WO2011092884A1 - 紫外線硬化型樹脂組成物、硬化物及び物品 - Google Patents
紫外線硬化型樹脂組成物、硬化物及び物品 Download PDFInfo
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- WO2011092884A1 WO2011092884A1 PCT/JP2010/064960 JP2010064960W WO2011092884A1 WO 2011092884 A1 WO2011092884 A1 WO 2011092884A1 JP 2010064960 W JP2010064960 W JP 2010064960W WO 2011092884 A1 WO2011092884 A1 WO 2011092884A1
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- acrylate
- resin composition
- curable resin
- ultraviolet curable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/254—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers
- G11B7/2542—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of protective topcoat layers consisting essentially of organic resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/2403—Layers; Shape, structure or physical properties thereof
- G11B7/24056—Light transmission layers lying on the light entrance side and being thinner than the substrate, e.g. specially adapted for Blu-ray® discs
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/2467—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes azo-dyes
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/258—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers
- G11B7/259—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers based on silver
Definitions
- the present invention relates to an ultraviolet curable resin composition useful for an optical disc having an organic dye recording layer.
- Optical disc recording media that are currently in practical use include CD-R, CD-RW, and the like, in which a recording layer, a reflective layer, and a protective layer made of an ultraviolet curable resin are laminated on a polycarbonate substrate having a thickness of 1.2 mm.
- a DVD-R, DVD + R, DVD-RW, DVD + RW, DVD which is composed of a 0.6 mm thick polycarbonate substrate and a 0.6 mm thick polycarbonate substrate having a recording layer and a reflective layer bonded together with an ultraviolet curable resin.
- -RAM is present.
- a Blu-ray Disc having a recording capacity about five times that of a single-layer DVD has been released.
- a reflective layer, a recording layer, and an interface layer are formed on a transparent or opaque plastic substrate having a thickness of 1.1 mm, and then a light transmission layer having a thickness of about 0.1 mm is laminated on the interface layer.
- the recording layer an organic dye or an inorganic compound, a light-transmitting inorganic material as the interface layer, and a cured layer of an ultraviolet curable resin as the light-transmitting layer are used.
- a Blu-ray disc having a recording layer made of an organic dye recording is performed by irradiating the recording layer with a laser beam and utilizing deformation due to a volume change of the organic dye.
- a technique for forming a curable resin having an elastic modulus at 25 ° C. of 40 MPa or less on an interface layer for the purpose of assisting the volume change of the dye and obtaining excellent recording signal characteristics (for example, jitter characteristics) Patent Document 1.
- Patent Document 2 A technique for forming a curable resin having an elastic modulus at 25 ° C. of 34 to 96 MPa
- an environmental test is performed in which the optical disk recording medium is left for 100 hours in an environment of temperature 80 ° C./relative humidity 80% RH.
- both the elastic modulus at 5 ° C. and 55 ° C. on the interface layer is 100 MPa or less, and the elastic modulus at 5 ° C. and 55 ° C.
- Patent Document 3 for forming a curable resin having an elastic modulus ratio of 10 or less has been proposed.
- Patent Documents 1 to 3 do not show specific examples of the curable resin formed on the interface.
- An object of the present invention is to provide an ultraviolet curable resin composition capable of imparting excellent recording signal characteristics and durability in an optical disc having an organic dye recording layer.
- the inventors of the present invention are excellent in optical disks having an organic dye recording layer according to an ultraviolet curable resin composition containing a (meth) acrylate having a specific structure.
- the present inventors have found that recording signal characteristics and durability can be imparted, and have completed the present invention.
- An ultraviolet curable resin composition for an optical disk having an organic dye recording layer comprising (A) (meth) acrylate having a structure represented by the following general formula (1) and (B) a photopolymerization initiator UV curable resin composition.
- n an integer of 2 to 16.
- the ultraviolet curable resin composition according to the above [1], wherein the (meth) acrylate (A) having the structure represented by the general formula (1) is the following general formula (2).
- the (meth) acrylate (A) having the structure represented by the general formula (1) is polypropylene glycol (meth) acrylate, polypropylene glycol di (meth) acrylate, polypropylene oxide modified nonylphenyl (meth) acrylate, polypropylene oxide.
- a (meth) acrylate (C) other than (A) is an epoxy (meth) acrylate, a polyester polyol or a polyether polyol, a reaction product of polyisocyanate and hydroxy (meth) acrylate, and an ethylene oxide-modified bisphenol A type 6.
- n an integer of 2 to 16.
- the ultraviolet curable resin composition according to the above [9], wherein the (meth) acrylate (A) having the structure represented by the general formula (3) is the following general formula (4).
- n represents an integer of 7 to 13.
- a Blu-ray disc having a reflective layer, an organic dye recording layer, an interface layer, and a light transmission layer in this order on a substrate, wherein the light transmission layer is the above [1] to [6] or the above [9] to [9] [10]
- a Blu-ray disc comprising a cured product obtained by irradiating the ultraviolet curable resin composition according to any one of [10] with active energy rays.
- an ultraviolet curable resin composition containing (meth) acrylate having the structure represented by the general formula (1) of the present invention is used for the light transmission layer of an optical disc having an organic dye recording layer, the recording medium and high temperature
- a highly reliable optical disk can be provided for long-time use under humidity.
- the ultraviolet curable resin composition for optical disks having the organic dye recording layer of the present invention (hereinafter simply referred to as “ultraviolet curable resin composition”) has a (meth) acrylate having a structure represented by the following general formula (1) ( A) and a photoinitiator (B) are contained.
- (meth) acrylate means methacrylate or acrylate, and the kind thereof is not particularly limited.
- n an integer of 2 to 16.
- the (meth) acrylate (A) having the structure represented by the general formula (1) contained in the ultraviolet curable resin assembly composition of the present invention is used without limitation in the range of n of 2 to 16. be able to.
- the structure represented by the general formula (1) may be linear or branched, but is preferably a branched structure derived from propylene glycol.
- polypropylene glycol (meth) acrylate for example, NOF Corporation from the viewpoint of imparting excellent recording signal characteristics and durability.
- polypropylene oxide modified nonylphenyl (meth) acrylate for example, Toa Gosei Co., Ltd.
