WO2011162244A1 - 塊状処理剤 - Google Patents
塊状処理剤 Download PDFInfo
- Publication number
- WO2011162244A1 WO2011162244A1 PCT/JP2011/064143 JP2011064143W WO2011162244A1 WO 2011162244 A1 WO2011162244 A1 WO 2011162244A1 JP 2011064143 W JP2011064143 W JP 2011064143W WO 2011162244 A1 WO2011162244 A1 WO 2011162244A1
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- Prior art keywords
- treatment agent
- present
- water
- acid
- odor
- Prior art date
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- PXEDJBXQKAGXNJ-QTNFYWBSSA-L disodium L-glutamate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](N)CCC([O-])=O PXEDJBXQKAGXNJ-QTNFYWBSSA-L 0.000 description 1
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- 235000010350 erythorbic acid Nutrition 0.000 description 1
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- 239000010794 food waste Substances 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- RQFCJASXJCIDSX-UUOKFMHZSA-N guanosine 5'-monophosphate Chemical compound C1=2NC(N)=NC(=O)C=2N=CN1[C@@H]1O[C@H](COP(O)(O)=O)[C@@H](O)[C@H]1O RQFCJASXJCIDSX-UUOKFMHZSA-N 0.000 description 1
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- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
- RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
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- 229940026239 isoascorbic acid Drugs 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000027939 micturition Effects 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
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- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- NFIYTPYOYDDLGO-UHFFFAOYSA-N phosphoric acid;sodium Chemical compound [Na].OP(O)(O)=O NFIYTPYOYDDLGO-UHFFFAOYSA-N 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002643 polyglutamic acid Polymers 0.000 description 1
- 229920005596 polymer binder Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- CHKVPAROMQMJNQ-UHFFFAOYSA-M potassium bisulfate Chemical compound [K+].OS([O-])(=O)=O CHKVPAROMQMJNQ-UHFFFAOYSA-M 0.000 description 1
- 229910000343 potassium bisulfate Inorganic materials 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 229940074386 skatole Drugs 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000010352 sodium erythorbate Nutrition 0.000 description 1
- 239000004320 sodium erythorbate Substances 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 1
- 239000008279 sol Substances 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229920000247 superabsorbent polymer Polymers 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- ODBLHEXUDAPZAU-UHFFFAOYSA-N threo-D-isocitric acid Natural products OC(=O)C(O)C(C(O)=O)CC(O)=O ODBLHEXUDAPZAU-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 210000004916 vomit Anatomy 0.000 description 1
- 230000008673 vomiting Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/23—Solid substances, e.g. granules, powders, blocks, tablets
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/014—Deodorant compositions containing sorbent material, e.g. activated carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/005—Black water originating from toilets
Definitions
- the present invention relates to a treatment agent. More specifically, the present invention relates to a treatment agent used for treatment of manure and the like.
- toilets can be divided into two types: a flush type that allows manure to flow into the sewer along with water, and a flush type that can be stored in a tank.
- a flush toilet manure is flushed with the water into the sewer and processed at the sewage treatment plant.
- a draw-up type toilet manure is drawn from the tank by a vacuum car or the like and is transported to a sewage treatment plant for processing.
- sewage containing manure is stored in a septic tank, where organic matter in manure is decomposed and removed by the action of microorganisms such as activated sludge, and then the water is purified through several stages of treatment, Released into the river.
- microorganisms such as activated sludge
- Patent Document 1 discloses that an acrylic acid monomer aqueous solution having a neutralization rate of 50 mol% or more is subjected to a polymerization reaction, and after adding a hydrophilic polyvalent epoxy compound and a polymerization initiator, light is emitted. Irradiated to repolymerize to form a gel-like solid, and this gel-like solid is dried with hot air, pulverized and selected, and surface treated with a surface cross-linking agent. A polymer is disclosed.
- an object of the present invention is to suppress the generation of bad odor and gas from the object to be processed, and to solve at least one of the problems in use.
- a toilet bowl in which the bulk treatment agent according to any one of (1) to (5) or the granular treatment agent according to (6) or (7) is arranged in advance.
- An absorptive article for manure which is formed by including the block treatment agent according to any one of (1) to (5) or the granule treatment agent according to (6) or (7).
- the present invention has the following effects by the above-described invention.
- the first of the present invention is a block treatment agent containing slaked lime or limestone, a water-absorbing polymer, and a binder.
- the 1st block treatment agent of this invention can neutralize the ammonia which may generate
- a to-be-processed object for example, stool, urine
- the handling area is improved while the contact area with the workpiece is increased, and the reaction with the workpiece is increased. Efficiency can be improved.
- the 1st block treatment agent of this invention further containing at least 1 sort (s) of additive selected from the group which consists of a zeolite, activated carbon, baking soda, and a lubrication agent. .
- the 1st block treatment agent of this invention contains slaked lime or limestone, a water absorbing polymer, and a binder, it is especially suitable for the treatment of manure.
- a second aspect of the present invention is a granular treatment agent obtained by pulverizing the first bulk treatment agent of the present invention.
- the handling area is improved while the contact area with the object to be treated is increased.
- the reaction efficiency with the product can be improved.
- a third aspect of the present invention is a toilet in which the first bulk treatment agent of the present invention or the second granular treatment agent of the present invention is arranged in advance.
- the toilet bowl of the present invention is preliminarily provided with a treatment agent, after excretion, the user does not need to check his / her own (or care recipient, etc.) feces and urine, and the user can use it comfortably. Can do.
- a fourth aspect of the present invention is formed by including the block treatment agent according to any one of (1) to (5) or the granule treatment agent according to (6) or (7). It is an absorbent article for manure. With such a configuration, it is possible to easily and efficiently treat urine and the like without requiring an operation such as stirring, and it is possible to suppress the generation of malodor and gas. Further, the first lump treatment agent of the present invention or the second granular treatment agent of the present invention present in the absorbent article has a very excellent deodorizing property and a dry feeling is remarkable. This can greatly reduce the burden on the person who is doing this and for the caregivers.
- the first of the present invention is a block treatment agent containing slaked lime or limestone, a water-absorbing polymer, and a binder.
- the processing agent of this invention is solidified by including a binder, it is excellent in handleability.
- the component which comprises the 1st block treatment agent of this invention exists in the state mutually bound by the binder.
- the shape of the first lump treatment agent of the present invention also includes slaked lime or limestone, a water-absorbing polymer, and a binder.
- treatment agent slaked lime or limestone
- a water-absorbing polymer e.g., polystyrene resin
- a binder e.g., polystyrene resin
- any shape such as a spherical shape, a cylindrical shape, a middle-high cylindrical shape, and a rectangular parallelepiped shape may be used.
- a spherical shape, a cylindrical shape, a middle-high columnar shape, and the like are preferable, and from a viewpoint of manufacturing, a cylindrical shape and a middle-high columnar shape are preferable.
- the average diameter of the first block treatment agent of the present invention is preferably 3 to 100 mm. By being in such a range, the above-mentioned problems due to dust can be significantly solved, and the contact area with the object to be processed is increased while improving the handleability, and the reaction efficiency with the object to be processed. It is easy to improve the above-described effects.
- the average diameter of the first block treatment agent of the present invention is more preferably 6 to 50 mm, and further preferably 7 to 20 mm.
- the average diameter of the first bulk treatment agent of the present invention is an average obtained by arbitrarily selecting 50 grain treatment agents, measuring the longest particle diameter for each grain, and arithmetically averaging them. Mean value.
- the average thickness of the first block treatment agent of the present invention is preferably 1 to 30 mm.
- the average thickness of the first block treatment agent of the present invention is more preferably 2 to 15 mm, and further preferably 4 to 10 mm. By being in this range, the above-described effects can be easily achieved.
- the average diameter is 7 to 20 mm and the average thickness is 4 to 10 mm, the rate of disintegration when contacted with the workpiece increases, and also from the viewpoint of producing such a treatment agent. It is easy and particularly preferred.
- the 1st block treatment agent of this invention is a column shape, a middle-high column shape, and a rectangular parallelepiped form, a long axis will become an average diameter.
- the weight of the first bulk treatment agent of the present invention is not particularly limited, but in view of transportability and handleability, the weight per grain is preferably about 0.05 to 30 g, more preferably Is about 0.2 to 10 g, more preferably about 0.3 to 2 g. Of course, it may be outside this range.
- slaked lime Since slaked lime (Ca (OH) 2 ) that can be contained in the first bulk treatment agent of the present invention is a strong alkali, it has a large bactericidal effect during the excrement treatment (especially stool). In addition, animals and livestock infected by foot-and-mouth disease and bird flu, or dead bodies thereof, food (plants, etc.) that the animals and livestock were eating, livestock houses where the animals or livestock existed or existed, Alternatively, it is effective for sterilizing, sterilizing, disinfecting, and deodorizing soil and roads in the vicinity of the livestock house. This stops fermentation and decomposition of organic matter. Then, it is sterilized, sterilized and disinfected. And the effect which reduces an odor can be acquired. Moreover, since slaked lime mainly adsorb
- the shape of the slaked lime is not particularly limited, and examples thereof include powdery granules and pellets, but are preferably granular from the viewpoint of effectively dispersing slaked lime with respect to stool.
- the lower limit of the average particle diameter is not particularly limited, but is not particularly limited, for example, 10 ⁇ m or more, more preferably 50 ⁇ m or more
- the upper limit is, for example, 1000 ⁇ m or less, preferably 500 ⁇ m or less, more preferably 300 ⁇ m.
- it is more preferably 150 ⁇ m or less. That is, 10 to 1000 ⁇ m is preferable, 50 to 300 ⁇ m is preferable, and 100 to 150 ⁇ m is preferable.
- the slaked lime may be used in combination of two or more slaked limes having different average particle sizes.
- the average particle diameter means an average value obtained by arbitrarily selecting 100 grains, measuring the longest grain diameter for each grain, and arithmetically averaging them.
- the “average particle diameter” described in the present specification has the same definition. In order to obtain a desired average particle size, it may be appropriately sieved.
