WO2009144952A1 - 二剤式泡状染毛剤 - Google Patents
二剤式泡状染毛剤 Download PDFInfo
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- WO2009144952A1 WO2009144952A1 PCT/JP2009/002383 JP2009002383W WO2009144952A1 WO 2009144952 A1 WO2009144952 A1 WO 2009144952A1 JP 2009002383 W JP2009002383 W JP 2009002383W WO 2009144952 A1 WO2009144952 A1 WO 2009144952A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/415—Aminophenols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
Definitions
- the present invention relates to a two-component foam hair dye.
- a two-component foam hair dye is a hair dyeing operation that is easily performed by discharging a mixture of a first agent containing an alkali agent and an oxidative dye and a second agent containing an oxidizer into a foam.
- a high hair dyeing effect can be obtained by a single treatment compared with a one-component foam hair dye.
- aerosol type two-component foam hair dye is liable to cause decoloration unevenness and dyeing unevenness, metal pressure resistant container etc. is oxidized and corroded by hydrogen peroxide, internal pressure of pressure resistant container by decomposition of hydrogen peroxide Has the problem of rising excessively.
- Patent Documents 1 to 6 there has been proposed one in which a two-component hair dye is discharged in a foam form from a non-aerosol-type former container. These can be applied to the hair without any unevenness by discharging the mixed liquid of the first agent and the second agent from the former container in the form of foam, and color unevenness does not occur in the finish. It is useful for eliminating the level difference.
- an oxidative dye may be blended at a high concentration, and among oxidative dyes, an oxidative dye having a phenolic hydroxyl group is required to prepare various colors. It is an important oxidation dye.
- the present invention includes a first agent containing an alkali agent, a second agent containing hydrogen peroxide, and a non-aerosol foamer container for discharging a mixture of the first agent and the second agent in the form of foam.
- a foam-type hair dye which contains the components (A), (B) and (C1) in the first agent and may contain the component (C2).
- a two-component foam hair dye in which the total concentration of components (C1) and (C2) is 0.16 to 0.50 mol / kg, and the viscosity of the mixed solution at 25 ° C. is 1 to 300 mPa ⁇ s. .
- A Water-soluble cationic polymer
- B Alkali metal ion 0.20 to 2.00 mol / kg
- C1 Oxidative dye having phenolic hydroxyl group 0.05mol / kg or more
- the first agent of the non-aerosol type two-component foam hair dye contains a water-soluble cationic polymer and an oxidative dye having a high concentration of phenolic hydroxyl group
- the water-soluble cationic polymer is combined with the oxidative dye. It has now been found that forming a complex between the two causes the following problems. 1) The formation of a complex in the first agent impairs its storage stability. 2) Since the complex is also present in the mixed solution of the first agent and the second agent, a non-aerosol Dischargeability from the former container will deteriorate
- the present invention contains a water-soluble cationic polymer and an oxidation dye having a high concentration of phenolic hydroxyl group, the storage stability and the dischargeability of the mixed liquid from the non-aerosol foamer container are good.
- the present invention relates to a two-component foam hair dye.
- alkali metal ions that is a component that is known to suppress the swelling of the hair (for example, "Chemical and physical behavior of human hair 4 th. Edition ,” published in 2002, Clarence R. Robbins al., Springer- Verlag Hew York, Inc., page 436).
- the hair dyeing property is improved by including a component that suppresses swelling such as alkali metal ions. It was surprising that
- alkaline agent As the alkaline agent contained in the first agent, for example, ammonia, alkanolamines such as monoethanolamine, sodium hydroxide, potassium hydroxide and the like can be used.
- ammonium salts such as ammonium hydrogen carbonate, ammonium carbonate, and ammonium chloride, carbonates such as potassium carbonate, sodium hydrogen carbonate, and the like can be appropriately added as a buffering agent.
- the pH of the mixed solution of the first agent and the second agent in the two-component foam hair dye of the present invention is preferably 8 to 11, more preferably 8.5 to 10.5.
- the amount of the alkaline agent used is such that the pH of the mixed solution is It adjusts suitably so that it may become the above.
- the content of hydrogen peroxide in the second agent is preferably 1 to 9% by mass, more preferably 3 to 6% by mass.
- the content of hydrogen peroxide in the mixed solution of the first agent and the second agent is preferably 1 to 6% by mass, more preferably 2 to 5% by mass.
- the pH of the second agent is preferably 2 to 6, and more preferably 2.5 to 4 in order to suppress decomposition of hydrogen peroxide during storage.
- the two-component foam hair dye of the present invention contains a water-soluble cationic polymer in at least the first agent.
- the water-soluble cationic polymer refers to a water-soluble polymer having a cationic group or a group that can be ionized to a cationic group, and includes an amphoteric polymer that becomes cationic as a whole.
- the water-soluble cationic polymer includes an amino group or an ammonium group in the side chain of the polymer chain, or a water-soluble one containing a diallyl quaternary ammonium salt as a constituent unit, such as cationized cellulose, cationic starch, Examples thereof include cationized guar gum, a polymer or copolymer of diallyl quaternary ammonium salt, and quaternized polyvinyl pyrrolidone.