- n in the general formula (1) according to the number of (meth) acryloyl groups in the molecule are particularly preferred.
- n is preferably 2 or more.
- n is preferably 7 or more.
- the content of the component (A) in the ultraviolet curable resin composition is usually 10 to 95% by weight, more preferably 20 to 95% by weight, and still more preferably 20 to 80% by weight. If it is less than 10% by weight, the change in the volume of the dye cannot be assisted, and the jitter value (%), which is an indicator of the recording signal characteristics, becomes worse.
- the jitter value (%) is particularly good when it is 20% by weight or more, and is preferably in the range of 20 to 95% by weight.
- the photopolymerization initiator (B) contained in the ultraviolet curable resin composition of the present invention is not particularly limited.
- 1-hydroxycyclohexyl phenyl ketone (Irgacure 184; manufactured by Ciba Specialty Chemicals)
- 2-hydroxy-2-methyl- [4- (1-methylvinyl) phenyl] propanol oligomer (ONE-Rifened)
- 1- [4- (2-hydroxyethoxy) -phenyl] -2-hydroxy-2-methyl- 1-propan-1-one (Irgacure 2959; manufactured by Ciba Specialty Chemicals)
- 2-hydroxy-1- ⁇ 4- [4- (2-hydroxy-2-methyl-propionyl) -benzyl] -phenyl ⁇ - 2-Methyl-propan-1-one (Irgacure 127; Ciba Specialty Chemicals 2,2-dimethoxy-2-phenylacetophenone (Irgacure 651; manufactured by Ciba
- these components (B) can be used alone or in combination of two or more at any ratio.
- the content of the component (B) in the ultraviolet curable resin composition is usually 0.5 to 20% by weight, preferably 1 to 10% by weight.
- amines that can serve as photopolymerization initiation assistants can be used in combination with the photopolymerization initiator (B).
- examples of amines that can be used include benzoic acid 2-dimethylaminoethyl ester, dimethylaminoacetophenone, p-dimethylaminobenzoic acid ethyl ester, and p-dimethylaminobenzoic acid isoamyl ester.
- the content in the ultraviolet curable resin composition of the present invention is usually 0.005 to 5% by weight, preferably 0.01 to 3% by weight.
- the ultraviolet curable resin composition of the present invention may further contain (meth) acrylate (C) other than (A) in addition to the above components.
- (meth) acrylates (C) other than (A) contained in the ultraviolet curable resin composition of the present invention include (meth) acrylates having at least one (meth) acryloyl group.
- the type of (meth) acrylate (C) other than (A) in the present invention is not particularly limited, but (C-1) epoxy (meth) acrylate, (C-2) urethane (meth) acrylate, (C-3) A (meth) acrylate monomer or the like can be used.
- component (C) (C-1) epoxy (meth) acrylate and / or (C-2) urethane (meth) acrylate and (C-3) (meth) acrylate monomer, respectively It is preferably used alone or in combination.
- the epoxy (meth) acrylate (C-1) that can be used in the present invention has functions of improving curability and improving the hardness, mechanical strength (brittleness) and curing speed of the cured product.
- any epoxy (meth) acrylate may be used as long as it is obtained by reacting a glycidyl ether type epoxy compound with (meth) acrylic acid, but is preferably used in the present invention.
- Examples of glycidyl ether type epoxy compounds for obtaining epoxy (meth) acrylates include diglycidyl ether of bisphenol A or its alkylene oxide adduct, diglycidyl ether of bisphenol F or its alkylene oxide adduct, hydrogenated bisphenol A or its Diglycidyl ether of alkylene oxide adduct, hydrogenated bisphenol F or diglycidyl ether of its alkylene oxide adduct, ethylene glycol diglycidyl ether, propylene glycol Le diglycidyl ether, neopentyl glycol diglycidyl ether, butanediol diglycidyl ether hexanediol diglycidyl ether to, cyclohexanedimethanol diglycidyl ether, and polypropylene glycol diglycidyl ether.
- Epoxy (meth) acrylate is obtained by reacting these glycidyl ether type epoxy compounds with (meth) acrylic acid under the following conditions.
- (Meth) acrylic acid is reacted at a ratio of 0.9 to 1.5 mol, more preferably 0.95 to 1.1 mol, per 1 equivalent of epoxy group of the glycidyl ether type epoxy compound.
- the reaction temperature is preferably 80 to 120 ° C., and the reaction time is about 10 to 35 hours.
- a catalyst such as triphenylphosphine, 2,4,6-tris (dimethylaminomethyl) phenol (TAP), triethanolamine, tetraethylammonium chloride and the like.
- TEP 2,4,6-tris (dimethylaminomethyl) phenol
- triethanolamine tetraethylammonium chloride and the like.
- paramethoxyphenol, methyl hydroquinone, etc. can also be used as a polymerization inhibitor, for example.
- the epoxy (meth) acrylate (C-1) is more preferably bisphenol A type epoxy (meth) acrylate obtained from a bisphenol A type epoxy compound.
- the molecular weight of the epoxy (meth) acrylate (C-1) is preferably 500 to 10,000.
- the urethane (meth) acrylate (C-2) that can be used in the present invention has a function of improving the mechanical properties (warpage, distortion, etc.) of an optical disk bonded using the ultraviolet curable resin composition of the present invention.
- Urethane (meth) acrylate is obtained by reacting a polyhydric alcohol, polyisocyanate, and a hydroxy (meth) acrylate compound.
- polyhydric alcohol examples include neopentyl glycol, 3-methyl-1,5-pentanediol, (poly) ethylene glycol, (poly) propylene glycol, 1,4-butanediol, 1,6-hexanediol, tri
- polyhydric alcohols and polybasic acids for example, succinic acid, phthalic acid, hexahydrophthalic anhydride, terephthalic acid, adipic acid, methylolpropane, pentaerythritol, tricyclodecane dimethylol, bis- [hydroxymethyl] -cyclohexane, etc.
- polyester polyol or polyether polyol is preferable.
- polyisocyanate examples include isophorone diisocyanate, hexamethylene diisocyanate, tolylene diisocyanate, xylene diisocyanate, diphenylmethane-4,4'-diisocyanate, and dicyclopentanyl isocyanate. Of these, isophorone diisocyanate is preferred.
