WO2011033991A1 - シャンプー組成物 - Google Patents
シャンプー組成物 Download PDFInfo
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- WO2011033991A1 WO2011033991A1 PCT/JP2010/065557 JP2010065557W WO2011033991A1 WO 2011033991 A1 WO2011033991 A1 WO 2011033991A1 JP 2010065557 W JP2010065557 W JP 2010065557W WO 2011033991 A1 WO2011033991 A1 WO 2011033991A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Definitions
- the present invention prevents “entanglement at the time of shampooing” of hair damaged by repeated coloring, permanents, and excessive dryer drying, and eliminates “pasting after drying” and reduces “skin rustling”. It relates to a shampoo composition that can be made.
- a liquid crystal dispersion cleaning composition comprising a cationic surfactant, a higher alcohol and a polyglycerol fatty acid ester
- a cleaning composition such as an amphoteric surfactant, a cationic interface
- Patent Document 2 A shampoo composition containing an activator and an oil component forming a liquid crystal structure (see Patent Document 2), a silicone compound, a poorly water-soluble liquid crystal structure, and a detersive surfactant containing an amphoteric surfactant (Patent Document) 3) is proposed.
- each of the above prior art documents contains a preservative (paraben, benzoic acid or a salt thereof, etc.) in order to obtain long-term storage stability of the preparation, and therefore, for people with weak skin or people with dry skin. It is known that the stimulation is too strong and may cause skin disorders such as contact dermatitis and allergies (see Non-Patent Document 1). In addition, the effect of preventing “entanglement at the time of shampooing” of hair damaged by repeated coloring, perm, and excessive drying of the hair, eliminating “pasting after drying”, and reducing the “background scalp” It is not sufficient, and the current situation is that further improvement and development are desired.
- a preservative paraben, benzoic acid or a salt thereof, etc.
- the present invention prevents “entanglement at the time of shampooing” of hair damaged by repeated coloring, permanents, and excessive dryer drying, eliminates “pasting after drying”, and reduces “skin rustling”. It is an object of the present invention to provide a shampoo composition that is excellent in preservative power even if it contains no preservative (paraben, benzoic acid or its salt, etc.).
- the present invention is based on the above findings by the present inventors, and means for solving the above problems are as follows. That is, ⁇ 1> (A) Cationic surfactant, (B) Long-chain aliphatic alcohol having 12 to 24 carbon atoms, (C) Amphoteric surfactant 10% by mass to 30% by mass, and (D) Glycerin 8% by mass Containing 30% by weight, A shampoo composition wherein the mass ratio of the component (C) to the component (D) [(D) / ((C) + (D))] is 0.30 to 0.70. .
- ⁇ 2> Further contains (E) alkylamine oxide 0.3% by mass to 5% by mass,
- at least one of R 3 and R 4 is a linear or branched alkyl or alkenyl group having 12 to 28 carbon atoms.
- R 3 and R 4 is a methyl group or an ethyl group, and these may be the same as or different from each other.
- R 5 and R 6 are a methyl group or an ethyl group.
- Z ⁇ represents an anion.
- the shampoo composition of the present invention contains (A) a cationic surfactant, (B) a long-chain aliphatic alcohol, (C) an amphoteric surfactant, and (D) glycerin, preferably (E) an alkylamine oxide. And further contains other components as required.
- the cationic surfactant of the component (A) is not particularly limited as long as it can be blended in the shampoo composition, and may be used alone or in combination of two or more.
- a cationic surfactant having a hydrocarbon group having 12 or more carbon atoms is preferable.
- the hydrocarbon group having 12 or more carbon atoms may be divided by a functional group such as —O—, —CONH—, —COO—, etc., and the carbon number of 12 includes, for example, —CONH—, —COO—, etc. Contains the carbon number of the functional group.
- the cationic surfactant of the component (A) is usually contained in the form of a salt, specifically, inorganic salts such as hydrochloride, bromate, sulfate, phosphate, etc .; glycolate, acetate And organic acid salts such as lactate, succinate, tartrate, citrate, acidic amino acid salt, higher fatty acid salt, pyroglutamate, and p-toluenesulfonate.
- inorganic salts such as hydrochloride, bromate, sulfate, phosphate, etc .
- organic acid salts such as lactate, succinate, tartrate, citrate, acidic amino acid salt, higher fatty acid salt, pyroglutamate, and p-toluenesulfonate.
- the cationic surfactant having a hydrocarbon group having 12 or more carbon atoms is not particularly limited as long as it can be blended in a shampoo composition, and can be appropriately selected according to the purpose. ) Quaternary ammonium salt, (2) quaternary ammonium salt containing 1 to 3 ester groups in the molecule, (3) amidoamine type surfactant, (4) amine type surfactant, (5) guanidine derivative Or a salt thereof, (6) an amino acid-based cationic surfactant, and the like.
- R 3 and R 4 are a linear or branched alkyl or alkenyl group having 12 to 28 carbon atoms, preferably 16 to 24 carbon atoms, more preferably 22 carbon atoms. And straight chain alkyl groups are particularly preferred. Either one of R 3 and R 4 may be a methyl group or an ethyl group, and these may be the same as or different from each other. R 5 and R 6 are both methyl groups or ethyl groups.
- Z ⁇ represents an anion, and examples thereof include CH 3 SO 4 ⁇ , C 2 H 5 SO 4 ⁇ , Cl ⁇ and Br ⁇ .
- Examples of the quaternary ammonium salt represented by the general formula (1) include behenyltrimethylammonium chloride and dibehenyldimethylammonium chloride.
- R 7 is a linear or branched alkyl group or alkenyl group having 12 to 26 carbon atoms and including one ester group.
- R 8 represents a methyl group, an ethyl group, or a hydroxyalkyl group having 1 to 4 carbon atoms, and the R 8 may be the same or different from each other.
- X ⁇ represents an anion, and examples thereof include CH 3 SO 4 ⁇ , C 2 H 5 SO 4 ⁇ , Cl ⁇ and Br ⁇ .
- the quaternary ammonium salt containing one ester group in the molecule is preferably a compound represented by the following general formula (3).
- R 9 represents a linear or branched alkyl group or alkenyl group having 9 to 23 carbon atoms, and as R 9 , the linear alkyl group having 13 to 21 carbon atoms or Alkenyl groups are preferred.
- R 9 is preferably a residue obtained by removing a carboxyl group from a fatty acid such as stearic acid, palmitic acid, myristic acid, oleic acid, and elaidic acid.
- Examples of the quaternary ammonium salt containing two ester groups in the molecule include compounds represented by the following general formula (4).
- R 7 , R 8 and X ⁇ have the same meaning as in the general formula (2).
- R 7 and R 8 may be the same as or different from each other.
- the quaternary ammonium salt containing two ester groups in the molecule is preferably a compound represented by the following general formula (5).
- R 9 has the same meaning as in the general formula (3).
- R 9 may be the same as or different from each other, and is preferably a linear alkyl group or alkenyl group having 13 to 21 carbon atoms.
