WO2013027431A1 - 硫化水素合成反応器、硫化水素製造装置、硫化水素ナトリウム製造装置、及びそれらの方法 - Google Patents
硫化水素合成反応器、硫化水素製造装置、硫化水素ナトリウム製造装置、及びそれらの方法 Download PDFInfo
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- WO2013027431A1 WO2013027431A1 PCT/JP2012/056615 JP2012056615W WO2013027431A1 WO 2013027431 A1 WO2013027431 A1 WO 2013027431A1 JP 2012056615 W JP2012056615 W JP 2012056615W WO 2013027431 A1 WO2013027431 A1 WO 2013027431A1
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- hydrogen sulfide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/16—Hydrogen sulfides
- C01B17/161—Preparation from elemental sulfur
- C01B17/162—Preparation from elemental sulfur from elemental sulfur and hydrogen
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/16—Hydrogen sulfides
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/22—Alkali metal sulfides or polysulfides
- C01B17/32—Hydrosulfides of sodium or potassium
Definitions
- the present invention relates to a method for producing hydrogen sulfide by reacting sulfur and hydrogen, and a hydrogen sulfide producing apparatus used in the method.
- the present invention further relates to a method for producing sodium hydrogen sulfide by reacting hydrogen sulfide with sodium hydroxide, and a sodium hydrogen sulfide production apparatus used in the method.
- Hydrogen sulfide is a flammable toxic gas, and is produced by hydrodesulfurizing sulfur compounds contained in petroleum and natural gas, and is recovered as solid sulfur through a sulfur recovery device. On the other hand, hydrogen sulfide is also a valuable compound as a raw material for synthesizing various sulfur-containing compounds. Hydrogen sulfide or sodium hydrogen sulfide produced from hydrogen sulfide and sodium hydroxide is widely used as a raw material for fine chemicals such as dyes, agricultural chemicals, plastics, pharmaceuticals and cosmetics, and as a raw material for producing metal sulfides.
- Catalytic reaction Sulfur gas and hydrogen gas react in a reaction tube filled with a catalyst to produce hydrogen sulfide.
- the heat of reaction is removed by flowing a heat medium outside the reaction tube.
- Such a catalytic reaction is shown, for example, in Patent Document 1 below.
- Non-catalytic reaction The non-catalytic gas phase reaction is shown, for example, in Figure 1 on page 474 of Non-Patent Document 1 below.
- hydrogen sulfide is produced using a reaction tower having a tower bottom portion that retains liquid sulfur at a boiling temperature and a gas space portion that reacts sulfur gas and hydrogen gas.
- Hydrogen gas is introduced into the liquid sulfur in the tower bottom, and the hydrogen gas and sulfur gas react in the gas space to produce hydrogen sulfide.
- the reaction heat of hydrogen sulfide is recovered by contacting with liquid sulfur supplied from the upper part of the gas space.
- the product gas containing hydrogen sulfide and sulfur gas is cooled by a heat exchanger to solidify the sulfur, thereby purifying the hydrogen sulfide gas.
- the catalytic reaction of hydrogen sulfide increases the temperature rise due to heat of reaction when the sulfur concentration is high, and the catalyst is abnormally heated, leading to deterioration. Therefore, it is necessary to take heat removal measures to prevent this, and the reactor structure becomes complicated. Moreover, since the used catalyst is sulfided and may ignite when exposed to air, regular maintenance is not easy.
- Hydrogen sulfide is synthesized by reducing impurities such as hydrogen polysulfide (chemical substance represented by the chemical formula H 2 S X ) during the synthesis, thereby simplifying the purification process, improving economy, and using hydrogen sulfide as a raw material. This can contribute to improving the quality of the final product. Therefore, in the synthesis of hydrogen sulfide, it is desirable to prevent the generation of hydrogen polysulfide, which is a by-product.
- impurities such as hydrogen polysulfide (chemical substance represented by the chemical formula H 2 S X )
- an object of the present invention is to produce hydrogen sulfide with high purity by reducing the production of side reactants.
- a hydrogen sulfide synthesis reactor for synthesizing hydrogen sulfide by reacting sulfur and hydrogen in a gas phase without catalyst, A reactor body that stores liquid sulfur at the bottom; A heating unit for gasifying part of the liquid sulfur; A hydrogen gas supply unit for supplying hydrogen gas to the liquid sulfur; A heat exchange section provided in a gas phase reaction region above the liquid level of liquid sulfur in the reactor body, The heat exchange unit is configured to change the exchange heat amount per unit volume of the gas phase reaction region far from the liquid surface and the exchange heat amount per unit volume in the gas phase reaction region near the liquid surface, thereby changing the gas phase reaction region.
- a hydrogen sulfide synthesis reactor characterized in that the reaction temperature in the reactor is set within a predetermined temperature. It is possible to produce hydrogen sulfide with high purity by reducing generation of side reaction products.
- Item 2 The hydrogen sulfide synthesis reactor according to Item 1, wherein the heat exchanging unit is configured such that the amount of heat exchanged per unit volume decreases with increasing distance from the liquid surface. 3.
- the heat exchange unit is configured such that the heat transfer area per unit volume of the gas phase reaction region near the liquid surface is larger than the heat transfer area per unit volume of the gas phase reaction region far from the liquid surface.
- the gas flow from the lower part to the upper part is rectified and uniformly dispersed, and the reverse flow to the lower part that may be caused by cooling is prevented, so that a theoretical conversion rate corresponding to the height of the gas phase part can be realized.
- the heat exchanging unit When heat radiation from the surface of the reactor main body is higher than the amount of heat generated by the heat of hydrogen sulfide reaction, the heat exchanging unit is installed in the reactor main body in order to keep the reaction temperature in the gas phase reaction region within a predetermined temperature.
- the hydrogen sulfide synthesis reactor according to any one of items 1 to 8, wherein the reactor is configured to be heated. Even when the tower diameter of the reactor main body is small, it is possible to produce high-purity hydrogen sulfide by reducing the production of by-products. 10.
- the hydrogen sulfide synthesis reactor according to any one of items 1 to 9, Hydrogen sulfide production, comprising: a hydrogenation reactor for synthesizing hydrogen sulfide by reacting unreacted sulfur gas released from the hydrogen sulfide synthesis reactor with hydrogen gas using a hydrogenation catalyst. apparatus. Unreacted sulfur gas can be converted to hydrogen sulfide gas with hydrogen gas. 11. 11. The hydrogen sulfide production apparatus according to any one of items 1 to 10, further comprising a liquefaction apparatus that liquefies hydrogen sulfide.
