ZA200601229B - Process for the preparation of hydrogen peroxide by the anthraquinone cyclic process - Google Patents

Process for the preparation of hydrogen peroxide by the anthraquinone cyclic process Download PDF

Info

Publication number: ZA200601229B
Authority: ZA; South Africa
Prior art keywords: working solution; stage; process according; alkyl; regeneration
Prior art date: 2003-08-11

Application number

ZA200601229A

Other languages

English (en)

Inventor

Goor Gustaaf

Juergen Glenneberg

Staab Eugen

Original Assignee

Degussa

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2003-08-11

Filing date

2006-02-10

Publication date

2007-05-30

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34129537&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ZA200601229(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2006-02-10 Application filed by Degussa filed Critical Degussa

2007-05-30 Publication of ZA200601229B publication Critical patent/ZA200601229B/en

Links

238000000034 method Methods 0.000 title claims abstract description 66
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 44
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 title claims abstract description 28
238000002360 preparation method Methods 0.000 title claims abstract description 9
239000012224 working solution Substances 0.000 claims abstract description 87
230000008929 regeneration Effects 0.000 claims abstract description 39
238000011069 regeneration method Methods 0.000 claims abstract description 39
-1 alkyl anthrahydroquinone Chemical compound 0.000 claims abstract description 25
125000000217 alkyl group Chemical group 0.000 claims abstract description 19
125000004122 cyclic group Chemical group 0.000 claims abstract description 10
239000007864 aqueous solution Substances 0.000 claims abstract description 7
239000000243 solution Substances 0.000 claims description 28
239000000376 reactant Substances 0.000 claims description 20
230000001172 regenerating effect Effects 0.000 claims description 19
230000003647 oxidation Effects 0.000 claims description 10
238000007254 oxidation reaction Methods 0.000 claims description 10
239000012071 phase Substances 0.000 claims description 10
239000008346 aqueous phase Substances 0.000 claims description 9
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
239000007789 gas Substances 0.000 claims description 8
239000001301 oxygen Substances 0.000 claims description 8
229910052760 oxygen Inorganic materials 0.000 claims description 8
238000005191 phase separation Methods 0.000 claims description 8
238000000605 extraction Methods 0.000 claims description 7
239000002657 fibrous material Substances 0.000 claims description 4
229920000914 Metallic fiber Polymers 0.000 claims description 3
229910001854 alkali hydroxide Inorganic materials 0.000 claims description 3
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 3
238000009903 catalytic hydrogenation reaction Methods 0.000 claims description 3
239000000835 fiber Substances 0.000 claims description 2
230000001737 promoting effect Effects 0.000 claims description 2
229910001220 stainless steel Inorganic materials 0.000 claims description 2
239000010935 stainless steel Substances 0.000 claims description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
238000011084 recovery Methods 0.000 claims 1
239000003054 catalyst Substances 0.000 description 15
HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 14
238000005984 hydrogenation reaction Methods 0.000 description 10
125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 description 10
239000002904 solvent Substances 0.000 description 9
239000001257 hydrogen Substances 0.000 description 7
229910052739 hydrogen Inorganic materials 0.000 description 7
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
239000012492 regenerant Substances 0.000 description 6
239000007787 solid Substances 0.000 description 6
230000003113 alkalizing effect Effects 0.000 description 5
150000004053 quinones Chemical class 0.000 description 5
239000006227 byproduct Substances 0.000 description 4
239000000203 mixture Substances 0.000 description 4
229910000510 noble metal Inorganic materials 0.000 description 4
KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
125000004151 quinonyl group Chemical group 0.000 description 4
238000004821 distillation Methods 0.000 description 3
GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 3
239000000463 material Substances 0.000 description 3
239000007800 oxidant agent Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
239000003513 alkali Substances 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000012074 organic phase Substances 0.000 description 2
229910052763 palladium Inorganic materials 0.000 description 2
230000003068 static effect Effects 0.000 description 2
SNDGLCYYBKJSOT-UHFFFAOYSA-N 1,1,3,3-tetrabutylurea Chemical compound CCCCN(CCCC)C(=O)N(CCCC)CCCC SNDGLCYYBKJSOT-UHFFFAOYSA-N 0.000 description 1
VKAMZEDHHWTTNZ-UHFFFAOYSA-N 1-octylazepan-2-one Chemical compound CCCCCCCCN1CCCCCC1=O VKAMZEDHHWTTNZ-UHFFFAOYSA-N 0.000 description 1
JWXBQHIMYKKGJT-UHFFFAOYSA-N 2-(4-methylpentyl)anthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(CCCC(C)C)=CC=C3C(=O)C2=C1 JWXBQHIMYKKGJT-UHFFFAOYSA-N 0.000 description 1
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
HXQPUEQDBSPXTE-UHFFFAOYSA-N Diisobutylcarbinol Chemical compound CC(C)CC(O)CC(C)C HXQPUEQDBSPXTE-UHFFFAOYSA-N 0.000 description 1
239000007868 Raney catalyst Substances 0.000 description 1
NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
229910000564 Raney nickel Inorganic materials 0.000 description 1
GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000000654 additive Substances 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
239000006286 aqueous extract Substances 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
239000002585 base Substances 0.000 description 1
150000001555 benzenes Chemical class 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
150000004657 carbamic acid derivatives Chemical class 0.000 description 1
235000013877 carbamide Nutrition 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000000470 constituent Substances 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
239000007857 degradation product Substances 0.000 description 1
239000008367 deionised water Substances 0.000 description 1
229910021641 deionized water Inorganic materials 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
229910052741 iridium Inorganic materials 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
IMXBRVLCKXGWSS-UHFFFAOYSA-N methyl 2-cyclohexylacetate Chemical compound COC(=O)CC1CCCCC1 IMXBRVLCKXGWSS-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
238000000465 moulding Methods 0.000 description 1
239000012454 non-polar solvent Substances 0.000 description 1
239000004745 nonwoven fabric Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
238000012856 packing Methods 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
150000003014 phosphoric acid esters Chemical class 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
239000002798 polar solvent Substances 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
150000004040 pyrrolidinones Chemical class 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
229910052707 ruthenium Inorganic materials 0.000 description 1
150000003333 secondary alcohols Chemical class 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
150000003672 ureas Chemical class 0.000 description 1
239000002759 woven fabric Substances 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

