WO2010050466A1 - 光電変換装置用波長変換膜形成組成物及び光電変換装置用波長変換膜並びに光電変換装置 - Google Patents
光電変換装置用波長変換膜形成組成物及び光電変換装置用波長変換膜並びに光電変換装置 Download PDFInfo
- Publication number
- WO2010050466A1 WO2010050466A1 PCT/JP2009/068396 JP2009068396W WO2010050466A1 WO 2010050466 A1 WO2010050466 A1 WO 2010050466A1 JP 2009068396 W JP2009068396 W JP 2009068396W WO 2010050466 A1 WO2010050466 A1 WO 2010050466A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- wavelength
- wavelength conversion
- polymer
- conversion film
- photoelectric conversion
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 32
- 239000012528 membrane Substances 0.000 title abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims abstract description 111
- 229920000642 polymer Polymers 0.000 claims abstract description 60
- 239000002904 solvent Substances 0.000 claims abstract description 20
- 230000015572 biosynthetic process Effects 0.000 claims description 39
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 24
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 14
- -1 polysiloxane Polymers 0.000 claims description 12
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 11
- 229920003986 novolac Polymers 0.000 claims description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 claims description 6
- 238000004132 cross linking Methods 0.000 claims description 6
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Natural products C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 claims description 5
- 239000003431 cross linking reagent Substances 0.000 claims description 5
- 229920002098 polyfluorene Polymers 0.000 claims description 5
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims description 5
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims description 4
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 claims description 4
- 229920003180 amino resin Polymers 0.000 claims description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 4
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 claims description 4
- RMBPEFMHABBEKP-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2C3=C[CH]C=CC3=CC2=C1 RMBPEFMHABBEKP-UHFFFAOYSA-N 0.000 claims description 4
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 claims description 4
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N o-biphenylenemethane Natural products C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 3
- 239000004642 Polyimide Substances 0.000 claims description 3
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 229960000956 coumarin Drugs 0.000 claims description 3
- 235000001671 coumarin Nutrition 0.000 claims description 3
- YQGOJNYOYNNSMM-UHFFFAOYSA-N eosin Chemical compound [Na+].OC(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C(O)=C(Br)C=C21 YQGOJNYOYNNSMM-UHFFFAOYSA-N 0.000 claims description 3
- 239000000113 methacrylic resin Substances 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 claims description 3
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 claims description 3
- 229920000548 poly(silane) polymer Polymers 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 229920003257 polycarbosilane Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 229920001721 polyimide Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 239000002516 radical scavenger Substances 0.000 claims description 3
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 claims description 3
- 235000021286 stilbenes Nutrition 0.000 claims description 3
- VXQBJTKSVGFQOL-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethyl acetate Chemical compound CCCCOCCOCCOC(C)=O VXQBJTKSVGFQOL-UHFFFAOYSA-N 0.000 claims description 2
- CRWNQZTZTZWPOF-UHFFFAOYSA-N 2-methyl-4-phenylpyridine Chemical compound C1=NC(C)=CC(C=2C=CC=CC=2)=C1 CRWNQZTZTZWPOF-UHFFFAOYSA-N 0.000 claims description 2
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims description 2
- 229940116333 ethyl lactate Drugs 0.000 claims description 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims description 2
- 125000005577 anthracene group Chemical group 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 13
- 238000004528 spin coating Methods 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 64
- 238000003786 synthesis reaction Methods 0.000 description 31
- 239000000243 solution Substances 0.000 description 25
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 18
- 239000000463 material Substances 0.000 description 13
- 238000000576 coating method Methods 0.000 description 12
- 239000011248 coating agent Substances 0.000 description 11
- 238000005227 gel permeation chromatography Methods 0.000 description 11
- HTZCNXWZYVXIMZ-UHFFFAOYSA-M benzyl(triethyl)azanium;chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC1=CC=CC=C1 HTZCNXWZYVXIMZ-UHFFFAOYSA-M 0.000 description 10
- 239000010453 quartz Substances 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 239000000758 substrate Substances 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 9
- 230000005284 excitation Effects 0.000 description 9
- 239000004593 Epoxy Substances 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 239000000178 monomer Substances 0.000 description 8
- 239000004793 Polystyrene Substances 0.000 description 7
- 229920002223 polystyrene Polymers 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000010992 reflux Methods 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 4
- 229910052761 rare earth metal Inorganic materials 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- XGWFJBFNAQHLEF-UHFFFAOYSA-N 9-anthroic acid Chemical compound C1=CC=C2C(C(=O)O)=C(C=CC=C3)C3=CC2=C1 XGWFJBFNAQHLEF-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 3
- NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 description 2
- VXIXUWQIVKSKSA-UHFFFAOYSA-N 4-hydroxycoumarin Chemical compound C1=CC=CC2=C1OC(=O)C=C2O VXIXUWQIVKSKSA-UHFFFAOYSA-N 0.000 description 2
- CFNMUZCFSDMZPQ-GHXNOFRVSA-N 7-[(z)-3-methyl-4-(4-methyl-5-oxo-2h-furan-2-yl)but-2-enoxy]chromen-2-one Chemical compound C=1C=C2C=CC(=O)OC2=CC=1OC/C=C(/C)CC1OC(=O)C(C)=C1 CFNMUZCFSDMZPQ-GHXNOFRVSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920003270 Cymel® Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910021417 amorphous silicon Inorganic materials 0.000 description 2
- 229930003836 cresol Natural products 0.000 description 2
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 2
- VEZUQRBDRNJBJY-UHFFFAOYSA-N cyclohexanone oxime Chemical compound ON=C1CCCCC1 VEZUQRBDRNJBJY-UHFFFAOYSA-N 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- AOGQPLXWSUTHQB-UHFFFAOYSA-N hexyl acetate Chemical compound CCCCCCOC(C)=O AOGQPLXWSUTHQB-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 2
- 239000003566 sealing material Substances 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- JHNRZXQVBKRYKN-VQHVLOKHSA-N (ne)-n-(1-phenylethylidene)hydroxylamine Chemical compound O\N=C(/C)C1=CC=CC=C1 JHNRZXQVBKRYKN-VQHVLOKHSA-N 0.000 description 1
- MCEKOERWHIKDFW-UHFFFAOYSA-N 1,1,3,3-tetrakis(butoxymethyl)urea Chemical compound CCCCOCN(COCCCC)C(=O)N(COCCCC)COCCCC MCEKOERWHIKDFW-UHFFFAOYSA-N 0.000 description 1
