AR045031A1 - Proceso para fabricar vulcanizados termoplasticos - Google Patents
Proceso para fabricar vulcanizados termoplasticosInfo
- Publication number
- AR045031A1 AR045031A1 ARP040102384A ARP040102384A AR045031A1 AR 045031 A1 AR045031 A1 AR 045031A1 AR P040102384 A ARP040102384 A AR P040102384A AR P040102384 A ARP040102384 A AR P040102384A AR 045031 A1 AR045031 A1 AR 045031A1
- Authority
- AR
- Argentina
- Prior art keywords
- component
- thermoplastic vulcanized
- manufacture thermoplastic
- provides
- crosslinkable
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/006—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/023—On to modified polymers, e.g. chlorinated polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/026—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethylene-vinylester copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
- C08L2312/08—Crosslinking by silane
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
Abstract
La presente provee un proceso para vulcanización dinámica que comprende injertar silano orgánico sobre el componente de fase dispersa, introduciendo así cadenas en el componente que son reticulables en presencia de agentes reticuladores cuando el componente se funde. La presente provee además vulcanizados termoplásticos que tienen propiedades superiores, incluyendo alta flexibilidad y resistencia al impacto, baja higroscopicidad, no-toxicidad y excelente capacidad de procesamiento.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IL15687003A IL156870A0 (en) | 2003-07-10 | 2003-07-10 | Process for making thermoplastic vulcanizates |
Publications (1)
Publication Number | Publication Date |
---|---|
AR045031A1 true AR045031A1 (es) | 2005-10-12 |
Family
ID=32652260
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP040102384A AR045031A1 (es) | 2003-07-10 | 2004-07-07 | Proceso para fabricar vulcanizados termoplasticos |
Country Status (18)
Country | Link |
---|---|
US (1) | US7589154B2 (es) |
EP (1) | EP1644439B1 (es) |
JP (1) | JP2007518837A (es) |
KR (1) | KR20060041217A (es) |
CN (1) | CN1826378A (es) |
AR (1) | AR045031A1 (es) |
AT (1) | ATE427978T1 (es) |
AU (1) | AU2004255942B2 (es) |
BR (1) | BRPI0411870A (es) |
CA (1) | CA2530754A1 (es) |
CL (1) | CL2004001739A1 (es) |
DE (1) | DE602004020476D1 (es) |
IL (2) | IL156870A0 (es) |
MX (1) | MXPA05014179A (es) |
PE (1) | PE20050560A1 (es) |
RU (1) | RU2006114387A (es) |
UA (1) | UA82887C2 (es) |
WO (1) | WO2005005532A1 (es) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2032647B1 (en) * | 2006-06-23 | 2013-07-24 | Basell Poliolefine Italia S.r.l. | Polyolefin thermoplastic vulcanizate elastomers |
EP2083290A4 (en) | 2006-11-17 | 2012-02-08 | Nippon Oil Corp | ELLIPTIC POLARIZING PLATE AND VERTICALLY ALIGNED LIQUID CRYSTAL DISPLAY |
JP2009075533A (ja) | 2007-08-31 | 2009-04-09 | Nippon Oil Corp | 楕円偏光板および液晶表示装置 |
WO2009056409A1 (en) * | 2007-10-31 | 2009-05-07 | Borealis Technology Oy | Silane-functionalised polyolefin compositions, products thereof and preparation processes thereof for wire and cable applications |
WO2009056407A1 (en) * | 2007-10-31 | 2009-05-07 | Borealis Technology Oy | Silane-functionalised polyolefin compositions, products thereof and preparation processes thereof for wire and cable applications |
CA2712668A1 (en) * | 2008-02-02 | 2009-08-06 | Renolit Belgium N.V. | Photovoltaic modules and production process |
JP2009300760A (ja) | 2008-06-13 | 2009-12-24 | Nippon Oil Corp | 楕円偏光板およびそれを用いた垂直配向型液晶表示装置 |
WO2010002793A2 (en) * | 2008-06-30 | 2010-01-07 | Union Carbide Chemicals & Plastics Technology Llc (Formerly Union Carbide Chemicals & Plastics Technology Corporation) | Moisture crosslinkable polyethylene composition |