- An apparatus for producing sodium hydrogen sulfide for synthesizing sodium hydrogen sulfide The hydrogen sulfide synthesis reactor according to any one of items 1 to 11, A hydrogenation reactor for synthesizing hydrogen sulfide by reacting unreacted sulfur gas released from the hydrogen sulfide synthesis reactor with hydrogen gas using a hydrogenation catalyst; An apparatus for producing sodium hydrogen sulfide, comprising: a sodium hydrogen sulfide synthesis reactor for reacting hydrogen sulfide with an aqueous sodium hydroxide solution to synthesize sodium hydrogen sulfide. 13.
- Item 15 The hydrogen sulfide synthesis reactor according to Item 13 or 14, wherein the predetermined temperature is 380 ° C to 410 ° C. 16.
- Item 16. The hydrogen sulfide production reaction according to any one of Items 13 to 15, wherein the heat removal is performed with a refrigerant having a sulfur freezing point or higher. 17.
- Item 17 The method for producing hydrogen sulfide according to any one of Items 13 to 16, wherein the gas passes through a rectifying unit having a plurality of holes provided with a heat exchange unit for performing heat removal. 18. 18.
- the heat removal step includes a heating step in order to keep the reaction temperature in the gas phase reaction region within a predetermined temperature when heat radiation from the surface of the reactor main body is higher than the amount of heat generated by the hydrogen sulfide reaction heat. Item 19.
- a method for producing sodium hydrogen sulfide for producing sodium hydrogen sulfide comprising: 20.
- a method for producing sodium hydrogen sulfide wherein hydrogen sulfide produced by the method for producing hydrogen sulfide according to any one of items 13 to 19 is reacted with an aqueous sodium hydroxide solution to produce sodium hydrogen sulfide.
- the present invention can produce high-purity hydrogen sulfide by reducing the production of by-products.
- Hydrogen sulfide concentration in equilibrium is a diagram showing the relationship between H 2 S 2 concentration. It is a figure which shows an example of a hydrogen sulfide synthesis reactor with insufficient temperature control. It is a figure which shows the 1st example of a hydrogen sulfide synthesis reactor. It is a figure which shows an example of the relationship between the hydrogen sulfide density
- FIG. 1 is a diagram showing the relationship between hydrogen sulfide concentration and H 2 S 2 concentration in an equilibrium state of a ternary system of H 2 , H 2 S, and H 2 S 2 .
- FIG. 1 shows H 2 S 2 concentration correlation curves 1001 to 1003 at a pressure of 0.5 MPaG at 380 ° C., 410 ° C., and 500 ° C., respectively.
- the vertical axis of the graph shown in FIG. 1 is the equilibrium concentration [mol ppm] of H 2 S 2
- the horizontal axis is the equilibrium concentration [mol%] of hydrogen sulfide.
- the concentration of H 2 S 2 increases as the concentration of hydrogen sulfide increases. This is shown in the hydrogen sulfide concentration and H 2 S 2 concentration correlation curves 1001 to 1003 shown in FIG. As shown, with increasing equilibrium temperature, it rises the concentration of H 2 S 2 with respect to the concentration of H 2 S.
- Formula 2 is an endothermic reaction, and the concentration of H 2 S 2 increases as the temperature increases. Since the reaction rate is higher at higher temperatures, it is preferable to reduce the reactor size as high as possible. On the other hand, in terms of reaction equilibrium, the concentration of H 2 S 2 increases as the temperature increases.
- the temperature in order to match the H 2 S 2 concentration to the product specifications of hydrogen sulfide required to be a certain concentration or less.
- the concentration correlation curve 1001 when the concentration of hydrogen sulfide in the refined gas is 60%, the pressure 0.5 is used to keep the H 2 S 2 concentration below 10 ppm.
- the pressure is MPa
- the reaction temperature must be controlled to 410 ° C. or lower.
- the reaction temperature of hydrogen sulfide is preferably 410 ° C. or lower.
- the reaction rate is lowered.
- FIG. 2 is a reference diagram showing an example of a hydrogen sulfide synthesis reactor with insufficient temperature control.
- the sulfur gas that is gasified by heating the liquid sulfur held at the bottom with a heater or the like (not shown) and the hydrogen gas that has passed the liquid sulfur are in the gas phase. Reaction occurs in the reaction zone 530 to produce hydrogen sulfide.
- the reaction temperature rises in the gas phase reaction region 530 and H 2 S 2 increases, and the H 2 S 2 concentration exceeds the product specification.
- FIG. 3 is a diagram showing a first example of a hydrogen sulfide synthesis reactor according to an embodiment of the present invention.
- a hydrogen sulfide synthesis reactor 100 shown in FIG. 3 includes a reactor main body 105 that can store liquid sulfur in a lower part, a heat exchange unit 110 that maintains a constant reaction region temperature in the reactor main body 105, and a reactor main body 105.
- a heating unit 120 that heats the stored liquid sulfur to gasify part of the liquid sulfur, and a hydrogen supply unit 130 that supplies hydrogen gas into the liquid sulfur are provided.
- a liquid sulfur supply pipe 11, a hydrogen gas supply pipe 12, and a product gas discharge pipe 13 are provided.
- the hydrogen sulfide synthesis reactor 100 uses the interior of the reactor main body 105 as a liquid sulfur holding unit 101 that holds liquid sulfur and a gas phase reaction region 102 that is a space where a non-catalytic gas phase reaction occurs.
- the heat exchange unit 110 of the present invention has three heat exchangers 111 to 113, and the heat exchanger 111 on the side close to the sulfur liquid surface has the largest heat exchange capacity, and heat exchanges in the order of the heat exchangers 112 and 113. It is comprised so that a capacity
- the heating unit 120 is composed of a heat transfer coil or the like that is not shown in the figure, and heats the liquid sulfur to enable the gasification of the sulfur.
- the gasified sulfur gas rises from the liquid level to the gas phase.
- the heating unit 120 supplies the amount of heat necessary to supply the sulfur gas necessary for the hydrogen sulfide generation reaction indicated by the reaction conditions.
- the hydrogen sulfide synthesis reactor 100 includes a liquid level controller 51 that detects the liquid level of the liquid sulfur holding unit 101 and controls the liquid level at a predetermined position.
- the liquid sulfur supply pipe 11 is connected to a raw sulfur preheating tank (not shown), and a flow control valve 54 for liquid sulfur heated in the preheating tank is provided.