- Slaked lime used in the present invention may be surface-treated with a hydrophobic coating agent. Moreover, the slaked lime used by this invention may synthesize
- the content of the slaked lime is about 5 to 90% by mass, 10 to 80% by mass with respect to the total mass (100% by mass; the same applies hereinafter) of the block treatment agent. % Or 15 to 70 mass. If it is this range, the effect of odor reduction and the suppression of gas generation
- Limestone (calcium carbonate) that can be contained in the first bulk treatment agent of the present invention is a calcium carbonate represented by the composition formula CaCO 3 . Since limestone is alkaline, it has the same effect as slaked lime.
- the shape of the limestone is not particularly limited, and examples thereof include a granular shape and a pellet shape. From the viewpoint of effectively dispersing the stool, the limestone shape is preferable.
- the lower limit of the average particle diameter is not particularly limited, but is not particularly limited, for example, 10 ⁇ m or more, more preferably 50 ⁇ m or more, and the upper limit is, for example, 1000 ⁇ m or less, preferably 500 ⁇ m or less, more preferably 300 ⁇ m.
- it is more preferably 150 ⁇ m or less. That is, 10 to 1000 ⁇ m is preferable, 50 to 300 ⁇ m is preferable, and 100 to 150 ⁇ m is preferable.
- the production can be facilitated and the production cost can be reduced, the contact area between the resulting treatment agent and the object to be treated is increased, and the reaction efficiency may be improved. It does not occur and no unreacted material remains.
- the said limestone may be used in combination of 2 or more types of limestone from which average particle diameter differs.
- the content of the limestone is about 5 to 90% by mass, about 10 to 80% by mass, or 15 to 70% with respect to the total mass of the block treatment agent. It is about mass%. If it is this range, the effect of the odor reduction at the time of processing of a to-be-processed object (for example, manure) and the suppression of gas generation will be acquired more favorably.
- a method of preparing limestone a method of purchasing a commercially available product is preferable, and for example, Tankar of Ube Materials Co., Ltd., Industrial Tankar of Yoshizawa Lime Industry Co., Ltd., etc. are preferable.
- Water-absorbing polymer also referred to as water-absorbing agent or polymer water-absorbing agent
- the water-absorbing polymer (water-absorbing agent) contained in the first block treatment agent of the present invention serves to assist slaked lime or limestone. That is, for example, when only slaked lime or limestone is used as the treatment agent, it may not be able to absorb the moisture of the object to be treated (for example, in manure) and may become a muddy state. When slaked lime gets wet, the slaked lime itself may give off a unique malodor. Further, if the manure remains in a muddy state, the manure may come into contact with the air, and the fermentation and decomposition of the manure may proceed.
- the first bulk treatment agent of the present invention contains a water-absorbing polymer (polymer water-absorbing agent), it can absorb moisture in the object to be treated and solidify.
- a water-absorbing polymer polymer water-absorbing agent
- slaked lime or limestone and water-absorbing polymer are added to the object to be treated, the object to be treated solidifies, and the solidified object is covered with slaked lime or limestone to stop the fermentation and decomposition activities of microorganisms.
- the above-described effects can be obtained.
- the addition amount of slaked lime or limestone can be reduced, and the malodor which slaked lime or limestone itself emits can be reduced more.
- the water-absorbing polymer swells when it comes into contact with moisture, it serves as a base point for the collapse of the solidified treatment agent.
- the water-absorbing polymer used in the present invention is not particularly limited as long as it does not adversely affect the effects of the present invention, and known substances can be used. Specific examples thereof include, for example, starch-acrylonitrile graft polymer hydrolysates, starch-based water-absorbing polymers such as starch-acrylic acid graft polymers, cellulose-acrylonitrile graft polymers, cellulose-styrene sulfonic acid graft copolymers.
- Cellulose-based water-absorbing polymers such as polymers, polysaccharide-based water-absorbing polymers, protein-based water-absorbing polymers such as collagen, polyvinyl alcohol-based water-absorbing polymers such as polyvinyl alcohol-crosslinked polymers, crosslinked sodium polyacrylate, heavy acrylic acid Acrylic water-absorbing polymer such as sodium acrylate-vinyl alcohol copolymer, maleic anhydride water-absorbing polymer, vinyl pyrrolidone water-absorbing polymer, polyethylene glycol diac Polyether type water-absorbing polymer, such as rate crosslinked polymer and the like, and the like.
- These water-absorbing polymers may be used alone or in combination of two or more. These water-absorbing polymers may be synthesized or commercially available.
- Hymosub HS-960 manufactured by Hymo Co., Ltd.
- examples of commercially available products include, for example, Aquakeep (registered trademark) SA (manufactured by Sumitomo Seika Co., Ltd.), Aquaric (registered trademark) CA (manufactured by Nippon Shokubai Co., Ltd.), Sunfresh, Aquapearl (Sundia Polymer Co., Ltd.) And Hymosub HS-960 (manufactured by Hymo Co., Ltd.).
- these water-absorbing polymers Hymosub HS-960 (manufactured by Hymo Co., Ltd.) is more preferable (Example: Hymosub HS-960).
- the average particle diameter of the water-absorbing polymer contained in the first bulk treating agent of the present invention is not particularly limited, but is preferably 50 to 1000 ⁇ m, more preferably 80 to 850 ⁇ m, and further preferably 100 to 600 ⁇ m. It is.
- SA-50II or SA60-S is preferable, and SA60-S is preferable from the viewpoint of water absorption. From the viewpoint of cost, SA-50II is preferable.
- the shape of the water-absorbing polymer is not particularly limited, and examples thereof include a granular shape, a powder shape, a granular shape, and a pellet shape.
- the content of the water-absorbing polymer can be appropriately adjusted depending on the type and shape of the water-absorbing polymer and the amount of water contained in the object to be treated, but is about 1 to 90% by mass with respect to the total mass of the bulk treatment agent. It is preferably about 5 to 50% by mass or about 10 to 48% by mass. If it is this range, the effect of a water-absorbing polymer can be acquired significantly, an unreacted water-absorbing polymer does not remain, and it is advantageous in cost.
- the binder contained in the first block treatment agent of the present invention may be an organic binder described below or an inorganic binder such as baking soda.
- the binder contained in the first block treatment agent of the present invention is at least one selected from the group consisting of a cellulose binder, a polymer binder, and a starch binder.
- An organic binder is preferable, and in particular, the binder is preferably a cellulose binder.
- the first lump treatment agent of the present invention is characterized in that components such as slaked lime or limestone are solidified.
- the first block treatment agent of the present invention contains a water-absorbing polymer (water-absorbing agent) in addition to slaked lime or limestone.
- the water-absorbing polymer (water-absorbing agent) is cushion-like when solidified (at the time of compression). May be difficult to compress and compress.
- the first block treatment agent of the present invention contains a binder (binder), solidification, tableting, and granulation are facilitated.
- the 1st block treatment agent of this invention has sufficient intensity
- the binder contained in the first bulk treatment agent of the present invention may be synthesized by a conventionally known method or may be prepared by purchasing a commercial product.
- Commercially available products include Cerrosa K2, PH-102, TG-101, ST-02, TG-101 manufactured by Asahi Kasei Chemicals, PVPK-15, PVPK-30, PVPK-90 (polyvinylpyrrolidone) manufactured by Higuchi Trading Co., Ltd.
- KC flocs (W-50S, W-50, W-100 / 100G, W-200 / 200G, W-250, W-300G, W-400G) manufactured by Nippon Paper Chemicals are preferably used.
- Cellosa K2 manufactured by Asahi Kasei Chemicals and KC floc manufactured by Nippon Paper Chemicals, a cellulose-based chemical are preferable from the viewpoint of bonding strength and disintegration because they are fibrous.
- the present inventor has found that KC Flock manufactured by Nippon Paper Chemicals Co., Ltd. and Cerossa K2 manufactured by Asahi Kasei Chemicals Co., Ltd. are very excellent in terms of binding properties.
- Cerrosa K2 manufactured by Asahi Kasei Chemicals Co., Ltd. has a granular shape and fine particles, and thus has a high binding force and is extremely excellent in terms of smooth feed from the hopper of the tableting machine. Is heading.
- the average particle size of the binder contained in the first bulk treatment agent of the present invention is not particularly limited, but is preferably 1 ⁇ m to 100 ⁇ m, more preferably 5 ⁇ m to 70 ⁇ m, and further preferably 20 ⁇ m to 60 ⁇ m. .
- the binder content is about 1 to 80% by mass, about 5 to 70% by mass, about 8 to 65% by mass, or 20 to 60% by mass with respect to the total mass of the first bulk treatment agent of the present invention. Is about. Within such a range, the powdered slaked lime or limestone and the water-absorbing polymer are made into a lump, which is preferable from the viewpoint of the effect of preventing dust scattering during use. For example, when a cellulosic binder is used as the binder, if the amount of the binder increases, the following effects are obtained.
- the binder itself also has water absorption, exhibits a function of assisting the water-absorbing agent serving as a base point of disintegration, and increases the disintegration speed when it comes into contact with the workpiece.
- the cost can be kept low, and as the capacity is reduced, the area in contact with the object to be processed is increased and the reactivity is improved.
- the especially preferable form of the 1st block treatment agent of this invention contains an acidic solid substance.
- the 1st block treatment agent of this invention contains an acidic solid substance, the ammonia which can be generated from a to-be-processed object (for example, stool, urine) can be neutralized. Therefore, malodor can be further suppressed.
- a to-be-processed object for example, stool, urine
- the acidic solid material that can be used in the present invention is not particularly limited, but the temperature is ⁇ 10 to 60 ° C., preferably 0 to 50 ° C., and the pressure is 0.5 to 1.2 atm, preferably 1 atm. It is preferably an acidic substance that can exist in a solid form.
- the acidic solid substance any conventionally known substance such as an inorganic acid or a salt thereof, an organic acid or a salt thereof can be used.
- a liquid acid is employed as the acidic substance, it can be used by impregnating it with talc, cellulose or the like, but a solid acid (solid substance) is preferably used.
- the pH of the acidic solid substance is not particularly limited as long as it exhibits acidity, but is preferably less than 1.5 to 7 from the viewpoint of preventing corrosiveness when a human touches the skin. Is more preferable, and 3.5 to 5.5 is even more preferable.
- the pH described in the present specification means a value measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. If it has pH in such a range, it can neutralize with the basic component (for example, ammonia) etc. which are contained in a to-be-processed object (for example, excrement), and can suppress bad odor efficiently.