- hydroxy (meth) acrylate compound examples include hydroxyethyl (meth) acrylate, hydroxypropyl (meth) acrylate, hydroxybutyl (meth) acrylate, dimethylol cyclohexyl mono (meth) acrylate, hydroxycaprolactone (meth) acrylate, and the like. .
- hydroxyethyl (meth) acrylate is preferable, and 2-hydroxyethyl (meth) acrylate is particularly preferable.
- the reaction is performed, for example, as follows. That is, the polyhydric alcohol is mixed with an organic polyisocyanate per equivalent of the hydroxyl group so that the isocyanate group is preferably 1.1 to 2.0 equivalent, and reacted at a reaction temperature of preferably 70 to 90 ° C. Synthesize oligomers. Next, the hydroxy (meth) acrylate compound is mixed so that the hydroxyl group is preferably 1 to 1.5 equivalents per equivalent of the isocyanate group of the urethane oligomer, and reacted at 70 to 90 ° C. to react with the target urethane (meth). ) Acrylate can be obtained.
- UX-0937 polyether urethane acrylate (manufactured by Nippon Kayaku Co., Ltd.).
- the molecular weight of the urethane (meth) acrylate (C-2) is preferably about 400 to 10,000.
- the (meth) acrylate monomer (C-3) that can be used as the (meth) acrylate (C) other than (A) can be used to adjust the viscosity and coating strength (mechanical strength), and the type thereof is particularly limited.
- C8-C18 alkyl (meth) acrylate and ethylene oxide-modified phenoxyethyl (meth) acrylate are preferred.
- the (meth) acrylate monomer having one (meth) acryloyl group has a function of improving the mechanical properties (suppression of warpage, distortion, etc.) of an optical disk formed with the ultraviolet curable resin composition of the present invention as a light transmission layer. In particular have.
- (Meth) acrylate monomer (C-3) that can be used as (meth) acrylate (C) other than (A)
- the (meth) acrylate monomer having two (meth) acryloyl groups is cyclohexane-1,4-dimethanoldi (Meth) acrylate, cyclohexane-1,3-dimethanol di (meth) acrylate, tricyclodecane dimethylol di (meth) acrylate (for example, KAYARAD R-684, manufactured by Nippon Kayaku Co., Ltd., tricyclodecane dimethylol di Acrylate, etc.), dioxane glycol di (meth) acrylate (for example, KAYARAD R-604, dioxane glycol diacrylate, etc., manufactured by Nippon Kayaku Co., Ltd.), neopentyl glycol di (meth) acrylate, dicyclopentanyl di ( Meta) Acu Rate, 1,6-
- polyethylene glycol di (meth) acrylate polytetramethylene glycol di (meth) acrylate, and ethylene oxide-modified bisphenol A type di (meth) acrylate are preferably used.
- ethylene oxide-modified bisphenol A type is particularly preferable. It is preferable to use di (meth) acrylate.
- (Meth) acrylate monomer (C-3) that can be used as (meth) acrylate (C) other than (A)
- the (meth) acrylate monomer having three (meth) acryloyl groups is trimethylolpropane tri (meth).
- (meth) acrylate monomer (C-3) that can be used as (meth) acrylate (C) other than (A), as (meth) acrylate monomer having four (meth) acryloyl groups, pentaerythritol polyethoxytetra (meth) ) Acrylate, pentaerythritol polypropoxytetra (meth) acrylate, pentaerythritol tetra (meth) acrylate, ditrimethylolpropane tetra (meth) acrylate, dipentaerythritol tetra (meth) acrylate, and the like.
- pentaerythritol polyethoxytetra (meth) ) Acrylate pentaerythritol polypropoxytetra (meth) acrylate
- pentaerythritol tetra (meth) acrylate ditrimethylolpropane tetra
- (Meth) acrylate monomer (C-3) that can be used as (meth) acrylate (C) other than (A)
- the (meth) acrylate monomer having five (meth) acryloyl groups is dipentaerythritol penta (meth). Examples thereof include acrylate and caprolactone-modified dipentaerythritol penta (meth) acrylate.
- (Meth) acrylate monomer (C-3) that can be used as (meth) acrylate (C) other than (A) (meth) acrylate monomer having 6 (meth) acryloyl groups is dipentaerythritol hexa (meth) Examples thereof include acrylate and caprolactone-modified dipentaerythritol hexa (meth) acrylate.
- the (meth) acrylate monomer that can be used in the present invention may be a polyfunctional monomer having 7 or more (meth) acryloyl groups.
- these components (C) can be used alone or in combination of two or more at any ratio.
- the content of the component (C) in the ultraviolet curable resin composition is usually 0 to 80% by weight, preferably 5 to 70% by weight.
- (C-1) and / or (C-2) and (C-3) are usually light 5 to 70 parts by weight, preferably about 10 to 60 parts by weight per 100 parts by weight of the polymerizable compound component, About 20 to 75 parts by weight are preferably used.
- a photopolymerizable compound refers to the compound component which has a (meth) acryloyl group.
- the ultraviolet curable resin composition of the present invention includes a rust inhibitor, antioxidant, organic solvent, silane coupling agent, polymerization inhibitor, leveling agent, antistatic agent, surface lubricant, fluorescent whitening as necessary.
- Any known hindered amine compound can be used without particular limitation. Specific examples thereof include 1,2,2,6,6-pentamethyl-4-piperidyl alcohol, 2,2,6,6-tetra Examples thereof include methyl-4-piperidyl alcohol, 1,2,2,6,6-pentamethyl-4-piperidyl (meth) acrylate (manufactured by Adeka Co., Ltd., LA-82).
- the ultraviolet curable resin composition of the present invention can be obtained by mixing and dissolving the aforementioned components at room temperature to 80 ° C., and if necessary, impurities may be removed by an operation such as filtration.
- impurities may be removed by an operation such as filtration.
- the more preferable aspect of the ultraviolet curable resin composition of this invention is described concretely below.
- (A) The ultraviolet curable resin composition according to 1 above, wherein the (meth) acrylate having the structure represented by the general formula (2) is polypropylene glycol diacrylate, wherein n 12. 3.