- NNOZGCICXAYKLW-UHFFFAOYSA-N 1,2-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC=C1C(C)(C)N=C=O NNOZGCICXAYKLW-UHFFFAOYSA-N 0.000 description 1
- XGQJGMGAMHFMAO-UHFFFAOYSA-N 1,3,4,6-tetrakis(methoxymethyl)-3a,6a-dihydroimidazo[4,5-d]imidazole-2,5-dione Chemical compound COCN1C(=O)N(COC)C2C1N(COC)C(=O)N2COC XGQJGMGAMHFMAO-UHFFFAOYSA-N 0.000 description 1
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 1
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- RZRJYURCNBXIST-UHFFFAOYSA-N 2-anthroic acid Chemical compound C1=CC=CC2=CC3=CC(C(=O)O)=CC=C3C=C21 RZRJYURCNBXIST-UHFFFAOYSA-N 0.000 description 1
- JYBJXKVJBAHQNF-UHFFFAOYSA-N 2-ethenylanthracene Chemical compound C1=CC=CC2=CC3=CC(C=C)=CC=C3C=C21 JYBJXKVJBAHQNF-UHFFFAOYSA-N 0.000 description 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- SBBQDUFLZGOASY-OWOJBTEDSA-N 4-[(e)-2-(4-carboxyphenyl)ethenyl]benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1\C=C\C1=CC=C(C(O)=O)C=C1 SBBQDUFLZGOASY-OWOJBTEDSA-N 0.000 description 1
- MGKOJZBNNSRXRO-UHFFFAOYSA-N 6-(n-methylanilino)naphthalene-2-sulfonic acid Chemical compound C=1C=C2C=C(S(O)(=O)=O)C=CC2=CC=1N(C)C1=CC=CC=C1 MGKOJZBNNSRXRO-UHFFFAOYSA-N 0.000 description 1
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 1
- CJIJXIFQYOPWTF-UHFFFAOYSA-N 7-hydroxycoumarin Natural products O1C(=O)C=CC2=CC(O)=CC=C21 CJIJXIFQYOPWTF-UHFFFAOYSA-N 0.000 description 1
- OGOYZCQQQFAGRI-UHFFFAOYSA-N 9-ethenylanthracene Chemical compound C1=CC=C2C(C=C)=C(C=CC=C3)C3=CC2=C1 OGOYZCQQQFAGRI-UHFFFAOYSA-N 0.000 description 1
- HTPXFGUCAUTOEL-UHFFFAOYSA-N 9h-fluorene-1-carboxylic acid Chemical compound C1C2=CC=CC=C2C2=C1C(C(=O)O)=CC=C2 HTPXFGUCAUTOEL-UHFFFAOYSA-N 0.000 description 1
- DNVJGJUGFFYUPT-UHFFFAOYSA-N 9h-fluorene-9-carboxylic acid Chemical compound C1=CC=C2C(C(=O)O)C3=CC=CC=C3C2=C1 DNVJGJUGFFYUPT-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- YKTKWLUPBJBDEI-UHFFFAOYSA-M C(=O)N(C)C.O.[Br-].[Li+] Chemical compound C(=O)N(C)C.O.[Br-].[Li+] YKTKWLUPBJBDEI-UHFFFAOYSA-M 0.000 description 1
- YNDZLBYYUYXQED-UHFFFAOYSA-N CC=C.C(COCCO)O Chemical group CC=C.C(COCCO)O YNDZLBYYUYXQED-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000001089 [(2R)-oxolan-2-yl]methanol Substances 0.000 description 1
- ZDGWGNDTQZGISB-UHFFFAOYSA-N acetic acid;perchloric acid Chemical compound CC(O)=O.OCl(=O)(=O)=O ZDGWGNDTQZGISB-UHFFFAOYSA-N 0.000 description 1
- PXAJQJMDEXJWFB-UHFFFAOYSA-N acetone oxime Chemical compound CC(C)=NO PXAJQJMDEXJWFB-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- JCJNNHDZTLRSGN-UHFFFAOYSA-N anthracen-9-ylmethanol Chemical compound C1=CC=C2C(CO)=C(C=CC=C3)C3=CC2=C1 JCJNNHDZTLRSGN-UHFFFAOYSA-N 0.000 description 1
- 150000001454 anthracenes Chemical class 0.000 description 1
- MNFORVFSTILPAW-UHFFFAOYSA-N azetidin-2-one Chemical compound O=C1CCN1 MNFORVFSTILPAW-UHFFFAOYSA-N 0.000 description 1
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 229920001429 chelating resin Polymers 0.000 description 1
- VYXSBFYARXAAKO-WTKGSRSZSA-N chembl402140 Chemical compound Cl.C1=2C=C(C)C(NCC)=CC=2OC2=C\C(=N/CC)C(C)=CC2=C1C1=CC=CC=C1C(=O)OCC VYXSBFYARXAAKO-WTKGSRSZSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006059 cover glass Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- BEPAFCGSDWSTEL-UHFFFAOYSA-N dimethyl malonate Chemical compound COC(=O)CC(=O)OC BEPAFCGSDWSTEL-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- ZBQZBWKNGDEDOA-UHFFFAOYSA-N eosin B Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC([N+]([O-])=O)=C(O)C(Br)=C1OC1=C2C=C([N+]([O-])=O)C(O)=C1Br ZBQZBWKNGDEDOA-UHFFFAOYSA-N 0.000 description 1
- SEACYXSIPDVVMV-UHFFFAOYSA-L eosin Y Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 SEACYXSIPDVVMV-UHFFFAOYSA-L 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- AFMVESZOYKHDBJ-UHFFFAOYSA-N fluoren-9-ol Chemical compound C1=CC=C2C(O)C3=CC=CC=C3C2=C1 AFMVESZOYKHDBJ-UHFFFAOYSA-N 0.000 description 1
- MHMNJMPURVTYEJ-UHFFFAOYSA-N fluorescein-5-isothiocyanate Chemical compound O1C(=O)C2=CC(N=C=S)=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 MHMNJMPURVTYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- DNYZBFWKVMKMRM-UHFFFAOYSA-N n-benzhydrylidenehydroxylamine Chemical class C=1C=CC=CC=1C(=NO)C1=CC=CC=C1 DNYZBFWKVMKMRM-UHFFFAOYSA-N 0.000 description 1
- WHIVNJATOVLWBW-UHFFFAOYSA-N n-butan-2-ylidenehydroxylamine Chemical compound CCC(C)=NO WHIVNJATOVLWBW-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- CLYVDMAATCIVBF-UHFFFAOYSA-N pigment red 224 Chemical compound C=12C3=CC=C(C(OC4=O)=O)C2=C4C=CC=1C1=CC=C2C(=O)OC(=O)C4=CC=C3C1=C42 CLYVDMAATCIVBF-UHFFFAOYSA-N 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 239000002096 quantum dot Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229940043267 rhodamine b Drugs 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 1
- BSYVTEYKTMYBMK-UHFFFAOYSA-N tetrahydrofurfuryl alcohol Chemical compound OCC1CCCO1 BSYVTEYKTMYBMK-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- ORHBXUUXSCNDEV-UHFFFAOYSA-N umbelliferone Chemical compound C1=CC(=O)OC2=CC(O)=CC=C21 ORHBXUUXSCNDEV-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/054—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means
- H01L31/055—Optical elements directly associated or integrated with the PV cell, e.g. light-reflecting means or light-concentrating means where light is absorbed and re-emitted at a different wavelength by the optical element directly associated or integrated with the PV cell, e.g. by using luminescent material, fluorescent concentrators or up-conversion arrangements
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
- C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/10—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/14—Macromolecular compounds
- C09K2211/1408—Carbocyclic compounds
- C09K2211/1416—Condensed systems
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/14—Macromolecular compounds
- C09K2211/1441—Heterocyclic
- C09K2211/145—Heterocyclic containing oxygen as the only heteroatom
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/52—PV systems with concentrators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/542—Dye sensitized solar cells
Definitions
- the present invention relates to a composition for forming a wavelength conversion film provided in a photoelectric conversion device, for example, a solar cell, in which the conversion efficiency from light energy to electric power is improved. Moreover, it is related with the wavelength conversion film formed using the said composition.
- photoelectric conversion for example, an ultraviolet light region
- photoelectric conversion for example, a visible light region
- Japanese Patent Laid-Open No. 7-142752 Japanese Patent Laid-Open No. 9-230396 JP 2000-313877 A JP 2001-308365 A JP 2003-243682 A JP 2004-297025 A JP 2006-173545 A JP 2006-269373 A JP 2006-303033 A JP 2007-265629 A
- Patent Document 1 a solar cell having a wavelength conversion function proposed so far has a wavelength conversion substance, that is, a film in which a phosphor is dispersed.