- diallyl quaternary ammonium salt examples include dimethyldiallylammonium chloride polymer (polyquaternium-6, such as Marquat 100; Nalco), dimethyldiallylammonium chloride / acrylic acid copolymer (polyquaternium- 22, eg, Marquat 280, 295; Nalco), dimethyldiallylammonium chloride / acrylamide copolymer (polyquaternium-7, eg, Marquat 550; Nalco); acrylic acid / diallyl quaternary ammonium salt / acrylamide copolymer ( Polyquaternium-39 such as Marquat Plus 3331 (Nalco).
- Polyquaternium-39 such as Marquat Plus 3331 (Nalco).
- quaternized polyvinylpyrrolidone examples include a quaternary ammonium salt (polyquaternium-11 such as Guffcoat 734, 755, and 755N) obtained from a copolymer of vinylpyrrolidone (VP) and dimethylaminoethyl methacrylate and diethyl sulfate. ; IS Japan Co., Ltd.).
- polyquaternium-11 such as Guffcoat 734, 755, and 755N
- the cationized cellulose include a polymer of a quaternary ammonium salt obtained by adding glycidyltrimethylammonium chloride to hydroxyethyl cellulose (polyquaternium-10 such as Leogard G, GP; Lion Corporation, polymer JR-125, JR-400, JR-30M, LR-400, LR-30M; Amerchol), hydroxyethylcellulose / dimethyldiallylammonium chloride copolymer (Polyquaternium-4, eg Cellcoat H-100, L-200; National Starch and Chemical Co.).
- polyquaternium-10 such as Leogard G, GP; Lion Corporation, polymer JR-125, JR-400, JR-30M, LR-400, LR-30M
- Amerchol hydroxyethylcellulose / dimethyldiallylammonium chloride copolymer
- Polyquaternium-4 eg Cellcoat H-100, L-200; National Starch and Chemical Co.
- polyquaternium-4, polyquaternium-6, polyquaternium-7, polyquaternium-22, polyquaternium-39 is preferable, and polyquaternium-6, polyquaternium-7, Polyquaternium-22 and polyquaternium-39 are preferable, and polyquaternium-22 is particularly preferable.
- the water-soluble cationic polymer of component (A) can be used in combination of two or more, and the content thereof is from the viewpoint of good foaming, prevention of dripping and good dischargeability from the former container.
- the amount is preferably 0.02 to 6% by mass, more preferably 0.1 to 4% by mass, and further preferably 0.2 to 3% by mass in one agent.
- the two-component foam hair dye of the present invention contains an alkali metal ion in at least the first agent from the viewpoint of good storage stability of the first agent.
- alkali metal ions form a complex between the water-soluble cationic polymer of component (A) and the oxidation dye having a phenolic hydroxyl group of component (C1) or the anionic surfactant of component (C2). And has the function of improving the storage stability of the first agent and the dischargeability of the mixed liquid.
- the presence of alkali metal ions in a hair dye is considered to reduce hair dyeing performance, but in the present invention, it has extremely excellent hair dyeing properties.
- alkali metal ion source in addition to salts such as sodium chloride, potassium chloride, sodium sulfate, sodium sulfite, sodium hydroxide, potassium hydroxide, tetrasodium edetate, and the anionic surfactant of the component (C2) described later A counter ion is mentioned.
- component (B) Two or more types of alkali metal ions of component (B) can be used in combination, and the content (ion conversion amount) is between component (A) and component (C1) or component (C2). From the viewpoint of effectively suppressing the formation of the complex, it is 0.20 to 2.00 mol / kg in the first agent, preferably 0.30 to 1.50 mol / kg, more preferably 0.40 to 1.00 mol / kg.
- the first agent of the two-component foam hair dye of the present invention contains an oxidation dye having a phenolic hydroxyl group as the component (C1).
- the oxidation dye having a phenolic hydroxyl group of component (C1) forms a complex with the water-soluble cationic polymer of component (A). This causes the storage stability of one agent and the dischargeability of the mixed solution to deteriorate.
- the presence of a specific concentration of alkali metal ions as the component (B) suppresses the formation of the complex, and good storage.
- oxidation dyes include dye precursors such as paraaminophenol, 4-amino-3-methylphenol, 6-amino-3-methylphenol and orthoaminophenol, resorcin, 2-methylresorcin, metaaminophenol, 5
- couplers such as -aminoorthocresol, 5- (2-hydroxyethylamino) -2-methylphenol, and 1-naphthol.
- the content of the oxidation dye having a phenolic hydroxyl group as the component (C1) is 0.05 mol / kg or more in the first agent, preferably 0.055 to 0.45 mol. / kg, more preferably 0.06 to 0.40 mol / kg.
- the two-component foam hair dye of the present invention may contain an oxidative dye or a direct dye other than the component (C1).