- the ultraviolet curable resin composition according to any one of the above 1 or 2, wherein the amount is 20 to 75 parts by weight. 4).
- Epoxy (meth) acrylate is an epoxy (meth) acrylate obtained by reacting bisphenol A type epoxy resin with 1 molar equivalent of epoxy group and 1 molar equivalent of (meth) acrylic acid, and (C-2) Any one of the above 1 to 4, wherein the urethane (meth) acrylate is a urethane (meth) acrylate obtained by reacting polytetramethylene glycol, isophorone diisocyanate, and hydroxyethyl (meth) acrylate in a molar ratio of 1: 2: 2.
- (C-3) (meth) acrylate monomer is ethylene oxide modified bisphenol A type di (meth) acrylate, propylene oxide 3 mol modified trimethylolpropane tri (meth) acrylate, C8-C18 alkyl (meth) acrylate, ethylene oxide modified 6.
- the above (meth) acrylate monomer is at least one selected from the group consisting of ethylene oxide-modified bisphenol A type di (meth) acrylate and propylene oxide 3 mol-modified trimethylolpropane tri (meth) acrylate 7.
- the ultraviolet curable resin composition according to any one of 1 to 6.
- the ultraviolet curable resin composition of the present invention is suitably used as a coating agent (light transmission layer forming composition) for a light transmission layer of an optical disk having a recording layer formed of an organic dye material.
- the light transmission layer is a layer formed directly or via another layer such as an interface layer on the surface on which the recording / reproducing light laser is incident of an organic dye layer (hereinafter referred to as an organic dye recording layer) which is a recording layer. And has a function of protecting the organic dye recording layer.
- the ultraviolet curable resin composition of the present invention is a composition for forming a light transmission layer in a Blu-ray disc in which a substrate, a reflective layer, a recording layer, an interface layer, and a light transmission layer are laminated in this order It is preferable to use it as a product.
- the ultraviolet curable resin composition of the present invention forms a light transmissive layer by being applied on an organic dye recording layer or an interface layer and then cured by irradiation with active energy rays.
- the cured product obtained by irradiating the ultraviolet curable resin composition of the present invention with active energy rays has a wavelength of light to be transmitted (405 nm for a Blu-ray disc) in order to sufficiently irradiate the recording layer with laser light.
- the transmittance is preferably 80% or more, and particularly preferably 90% or more.
- the material of the organic dye recording layer needs to be sensitive to the wavelength of the laser beam used for recording and reproduction. Furthermore, the refractive index of the material of the organic dye recording layer needs to change due to physical change or chemical reaction upon irradiation with laser light. Therefore, examples of the material for the organic dye recording layer include cyanine dyes, oxonol dyes, azo dyes, phthalocyanine dyes, and porphyrin dyes.
- An organic dye recording layer is formed by spin coating or the like using a solution obtained by mixing these organic materials with a solvent such as cellosolve acetate or tetrafluoropropanol.
- the film thickness of the organic dye recording layer is preferably 15 nm or more and 25 nm or less.
- the interface layer is a mixture such as diffusion of the dye contained in the organic dye layer during the formation of the light transmissive layer into the light transmissive layer and penetration of the cured resin solvent for forming the light transmissive layer into the organic dye layer. There is a function to prevent the phenomenon.
- the material constituting the interface layer is silicon oxide, particularly silicon dioxide, zinc oxide, cerium oxide, yttrium oxide, indium oxide (ITO) and other oxides, zinc sulfide, sulfides such as yttrium sulfide, and nitrides such as silicon nitride. , Silicon carbide, a mixture of oxide and sulfur, a mixture of silicon dioxide and zinc sulfide, aluminum oxide and the like.
- This interface layer is formed by a method such as sputtering.
- examples of the reflective layer include visible light used as a recording / reproducing wavelength, in particular, Au, Ag, Al having a high reflectance in the blue wavelength region, and alloys containing these as main components.
- the reflective layer is formed by a method such as sputtering, ion plating, or electron beam evaporation.
- polycarbonate resin polyolefin resin, acrylic resin, epoxy resin or the like generally used for DVD can be used.
- the ultraviolet curable resin composition of the present invention can be suitably used as a coating agent for a light transmission layer on the laser incident side of a Blu-ray disc or the like.
- the composition is applied to the optical disk substrate by an arbitrary method such as a spin coating method, a 2P method, a roll coating method, or a screen printing method so that the thickness of the applied resin is 1 to 100 ⁇ m.
- the film is cured by irradiating ultraviolet rays to near ultraviolet rays (wavelength of 200 to 400 nm) from one side or both sides.
- Irradiation dose is preferably from about 50 ⁇ 1500mJ / cm 2, particularly preferably 100 ⁇ 1000mJ / cm 2 approximately.
- any light source may be used as long as it is a lamp that emits ultraviolet to near ultraviolet rays.
- a low-pressure, high-pressure or ultrahigh-pressure mercury lamp, metal halide lamp, (pulse) xenon lamp, or electrodeless lamp can be used.
- the ultraviolet curable resin composition of this invention is applicable also when a light transmissive layer consists of a some layer.
- a first resin layer in which a light transmission layer is formed on a recording layer or an interface layer, and a second resin formed on a surface opposite to the recording layer or interface layer side when viewed from the first resin layer When comprised from a layer, it can be used conveniently for said 1st resin layer.
- the thickness of the first resin layer is usually 1 ⁇ m to 50 ⁇ m, preferably 5 ⁇ m to 40 ⁇ m, more preferably 10 ⁇ m to 30 ⁇ m.
- the thickness of the second resin layer is usually 50 ⁇ m to 100 ⁇ m, preferably 60 ⁇ m to 95 ⁇ m, more preferably 70 ⁇ m to 90 ⁇ m.
- the light transmission layer is formed by any method such that the resin applied as the first resin layer has a thickness of 1 to 50 ⁇ m.
- the composition is applied to the optical disk substrate by spin coating, 2P, roll coating, screen printing, or the like.
- the film is cured by irradiating ultraviolet rays to near ultraviolet rays (wavelength of 200 to 400 nm) from one side or both sides. Irradiation dose is preferably from 50 ⁇ 1500mJ / cm 2, particularly preferably 100 ⁇ 1000mJ / cm 2 approximately.