- Patent Document 1 suggests a wavelength conversion layer made of the wavelength conversion material and a wavelength conversion layer made of another material (transparent resin or the like) in which one or more wavelength conversion materials are dispersed.
- the wavelength conversion layers in which the former N-methyl-2-anilino-naphthalene-6-sulfonic acid is dispersed in polymethyl methacrylate or a P-type silicon layer are described, There is no specific description that a wavelength conversion layer made of a wavelength conversion substance is manufactured.
- a film having a wavelength conversion function in which phosphors are dispersed has a problem that if the phosphor is excessively introduced in order to enhance the effect of wavelength conversion, the film may be deteriorated due to aggregation or the like, and uniform dispersion in the film is difficult. Problems such as becoming. Furthermore, when rare earth elements or rare earth complexes such as europium (Eu) and terbium (Tb) are used as phosphors, there is a problem of rising prices due to the recent increase in demand for rare earth compounds and the uneven distribution of resources, realizing a low cost. May be difficult.
- Eu europium
- Tb terbium
- An object of the present invention is to obtain a composition for forming a wavelength conversion film for a photoelectric conversion device that can be expected to improve the photoelectric conversion efficiency by wavelength conversion and that can also realize low cost. Furthermore, this invention aims at provision of a photoelectric conversion apparatus provided with the wavelength conversion film for photoelectric conversion apparatuses formed from the said composition, and this conversion film.
- the present invention is a wavelength conversion film forming composition for a photoelectric conversion device, which contains a polymer or oligomer having a fluorescent site (fluorescence generating site) and a solvent.
- the fluorescent site of the polymer or oligomer contained in the wavelength conversion film-forming composition according to the present invention is introduced into the main chain or side chain of the polymer or oligomer, specifically, anthracene or a derivative thereof. , Coumarin or derivatives thereof, fluorescein or derivatives thereof, rhodamine, eosin, perylene or derivatives thereof, fluorene or derivatives thereof, or stilbene or derivatives thereof.
- Examples of the polymer or oligomer contained in the wavelength conversion film forming composition according to the present invention include acrylic resin, methacrylic resin, novolac resin, aminoplast polymer, polyamide, polyimide, polyester, polyfluorene, polyfluorene derivative, polysiloxane, Polysilane or polycarbosilane may be mentioned.
- the number average molecular weight Mn of the polymer or oligomer is, for example, in the range of 500 to 50,000.
- Solvents contained in the wavelength conversion film forming composition according to the present invention include propylene glycol monomethyl ether acetate (PGMEA), propylene glycol monomethyl ether (PGME), propylene glycol monoethyl ether, ethyl lactate, cyclohexanone, cyclohexanol, and ⁇ -butyrolactone.
- PGMEA propylene glycol monomethyl ether acetate
- PGME propylene glycol monomethyl ether
- PGME propylene glycol monoethyl ether
- ethyl lactate propylene glycol monoethyl ether
- cyclohexanone cyclohexanol
- ⁇ -butyrolactone ⁇ -butyrolactone
- NMP N-methyl-2-pyrrolidone
- the solvent may be a combination of two or more organic solvents.
- the ratio of the solid content to the composition is, for example, 3 to 40% by mass, preferably 7 to 30% by mass.
- the polymer or oligomer contained in the wavelength conversion film forming composition according to the present invention may further have a crosslinking site.
- the crosslinking site include a hydroxy group, a carboxyl group, an epoxy group, an amino group, a silanol group, and an alkynyl group.
- the wavelength conversion film forming composition according to the present invention may further contain a crosslinking agent.
- crosslinking agent examples include hexamethoxymethylmelamine, tetramethoxymethylbenzoguanamine, 1,3,4,6-tetrakis (methoxymethyl) glycoluril, 1,3,4,6-tetrakis (butoxymethyl) glycoluril, 1,3 , 4,6-tetrakis (hydroxymethyl) glycoluril, 1,3-bis (hydroxymethyl) urea, 1,1,3,3-tetrakis (butoxymethyl) urea, 1,1,3,3-tetrakis (methoxy) Methyl) urea, blocked isocyanate (4,4′-diphenylmethane diisocyanate, polymethylene polyphenyl polyisocyanate, tolylene diisocyanate, hexamethylene diisocyanate, isophorone diisocyanate, tetramethylxylylene diisocyanate, etc., methanol, Alcohols such as ethanol, propanol, isopropyl
- the wavelength conversion film forming composition according to the present invention may further contain an antioxidant and / or a radical scavenger as an additive.
- an antioxidant and / or a radical scavenger as an additive.
- a known compound can be applied to both the antioxidant and the radical scavenger, and the stability of the polymer or oligomer can be improved when the stability (particularly heat resistance and light resistance) is insufficient.
- These additives may or may not be used in combination with a crosslinking agent, and may or may not be used in combination with a polymer or oligomer having a crosslinking site.
- this invention also makes object the wavelength conversion film for photoelectric conversion apparatuses formed from the said wavelength conversion film formation composition.
- the wavelength conversion film according to the present invention can be easily formed by various coating methods such as spin coating, spraying, and dipping, and is formed at a relatively low temperature of about 160 ° C. (eg, 100 ° C. to 220 ° C.). A membrane is possible.
- the wavelength conversion film for a photoelectric conversion device thus obtained can be applied to a solar cell.
- a wavelength conversion film can also be obtained by applying the wavelength conversion film forming composition according to the present invention to a film that is a base material.
- a wavelength conversion film can also be formed by extending
- the composition for forming a wavelength conversion film for a photoelectric conversion device of the present invention does not use a rare earth compound, it becomes possible to provide a wavelength conversion film for a photoelectric conversion device at a low cost, and thus, the photoelectric conversion efficiency of a solar cell can be reduced at a low cost. Improvement can be expected.
- the film in which the wavelength converting substance (phosphor) is dispersed the film is formed using a polymer or oligomer in which the fluorescent site (fluorescence generating site) is chemically bonded, thereby replacing the fluorescent site. While more (fluorescence generation site) can be introduced into the film, the stability of the formed wavelength conversion film is improved. Furthermore, it can be expected to further improve the photoelectric conversion efficiency of various solar cells by selecting an appropriate fluorescent site.
- FIGS. 1A to 1D are diagrams showing application examples of a wavelength conversion film formed from the wavelength conversion film forming composition according to the present invention in a silicon-based solar cell.
- Examples of the polymer or oligomer contained in the wavelength conversion film-forming composition according to the present invention include acrylic resin, methacrylic resin, novolac resin, aminoplast polymer, polyamide, polyimide, and polyester.
- the novolak resin may be either a phenol novolak or a cresol novolak.
- polyfluorene or a derivative thereof, polysiloxane, polysilane, or polycarbosilane may be used as the polymer or oligomer.
- Examples of the fluorescent site (fluorescence generating site) of the polymer or oligomer include anthracene or a derivative thereof (2-anthracenecarboxylic acid, 9-anthracenecarboxylic acid, 2-vinylanthracene, 9-vinylanthracene, 9-hydroxymethylanthracene, etc.), Coumarin or derivatives thereof (4-hydroxycoumarin, 7-hydroxycoumarin etc.), fluorescein or derivatives thereof (fluorescein isothiocyanate etc.), rhodamine (rhodamine B, rhodamine 6G etc.), eosin (eosin-Y, eosin-B etc.), Perylene or a derivative thereof (3,4,9,10-perylenetetracarboxylic dianhydride, etc.), fluorene or a derivative thereof (9-fluorenol, 1-fluorenecarboxylic acid, 9-fluorenecarboxylic acid,
- the fluorescent site (fluorescence generating site) is introduced into the side chain of the polymer or oligomer, for example, but may be contained in the main chain of the polymer or oligomer.