- R 9 is preferably a residue obtained by removing a carboxyl group from a fatty acid such as stearic acid, palmitic acid, myristic acid, oleic acid, and elaidic acid.
- Examples of the quaternary ammonium salt containing three ester groups in the molecule include compounds represented by the following general formula (6).
- R 7 , R 8 and X ⁇ have the same meaning as in the general formula (2).
- R 7 may be the same as or different from each other.
- the quaternary ammonium salt containing three ester groups in the molecule is preferably a compound represented by the following general formula (7).
- R 9 has the same meaning as in the general formula (3).
- R 9 may be the same as or different from each other, and is preferably a linear alkyl group or alkenyl group having 13 to 21 carbon atoms.
- R 9 is preferably a residue obtained by removing a carboxyl group from a fatty acid such as stearic acid, palmitic acid, myristic acid, oleic acid, and elaidic acid.
- R 9 is a residue obtained by removing a carboxyl group from a fatty acid having 10 to 24 carbon atoms, and is a group derived from one of a saturated fatty acid, an unsaturated fatty acid, a linear fatty acid, and a branched fatty acid.
- a saturated fatty acid an unsaturated fatty acid
- a linear fatty acid a linear fatty acid
- a branched fatty acid branched fatty acid.
- the mass ratio (cis / trans) is preferably 25/75 to 80/20, and more preferably 40/60 to 80/20.
- Examples of the fatty acid used as R 9 include stearic acid, palmitic acid, myristic acid, lauric acid, oleic acid, elaidic acid, linoleic acid, partially hydrogenated palm oil fatty acid (iodine value 10 to 60), partial Examples include hydrogenated beef tallow fatty acid (iodine value 10 to 60).
- oleic acid, elaidic acid, linoleic acid, and stearic acid are particularly preferable.
- a predetermined amount of stearic acid, palmitic acid, myristic acid, oleic acid and elaidic acid derived from plants is combined to give a mass ratio (saturated / unsaturated) of 95/5 to 50/50, and a mass ratio of cis / trans isomer of 40 / It is preferably 60 to 80/20, the ratio of 18 carbon atoms is preferably 60% by mass or more, the fatty acid having 20 carbon atoms is 2% by mass or less, and the fatty acid having 22 carbon atoms is 1% by mass or less. It is preferable to use the fatty acid composition adjusted as described above.
- the quaternary ammonium salt containing 1 to 3 ester groups in the molecule is obtained by a condensation reaction between the fatty acid composition or the fatty acid methyl ester composition and triethanolamine, followed by a quaternizing reagent such as dimethyl sulfate. It can be synthesized by a quaternization reaction.
- the R 7 in the general formula (2) to (7) in, R 8, R 9 and X - is, R 7 in the other formula (2) to (7), R 8, R 9 and X - and they are each independently.
- amidoamine type surfactant examples include compounds represented by the following general formula (8).
- R 10 preferably has 11 to 27 carbon atoms, more preferably 15 to 23, and still more preferably a linear or branched alkyl group or alkenyl group having 21 carbon atoms.
- R 11 is an alkyl group having 1 to 4 carbon atoms, preferably a methyl group or an ethyl group.
- n represents an integer of 2 to 4.
- amidoamine type surfactant represented by the general formula (8) examples include stearic acid diethylaminoethylamide, stearic acid dimethylaminoethylamide, palmitic acid diethylaminoethylamide, coconut oil fatty acid diethylaminopropylamide, and palmitic acid dimethylamino.
- stearic acid dimethylaminopropylamide stearic acid diethylaminoethylamide, behenic acid diethylaminoethylamide, and behenic acid dimethylaminopropylamide are particularly preferable.
- These surfactants are usually contained in the above-described various salt forms, and acidic amino acid salts, citrates, and hydrochlorides are preferable.
- the salt used for neutralization may be used individually by 1 type, and may use 2 or more types together.
- amine surfactant examples include stearoxypropyldimethylamine.
- R 12 preferably has 11 to 27 carbon atoms, and more preferably a linear or branched alkyl group or alkenyl group having 11 to 21 carbon atoms.
- A is a linear or branched alkylene group having 1 to 10 carbon atoms or an alkenylene group.
- t is an integer of 1 to 5, and when t is 2 or more, A in each block may be different from each other.
- R 12 examples include C 11 H 23- , C 12 H 25- , C 13 H 27- , C 14 H 29- , C 15 H 31- , C 16 H 33- , C 17 H 35- , (C 8 H 17 ) 2 CH—, 4-C 2 H 5 C 15 H 30 — and the like.
- the substituent A in the general formula (9) preferably has 1 to 10 carbon atoms, more preferably a linear or branched alkylene group or alkenylene group having 2 to 6 carbon atoms, such as a methylene group, ethylene Group, propylene group, butylene group, pentylene group, hexylene group, isopropylene group, 2-pentenyl group, 2-ethylbutylene group and the like.
- the guanidine derivative represented by the general formula (9) is usually contained in the above-described various salt forms, and in the form of hydrochloride, bromate, acetate, glycolate, citrate, or acidic amino acid salt. preferable.
- amino acid-based cationic surfactant examples include mono-N-long chain (C12-22) acyl basic amino acid lower (C1-8) alkyl ester salts.
- basic amino acids constituting the amino acid cationic surfactant include natural amino acids such as ornithine, lysine and arginine. Synthetic amino acids such as ⁇ , ⁇ -diaminobutyric acid can also be used. These may be optically active or racemic.
- the acyl group is a saturated or unsaturated higher fatty acid residue having 12 to 22 carbon atoms.
- These may be natural or synthesized, for example, natural mixtures such as single fatty acid residues such as lauroyl group, myristoyl group, palmitoyl group, stearoyl group, coconut oil fatty acid residue, beef tallow higher fatty acid residue, etc. And higher fatty acid residues.
- lower alkyl ester examples include methyl ester, ethyl ester, propyl ester, butyl ester, pentyl ester, hexyl ester, heptyl ester, octyl ester and the like.
- the lower alkyl ester is usually blended in the form of a salt, specifically, inorganic salts such as hydrochloride, bromate, sulfate, phosphate, etc .; glycolate, acetate, lactate, succinic acid And organic acid salts such as salts, tartrate, citrate, acidic amino acid salt, higher fatty acid salt, pyroglutamate, and p-toluenesulfonate.
- hydrochloride, L- or DL-pyrrolidone carboxylate, and acidic amino acid salt are particularly preferable.
- the quaternary ammonium salt represented by the general formula (1) is preferable, and behenyltrimethylammonium chloride is particularly preferable in that it can provide no dryness after drying.
- the content of the cationic surfactant of the component (A) is not particularly limited and can be appropriately selected according to the purpose, and is based on the total amount of the shampoo composition.
- the content is preferably 1% by mass to 3% by mass.
- the content is less than 1% by mass, the hair may not be entangled in wet hair and the hair may not be dry after drying.
- the content exceeds 3% by mass, the hair is sticky. Such a weight may be generated, and the lack of smoothness may be reduced.