- oxidation dyes other than the component (C1) paraphenylenediamine, toluene-2,5-diamine, N, N-bis (2-hydroxyethyl) paraphenylenediamine, 2- (2-hydroxyethyl) paraphenylenediamine
- dye precursors such as 1-hydroxyethyl-4,5-diaminopyrazole, and couplers such as metaphenylenediamine and 2,4-diaminophenoxyethanol.
- the direct dye include paranitroorthophenylenediamine, paranitrometaphenylenediamine, basic yellow 87, basic orange 31, basic red 12, basic red 51, basic blue 99, and acid orange 7.
- the first agent or the second agent, or Both contain a surfactant.
- a surfactant an anionic surfactant as an ingredient (C2), an amphoteric surfactant, a nonionic surfactant is used in order to realize good foaming that is easy to apply to hair even when the liquid temperature is low or close to room temperature.
- a surfactant is preferred.
- anionic surfactant of component (C2) examples include alkyl sulfates and polyoxyalkylene alkyl sulfates, and those having an alkyl group of 10 to 24 carbon atoms, more preferably 12 to 18 carbon atoms are preferable.
- the alkyl group is a straight chain.
- polyoxyalkylene alkyl sulfates, more preferably polyoxyethylene alkyl sulfates are preferable, and those having an average addition mole number of oxyethylene groups of 1 to 10, and more preferably 2 to 5 are particularly preferable.
- the anionic surfactant of component IV (C2) forms a complex with the water-soluble cationic polymer of component (A) in the same manner as the oxidation dye having a phenolic hydroxyl group of component (C1) and preserves the first agent.
- the presence of a specific concentration of alkali metal ions as a component (B) suppresses the formation of a complex, which is a good cause. Demonstrates storage stability and dischargeability from the former container.
- Two or more anionic surfactants of component (C2) can be used in combination, and the content thereof is preferably 0 to 0.45 mol / kg, more preferably 0.001 to 0.40 mol / kg, Is preferably 0.01 to 0.30 mol / kg.
- the total concentration of component (C1) and component (C2) in the first agent is 0.16 to 0.50 mol / kg, preferably 0.17 to 0.45 mol / kg, more preferably 0.18 to 0.40 mol / kg. It is.
- Amphoteric surfactants include carbobetaines, amidebetaines, sulfobetaines, hydroxysulfobetaines, amidesulfobetaines, phosphobetaines, imidazo having 8 to 24 carbon atoms, alkyl groups, alkenyl groups or acyl groups. Examples thereof include linium-based surfactants, and among them, carbobetaine-based surfactants and sulfobetaine-based surfactants are preferable.
- Preferred amphoteric surfactants include lauric acid amidopropyl betaine, coconut oil fatty acid amidopropyl betaine, lauryldimethylaminoacetic acid betaine, lauryl hydroxysulfobetaine and the like.
- the content of the first agent and the second agent in the mixed solution is preferably 0.001 to 5% by mass, more preferably 0.002 to 2.5% by mass, Is preferably 0.003 to 1% by mass.
- nonionic surfactant examples include alkyl polyglucoside, polyoxyalkylene alkyl ether, alkyl glyceryl ether and the like.
- alkyl polyglucoside those in which the alkyl group has 8 to 18 carbon atoms, more preferably 8 to 14 carbon atoms, and further 9 to 11 carbon atoms are preferable, and those in which the alkyl group is linear are preferable.
- the average degree of polymerization of glucoside is preferably 1 to 5, more preferably 1 to 2.
- polyoxyalkylene alkyl ether those in which the alkyl group has 10 to 22 carbon atoms, more preferably 12 to 18 carbon atoms, are preferred, and those in which the alkyl group is linear are preferred.
- Polyoxyethylene alkyl ethers are more preferable, and those having an average addition mole number of oxyethylene groups of 1 to 40, more preferably 4 to 30, are particularly preferable.
- the alkyl glyceryl ether those in which the alkyl group has 8 to 18 carbon atoms, more preferably 8 to 12 carbon atoms, are preferred, and those in which the alkyl group is branched are preferred.
- Two or more nonionic surfactants can be used in combination.
- the content of the first agent and the second agent in the mixed solution is preferably 0.1 to 20% by mass, more preferably 0.2 to 15% by mass, 0.3 to 10% by mass is preferable.
- the two-component foam hair dye of the present invention can contain a higher alcohol in order to improve foaming and enhance the effect of suppressing dripping after being left on the hair.
- a higher alcohol those having an alkyl group or alkenyl group having 10 to 30, more preferably 12 to 24, more preferably 14 to 22 carbon atoms are preferable, and those having an alkyl group and further a linear alkyl group are preferred.
- the higher alcohol include myristyl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, isostearyl alcohol, oleyl alcohol and the like. Two or more of these can be used in combination.
- Two or more types of higher alcohols can be used in combination, and can be contained in one or both of the first agent and the second agent.