- Introduction of a fluorescent site (fluorescence generating site) into a polymer or oligomer side chain can be performed, for example, by graft polymerization.
- the introduction ratio of the fluorescent moiety is not particularly limited, and may be an arbitrary ratio exceeding 0 mol% with respect to the polymer or oligomer.
- the wavelength conversion film according to the present invention has a function of converting a wavelength that does not contribute to photoelectric conversion into a wavelength that contributes to photoelectric conversion. Specifically, the wavelength conversion film according to the present invention converts a certain wavelength to a longer wavelength, for example, a wavelength shorter than 370 nm to a wavelength of 370 nm or more. In particular, the wavelength in the ultraviolet region (10 nm to 365 nm) is converted to the wavelength in the visible region (370 nm to 800 nm). In addition, the range of the wavelength which contributes to photoelectric conversion changes with the kind of solar cell, for example, even if it is a silicon-type solar cell, it changes with the crystal
- the amorphous silicon solar cell has a thickness of about 400 nm to about 700 nm, and the polycrystalline silicon solar cell has a thickness of about 600 nm to about 1100 nm. Therefore, the wavelength contributing to photoelectric conversion is not necessarily the wavelength in the visible light region.
- the solar cell to which the wavelength conversion film according to the present invention is applied is not limited to a specific type.
- organic solar cells such as solar cells, organic thin film solar cells, dye-sensitized solar cells, and quantum dot solar cells.
- positioning aspect is not specifically limited but is arbitrary.
- the average molecular weight of the polymer shown in the present specification is a measurement result by gel permeation chromatography (hereinafter abbreviated as GPC).
- GPC gel permeation chromatography
- the epoxy value shown in this specification is a measurement result by titration.
- the equipment and conditions used are as follows.
- Titration reagent 0.1 mol / L
- Solvent Propylene glycol monomethyl ether
- Example 1 2.16 g of propylene glycol monomethyl ether acetate and 1.08 g of N, N-dimethylformamide were added as solvents to 1.00 g of the polymer obtained in Synthesis Example 2. This solution was applied onto a quartz substrate by a spinner and then baked on a hot plate at 205 ° C. for 1 minute. Using a spectrofluorophotometer F-7000 (manufactured by Hitachi High-Technologies Corporation), the fluorescence of the coating film obtained by baking was measured and found to have an excitation wavelength of 365 nm and a fluorescence wavelength of 450 nm.
- Example 2 As a solvent, 2.16 g of propylene glycol monomethyl ether acetate and 1.08 g of N, N-dimethylformamide were added to 1.00 g of the polymer obtained in Synthesis Example 3. This solution was applied onto a quartz substrate by a spinner and then baked on a hot plate at 205 ° C. for 1 minute. Using a spectrofluorimeter F-7000 (manufactured by Hitachi High-Technologies Corporation), the fluorescence of the coating film obtained by baking was measured, and the excitation wavelength was 276 nm and the fluorescence wavelength was 370 nm.
- F-7000 manufactured by Hitachi High-Technologies Corporation
- Example 3 As a solvent, 2.16 g of propylene glycol monomethyl ether acetate and 1.08 g of N, N-dimethylformamide were added to 1.00 g of the polymer obtained in Synthesis Example 4. This solution was applied onto a quartz substrate by a spinner and then baked on a hot plate at 205 ° C. for 1 minute. Using a spectrofluorimeter F-7000 (manufactured by Hitachi High-Technologies Corporation), the fluorescence of the coating film obtained by baking was measured, and the excitation wavelength was 322 nm and the fluorescence wavelength was 388 nm.
- Example 4 As a solvent, 2.16 g of propylene glycol monomethyl ether acetate and 1.08 g of N, N-dimethylformamide were added to 1.00 g of the polymer obtained in Synthesis Example 5. This solution was applied onto a quartz substrate by a spinner and then baked on a hot plate at 205 ° C. for 1 minute. Using a spectrofluorimeter F-7000 (manufactured by Hitachi High-Technologies Corporation), the fluorescence of the coating film obtained by baking was measured, and the excitation wavelength was 565 nm and the fluorescence wavelength was 587 nm.
- a spectrofluorimeter F-7000 manufactured by Hitachi High-Technologies Corporation
- Example 5 2.16 g of propylene glycol monomethyl ether acetate and 1.08 g of N, N-dimethylformamide were added as solvents to 1.00 g of the polymer obtained in Synthesis Example 6. This solution was applied onto a quartz substrate by a spinner and then baked on a hot plate at 205 ° C. for 1 minute. Using a spectrofluorimeter F-7000 (manufactured by Hitachi High-Technologies Corporation), the fluorescence of the coating film obtained by baking was measured, and the excitation wavelength was 360 nm and the fluorescence wavelength was 526 nm.
- F-7000 manufactured by Hitachi High-Technologies Corporation
- Example 6 As a solvent, 5.00 g of propylene glycol monomethyl ether acetate was added to 5.00 g of the solution containing the polymer described in Synthesis Example 7. This solution was applied onto a quartz substrate by a spinner and then baked on a hot plate at 205 ° C. for 1 minute. When the fluorescence of this coating film was measured using a spectrofluorometer F-7000 (manufactured by Hitachi High-Technologies Corporation), the excitation wavelength was 366 nm and the fluorescence wavelength was 465 nm.
- Example 7 5.00 g of propylene glycol monomethyl ether acetate was added as a solvent to 5.00 g of the solution containing the polymer described in Synthesis Example 8. This solution was applied onto a quartz substrate by a spinner and then baked on a hot plate at 205 ° C. for 1 minute. When the fluorescence of this coating film was measured using a spectrofluorimeter F-7000 (manufactured by Hitachi High-Technologies Corporation), the excitation wavelength was 325 nm and the fluorescence wavelength was 460 nm.
- Example 8 5.00 g of propylene glycol monomethyl ether acetate was added as a solvent to 5.00 g of the solution containing the polymer described in Synthesis Example 9. This solution was applied onto a quartz substrate by a spinner and then baked on a hot plate at 205 ° C. for 1 minute. When the fluorescence of this coating film was measured using a spectrofluorometer F-7000 (manufactured by Hitachi High-Technologies Corporation), the excitation wavelength was 260 nm and the fluorescence wavelength was 390 nm.
- Example 9 5.00 g of propylene glycol monomethyl ether acetate was added as a solvent to 5.00 g of the solution containing the polymer or oligomer obtained in Synthesis Example 10. This solution was applied onto a quartz substrate by a spinner and then baked on a hot plate at 205 ° C. for 1 minute. When the fluorescence of this coating film was measured using a spectrofluorometer F-7000 (manufactured by Hitachi High-Technologies Corporation), the excitation wavelength was 263 nm and the fluorescence wavelength was 296 nm.
- the coating films formed in each of the above examples all have a wavelength conversion function, they are useful as wavelength conversion films provided in photoelectric conversion devices (solar cells). Furthermore, the solar cell provided with the wavelength conversion film is expected to improve the photoelectric conversion efficiency. For example, since the coating films formed in Examples 1, 3, 6, 7, and 8 can convert the wavelength of the ultraviolet light region into the wavelength of the visible light region, the sensitivity in the ultraviolet light region is low, and the visible light region. It is useful for solar cells with high sensitivity.
- FIG. 1A An example in which a wavelength conversion film according to the present invention is provided in a silicon-based solar cell is shown in FIG.