- the long-chain aliphatic alcohol having 12 to 24 carbon atoms as the component (B) can form a liquid crystal structure alone with the cationic surfactant of the component (A) in the shampoo composition. Particularly preferred.
- the number of carbon atoms is less than 12, skin irritation may occur and it may be difficult to form a liquid crystal structure with a cationic surfactant.
- the number of carbon atoms exceeds 24, the melting point becomes high and the system is difficult to dissolve. It may be difficult to form a structure.
- Examples of the long chain aliphatic alcohol having 12 to 24 carbon atoms as the component (B) include higher alcohols represented by the following general formula (10).
- R 13 —OH General formula (10)
- R 13 is an aliphatic hydrocarbon group having 12 to 24 carbon atoms, preferably a linear or branched alkyl group or alkenyl group having 16 to 22 carbon atoms, A straight chain alkyl group of 16 to 22 is more preferred.
- Examples of the long-chain aliphatic alcohol represented by the general formula (10) include myristyl alcohol, cetyl alcohol, stearyl alcohol, 2-hexyldecyl alcohol, cetostearyl alcohol, stearyl alcohol, isostearyl alcohol, octyldodecyl alcohol, Examples include aralkyl alcohol, behenyl alcohol, hardened rapeseed oil alcohol, oleyl alcohol, elaidyl alcohol, linoleyl alcohol, carnervir alcohol, and seryl alcohol. These may be used individually by 1 type and may use 2 or more types together.
- linear alcohols having 16 to 22 carbon atoms are preferable from the viewpoint of high-temperature stability
- behenyl alcohol having 22 carbon atoms is the cationic interface of (A). Since it is easy to form a liquid crystal structure with an activator and to be easily adsorbed to the hair, it is particularly preferable from the viewpoint of the dryness of the hair after drying.
- the content of the long-chain aliphatic alcohol as the component (B) is not particularly limited and can be appropriately selected according to the purpose.
- the content is 0.5% by mass to 10% by mass with respect to the total amount of the shampoo composition.
- Preferably, 2% by mass to 10% by mass is more preferable from the viewpoints of no entanglement of hair in wet hair and no looseness of hair after drying.
- When the content is less than 0.5% by mass, there may be no entanglement of hair in wet hair, and there may be no dryness of hair after drying. Storage stability may deteriorate.
- the mass ratio [(A) / (B)] of the cationic surfactant as the component (A) and the long-chain aliphatic alcohol having 12 to 24 carbon atoms as the component (B) is 1 / It is preferably 1 to 1/4. If the mass ratio [(A) / (B)] exceeds 1/1, it may not be possible to impart no entanglement of hair in wet hair and no looseness of hair after drying. On the other hand, if the mass ratio [(A) / (B)] is less than 1/4, in addition to the fact that the hair is not entangled in wet hair and the hair is not dry after drying. , Long-term storage stability may deteriorate.
- amphoteric surfactant of the component (C) is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include alkylbetaine activators, amide betaine activators, sulfobetaine activators, hydroxy Examples include sulfobetaine activators, amide sulfobetaine activators, phosphobetaine activators, imidazolinium betaine activators, aminopropionic acid activators, amino acid activators, and the like. Among these, alkylbetaine surfactants are particularly preferable.
- alkylbetaine surfactant examples include lauric acid amidopropyl betaine, lauryldimethylaminoacetic acid betaine, coconut oil fatty acid amidopropyl betaine, coconut oil fatty acid dimethylaminoacetic acid betaine, lauryl hydroxysulfobetaine, 2-alkyl-N- Examples thereof include carboxymethyl-N-hydroxyethyl imidazolinium betaine. These may be used individually by 1 type and may use 2 or more types together. Among these, amidopropyl betaine laurate improves bubbling and eliminates tangling during hair washing because bubbles spread to the hair, and also improves antiseptic power against Escherichia coli, staphylococci, and mold. This is particularly preferable.
- the content of the amphoteric surfactant as the component (C) is 10% by mass to 30% by mass, and preferably 14% by mass to 24% by mass with respect to the total amount of the shampoo composition.
- the content is less than 10% by mass, foaming of the main purpose as shampoo performance is lowered, so that foam does not flow in the hair, there is no entanglement of hair in wet hair, and there is no looseness of hair after drying. Is not sufficient, and the antiseptic power of Escherichia coli, staphylococci and fungi may be reduced.
- the content exceeds 30% by mass, the dispersibility of the cationic surfactant as the component (A) and the long-chain aliphatic alcohol having 12 to 24 carbon atoms as the component (B) decreases, and the shampoo composition Since the uniformity of the product cannot be ensured, the increase in the viscosity of the preparation may not exhibit the effect of imparting no tangling of the hair in wet hair and no looseness of the hair after drying.
- the glycerin may be derived from a plant or synthesized.
- the content of the glycerin is 8% by mass to 30% by mass, and more preferably 12% by mass to 25% by mass with respect to the total amount of the shampoo composition. If the content is less than 8% by mass, the effect of imparting dryness to the hair after drying is not sufficient, and the antiseptic power of Escherichia coli, staphylococci and fungi may be reduced in terms of antiseptic power. If it exceeds 30% by mass, it may cause the hair to become sticky and reduce the roughness.
- the mass ratio [(D) / ((C) + (D))] of the component (C) and the component (D) is 0.30 to 0.70, and is 0.40 to 0.60. It is preferable from the viewpoints of no entanglement of hair in wet hair, no dryness of hair after drying, suppression of scalp scalp, long-term storage stability, and antiseptic properties against mold.
- the mass ratio [(D) / ((C) + (D))] is less than 0.30, the moisturizing effect of the glycerin (D) component is not sufficient, so that there is no tangling of hair in wet hair.
- the effect of imparting dryness to the hair after drying may be reduced, and the effect of suppressing scuffing of the background may not be sufficient.
- the mass ratio [(D) / ((C) + (D))] exceeds 0.70, the ratio of the glycerin of the component (D) is increased, resulting in a weight that is sticky to the hair, While the lack of smoothness decreases, the effect of suppressing scuffing of the background may be reduced.
- the mass ratio [(D) / ((C) + (D))] is obtained by rounding off the third decimal point.
- the effect of suppressing scuffing on the background and the antiseptic effect are dramatically improved.
- the alkylamine oxide of the component (E) include decyl dimethylamine oxide, lauryl dimethylamine oxide, myristyl dimethylamine oxide, and the like.
- lauryl dimethylamine oxide is particularly preferable in terms of the effect of suppressing scuffing of the background.
- the number of carbon atoms of the alkylamine oxide as the component (E) is preferably 8 to 18, and more preferably 10 to 14, from the viewpoint of the effect of reducing the color of the background.
- the content of the alkylamine oxide as the component (E) is preferably 0.3% by mass to 5% by mass, and more preferably 0.3% by mass to 3% by mass with respect to the total amount of the shampoo composition. If the content is less than 0.3% by mass, the effect of suppressing scalp on the background may not be sufficient, and if it exceeds 5% by mass, an excessive amount of alkylamine oxide remains on the background. Kayumi may come out.