- the composition is applied to the optical disk substrate by an arbitrary method such as spin coating, 2P, roll coating, or screen printing so that the film thickness of the second resin layer is 50 to 100 ⁇ m. .
- the film is cured by irradiating ultraviolet rays to near ultraviolet rays (wavelength of 200 to 400 nm) from one side or both sides. Irradiation dose is preferably from about 50 ⁇ 1500mJ / cm 2, particularly preferably 100 ⁇ 1000mJ / cm 2 approximately.
- any light source may be used as long as it is a lamp that irradiates ultraviolet to near ultraviolet rays.
- a low-pressure, high-pressure or ultrahigh-pressure mercury lamp, metal halide lamp, (pulse) xenon lamp, or electrodeless lamp can be used.
- the ultraviolet curable resin composition of the present invention can be suitably used not only in the case where the recording layer is an organic dye but also in the case of an inorganic compound such as a copper alloy, but is particularly prominent when the recording layer is an organic dye. Has an effect.
- each component shown with the abbreviation in Table 1 is as follows.
- EA-1 Epoxy acrylate obtained by reacting bisphenol A type epoxy resin (epoxy equivalent: 185 g / eq.) With 1 mol equivalent of epoxy group and 1 mol equivalent of acrylic acid to 0.5 mg ⁇ KOH / g oxidation
- BPE-10 Ethylene oxide 10 mol modified bisphenol A diacrylate, manufactured by Daiichi Kogyo Seiyaku Co., Ltd.
- Irgacure 184 1-Hydroxycyclohexyl phenyl keto , Ciba Specialty Chemicals Co., Ltd.
- LA-82 1,2,2,6,6-pentamethyl-4-piperidyl methacrylate, manufactured by Asahi Denka Co.
- PMP 4-mercaptophenol
- a Blu-ray disc having an organic dye recording layer was prepared and evaluated for characteristics.
- a reflective layer was formed by sputtering a silver alloy to a thickness of 100 nm on a polycarbonate substrate having a diameter of 12 cm and a thickness of 1.1 mm having guide grooves with a track pitch of 0.32 ⁇ m. Thereafter, a dye solution in which an azo dye was dissolved in a TFP (tetrafluoropropanol) solvent was applied by spin coating, and dried at 80 ° C. for 30 minutes to form an organic dye recording layer.
- TFP tetrafluoropropanol
- ZnS—SiO 2 (molar ratio 80:20) was sputtered to a thickness of about 15 nm to form an interface layer, and a Blu-ray Disc substrate was produced.
- a Blu-ray disc substrate is placed on a spin table so that the interface layer is on top, and a circular cap treatment is performed so as to cover the inner diameter of 11.5 mm, and then the UV curable resin composition of the present invention is 2.0 g in the center cap. Supplied on top. 3.
- spin coating was performed at a speed range of 1000 rpm to 1500 rpm for 4 seconds to 7 seconds, and each coating film thickness was 25 ⁇ m.
- the xenon flash lamp was irradiated with two shots, and cured so that the fluidity of the surface disappeared. 4).
- the ultraviolet curable resin composition of the present invention was completely cured by irradiation from the upper side at 400 mJ / cm 2 for 3 seconds. 5.
- the cured UV-curable resin composition of the present invention is placed on a spin table so that a circular cap treatment is performed so as to cover the inner diameter of 11.5 mm, and then BRD-864 (Nippon Kayaku Co., Ltd. Blu-ray) is applied.
- the resin for the light transmission layer for disk was supplied onto the cap at the center of 3.0 g. 6.
- Example 6-9 Preparation of Blu-ray Disc with Organic Dye Recording Layer.
- a reflective layer was formed by sputtering a silver alloy to a thickness of 100 nm on a polycarbonate substrate having a diameter of 12 cm and a thickness of 1.1 mm having guide grooves with a track pitch of 0.32 ⁇ m. Thereafter, a dye solution in which an azo dye was dissolved in a TFP (tetrafluoropropanol) solvent was applied by spin coating, and dried at 80 ° C. for 30 minutes to form an organic dye recording layer.
- TFP tetrafluoropropanol
- ZnS—SiO 2 (molar ratio 80:20) was sputtered to a thickness of about 15 nm to form an interface layer, and a Blu-ray Disc substrate was produced.
- a Blu-ray disc substrate is placed on a spin table so that the interface layer is on top, and a circular cap treatment is performed so as to cover the inner diameter of 11.5 mm, and then the UV curable resin composition of the present invention is 2.0 g in the center cap. Supplied on top. 3.
- spin coating was performed at a speed range of 800 rpm to 1300 rpm for 4 seconds to 7 seconds, and the coating film thickness was 100 ⁇ m.
- the xenon flash lamp was irradiated with two shots, and cured so that the fluidity of the surface disappeared. 4).
- the ultraviolet curable resin composition of the present invention was completely cured by irradiating at 400 mJ / cm 2 from the upper side for 3 seconds to produce the Blu-ray Disc of the present invention.
- the optical disc of the present invention was left in an environment of 80 ° C. and 85% RH for 250 hours.
- the recording signal characteristics (jitter value) of the Blu-ray disc before and after the durability test were measured using a Blu-ray Disc data signal measuring device ODU-1000 manufactured by Pulse Tech Co., Ltd., and evaluated according to the following criteria.
- the jitter value is one of the electrical signals of the optical disk. The higher these values are, the more the signal data of the Blu-ray disk is degraded. When the value is 10% or more, it becomes difficult to read and write data. Evaluation of jitter value ⁇ Jitter value is less than 10.0%.
- X Jitter value of 10.0% or more.
- Light transmittance measurement test A film having a thickness of 100 ⁇ m was prepared, and the absorbance value at 405 nm of the film was measured using a spectrophotometer (U-3310, manufactured by Hitachi High-Technologies Corporation).