- the liquid level controller 51 detects the liquid level of the sulfur liquid, and when the sulfur liquid falls below a predetermined liquid level, the liquid level controller 51 opens the flow rate control valve 54 to supply liquid sulfur into the reactor main body 105, thereby The liquid level of the sulfur holding unit 101 is controlled to be constant.
- the hydrogen gas supply unit 130 has a supply nozzle 131 that distributes and supplies hydrogen gas into the liquid sulfur holding unit 101, and the hydrogen gas supplied from the nozzle 131 forms bubbles in the liquid sulfur holding unit 101. It rises and reaches the gas phase reaction region 102 with entrainment of sulfur gas.
- the hydrogen gas supply pipe 12 connected to the hydrogen supply nozzle 131 is provided with a hydrogen gas flow rate control valve 54 and a flow rate controller 53 for detecting the flow rate of the hydrogen gas and controlling it to a predetermined flow rate. Yes.
- the flow rate controller 53 controls the flow rate to a predetermined flow rate necessary for supplying hydrogen gas necessary for the hydrogen sulfide production reaction.
- FIG. 4 is a graph showing the relationship between the hydrogen sulfide concentration and the height from the hydrogen sulfide liquid level held by the reactor body 105 It is an example.
- the vertical axis of the graph shown is the hydrogen sulfide concentration [mol%], and the horizontal axis is the height [m] from the liquid level when the sulfur liquid level is set to “0”.
- the reaction rate of hydrogen sulfide generation is higher as it is closer to the liquid level. For example, in the range of 1 [m] from the liquid level, the conversion rate is high, and it is understood that reaction heat removal and temperature control are necessary in this range.
- the conversion rate is high in the vicinity of the liquid level, and the conversion rate per unit height decreases as the liquid level leaves. This is because in the vicinity of the liquid level, the hydrogen sulfide concentration is low, and the sulfur concentration and the hydrogen concentration are high. If the conversion is high, the reaction temperature is likely to rise due to the heat of reaction. Therefore, as will be described later with reference to FIGS. 3, 5A, and 5B, the heat exchange amount of the heat exchangers 111 to 113 is increased as the liquid level is approached. It is possible to prevent the temperature from becoming higher than the temperature, to prevent excessive production of hydrogen polysulfide, and to prevent the temperature from becoming lower than the predetermined temperature to prevent the reaction rate from decreasing.
- the heat exchanging part removes more heat in the gas phase reaction region closer to the liquid surface than in the gas phase reaction region far from the liquid level, and decreases with increasing distance from the liquid level so as not to cause excessive heat removal. It is configured to appropriately remove the heat of hydrogen sulfide reaction in the phase reaction region.
- FIG. 5A is a diagram illustrating a detailed example of a heat exchanger.
- the heat exchange unit needs to be configured to appropriately remove the heat of hydrogen sulfide reaction in the gas phase reaction region.
- the temperature of the tube is lower than the freezing point of the sulfur when the refrigerant temperature is lowered and the heat removal amount is controlled by the temperature difference delta T, the solidification of the sulfur on the tube surface, resulting in a decrease in the heat transfer coefficient, The amount of heat exchange in the heat exchange section decreases. Therefore, the detailed example of the heat exchange part shown below changes the heat exchange amount by increasing the heat transfer area while keeping the temperature difference delta T in a certain range.
- the heat exchanger 111 is a tube having a spiral shape and cools the gas phase reaction region 102 inside the reactor main body 105.
- the refrigerant flowing in the tube is supplied at a temperature above the freezing point of sulfur.
- oil or steam is used as the refrigerant.
- the heat exchanger 111 has a spiral shape composed of a plurality of loops.
- the refrigerant is supplied from the lower end of the tube, and the refrigerant is extracted from the upper end of the tube.
- the tube of the heat exchanger 111 is configured to fill the gas phase space inside the reactor and intersect with the gas rising from the liquid sulfur.
- the heat exchanger 111 may be configured to have a plurality of loops in the outer peripheral direction from the axial center of the reactor. The same applies to other heat exchangers inside the reactor.
- the distances d1, d2, and d3 (where d1 ⁇ d2 ⁇ d3) in the vertical direction of the loop become smaller as they approach the liquid level, so that the heat exchanger 111 can exchange heat per unit volume in the gas phase reaction region 102.
- the amount (heat removal amount) and the heat transfer area are configured to increase as the liquid level is approached.
- the heat exchanger 112 is configured such that the distances d4, d5, d6 between the loops (where d4 ⁇ d5 ⁇ d6) becomes smaller as it approaches the liquid level.
- the heat exchange amount (heat removal amount) per unit volume and the heat transfer area in the reaction region 102 are configured to increase as the liquid level is approached.
- the heat exchanger 111 occupies a smaller area in the gas phase reaction region 102 than the heat exchanger 112.
- the heat exchanger 111 has the same amount of heat exchange as the heat exchanger 112 or more than the heat exchanger 112, the heat exchangers 111 and 112 per volume in the gas phase reaction region 102 become closer to the liquid level.
- the heat exchange amount is configured to be large.
- the heat exchanger 111 nearest to the liquid level is disposed so as to cool a range within 1 [m] in height from the liquid level.
- the heat exchangers 111a and 112a may be configured so that The same applies to the heat exchanger 113a (not shown).
- the heat exchangers 111 to 113 as the heat exchanging unit 110 are removed from the liquid surface of the liquid sulfur holding unit 102 in order to appropriately remove the heat of hydrogen sulfide reaction in the gas phase reaction region 102. Further, it is arranged so as to occupy a space up to the product gas discharge pipe 13. As shown in FIG. 3, multi-stage heat exchangers are suitable as means for keeping the reaction temperature in the gas phase space as constant as possible and not increasing the H 2 S 2 concentration.
- the heat exchangers 111 to 113 as the heat exchange unit 110 are configured such that the heat exchange amount for heat removal increases as the temperature approaches the liquid level. Therefore, it is possible to prevent the hydrogen sulfide reaction temperature from exceeding the predetermined temperature, to prevent excessive production of hydrogen polysulfide, and to reduce the reaction rate by suppressing the hydrogen sulfide reaction temperature from becoming below the predetermined temperature. prevent.
- the heat exchangers 111 to 113 can prevent the hydrogen sulfide reaction from stopping by appropriately removing the heat of the hydrogen sulfide reaction in the gas phase reaction region that decreases as the distance from the liquid surface increases.