- the mass ratio [(D) / (E)] between the component (D) and the component (E) is preferably 5 to 40, and from the viewpoints of the effect of suppressing blemishes of the background, antiseptic effect, and long-term storage stability, 6 ⁇ 36 is more preferred.
- the mass ratio [(D) / (E)] is less than 5, the ratio of the alkylamine oxide of the component (E) is high with respect to the total amount of glycerin and alkylamine oxide which are moisturizers, so It may come out.
- the shampoo composition of the present invention is widely used in general shampoo compositions in addition to the components (A) to (D), preferably (E), as long as the object of the present invention is not impaired.
- Various additive components can be blended as necessary. These components include: silicone compounds such as dimethylpolysiloxane, polyether-modified silicone, and amino-modified silicone; hydrocarbons such as liquid paraffin and squalane; esters such as isopropyl myristate; vegetable oils such as camellia oil, almond oil, jojoba oil
- Nonionic surfactants such as polyoxyethylene alkyl ether, glycerin fatty acid ester, sucrose fatty acid ester and polyglycerin fatty acid ester; gallic acid derivatives; amino acids such as glycine, serine and arginine; pyrrolidone carboxylic acid or salt, herbal medicine, Anti-inflammatory agents such as vitamins, dipotassium glycyrrhizinate and glycyr
- fragrance and fragrance composition used in the shampoo composition of the present invention include the fragrance ingredients described in paragraph numbers [0021] to [0035] of JP-A No. 2003-300811, and further described in paragraph [0050].
- Perfume solvents and the like means a mixture comprising the above-described perfume ingredients, a solvent, a perfume stabilizer and the like.
- the content of the fragrance solvent is preferably 0.1% by mass to 99% by mass, and more preferably 1% by mass to 50% by mass with respect to the total amount of the fragrance composition.
- the fragrance stabilizer examples include dibutylhydroxytoluene, butylhydroxyanisole, vitamin E or a derivative thereof, a catechin compound, a flavonoid compound, a polyphenol compound, and the like. Among these, dibutylhydroxytoluene is particularly preferable.
- the content of the fragrance stabilizer is preferably 0.0001% by mass to 10% by mass and more preferably 0.001% by mass to 5% by mass with respect to the total amount of the fragrance composition.
- the content of the fragrance composition is preferably 0.005% by mass to 40% by mass and more preferably 0.01% by mass to 10% by mass with respect to the total amount of the shampoo composition.
- the shampoo composition of the present invention is prepared by mixing and dissolving the component (C) and the component (D), preferably a water-soluble component containing the component (E) in a hot water bath at 80 ° C.
- the oil phase containing the component (A) and the component (B) is added to the aqueous phase and mixed uniformly.
- it can prepare by adding a silicone emulsion and cooling to room temperature, further stirring.
- a stirring bar, a stirring blade, etc. are mentioned.
- the pH of the shampoo composition is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 5.0 to 6.0 at 25 ° C.
- the pH can be measured, for example, at 25 ° C. using a pH meter (HM-30G, manufactured by Toa DKK Corporation) of the shampoo composition diluted 10 times with purified water.
- the pH of the shampoo composition can be adjusted using a desired pH adjuster.
- the pH adjuster is not particularly limited and may be appropriately selected depending on the intended purpose. Examples thereof include citric acid, succinic acid, 2-amino-2-methyl-1-propanol, and monoethanolamine. .
- the viscosity of the shampoo composition of the present invention is not particularly limited and may be appropriately selected depending on the intended purpose, but is preferably 1 Pa ⁇ s to 30 Pa ⁇ s at 25 ° C.
- the viscosity can be measured, for example, using a viscometer (manufactured by TOKIMEC, BM type viscometer, No. 4 rotor) at 30 rpm, 20 seconds, and 25 ° C.
- the shampoo composition of the present invention prevents entanglement of hair damaged by repeated coloring, perm, and excessive dryer drying, eliminates ⁇ passiness after drying '', and ⁇ scalp scalp '' Since it has excellent antiseptic power even if it contains no preservatives (paraben, benzoic acid or its salt, etc.), it can be applied to, for example, skin cleansing shampoo, damage care shampoo, mild shampoo, rinse-in shampoo, etc. It can be used suitably.
- Examples 1 to 24 and Comparative Examples 1 to 8 Preparation of shampoo composition- According to the composition shown in Table 1 (unit: mass%), shampoo compositions of Examples 1 to 24 and Comparative Examples 1 to 8 were prepared by a conventional method. Specifically, in a hot water bath at 80 ° C., the water-soluble component containing the component (C), the component (D), and the component (E) as necessary was mixed and dissolved to obtain an aqueous phase. The oil phase containing the component (A) and the component (B) was added to the aqueous phase and mixed uniformly. Thereafter, a silicone emulsion was added and further cooled to room temperature with stirring. The pH was adjusted using citric acid as a pH adjuster. Each obtained shampoo composition was diluted 10 times with purified water, and pH was measured at 25 ° C. using a pH meter (HM-30G, manufactured by Toa DKK Corporation). The results are shown in Table 1.
- ⁇ Evaluation method of long-term storage stability About 40 mL of each shampoo composition was filled into a 50 mL glass vial, stored at 40 ° C. for 6 months, and the appearance of each shampoo composition was visually determined according to the following criteria. The results are shown in Table 1. ⁇ Evaluation criteria ⁇ ⁇ : No change in appearance, no separation is observed ⁇ : Appearance is partially non-uniform in color tone, but no separation is observed ⁇ : Very little separation is observed ⁇ : Separation is recognized Be
- Escherichia coli NBRC3972 and Staphylococcus aureus NBRC13276 were used. These were all obtained from the National Institute of Technology and Evaluation (NITE).
- NITE National Institute of Technology and Evaluation
- Paecilomyces variotii derived from the environment
- Each of these test bacteria was cultured in an optimum medium, and a bacterial suspension was prepared so as to be about 10 8 to 10 9 cells / mL.
- 0.2 mL of the bacterial suspension was added to 20 g of the evaluation sample and mixed well to prepare an evaluation sample solution, and then the bacteria were stored at 20 ° C. and the fungi were stored at 25 ° C. in the dark.
- 1 g of the evaluation sample solution is aseptically collected and placed in 9 mL of lecithin / polysorbate 80-added soybean / casein / digest liquid medium. Diluted and mixed. Take 1 mL and 0.1 mL of the solution obtained by dilution and mixing in petri dishes, and mix with bacteria in lecithin / polysorbate 80-added soybean / casein / digest agar and fungi in lecithin / polysorbate 80+ glucose / pepton agar. It was. Bacteria were cultured at 30 ° C. for 4 days, and fungi were cultured at 25 ° C.
- Hardened rapeseed oil alcohol consists of stearyl alcohol (carbon number 18), aralkyl alcohol (carbon number 20), and behenyl alcohol (carbon number 22).