- the content of the higher alcohol in the mixed liquid of the first agent and the second agent does not inhibit the foaming property when the liquid temperature is low, and enhances the effect of suppressing dripping while standing, It is 0.01 to 0.8% by mass, preferably 0.1 to 0.7% by mass, and further 0.2 to 0.6% by mass.
- Non-volatile hydrophilic solvent Furthermore, it is preferable to contain a non-volatile hydrophilic solvent in the first agent or the second agent. As a result, after applying the two-component foam hair dye of the present invention to the hair and leaving it to stand, moisture evaporates from the hair dye to concentrate irritating components such as hydrogen peroxide. Can reduce irritation to the scalp.
- the non-volatile hydrophilic solvent those having no defoaming action such as polyols and lower (1 to 4 carbon atoms) alkyl ethers thereof are preferable.
- polyols those having 2 to 6 carbon atoms are preferable, and examples thereof include glycerin, propylene glycol, dipropylene glycol, 1,3-butanediol, ethylene glycol, diethylene glycol, isoprene glycol, sorbitol and the like.
- the lower alkyl ethers of the polyol include mono-lower alkyl ethers and poly-lower alkyl ethers (for example, di-lower alkyl ethers) of the above-described polyols.
- monomethyl ether or monoethyl ether of polyol is preferable, and specific examples include ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol monomethyl ether, and diethylene glycol monoethyl ether. Two or more of these can be used in combination.
- the content of the non-volatile hydrophilic solvent in the mixture of the first agent and the second agent is 0.01 to 5 mass from the viewpoint of reducing the scalp irritation and improving the foam quality even when the liquid temperature is low. %, More preferably 0.1 to 4% by mass, and further preferably 0.2 to 3% by mass.
- the two-component foam hair dye of the present invention may further contain silicones.
- silicones include dimethylpolysiloxane, methylphenylpolysiloxane, polyether-modified silicone, amino-modified silicone, oxazoline-modified silicone elastomer, and the like, and emulsions in which these are dispersed in water using a surfactant.
- polyether-modified silicones, amino-modified silicones, and emulsions thereof are preferable because they can be stably dispersed in water without using a thickener.
- the polyether-modified silicone includes terminal-modified and side-chain-modified types such as a pendant type (comb type), a both-end modified type, and a one-end modified type.
- modified silicones include dimethylsiloxane / methyl (polyoxyethylene) siloxane copolymer, dimethylsiloxane / methyl (polyoxypropylene) siloxane copolymer, dimethylsiloxane / methyl (polyoxyethylene / polyoxypropylene) siloxane.
- a copolymer etc. are mentioned.
- the polyether-modified silicone those having an HLB of 10 or more, and further having an HLB of 10 to 18 are preferable from the viewpoint of compatibility with water.
- HLB is based on the value obtained from the cloud number (cloud number: an index correlated with HLB and applied to ether type nonionic surfactants).
- the amino-modified silicone is not particularly limited as long as it has an amino group or an ammonium group, but amodimethicone is preferable.
- the content of silicones in the mixed solution of the first agent and the second agent is preferably 0.01 to 10% by mass in order to make the foam smoothly fit into the hair and to give a high conditioning effect to the hair. It is preferably 0.1 to 5% by mass, more preferably 0.5 to 3% by mass.
- the first agent and the second agent are fragrances, ultraviolet absorbers, sequestering agents such as edetic acid, bactericides, preservatives such as methyl parahydroxybenzoate, phenacetin, 1-hydroxyethane-1 , 1-diphosphonic acid, a stabilizer such as oxyquinoline sulfate, an organic solvent such as ethanol, benzyl alcohol and benzyloxyethanol, a water-soluble polymer compound such as hydroxyethyl cellulose, a humectant, and the like.
- the mixed liquid of the first agent and the second agent is preferably water as a main medium.
- the oxidative hair dye composition of the present invention is provided as a two-component oxidative hair dye containing a first agent containing an alkaline agent and a second agent containing hydrogen peroxide.
- the two-part formula means a three-part oxidative hair dye which is used by further mixing a third part containing a persulfate or a third part containing a conditioning component in addition to the first and second parts.
- Agents should also be included.
- the mixing ratio of the first agent and the second agent is preferably 1: 4 to 4: 1 by mass ratio, more preferably 1: 2: to 2: 1.
- the viscosity of the mixed solution of the first agent and the second agent is 1 to 300 mPa ⁇ s, preferably 2 to 200 mPa ⁇ s, more preferably 3 to 100 mPa ⁇ s, and further preferably 5 to 30 mPa ⁇ s. .
- the viscosity here is a value after rotating at 60 rpm for 1 minute using a rotor No. 1 or No. 2 with a B-type rotational viscometer (model TV-10) manufactured by Tokimec Co., Ltd. at 25 ° C. To do.
- the object to be measured is less than 100 mPa ⁇ s, use rotor No.
- the viscosity of the mixed solution of the first agent and the second agent By adjusting the viscosity of the mixed solution of the first agent and the second agent to be in the above range, it is possible to realize a foam volume that is easy to apply, and to prevent dripping after the mixed solution is applied to the hair. In addition to being able to suppress, it becomes easy to squeeze when discharging bubbles with a squeeze foamer or the like.