- a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation If it has pH in such a range, it can neutralize with the basic component (for example, ammonia) etc. which are contained in a to-be-processed object (for example, excrement), and can suppress bad odor efficiently.
- acidic solid substances that can be used in the present invention include acetic acid, citric acid (food additive pH: 2.36), isocitric acid, malic acid (food additive pH: 2.45), and tartaric acid.
- Food additive pH: 2.28 lactic acid, gluconic acid, succinic acid, glycolic acid, oxalic acid, maleic acid, maleic anhydride, itaconic acid, benzoic acid, hydroxybenzoic acid, nitrilotriacetic acid, carbonic acid, salicylic acid, It consists of fumaric acid, adipic acid, phthalic acid, terephthalic acid, inosinic acid, guanylic acid, glutamic acid, erythorbic acid, sorbic acid, polyglutamic acid, benzenesulfonic acid, toluenesulfonic acid, phytic acid, phosphoric acid, phosphonic acid and boric acid It may be an unneutralized acidic component (first component) (first component
- sodium dihydrogen phosphate (pH: 4.3 to 4.9), potassium dihydrogen phosphate (pH: 4.4 to 4.9), disodium dihydrogen pyrophosphate (pH: 3.8 to 4) .5), aluminum aluminum tripolyphosphate (pH: 2.4 to 2.8), monosodium fumarate (pH: 3.0 to 4.0), sodium ultraphosphate (pH: 1.7 to 1.9) ), Acidic sodium hexametaphosphate (pH: 3.8 to 4.5) or grass charcoal (peat) containing humic acid (humic acid) (pH: 3.0 to 6.8). This is particularly preferable from the viewpoint of not reducing the amount.
- an acidic solid component such as sodium dihydrogen phosphate
- the following effects are obtained. That is, when the ratio of slaked lime increases in the treatment agent, the alkali concentration increases, and there may be an environment where ammonia is likely to be generated. In such a case, a bad odor derived from ammonia may occur. Therefore, it is particularly preferable to include an acidic solid component such as sodium dihydrogen phosphate for neutralizing ammonia and maintaining the sterilizing ability of slaked lime. Further, the second component such as sodium dihydrogen phosphate is also preferable from the viewpoint that the water absorption capacity of the water absorbing polymer is not deteriorated so much.
- the acidic solid material is composed only of the first component
- the “salt portion” of the polyacrylate is consumed, which is preferable from the viewpoint of water absorption characteristics. There may not be.
- an acidic solid substance consists only of a 2nd component, it is preferable from a viewpoint of a water absorption characteristic.
- the effect of neutralizing ammonia in the object to be treated is also significantly high.
- the specific acidic solid substances listed above may be synthesized by appropriately referring to or combining conventionally known methods, or may be prepared by purchasing commercially available products.
- Commercially available products include Daimei Chemical's sulfate band, alum, Iwata Chemical's citric acid, malic acid, tartaric acid, lactic acid, itaconic acid, spicrispolic acid, and Tsuchino Food Industry's phytin.
- the amount of the acidic solid substance (if a plurality of types are used, the total mass of the plurality of types) is preferably 10 to 95% by mass, more preferably 13 to 50% by mass, based on the entire bulk treatment agent (100% by mass). More preferably, it is 14 to 30% by mass. If it is such a range, the efficiency which acts on components, such as ammonia which can be generated from a to-be-processed object, will go up, and the deodorizing function as a processing agent will improve significantly.
- the bulk treatment agent of the present invention contains slaked lime or limestone, a water-absorbing polymer, and a binder as essential components.
- the preferred content of these components is as described above. However, when an acidic solid substance is further included, the content of these components is reduced accordingly, so the preferred content of these components is as follows. It is preferable. However, it should be understood that the preferred ranges described below can be the preferred ranges of these “slaked lime or limestone, water-absorbing polymer, and binder” even if they do not contain acidic solid materials. .
- the slaked lime or limestone is preferably 5 to 50% by mass, more preferably 10 to 40% by mass, and further preferably about 15 to 30% by mass with respect to the total mass of the bulk treatment agent. In such a range, the effect of stopping the fermentation and decomposition activities of microorganisms is particularly remarkable.
- the water-absorbing polymer is preferably 5 to 50% by mass, more preferably 10 to 40% by mass, and further preferably about 20 to 35% by mass with respect to the total mass of the bulk treatment agent. Within such a range, the effect of absorbing water from manure and solidifying in a jelly form, preventing leakage from a plastic bag, which is a simple toilet, and preventing the diffusion of filth is particularly remarkable.
- the binder is preferably 5 to 50% by mass, more preferably 8 to 45% by mass, and further preferably about 10 to 40% by mass with respect to the total mass of the bulk treatment agent.
- the powdery slaked lime and the water-absorbing polymer are agglomerated, and the effect of preventing dust scattering during use is particularly remarkable.
- the size of the acidic solid substance is not particularly limited, but the average particle size is about 100 nm to 3 mm, more preferably about 0.01 to 1 mm. From the viewpoint of supporting the water-absorbing polymer. Of course, it may be out of these ranges depending on the type or in consideration of manufacturing convenience.
- the pH of the object to be treated treated with the first bulk treating agent of the present invention is preferably controlled to about 5 to 8, more preferably about 6 to 7. It is preferable. By controlling in this way, it becomes easy to control the malodor derived from a basic component (especially ammonia) especially.
- the control method include a method of adding an acidic solid substance exhibiting acidity to the first block treatment agent of the present invention.
- the other preferable form of the 1st block treatment agent of this invention contains an additive.
- the additive for the first bulk treating agent of the present invention is preferably at least one selected from the group consisting of zeolite, activated carbon, baking soda and lubricant.
- the amount of the additive is not particularly limited as long as it exhibits the initial effects of the present invention, but about 0.8 to 30% by mass, 0% with respect to the total mass of the first bulk treatment agent of the present invention. About 7 to 20% by mass, or about 0.5 to 18% by mass.
- the 1st block treatment agent of this invention is good to further contain the additive which is a zeolite.
- zeolite is a general term for minerals called zeolites, and about 40 kinds of natural zeolites have been discovered.
- the ammonia component contained in the to-be-processed object for example, manure
- the pores of the zeolite can take in malodor and suppress the malodor.
- the zeolite of the present invention may be natural or artificial, but is preferably artificial from the viewpoint of availability.
- the zeolite of the present invention is preferably a zeolite called mordenite in which very small cavities of about 5.5 to 8 mm, which are slightly larger than water and nitrogen molecules, are formed in a tunnel shape.
- Zeolite 2460, Zeolite 60, Zeolite CP, etc., manufactured by New Tohoku Chemical Co., Ltd. are preferable.
- zeolite 60 is preferable from the viewpoint of easy feeding to a tableting machine.
- the average particle size of the zeolite of the present invention is not particularly limited, but is preferably about 0.05 to 1.5 mm, and more preferably about 0.1 to 1.2 mm.
- the zeolite used in the present invention includes SiO 2 (silicon oxide), Al 2 O 3 (aluminum oxide), CaO (calcium oxide), Na 2 O (sodium oxide), K 2 O (potassium oxide), Fe 2 O. 3 (iron oxide), MgO (magnesium oxide), adhering water (H 2 O), bound water (H 2 O), and others are 70.5% by mass, 11.3% by mass, 2.6% by mass, respectively. , 1.6% by mass, 1.3% by mass, 0.7% by mass, 0.1% by mass, 8.0% by mass, 3.9% by mass, of course, but limited to this composition However, it is possible to use those prepared so that each component is about 0.1 to 20% and the total is 100%. In the present invention, for example, zeolite such as K [AlSi 2 O 6 ] may be used.
- the amount used in the case of using zeolite can be adjusted as appropriate depending on the type and shape of the zeolite and the components contained in the material to be treated (for example, excrement). More preferably, it is in the range of about 1 to 50% by mass, 1 to 30% by mass, or about 2 to 20% by mass. Within such a range, the effect of suppressing bad odor becomes higher, which is economical in terms of cost.
- Activated carbon is preferably added from the viewpoint of suppressing malodor that the slaked lime may emit. Activated carbon also has a function of suppressing bad odor generated during excrement treatment.
- the activated carbon used in the present invention is not particularly limited.
- Specific examples of the activated carbon include, for example, activated carbon obtained by a known method using, as raw materials, synthetic resin such as charcoal, coke, coconut husk, natural fiber, polyacrylonitrile, rayon, phenol resin, and the like. . These may be used alone or in combination of two or more.
- the activated carbon may be synthesized or a commercially available product may be used.
- activated carbon GY alkali use, activated carbon GX acidic use (above, Toyobo Co., Ltd. product), or these mixtures are mentioned, for example.
- slaked lime component and activated carbon component of the processing agent of this invention using the commercial item in which slaked lime and activated carbon are mixed previously, for example, Solvalit (made by Ube Materials Co., Ltd.).
- Solvalit made by Ube Materials Co., Ltd.
- sol barit is more preferable from the viewpoint of adsorption of malodorous substances.
- the shape of the activated carbon is not particularly limited, and examples thereof include granule, powder, granule, pellet, macaroni, fiber, and honeycomb.
- the amount of activated carbon used can be adjusted as appropriate depending on the type and shape of the activated carbon and the components contained in the object to be treated (for example, excrement), but is 0. 0% relative to the total mass of the treatment agent. About 1 to 20% by mass, about 0.4 to 15% by mass, or about 0.3 to 10% by mass. Within such a range, the effect of suppressing bad odor becomes higher, which is economical in terms of cost.
- Baking soda is a component that assists the alkaline components of slaked lime and limestone.
- the average particle size of sodium bicarbonate is not particularly limited.
- the amount used when baking soda is used can be appropriately adjusted depending on the type and shape of baking soda and the components contained in the object to be treated (for example, manure) so as to exert the effect of suppressing malodor.
- the lubricant that can be contained in the first bulk treatment agent of the present invention is used for smooth feeding to the die of the tableting machine, particularly when producing the first bulk treatment agent of the present invention.
- a conventionally well-known thing can be selected suitably, or can be used in combination.
- ester type such as sucrose fatty acid ester
- silicon type such as silicon dioxide, calcium stearate, potassium stearate and the like are used, and ester type, silicon type and calcium stearate are preferable.