- the shampoo composition of the present invention prevents entanglement of hair damaged by repeated coloring, permanents and excessive dryer drying, eliminates ⁇ passiness after drying '', and ⁇ skin scalp '' Because it has excellent antiseptic power even without preservatives (parabens, benzoic acid or its salts, etc.), it can be used in, for example, skin cleansing shampoos, damage care shampoos, mild shampoos, and rinse-in shampoos. It can be used suitably.
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Abstract
Description
このような不具合を解決する手段として、シャンプー組成物中にリンス成分であるカチオン界面活性剤や高級アルコールを配合することで、髪をすすいだ時に液晶構造体が髪に吸着してなめらかさを発現し、乾燥後の毛髪のパサつきを抑制し、滑らかな感触を与える技術が種々提案されている。
更に、好ましくは(E)アルキルアミンオキサイドを配合することにより、意外にも地肌のカユミを抑える効果が飛躍的に向上することを知見した。
<1> (A)カチオン界面活性剤、(B)炭素数12~24の長鎖脂肪族アルコール、(C)両性界面活性剤10質量%~30質量%、及び(D)グリセリン8質量%~30質量%を含有し、
前記(C)成分と前記(D)成分の質量比〔(D)/((C)+(D))〕が、0.30~0.70であることを特徴とするシャンプー組成物である。
<2> 更に(E)アルキルアミンオキサイド0.3質量%~5質量%を含有し、
(D)成分と前記(E)成分の質量比〔(D)/(E)〕が、5~40である前記<1>に記載のシャンプー組成物である。
<3> (A)成分のカチオン界面活性剤が、下記一般式(1)で表される化合物である前記<1>から<2>のいずれかに記載のシャンプー組成物である。
<4> (B)成分の長鎖脂肪族アルコールの炭素数が16~22である前記<1>から<3>のいずれかに記載のシャンプー組成物である。
前記(A)成分のカチオン界面活性剤としては、シャンプー組成物に配合し得るものであれば特に制限はなく、1種単独で使用してもよいし、2種以上を併用してもよい。これらの中でも、炭素数12以上の炭化水素基を有するカチオン界面活性剤が好適である。
前記炭素数12以上の炭化水素基は、-O-、-CONH-、-COO-等の官能基で分断されていてもよく、該炭素数12には、-CONH-、-COO-等の官能基の炭素数を含む。
前記第4級アンモニウム塩としては、下記一般式(1)で表される化合物が好適である。
R5及びR6は、いずれもメチル基又はエチル基である。
Z-は、アニオンを表し、例えば、CH3SO4 -、C2H5SO4 -、Cl-、Br-などが挙げられる。
前記分子内にエステル基を1つ含む第4級アンモニウム塩としては、下記一般式(2)で表される化合物が挙げられる。
R8は、メチル基、エチル基、又は炭素数1~4のヒドロキシアルキル基を示し、該R8は、互いに同一であっても異なっていてもよい。
X-は、アニオンを示し、例えば、CH3SO4 -、C2H5SO4 -、Cl-、Br-などが挙げられる。
前記R9のもととなる脂肪酸としては、例えば、ステアリン酸、パルミチン酸、ミリスチン酸、ラウリン酸、オレイン酸、エライジン酸、リノール酸、部分水添パーム油脂肪酸(ヨウ素価10~60)、部分水添牛脂脂肪酸(ヨウ素価10~60)などが挙げられる。これらの中でも、オレイン酸、エライジン酸、リノール酸、ステアリン酸が特に好ましい。
植物由来のステアリン酸、パルミチン酸、ミリスチン酸、オレイン酸、エライジン酸を所定量組み合わせて、質量比率(飽和/不飽和)が95/5~50/50、シス/トランス体の質量比率が40/60~80/20であることが好ましく、炭素数18の比率が60質量%以上であることが好ましく、炭素数20の脂肪酸を2質量%以下、炭素数22の脂肪酸を1質量%以下となるように調整した脂肪酸組成を用いることが好ましい。
前記分子内にエステル基を1~3つ含む第4級アンモニウム塩は、前記脂肪酸組成物又は脂肪酸メチルエステル組成物と、トリエタノールアミンとの縮合反応、続いてジメチル硫酸等の4級化試薬による4級化反応により合成することができる。
なお、前記一般式(2)~(7)中のR7、R8、R9及びX-は、他の一般式(2)~(7)中のR7、R8、R9及びX-とはそれぞれ独立である。
前記アミドアミン型界面活性剤としては、下記一般式(8)で表される化合物が挙げられる。
R11は、炭素数1~4のアルキル基であり、メチル基又はエチル基が好ましい。
nは、2~4の整数を示す。
これらの界面活性剤は、通常、上述の各種塩の形で含有され、酸性アミノ酸塩、クエン酸塩、塩酸塩の形が好ましい。なお、中和に用いられる塩は、1種単独で使用してもよいし、2種以上を併用してもよい。
前記アミン型界面活性剤としては、例えば、ステアロキシプロピルジメチルアミンなどが挙げられる。
前記グアニジン誘導体又はその塩としては、下記一般式(9)で表される化合物が挙げられる。
前記一般式(9)で表されるグアニジン誘導体は、通常、上述の各種塩の形で含有され、塩酸塩、臭素酸塩、酢酸塩、グリコール酸塩、クエン酸塩、酸性アミノ酸塩の形が好ましい。
前記アミノ酸系カチオン界面活性剤としては、例えば、モノ-N-長鎖(炭素数12~22)アシル塩基性アミノ酸低級(炭素数1~8)アルキルエステル塩などが挙げられる。
前記アミノ酸系カチオン界面活性剤を構成する塩基性アミノ酸としては、例えば、オルニチン、リシン、アルギニン等の天然アミノ酸などが挙げられる。また、α,γ-ジアミノ酪酸のような合成アミノ酸を用いることもできる。これらは光学活性体でもラセミ体でもよい。
前記アシル基は、炭素数が12~22の飽和又は不飽和の高級脂肪酸残基である。これらは天然のものでも合成されたものでもよく、例えば、ラウロイル基、ミリストイル基、パルミトイル基、ステアロイル基等の単一脂肪酸残基、ヤシ油脂肪酸残基、牛脂高級脂肪酸残基等の天然の混合高級脂肪酸残基などが挙げられる。
前記(B)成分の炭素数12~24の長鎖脂肪族アルコールは、前記シャンプー組成物中において、前記(A)成分のカチオン界面活性剤と単独で液晶構造体を形成することができるものが特に好ましい。
前記炭素数が12未満であると、皮膚刺激があり、カチオン界面活性剤と液晶構造体を形成しにくい場合があり、炭素数が24を超えると、融点が高くなり、系に解けにくく、液晶構造体の形成がしにくい場合がある。
R13-OH ・・・一般式(10)
ただし、前記一般式(10)中、R13は、炭素数12~24の脂肪族炭化水素基であり、炭素数16~22の直鎖又は分岐鎖のアルキル基又はアルケニル基が好ましく、炭素数16~22の直鎖アルキル基がより好ましい。
前記(C)成分の両性界面活性剤としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、アルキルベタイン系活性剤、アミドベタイン系活性剤、スルホベタイン系活性剤、ヒドロキシスルホベタイン系活性剤、アミドスルホベタイン系活性剤、ホスホベタイン系活性剤、イミダゾリニウムベタイン系活性剤、アミノプロピオン酸系活性剤、アミノ酸系活性剤などが挙げられる。これらの中でも、アルキルベタイン系界面活性剤が特に好ましい。