- a water-soluble solvent such as ethanol may be added, or the content and type of surfactants, polyols, higher alcohols, and the like may be appropriately adjusted.
- the gas / liquid mixing ratio of air and liquid mixture by the foam discharge means of the former container is preferably 7 to 40 mL / g, more preferably 15 to 30 mL / g from the viewpoint of ease of application of the agent to the hair and ease of application. preferable.
- the gas-liquid mixing ratio here is a value measured as follows.
- the gas-liquid mixing ratio is obtained by measuring the mass and volume of the foam discharged at 25 ° C. Put 100g of liquid mixture into S1 squeeze foamer container (Daiwa Seisakusha, volume 210mL, mesh roughness (mesh) is 150 mesh per mixing chamber (150 mesh per 1 inch (25.4mm)), tip 200 mesh) From the time when the remaining amount is 80 g, 20 g of foam is discharged into a 1000 mL measuring cylinder, and the volume of the foam is measured 1 minute after the start of discharge. The gas-liquid mixing ratio (mL / g) is obtained by dividing the volume (mL) of the discharged foam by the mass of 20 g.
- the former container is a non-aerosol type container, and is used for mixing the liquid mixture of the first agent and the second agent with air without using a propellant and ejecting it in the form of foam. .
- a non-aerosol type container can manufacture a product at a lower cost than an aerosol type container and does not require a propellant for high-pressure gas, so that the product can be handled more safely in distribution.
- non-aerosol foamer container a known pump foamer container having a foam discharge means, a squeeze foamer container, an electric foamer, a pressure accumulating pump former container, or the like can be used. More specifically, for example, pump former E3 type, F2 type [above, Daiwa Steel, Food and Containers (vol.35, No.10, p588-593 (1994); vol.35, No. 11, p624 to 627 (1994); vol.36, No.3, p154 to 158 (1995))], S1 squeeze former (Yamato Seisakusha, JP 7-215352 A), electric whisk (Matsushita) Electric industry), air spray former (air spray international company), and the like.
- a pump former container and a squeeze foamer container are preferable because they are inexpensive and easy to use.
- a pump former container or a squeeze foamer container has a foam-generating part such as a net, and when the liquid mixture of one agent and two agents is dried and solidified to cause clogging, bubbles are generated at the next discharge. It is preferable to have a thin-walled net because the solidified material can be immediately dissolved by this flow to eliminate clogging.
- the net mesh is preferably 50 to 280 mesh, more preferably 90 to 250 mesh, and more preferably 130 to 220 mesh.
- the mesh means the number of eyes per inch.
- Examples of the material of such a net include nylon, polyethylene, polypropylene, polyester, Teflon (registered trademark), carbon fiber, stainless steel, and the like, more preferably nylon, polyethylene, polypropylene, polyester, and more. Nylon is preferable.
- At least one, preferably a plurality of such nets are disposed, from the viewpoints of economy, foam stability, and the like.
- One sheet is preferably provided at each of the two locations of the mixing chamber and the tip.
- the parts that come into contact with the contents are not corroded by alkali and hydrogen peroxide, and the material through which oxygen generated by the decomposition of hydrogen peroxide permeates. It is preferable to comprise.
- the first agent or the second agent is a container separate from the non-aerosol foamer container, respectively.
- the two agents may be transferred to a non-aerosol foamer container and mixed at the time of use, but one agent is filled in a non-aerosol foamer container and the other agent is filled in a separate container. In use, the other agent may be transferred into a non-aerosol foamer container.
- the second agent is a gas-permeable container, particularly an oxygen-permeable material (for example, polyethylene) in order to prevent the pressure in the container from rising due to oxygen generated by the decomposition of hydrogen peroxide.
- the non-aerosol foamer container is preferably filled.
- the first agent needs to use a container that does not easily transmit oxygen.
- the two-component foam hair dye of the present invention is mixed with the first agent and the second agent in a non-aerosol foamer container.
- the foamy liquid mixture discharged from the container may be applied directly to the hair, or may be applied to the hair using a tool such as a hand or a brush. From the viewpoint of preventing the agent from splashing and dripping, it is more preferable to apply it to the hair after taking it once in a hand (with gloves).
- the time of foaming again may be after the foam has completely disappeared, in the middle of disappearance of the foam, or before the applied foam changes. Or it may be in the middle of application, even after it completes application to the whole range which wants to apply foam.
- Foaming again may be performed once continuously or may be repeated a plurality of times intermittently.
- Examples 1 to 9 and Comparative Examples 1 to 6 The 1st agent and 2nd agent of the compounding composition (mass%) shown in Table 1, 3 and 5 were prepared, and the evaluation shown below was performed.