- the hydrogen sulfide synthesis reactor 100 has the heat removal exchange amount per unit volume in the gas phase reaction region far from the liquid level and the heat exchange per unit volume in the gas phase reaction region near the liquid level. Since the amount of heat is changed so that the reaction temperature in the gas phase reaction region is within a predetermined temperature, it is possible to produce high-purity hydrogen sulfide with less generation of side reaction products.
- Rectifying Unit In the heat exchangers 111 to 113 as the heat exchanging unit 110, rectifying plates 115 and 116 (FIG. 3 or 5A, 5B) having a plurality of holes are arranged at appropriate positions in the middle. Gas that rises from the liquid level passes through the plurality of holes, and portions other than the holes prevent the backflow of the cooled gas. In this way, by arranging the rectifying plates 115 and 116 between the heat exchangers 111 to 113, the gas flow from the lower part to the upper part is rectified and uniformly dispersed, and the lower part that can be generated by cooling is reduced. Backflow is prevented, and a theoretical conversion rate according to the gas phase height as shown in FIG. 4 can be realized.
- the heat exchangers 111 to 113 as the heat exchanging unit 110 are configured, and the hydrogen sulfide reaction temperature is prevented from becoming a predetermined temperature or more, and excessive production of hydrogen polysulfide is generated. Moreover, the fall of reaction rate is prevented by suppressing that it becomes below predetermined temperature.
- FIG. 6 is a view showing a modification of the reactor shown in FIG. Since the reactor 100a shown in FIG. 6 has the same configuration as the reactor 100 shown in FIG. 3 except for the heat exchanger and the rectifying plate, the description of the same configuration is omitted. Since the number of heat exchangers is one in the hydrogen sulfide synthesis reactor 100a, it is not necessary to serialize the heat exchangers. Therefore, when the heat of hydrogen sulfide reaction is smaller than that of the hydrogen sulfide synthesis reactor 100, This is suitable when the flow rate of the tube side fluid is large.
- one heat exchanger 110a as the heat exchange unit 110 is configured to increase the heat exchange amount (heat removal amount) per unit volume and the heat transfer area in the gas phase reaction region 102 as it approaches the liquid level. It is possible to suppress the hydrogen sulfide reaction temperature from exceeding a predetermined temperature and to prevent excessive generation of hydrogen polysulfide.
- the heat exchange unit 110 of the present invention is basically configured to have a large heat exchange capacity on the side close to the sulfur liquid surface, regardless of whether it is composed of one heat exchanger or a plurality of heat exchangers.
- the heat exchange capacity of the entire heat exchanging section is continuously changing, but also the heat on the side close to the liquid surface due to the stepwise discontinuous change of the heat exchange capacity. Anything configured to increase the exchange capacity is the configuration of the present invention.
- the rectifying plates 115a and 116a as the rectifying units are not arranged between the plurality of heat exchangers as the heat exchanging unit 110, but are configured to penetrate the heat exchanging unit 110a including one heat exchanger.
- the rectifying plates 115a and 116a rectify the gas flow from the lower part to the upper part to realize uniform heat exchange between the tube and the fluid, and prevent the back flow that may be caused by cooling to the lower part of the gas phase. A corresponding theoretical conversion rate can be realized.
- FIG. 7 is a diagram illustrating an example of a hydrogen sulfide synthesis reactor that controls the reaction temperature of hydrogen sulfide by controlling the amount of refrigerant in the heat exchange unit 110.
- a hydrogen sulfide synthesis reactor 100A shown in FIG. 7 includes temperature detectors 171 to 173 that detect gas temperatures downstream of the heat exchangers 111, 112, and 113 serving as the heat exchange unit 110.
- the heat exchangers 111, 112, and 113 include flow control valves 174, 175, and 176 that adjust the refrigerant flow rate, respectively.
- the hydrogen sulfide synthesis reactor 100A further includes a control unit 160 that controls the reaction temperature of hydrogen sulfide by controlling the flow rate control valve.
- control unit 160 When the gas temperature detected by the temperature detectors 171 to 173 rises above a predetermined value, the control unit 160 opens the flow rate control valves 171 to 173 so that the heat exchange amounts of the heat exchangers 111 to 113 as the heat exchange unit 110 are opened. And the heat is removed so that the gas temperature becomes a predetermined value.
- the control unit 160 is, for example, a distributed control system.
- the temperature at the top of the tower can be set to a predetermined value by the temperature controller 551 at the top of the tower and the refrigerant flow control valve 552 of the heat exchanger 540.
- the temperature in the gas phase reaction region 530 as a whole, particularly in the vicinity of the sulfur liquid surface cannot be controlled, the reaction temperature rises in the region 530 and the H 2 S 2 concentration exceeds the product specification.
- the heat exchange amount of the heat exchangers 111 to 113 as the heat exchanging portion 110 is increased while the heat removal amount on the side close to the sulfur liquid surface is increased, and the side far from the sulfur liquid surface. Control is performed to avoid overcooling in the tank. This makes it possible to control the temperature of the gas phase reaction region 102 as a whole, and eliminate the gas phase reaction region where the temperature cannot be controlled as shown in FIG. 2 to prevent the generation of hydrogen polysulfide and the stop of the hydrogen sulfide reaction.
- FIG. 8 is a diagram showing a second example of the hydrogen sulfide synthesis reactor.
- the hydrogen sulfide synthesis reactor 100a shown in FIG. 8 is smaller in the tower diameter of the reactor main body 105a than the hydrogen sulfide synthesis reactor 100 shown in FIG. 3 and has a large heat exchange area with the outside. It has a large configuration.
- the heating unit 120 provided on the outer surface of the bottom of the reactor main body 105a is composed of electric heaters 121a and 122a, gasifies part of the liquid sulfur, and the temperature detected by the thermometers 174a and 175a is within a predetermined temperature.
- the controller 160 controls the power supply so that
- the hydrogen sulfide synthesis reactor 100a uses the interior of the reactor main body 105 as a liquid sulfur holding unit 101 that holds liquid sulfur and a gas phase reaction region 102 that is a space where a non-catalytic gas phase reaction occurs.
- the heat exchange unit 110b includes electric heaters 111a to 113a. Since the tower diameter is very small, the amount of natural heat radiation around the reactor main body 105a is large, and the reaction temperature cannot be kept constant unless heated by the electric heaters 111a to 113a.
- the electric heaters 111a to 113a are controlled to be fed by the control unit 160 so that the temperatures detected by the thermometers 171a to 173a are within a predetermined temperature.