- the content of the lubricant is preferably about 0.5 to 20% by mass, or about 0.8 to 17% by mass with respect to the total amount of the first bulk treatment agent of the present invention. Within such a range, the feed and disintegration of the raw material are enhanced.
- the treatment agent of the present invention may further contain other additives as long as they do not adversely affect the present invention.
- additives include a fragrance, a deodorant, or a deodorant from the viewpoint of odor countermeasures; a hydrophilic organic compound such as alcohol, or a surfactant; from the viewpoint of controlling the water content in manure, Desiccant such as silica gel and anhydrous sodium sulfate; from the viewpoint of sterilization and deodorization; chlorine-containing compounds such as sodium hypochlorite; from the viewpoint of complementing the alkaline conditions during the excrement treatment, from the group 1 elements such as sodium hydroxide A hydroxide etc. are mentioned.
- These additives may be used alone or in combination of two or more.
- fragrances examples include lemon oil, lemon grass, cinnamon oil, lavender oil, and vetiver.
- surfactants can be used as the surfactant, and specific examples thereof include, for example, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene monofatty acid ester, polyoxyethylene alkyl ester, Nonionic surfactants such as oxyethylene difatty acid ester, polyoxyethylene propylene glycol fatty acid ester, polyethylene sorbitan monofatty acid ester, glycerin monofatty acid ester; alkylbenzene sulfonate, alkyl sulfosuccinate, alkyl sulfate, polyoxyethylene alkyl sulfate , Anionic surfactants such as aryl sulfonates; long-chain primary amine salts, dialkyldimethylammonium salts, alkyltrimethylammonium salts, benzyl Trimethyl ammonium chloride, alkylpyridinium salts, benzalkonium chloride, cationic surfactants such as benze
- a wrapping bag made of a water-soluble resin, a wrapping bag made of water-soluble paper, or a wrapping bag made of a water-degradable nonwoven fabric which can be used when adding the treatment agent to manure, is also an additive for the treatment agent of the present invention. It can be contained as
- additives are about 0.1 to 10% by mass, or about 1 to 3% by mass with respect to the total amount of the first block treatment agent of the present invention.
- the 1st block treatment agent of this invention can be produced by mixing said composition and compressing so that it may become a desired magnitude
- the respective components may be mixed at a time, or the respective components may be mixed sequentially.
- the continuous tableting machine may or may not be a direct tableting machine, but it requires time for pretreatment (for example, granulation step; in the present invention, a dry process is preferred because a water-absorbing polymer is used). It is also preferable to adopt a direct hitting method that improves productivity in that it can be omitted.
- the slaked lime that can be used as the main component of the present invention has a small particle size, it is preferable to add a lubricant to make it easy to feed such fine powder.
- the present invention is made by tableting a mixture of a binder (binder) mixed with a granulated fine powder by applying a large pressure using a roller compactor.
- the first block treatment agent may be prepared.
- a tableting machine model AP18-SS, etc.
- the diameter of the mortar at this time is about 13 mm, and the number of uprights is about 18. If such a tableting machine is used, the raw materials are prepared in a desired ratio, mixed, the mixed raw materials are put into the hopper of the tableting machine, and the tableting machine is used for tableting in a rotary manner. Production is possible and preferable.
- the first block treatment agent of the present invention may be produced by a continuous rotary tableting machine. Specifically, each component (for example, slaked lime, activated carbon, water-absorbing polymer, binder, lubricant) is mixed to prepare a mixture, and the mixture is put into a hopper of a continuous tableting machine for tableting.
- the shape of the ridge may be, for example, an upper and lower circular plate type.
- the method for solidification for producing the first block treatment agent of the present invention there is no particular limitation on the method for solidification for producing the first block treatment agent of the present invention.
- tableting, roller compactor, and wet compression may be applied in an appropriate combination.
- the 1st block treatment agent of this invention contains a water absorptive polymer
- the mixture with additives such as a stage before mixing a water absorptive polymer, slaked lime, activated carbon, is wet-granulated, and then water absorption A method of mixing with a conductive polymer is also good.
- the shape of the ridge may be, for example, an upper and lower circular plate type.
- the application of the first block treatment agent of the present invention is not particularly limited. For example, it can be used to treat manure, organic sludge, animals and plants, livestock, livestock barns or soil.
- the first lump treatment agent of the present invention exhibits various effects when used as a manure treatment agent, an organic sludge treatment agent, an animal and plant treatment agent, a livestock treatment agent, a livestock treatment agent, or a soil treatment agent.
- the treatment agent of the present invention is solidified, so that dust is used when using the treatment agent. Therefore, the handleability is improved.
- manure treatment includes disaster toilets, traffic jam toilets (toilets used in the car during traffic jams), temporary toilets at construction sites, pet toilets (cat sand and dog toilets), and water washing overseas There are applications in areas without infrastructure.
- this excrement includes not only human excrement, but also animal excrement such as cattle excrement, pig excrement, chicken excrement, etc.
- the stool may be stool alone, urine alone, or a mixture of stool and urine. In the case of stool alone, it is preferable to contain a lot of water.
- the treatment of organic sludge can be suitably used for the treatment of contaminated rivers, food residues discharged from restaurants, vomit treatment of infectious patients, blood treatment, and the like.
- the treatment of animals, plants, livestock, livestock houses or soils is specifically applicable to the treatment of animals infected with infectious diseases such as foot-and-mouth disease and bird flu, livestock, their feed, livestock, livestock houses or soil. is there.
- infectious diseases such as foot-and-mouth disease and bird flu
- livestock, their feed, livestock, livestock houses or soil. for sterilization of foot-and-mouth disease and avian influenza, powdered slaked lime is usually used.
- the treatment agent of the present invention is solidified, animal and plant treatment agents, livestock treatment agents, livestock treatment agents or soil treatments are used.
- Use in disinfectants significantly reduces dust damage, improves handling (handling), does not degrade reactivity, and uses disinfectants, disinfectants, sterilants, and deodorants Can also be used.
- slaked lime, limestone, and the like used for disinfection also have granularity, but are generally used in powder form because of poor reactivity.
- particles are formed by mixing a water-absorbing polymer (polymer water-absorbing agent) and solidified, and the polymer water-absorbing agent serves as a base point for disintegration due to swelling when in contact with moisture. . Therefore, the reactivity does not decrease even in the case of a lump (in other words, while having the same degree of reactivity as powder), handling becomes very good, and the reactivity does not decrease because it breaks into powder. It is very suitable for foot-and-mouth disease and avian influenza disinfection. In addition, collection is facilitated.
- the second of the present invention is a granular processing agent obtained by pulverizing the first massive processing agent of the present invention.
- a granular treatment agent in the case of a granular treatment agent, it is not necessary to maintain the solid state for a long time as in the case of a bulk treatment agent, so that the unit weight of the bulk treatment agent can be reduced from the viewpoint that the amount of binder can be reduced.
- the ratio of the active ingredient per hit can be increased.
- the 2nd granular processing agent of this invention consists of grind
- the second granular processing agent of the present invention is different from a conventional powdery processing agent in terms of constitution (presence or absence of binder).
- the method for pulverizing the first block treatment agent of the present invention is not particularly limited, and can be performed, for example, by using a conventionally known atomization apparatus.
- the finer that can be used is classified into a shear crusher, an impact crusher, and a high-speed rotary crusher, and preferably has one or more of crushing mechanisms such as cutting, shearing, impact, and friction.
- a sizing machine at Hata Iron Works or a table mill at Okada Seiko can be used. Of course, other devices may be used. Alternatively, it may be crushed with a hammer or the like.
- the average particle diameter of the second granular treatment agent of the present invention is preferably more than 150 ⁇ m to less than 3 mm, more preferably about 0.05 to 2 mm, and still more preferably about 0.1 to 1 mm per one grain. It is. Within such a range, the handling area is improved, the contact area with the object to be processed is increased, and the reaction efficiency with the object to be processed can be improved.
- the second granular treatment agent of the present invention can reduce the amount of the binder as compared with the first bulk treatment agent of the present invention.
- the standard of the amount of the binder is preferably 10% reduction, more preferably 30% reduction, and further preferably 50% reduction to 70% reduction in the case of the first bulk treatment agent of the present invention. What is necessary is just to increase the quantity of slaked lime or limestone, a binder, an acidic solid substance, an additive, etc. in the part which could be reduced, and to make the whole 100 mass%.
- 3rd of this invention is a toilet bowl by which the 1st block treatment agent of this invention or the 2nd granule treatment agent of this invention is arrange
- the third toilet of the present invention is very preferable from the viewpoint of handleability when the first block treatment agent of the present invention is included. Of course, it is also preferable that the third toilet of the present invention contains the second granular processing agent of the present invention, and in this case, there is an effect of increasing the surface area and improving the reactivity.
- the usage-amount of a 1st block treatment agent is 100 mass parts of to-be-processed objects (for example, excrement).
- the range is preferably 10 to 200 parts by mass, more preferably 20 to 100 parts by mass, and still more preferably 30 to 60 parts by mass.
- the amount of the treatment agent used is less than 10 parts by mass, the contact area between the excreta and slaked lime is reduced, so that the excrement may come into contact with the air and the fermentation and decomposition of the excrement may proceed.
- it exceeds 100 mass parts the residue after a process increases and the waste after a process may increase. In addition, the cost may increase.
- the first lump treatment agent of the present invention or the second granular treatment agent of the present invention is disposed in advance in the third toilet of the present invention, it is preferably disposed in an amount within the above range.
- the third toilet of the present invention includes, for example, a sheet having a surface subjected to water-repellent treatment or a bag having an inner surface subjected to water-repellent treatment, etc. It is preferable to arrange one lump treatment agent or the second granular treatment agent of the present invention, and by adding feces and urine to the lump treatment agent, it becomes very easy even when discarded.
- feces and urine odors are roughly classified into fecal odors and ammonia odors.
- Fecal odor is an organic odor
- ammonia odor is an inorganic odor.
- the ammonia odor is an inorganic odor, and is an odor that hardly diffuses after excretion if a sheet whose surface is water-repellent is bound.
- stool odor tends to leak and diffuse even if the plastic bag is tied up because the gas is generated from the specimen itself, so that the internal pressure in the sheet (for example, plastic bag) whose surface is water repellent is increased.
- manure treatment agents have a low deodorizing effect, and it has been difficult to suppress manure odor (particularly fecal odor).