- Foaming ⁇ Extremely uniform and fine foam ⁇ : Uniform and fine foam ⁇ : Uneven and coarse foam ⁇ : Cannot be completely foamed, mixed with moisture
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Abstract
Description
(A)水溶性カチオン性ポリマー
(B)アルカリ金属イオン 0.20~2.00mol/kg
(C1)フェノール性水酸基を有する酸化染料 0.05mol/kg以上
(C2)アニオン界面活性剤
1)第1剤中にコンプレックスが形成されることにより、その保存安定性が損なわれること
2)第1剤と第2剤との混合液中にもコンプレックスが存在することになるため、非エアゾールフォーマー容器からの吐出性が悪くなってしまうこと
第1剤が含有するアルカリ剤としては、例えば、アンモニア、モノエタノールアミン等のアルカノールアミン、水酸化ナトリウム、水酸化カリウム等を使用することができる。また、適宜、緩衝剤として、炭酸水素アンモニウム、炭酸アンモニウム、塩化アンモニウム等のアンモニウム塩や、炭酸カリウム、炭酸水素ナトリウム等の炭酸塩などを添加することができる。
第2剤中の過酸化水素の含有量は、1~9質量%、更には3~6質量%が好ましい。第1剤と第2剤の混合液中における過酸化水素の含有量は、1~6質量%、更には2~5質量%が好ましい。また、第2剤のpHは、保存中の過酸化水素の分解抑制のため、2~6、更にはpH2.5~4とすることが好ましい。
本発明の二剤式泡状染毛剤は、少なくとも第1剤に水溶性カチオン性ポリマーを含有する。水溶性カチオン性ポリマーとは、カチオン基又はカチオン基にイオン化され得る基を有する水溶性のポリマーをいい、全体としてカチオン性となる両性ポリマーも含まれる。すなわち、水溶性カチオン性ポリマーとしては、ポリマー鎖の側鎖にアミノ基又はアンモニウム基を含むか、又はジアリル4級アンモニウム塩を構成単位として含む水溶性のもの、例えばカチオン化セルロース、カチオン性澱粉、カチオン化グアーガム、ジアリル4級アンモニウム塩の重合体又は共重合体、4級化ポリビニルピロリドン等が挙げられる。
本発明の二剤式泡状染毛剤は、第1剤の良好な保存安定性の点から、少なくとも第1剤にアルカリ金属イオンを含有する。本発明において、アルカリ金属イオンは、成分(A)の水溶性カチオン性ポリマーと成分(C1)のフェノール性水酸基を有する酸化染料や成分(C2)のアニオン界面活性剤との間でのコンプレックスの形成を抑制し、第1剤の保存安定性、混合液の吐出性を向上させる機能を有する。一般に、染毛剤においてアルカリ金属イオンの存在は、染毛性能を低下させるものとされているが、本発明においては、極めて優れた染毛性を有する。
本発明の二剤式泡状染毛剤の第1剤は、成分(C1)としてフェノール性水酸基を有する酸化染料を含有する。前述のとおり、成分(C1)のフェノール性水酸基を有する酸化染料は、成分(A)の水溶性カチオン性ポリマーとの間でコンプレックスを形成するため、これを高濃度に含有する場合には、第1剤の保存安定性や、混合液の吐出性が悪くなる原因となる。しかし、本発明においては、かかる成分(C1)を高濃度に含有するにもかかわらず、成分 (B)として特定濃度のアルカリ金属イオンを共存させることにより、コンプレックスの形成が抑制され、良好な保存安定性とフォーマー容器からの吐出性を発揮する。このような酸化染料としては、パラアミノフェノール、4-アミノ-3-メチルフェノール、6-アミノ-3-メチルフェノール、オルトアミノフェノール等の染料前駆体、レゾルシン、2-メチルレゾルシン、メタアミノフェノール、5-アミノオルトクレゾール、5-(2-ヒドロキシエチルアミノ)-2-メチルフェノール、1-ナフトール等のカップラーが挙げられる。
フォーマー容器の泡吐出手段によって空気と毛髪化粧料が混合されることで容易に泡が形成され、かつその泡が安定となるようにするため、第1剤と第2剤のいずれか一方、又は両方に界面活性剤を含有させる。界面活性剤としては、液温が低い時でも常温に近い時でも毛髪に塗布しやすい良好な泡立ちを実現するために、成分(C2)としてのアニオン界面活性剤や、両性界面活性剤、非イオン界面活性剤が好ましい。
本発明の二剤式泡状染毛剤には、泡もちを良くし、毛髪に塗布した後、放置している間の液だれを抑制する効果を高めるため、高級アルコールを含有させることができる。高級アルコールとしては、炭素数が10~30、更には12~24、更には14~22のアルキル基又はアルケニル基を有するものが好ましく、なかでもアルキル基、更には直鎖アルキル基を有するものが好ましい。高級アルコールとしては、例えば、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、ベヘニルアルコール、イソステアリルアルコール、オレイルアルコール等が挙げられる。これらは、二種以上を併用することができる。