- a p-layer 102, an n-layer 103, and an antireflection film 104 are stacked over a back electrode 101, a surface electrode 105 is formed in connection with the n-layer 103, and a cover material 106 is further provided.
- 2 shows a cross-sectional structure of a solar cell.
- a sealing material (not shown) is further provided between the front electrode 105 and the antireflection film 104 and the cover material 106, and a sealing material and a back sheet (not shown) are further provided outside the back electrode 101.
- a total reflection layer may be provided on the outside of the backsheet.
- the surface electrode 105 is also expressed as a light receiving surface electrode.
- the cover material 106 is made of glass or resin, and in the former case is called a cover glass.
- the wavelength conversion film 100 is provided between the n layer 103 and the antireflection film 104.
- FIG. 1B is an example different from FIG. 1A in that the wavelength conversion film 100 is provided between the antireflection film 104 and the cover material 106.
- the cover material 106 may be omitted (see FIG. 1C).
- the cover member 106 with the wavelength conversion film 100 may be detachable.
- the wavelength conversion film 100 having a function as a cover material may be detachable.
- FIG. 1D is an example different from FIGS. 1A to 1C in that the wavelength conversion film 100 is provided on the cover material 106. Further, the cover member 106 with the wavelength conversion film 100 may be detachable.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Photovoltaic Devices (AREA)
Abstract
Description
本発明は、波長変換による光電変換効率の向上が期待でき、しかも、低コストの実現をも図れる光電変換装置用波長変換膜形成組成物を得ることを目的とする。さらに本発明は、上記組成物より形成された光電変換装置用波長変換膜並びに該変換膜を備える光電変換装置の提供を目的とする。
本発明に係る波長変換膜形成組成物は、さらに架橋剤を含むこともできる。架橋部位を有すること又は架橋剤を用いることにより、前記ポリマー又はオリゴマーの安定性(特に耐熱性、耐光性)が不十分である場合に、架橋により、その安定性を向上させることができる。架橋剤として、例えばヘキサメトキシメチルメラミン、テトラメトキシメチルベンゾグアナミン、1,3,4,6-テトラキス(メトキシメチル)グリコールウリル、1,3,4,6-テトラキス(ブトキシメチル)グリコールウリル、1,3,4,6-テトラキス(ヒドロキシメチル)グリコールウリル、1,3-ビス(ヒドロキシメチル)尿素、1,1,3,3-テトラキス(ブトキシメチル)尿素、1,1,3,3-テトラキス(メトキシメチル)尿素、ブロックイソシアネート(4,4’-ジフェニルメタンジイソシアネート、ポリメチレンポリフェニルポリイソシアネート、トリレンジイソシアネート、ヘキサメチレンジイソシアネート、イソホロンジイソシアネート、テトラメチルキシリレンジイソシアネートなどをメタノール、エタノール、プロパノール、イソプロピルアルコール、ブタノール、2-エチルヘキサノール、シクロヘキサノール等のアルコール類、フェノール類、マロン酸ジメチル、アセト酢酸エチル等の活性メチレン類、メチルエチルケトンオキシム、アセトンオキシム、シクロヘキサノンオキシム、アセトフェノンオキシム、ベンゾフェノンオキシム等のオキシム類、ε-カプロラクタム、γ-カプロラクタム、β-プロピオラクタム等のラクタム類により保護した化合物)が挙げられる。
こうして得られた上記光電変換装置用波長変換膜は太陽電池に適用可能である。
さらに、基材であるフィルムに本発明に係る波長変換膜形成組成物を塗布することにより、波長変換フィルムを得ることもできる。
また、本発明に係る波長変換膜形成組成物を原料として、延伸等により波長変換フィルムを形成することもできる。
また、波長変換物質(蛍光体)を分散させた膜に代えて、蛍光部位(蛍光発生部位)が化学的に結合したポリマー又はオリゴマーを用いて膜を形成させることにより、蛍光体に代わる蛍光部位(蛍光発生部位)をより多く膜中に導入することができるとともに、形成される波長変換膜の安定性が向上する。さらに、適切な蛍光部位を選択することによって、各種太陽電池の光電変換効率をさらに向上させることが期待できる。
・合成例1乃至6及び9
GPC装置:HLC-8220GPC(東ソー(株)製)
GPCカラム:Asahipak〔登録商標〕GF510HQ(昭和電工(株)製)
カラム温度:40℃
溶媒:10mmol/L 臭化リチウム一水和物 ジメチルホルムアミド(DMF)溶液
流量:0.6ml/分
標準試料:ポリスチレン(昭和電工(株)製)
・合成例7、8及び10
GPC装置:HLC-8220GPC(東ソー(株)製)
GPCカラム:Shodex〔登録商標〕KF803L,KF802,KF801(昭和電工(株)製)
カラム温度:40℃
溶媒:テトラヒドロフラン(THF)
流量:1.0ml/分
標準試料:ポリスチレン(昭和電工(株)製)
使用する装置、条件等は次のとおりである。
滴定装置:自動滴定装置GT-100(三菱化学(株)製)
滴定試薬:0.1mol/L 過塩素酸 酢酸溶液
溶媒:プロピレングリコールモノメチルエーテル
窒素置換した反応容器中に式(1):
合成例1で得たポリマー3.00gに対し、アントラセン誘導体の一種である式(2):
合成例1で得たポリマー3.00gに対し、クマリン誘導体の一種である式(3):
合成例1で得たポリマー3.00gに対し、クマリン誘導体の一種である式(4):
合成例1で得たポリマー3.00gに対し、ローダミンの一種である式(5):
合成例1で得たポリマー3.00gに対し、フルオレセインである式(6):
式(7)で表される、構造単位E及び構造単位BをE:B=0.65:0.35のモル比率で有する共重合体であるポリマーを含む溶液を用意した。当該ポリマーのGPCによる平均分子量は、標準ポリスチレン換算で重量平均分子量36,000であった。
式(8)で表される構造単位を有するポリマーを含む溶液を用意した。当該ポリマーのGPCによる平均分子量は、標準ポリスチレン換算で重量平均分子量6,100、数平均分子量2,700であった。
式(9a)で表されるCYMEL〔登録商標〕303(ヘキサメトキシメチルメラミン)及び式(9b)で表されるCYMEL〔登録商標〕1123(テトラメトキシメチルベンゾグアナミン)(以上、サイテック・インダズトリーズ社)を用い、特表2003-531252号公報に記載の実施例3(調剤I)にしたがって得られた、ポリマーを含む溶液を用意した。当該ポリマーはアミノプラスト重合体の一種であり、GPCによる平均分子量は、標準ポリスチレン換算で重量平均分子量11,000、数平均分子量2,200であった。本合成例におけるポリマーにおいて、式(9b)に由来するベンゾグアナミン構造単位が蛍光部位であると推定される。
陽イオン交換樹脂(商品名:アンバーリスト15JWET、ローム・アンド・ハース社製)24.80gに対し、式(10)、式(11)、式(12)、式(13):
合成例2で得たポリマー1.00gに対し、溶剤としてプロピレングリコールモノメチルエーテルアセテート2.16g及びN,N-ジメチルホルムアミド1.08gを加えた。この溶液をスピナーにより、石英基板上に塗布した後、ホットプレート上、205℃で1分間ベークした。分光蛍光光度計F-7000((株)日立ハイテクノロジーズ製)を用いて、ベークにより得られた塗膜の蛍光を測定したところ励起波長365nm、蛍光波長450nmであった。
合成例3で得たポリマー1.00gに対し、溶剤としてプロピレングリコールモノメチルエーテルアセテート2.16g及びN,N-ジメチルホルムアミド1.08gを加えた。この溶液をスピナーにより、石英基板上に塗布した後、ホットプレート上、205℃で1分間ベークした。分光蛍光光度計F-7000((株)日立ハイテクノロジーズ製)を用いて、ベークにより得られた塗膜の蛍光を測定したところ励起波長276nm、蛍光波長370nmであった。