- the first bulk treatment agent of the present invention the second granular treatment agent of the present invention, and the third toilet of the present invention, which does not require an operation such as stirring, and is simple and Since it is possible to treat urine etc. efficiently and sterilize etc., it is possible to suppress the generation of bad odor and gas, for example, the toilet situation in the disaster area can be remarkably improved, It is very suitable in terms of hygiene.
- the first block treatment agent of the present invention since the first block treatment agent of the present invention is solidified, it can be laid in advance in a portable toilet or the like, and urine or defecation can be performed from there. Then, dust such as slaked lime does not rise with the momentum of urination or defecation. Then, since the slaked lime which is a strong alkali having corrosiveness contained therein does not rise, it is preferable from the viewpoint of health without scattering to delicate parts of the human body.
- the 1st block treatment agent of this invention or the 2nd granule treatment agent of this invention is previously arrange
- the toilet bowl of the present invention is preliminarily provided with a treatment agent, after excretion, the user does not need to check his / her own (or care recipient, etc.) feces and urine, and the user can use it comfortably. Can do.
- the treatment agent after the treatment agent is excreted, it is necessary to sprinkle the treatment agent on manure (or a caregiver or the like), and the user (or caregiver or the like) may become uncomfortable. there were.
- the treatment agent is arranged in advance, there is an effect that it is sufficient to discard the toilet bowl as it is without needing confirmation after excretion.
- ⁇ Fourth aspect of the present invention> 4th of this invention is an absorbent article formed by including the 1st block treatment agent of this invention, or the 2nd granule treatment agent of this invention.
- the absorbent article according to the fourth aspect of the present invention is the above-described first bulk treatment agent of the present invention or the second granular treatment agent of the present invention, a liquid-permeable top sheet, and a liquid-impermeable back surface. It is preferable to provide a sheet.
- the manufacturing method of the absorbent article concerning this invention is not specifically limited,
- the 1st block treatment agent of this invention or the 2nd granular treatment agent of this invention is liquid-permeable base material (surface Sheet) and a liquid-impermeable base material (back sheet) and, if necessary, equipped with an elastic member, a diffusion layer, an adhesive tape, etc., absorbent articles such as adult paper diapers, A sanitary napkin may be used.
- the first bulk treatment agent of the present invention or the second granular treatment agent of the present invention can impart a deodorizing function to an absorbent article and exhibits excellent deodorizing performance and absorption characteristics over a long period of time. .
- absorbent articles include adult paper diapers that have grown significantly in recent years, hygiene materials such as diapers for children, sanitary napkins, so-called incontinence pads, and the like, and are particularly limited thereto. It is not a thing.
- the first lump treatment agent of the present invention or the second granular treatment agent of the present invention present in the absorbent article has a very excellent deodorizing property and has a remarkable dry feeling. This can greatly reduce the burden on the person and the caregiver.
- the amount of the first bulk treatment agent of the present invention or the second granular treatment agent of the present invention contained in the absorbent article may be appropriately adjusted according to the use. It is preferable to add 5 to 50 g, or 10 to 30 g.
- Example 1 Place 0.8 g of the drug substance and 0.2 g of KC Flock (registered trademark), which is a cellulose binder, into the mortar of a tabletop tableting machine (manufactured by Kikusui Seisakusho Co., Ltd.) and apply 40 kN of pressure. Tablets (average diameter: 15 mm, average thickness: 5 mm) were obtained. The scissors used were upper and lower planographic types having a diameter of 15 mm.
- KC Flock registered trademark
- Solvalite (slaked lime containing 10% by weight of activated carbon, manufactured by Ube Materials Co., Ltd.) 80 parts by weight, and water-absorbing polymer (also referred to as “water absorbent”) (product name: Hymosub HS-960 (manufactured by Hymo Co., Ltd.))
- water absorbent also referred to as “water absorbent”
- the mixture consisting of 20 parts by weight is referred to as “the drug substance”. The same applies hereinafter.
- the obtained tablet of the treatment agent was capable of forming a complete molded product, and had a strength that did not collapse even after one month and did not collapse even when pressed by hand.
- the handleability was very good.
- Example 2 (Ref: B-5) Treating agent tablets (average diameter: 15 mm, average thickness: 5 mm) as in Example 1 except that the amount of the drug substance is 0.9 g and the amount of KC Flock (registered trademark) is 0.1 g. )
- the obtained tablet of the treatment agent was a molded product with some corners missing, but had a strength that did not collapse even after one month and did not collapse even by hand. The handleability was very good.
- Example 3 (Ref: B-8) 0.8 g of the drug substance was prepared, and solidified under pressure using a roller compactor (manufactured by Turbo Kogyo Co., Ltd.) to obtain a granular mixture.
- This granular mixture and 0.2 g of KC Flock (registered trademark) as a binder are put into a mortar of a tabletop tableting machine (manufactured by Kikusui Seisakusho Co., Ltd.). Average diameter: 15 mm, average thickness: 5 mm).
- the scissors used were upper and lower planographic types having a diameter of 15 mm.
- the obtained tablet of the treatment agent was able to form a complete molded body, and had a strength that did not collapse even after one month and did not collapse even by hand.
- the handleability was very good.
- Example 4 (Ref: B-9) 0.8 g of the drug substance was prepared and solidified under pressure using a tabletop tableting machine (manufactured by Kikusui Seisakusho Co., Ltd.) to obtain a granular material.
- This granular product is pulverized into a powder using a mortar and pestle, and the obtained powdery drug substance and 0.2 g of KC Flock (registered trademark) as a binder are used as a tabletting tablet machine (Kikusui Seisakusho Co., Ltd.).
- KC Flock registered trademark
- KC Flock registered trademark
- the obtained tablet of the treatment agent was able to form a complete molded body, and had a strength that did not collapse even after one month and did not collapse even by hand.
- the handleability was very good.
- Example 5 (Ref: C-2) Solvalit (slaked lime containing 10% by weight of activated carbon, manufactured by Ube Materials Co., Ltd.) 0.3 g, water absorbent (Himosub HS-960) 0.3 g, KC Flock (registered trademark) 0.65 g as a binder, lubricant Ester and silicon (sucrose fatty acid ester DK ester manufacturer name: Daiichi Kogyo Seiyaku Co., Ltd.
- the obtained tablet of the treatment agent was able to form a complete molded body, and had a strength that did not collapse even after one month and did not collapse even by hand.
- the handleability was very good.
- Example 6 (Ref: C-3) Solvalite (slaked lime containing 5% by weight of activated carbon, made by Ube Materials Co., Ltd.) 0.5g, water absorbent (Himosub HS-960) 0.3g, KC Flock (registered trademark) 0.4g as binder Were the same as in Example 5 to obtain tablets of the treatment agent (average diameter: 15 mm, average thickness: 5 mm).
- the obtained tablet of the treatment agent was able to form a complete molded body, and had a strength that did not collapse even after one month and did not collapse even by hand.
- the handleability was very good.
- Comparative Example 1 (Ref: A-1) 0.5 g of the drug substance was placed in a mortar of a tabletop tableting machine (manufactured by Kikusui Seisakusho Co., Ltd.) and tableted by applying a pressure of 2 kN to obtain a treating agent tablet.
- the scissors used were upper and lower planographic types having a diameter of 15 mm.
- the obtained tablet of the treatment agent was a molded product with some corners missing, but completely disintegrated after several days.
- Comparative Example 2 (Ref: A-2) A treating agent tablet was obtained in the same manner as in Comparative Example 1 except that the pressure was 4 kN.
- the tablet of the obtained treatment agent had a shape as a molded body immediately after molding, but it collapsed after 20 days.
- Comparative Example 3 (Ref: B-1) 1.0 g of the drug substance was placed in a mortar of a tabletop tableting machine (manufactured by Kikusui Seisakusho Co., Ltd.) and tableted by applying a pressure of 20 kN to obtain a tablet as a treatment agent.
- the scissors used were upper and lower planographic types having a diameter of 15 mm.
- the resulting treatment tablet disintegrated immediately after molding.
- Comparative Example 4 (Ref: B-2) A treating agent tablet was obtained in the same manner as in Comparative Example 1, except that the pressure was 40 kN.
- the resulting treatment tablet disintegrated immediately after molding.
- the urine odor (mainly ammonia) was evaluated using an ammonia gas detector tube (Kitakawa type) (manufactured by Komyo Chemical Co., Ltd.).
- Example 7 (Ref: Experiment No. 2) 50 g of the treatment agent obtained in Example 5 was placed in a container (plastic bag) -like toilet pack in which the inner surface receiving feces and urine has water repellency. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added. There was almost no odor when 30 minutes passed after contact (odor level: 0), and there was almost no odor even after 2 weeks (odor level: 0).
- Example 8 (Ref: Experiment No. 3) 100 g of the treatment agent obtained in Example 5 was placed in a container (plastic bag) -like toilet pack in which the inner surface receiving feces and urine has water repellency. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added. There was almost no odor when 30 minutes passed after contact (odor level: 0), and there was almost no odor even after 2 weeks (odor level: 0).
- Example 9 (Ref: Experiment No. 4) The treatment was performed in the same manner as in Example 8 except that the treatment agent was changed to 75 g. There was almost no odor when 30 minutes passed after contact (odor level: 0), and there was almost no odor even after 2 weeks (odor level: 0).
- Example 10 (Ref: C) A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g.
- 50 tablets of the bulk treatment agent were prepared by tableting 50 g of this mixture with a tableting machine (HS series) of Fuji Pharmaceutical Co., Ltd., using a 15 mm diameter punch and mortar at a main pressure of 1.5 kN and 30 rpm. (1 g of 1 grain, average diameter: 15 mm, average thickness: 6 mm). The handleability was very good.
- the hardness of the block treatment agent was 12 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.
- Example 10 50 g of the treatment agent obtained in Example 10 was placed in a container (plastic bag) -like toilet pack in which the inner surface receiving manure has water repellency. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added. There was almost no odor when 30 minutes passed after the treatment (odor level: 0).
- a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. The result was 360 ppm. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).
- the particle size distribution of Aqua Keep SA50-II is as follows.
- Example 11 (Ref: T1) A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g.