- the electric heaters 111a to 113a are configured such that the amount of heat exchange of the electric heater 111a on the side close to the sulfur liquid surface is the largest, and the amount of heat exchange decreases in the order of the electric heaters 112a and 113a.
- the tower diameter of the reactor main body is small and the heat exchange area with the outside is large, even if the amount of natural heat radiation is large, cooling of the reactor is suppressed by heating with an electric heater. Since the reaction heat of hydrogen sulfide decreases with increasing distance from the liquid surface, the amount of heat released also decreases with increasing distance from the liquid surface. Accordingly, the amount of exchange heat for heating the electric heater is configured to become smaller as the distance from the liquid level increases.
- the temperature and pressure conditions of the reactor main body 105a at this time are the same as those in the reactor of the hydrogen synthesis reactor 100 described with reference to FIG.
- the hydrogen sulfide synthesis reactor 100a has an exchange heat amount for heating per unit volume in the gas phase reaction region far from the liquid level, and for heating per unit volume in the gas phase reaction region near the liquid level. Since the reaction temperature in the gas phase reaction region is changed within a predetermined temperature by changing the exchange heat quantity of the reactor, even if the column diameter of the reactor main body is small, the production of by-products is reduced and high-purity hydrogen sulfide Can be manufactured.
- FIG. 9 is a diagram showing an example of a hydrogen sulfide production apparatus including the hydrogen sulfide synthesis reactor shown in FIG.
- the hydrogen sulfide production apparatus 10 includes a hydrogen sulfide synthesis reactor 100 shown in FIG. 3, a hydrogenation reactor 200 that converts unreacted sulfur gas released together with hydrogen sulfide gas into hydrogen sulfide, a high-temperature product gas, and a raw material.
- a hydrogen gas heat exchanger 210 that exchanges heat of hydrogen gas, a liquefier 220, and a gas-liquid separator 300 that separates hydrogen gas and liquefied hydrogen sulfide are included.
- the hydrogenation reactor 200 is internally filled with a hydrogenation catalyst such as Co—Mo or Ni—Mo sulfide or Ni 2 S 2 , and hydrogen gas, sulfur from the hydrogen sulfide synthesis reactor 100 through the pipe 13. Gas and hydrogen sulfide gas are received, and unreacted sulfur gas is converted into hydrogen sulfide gas with hydrogen gas. Further, the hydrogen gas is separated by the gas-liquid separator 300 in the subsequent stage and reused in the hydrogen sulfide synthesis reactor 100.
- a hydrogenation catalyst such as Co—Mo or Ni—Mo sulfide or Ni 2 S 2
- outlet gas of the hydrogenation reactor 200 has a sulfur gas concentration of substantially zero, so that no downstream equipment for removing sulfur gas is required.
- the liquefaction device 220 includes a product gas compressor 230 that compresses the product gas and a heat exchanger 240 that cools the product gas.
- the gas processed in the hydrogenation reactor 200 is supplied to the heat exchanger 210 via the pipe 14 and is heat-exchanged with the low-temperature hydrogen gas supplied from the gas-liquid separator 300.
- the exhaust gas from the heat exchanger 210 is compressed by the product gas compressor 230 and supplied to the heat exchanger 240 through the pipe 15.
- the heat exchanger 240 is cooled, for example, at minus 30 ° C., and is divided into liquid hydrogen sulfide and hydrogen gas by the gas-liquid separator 300.
- the hydrogen gas is supplied to the reactor main body 110 through the pipe 16 and the pipe 12, and the liquefied hydrogen sulfide is used in product shipment or other processes through the pipe 17.
- FIG. 10 is a diagram showing an example of a sodium hydrogen sulfide production apparatus including the hydrogen sulfide synthesis reactor shown in FIG.
- the sodium hydrogen sulfide production apparatus 20 shown in FIG. 10 does not include the product gas compressor 230, the cooler 240, and the gas-liquid separator 300, instead of the hydrogen sulfide production apparatus 10 shown in FIG.
- the sodium hydrogen sulfide synthesis reactor 400 has a packed bed filled with, for example, a 1-inch pole ring, and hydrogen sulfide discharged from the line 23 by contacting sodium hydroxide and hydrogen sulfide in the packed bed. Reduce gas concentration.
- the sodium hydrogen sulfide production apparatus 20 can prevent the generation of sodium polysulfide by preventing the generation of hydrogen disulfide in the hydrogen sulfide synthesis reactor 100.
- the hydrogen sulfide production apparatus 10 In the hydrogen sulfide production apparatus 10, equipment such as the product gas compressor 230 is required to liquefy and separate hydrogen sulfide. However, the sodium hydrogen sulfide production apparatus 20 uses hydrogen sulfide as a gas to produce water. By reacting with sodium oxide, equipment such as the product gas compressor 230 is not required.
- Hydrogen sulfide was synthesized using the hydrogen sulfide synthesis reactor 100 shown in FIG.
- the reactor main body 105 is made of, for example, stainless steel having an inner diameter of 1200 mm and a height of 4000 mm, and hydrogen gas heated to 200 ° C. is fed from the lower part of the reactor main body 105 through the pipe 12, so that the hydrogen sulfide synthesis reactor Liquid sulfur was heated to 410 ° C. with a heater.
- hydrogen sulfide is generated under the following reaction conditions.
- Reaction temperature 405 to 410 [° C.]
- the hydrogen polysulfide concentration can be less than 10 ppm.
- Hydrogen sulfide was synthesized using the hydrogen sulfide synthesis reactor 100a shown in FIG.
- the reactor body 105 is made of stainless steel having a diameter of 80 mm (3 inches) and a height of 2500 mm, and a sulfur condenser (not shown) is installed thereon. Outside the reactor, electric heaters 120a and 110b divided into five parts are installed for temperature control.