合成例4で得たポリマー1.00gに対し、溶剤としてプロピレングリコールモノメチルエーテルアセテート2.16g及びN,N-ジメチルホルムアミド1.08gを加えた。この溶液をスピナーにより、石英基板上に塗布した後、ホットプレート上、205℃で1分間ベークした。分光蛍光光度計F-7000((株)日立ハイテクノロジーズ製)を用いて、ベークにより得られた塗膜の蛍光を測定したところ励起波長322nm、蛍光波長388nmであった。
合成例5で得たポリマー1.00gに対し、溶剤としてプロピレングリコールモノメチルエーテルアセテート2.16g及びN,N-ジメチルホルムアミド1.08gを加えた。この溶液をスピナーにより、石英基板上に塗布した後、ホットプレート上、205℃で1分間ベークした。分光蛍光光度計F-7000((株)日立ハイテクノロジーズ製)を用いて、ベークにより得られた塗膜の蛍光を測定したところ励起波長565nm、蛍光波長587nmであった。
合成例6で得たポリマー1.00gに対し、溶剤としてプロピレングリコールモノメチルエーテルアセテート2.16g及びN,N-ジメチルホルムアミド1.08gを加えた。この溶液をスピナーにより、石英基板上に塗布した後、ホットプレート上、205℃で1分間ベークした。分光蛍光光度計F-7000((株)日立ハイテクノロジーズ製)を用いて、ベークにより得られた塗膜の蛍光を測定したところ励起波長360nm、蛍光波長526nmであった。
合成例7に記載したポリマーを含む溶液5.00gに対し、溶剤としてプロピレングリコールモノメチルエーテルアセテート5.00gを加えた。この溶液をスピナーにより、石英基板上に塗布した後、ホットプレート上、205℃で1分間ベークした。分光蛍光光度計F-7000((株)日立ハイテクノロジーズ製)を用いて、この塗膜の蛍光を測定したところ励起波長366nm、蛍光波長465nmであった。
合成例8に記載したポリマーを含む溶液5.00gに対し、溶剤としてプロピレングリコールモノメチルエーテルアセテート5.00gを加えた。この溶液をスピナーにより、石英基板上に塗布した後、ホットプレート上、205℃で1分間ベークした。分光蛍光光度計F-7000((株)日立ハイテクノロジーズ製)を用いて、この塗膜の蛍光を測定したところ励起波長325nm、蛍光波長460nmであった。
合成例9に記載したポリマーを含む溶液5.00gに対し、溶剤としてプロピレングリコールモノメチルエーテルアセテート5.00gを加えた。この溶液をスピナーにより、石英基板上に塗布した後、ホットプレート上、205℃で1分間ベークした。分光蛍光光度計F-7000((株)日立ハイテクノロジーズ製)を用いて、この塗膜の蛍光を測定したところ励起波長260nm、蛍光波長390nmであった。
合成例10で得たポリマー又はオリゴマーを含む溶液5.00gに対し、溶剤としてプロピレングリコールモノメチルエーテルアセテート5.00gを加えた。この溶液をスピナーにより、石英基板上に塗布した後、ホットプレート上、205℃で1分間ベークした。分光蛍光光度計F-7000((株)日立ハイテクノロジーズ製)を用いて、この塗膜の蛍光を測定したところ励起波長263nm、蛍光波長296nmであった。
合成例1で得たポリマー3.00gに対し、合成例2で用いた式(2):
シリコン系太陽電池に、本発明に係る波長変換膜を設ける例を図1に示す。図1(A)は、裏面電極101上に、p層102、n層103及び反射防止膜104が積層され、n層103と接続して表面電極105が形成され、さらにカバー材106が設けられた太陽電池の断面構造を示す。通常は、表面電極105及び反射防止膜104とカバー材106との間に、さらに図示しない封止材が設けられ、裏面電極101の外側に、さらに図示しない封止材及びバックシートが設けられる。そのバックシートの外側には全反射層が設けられてもよい。表面電極105は、受光面電極とも表現される。カバー材106は、ガラス製又は樹脂製であり、前者の場合カバーガラスと称する。この例では、波長変換膜100は、n層103と反射防止膜104の間に設けられる。
101 裏面電極
102 p層
103 n層
104 反射防止膜
105 表面電極
106 カバー材
Claims (11)
- 蛍光部位を有するポリマー又はオリゴマー及び溶剤を含有する光電変換装置用波長変換膜形成組成物。
- 前記ポリマー又はオリゴマーは、前記蛍光部位が該ポリマー又はオリゴマーの主鎖又は側鎖に導入されたものである、請求項1に記載の光電変換装置用波長変換膜形成組成物。
- 前記蛍光部位は、アントラセン若しくはその誘導体、クマリン若しくはその誘導体、フルオレセイン若しくはその誘導体、ローダミン、エオシン、ペリレン若しくはその誘導体、フルオレン若しくはその誘導体、又はスチルベン若しくはその誘導体である、請求項1又は請求項2に記載の光電変換装置用波長変換膜形成組成物。
- 前記ポリマー又はオリゴマーは、アクリル樹脂、メタクリル樹脂、ノボラック樹脂、アミノプラスト重合体、ポリアミド、ポリイミド、ポリエステル、ポリフルオレン、ポリフルオレン誘導体、ポリシロキサン、ポリシラン、又はポリカルボシランである、請求項1乃至請求項3のいずれか一項に記載の光電変換装置用波長変換膜形成組成物。
- 前記溶剤は、プロピレングリコールモノメチルエーテルアセテート、プロピレングリコールモノメチルエーテル、乳酸エチル、シクロヘキサノン、γ-ブチロラクトン、ジエチレングリコールモノブチルエーテルアセテート、ジエチレングリコールモノブチルエーテル、ジエチレングリコールジブチルエーテル、アセチルアセトン、トルエン及びN,N-ジメチルホルムアミドからなる群から選択される少なくとも1種の有機溶媒である、請求項1乃至請求項4のいずれか一項に記載の光電変換装置用波長変換膜形成組成物。
- 前記ポリマー又はオリゴマーはさらに架橋部位を有する、請求項1乃至請求項5のいずれか一項に記載の光電変換装置用波長変換膜形成組成物。
- さらに架橋剤を含有する、請求項1乃至請求項6のいずれか一項に記載の光電変換装置用波長変換膜形成組成物。
- さらに酸化防止剤及び/又はラジカル捕捉剤を含有する、請求項1乃至請求項7のいずれか一項に記載の光電変換装置用波長変換膜形成組成物。
- 請求項1乃至請求項8のいずれか一項に記載の波長変換膜形成組成物から形成された光電変換装置用波長変換膜。
- 紫外光領域の波長を可視光領域の波長へ変換するために用いられる、請求項9に記載の光電変換装置用波長変換膜。
- 請求項9又は請求項10に記載の光電変換装置用波長変換膜を備えた太陽電池。
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09823576A EP2355162A4 (en) | 2008-10-31 | 2009-10-27 | COMPOSITIONS FOR FORMING WAVELENGTH CONVERSION MEMBRANES FOR PHOTOVOLTAIC DEVICES, WAVELENGTH CONVERTING MEMBRANES FOR PHOTOVOLTAIC DEVICES, AND PHOTOVOLTAIC DEVICES |
CN200980143218XA CN102203951A (zh) | 2008-10-31 | 2009-10-27 | 形成光电转换装置用波长转换膜的组合物、光电转换装置用波长转换膜以及光电转换装置 |
US13/126,675 US20110204292A1 (en) | 2008-10-31 | 2009-10-27 | Compositions for forming wavelength conversion films for photovoltaic devices, wavelength conversion films for photovoltaic devices, and photovoltaic devices |
JP2010535798A JPWO2010050466A1 (ja) | 2008-10-31 | 2009-10-27 | 太陽電池用波長変換膜形成組成物及び太陽電池用波長変換膜並びに太陽電池 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008-281183 | 2008-10-31 | ||
JP2008281183 | 2008-10-31 | ||
JP2009090392 | 2009-04-02 | ||
JP2009-090392 | 2009-04-02 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2010050466A1 true WO2010050466A1 (ja) | 2010-05-06 |
Family
ID=42128827
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2009/068396 WO2010050466A1 (ja) | 2008-10-31 | 2009-10-27 | 光電変換装置用波長変換膜形成組成物及び光電変換装置用波長変換膜並びに光電変換装置 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20110204292A1 (ja) |
EP (1) | EP2355162A4 (ja) |
JP (1) | JPWO2010050466A1 (ja) |
KR (1) | KR20110079904A (ja) |
CN (1) | CN102203951A (ja) |
TW (1) | TW201036176A (ja) |
WO (1) | WO2010050466A1 (ja) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012508992A (ja) * | 2008-11-13 | 2012-04-12 | コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ | 適応性波長変換装置及び太陽電池 |
JP2015513212A (ja) * | 2012-02-01 | 2015-04-30 | 日東電工株式会社 | 太陽光捕集効率を向上させるためのガラスプレート上の波長変換層 |