- 50 tablets of the bulk treatment agent were prepared by tableting 50 g of this mixture with a tableting machine (HS series) of Fuji Pharmaceutical Co., Ltd., using a 15 mm diameter punch and mortar at a main pressure of 1.5 kN and 30 rpm. (1 g of 1 grain, average diameter: 15 mm, average thickness: 6 mm). The feed from the hopper could be done smoothly. Moreover, the handleability was very excellent.
- the hardness of the block treatment agent was 12 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.
- Example 11 50 g of the treatment agent obtained in Example 11 was placed in a container (plastic bag) -like toilet pack in which the inner surface receiving manure was water-repellent. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added.
- the pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).
- Example 12 (Ref: Experiment (6) -1) A mixture was prepared by mixing the components shown in the table below at a mixing ratio shown in the table below (total 100% by mass) so as to be 45 g. 45 g of this mixture were tableted with a HT-AP18SS-II continuous tableting machine manufactured by Hata Iron Works Co., Ltd., using a 13 mm diameter pestle and mortar and 30 rpm at a main pressure of 1.5 kN. (1 g of 1 grain, average diameter: 13 mm, average thickness: 6 mm). The feed from the hopper could be done smoothly. Moreover, the handleability was very excellent. The hardness of the block treatment agent was 12 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.
- Example 12 45 g of the treatment agent obtained in Example 12 was placed in a container (plastic bag) -like toilet pack in which the inner surface receiving manure was water-repellent. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added.
- odor level: 0 After the treatment, there was almost no odor when 30 minutes passed (odor level: 0).
- a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0.2 ppm.
- the pH of the treated product 24 hours after the treatment was 6.8.
- the pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).
- Example 13 (Ref: Experiment (7) -1) A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g.
- a mixing ratio shown in the following table total 100% by mass
- Example 13 50 g of the treatment agent obtained in Example 13 was placed in a container (plastic bag) -like toilet pack in which the inner surface receiving manure was water-repellent. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added.
- odor level: 0 After the treatment, there was almost no odor when 30 minutes passed (odor level: 0).
- a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0.1 ppm.
- the pH of the treated product 24 hours after the treatment was 6.8.
- the pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).
- Example 14 (Ref: Experiment (7) -2) A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g. 67 tablets of the lump treatment agent were obtained by tableting 50 g of this mixture with a HT-AP18SS-II continuous tableting machine manufactured by Hata Iron Works Co., Ltd., using a ⁇ 13 mm punch and mortar at 20 rpm with a main pressure of 5.58 kN. (About 0.75 g per grain, average diameter: 13 mm, average thickness: 5 mm). The feed from the hopper could be done smoothly. Moreover, the handleability was very excellent. The hardness of the block treatment agent was 12 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.
- Example 14 50 g of the treatment agent obtained in Example 14 was placed in a container (plastic bag) -like toilet pack in which the inner surface receiving manure was water-repellent. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added.
- odor level: 0 After the treatment, there was almost no odor when 30 minutes passed (odor level: 0).
- a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0.1 ppm.
- the pH of the treated product after 24 hours from the treatment was 6.82.
- the pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).
- Example 15 (Ref: Experiment (7) -6) A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g.
- a mixing ratio shown in the following table total 100% by mass
- Example 15 50 g of the treatment agent obtained in Example 15 was placed in a toilet pack in the form of a container (plastic bag) whose inner surface receiving manure has water repellency. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added.
- odor level: 0 After the treatment, there was almost no odor when 30 minutes passed (odor level: 0).
- a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0.5 ppm.
- the pH of the treated product that passed 24 hours after the treatment was 6.91.
- the pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).
- Example 16 (Ref: Experiment (7) -7) A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g.
- a mixing ratio shown in the following table total 100% by mass
- the hardness of the block treatment agent was 12 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.
- Example 16 50 g of the treatment agent obtained in Example 16 was placed in a toilet pack in the form of a container (plastic bag) whose inner surface receiving manure has water repellency. 50 g of urine was added on the arranged treatment agent, and then 200 g of stool was added.
- odor level: 0 After the treatment, there was almost no odor when 30 minutes passed (odor level: 0).
- a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0.5 ppm.
- the pH of the treated product after 24 hours from the treatment was 6.95.
- the pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).
- Example 17 (Ref: FJG-A) A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) to 38.5 g. 39 tablets of the bulk treatment agent were obtained by tableting 38.5 g of this mixture with a HT-AP18SS-II continuous tableting machine manufactured by Hata Iron Works Co., Ltd. using a ⁇ 13 mm scissors and mortar at 40 rpm with a main pressure of 10 kN. (About 1 g per grain, average diameter: 13 mm, average thickness: 7 mm). The feed from the hopper could be done smoothly. Moreover, the handleability was very excellent. The hardness of the block treatment agent was 7 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.
- 38.5 g of the treatment agent obtained in Example 17 was pulverized by hand with this lump treatment agent, and 150 ⁇ m or less was selected with a sieve to produce a granular treatment agent of more than 150 ⁇ m.
- 50 g of urine is added to a container (plastic bag) -like toilet pack whose inner surface that receives excreta has water repellency, 200 g of stool is then added, and 38.5 g of crushed treatment agent is added to 200 g of stool. Sprinkled.
- odor level: 0 After the treatment, there was almost no odor when 30 minutes passed (odor level: 0).
- a plastic bag of a processed product that had been processed for 24 hours was tied and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0 ppm (that is, below the detection limit).
- the pH of the treated product after 24 hours from the treatment was 6.61.
- the pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation. Thereafter, the plastic bag was opened and left for 2 weeks. The odor was confirmed after standing for 2 weeks, but there was almost no odor (odor level: 0).
- Example 18 A mixture was prepared by mixing the components shown in the table below at a mixing ratio shown in the table below (total 100% by mass) so as to be 45 g.
- 45 g of this mixture was tableted with a HT-AP18SS-II continuous tableting machine manufactured by Hata Iron Works Co., Ltd. using a ⁇ 13 mm scissors and mortar at a main pressure of 1.5 kN and 30 rpm, to obtain 45 bulk treatment agents.
- the hardness of the block treatment agent was 12 kgf. The hardness at this time was measured with a tablet breaking strength measuring instrument (hardness meter) TH-203MP.
- Example 18 45 g of the treatment agent obtained in Example 18 was placed in a container (plastic bag) -like toilet pack in which the inner surface that receives excreta has water repellency. 500 g of urine was added on the arranged treatment agent.
- the treated plastic bag was tied up for 24 hours and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and the gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0 ppm.
- the pH of the treated product 24 hours after the treatment was 6.6.
- the pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation.
- Example 19 A mixture was prepared by mixing the components shown in the following table at a mixing ratio shown in the following table (total 100% by mass) so as to be 50 g.
- a mixing ratio shown in the following table total 100% by mass
- Example 19 50 g of the treatment agent obtained in Example 19 was placed in a container (plastic bag) -like toilet pack in which the inner surface receiving manure was water-repellent. 500 g of urine was added on the arranged treatment agent.
- the treated plastic bag was tied up for 24 hours and left for 1 hour, then a small hole was made in the plastic bag, a detector tube was inserted, and the gas was measured with a gas detector tube for measuring ammonia. As a result, it was 0 ppm.
- the pH of the treated product after 24 hours from the treatment was 6.62.
- the pH of the present invention was measured using a PH recorder SD card recording system model number PH-SD manufactured by Sato Corporation.
