ZA200601229B - Process for the preparation of hydrogen peroxide by the anthraquinone cyclic process - Google Patents
Process for the preparation of hydrogen peroxide by the anthraquinone cyclic process Download PDFInfo
- Publication number
- ZA200601229B ZA200601229B ZA200601229A ZA200601229A ZA200601229B ZA 200601229 B ZA200601229 B ZA 200601229B ZA 200601229 A ZA200601229 A ZA 200601229A ZA 200601229 A ZA200601229 A ZA 200601229A ZA 200601229 B ZA200601229 B ZA 200601229B
- Authority
- ZA
- South Africa
- Prior art keywords
- working solution
- stage
- process according
- alkyl
- regeneration
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 66
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 44
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000012224 working solution Substances 0.000 claims abstract description 87
- 230000008929 regeneration Effects 0.000 claims abstract description 39
- 238000011069 regeneration method Methods 0.000 claims abstract description 39
- -1 alkyl anthrahydroquinone Chemical compound 0.000 claims abstract description 25
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 19
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 10
- 239000007864 aqueous solution Substances 0.000 claims abstract description 7
- 239000000243 solution Substances 0.000 claims description 28
- 239000000376 reactant Substances 0.000 claims description 20
- 230000001172 regenerating effect Effects 0.000 claims description 19
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 239000012071 phase Substances 0.000 claims description 10
- 239000008346 aqueous phase Substances 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- 229910052760 oxygen Inorganic materials 0.000 claims description 8
- 238000005191 phase separation Methods 0.000 claims description 8
- 238000000605 extraction Methods 0.000 claims description 7
- 239000002657 fibrous material Substances 0.000 claims description 4
- 229920000914 Metallic fiber Polymers 0.000 claims description 3
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 3
- 238000009903 catalytic hydrogenation reaction Methods 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 2
- 230000001737 promoting effect Effects 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 238000011084 recovery Methods 0.000 claims 1
- 239000003054 catalyst Substances 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 14
- 238000005984 hydrogenation reaction Methods 0.000 description 10
- 125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 description 10
- 239000002904 solvent Substances 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 239000012492 regenerant Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 230000003113 alkalizing effect Effects 0.000 description 5
- 150000004053 quinones Chemical class 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910000510 noble metal Inorganic materials 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 125000004151 quinonyl group Chemical group 0.000 description 4
- 238000004821 distillation Methods 0.000 description 3
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- SNDGLCYYBKJSOT-UHFFFAOYSA-N 1,1,3,3-tetrabutylurea Chemical compound CCCCN(CCCC)C(=O)N(CCCC)CCCC SNDGLCYYBKJSOT-UHFFFAOYSA-N 0.000 description 1
- VKAMZEDHHWTTNZ-UHFFFAOYSA-N 1-octylazepan-2-one Chemical compound CCCCCCCCN1CCCCCC1=O VKAMZEDHHWTTNZ-UHFFFAOYSA-N 0.000 description 1
- JWXBQHIMYKKGJT-UHFFFAOYSA-N 2-(4-methylpentyl)anthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(CCCC(C)C)=CC=C3C(=O)C2=C1 JWXBQHIMYKKGJT-UHFFFAOYSA-N 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- HXQPUEQDBSPXTE-UHFFFAOYSA-N Diisobutylcarbinol Chemical compound CC(C)CC(O)CC(C)C HXQPUEQDBSPXTE-UHFFFAOYSA-N 0.000 description 1
- 239000007868 Raney catalyst Substances 0.000 description 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
- 229910000564 Raney nickel Inorganic materials 0.000 description 1