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Abstract
Description
硫黄ガス及び水素ガスが、触媒が充填された反応管内で反応することで、硫化水素が生成する。反応熱は、反応管の外部に熱媒体を流して除去する。このような触媒反応は、例えば、下記特許文献1に示される。
無触媒気相反応は、例えば、下記非特許文献1の頁474のFigure1に示される。無触媒の気相反応では、沸点温度で液体硫黄を保持する塔底部と、硫黄ガスと水素ガスとを反応させるガス空間部を有する反応塔を用いて、硫化水素を製造する。水素ガスは、塔底部内の液体硫黄に導入され、水素ガスおよび硫黄ガスは、ガス空間部で反応し、硫化水素を生成する。硫化水素の反応熱は、ガス空間部上部から供給される液体硫黄と接触させることで、回収される。硫化水素と硫黄ガスを含有する生成物ガスは、熱交換器により冷却して、硫黄を固化することで、硫化水素ガスを精製する。
1.硫黄と水素とを無触媒で気相反応させて、硫化水素を合成する硫化水素合成反応器であって、
下部に液体硫黄を溜める反応器本体と、
前記液体硫黄の一部をガス化する加熱部と、
前記液体硫黄に水素ガスを供給する水素ガス供給部と、
前記反応器本体内の液体硫黄の液面より上方の気相反応領域に設ける熱交換部と、を備え、
前記熱交換部を、前記液面から遠い気相反応領域の単位容積当りの交換熱量と、前記液面に近い気相反応領域で単位容積当りの交換熱量とを変えて、前記気相反応領域での反応温度を所定の温度内にするように構成することを特徴とする硫化水素合成反応器。副反応物の生成を少なくして純度の高い硫化水素を製造することができる。
2.前記熱交換部は、液面から離れるにつれて、単位容積当りの交換熱量が下がるように構成される項目1に記載の硫化水素合成反応器。
3.前記熱交換部を、前記液面から遠い気相反応領域の単位容積当たりの伝熱面積より、前記液面に近い気相反応領域の単位容積当たりの伝熱面積が大きくなるように構成する項目1又は2に記載の硫化水素合成反応器。
4.前記所定の温度は、380℃~410℃である項目1~3の何れか1項に記載の硫化水素合成反応器。410℃以下にすることで、圧力0.5
MPaの時、H2S2の濃度を10ppm未満に抑えることができる。反応温度を下げると、反応速度が下がるために、少なくとも380℃以上にする。
5.前記熱交換部の冷媒は、硫黄の凝固点以上で供給される項目1~4の何れか1項に記載の硫化水素合成反応器。
6.前記熱交換部は、複数の熱交換器から構成される項目1~5の何れか1項に記載の硫化水素合成反応器。
7.前記熱交換部に、前記ガスが通過する複数の孔を有する整流部を備える項目1~6の何れか1項に記載の硫化水素合成反応器。下部から上部へのガス流を整流して均一に分散するとともに、冷却により生じ得る下部への逆流を防ぎ、気相部高さに応じた理論的な転化率を実現できる。
8.前記気相反応領域のガス温度を検出する温度検出器と、
前記検出した温度が所定値になるように、前記各熱交換部の熱交換量を制御する制御部と、をさらに備える項目1~7の何れか1項に記載の硫化水素合成反応器。
9.前記硫化水素反応熱により生じる熱量より、前記反応器本体の表面からの放熱が高い場合、気相反応領域における反応温度を所定温度内に保つために、前記熱交換部を、前記反応器本体を加熱するように構成することを特徴とする項目1~8の何れか1項に記載の硫化水素合成反応器。反応器本体の塔径が小さい場合でも、副反応物の生成を少なくして純度の高い硫化水素を製造することができる。
10.項目1~9の何れか1項に記載の前記硫化水素合成反応器と、
前記硫化水素合成反応器から放出される未反応硫黄ガスと水素ガスとを水添触媒を用いて反応させて、硫化水素を合成する水添反応器と、を備えることを特徴とする硫化水素製造装置。未反応の硫黄ガスを、水素ガスで硫化水素ガスに転化することができる。
11.硫化水素を液化する液化装置をさらに備える項目1~10の何れか1項に記載の硫化水素製造装置。
12.硫化水素ナトリウムを合成する硫化水素ナトリウム製造装置であって、
項目1~11の何れか1項に記載の前記硫化水素合成反応器と、
前記硫化水素合成反応器から放出される未反応硫黄ガスと水素ガスとを水添触媒を用いて反応させて、硫化水素を合成する水添反応器と、
硫化水素と、水酸化ナトリウム水溶液を反応させて、硫化水素ナトリウムを合成する硫化水素ナトリウム合成反応器と、を備える硫化水素ナトリウム製造装置。
13.硫黄と水素とを無触媒で気相反応させて、硫化水素を合成する硫化水素製造方法であって、
反応器の下部に溜まった液体硫黄の一部を加熱し、
前記液体硫黄に水素ガスを供給し、
前記反応器内の液体硫黄の液面より上方の気相反応領域で、前記加熱により生成した硫黄ガスと、前記水素ガスとを気相反応させ、
前記液面から遠い気相反応領域の単位容積当りの交換熱量と、前記液面に近い気相反応領域で単位容積当りの交換熱量とを変えて、前記気相反応領域での反応温度を所定の温度内にするように除熱する、ことを特徴とする硫化水素製造方法。
14.前記除熱工程は、液面から離れるにつれて、単位容積当りの交換熱量が下がるように除熱することを含む項目13に記載の硫化水素製造方法。
15.前記所定の温度は、380℃~410℃である項目13又は14に記載の硫化水素合成反応器。
16.前記除熱は、硫黄の凝固点以上の冷媒で行う項目13~15の何れか1項に記載の硫化水素製造反応。
17.前記除熱を行う熱交換部の設けられた複数の孔を有する整流部を、前記ガスが通過する項目13~16の何れか1項に記載の硫化水素製造方法。
18.前記硫化水素合成反応器から放出される未反応硫黄ガスと水素ガスとを水添触媒を用いて反応させて、硫化水素に転化する項目13~17の何れか1項に記載の硫化水素製造方法。
19.前記除熱工程は、前記硫化水素反応熱により生じる熱量より、前記反応器本体の表面からの放熱が高い場合、気相反応領域における反応温度を所定温度内に保つために、加熱する工程を含む項目13~18の何れか1項に記載の硫化水素製造方法。
20.硫化水素を液化する項目13~19の何れか1項に記載の硫化水素製造方法。
21.硫化水素ナトリウムを生成する硫化水素ナトリウム製造方法であって、
項目13~19の何れか1項に記載の硫化水素製造方法により生成された硫化水素と、水酸化ナトリウム水溶液とを反応させて、硫化水素ナトリウムを生成する硫化水素ナトリウム製造方法。
硫化水素生成反応は、以下の式1により進行するが、硫化水素生成とともに、式2に示す反応式により、多硫化水素が生成する。以下の説明においては、硫化水素生成反応において、最も濃度が高い多硫化水素である二硫化水素(H2S2)について説明する。
H2 + 1/2S2 → H2S (式1)
2H2S → H2 + H2S2 (式2)