更に、第1剤又は第2剤中に不揮発性親水性溶剤を含有することが好ましい。これにより、本発明の二剤式泡状染毛剤を毛髪に塗布した後、放置している間に、染毛剤から水分が蒸発して過酸化水素等の刺激性の成分が濃縮されることによる頭皮に対する刺激を軽減することができる。不揮発性親水性溶剤としては、ポリオール類やその低級(炭素数1~4)アルキルエーテル類などの消泡作用のないものが好ましい。ポリオール類としては、炭素数2~6のものが好ましく、例えば、グリセリン、プロピレングリコール、ジプロピレングリコール、1,3-ブタンジオール、エチレングリコール、ジエチレングリコール、イソプレングリコール、ソルビトール等が挙げられる。ポリオールの低級アルキルエーテル類としては、前掲のポリオールのモノ低級アルキルエーテルやポリ低級アルキルエーテル(例えば、ジ低級アルキルエーテル)などが挙げられる。なかでもポリオールのモノメチルエーテル又はモノエチルエーテルが好ましく、具体的には、エチレングリコールモノメチルエーテル、エチレングリコールモノエチルエーテル、ジエチレングリコールモノメチルエーテル、ジエチレングリコールモノエチルエーテルが挙げられる。これらは、二種以上を併用することができる。
本発明の二剤式泡状染毛剤には、更にシリコーン類を含有させることができる。シリコーン類としては、ジメチルポリシロキサン、メチルフェニルポリシロキサン、ポリエーテル変性シリコーン、アミノ変性シリコーン、オキサゾリン変性シリコーンエラストマー等、及びこれらを界面活性剤により水中に分散させたエマルションが挙げられる。これらのうち、増粘剤を用いることなく安定に水中に分散可能な点から、ポリエーテル変性シリコーン、アミノ変性シリコーン及びこれらのエマルションが好ましい。
その他、第1剤及び第2剤は、目的に応じて、香料、紫外線吸収剤、エデト酸等の金属封鎖剤、殺菌剤、パラオキシ安息香酸メチル等の防腐剤、フェナセチン、1-ヒドロキシエタン-1,1-ジホスホン酸、硫酸オキシキノリン等の安定化剤、エタノール、ベンジルアルコール、ベンジルオキシエタノール等の有機溶剤、ヒドロキシエチルセルロース等の水溶性高分子化合物、保湿剤等を含有することができる。また、第1剤及び第2剤の混合液は、水を主たる媒体とすることが好ましい。
第1剤と第2剤の混合液の粘度は、1~300mPa・sとされるが、2~200mPa・s、更には3~100mPa・s、更には5~30mPa・sとするのが好ましい。なお、ここでの粘度は、25℃、株式会社トキメック製B型回転粘度計(モデルTV-10)で、ローターNo.1又はNo.2を用い、60rpmで1分間回転させた後の値とする。測定対象が100mPa・s未満の場合はローターNo.1を用い、100~499mPa・sの場合はローターNo.2を用いて測定する。なお、測定は25℃の恒温槽において測定するものとし、第1剤と第2剤とを混合後ただちに測定するものとし、反応熱による温度変化は無視するものとする。
フォーマー容器の泡吐出手段による空気と混合液との気液混合比は、剤の髪への馴染み易さ及び塗り易さの点から、7~40mL/gが好ましく、15~30mL/gがより好ましい。なお、ここでの気液混合比は次のようにして測定した値である。
本発明において、フォーマー容器は、非エアゾールタイプの容器であって、第1剤と第2剤の混合液を、噴射剤を使用することなく空気と混合して泡状に吐出させるために使用する。フォーマー容器の使用により、吐出させた剤の飛び散りを防止できるという効果も得られる。特に、非エアゾールタイプの容器は、エアゾールタイプの容器に比べて、製品を安価に製造可能であり、高圧ガスの噴射剤が不要であるため、製品を流通においてより安全に取り扱うことができる。
本発明の二剤式泡状染毛剤を使用して毛髪(特に頭髪)を染色するには、予め毛髪を梳かしておくことが好ましい。これにより、後述する再度泡立てる処理中に毛髪がからみにくくなるので、混合液が飛び散るおそれがない。また、毛髪を梳かした後、染毛剤組成物の適用で汎用されているブロッキング操作を行う必要はなく、更にはブロッキング操作を行わないことが好ましい。これにより、後述する染毛剤組成物を毛髪に適用する操作や再度泡立てる操作がやりやすくなる。次いで、本発明の二剤式染毛剤を非エアゾールフォーマー容器内で第1剤と第2剤を混合する。その容器から吐出される泡状の混合液を、直接毛髪に適用してもよく、手又はブラシなどの道具を使って毛髪に適用してもよい。剤の飛び散りや液ダレを防止する観点から、(手袋をした)手にいったん取った後、毛髪に適用することがより好ましい。
表1、3及び5に示す配合組成(質量%)の第1剤と第2剤を調製し、以下に示す評価を行った。
得られた第1剤を-5℃で1ヵ月保存した後、その外観を目視観察し、以下の基準で評価した。
◎:透明である
○:濁りが生じるが、その後25℃に1日置くと透明になる
△:白色沈殿が生じるが、その後25℃に1日置くと白色沈殿が無くなる
×:白色沈殿が生じ、その後25℃に1日置いても白色沈殿が無くならない
図1に示すように、第1剤(A1)の40gを第1容器(2)に、第2剤(A2)60gを第2容器(3)(兼スクイズ容器の容器本体(4);内容積210mL)に、それぞれ充填した。また、スクイズフォーマー(5)(大和製罐社製のS1スクイズフォーマー、メッシュの粗さは混合室150メッシュ、先端200メッシュ、ネットの材質はナイロン)を用意した。
第1剤と第2剤を1:1.5の比率(質量比)で容器本体(4)に入れて混合し、図2の状態とした。このフォーマー容器から混合液を泡状に吐出させ、以下に示す評価を行った。
◎:フォーマー容器を軽く押しても簡単に泡が出る
○:フォーマー容器を強く押すと泡が出る