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000006286 aqueous extract Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- IMXBRVLCKXGWSS-UHFFFAOYSA-N methyl 2-cyclohexylacetate Chemical compound COC(=O)CC1CCCCC1 IMXBRVLCKXGWSS-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000012454 non-polar solvent Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10336852A DE10336852A1 (de) | 2003-08-11 | 2003-08-11 | Verfahren zur Herstellung von Wasserstoffperoxid nach dem Anthrachinon-Kreisprozess |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200601229B true ZA200601229B (en) | 2007-05-30 |
Family
ID=34129537
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200601229A ZA200601229B (en) | 2003-08-11 | 2006-02-10 | Process for the preparation of hydrogen peroxide by the anthraquinone cyclic process |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP1654194B1 (es) |
KR (1) | KR100779894B1 (es) |
AT (1) | ATE356079T1 (es) |
BR (1) | BRPI0413433A (es) |
CA (1) | CA2535500C (es) |
DE (2) | DE10336852A1 (es) |
ES (1) | ES2284022T3 (es) |
IL (1) | IL173606A (es) |
PL (1) | PL1654194T3 (es) |
TW (1) | TW200510247A (es) |
WO (1) | WO2005014471A1 (es) |
ZA (1) | ZA200601229B (es) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013053617A1 (en) * | 2011-10-11 | 2013-04-18 | Solvay Sa | Process for producing hydrogen peroxide |
US10570014B2 (en) * | 2012-12-20 | 2020-02-25 | Solvay Sa | Process for manufacturing a purified aqueous hydrogen peroxide solution |
JP2018135229A (ja) * | 2017-02-21 | 2018-08-30 | 三菱瓦斯化学株式会社 | 過酸化水素の製造方法 |
CN111717893A (zh) * | 2019-03-22 | 2020-09-29 | 中国石油化工股份有限公司 | 蒽醌法生产过氧化氢的氧化装置和方法 |
CN111714922A (zh) * | 2019-03-22 | 2020-09-29 | 中国石油化工股份有限公司 | 一种应急处理装置及包括其的双氧水生产装置 |
CN110523407B (zh) * | 2019-08-26 | 2022-08-02 | 岳阳聚成化工有限公司 | 用于循环工作液再生的催化剂及其制备方法以及循环工作液的再生方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1118165B (de) | 1960-10-07 | 1961-11-30 | Degussa | Verfahren zum Aufarbeiten von teilweise abgebauten Arbeitsloesungen der Herstellung von Wasserstoffperoxyd nach dem Anthrachinonverfahren |
ZA728652B (en) | 1971-12-20 | 1973-08-29 | Laporte Industries Ltd | Improvements in a cyclic process for hydrogen peroxide production |
FI108432B (fi) * | 2000-03-06 | 2002-01-31 | Kemira Chemicals Oy | Ty÷liuoksen regenerointi vetyperoksidin tuotantoprosessissa |
FI110427B (fi) * | 2001-03-28 | 2003-01-31 | Kemira Chemicals Oy | Työliuoksen hydraus vetyperoksidin valmistusprosessissa |
-
2003
- 2003-08-11 DE DE10336852A patent/DE10336852A1/de not_active Withdrawn
-
2004
- 2004-06-22 WO PCT/EP2004/006720 patent/WO2005014471A1/en active IP Right Grant
- 2004-06-22 CA CA002535500A patent/CA2535500C/en not_active Expired - Fee Related
- 2004-06-22 AT AT04740150T patent/ATE356079T1/de not_active IP Right Cessation
- 2004-06-22 PL PL04740150T patent/PL1654194T3/pl unknown
- 2004-06-22 ES ES04740150T patent/ES2284022T3/es not_active Expired - Lifetime
- 2004-06-22 KR KR1020067002729A patent/KR100779894B1/ko not_active IP Right Cessation
- 2004-06-22 EP EP04740150A patent/EP1654194B1/en not_active Expired - Lifetime
- 2004-06-22 BR BRPI0413433-8A patent/BRPI0413433A/pt not_active IP Right Cessation
- 2004-06-22 DE DE602004005212T patent/DE602004005212T2/de not_active Expired - Lifetime
- 2004-08-09 TW TW093123822A patent/TW200510247A/zh unknown
-
2006
- 2006-02-08 IL IL173606A patent/IL173606A/en not_active IP Right Cessation
- 2006-02-10 ZA ZA200601229A patent/ZA200601229B/en unknown
Also Published As
Publication number | Publication date |
---|---|
IL173606A0 (en) | 2006-07-05 |
KR20060063940A (ko) | 2006-06-12 |
BRPI0413433A (pt) | 2006-10-10 |
EP1654194A1 (en) | 2006-05-10 |
DE602004005212D1 (de) | 2007-04-19 |
CA2535500A1 (en) | 2005-02-17 |
PL1654194T3 (pl) | 2007-08-31 |
ES2284022T3 (es) | 2007-11-01 |
EP1654194B1 (en) | 2007-03-07 |
DE602004005212T2 (de) | 2007-11-15 |
KR100779894B1 (ko) | 2007-11-28 |
WO2005014471A1 (en) | 2005-02-17 |
CA2535500C (en) | 2009-08-18 |
IL173606A (en) | 2010-06-30 |
ATE356079T1 (de) | 2007-03-15 |
TW200510247A (en) | 2005-03-16 |
DE10336852A1 (de) | 2005-03-10 |
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