ZA200601229A 2003-08-11 2006-02-10 Process for the preparation of hydrogen peroxide by the anthraquinone cyclic process ZA200601229B (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
DE10336852A DE10336852A1 (de)	2003-08-11	2003-08-11	Verfahren zur Herstellung von Wasserstoffperoxid nach dem Anthrachinon-Kreisprozess

Publications (1)

Publication Number	Publication Date
ZA200601229B true ZA200601229B (en)	2007-05-30

Family

ID=34129537

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
ZA200601229A ZA200601229B (en)	2003-08-11	2006-02-10	Process for the preparation of hydrogen peroxide by the anthraquinone cyclic process

Country Status (12)

Country	Link
EP (1)	EP1654194B1 (ko)
KR (1)	KR100779894B1 (ko)
AT (1)	ATE356079T1 (ko)
BR (1)	BRPI0413433A (ko)
CA (1)	CA2535500C (ko)
DE (2)	DE10336852A1 (ko)
ES (1)	ES2284022T3 (ko)
IL (1)	IL173606A (ko)
PL (1)	PL1654194T3 (ko)
TW (1)	TW200510247A (ko)
WO (1)	WO2005014471A1 (ko)
ZA (1)	ZA200601229B (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2013053617A1 (en) *	2011-10-11	2013-04-18	Solvay Sa	Process for producing hydrogen peroxide
US10570014B2 (en) *	2012-12-20	2020-02-25	Solvay Sa	Process for manufacturing a purified aqueous hydrogen peroxide solution
JP2018135229A (ja) *	2017-02-21	2018-08-30	三菱瓦斯化学株式会社	過酸化水素の製造方法
CN111717893A (zh) *	2019-03-22	2020-09-29	中国石油化工股份有限公司	蒽醌法生产过氧化氢的氧化装置和方法
CN111714922A (zh) *	2019-03-22	2020-09-29	中国石油化工股份有限公司	一种应急处理装置及包括其的双氧水生产装置
CN110523407B (zh) *	2019-08-26	2022-08-02	岳阳聚成化工有限公司	用于循环工作液再生的催化剂及其制备方法以及循环工作液的再生方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1118165B (de)	1960-10-07	1961-11-30	Degussa	Verfahren zum Aufarbeiten von teilweise abgebauten Arbeitsloesungen der Herstellung von Wasserstoffperoxyd nach dem Anthrachinonverfahren
ZA728652B (en)	1971-12-20	1973-08-29	Laporte Industries Ltd	Improvements in a cyclic process for hydrogen peroxide production
FI108432B (fi) *	2000-03-06	2002-01-31	Kemira Chemicals Oy	Ty÷liuoksen regenerointi vetyperoksidin tuotantoprosessissa
FI110427B (fi) *	2001-03-28	2003-01-31	Kemira Chemicals Oy	Työliuoksen hydraus vetyperoksidin valmistusprosessissa