前記アルキルベタイン系界面活性剤としては、例えば、ラウリン酸アミドプロピルベタイン、ラウリルジメチルアミノ酢酸ベタイン、ヤシ油脂肪酸アミドプロピルベタイン、ヤシ油脂肪酸ジメチルアミノ酢酸ベタイン、ラウリルヒドロキシスルホベタイン、2-アルキル-N-カルボキシメチル-N-ヒドロキシエチルイミダゾリニウムベタインなどが挙げられる。これらは、1種単独で使用してもよいし、2種以上を併用してもよい。これらの中でも、ラウリン酸アミドプロピルベタインが、泡立ちが向上し、髪に泡が行渡るので「洗髪時の絡まり」がなくなり、また防腐力上も大腸菌、ブドウ球菌、カビに対して防腐力が向上する点で特に好ましい。
前記グリセリンは、植物由来でもよく、合成したものであってもよい。
前記グリセリンの含有量は、前記シャンプー組成物全量に対して8質量%~30質量%であり、12質量%~25質量%がより好ましい。前記含有量が、8質量%未満であると、乾燥後の髪のパサツキのなさを付与する効果が十分でなく、防腐力上も大腸菌、ブドウ球菌、カビに対して防腐力が低下することがあり、30質量%を超えると、毛髪にべたつくような重さを生じ、パサツキのなさが低下することがある。
本発明のシャンプー組成物においては、(E)成分のアルキルアミンオキサイドを更に含有することにより、地肌のカユミを抑える効果、防腐効果が飛躍的に向上する。
前記(E)成分のアルキルアミンオキサイドとしては、例えば、デシルジメチルアミンオキシド、ラウリルジメチルアミンオキシド、ミリスチルジメチルアミンオキシドなどが挙げられる。これらの中でも、地肌のカユミを抑える効果の点でラウリルジメチルアミンオキシドが特に好ましい。
前記(E)成分のアルキルアミンオキサイドの炭素数は、地肌のカユミを低減する効果の面から、8~18が好ましく、10~14がより好ましい。
前記(E)成分のアルキルアミンオキサイドの含有量は、前記シャンプー組成物全量に対して0.3質量%~5質量%が好ましく、0.3質量%~3質量%がより好ましい。前記含有量が、0.3質量%未満であると、地肌のカユミを抑える効果が十分ではなくなることがあり、5質量%を超えると、過剰量のアルキルアミンオキサイドが地肌に残るため、逆にカユミが出てしまうことがある。
本発明のシャンプー組成物には、前記(A)成分~(D)成分、好ましくは(E)成分以外にも、本発明の目的を損なわない範囲で、一般のシャンプー組成物に汎用されている各種添加成分を必要に応じて配合することができる。これらの成分としては、ジメチルポリシロキサン、ポリエーテル変性シリコーン、アミノ変性シリコーン等のシリコーン化合物;流動パラフィン、スクワラン等の炭化水素;イソプロピルミリステート等のエステル;ツバキ油、アーモンド油、ホホバ油等の植物油;ポリオキシエチレンアルキルエ-テル、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ポリグリセリン脂肪酸エステル等のノニオン界面活性剤;没食子酸誘導体;グリシン、セリン、アルギニン等のアミノ酸;ピロリドンカルボン酸又は塩、生薬、ビタミン、グリチルリチン酸ジカリウム、グリチルレチン酸等の消炎剤;ピロクトンオラミン、ジンクピリチオン等のフケ止め剤;イソプロピルメチルフェノール、トリクロサン等の殺菌剤;タール色素、紫外線吸収剤、酸化防止剤、エタノール等の溶剤;アクリル酸系ポリマー等のアニオン性ポリマー;ビニルピロリドン系ポリマー等のノニオン性ポリマー;塩化ジアリルジメチルアンモニウム/アクリル酸等の両性ポリマー、カチオン化セルロ-ス、カチオン化グアーガム等のカチオン性ポリマー;無水シリカ、マグネシアシリカ等の無機粉体;ナイロン、ポリエチレン等の有機粉体、などが挙げられる。これらは、1種単独で使用してもよいし、2種以上を併用してもよい。
前記香料用溶剤の含有量は、前記香料組成物全量に対して0.1質量%~99質量%が好ましく、1質量%~50質量%がより好ましい。
前記香料安定化剤としては、例えば、ジブチルヒドロキシトルエン、ブチルヒドロキシアニソール、ビタミンE又はその誘導体、カテキン化合物、フラボノイド化合物、ポリフェノール化合物などが挙げられる。これらの中でも、ジブチルヒドロキシトルエンが特に好ましい。
前記香料安定剤の含有量は、前記香料組成物全量に対して0.0001質量%~10質量%が好ましく、0.001質量%~5質量%がより好ましい。
前記香料組成物の含有量は、前記シャンプー組成物全量に対して、0.005質量%~40質量%が好ましく、0.01質量%~10質量%がより好ましい。
前記シャンプー組成物のpHとしては、特に制限はなく、目的に応じて適宜選択することができるが、25℃で、5.0~6.0が好ましい。
前記pHは、例えば、精製水で10倍に薄めた前記シャンプー組成物をpHメーター(東亜ディーケーケー株式会社製、HM-30G)を用いて25℃で測定することができる。
前記シャンプー組成物のpHは、所望のpH調整剤を用いて調整することができる。前記pH調整剤としては、特に制限はなく、目的に応じて適宜選択することができ、例えば、クエン酸、コハク酸、2-アミノ-2-メチル-1-プロパノール、モノエタノールアミンなどが挙げられる。
本発明のシャンプー組成物の粘度としては、特に制限はなく、目的に応じて適宜選択することができるが、25℃で、1Pa・s~30Pa・sが好ましい。
前記粘度は、例えば、粘度計(TOKIMEC社製、BM型粘度計、No.4ローター)を用い、30rpm、20秒後、25℃で測定することができる。
本発明のシャンプー組成物は、カラーリングやパーマ、過度のドライヤー乾燥の繰り返しによって損傷した毛髪の「洗髪時の絡まり」を防止し、「乾燥後のパサツキ」を解消すると共に、「地肌のカユミ」を低減することができ、防腐剤(パラベン、安息香酸又はその塩等)を無配合でも防腐力に優れているので、例えば、地肌クレンジング用シャンプー、ダメージケア用シャンプー、マイルドシャンプー、リンスインシャンプー等に好適に用いることができる。
-シャンプー組成物の調製-
表1に示す組成(単位は質量%)に従い、実施例1~24及び比較例1~8のシャンプー組成物を常法により調製した。具体的には、80℃の湯浴中で、(C)成分、(D)成分、及び必要に応じて(E)成分を含む水溶性成分を混合溶解し水相とした。この水相に、(A)成分及び(B)成分を含む油相を添加し、均一に混合した。その後、シリコーンエマルションを添加し、更に攪拌しながら室温まで冷却した。なお、pH調整剤としてクエン酸を用いてpHを調整した。
得られた各シャンプー組成物を精製水で10倍に薄めて、pHメーター(東亜ディーケーケー株式会社製、HM-30G)を用い、25℃でpHを測定した。結果を表1に示す。
「ぬれ髪における髪の絡みのなさ」、「乾燥後の髪のパサツキのなさ」、及び「地肌のカユミのなさ」について、以下のようにして、官能評価を行った。結果を表1に示す。
〔官能評価方法〕
カラーリング、パーマ等の化学処理を3ヶ月以内に行い、洗髪時の髪の絡まり、洗髪しドライヤーで乾燥後に髪のパサツキを感じるとともに、地肌のカユミを現在感じている30~40代の女性30名で、各シャンプー組成物を7日間使用し、下記基準に則り評価を行った。
〔評価基準〕
◎:良好と答えた者が30名中27名以上
◎~○:良好と答えた者が30名中24名~26名
○:良好と答えた者が30名中15名~23名
△:良好と答えた者が30名中5名~14名
×:良好と答えた者が5名未満