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Abstract
Description
〔1〕 有機色素記録層を有する光ディスク用紫外線硬化型樹脂組成物であって、(A)下記一般式(1)で示される構造を有する(メタ)アクリレート及び(B)光重合開始剤を含有する紫外線硬化型樹脂組成物。
〔2〕 一般式(1)で示される構造を有する(メタ)アクリレート(A)が下記一般式(2)である、上記〔1〕記載の紫外線硬化型樹脂組成物。
〔3〕 一般式(1)で示される構造を有する(メタ)アクリレート(A)が、ポリプロピレングリコール(メタ)アクリレート、ポリプロピレングリコールジ(メタ)アクリレート、ポリプロピレンオキサイド変性ノニルフェニル(メタ)アクリレート、ポリプロピレンオキサイド変性ネオペンチルグリコールジ(メタ)アクリレート、ポリプロピレンオキサイド変性1,6-ヘキサンジオールジ(メタ)アクリレート、ポリプロピレンオキサイド変性ビスフェノールA型ジ(メタ)アクリレート及びメトキシトリプロピレングリコール(メタ)アクリレートからなる群から選ばれる1種以上である、上記〔1〕または上記〔2〕に記載の紫外線硬化型樹脂組成物。
〔4〕 (C)(A)以外の(メタ)アクリレートを含有する、上記〔1〕~〔3〕の何れか1項に記載の紫外線硬化型樹脂組成物。
〔5〕 一般式(1)で示される構造を有する(メタ)アクリレート(A)が、組成物全体に対して10~95重量%含まれる、上記〔1〕~〔4〕のいずれか1項に記載の紫外線硬化型樹脂組成物。
〔6〕 (A)以外の(メタ)アクリレート(C)が、エポキシ(メタ)アクリレート、ポリエステルポリオール又はポリエーテルポリオールとポリイソシアネートとヒドロキシ(メタ)アクリレートとの反応物、及びエチレンオキサイド変性ビスフェノールA型ジアクリレートからなる群から選ばれる1種以上である、上記〔1〕~〔5〕のいずれか1項に記載の紫外線硬化型樹脂組成物。
〔7〕 上記〔1〕~〔6〕のいずれか1項に記載の紫外線硬化型樹脂組成物に活性エネルギー線を照射して得られる硬化物。
〔8〕 光ディスク基板に、上記〔1〕~〔6〕のいずれか1項に記載の紫外線硬化型樹脂組成物を塗布し、活性エネルギー線を照射して得られる光ディスク。
〔9〕 基板上に反射層、有機色素記録層、界面層及び光透過層をこの順に有するブルーレイディスクの前記光透過層の形成材料として用いられる紫外線硬化型樹脂組成物であって、(A)下記一般式(3)で示される構造を有する(メタ)アクリレート及び(B)光重合開始剤を含有する紫外線硬化型樹脂組成物。
〔10〕 一般式(3)で示される構造を有する(メタ)アクリレート(A)が下記一般式(4)である、上記〔9〕記載の紫外線硬化型樹脂組成物。
〔11〕 基板上に反射層、有機色素記録層、界面層及び光透過層をこの順に有するブルーレイディスクであって、前記光透過層が上記〔1〕~〔6〕または上記〔9〕~〔10〕のいずれか一項に記載の紫外線硬化型樹脂組成物に活性エネルギー線を照射して得られる硬化物からなるブルーレイディスク。
一般式(1)で示される構造を有する(メタ)アクリレート(A)としては、優れた記録信号特性及び耐久性を付与するという見地から、ポリプロピレングリコール(メタ)アクリレート(例えば、日油(株)社製ブレンマー AP-150:式中n=3、AP-400:式中n=6、AP-550:式中n=9、AP-800:式中n=13)、ポリプロピレングリコールジ(メタ)アクリレート(例えば、日立化成工業(株)社製FANCRYL FA-P240A:式中n=7、FA-P270A:式中n=12)、ポリプロピレンオキサイド変性ノニルフェニル(メタ)アクリレート(例えば、東亜合成(株)社製M-117:式中n=2.5、第一工業製薬(株)社製ニューフロンティア NP-5P:式中n=5)及びメトキシトリプロピレングリコール(メタ)アクリレート(例えば、新中村化学(株)社製NKエステル AM-30PG:式中n=3)、ポリプロピレンオキサイド変性ネオペンチルグリコールジ(メタ)アクリレート、ポリプロピレンオキサイド変性1,6-ヘキサンジオールジ(メタ)アクリレート、ポリプロピレンオキサイド変性ビスフェノールA型ジ(メタ)アクリレート(例えば、第一工業製薬(株)社製ニューフロンティア BPP-6:式中n=6)が好ましい。
ここで、さらに優れた記録信号特性及び耐久性を付与するという見地から、分子中の(メタ)アクリロイル基の個数に応じて一般式(1)中のnの値が大きいものが特に好ましく、分子中に(メタ)アクリロイル基が1個の場合はnは2以上、(メタ)アクリロイル基が2個の場合はnは7以上であるのが好適である。具体的には、ポリプロピレングリコール(メタ)アクリレート(例えば、日油(株)社製ブレンマー AP-150:式中n=3、AP-400:式中n=6、AP-550:式中n=9)、ポリプロピレングリコールジ(メタ)アクリレート(例えば、日立化成工業(株)社製FANCRYL FA-P240A:式中n=7、FA-P270A:式中n=12)、ポリプロピレンオキサイド変性ノニルフェニル(メタ)アクリレート(例えば、東亜合成(株)社製M-117:式中n=2.5、第一工業製薬(株)社製ニューフロンティア NP-5P:式中n=5)及びメトキシトリプロピレングリコール(メタ)アクリレート(例えば、新中村化学(株)社製NKエステル AM-30PG:式中n=3)が挙げられる。
この場合において硬化物の脆さを改善する観点から、nの値が7~13のものが好ましく、特にn=12のものが特に好ましい。
本発明の紫外線硬化型樹脂組成物に含有される(A)以外の(メタ)アクリレート(C)としては、例えば(メタ)アクリロイル基を1個以上有する(メタ)アクリレートを挙げることができる。本発明における(A)以外の(メタ)アクリレート(C)の種類は特に限定されないが、(C-1)エポキシ(メタ)アクリレート、(C-2)ウレタン(メタ)アクリレート、(C-3)(メタ)アクリレートモノマー等を用いることができる。特に、本発明においては(C)成分として、(C-1)エポキシ(メタ)アクリレート及び/又は(C-2)ウレタン(メタ)アクリレートと、(C-3)(メタ)アクリレートモノマーとをそれぞれ単独であるいは併用して用いることが好ましい。