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- Treatment Of Sludge (AREA)
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Abstract
Description
(1)塊状処理剤
本発明の第1は、消石灰または石灰石と、吸水性ポリマーと、バインダと、を含む、塊状処理剤である。上記のように、本発明の処理剤は、バインダを含むことによって固形化されてなるため、取り扱い性に優れる。なお、本発明の第1の塊状処理剤を構成する成分は、バインダによって相互に結着した状態で存在する。
本発明の第1の塊状処理剤に含まれうる消石灰(Ca(OH)2)は、強アルカリであるため、糞尿処理の際(特に大便)の殺菌効果が大きい。また、***や鳥インフルエンザなどに感染した動物や家畜あるいはその死骸、その動物や家畜が食べていた餌(植物など)、その動物や家畜が存在していた、または、存在している家畜舎、あるいは、その家畜舎付近の土壌や道路などを、殺菌、滅菌、消毒、消臭することなどに効果がある。これにより、有機物の発酵・分解が止まる。すると、殺菌、滅菌、消毒される。そして、臭気を低減させる効果を得ることができる。また、消石灰は、主に硫化物を吸着するため、この点からも消石灰を使用することによる臭気の低減効果が大きいと言える。
本発明の第1の塊状処理剤に含まれうる、石灰石(炭酸カルシウム)は、組成式CaCO3で表されるカルシウムの炭酸塩である。石灰石は、アルカリ性であるため、消石灰と同様の効果がある。
本発明の第1の塊状処理剤に含まれる吸水性ポリマー(吸水剤)は、消石灰または石灰石を補助する役割をする。つまり、例えば、処理剤として、消石灰または石灰石だけを用いた場合、被処理物(例えば糞尿中)の水分を吸収しきれず泥状となる場合がある。消石灰が湿ると、消石灰自身が独特の悪臭を放つ場合がある。また、糞尿が泥状のままであれば、糞尿が空気に触れ、糞尿の発酵・分解が進む虞がある。
本発明の第1の塊状処理剤に含まれるバインダは、下記で説明する有機系バインダであっても、重曹などの無機系バインダであってもよい。しかし、結着性を鑑みると、好ましくは、本発明の第1の塊状処理剤に含まれるバインダは、セルロース系バインダ、高分子系バインダおよびでんぷん系バインダからなる群から選択される少なくとも1種の有機系バインダであることが好ましく、特には、前記バインダが、セルロース系バインダであると好ましい。
本発明の第1の塊状処理剤の特に好ましい形態は、酸性固形物質を含む。本発明の第1の塊状処理剤が、酸性固形物質を含むことによって、被処理物(例えば、大便、小便)から発生しうるアンモニアを中和させることができる。よって、悪臭をさらに抑制することができる。上記でも述べたが、酸性固形物質を入れる際も相互に結着した状態で存在することになる。
本発明の第1の塊状処理剤の他の好ましい形態は、添加剤を含む。本発明の第1の塊状処理剤の添加剤としては、ゼオライト、活性炭、重曹および潤滑剤からなる群から選択される少なくとも1種であることが好ましい。
本発明の第1の塊状処理剤は、ゼオライトである添加剤をさらに含むとよい。「ゼオライト」とは沸石類と呼ばれる鉱物の総称で、天然のゼオライトは約40種類発見されている。ゼオライトが含まれると、被処理物(例えば、糞尿)に含まれるアンモニア成分を吸着し、消臭、脱臭に効果がある。ゼオライトを含むことによって、ゼオライトの細孔が、悪臭を取り込んで、悪臭を抑制することができる。
活性炭は、上記の消石灰が放つことがある悪臭を抑制する観点から添加されると好ましい。また、活性炭は、糞尿処理中に発生する悪臭を抑制する働きをも有する。
重曹(炭酸水素ナトリウム)は、消石灰や石灰石のアルカリ成分の補助を行う成分である。
本発明の第1の塊状処理剤に含まれうる潤滑剤は、本発明の第1の塊状処理剤を作製する際に、特に、打錠機の臼へのフィードをスムーズになるために用いられるものである。潤滑剤の種類としては、従来公知のものを適宜選択して、あるいは、組み合わせて使用することができる。例えば、ショ糖脂肪酸エステルなどのエステル系、二酸化ケイ素などのケイ素系、ステアリン酸カルシウム、ステアリン酸カリウムなどが使われ、エステル系、ケイ素系、ステアリン酸カルシウムが好ましい。潤滑剤の含有量は、本発明の第1の塊状処理剤の総量に対して、0.5~20質量%程度、あるいは、0.8~17質量%程度であることが好ましい。かかる範囲であると、原料のフィード、崩壊性を高める。
本発明の処理剤は、本発明において悪影響を及ぼさない限り、その他の添加剤をさらに含有していてもよい。かかる添加剤の例としては、臭気対策の観点から、香料、消臭剤、または脱臭剤;アルコール等の親水性有機化合物、または界面活性剤;糞尿中の水分含有量を制御するという観点から、シリカゲル、無水硫酸ナトリウム等の乾燥剤;殺菌・脱臭の観点から、次亜塩素酸ナトリウム等の塩素含有化合物;糞尿処理時のアルカリ性条件を補完する観点から、水酸化ナトリウム等の第1族元素の水酸化物等が挙げられる。これらの添加剤は、単独で使用してもよいし2種以上を組み合わせて使用してもよい。
本発明の第1の塊状処理剤は、上記の組成を、混合し、所望の大きさあるいは重量になるように、圧縮することによって、作製することができる。この際、混合する方法は、各成分を一度に混合してもよいし、各成分を順次混合してもよい。
卓上式手動の打錠機(杵と臼はそれぞれ一つ)で固化するために、まず、杵には、固化をする各成分を手でスプーンにて入れる。この際、フィードの難しさは考える必要はない。その後、手動(油圧)にてレバーを下して圧力をかけて、各成分を固化させることによって、第1の塊状処理剤を作製する。なお、卓上式手動の打錠機の利点は、かなりの時間、滞留させて圧力をかけるので固まりにくい組み合わせであっても固化できるというところである。なお、例えば口径の小さい杵(直径7mm:上下円版型)を用いた場合、口径が小さい方が面積当たりにより高い圧力がかかるので固化しにくいものでも固まる傾向がある。一方で、例えば口径の大きい杵(直径15mm:上下平版型)を用いる場合、口径が大きい方が面積当たりに小さい圧力になるので固化しにくいものには不利になるが、口径の大きい分、杵へのフィードは有利になり、生産性は向上する。
また、連続式の打錠機は、直打式であってもなくてもよいが、前処理の手間(例えば、造粒工程;本発明では、吸水性ポリマーが使用されるため乾式が好ましい)を省くことができるという点で生産性が向上する直打式を採用することも好ましい。ただ、本発明の主成分として用いられうる消石灰は、その粒子径が小さいため、そのような微粉のものをフィードしやすくするために潤沢剤を入れることが好ましい。一方で、前処理を行う場合は、例えば、ローラーコンパクターを用いて大きな圧力をかけて圧延して微粉を造粒したものにバインダ(結合剤)を混合したものを打錠することによって、本発明の第1の塊状処理剤を作製してもよい。大量生産を鑑みると、例えば、株式会社畑鐵工所製の打錠機(型式AP18-SSなど)を使用することが好ましい。この際の杵臼の直径は、13mm程度であり、杵立数は、18本程度である。かかる打錠機を使用すれば、原料を所望の割合となるように調製し、混合し、打錠機のホッパーに混合した原料を入れ、打錠機で回転式に打錠をしていくだけで生産が可能であり、好ましい。
本発明の第1の塊状処理剤の用途は特に制限されない。例えば、糞尿、有機性汚泥、動植物、家畜、家畜舎または土壌の処理に用いられうる。本発明の第1の塊状処理剤が、糞尿処理剤、有機性汚泥処理剤、動植物処理剤、家畜処理剤、家畜舎処理剤または土壌処理剤として使用されることによって、様々な効果を奏する。具体的には、本発明の第1の塊状処理剤が、糞尿処理剤に含まれることによって、本発明の処理剤は、固形化されているため、処理剤を使用する際に、粉塵が舞わないため、取り扱い性が向上する。具体的には、糞尿の処理は、災害用トイレ、渋滞用トイレ(渋滞時に車内で使用するトイレ)、工事現場等の仮設トイレ、ペット用トイレ(猫砂や犬のトイレ)、海外での水洗インフラのない地域での応用などがある。なお、本発明の第1の塊状処理剤が、糞尿処理に用いられる場合、かかる糞尿は、人糞尿のみならず、例えば、牛糞尿、豚糞尿、鶏糞尿等の畜糞尿等も包含する。また、前記糞尿は、大便単独でもよいし、小便単独でもよいし、大便と小便との混合物であってもよい。大便単独の場合、水分を多く含むことが好ましい。また、有機性汚泥の処理は、汚染された河川の処理、外食店舗から排出される食品残さ、感染症患者の嘔吐物の処理、血液の処理等の用途に好適に用いられうる。
本発明の第2は、本発明の第1の塊状処理剤を粉砕することによってなる、顆粒状処理剤である。本発明の第2のように、顆粒状処理剤であると、塊状処理剤のように固形状態を長持間保つ必要がないのでバインダの量を少なくできるとの観点で、塊状処理剤の単位重量当たりの有効成分の割合を高めることができる。
本発明の第3は、本発明の第1の塊状処理剤または本発明の第2の顆粒状処理剤が予め配置されてなる、便器である。本発明の第3の便器は、本発明の第1の塊状処理剤や本発明の第2の顆粒状処理剤を含んでいるので、本発明の第1の塊状処理剤、本発明の第2の顆粒状処理剤の効果を有する。ここで、特には、本発明の第3の便器は、本発明の第1の塊状処理剤が含まれると、取り扱い性の観点から非常に好ましい。無論、本発明の第3の便器が、本発明の第2の顆粒状処理剤を含むことも好ましく、その際は、表面積が大きくなり反応性のより良くなる効果がある。
本発明の第4は、本発明の第1の塊状処理剤または本発明の第2の顆粒状処理剤を含んで成形されてなる、吸収性物品である。本発明の第4にかかる吸収性物品は、上記した本発明の第1の塊状処理剤または本発明の第2の顆粒状処理剤、液透過性を有する表面シート、液不透過性を有する背面シートを備えると好ましい。
原薬剤 0.8g、およびバインダとして、セルロース系のバインダであるKCフロック(登録商標)0.2gを、卓上打錠機(株式会社菊水製作所製)の臼に入れ、40kNの圧力をかけて打錠し、処理剤の錠剤(平均直径:15mm、平均厚さ:5mm)を得た。なお、使用した杵は、直径15mmの上下平版型であった。なお、ゾルバリット(活性炭を10重量%含む消石灰、宇部マテリアルズ株式会社製)80重量部、および、吸水性ポリマー(「吸水剤」とも称する)(品名:ハイモサブ HS-960(ハイモ株式会社製))20重量部からなる混合物を、「原薬剤」と称する。以下、同じである。
原薬剤の量を0.9gとし、KCフロック(登録商標)の量を0.1gとしたこと以外は、実施例1と同様にして処理剤の錠剤(平均直径:15mm、平均厚さ:5mm)を得た。
原薬剤 0.8gを準備し、ローラーコンパクター(ターボ工業株式会社製)を用いて、加圧固化し、粒状の混合物を得た。この粒状の混合物と、バインダとしてKCフロック(登録商標)0.2gとを卓上打錠機(株式会社菊水製作所製)の臼に入れ、40kNの圧力をかけて打錠し、処理剤の錠剤(平均直径:15mm、平均厚さ:5mm)を得た。なお、使用した杵は、直径15mmの上下平版型であった。