なお、上記評価基準において、「良好」とは、各評価項目毎に、「ぬれ髪における髪の絡みがないこと」、「乾燥後の髪のパサツキがないこと」、及び「地肌のカユミがないこと」を意味する。
各シャンプー組成物を50mLのガラスバイアルビンに約40mL充填し、40℃で6ヶ月保存を実施し、各シャンプー組成物の外観を下記基準に則り目視で判定した。結果を表1に示す。
〔評価基準〕
◎:外観に変化がなく、分離が認められない
○:外観が一部色調に不均一な濃淡が認められるが、分離は認められない
△:ごく一部、分離が認められる
×:分離が認められる
供試菌として、細菌は、Eschericia coli NBRC3972、Staphylococcus aureus NBRC13276を用いた。これらは、いずれも独立行政法人製品評価技術基盤機構(NITE)から入手した。
真菌は、Paecilomyces variotii(環境由来)を用いた。
これら供試菌を、それぞれ至適培地で培養し、約108~109個/mLとなるように菌懸濁液を調製した。
評価試料20gに前記菌懸濁液0.2mLを添加し、十分に混合して、評価用試料液を調製した後、細菌は20℃、真菌は25℃でそれぞれ暗所に保存した。
次に、保存1日後、4日後、7日後、14日後、及び28日後に、前記評価用試料液から1gを無菌的に採取し、レシチン・ポリソルベート80加ソイビーン・カゼイン・ダイジェスト液体培地9mLにそれぞれ希釈混合した。希釈混合して得た液1mL、0.1mLをそれぞれシャーレに取り、細菌はレシチン・ポリソルベート80加ソイビーン・カゼイン・ダイジェスト寒天培地、真菌はレシチン・ポリソルベート80加グルコース・ペプトン寒天培地で混釈を行った。細菌は30℃で4日間、真菌は25℃で7日間培養を行い、前記試料中の生残菌数を測定した。
判定は、添加した細菌又は真菌が検出限界以下(10個/g以下)になるまでの日数に基づき、下記基準により評価した。結果を表1に示す。
〔評価基準〕
◎:7日以内に検出限界以下(10個/g以下)となり、添加した菌の死滅が認められた
○:8~14日以内に検出限界以下(10個/g以下)となり、添加した菌の死滅が認められた
△:検出限界以下(10個/g以下)になるのに14日を超える
×:添加した菌の死滅が認められない
下記実施例25~27について、上記実施例1~24と同様にして評価したところ、いずれも優れた効果を示した。
-シャンプー-
・塩化ベヘニルトリメチルアンモニウム 2.5質量%
・ベヘニルアルコール 6質量%
・ラウリン酸アミドプロピルベタイン 14質量%
・グリセリン 15質量%
・ラウリルジメチルアミンオキシド 1質量%
・ポリオキシエチレンラウリル硫酸Na 1質量%
・ポリオキシエチレンベヘニルエーテル 0.2質量%
・スメクタイト 0.3質量%
・高重合アミノ変性シリコーンエマルション 3質量%
・アミノ変性シリコーンエマルション 0.5質量%
・ヒドロキシプロピルメチルセルロース 0.1質量%
・ヒドロキシエタンジホスホン酸 0.1質量%
・ポリオキシエチレンセトステアリル
ヒドロキシミリスチレンエーテル 0.35質量%
・香料B 0.5質量%
・クエン酸 適量
・精製水 バランス
合計 100質量%
質量比〔(D)/((C)+(D))〕=0.52
質量比〔(D)/(E)〕=15
pH5.3(25℃)、粘度8.0Pa・s(25℃)
<評価結果>
ぬれ髪における髪の絡みのなさ:◎
乾燥後の髪のパサツキのなさ:◎
地肌のカユミのなさ:◎
長期保存安定性:○
防腐効果(ブドウ球菌):◎
防腐効果(大腸菌):◎
防腐効果(カビ):◎
-シャンプー-
・塩化ベヘニルトリメチルアンモニウム 2.5質量%
・ベヘニルアルコール 6質量%
・ラウリン酸アミドプロピルベタイン 10質量%
・ヤシ油脂肪酸アミドプロピルベタイン 5質量%
・グリセリン 15質量%
・ラウリルジメチルアミンオキシド 2質量%
・ポリオキシエチレンラウリル硫酸Na 1質量%
・ポリオキシエチレンベヘニルエーテル 0.2質量%
・スメクタイト 0.3質量%
・高重合アミノ変性シリコーンエマルション 2質量%
・ジメチルシリコーンエマルション 1質量%
・ヒドロキシプロピルメチルセルロース 0.1質量%
・ヒドロキシエタンジホスホン酸 0.1質量%
・ポリオキシエチレンセトステアリル
ヒドロキシミリスチレンエーテル 0.8質量%
・香料C 0.5質量%
・クエン酸 適量
・精製水 バランス
合計 100質量%
質量比〔(D)/((C)+(D))〕=0.50
質量比〔(D)/(E)〕=7.5
pH5.3(25℃)、粘度20Pa・s(25℃)
<評価結果>
ぬれ髪における髪の絡みのなさ:◎
乾燥後の髪のパサツキのなさ:◎
地肌のカユミのなさ:◎
長期保存安定性:○
防腐効果(ブドウ球菌):◎
防腐効果(大腸菌):◎
防腐効果(カビ):◎
-シャンプー-
・塩化ベヘニルトリメチルアンモニウム 2.5質量%
・ベヘニルアルコール 6質量%
・ラウリン酸アミドプロピルベタイン 15質量%
・グリセリン 12質量%
・ラウリルジメチルアミンオキシド 1質量%
・ポリオキシエチレンラウリル硫酸Na 2質量%
・ポリオキシエチレンベヘニルエーテル 0.2質量%
・スメクタイト 0.3質量%
・高重合アミノ変性シリコーンエマルション 5質量%
・アミノ変性シリコーンエマルション 0.5質量%
・ヒドロキシプロピルメチルセルロース 0.05質量%
・ヒドロキシエタンジホスホン酸 0.1質量%
・ポリオキシエチレンセトステアリル
ヒドロキシミリスチレンエーテル 0.2質量%
・香料D 0.5質量%
・クエン酸 適量
・精製水 バランス
合計 100質量%
質量比〔(D)/((C)+(D))〕=0.44
質量比〔(D)/(E)〕=12
pH5.3(25℃)、粘度5.0Pa・s(25℃)
<評価結果>
ぬれ髪における髪の絡みのなさ:◎
乾燥後の髪のパサツキのなさ:◎
地肌のカユミのなさ:◎
長期保存安定性:○
防腐効果(ブドウ球菌):◎
防腐効果(大腸菌):◎
防腐効果(カビ):◎
Claims (2)
- (A)カチオン界面活性剤、(B)炭素数12~24の長鎖脂肪族アルコール、(C)両性界面活性剤10質量%~30質量%、及び(D)グリセリン8質量%~30質量%を含有し、
前記(C)成分と前記(D)成分の質量比〔(D)/((C)+(D))〕が、0.30~0.70であることを特徴とするシャンプー組成物。 - 更に(E)アルキルアミンオキサイド0.3質量%~5質量%を含有し、
(D)成分と前記(E)成分の質量比〔(D)/(E)〕が、5~40である請求項1に記載のシャンプー組成物。
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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CN201080041844.0A CN102510750B (zh) | 2009-09-17 | 2010-09-09 | 洗发剂组合物 |
KR1020127006632A KR101776348B1 (ko) | 2009-09-17 | 2010-09-09 | 샴푸 조성물 |
HK12108382.5A HK1167612A1 (en) | 2009-09-17 | 2012-08-28 | Shampoo composition |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2009-216085 | 2009-09-17 | ||
JP2009216085A JP5502408B2 (ja) | 2009-09-17 | 2009-09-17 | シャンプー組成物 |
Publications (1)
