gases are 1.25 to 2 pounds per square inch gauge (psig) and higher.

In operating the burner body, the larger stream of the two streams to be united is conducted to the burner body through an orifice into a *o 20 bend leading to the uniting chamber, and the precise composition of the stream is determined in the manner disclosed in U.S. Pat. No. 3,199,977.

Unfortunately, however, the use of low pressure gaseous fuel and/or liquid fuels, which fuels have a line pressure less than the pressure exiting in the burner body, require modifications to the prior art 25 burners and special operating conditions and a new burner design adapted to use these fuels is very much desired by industry.

OBJECT AND SUMMARY OF THE INVENTION It is the object of the present invention to overcome or substantially ameliorate the above disadvantages.

30 There is disclosed herein a burner for mounting on a shaft furnace SWen QSeA,.. me-1t or opper or the like, said burner comprising: a mixing section for uniting a stream of fuel and a stream of oxygen-containing gas to form a unitary stream, the mixing section having a fuel inlet and an oxygen-containing gas inlet, and a mixing chamber downstream of said, inlets, a flame holder section communicating with the mixing section, said flame holder section further including an igniter bar and a spark plug ,7>TMS/29861 -4 j A.

for igniting the unitary stream to produce a reducing flame, and a combustion chamber downstream of the flame holder section, said combustion chamber being adapted to extend into the furnace, wherein the gas and fuel Inlets communicate with an aspirator gas mixer within the mixing section. i There is further disclosed herein a method 4efmelting copper in a shaft furnace to produce molten copper containing less than about 0.05% by weight oxygen by carrying out combustion in the shaft furnace to produce a reducing flame whereby insufficient oxygen-containing gas is supplied to the burner to completely burn fuel supplied to the burner, said fuel being low pressure gaseous or liquid fuel, wherein the combustion is carried out with a burner as disclosed above.

Typically, this invention provides a highly effective burner for melting metals without significant contamination of the metals and which is capable of using a wide variety of fuels including low and high pressure gaseous fuels and liquid fuels. The burner is an improvement of the burners described in U.S. Patent Nos. 3,199,977 and 4,536,152 and typically employs an aspirator mixer in place of the pressure mixing section of the prior art burners, which aspirator mixer allows the use of 20 fuels having a pressure less than the pressure, air pressure, in the burner. For example, the prior art burners normally require a 12-15 inches of water pressure higher than the air pressure to operate. Using the aspirator burner of the invention, the fuel pressure may be less than the air pressure.

Preferably, the burner includes an eyepiece aligned axially with the mixing chamber of the burner and which may be positioned in a displacement rod used to form the aspirator orifice In the mixer section of the burner. The eyepiece preferably has a wide angle viewing lens to provide a wide angle view of the burner chamber walls. A more preferred embodiment utilizes a telescoping viewing instrument desirably positioned in the displacement rod for focusing on certain parts of the burner and even the furnace interior.

DESCRIPTION OF THE DRAWINGS Fig. 1 Is an enlarged vertical section view describing the prior art4burner assembly; S429861 5A Fig. 2 is a section of the aspirator mixer section of the burner of the invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT The prior art burner shown in Fig. 1 and as discussed hereinabove is comprised of a number of sections and parts. The improved burner comprises replacing at or near point A of Fig. 1 the mi,ing section and bend portion 62 with the mixing section 71 of the invention as shown in Fig. 2. Mixing section 71 can be secured at point A by a threaded connection, o* i-

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Us TMSI29861 .i I WO90/02909 PCf/US89/03268 6 flange, or other mechanical seal. Tube 37 of Fig. 1 which leads to diaphragm control valve 38 would preferably be retained and, in a more preferred embodiment, a similar tub would be connected at the end of the mixing section 71 near point A. This tube would be connected in a tee fitting with tube 37 to provide a pressure indication to the valve 38 and increased control of the burner operation.

As can be seen in Fig. 2, mixing section 71 is comprised of a mixing chamber 72 having optionally disposed therein displacement rod 73 which forms an annular orifice 74. The smaller of the two streams to be united (usually the fuel stream) is introduced at inlet port 75 with the larger stream (usually the air stream) being introduced through inlet port 76.

Eyepieces 77 and 78 are disposed at the ends of the displacement rod 73, with eyepiece 78 preferably being a wide-angle lens capable of viewing the complete interior of the igniting section 51 and combustion chamber 52. A highly preferred embodiment employs a telescopic section 79 disposed in displacement rod 73 for focusing on specific parts of the burner 3 and even the interior of the furnace.

In operating the b'rner, natural gas was used as the fuel and introduced through inlet port 75 with air being introduced through inlet port 76. The mixing section 71 was North American Mfg. Co. (Cleveland, Ohio) Aspirator Air Gas Mixer No. 3065-6 without a displacement rod. Dimensions of the burner may be found in their brochure entitled "Dimensions 30.65, 1-87", pages 1 and 2. The aspirator provided approximately 1.1 million BTU per hour of natural ga at 20 inch water'.

column air pressure drop across orifice 74. The orifice annular area was 1.290 square inches. The pressure of the natural gas was .28 psig and the air pressure was .87 psig.

Measurement of the fuel-air mixture at 1 A 1 1 1 J l i ,t 1 (1 41.31111 -I-i(ll.ji.l. 1_ .i i ji ililli Ij; i. l. il.l

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WO 90/02909 PCT/US89/03268 7 openings 69 and 70 showed a uniform mixture indicating that the flame in combustion chamber 52 would likewise be uniform and provide mlting without the introduction of unwanted oxygen into the material being melted. This was confirmed when the burner was used to melt cathode copper in an industrial shaft furnace. Exemplary oxygen contents of the cathode and finished product were .01% and respectively.

It will be apparent that many changes and modifications of the several features described herein may be made without departing from the spirit and scope of the invention. It is therefore apparent that the foregoing description is by way of illustration of the invention rather than limitation of the invention.

Claims (3)

1. 2. A burner according to claim 1, which comprises an eyepiece adapted to extend axially through the mixing section so as to permit viewing downstream from the mixing section.
2. 3. A burner according to claim 2, wherein the 0 eyepiece is the form of a telescope which may be adjusted to view desired sections of the burner. 0' 0: 4. A burner according to claim 2 or 3, wherein the eyepiece is enclosed within an axially positioned rod of the burner, the rod serving to define a portion of the aspirator mixer in the burner. A method fot-.melting copper in a shaft furnace to produce molten copper containing 'ess than about 0.05% by weight oxygen by carrying out combustion in the shaft furnace to produce a reducing flame whereby insufficient oxygen-containing gas is supplied to the burner to completely burn fuel supplied to the burner, said fuel being low pressure gaseous or liquid fuel, wherein the combustion is carried out with a burner according to any one of the fy, !S I- r 1 t:
3. 9- preceding claims. 6. A burner for mounting on a shaft furnace for melting copper or the like according to claim 1, substantially as herein described with reference to Figure 2 of the accompanying drawings. 7. A method for melting copper in a shaft furnace according to claim 5, substantially as herein described with reference to Figure 2 of the accompanying drawings. 8. A method for melting copper in a shaft furnace, the method being substantially as hereinbefore described with reference to Figure 2 of the accompanying drawings, DATED this SIXTH day of JANUARY 1992 Asarco Incorporated Patent Attorneys for the Applicant SPRUSON FERGUSON *S S SS S S S S S S. TMS/29861 I