WO2010014499A2 (en) * | 2008-08-01 | 2010-02-04 | Union Carbide Chemicals & Plastics Technology Llc | Silicone-thermoplastic polymer reactive blends and copolymer products |
US9932435B2 (en) | 2012-01-18 | 2018-04-03 | Iowa State University Research Foundation, Inc. | Thermoplastic elastomers via atom transfer radical polymerization of plant oil |
KR20160009583A (ko) | 2013-05-20 | 2016-01-26 | 아이오와 스테이트 유니버시티 리서치 파운데이션, 인코퍼레이티드 | 트리글리세라이드의 가역적 부가-단편화 사슬 이동 중합을 통한 열가소성 엘라스토머 |
US10040888B1 (en) | 2013-06-14 | 2018-08-07 | Cooper-Standard Automotive Inc. | Composition including silane-grafted polyolefin |
US10100139B2 (en) | 2013-08-01 | 2018-10-16 | Cooper-Standard Automotive Inc. | Hose, composition including silane-grafted polyolefin, and process of making a hose |
US10371292B2 (en) | 2014-07-02 | 2019-08-06 | Cooper-Standard Automotive Inc. | Hose, abrasion resistant composition, and process of making a hose |
WO2017138641A1 (ja) * | 2016-02-12 | 2017-08-17 | 古河電気工業株式会社 | 耐熱性塩素含有架橋樹脂成形体及びその製造方法、シランマスターバッチ、マスターバッチ混合物及びその成形体、並びに、耐熱性製品 |
CN106009449B (zh) * | 2016-05-25 | 2020-06-02 | 北京化工大学 | 一种耐高温耐油热塑性硫化胶及其制备方法 |
EP3551715B1 (en) | 2016-12-10 | 2023-11-08 | Cooper-Standard Automotive, Inc. | Microdense seals, compositions, and methods of making the same |
EP3551453A1 (en) | 2016-12-10 | 2019-10-16 | Cooper-Standard Automotive, Inc. | Roofing membranes, compositions, and methods of making the same |
WO2020091989A1 (en) * | 2018-10-30 | 2020-05-07 | Dow Global Technologies Llc | A thermoplastic vulcanate-like material |
TWI704179B (zh) * | 2018-12-07 | 2020-09-11 | 財團法人工業技術研究院 | 熱塑性硫化彈性體及其製造方法 |
US11578244B2 (en) | 2018-12-17 | 2023-02-14 | Carmel Olefins Ltd. | Thermoplastic shape-stable polymer compositions for storing thermal energy |
US11413800B2 (en) * | 2019-05-20 | 2022-08-16 | Kraton Polymers Llc | Molding compositions and articles made thereof |
CN110330692B (zh) * | 2019-07-23 | 2021-06-01 | 华侨大学 | 一种液体橡胶系动态交联剂及其应用 |
JP2021147416A (ja) * | 2020-03-16 | 2021-09-27 | Mcppイノベーション合同会社 | 変性エラストマー組成物、架橋エラストマー組成物及びその射出成形体 |
CN111484605B (zh) * | 2020-05-18 | 2022-04-26 | 郑州大学 | 一种用于与聚乳酸动态硫化的全生物基不饱和聚酯预聚物及其制备方法 |
CN112694740A (zh) * | 2020-12-10 | 2021-04-23 | 常州迪声声学科技有限公司 | 一种抗冲击汽车前挡板减震垫及其制备方法 |
WO2022133412A1 (en) * | 2020-12-18 | 2022-06-23 | Saint-Gobain Performance Plastics Corporation | Long life pump tubing |
WO2022146809A1 (en) * | 2020-12-30 | 2022-07-07 | Avient Corporation | Polymer blends of thermoplastic elastomer and cross-linked silane grafted polyolefin |
CN112778990B (zh) * | 2021-02-05 | 2022-06-03 | 西南石油大学 | 一种用于油田注水井的污水混配暂堵剂及其制备方法 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4130534A (en) | 1976-12-27 | 1978-12-19 | Monsanto Company | Elastoplastic compositions of butyl rubber and polyolefin resin |
US4183876A (en) | 1978-11-27 | 1980-01-15 | Monsanto Company | Thermoplastic compositions of polyalkenamer rubber and polyolefin resin |
JPS59115351A (ja) * | 1982-12-22 | 1984-07-03 | Mitsubishi Petrochem Co Ltd | プロピレン系樹脂架橋体の製造方法 |
US4614764A (en) * | 1985-03-06 | 1986-09-30 | Mobil Oil Corporation | Linear low density ethylene polymers blended with modified linear low density ethylene polymers |
US4803244A (en) | 1987-11-16 | 1989-02-07 | Union Carbide Corporation | Process for the preparation of thermoplastic elastomers |
US4873042A (en) * | 1988-03-25 | 1989-10-10 | Union Carbide Chemicals And Plastics Company Inc. | Process for extruding a thermoplastic copolymer |
IT1227341B (it) | 1988-09-13 | 1991-04-08 | Ausimont Spa | Composizioni poliolefiniche plasto-elastomeriche e procedimento per la loro preparazione con metodi di vulcanizzazione dinamica |
JPH0618951B2 (ja) | 1989-07-17 | 1994-03-16 | チッソ株式会社 | ポリオレフィン系熱可塑性エラストマー組成物の製造方法 |
GB9308669D0 (en) | 1993-04-27 | 1993-06-09 | Du Pont Canada | Grafting of monomers onto polyolefins in presence of organic peroxides |