2003
- 2003-08-11 DE DE10336852A patent/DE10336852A1/de not_active Withdrawn
2004
- 2004-06-22 WO PCT/EP2004/006720 patent/WO2005014471A1/en active IP Right Grant
- 2004-06-22 CA CA002535500A patent/CA2535500C/en not_active Expired - Fee Related
- 2004-06-22 AT AT04740150T patent/ATE356079T1/de not_active IP Right Cessation
- 2004-06-22 PL PL04740150T patent/PL1654194T3/pl unknown
- 2004-06-22 ES ES04740150T patent/ES2284022T3/es not_active Expired - Lifetime
- 2004-06-22 KR KR1020067002729A patent/KR100779894B1/ko not_active IP Right Cessation
- 2004-06-22 EP EP04740150A patent/EP1654194B1/en not_active Expired - Lifetime
- 2004-06-22 BR BRPI0413433-8A patent/BRPI0413433A/pt not_active IP Right Cessation
- 2004-06-22 DE DE602004005212T patent/DE602004005212T2/de not_active Expired - Lifetime
- 2004-08-09 TW TW093123822A patent/TW200510247A/zh unknown
2006
- 2006-02-08 IL IL173606A patent/IL173606A/en not_active IP Right Cessation
- 2006-02-10 ZA ZA200601229A patent/ZA200601229B/en unknown

Also Published As

Publication number	Publication date
IL173606A0 (en)	2006-07-05
KR20060063940A (ko)	2006-06-12
BRPI0413433A (pt)	2006-10-10
EP1654194A1 (en)	2006-05-10
DE602004005212D1 (de)	2007-04-19
CA2535500A1 (en)	2005-02-17
PL1654194T3 (pl)	2007-08-31
ES2284022T3 (es)	2007-11-01
EP1654194B1 (en)	2007-03-07
DE602004005212T2 (de)	2007-11-15
KR100779894B1 (ko)	2007-11-28
WO2005014471A1 (en)	2005-02-17
CA2535500C (en)	2009-08-18
IL173606A (en)	2010-06-30
ATE356079T1 (de)	2007-03-15
TW200510247A (en)	2005-03-16
DE10336852A1 (de)	2005-03-10

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ZA200601229B (en)	2007-05-30	Process for the preparation of hydrogen peroxide by the anthraquinone cyclic process
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US6224845B1 (en)	2001-05-01	Process for manufacturing an aqueous hydrogen peroxide solution
US6749727B2 (en)	2004-06-15	Hydrogenation of a working solution in a hydrogen peroxide production process
ITMI20001218A1 (it)	2001-12-01	Processo per la produzioni in continuo di acqua ossigenata
RU2609474C2 (ru)	2017-02-02	Способ производства пероксида водорода
JP3617532B2 (ja)	2005-02-09	過酸化水素の製造方法
US7238335B2 (en)	2007-07-03	Process for the preparation of hydrogen peroxide by the anthraquinone cyclic process
USH1787H (en)	1999-02-02	Regeneration method of working solution
US6946061B2 (en)	2005-09-20	Regeneration of a working solution in a hydrogen peroxide production process
TW201836972A (zh)	2018-10-16	過氧化氫之製造方法
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