MPaの時、反応温度を410℃以下に制御する必要がある。当該反応温度より温度が上昇すると、H2S2濃度が10ppmを超えてしまう。このように、硫化水素の反応温度は、410℃以下になることが好ましい。一方、反応温度を下げると、反応速度が下がるために、少なくとも380温度以上になることが好ましい。
図3は、本発明の実施形態に係る硫化水素合成反応器の第1例を示す図である。図3に示す硫化水素合成反応器100は、液体硫黄を下部に貯留可能とする反応器本体105、反応器本体105内の反応領域温度を一定に維持する熱交換部110、反応器本体105に貯留される液体硫黄を加熱して、液体硫黄の一部をガス化する加熱部120、および液体硫黄中に水素ガスを供給する水素供給部130を備える。さらに、液体硫黄の供給用配管11、水素ガスの供給用配管12、及び生成ガスの排出用配管13を備える。硫化水素合成反応器100は、反応器本体105の内部を、液体硫黄を保持する液体硫黄保持部101と、無触媒気相反応が起こる空間である気相反応領域102として使用する。本発明の熱交換部110は、3つの熱交換器111~113を有し、硫黄液面に近い側の熱交換器111の熱交換容量が最も大きく、熱交換器112、113の順に熱交換容量が小さくなるように構成されている。
図4は、硫化水素濃度と、反応器本体105で保持される硫化水素液面からの高さの関係を示すグラフの例である。図示するグラフの縦軸は、硫化水素濃度[mol%]であり、横軸は、硫黄液面を“0”とした場合の液面からの高さ[m]である。硫化水素生成の反応速度は、液面に近いほど高いことがわかる。例えば、液面から1[m]の範囲内では、転化率が高く、当該範囲で反応熱除去と、温度制御が必要なことがわかる。
熱交換部での除熱量が硫化水素反応熱より大きくなると、反応温度が低下し、硫化水素生成反応が停止する。それにより、未反応の水素、硫黄が増加して、硫化水素合成反応器100から流出する。したがって、液面側に近い熱交換器で硫化水素反応熱力より過剰に大きな除熱量をとる、又は、液面側から遠い熱交換器で硫化水素反応熱力より過剰に大きな除熱量をとると、硫化水素生成反応が停止するという問題が生じる。そのため、熱交換部は、液面から遠い気相反応領域より、液面に近い気相反応領域で多く除熱するとともに、過剰な除熱を生じないように、液面から離れるにつれて減少する気相反応領域の硫化水素反応熱を適切に除熱するように構成される。
図5Aは、熱交換器の詳細例を示す図である。上記したように、熱交換部は、気相反応領域の硫化水素反応熱を適切に除熱するように構成される必要がある。しかしながら、冷媒温度を下げて、除熱量を温度差デルタTで制御した場合、チューブの温度が硫黄の凝固点よりも低いと、チューブ表面での硫黄の固化、それによる伝熱係数の低下が生じ、熱交換部の熱交換量が下がる。そのため、以下に示す熱交換部の詳細例は、温度差デルタTを一定範囲に保ちながら、伝熱面積を増やすことにより、熱交換量を変化させる。
熱交換部110としての熱交換器111~113には、その中間の適宜の位置に複数の穴を有する整流板115及び116(図3又は図5A、5B)を配置する。複数の穴は、液面から上昇するガスが通過し、穴以外の部分は、冷えたガスの逆流を防ぐ。このように、整流板115及び116が、熱交換器111~113の間に配置されることで、下部から上部へのガス流を整流して均一に分散するとともに、冷却により生じ得る下部への逆流を防ぎ、図4に示すような、気相部高さに応じた理論的な転化率を実現できる。よって、理論的な転化率に基づいて、熱交換部110としての熱交換器111~113を構成し、硫化水素反応温度が、所定温度以上になることを抑制し、多硫化水素の過剰な生成を防ぐことができ、また、所定温度以下になることを抑制することで反応速度の低下を防ぐ。
図7は、熱交換部110の冷媒量を制御することで、硫化水素の反応温度を制御する硫化水素合成反応器の一例を説明する図である。図7に示す硫化水素合成反応器100Aは、熱交換部110としての熱交換器111、112、及び113の下流に、ガス温度を検出する温度検出器171~173を有する。熱交換器111、112、及び113は、それぞれ冷媒流量を調整する流量制御弁174、175、及び176を備える。硫化水素合成反応器100Aはさらに、流量制御弁を制御することで、硫化水素の反応温度を制御する制御部160を有する。制御部160は、温度検出器171~173で検出したガス温度が所定値より上がると、流量制御弁171~173を開くことで、熱交換部110としての熱交換器111~113の熱交換量を制御し、ガス温度が所定値になるように除熱する。制御部160は、例えば、分散制御システム(Distributed Control System)である。
図9は、図3に示した硫化水素合成反応器を含む硫化水素製造装置の一例を示す図である。硫化水素製造装置10は、図3に示した硫化水素合成反応器100、硫化水素ガスと共に放出される未反応硫黄ガスを、硫化水素に転化する水添反応器200、高温の生成ガスと、原料水素ガスを熱交換する水素ガス熱交換器210、液化装置220、及び、水素ガスと液化硫化水素とを分離する気液分離器300を有する。
図10は、図3に示した硫化水素合成反応器を含む硫化水素ナトリウム製造装置の一例を示す図である。図10に示す硫化水素ナトリウム製造装置20は、図3に示す硫化水素製造装置10と比して、生成ガス圧縮機230、冷却器240、及び、気液分離器300を有さず、代わりに、硫化水素と、水酸化ナトリウム(NaOH)から硫化水素ナトリウムを生成する硫化水素ナトリウム合成反応器400を有する。
2NaOH + H2S →Na2S + 2H2O (式3)
Na2S + H2S →2NaSH (式4)
NaOH + H2S →NaSH + H2O (式5)
2NaOH + H2S2 →Na2S2 + 2H2O (式6)
多硫化ナトリウムが多く含まれると下流反応工程の製品品質を悪化することに通じる。硫化水素ナトリウム製造装置20は、硫化水素合成反応器100において、二硫化水素の生成を防ぐことで、多硫化ナトリウムの生成を防ぐことができる。
反応温度 405~410[℃]
反応圧力 0.2~0.6[MPaA]
転化率 50~60[mol%]
多硫化水素濃度を10ppm未満とすることができる。
Claims (21)
- 硫黄と水素とを無触媒で気相反応させて、硫化水素を合成する硫化水素合成反応器であって、
下部に液体硫黄を溜める反応器本体と、
前記液体硫黄の一部をガス化する加熱部と、
前記液体硫黄に水素ガスを供給する水素ガス供給部と、
前記反応器本体内の液体硫黄の液面より上方の気相反応領域に設ける熱交換部と、を備え、
前記熱交換部を、前記液面から遠い気相反応領域の単位容積当りの交換熱量と、前記液面に近い気相反応領域で単位容積当りの交換熱量とを変えて、前記気相反応領域での反応温度を所定の温度内にするように構成することを特徴とする硫化水素合成反応器。 - 前記熱交換部は、液面から離れるにつれて、単位容積当りの交換熱量が下がるように構成される請求項1に記載の硫化水素合成反応器。