Publication Number | Publication Date |
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WO2011033991A1 true WO2011033991A1 (ja) | 2011-03-24 |
Family
ID=43758598
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/JP2010/065557 WO2011033991A1 (ja) | 2009-09-17 | 2010-09-09 | シャンプー組成物 |
Country Status (5)
Country | Link |
---|---|
JP (1) | JP5502408B2 (ja) |
KR (1) | KR101776348B1 (ja) |
CN (1) | CN102510750B (ja) |
HK (1) | HK1167612A1 (ja) |
WO (1) | WO2011033991A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3481507B1 (en) | 2016-07-07 | 2021-10-27 | L'oreal | Cosmetic composition comprising a particular combination of surfactants, a silicone, a cationic polymer, a fatty alcohol and a clay |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6172270B2 (ja) * | 2013-05-15 | 2017-08-02 | ライオン株式会社 | 乳化系毛髪化粧料 |
JP6360667B2 (ja) * | 2013-09-19 | 2018-07-18 | ホーユー株式会社 | 頭髪化粧料洗浄・除去剤 |
CN107106436B (zh) * | 2014-12-25 | 2020-10-27 | 狮王株式会社 | 液体皮肤洗净剂组合物 |
JP7264458B2 (ja) * | 2019-05-22 | 2023-04-25 | 株式会社アリミノ | 毛髪化粧料 |
CN118159246A (zh) * | 2021-10-29 | 2024-06-07 | 莱雅公司 | 用于清洁和调理头发的组合物 |
KR102569171B1 (ko) | 2022-10-20 | 2023-08-23 | 주식회사 제이피에스코스메틱 | 모발 톤업 샴푸 조성물, 이를 이용한 모발 톤업 샴푸 및 이의 제조방법 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08245984A (ja) * | 1995-03-09 | 1996-09-24 | Kawaken Fine Chem Co Ltd | 液体洗浄剤組成物 |
JP2001311099A (ja) * | 2000-04-28 | 2001-11-09 | Lion Corp | 洗浄剤組成物及び洗浄剤組成物の製造方法 |
JP2003146844A (ja) * | 2001-11-13 | 2003-05-21 | Ichimaru Pharcos Co Ltd | 毛髪用化粧料組成物 |
JP2004262805A (ja) * | 2003-02-28 | 2004-09-24 | Lion Corp | 毛髪洗浄剤組成物 |
JP2004292387A (ja) * | 2003-03-27 | 2004-10-21 | Lion Corp | シャンプー組成物 |
WO2008029516A1 (en) * | 2006-09-08 | 2008-03-13 | Kao Corporation | Skin or hair cleanser composition |
-
2009
- 2009-09-17 JP JP2009216085A patent/JP5502408B2/ja active Active
-
2010
- 2010-09-09 KR KR1020127006632A patent/KR101776348B1/ko active IP Right Grant
- 2010-09-09 WO PCT/JP2010/065557 patent/WO2011033991A1/ja active Application Filing
- 2010-09-09 CN CN201080041844.0A patent/CN102510750B/zh not_active Expired - Fee Related
-
2012
- 2012-08-28 HK HK12108382.5A patent/HK1167612A1/xx not_active IP Right Cessation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH08245984A (ja) * | 1995-03-09 | 1996-09-24 | Kawaken Fine Chem Co Ltd | 液体洗浄剤組成物 |
JP2001311099A (ja) * | 2000-04-28 | 2001-11-09 | Lion Corp | 洗浄剤組成物及び洗浄剤組成物の製造方法 |
JP2003146844A (ja) * | 2001-11-13 | 2003-05-21 | Ichimaru Pharcos Co Ltd | 毛髪用化粧料組成物 |
JP2004262805A (ja) * | 2003-02-28 | 2004-09-24 | Lion Corp | 毛髪洗浄剤組成物 |
JP2004292387A (ja) * | 2003-03-27 | 2004-10-21 | Lion Corp | シャンプー組成物 |
WO2008029516A1 (en) * | 2006-09-08 | 2008-03-13 | Kao Corporation | Skin or hair cleanser composition |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3481507B1 (en) | 2016-07-07 | 2021-10-27 | L'oreal | Cosmetic composition comprising a particular combination of surfactants, a silicone, a cationic polymer, a fatty alcohol and a clay |
Also Published As
Publication number | Publication date |
---|---|
HK1167612A1 (en) | 2012-12-07 |
JP2011063548A (ja) | 2011-03-31 |
JP5502408B2 (ja) | 2014-05-28 |
CN102510750B (zh) | 2014-02-19 |
KR20120074275A (ko) | 2012-07-05 |
CN102510750A (zh) | 2012-06-20 |
KR101776348B1 (ko) | 2017-09-07 |
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