1. 本発明の紫外線硬化型樹脂組成物の総量に対して、(A)前記一般式(2)で示される構造を有する(メタ)アクリレートを20~95重量%、(B)光重合開始剤を1~10重量%、(C)(A)以外の(メタ)アクリレートを0~80重量%を含有する紫外線硬化型樹脂組成物。
2. (A)前記一般式(2)で示される構造を有する(メタ)アクリレートがポリプロピレングリコールジアクリレートで式中n=12である上記1に記載の紫外線硬化型樹脂組成物。
3. (C)(A)以外の(メタ)アクリレートとして(C-1)エポキシ(メタ)アクリレート又は(C-2)ウレタンアクリレートの少なくとも一方を含み、さらに(C-3)(メタ)アクリレートモノマーを含み、(C-1)及び/又は(C-2)は光重合性化合物成分100重量部に対して10~60重量部であって、(C-3)は光重合性化合物成分100重量部に対して20~75重量部である上記1または2のいずれか一項に記載の紫外線硬化型樹脂組成物。
4. (C-1)エポキシ(メタ)アクリレートの分子量が400~10000であり、(C-2)ウレタン(メタ)アクリレートの分子量が500~10000である上記1~3のいずれか一項に記載の紫外線硬化型樹脂組成物。
5. (C-1)エポキシ(メタ)アクリレートがビスフェノールA型エポキシ樹脂をエポキシ基1モル当量と(メタ)アクリル酸1モル当量を反応させて得たエポキシ(メタ)アクリレートであり、(C-2)ウレタン(メタ)アクリレートがポリテトラメチレングリコール、イソホロンジイソシアネート、ヒドロキシエチル(メタ)アクリレートをモル比1:2:2で反応させて得たウレタン(メタ)アクリレートである上記1~4のいずれか一項に記載の紫外線硬化型樹脂組成物。
6. (C-3)(メタ)アクリレートモノマーが、エチレンオキサイド変性ビスフェノールA型ジ(メタ)アクリレート、プロピレンオキサイド3モル変性トリメチロールプロパントリ(メタ)アクリレート、C8~C18アルキル(メタ)アクリレート、エチレンオキサイド変性フェノキシエチル(メタ)アクリレート及びポリエチレングリコールジ(メタ)アクリレート、ポリテトラメチレングリコールジ(メタ)アクリレートからなる群から選ばれる少なくとも何れか一種である上記1~5のいずれか一項に記載の紫外線硬化型樹脂組成物。
7. (C-3)(メタ)アクリレートモノマーが、エチレンオキサイド変性ビスフェノールA型ジ(メタ)アクリレート及びプロピレンオキサイド3モル変性トリメチロールプロパントリ(メタ)アクリレートからなる群から選ばれる少なくとも何れか一種である上記1~6のいずれか一項に記載の紫外線硬化型樹脂組成物。
本発明の紫外線硬化型樹脂組成物に活性エネルギー線を照射して得られる硬化物は、記録層にレーザー光を十分に照射するために、透過させる波長の光(ブルーレイディスクにおいては、405nm)の透過率が80%以上であることが好ましく、90%以上であることが特に好ましい。
この場合において、前記第一の樹脂層の厚さは通常1μm~50μmであり、好ましくは5μm~40μm、より好ましくは10μm~30μmである。
また、前記第二の樹脂層の厚さは通常50μm~100μmであり、好ましくは60μm~95μm、より好ましくは70μm~90μmである。
M-117:プロピレンオキサイド2.5モル変性ノニルフェニルアクリレート、式中n=2.5、東亜合成(株)社製
NP-5P:プロピレンオキサイド5モル変性ノニルフェニルアクリレート、式中n=5、第一工業製薬(株)社製
AP-400:プロピレングリコールモノアクリレート、式中n=6、日油(株)社製
AM-30PG:メトキシトリプロピレングリコールアクリレート、式中n=3、新中村化学(株)社製
FA-P270A:ポリプロピレングリコールジアクリレート、式中n=12、日立化成工業(株)社製
TPGDA:トリプロピレングリコールジアクリレート、式中n=3、コグニス社製
TPA-330:プロピレンオキサイド3モル変性トリメチロールプロパントリアクリレート、式中n=1、日本化薬(株)社製
UA-1:ポリテトラメチレングリコール(分子量850)、イソホロンジイソシアネート、2-ヒドロキシエチルアクリレートの3成分をモル比1:2:2で反応させて得られたウレタンアクリレート
EA-1:ビスフェノールA型エポキシ樹脂(エポキシ当量:185g/eq.)をエポキシ基1モル当量とアクリル酸1モル当量を酸化0.5mg・KOH/gまで反応させて得られたエポキシアクリレート
BPE-10:エチレンオキサイド10モル変性ビスフェノールA型ジアクリレート、第一工業製薬(株)社製
NPG-2P:プロピレンオキサイド2モル変性ネオペンチルグリコールジアクリレート、式中n=1、第一工業製薬(株)社製
イルガキュアー184:1-ヒドロキシシクロヘキシルフェニルケトン、チバ・スペシャルティ・ケミカルズ(株)社製
LA-82:1,2,2,6,6-ペンタメチル-4-ピペリジルメタアクリレート、旭電化(株)社製
PMP:4-メルカプトフェノール
1.トラックピッチ0.32μmの案内溝を有する直径12cm、厚み1.1mmのポリカーボネート基板に銀合金を100nmの膜厚になるようスパッタし、反射層を形成した。その後、アゾ色素をTFP(テトラフルオロプロパノール)溶剤に溶かした色素溶液をスピンコート法により塗布し、80℃で30分間乾燥して有機色素記録層を形成した。さらに、ZnS-SiO2(モル比80:20)を約15nmの厚みになるようスパッタし、界面層を形成し、ブルーレイディスク基板を作製した。
2.ブルーレイディスク基板を界面層が上になるようスピンテーブルに乗せ、内径11.5mmまで覆う様に円状のキャップ処理を行い、ついで本発明の紫外線硬化型樹脂組成物を2.0g中心部のキャップ上に供給した。
3.本発明の紫外線硬化型樹脂組成物の粘度に合わせ、1000rpmから1500rpmの速度範囲で4秒から7秒間スピンコートし、各塗布膜厚が25μmとなるよう塗布した。スピンコート終了間際にキセノンフラッシュランプを2ショット照射し、表面の流動性が無くなる程度に硬化させた。