JP5783384B2 (ja) * | 2010-12-02 | 2015-09-24 | 日産化学工業株式会社 | 膜形成材料 |
JP2015532527A (ja) * | 2012-09-28 | 2015-11-09 | エレクトリシテ・ドゥ・フランス | 高変換効率を有する光起電力構成部品 |
JP2016021430A (ja) * | 2014-07-11 | 2016-02-04 | 大日本印刷株式会社 | 太陽電池モジュール用の封止材シート及びその製造方法 |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5976675B2 (ja) | 2011-01-05 | 2016-08-24 | 日東電工株式会社 | 波長変換ペリレンジエステル発色団および発光膜 |
CN105418582A (zh) | 2011-09-26 | 2016-03-23 | 日东电工株式会社 | 用于提高的日光采集效率的高荧光且光稳定性生色团 |
JP2013084952A (ja) | 2011-10-05 | 2013-05-09 | Nitto Denko Corp | 太陽光捕集効率を向上させるための、感圧接着剤層を含む波長変換膜 |
CN107463066B (zh) * | 2011-10-11 | 2020-10-30 | 日产化学工业株式会社 | 形成固化膜的组合物、取向材及相位差材 |
EP2788450B1 (en) | 2011-12-06 | 2017-06-21 | Nitto Denko Corporation | Wavelength conversion material as encapsulant for solar module systems to enhance solar harvesting efficiency |
WO2013172930A1 (en) * | 2012-05-15 | 2013-11-21 | Illinois Tool Works Inc. | Replaceable solar wavelength - converting film |
KR101638106B1 (ko) * | 2014-07-02 | 2016-07-11 | 충남대학교 산학협력단 | 형광 가교 폴리(n-아이소프로필 아크릴아마이드) 마이크로젤, 이의 제조방법 및 이를 포함하는 센서 |
TWI516520B (zh) | 2014-10-31 | 2016-01-11 | 財團法人工業技術研究院 | 波長轉換聚合物、其製法及包含其之波長轉換裝置 |
CN108624046B (zh) * | 2017-03-24 | 2021-05-25 | 张家港康得新光电材料有限公司 | 聚酰亚胺组合物、聚酰亚胺膜及其制备方法和应用 |
CN110407970A (zh) * | 2019-07-19 | 2019-11-05 | 深圳市华星光电技术有限公司 | 罗丹明类染料单体低聚合物的制备方法、纯色材料及液晶显示装置 |
Citations (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07142752A (ja) | 1993-06-16 | 1995-06-02 | Nikon Corp | 波長変換機能を有する太陽電池 |
JPH08157815A (ja) * | 1994-12-01 | 1996-06-18 | Chisso Corp | 白色発光素子 |
JPH09230396A (ja) | 1996-02-26 | 1997-09-05 | Kinya Adachi | 希土類錯体複合発光材料を用いる光変調増感型太陽電池の製造 |
JP2000313877A (ja) | 1999-04-28 | 2000-11-14 | Sumitomo Osaka Cement Co Ltd | 蛍光性透明膜と、この蛍光性透明膜を用いた太陽電池 |
JP2001308365A (ja) | 2000-04-20 | 2001-11-02 | Sumitomo Osaka Cement Co Ltd | 太陽電池 |
JP2003243682A (ja) | 2002-02-19 | 2003-08-29 | Sumitomo Bakelite Co Ltd | 太陽電池 |
JP2003531252A (ja) | 2000-04-19 | 2003-10-21 | ブルーワー サイエンス アイ エヌ シー. | アミノプラスト重合物を含む改良された反射防止コーティング組成物 |
JP2004083563A (ja) * | 2002-05-10 | 2004-03-18 | Nissan Chem Ind Ltd | ポリ(5−アミノキノキサリン)及びその利用 |
JP2004297025A (ja) | 2003-03-27 | 2004-10-21 | Science Univ Of Tokyo | 高効率太陽電池 |
WO2005042621A1 (ja) * | 2003-10-30 | 2005-05-12 | Nissan Chemical Industries, Ltd. | 電荷輸送性化合物、電荷輸送性材料、電荷輸送性ワニス、電荷輸送性薄膜及び有機エレクトロルミネッセンス素子 |
JP2005239790A (ja) * | 2004-02-24 | 2005-09-08 | Sanyo Electric Co Ltd | 有機エレクトロルミネッセント素子用有機材料及び有機エレクトロルミネッセント素子 |
JP2006024791A (ja) * | 2004-07-08 | 2006-01-26 | International Manufacturing & Engineering Services Co Ltd | 有機素子、有機エレクトロルミネッセント素子、及び有機太陽電池 |
JP2006173545A (ja) | 2004-12-13 | 2006-06-29 | Sc Technology Kk | 希土類ドープCaF2層を有する太陽電池構造及び太陽電池モジュール構造 |
JP2006269373A (ja) | 2005-03-25 | 2006-10-05 | Osaka Univ | 色素増感太陽電池 |
JP2006303033A (ja) | 2005-04-18 | 2006-11-02 | National Institute Of Advanced Industrial & Technology | 太陽電池モジュール |
JP2007026629A (ja) | 2004-12-28 | 2007-02-01 | Sharp Corp | 微細パターンの形成方法及び光メモリ素子用原盤の製造方法、並びに光メモリ素子用原盤、光メモリ素子用スタンパ及び光メモリ素子 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1141147A (en) * | 1964-12-22 | 1969-01-29 | Dainichiseika Color Chem | Fluorescent copolymers |
SU1728253A1 (ru) * | 1989-04-27 | 1992-04-23 | Научно-исследовательский физико-химический институт им.Л.Я.Карпова | Сшитые флуоресцирующие сополимеры |
EA001312B1 (ru) * | 1995-12-01 | 2001-02-26 | Вантико Аг | Поли/9,9'-спиробисфторены/, их получение и применение |
US6822069B2 (en) * | 2002-05-10 | 2004-11-23 | Nissan Chemical Industries, Ltd. | Poly (5-aminoquinoxalines) and use thereof |
US6894105B2 (en) * | 2002-07-26 | 2005-05-17 | 3M Innovatives Properties Company | Dyed fluoropolymers |
KR100794527B1 (ko) * | 2006-07-05 | 2008-01-17 | 연세대학교 산학협력단 | 광활성 방향족 중합체 및 이의 제조방법 |
-
2009
- 2009-10-27 JP JP2010535798A patent/JPWO2010050466A1/ja active Pending
- 2009-10-27 WO PCT/JP2009/068396 patent/WO2010050466A1/ja active Application Filing
- 2009-10-27 CN CN200980143218XA patent/CN102203951A/zh active Pending
- 2009-10-27 EP EP09823576A patent/EP2355162A4/en not_active Withdrawn
- 2009-10-27 KR KR1020117011591A patent/KR20110079904A/ko not_active Application Discontinuation
- 2009-10-27 US US13/126,675 patent/US20110204292A1/en not_active Abandoned
- 2009-10-30 TW TW098136985A patent/TW201036176A/zh unknown
Patent Citations (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07142752A (ja) | 1993-06-16 | 1995-06-02 | Nikon Corp | 波長変換機能を有する太陽電池 |