△:フォーマー容器を強く押してもほとんど泡が出ない
×:フォーマー容器を強く押しても全く泡が出ない
◎:極めて均一できめ細かい泡
○:均一できめ細かい泡
△:不均一できめが粗い泡
×:泡になりきれず、水分が混じる
◎:非常に持続性が高く、放置時まで泡が持続する
○:十分な持続性を有し、塗布後もしばらく泡が持続する
△:塗布する上で問題のない持続性を有するが、塗布した後すぐに泡が消える
×:吐出後すぐに泡が消え、塗布中に液ダレを生じることがある
染毛性については、ヤギ毛の毛束を染色することで評価した。ヤギ毛の毛束(ビューラックス社 1g10cm)に対し、吐出された泡を0.7g塗布し、30℃の恒温槽に30分間放置後、水洗、シャンプーすることにより染色した。当該毛束について、色彩色差計(Konica Minolta社製CR-400)を用いて染色の前後でΔEを測定(N=1)し、表1及び2の配合組成の下欄に示した。
2 第1容器
3 第2容器
4 スクイズ容器の容器本体
5 スクイズフォーマー
6 スクイズ容器
A1 第1剤
A2 第2剤
A3 混合液
Claims (3)
- アルカリ剤を含有する第1剤、過酸化水素を含有する第2剤、及び第1剤と第2剤の混合液を泡状に吐出するための非エアゾールフォーマー容器を含む二剤式泡状染毛剤であって、第1剤中に成分(A)、(B)及び(C1)を含有し、かつ成分(C2)を含有していてもよく、第1剤中における成分(C1)及び(C2)の合計濃度が0.16~0.50mol/kgであり、混合液の25℃における粘度が1~300mPa・sである二剤式泡状染毛剤。
(A)水溶性カチオン性ポリマー
(B)アルカリ金属イオン 0.20~2.00mol/kg
(C1)フェノール性水酸基を有する酸化染料 0.05mol/kg以上
(C2)アニオン界面活性剤 - 第1剤中の成分(A)の含有量が0.02~6質量%である請求項1記載の二剤式泡状染毛剤。
- 第1剤中の成分(C2)の含有量が0~0.45mol/kgである請求項1又は2記載の二剤式泡状染毛剤。
Priority Applications (5)
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US12/995,378 US8025703B2 (en) | 2008-05-30 | 2009-05-29 | Two-part foam hair dye |
EP09754460.5A EP2283803B2 (en) | 2008-05-30 | 2009-05-29 | Two-part foam hair dye |
BRPI0913134A BRPI0913134B1 (pt) | 2008-05-30 | 2009-05-29 | corante para os cabelos espumado de duas partes |
RU2010154439/15A RU2493820C2 (ru) | 2008-05-30 | 2009-05-29 | Двухкомпонентная пенообразующая краска для волос |
CN2009801159845A CN102014853B (zh) | 2008-05-30 | 2009-05-29 | 双剂型泡沫状染发剂 |
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EP (1) | EP2283803B2 (ja) |
JP (1) | JP5294991B2 (ja) |
CN (1) | CN102014853B (ja) |
BR (1) | BRPI0913134B1 (ja) |
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Also Published As
Publication number | Publication date |
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EP2283803A4 (en) | 2015-10-28 |
US20110073128A1 (en) | 2011-03-31 |
TW201000136A (en) | 2010-01-01 |
EP2283803B2 (en) | 2020-11-04 |
TWI407973B (zh) | 2013-09-11 |
BRPI0913134B1 (pt) | 2016-12-06 |
CN102014853B (zh) | 2013-01-02 |
BRPI0913134A2 (pt) | 2016-01-05 |
JP5294991B2 (ja) | 2013-09-18 |
CN102014853A (zh) | 2011-04-13 |
EP2283803A1 (en) | 2011-02-16 |
RU2010154439A (ru) | 2012-07-10 |
EP2283803B1 (en) | 2018-04-11 |
US8025703B2 (en) | 2011-09-27 |
RU2493820C2 (ru) | 2013-09-27 |
JP2010006803A (ja) | 2010-01-14 |
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