4.高圧水銀ランプを使用し、上側から400mJ/cm2で3秒間照射して本発明の紫外線硬化型樹脂組成物を完全硬化させた。
5.硬化した本発明の紫外線硬化型樹脂組成物が上になるようスピンテーブルに乗せ、内径11.5mmまで覆う様に円状のキャップ処理を行い、ついでBRD-864(日本化薬(株)製ブルーレイディスク用光透過層用樹脂)を3.0g中心部のキャップ上に供給した。
6.1500rpmの速度範囲で4秒から7秒間スピンコートし、塗布膜厚が75μmとなるよう塗布した。スピンコート終了間際にキセノンフラッシュランプを2ショット照射し、表面の流動性が無くなる程度に硬化させた。
7.高圧水銀ランプを使用し、上側から400mJ/cm2で3秒間照射してBRD-864を完全硬化させ、本発明のブルーレイディスクを作製した。
1.トラックピッチ0.32μmの案内溝を有する直径12cm、厚み1.1mmのポリカーボネート基板に銀合金を100nmの膜厚になるようスパッタし、反射層を形成した。その後、アゾ色素をTFP(テトラフルオロプロパノール)溶剤に溶かした色素溶液をスピンコート法により塗布し、80℃で30分間乾燥して有機色素記録層を形成した。さらに、ZnS-SiO2(モル比80:20)を約15nmの厚みになるようスパッタし、界面層を形成し、ブルーレイディスク基板を作製した。
2.ブルーレイディスク基板を界面層が上になるようスピンテーブルに乗せ、内径11.5mmまで覆う様に円状のキャップ処理を行い、ついで本発明の紫外線硬化型樹脂組成物を2.0g中心部のキャップ上に供給した。
3.本発明の紫外線硬化型樹脂組成物の粘度に合わせ、800rpmから1300rpmの速度範囲で4秒から7秒間スピンコートし、塗布膜厚が100μmとなるよう塗布した。スピンコート終了間際にキセノンフラッシュランプを2ショット照射し、表面の流動性が無くなる程度に硬化させた。
4.高圧水銀ランプを使用し、上側から400mJ/cm2で3秒間照射して本発明の紫外線硬化型樹脂組成物を完全硬化させ、本発明のブルーレイディスクを作製した。
本発明の光ディスクを、80℃、85%RH環境下、250時間放置した。ブルーレイディスクデータ信号測定装置パルステック社製ODU-1000を用いて、耐久性試験前後のブルーレイディスクの記録信号特性(ジッタ値)を測定し、下記基準で評価した。ジッタ値は光ディスクの電気信号のひとつであり、これらの数値が高いほど、ブルーレイディスクの信号データが劣化していることを示し、10%以上となるとデータの読み書きが困難となる。
ジッタ値の評価
○・・・ジッタ値10.0%未満。
×・・・ジッタ値10.0%以上。
100μmの膜を作り、分光光度計(U-3310、株式会社日立ハイテクノロジーズ製)を用いて、当該膜の405nmでの吸光度の値を測定して求めた。
なお、本出願は、2010年1月29日付で出願された日本特許出願(特願2010-017576)に基づいており、その全体が引用により援用される。また、ここに引用されるすべての参照は全体として取り込まれる。
Claims (11)
- 一般式(1)で示される構造を有する(メタ)アクリレート(A)が、ポリプロピレングリコール(メタ)アクリレート、ポリプロピレングリコールジ(メタ)アクリレート、ポリプロピレンオキサイド変性ノニルフェニル(メタ)アクリレート、ポリプロピレンオキサイド変性ネオペンチルグリコールジ(メタ)アクリレート、ポリプロピレンオキサイド変性1,6-ヘキサンジオールジ(メタ)アクリレート、ポリプロピレンオキサイド変性ビスフェノールA型ジ(メタ)アクリレート及びメトキシトリプロピレングリコール(メタ)アクリレートからなる群から選ばれる1種以上である、請求項1または請求項2に記載の紫外線硬化型樹脂組成物。
- (C)(A)以外の(メタ)アクリレートを含有する、請求項1~3の何れか1項に記載の紫外線硬化型樹脂組成物。
- 一般式(1)で示される構造を有する(メタ)アクリレート(A)が、組成物全体に対して10~95重量%含まれる、請求項1~4のいずれか1項に記載の紫外線硬化型樹脂組成物。
- (A)以外の(メタ)アクリレート(C)が、エポキシ(メタ)アクリレート、ポリエステルポリオール又はポリエーテルポリオールとポリイソシアネートとヒドロキシ(メタ)アクリレートとの反応物、及びエチレンオキサイド変性ビスフェノールA型ジアクリレートからなる群から選ばれる1種以上である、請求項1~5のいずれか1項に記載の紫外線硬化型樹脂組成物。
- 請求項1~6のいずれか1項に記載の紫外線硬化型樹脂組成物に活性エネルギー線を照射して得られる硬化物。
- 光ディスク基板に、請求項1~6のいずれか1項に記載の紫外線硬化型樹脂組成物を塗布し、活性エネルギー線を照射して得られる光ディスク。
- 基板上に反射層、有機色素記録層、界面層及び光透過層をこの順に有するブルーレイディスクであって、前記光透過層が請求項1~6または請求項9~10のいずれか一項に記載の紫外線硬化型樹脂組成物に活性エネルギー線を照射して得られる硬化物からなるブルーレイディスク。
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CN201080062775.1A CN102725794B (zh) | 2010-01-29 | 2010-09-01 | 紫外线固化型树脂组合物、固化物及物品 |
SG2012056271A SG182791A1 (en) | 2010-01-29 | 2010-09-01 | Ultraviolet-curable resin composition, cured product, and article |
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JP4759650B2 (ja) | 2011-08-31 |
CN102725794B (zh) | 2015-12-16 |
SG182791A1 (en) | 2012-09-27 |
JP2011119013A (ja) | 2011-06-16 |
TW201129864A (en) | 2011-09-01 |
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