- 前記熱交換部を、前記液面から遠い気相反応領域の単位容積当たりの伝熱面積より、前記液面に近い気相反応領域の単位容積当たりの伝熱面積が大きくなるように構成する請求項1又は2に記載の硫化水素合成反応器。
- 前記所定の温度は、380℃~410℃である請求項1~3の何れか1項に記載の硫化水素合成反応器。
- 前記熱交換部の冷媒は、硫黄の凝固点以上で供給される請求項1~4の何れか1項に記載の硫化水素合成反応器。
- 前記熱交換部は、複数の熱交換器から構成される請求項1~5の何れか1項に記載の硫化水素合成反応器。
- 前記熱交換部に、前記ガスが通過する複数の孔を有する整流部を備える請求項1~6の何れか1項に記載の硫化水素合成反応器。
- 前記気相反応領域のガス温度を検出する温度検出器と、
前記検出した温度が所定値になるように、前記各熱交換部の熱交換量を制御する制御部と、をさらに備える請求項1~7の何れか1項に記載の硫化水素合成反応器。 - 前記硫化水素反応熱により生じる熱量より、前記反応器本体の表面からの放熱が高い場合、気相反応領域における反応温度を所定温度内に保つために、前記熱交換部を、前記反応器本体を加熱するように構成することを特徴とする請求項1~8の何れか1項に記載の硫化水素合成反応器。
- 請求項1~9の何れか1項に記載の前記硫化水素合成反応器と、
前記硫化水素合成反応器から放出される未反応硫黄ガスと水素ガスとを水添触媒を用いて反応させて、硫化水素を合成する水添反応器と、を備えることを特徴とする硫化水素製造装置。 - 硫化水素を液化する液化装置をさらに備える請求項1~10の何れか1項に記載の硫化水素製造装置。
- 硫化水素ナトリウムを合成する硫化水素ナトリウム製造装置であって、
請求項1~11の何れか1項に記載の前記硫化水素合成反応器と、
前記硫化水素合成反応器から放出される未反応硫黄ガスと水素ガスとを水添触媒を用いて反応させて、硫化水素を合成する水添反応器と、
硫化水素と、水酸化ナトリウム水溶液を反応させて、硫化水素ナトリウムを合成する硫化水素ナトリウム合成反応器と、を備える硫化水素ナトリウム製造装置。 - 硫黄と水素とを無触媒で気相反応させて、硫化水素を合成する硫化水素製造方法であって、
反応器の下部に溜まった液体硫黄の一部を加熱し、
前記液体硫黄に水素ガスを供給し、
前記反応器内の液体硫黄の液面より上方の気相反応領域で、前記加熱により生成した硫黄ガスと、前記水素ガスとを気相反応させ、
前記液面から遠い気相反応領域の単位容積当りの交換熱量と、前記液面に近い気相反応領域で単位容積当りの交換熱量とを変えて、前記気相反応領域での反応温度を所定の温度内にするように除熱する、ことを特徴とする硫化水素製造方法。 - 前記除熱工程は、液面から離れるにつれて、単位容積当りの交換熱量が下がるように除熱することを含む請求項13に記載の硫化水素製造方法。
- 前記所定の温度は、380℃~410℃である請求項13又は14に記載の硫化水素合成反応器。
- 前記除熱は、硫黄の凝固点以上の冷媒で行う請求項13~15の何れか1項に記載の硫化水素製造反応。
- 前記除熱を行う熱交換部の設けられた複数の孔を有する整流部を、前記ガスが通過する請求項13~16の何れか1項に記載の硫化水素製造方法。
- 前記硫化水素合成反応器から放出される未反応硫黄ガスと水素ガスとを水添触媒を用いて反応させて、硫化水素に転化する請求項13~17の何れか1項に記載の硫化水素製造方法。
- 前記除熱工程は、前記硫化水素反応熱により生じる熱量より、前記反応器本体の表面からの放熱が高い場合、気相反応領域における反応温度を所定温度内に保つために、加熱する工程を含む請求項13~18の何れか1項に記載の硫化水素製造方法。
- 硫化水素を液化する請求項13~19の何れか1項に記載の硫化水素製造方法。
- 硫化水素ナトリウムを生成する硫化水素ナトリウム製造方法であって、
請求項13~19の何れか1項に記載の硫化水素製造方法により生成された硫化水素と、水酸化ナトリウム水溶液とを反応させて、硫化水素ナトリウムを生成する硫化水素ナトリウム製造方法。
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US13/781,757 US8551442B2 (en) | 2011-08-23 | 2013-03-01 | Reactor for synthesizing hydrogen sulfide, apparatus for producing hydrogen sulfide, apparatus for producing sodium hydrogen sulfide, method for producing hydrogen sulfide, and method for producing sodium hydrogen sulfide |
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WO2022255180A1 (ja) * | 2021-05-31 | 2022-12-08 | 古河機械金属株式会社 | 硫化水素製造装置および硫化水素の製造方法 |
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CN104971601B (zh) * | 2014-04-10 | 2017-04-12 | 中国石油化工股份有限公司 | 一种酸性气立式反应器及处理方法 |
CA3007925C (en) | 2015-12-10 | 2023-05-16 | Daniel M. Hasenberg | Hydrogen sulfide production process and related reactor vessels |
ES2873380T3 (es) | 2016-05-31 | 2021-11-03 | Novus Int Inc | Procedimiento para producir metil mercaptano a partir de sulfuro de dimetilo |
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CN108799644B (zh) * | 2018-07-27 | 2023-07-21 | 四川大学 | 过热硫蒸气制备装置 |
KR102623738B1 (ko) * | 2021-08-11 | 2024-01-11 | 주식회사 레이크테크놀로지 | 황화수소 반응기 및 황화수소 제조방법 |
KR102674768B1 (ko) * | 2021-10-28 | 2024-06-13 | 주식회사 레이크테크놀로지 | 황화수소 반응기 |
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