原薬剤 0.8gを準備し、卓上打錠機(株式会社菊水製作所製)を用いて、加圧固化し、粒状物を得た。この粒状物を、乳鉢および乳棒を用いて粉状に粉砕し、得られた原薬剤の粉状物と、バインダとしてKCフロック(登録商標)0.2gとを卓上打錠機(株式会社菊水製作所製)の臼に入れ、40kNの圧力をかけて打錠し、処理剤の錠剤(平均直径:15mm、平均厚さ:5mm)を得た。なお、使用した杵は、直径15mmの上下平版型であった。
ゾルバリット(活性炭を10重量%含む消石灰、宇部マテリアルズ株式会社製)0.3gと、吸水剤(ハイモサブ HS-960)0.3gと、バインダとしてKCフロック(登録商標)0.65gと、潤滑剤としてエステルとケイ素(ショ糖脂肪酸エステル DKエステル メーカー名:第一工業製薬(株)製と、微粒二酸化ケイ素 サイロページ720 メーカー名:富士シリシア化学(株)製) 0.24g(エステル:ケイ素(重量比)=2:3)とを、高速回転式打錠機(株式会社菊水製作所製)の臼に入れ、本圧2t(処理剤1粒当たりの圧力)をかけて打錠し、処理剤の錠剤(平均直径:15mm、平均厚さ:7mm)を得た。なお、使用した杵は、直径15mmの上下円版型であった。
ゾルバリット(活性炭を5重量%含む消石灰、宇部マテリアルズ株式会社製)0.5gとし、吸水剤(ハイモサブ HS-960)を0.3gとし、バインダとしてKCフロック(登録商標)0.4gとした以外は、実施例5と同様に、処理剤の錠剤(平均直径:15mm、平均厚さ:5mm)を得た。
原薬剤 0.5gを、卓上打錠機(株式会社菊水製作所製)の臼に入れ、2kNの圧力をかけて打錠し、処理剤の錠剤を得た。なお、使用した杵は、直径15mmの上下平版型であった。
圧力を4kNとしたこと以外は、比較例1と同様にして、処理剤の錠剤を得た。
原薬剤 1.0gを、卓上打錠機(株式会社菊水製作所製)の臼に入れ、20kNの圧力をかけて打錠し、処理剤の錠剤を得た。なお、使用した杵は、直径15mmの上下平版型であった。
圧力を40kNとしたこと以外は、比較例1と同様にして、処理剤の錠剤を得た。
・検体(性別:男、年齢:38歳の糞尿)
・臭気実験の条件:温度20℃、相対湿度55%
大便臭(主には、スカトールとインドール、硫化化合物)については、2段階の官能評価で行った。
「1」が、処理前の大便の臭いと同等である。
糞尿を受ける内面が撥水性を有する容器(ビニール袋)状のトイレパックに、実施例5で得られた処理剤50gを配置した。その配置された処理剤の上に、小便50gを添加し、その後、大便200gを添加した。接触後、30分経過した際の臭気は殆どなく(臭気レベル:0)、2週間経過しても、臭気は殆どなかった(臭気レベル:0)。
糞尿を受ける内面が撥水性を有する容器(ビニール袋)状のトイレパックに、実施例5で得られた処理剤100gを配置した。その配置された処理剤の上に、小便50gを添加し、その後、大便200gを添加した。接触後、30分経過した際の臭気は殆どなく(臭気レベル:0)、2週間経過しても、臭気は殆どなかった(臭気レベル:0)。
処理剤を75gとした以外は、実施例8と同様に、処理を行った。接触後、30分経過した際の臭気は殆どなく(臭気レベル:0)、2週間経過しても、臭気は殆どなかった(臭気レベル:0)。
下記表に示される成分を、下記表に示される混合割合で(合計100質量%)、50gとなるように混合することによって混合物を作製した。かかる混合物50gを(株)富士薬品機械の打錠機(HSシリーズ)で、φ15mmの杵と臼を用いて、本圧1.5kN、30rpm打錠することによって、塊状処理剤 50粒を作製した(1粒1g、平均直径:15mm、平均厚さ:6mm)。取り扱い性は、非常に優れていた。なお、塊状処理剤の硬度は、硬度12kgfであった。この際の硬度の測定は、錠剤破壊強度測定器(硬度計)TH-203MPにて行った。
下記表に示される成分を、下記表に示される混合割合で(合計100質量%)、50gとなるように混合することによって混合物を作製した。かかる混合物50gを(株)富士薬品機械の打錠機(HSシリーズ)で、φ15mmの杵と臼を用いて、本圧1.5kN、30rpm打錠することによって、塊状処理剤 50粒を作製した(1粒1g、平均直径:15mm、平均厚さ:6mm)。ホッパーからのフィードもスムーズに行うことができた。また、取り扱い性は、非常に優れていた。なお、塊状処理剤の硬度は、硬度12kgfであった。この際の硬度の測定は、錠剤破壊強度測定器(硬度計)TH-203MPにて行った。
下記表に示される成分を、下記表に示される混合割合で(合計100質量%)、45gとなるように混合することによって混合物を作製した。かかる混合物45gを(株)畑鉄工所製 HT-AP18SS-II 連続式打錠機で、φ13mmの杵と臼を用いて、本圧1.5kN、30rpm打錠することによって、塊状処理剤 45粒を作製した(1粒1g、平均直径:13mm、平均厚さ:6mm)。ホッパーからのフィードもスムーズに行うことができた。また、取り扱い性は、非常に優れていた。なお、塊状処理剤の硬度は、硬度12kgfであった。この際の硬度の測定は、錠剤破壊強度測定器(硬度計)TH-203MPにて行った。
下記表に示される成分を、下記表に示される混合割合で(合計100質量%)、50gとなるように混合することによって混合物を作製した。かかる混合物50gを(株)畑鉄工所製 HT-AP18SS-II 連続式打錠機で、φ13mmの杵と臼を用いて、本圧6.5kN、20rpm打錠することによって、塊状処理剤 77粒を作製した(1粒約0.65g、平均直径:13mm、平均厚さ:5.5mm)。ホッパーからのフィードもスムーズに行うことができた。また、取り扱い性は、非常に優れていた。なお、塊状処理剤の硬度は、硬度13kgfであった。この際の硬度の測定は、錠剤破壊強度測定器(硬度計)TH-203MPにて行った。
下記表に示される成分を、下記表に示される混合割合で(合計100質量%)、50gとなるように混合することによって混合物を作製した。かかる混合物50gを(株)畑鉄工所製 HT-AP18SS-II 連続式打錠機で、φ13mmの杵と臼を用いて、本圧5.58kN、20rpm打錠することによって、塊状処理剤 67粒を作製した(1粒約0.75g、平均直径:13mm、平均厚さ:5mm)。ホッパーからのフィードもスムーズに行うことができた。また、取り扱い性は、非常に優れていた。なお、塊状処理剤の硬度は、硬度12kgfであった。この際の硬度の測定は、錠剤破壊強度測定器(硬度計)TH-203MPにて行った。
下記表に示される成分を、下記表に示される混合割合で(合計100質量%)、50gとなるように混合することによって混合物を作製した。かかる混合物50gを(株)畑鉄工所製 HT-AP18SS-II 連続式打錠機で、φ13mmの杵と臼を用いて、本圧5.54kN、30rpm打錠することによって、塊状処理剤 83粒を作製した(1粒約0.6g、平均直径:13mm、平均厚さ:5.5mm)。ホッパーからのフィードもスムーズに行うことができた。また、取り扱い性は、非常に優れていた。なお、塊状処理剤の硬度は、硬度8kgfであった。この際の硬度の測定は、錠剤破壊強度測定器(硬度計)TH-203MPにて行った。
下記表に示される成分を、下記表に示される混合割合で(合計100質量%)、50gとなるように混合することによって混合物を作製した。かかる混合物50gを(株)畑鉄工所製 HT-AP18SS-II 連続式打錠機で、φ13mmの杵と臼を用いて、本圧7.5kN、20rpm打錠することによって、塊状処理剤 83粒を作製した(1粒約0.6g、平均直径:13mm、平均厚さ:5.5mm)。ホッパーからのフィードもスムーズに行うことができた。また、取り扱い性は、非常に優れていた。なお、塊状処理剤の硬度は、硬度12kgfであった。この際の硬度の測定は、錠剤破壊強度測定器(硬度計)TH-203MPにて行った。
下記表に示される成分を、下記表に示される混合割合で(合計100質量%)、38.5gとなるように混合することによって混合物を作製した。かかる混合物38.5gを(株)畑鉄工所製 HT-AP18SS-II 連続式打錠機で、φ13mmの杵と臼を用いて、本圧10kN、40rpm打錠することによって、塊状処理剤 39粒を作製した(1粒約1g、平均直径:13mm、平均厚さ:7mm)。ホッパーからのフィードもスムーズに行うことができた。また、取り扱い性は、非常に優れていた。なお、塊状処理剤の硬度は、硬度7kgfであった。この際の硬度の測定は、錠剤破壊強度測定器(硬度計)TH-203MPにて行った。
下記表に示される成分を、下記表に示される混合割合で(合計100質量%)、45gとなるように混合することによって混合物を作製した。かかる混合物45gを (株)畑鉄工所製 HT-AP18SS-II 連続式打錠機で、φ13mmの杵と臼を用いて、本圧1.5kN、30rpm打錠することによって、塊状処理剤 45粒を作製した(1粒1g)。ホッパーからのフィードもスムーズに行うことができた。また、取り扱い性は、非常に優れていた。なお、塊状処理剤の硬度は、硬度12kgfであった。この際の硬度の測定は、錠剤破壊強度測定器(硬度計)TH-203MPにて行った。
下記表に示される成分を、下記表に示される混合割合で(合計100質量%)、50gとなるように混合することによって混合物を作製した。かかる混合物50gを(株)畑鉄工所製 HT-AP18SS-II 連続式打錠機で、φ13mmの杵と臼を用いて、本圧5.54kN、30rpm打錠することによって、塊状処理剤 83粒を作製した(1粒約0.6g)。ホッパーからのフィードもスムーズに行うことができた。また、取り扱い性は、非常に優れていた。なお、塊状処理剤の硬度は、硬度8kgfであった。この際の硬度の測定は、錠剤破壊強度測定器(硬度計)TH-203MPにて行った。
糞尿を受ける内面が撥水性を有する容器(ビニール袋)状のトイレパックに、小便50gを添加し、その後、大便300gを添加した。その後、吸水性ポリマー(住友精化株式会社製 アクアキープSA-50II)10gを添加した。
Claims (10)
- 消石灰または石灰石と、
吸水性ポリマーと、
バインダと、
を含む、塊状処理剤。 - 酸性固形物質をさらに含む、請求項1に記載の塊状処理剤。
- 平均直径が3~100mmである、請求項1または2に記載の塊状処理剤。
- ゼオライト、活性炭、重曹および潤滑剤からなる群から選択される少なくとも1種の添加剤をさらに含む、請求項1~3のいずれか1項に記載の塊状処理剤。
- 糞尿の処理に用いられる、請求項1~4のいずれか1項に記載の塊状処理剤。
- 請求項1~5のいずれか1項に記載の塊状処理剤を粉砕することによってなる、顆粒状処理剤。
- 平均粒径が、150μm超~3mm未満である、請求項6に記載の顆粒状処理剤。
- 請求項1~5のいずれか1項に記載の塊状処理剤または請求項6もしくは7に記載の顆粒状処理剤が予め配置されてなる、便器。
- 水の非存在下に、請求項1~5のいずれか1項に記載の塊状処理剤または請求項6もしくは7に記載の顆粒状処理剤が予め配置されてなる、請求項8に記載の便器。
- 請求項1~5のいずれか1項に記載の塊状処理剤または請求項6もしくは7に記載の顆粒状処理剤を含んで成形されてなる、糞尿の吸収性物品。
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