JPH08157815A (ja) * | 1994-12-01 | 1996-06-18 | Chisso Corp | 白色発光素子 |
JPH09230396A (ja) | 1996-02-26 | 1997-09-05 | Kinya Adachi | 希土類錯体複合発光材料を用いる光変調増感型太陽電池の製造 |
JP2000313877A (ja) | 1999-04-28 | 2000-11-14 | Sumitomo Osaka Cement Co Ltd | 蛍光性透明膜と、この蛍光性透明膜を用いた太陽電池 |
JP2003531252A (ja) | 2000-04-19 | 2003-10-21 | ブルーワー サイエンス アイ エヌ シー. | アミノプラスト重合物を含む改良された反射防止コーティング組成物 |
JP2001308365A (ja) | 2000-04-20 | 2001-11-02 | Sumitomo Osaka Cement Co Ltd | 太陽電池 |
JP2003243682A (ja) | 2002-02-19 | 2003-08-29 | Sumitomo Bakelite Co Ltd | 太陽電池 |
JP2004083563A (ja) * | 2002-05-10 | 2004-03-18 | Nissan Chem Ind Ltd | ポリ(5−アミノキノキサリン)及びその利用 |
JP2004297025A (ja) | 2003-03-27 | 2004-10-21 | Science Univ Of Tokyo | 高効率太陽電池 |
WO2005042621A1 (ja) * | 2003-10-30 | 2005-05-12 | Nissan Chemical Industries, Ltd. | 電荷輸送性化合物、電荷輸送性材料、電荷輸送性ワニス、電荷輸送性薄膜及び有機エレクトロルミネッセンス素子 |
JP2005239790A (ja) * | 2004-02-24 | 2005-09-08 | Sanyo Electric Co Ltd | 有機エレクトロルミネッセント素子用有機材料及び有機エレクトロルミネッセント素子 |
JP2006024791A (ja) * | 2004-07-08 | 2006-01-26 | International Manufacturing & Engineering Services Co Ltd | 有機素子、有機エレクトロルミネッセント素子、及び有機太陽電池 |
JP2006173545A (ja) | 2004-12-13 | 2006-06-29 | Sc Technology Kk | 希土類ドープCaF2層を有する太陽電池構造及び太陽電池モジュール構造 |
JP2007026629A (ja) | 2004-12-28 | 2007-02-01 | Sharp Corp | 微細パターンの形成方法及び光メモリ素子用原盤の製造方法、並びに光メモリ素子用原盤、光メモリ素子用スタンパ及び光メモリ素子 |
JP2006269373A (ja) | 2005-03-25 | 2006-10-05 | Osaka Univ | 色素増感太陽電池 |
JP2006303033A (ja) | 2005-04-18 | 2006-11-02 | National Institute Of Advanced Industrial & Technology | 太陽電池モジュール |
Non-Patent Citations (1)
Title |
---|
See also references of EP2355162A4 * |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012508992A (ja) * | 2008-11-13 | 2012-04-12 | コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ | 適応性波長変換装置及び太陽電池 |
US9911884B2 (en) | 2008-11-13 | 2018-03-06 | Philips Lighting Holding B.V. | Device for adaptable wavelength conversion and a solar cell |
JP5783384B2 (ja) * | 2010-12-02 | 2015-09-24 | 日産化学工業株式会社 | 膜形成材料 |
JP2015513212A (ja) * | 2012-02-01 | 2015-04-30 | 日東電工株式会社 | 太陽光捕集効率を向上させるためのガラスプレート上の波長変換層 |
JP2015532527A (ja) * | 2012-09-28 | 2015-11-09 | エレクトリシテ・ドゥ・フランス | 高変換効率を有する光起電力構成部品 |
JP2016021430A (ja) * | 2014-07-11 | 2016-02-04 | 大日本印刷株式会社 | 太陽電池モジュール用の封止材シート及びその製造方法 |
Also Published As
Publication number | Publication date |
---|---|
US20110204292A1 (en) | 2011-08-25 |
TW201036176A (en) | 2010-10-01 |
KR20110079904A (ko) | 2011-07-11 |
CN102203951A (zh) | 2011-09-28 |
EP2355162A4 (en) | 2012-08-22 |
JPWO2010050466A1 (ja) | 2012-03-29 |
EP2355162A1 (en) | 2011-08-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2010050466A1 (ja) | 光電変換装置用波長変換膜形成組成物及び光電変換装置用波長変換膜並びに光電変換装置 | |
US10862038B2 (en) | Compositions comprising at least one polymer and at least one salt, and electroluminescent devices containing said compositions | |
CN103154138B (zh) | 成膜用组合物 | |
CN102459415A (zh) | 含三嗪环的聚合物及包含其的成膜组合物 | |
US9147626B2 (en) | Resin for transparent encapsulation material, and associated encapsulation material and electronic device | |
CN107674201A (zh) | 含三嗪环的聚合物和含有其的成膜组合物 | |
US20120043555A1 (en) | Liquid fluorescent composition and light emitting device | |
CN103781821A (zh) | 聚合物和含有该聚合物的组合物以及粘合剂用组合物 | |
TW201037001A (en) | Polyimide resin, curable resin composition and cured product | |
US10505061B2 (en) | Wavelength-conversion encapsulant composition, wavelength-converted encapsulant layer, and solar cell module using same | |
CN111279229B (zh) | 颜色转换面板及其制造方法 | |
EP2358765B1 (en) | Imidized polymers containing luminescent groups and method for obtaining them | |
JP2012533661A (ja) | 電子素子のための材料 | |
CN103339533B (zh) | 形成膜的材料 | |
TWI523869B (zh) | 膜形成材料 | |
TWI795154B (zh) | 光電轉換化合物及包括其之光電轉換組成物 | |
CN103649213B (zh) | 树脂组合物 | |
WO2015064688A1 (ja) | 波長変換型封止材組成物、波長変換型封止材層、および、それを用いた太陽電池モジュール | |
Kang et al. | White electroluminescence from bicarbazyl-containing conjugated polymers as single-emitting component | |
JP2016115852A (ja) | 太陽電池モジュール | |
WO2011093148A1 (ja) | 絶縁膜形成用組成物及び絶縁膜 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200980143218.X Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 09823576 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2010535798 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 13126675 Country of ref document: US |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 20117011591 Country of ref document: KR Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2009823576 Country of ref document: EP |