DE4402943C2 (de) * | 1994-02-01 | 1996-03-28 | Rustige Bernhard Gmbh & Co Kg | Polymerwerkstoff und Verfahren zu dessen Herstellung |
US5623030A (en) * | 1994-12-01 | 1997-04-22 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Curable composition and process for producing molded articles using the same |
US5840800A (en) * | 1995-11-02 | 1998-11-24 | Dow Corning Corporation | Crosslinked emulsions of pre-formed silicon modified organic polymers |
US5672660A (en) | 1995-12-01 | 1997-09-30 | Advanced Elastomer Systems, L.P. | Hydrosilylation crosslinking |
WO1998023687A1 (en) * | 1996-11-25 | 1998-06-04 | Dupont Dow Elastomers L.L.C. | Polymer blends with controlled morphologies |
CZ302375B6 (cs) | 1998-06-22 | 2011-04-20 | General Electric Company | Termoplastická vulkanizacní kompozice a zpusob její prípravy |
EP1050548B1 (en) * | 1999-05-06 | 2004-01-14 | Hans-Gerhard Prof. Dr. Fritz | A thermoplastic composition and a process for making the same |
US6222008B1 (en) | 1999-05-06 | 2001-04-24 | Shell Oil Company | Treatment of polymer solution with acid and ammonia to improve polymer color |
US6476132B1 (en) | 1999-07-23 | 2002-11-05 | Advanced Elastomer Systems, L.P. | Use of a silane grafted polyolefin in EPDM/polyolefin thermoplastic vulcanizates to improve compression set |
DE10142555A1 (de) | 2001-08-30 | 2003-03-20 | Degussa | Mittel für die Verbesserung der Scorch-Bedingungen bei der Herstellung gepfropfter und/oder vernetzter Polymere sowie gefüllter Kunststoffe |
-
2003
- 2003-07-10 IL IL15687003A patent/IL156870A0/xx unknown
-
2004
- 2004-07-07 AR ARP040102384A patent/AR045031A1/es unknown
- 2004-07-07 PE PE2004000650A patent/PE20050560A1/es not_active Application Discontinuation
- 2004-07-08 AU AU2004255942A patent/AU2004255942B2/en not_active Expired - Fee Related
- 2004-07-08 MX MXPA05014179A patent/MXPA05014179A/es unknown
- 2004-07-08 RU RU2006114387/04A patent/RU2006114387A/ru not_active Application Discontinuation
- 2004-07-08 WO PCT/IL2004/000615 patent/WO2005005532A1/en active Search and Examination
- 2004-07-08 US US10/561,825 patent/US7589154B2/en active Active
- 2004-07-08 CA CA002530754A patent/CA2530754A1/en not_active Abandoned
- 2004-07-08 CN CNA2004800195466A patent/CN1826378A/zh active Pending
- 2004-07-08 AT AT04744955T patent/ATE427978T1/de not_active IP Right Cessation
- 2004-07-08 DE DE602004020476T patent/DE602004020476D1/de not_active Expired - Lifetime
- 2004-07-08 JP JP2006518495A patent/JP2007518837A/ja not_active Withdrawn
- 2004-07-08 KR KR1020067000494A patent/KR20060041217A/ko not_active Application Discontinuation
- 2004-07-08 EP EP04744955A patent/EP1644439B1/en not_active Expired - Lifetime
- 2004-07-08 BR BRPI0411870-7A patent/BRPI0411870A/pt not_active IP Right Cessation
- 2004-07-09 CL CL200401739A patent/CL2004001739A1/es unknown
- 2004-08-07 UA UAA200600861A patent/UA82887C2/uk unknown
-
2005
- 2005-12-22 IL IL172766A patent/IL172766A/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
RU2006114387A (ru) | 2007-11-20 |
PE20050560A1 (es) | 2005-08-11 |
US7589154B2 (en) | 2009-09-15 |
IL156870A0 (en) | 2004-02-08 |
CL2004001739A1 (es) | 2005-05-27 |
AU2004255942A1 (en) | 2005-01-20 |
MXPA05014179A (es) | 2006-07-03 |
JP2007518837A (ja) | 2007-07-12 |
UA82887C2 (en) | 2008-05-26 |
US20060155072A1 (en) | 2006-07-13 |
EP1644439B1 (en) | 2009-04-08 |
CA2530754A1 (en) | 2005-01-20 |
EP1644439A1 (en) | 2006-04-12 |
KR20060041217A (ko) | 2006-05-11 |
BRPI0411870A (pt) | 2006-08-08 |
AU2004255942B2 (en) | 2008-11-06 |
DE602004020476D1 (de) | 2009-05-20 |
ATE427978T1 (de) | 2009-04-15 |
WO2005005532A1 (en) | 2005-01-20 |
IL172766A0 (en) | 2006-04-10 |
IL172766A (en) | 2011-03-31 |
CN1826378A (zh) | 2006-08-30 |
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